CN103553756A - Liquid fertilizer prepared by utilizing treated industrial waste alcohol and chelating nutrient elements - Google Patents
Liquid fertilizer prepared by utilizing treated industrial waste alcohol and chelating nutrient elements Download PDFInfo
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- CN103553756A CN103553756A CN201310578658.6A CN201310578658A CN103553756A CN 103553756 A CN103553756 A CN 103553756A CN 201310578658 A CN201310578658 A CN 201310578658A CN 103553756 A CN103553756 A CN 103553756A
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Abstract
The invention relates to a liquid fertilizer prepared by utilizing treated industrial waste alcohol and chelating nutrient elements, which is applied to agriculture and forest fields. The liquid fertilizer comprises the following main active ingredients in parts by weight: 20-80 parts of harmlessly treated industrial waste alcohol, 5-30 parts of potassium nitrite, 10-30 parts of monoammonium phosphate, 5-20 parts of potassium dihydrogen phosphate, 5-25 parts of urea, 5-25 parts of potassium sulfate, 0.5-5.5 parts of zinc sulfate, 0.1-4.5 parts of manganese sulfate, 1.5-5 parts of magnesium sulfate, 0.1-2.5 parts of ferrous sulfate, 0.1-0.5 part of ammonium molybdate, and 2-10 parts of boric acid, the pH value of the fertilizer is regulated to be neutral to slightly acidic. According to the liquid fertilizer, the problem that wastes pollute the environment by changing wastes into valuables, the produced fertilizer is abundant in various nutrition elements needed by plants, activate the physiological activity of crops, and enhance the nutrient element absorption and disease-resistant capability of crops; the liquid fertilizer is applicable to drip irrigation, flushing and foliage spray of fruit trees, vegetables and land for growing field crops, thus being an organic-inorganic green liquid fertilizer which is widely applied.
Description
Technical field
The present invention relates to utilize produce after industrial spirit liquid waste disposal agricultural organic, inorganic liquid fertilizer, is applied to agricultural field.Particularly relate to utilize industrial spirit waste liquid to produce the nutritive ingredient liquid fertilizer containing various plants demand.
Background technology
Current China planting patterns is progressively to agricultural modernization equipment as spray drip irrigation facility and the development of simplifying of farm crop cultivation mode, constantly rise large stretch of plantation and planting base in recent years, modern agriculture obtains tremendous development, the input in agriculture production, the degeneration-resistant mitigation work of farm crop along with equipment of mechanization, the various water soluble fertilizers that can supplement the nutrients for farm crop have fast obtained fast development, along with agricultural science and technology develops rapidly with the structure of agricultural production and constantly adjusts to new and high technology, the theory of the scientific and reasonable fertilising of farm crop is rooted in the hearts of the people.The complete water-soluble liquid organic fertilizer that adds various nutritive elements has improvement soil, strengthens the effect of plant receptivity, raising agricultural output and quality.Novel liquid fertilizer will greatly promote the development of modern agriculture with high efficiency with its outstanding advantage.
Summary of the invention
The object of the invention is to develop a kind of organic-inorganic sequester liquids fertilizer of full nutritive element, and be can meet field crop and extraordinary economic crops growing needs containing multiple amino acids, humic acid, organic matter, macroelement and in trace element chelated liquid fertilizer.
The invention provides a kind of industrial spirit waste liquid and nutritive element chelating of processing of utilizing and prepare liquid fertilizer, main raw material forms by weight: mother liquor 30-80 part proportionally after harmless treatment, add solid material zinc sulfate 0.5-5.5 part, manganous sulfate 0.1-4.5 part, sal epsom 1.5-5 part, ferrous sulfate 0.1-2.5 part, ammonium molybdate 0.01-0.5 part, boric acid 2-10 part, cupric nitrate 0.5-2 part.Be heated under 40-90 degree celsius temperature, under normal pressure, stirring reaction 1-6 hour, regulates pH value between 4-8, carries out chelatropic reaction; After having reacted, continue again to add macroelement raw material, addition is: containing saltpetre 5-30 part, monoammonium phosphate 10-30 part, potassium primary phosphate 5-20 part, urea 5-25 part, vitriolate of tartar 5-25 part, adjusting pH is 4-8, chelatropic reaction 1-6 hour under 40-90 degree celsius temperature, regulates pH value 5-6.5, makes the green organic liquid fertilizer containing multiple amino acids, humic acid, macroelement, middle trace element.
Utilize organic liquid fertilizer of the mother liquor production of alcohol slops harmless treatment to there is good water solubility, liquid fluidity is good, be rich in multiple amino acids, humic acid, organic content high, the complete water-soluble Liquid Fertilizer of green organic-inorganic of macroelement, middle microelement match science.
Embodiment
The present invention, in order to realize above-mentioned target, is further illustrated by following examples, and the organic chelated liquid fertilizer of the different proportionings between trace element in can realizing, but protection scope of the present invention is not limited to this preparation method.
Embodiment 1: 30 parts, harmless treatment mother liquor, adds 0.5 part, solid material zinc sulfate, 2 parts of manganous sulfates, 2 parts, sal epsom, 0.1 part, ferrous sulfate, 0.03 part of ammonium molybdate, 2 parts of boric acid.Regulating pH value is 7, be heated under 60 degree celsius temperature, and under normal pressure, stirring reaction 2 hours,, carry out chelatropic reaction; Continue again to add containing 5 parts, saltpetre, 15 parts of monoammonium phosphates, 7 parts of potassium primary phosphates, 15 parts, urea, 5 parts of vitriolate of tartar, regulating pH is 7,60 degrees Celsius of lower chelatropic reactions 2 hours, regulate pH value to 6, make the green organic liquid fertilizer containing multiple amino acids, humic acid, macroelement, middle trace element.
Embodiment 2: 40 parts, harmless treatment mother liquor, adds 0.7 part, solid material zinc sulfate, 0.5 part of manganous sulfate, 1 part, sal epsom, 0.2 part, ferrous sulfate, 0.05 part of ammonium molybdate, 3 parts of boric acid.Regulate pH value in 7.5 left and right, be heated under 70 degree celsius temperature, under normal pressure, stirring reaction 3 hours, carries out chelatropic reaction; Continue again to add containing 7 parts, saltpetre, 10 parts of monoammonium phosphates, 7 parts of potassium primary phosphates, 15 parts, urea, 8 parts of vitriolate of tartar, add suitable quantity of water, regulate pH value in 7.5 left and right, at 70 ℃, chelatropic reaction 3 hours, regulates pH value to 6, makes the green organic liquid fertilizer containing multiple amino acids, humic acid, macroelement, middle trace element.
Embodiment 3: 60 parts, harmless treatment mother liquor, adds 1 part, solid material zinc sulfate, 0.5 part of manganous sulfate, 3 parts, sal epsom, 0.5 part, ferrous sulfate, 0.03 part of ammonium molybdate, 2 parts of boric acid.Regulating pH value is 7.5, is heated under 75 degree celsius temperature, and under normal pressure, stirring reaction 5 hours, carries out chelatropic reaction; Continue again to add containing 5 parts, saltpetre, 12 parts of monoammonium phosphates, 10 parts of potassium primary phosphates, 13 parts, urea, 5 parts of vitriolate of tartar, add suitable quantity of water, regulating pH value is 7.5, be heated under 75 degrees Celsius, under normal pressure, stirring reaction 3 hours, regulate pH value to 6, make the green organic liquid fertilizer containing multiple amino acids, humic acid, macroelement, middle trace element.
Embodiment 4: 70 parts, harmless treatment mother liquor, adds 0.5 part, solid material zinc sulfate, 0.2 part of manganous sulfate, 1 part, sal epsom, 0.15 part, ferrous sulfate, 0.02 part of ammonium molybdate, 2 parts of boric acid.Regulate pH value in 7.5 left and right, be heated under 80 degrees Celsius, under normal pressure, stirring reaction 4 hours, carries out chelatropic reaction; Continue again to add containing 5 parts, saltpetre, 10 parts of monoammonium phosphates, 10 parts of potassium primary phosphates, 5 parts, urea, 5 parts of vitriolate of tartar, add suitable quantity of water, regulate pH value in 7.5 left and right, be heated under 80 degrees Celsius, chelatropic reaction 3 hours, regulates pH value to 6, makes the green organic liquid fertilizer containing multiple amino acids, humic acid, macroelement, middle trace element.
Embodiment described above has just illustrated ultimate principle of the present invention; it is the restriction that is subject to above-mentioned example that the present invention has more than; without departing from the spirit and scope of the present invention; can have multiple changes and improvements, so these changes and improvements all should require to fall in claimed scope.
Weight quota unit in each technical scheme of the present invention can for gram or kilogram (kilogram) or ton, can be also other unit.
Claims (2)
1. a liquid fertilizer that utilizes the industrial spirit waste liquid processed and nutritive element chelating to prepare, it is characterized in that: by aminoacids complex, humic acid generation sequestering action in plant desired nutritional element and the industrial spirit waste liquid processed, more supplementary macroelement obtains complete water-soluble organic liquid fertilizer.
2. as claimed in claim 1 containing a kind of liquid fertilizer that utilizes the industrial spirit waste liquid processed and nutritive element chelating to prepare, its preparation method is as follows:
(1) toward adding solid material in the mother liquor obtaining after 30-80 part is processed: zinc sulfate 0.5-5.5 part, manganous sulfate 0.1-4.5 part, sal epsom 1.5-5 part, ferrous sulfate 0.1-2.5 part, ammonium molybdate 0.01-0.5 part, boric acid 2-10 part, cupric nitrate 0.5-2 part, regulates pH value between 4-8, be heated under 40-90 degree celsius temperature, under normal pressure, stirring reaction 1-6 hour, carries out chelatropic reaction.
(2) after material reaction is complete, continue to add containing saltpetre 5-30 part, monoammonium phosphate 10-30 part, potassium primary phosphate 5-20 part, urea 5-25 part, vitriolate of tartar 5-25 part, regulate pH value between 4-8, be heated under 40-90 degree celsius temperature, under normal pressure, stirring reaction 1-6 hour, carries out chelatropic reaction, adjusting pH is 5-6.5, makes the green organic liquid fertilizer containing amino-acid chelate, humic acid inner complex, macroelement, middle trace element.
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| CN201310578658.6A CN103553756A (en) | 2013-11-19 | 2013-11-19 | Liquid fertilizer prepared by utilizing treated industrial waste alcohol and chelating nutrient elements |
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Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104058844A (en) * | 2014-06-09 | 2014-09-24 | 李学春 | Method for preparing multielement chelate fertilizer by use of threonine mother liquor |
| CN104529676A (en) * | 2014-12-19 | 2015-04-22 | 深圳市芭田生态工程股份有限公司 | Preparation method of organic liquid compound fertilizer rich in nitrogen, phosphorus and potassium |
| CN104860781A (en) * | 2015-05-05 | 2015-08-26 | 宁夏共享生物化工有限公司 | Lychee special fertilizer containing biochemical humic acid and preparation method thereof |
| CN105294319A (en) * | 2015-12-02 | 2016-02-03 | 江苏远山生物技术有限公司 | Method for preparing liquid fertilizer by using beneficial microorganism fermentation liquor |
| CN105330428A (en) * | 2014-11-15 | 2016-02-17 | 深圳市芭田生态工程股份有限公司 | Method for producing water-soluble small-molecule organic matter liquid fertilizer through acid hydrolysis method |
| CN105367165A (en) * | 2014-11-15 | 2016-03-02 | 深圳市芭田生态工程股份有限公司 | Four-state nitrogen organic liquid fertilizer and its preparation method and use |
| CN105367167A (en) * | 2014-11-15 | 2016-03-02 | 深圳市芭田生态工程股份有限公司 | Preparation method of trace element-containing organic carbon liquid fertilizer |
| CN105461451A (en) * | 2015-12-24 | 2016-04-06 | 北京沃土天地生物科技股份有限公司 | Microbial fermentation water-soluble fertilizer and preparation method thereof |
| CN105777353A (en) * | 2016-03-17 | 2016-07-20 | 广州甘蔗糖业研究所 | Bioactive organic chelate liquid fertilizer and preparation method thereof |
| CN105819968A (en) * | 2015-04-02 | 2016-08-03 | 贵州芭田生态工程有限公司 | Fertilizer additive containing organically complexed medium and trace elements and preparation method of additive |
| CN105859397A (en) * | 2015-04-21 | 2016-08-17 | 贵州芭田生态工程有限公司 | Complexing agent for complexing medium trace elements, preparation method thereof and application thereof |
| CN105859399A (en) * | 2015-04-21 | 2016-08-17 | 贵州芭田生态工程有限公司 | Fertilizer additive containing organic complexed medium trace elements and preparation method thereof |
| CN106134873A (en) * | 2016-06-22 | 2016-11-23 | 广西壮族自治区农业科学院农业资源与环境研究所 | A kind of green manure paddy rice crop rotation produces the method for selenium-rich rice |
| CN106518332A (en) * | 2016-10-31 | 2017-03-22 | 嘉善弘欣化工厂（普通合伙） | Formula and production method for humus acid liquid fertilizer |
| CN107628838A (en) * | 2017-10-24 | 2018-01-26 | 山东省农业科学院 | A kind of Eco-friendly foliar fertilizer for being applied to vegetables or fruit and preparation method thereof |
| CN112778045A (en) * | 2021-01-06 | 2021-05-11 | 陕西科技大学 | Humic acid liquid fertilizer and method for preparing same by utilizing fracturing flowback fluid of oil and gas field |
| CN113087560A (en) * | 2019-12-23 | 2021-07-09 | 纪忠孝 | Liquid organic fertilizer and preparation method thereof |
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Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104058844B (en) * | 2014-06-09 | 2016-04-20 | 李学春 | Threonine mother liquor is utilized to prepare the method for multicomponent chelate thing fertilizer |
| CN104058844A (en) * | 2014-06-09 | 2014-09-24 | 李学春 | Method for preparing multielement chelate fertilizer by use of threonine mother liquor |
| CN105367167B (en) * | 2014-11-15 | 2019-02-26 | 深圳市芭田生态工程股份有限公司 | A kind of preparation method of the organic carbon Liquid Fertilizer containing microelement |
| CN105330428B (en) * | 2014-11-15 | 2019-02-12 | 深圳市芭田生态工程股份有限公司 | A kind of method of acid hydrolyzation production soluble small molecular organic matter liquid fertilizer |
| CN105330428A (en) * | 2014-11-15 | 2016-02-17 | 深圳市芭田生态工程股份有限公司 | Method for producing water-soluble small-molecule organic matter liquid fertilizer through acid hydrolysis method |
| CN105367165A (en) * | 2014-11-15 | 2016-03-02 | 深圳市芭田生态工程股份有限公司 | Four-state nitrogen organic liquid fertilizer and its preparation method and use |
| CN105367167A (en) * | 2014-11-15 | 2016-03-02 | 深圳市芭田生态工程股份有限公司 | Preparation method of trace element-containing organic carbon liquid fertilizer |
| CN104529676B (en) * | 2014-12-19 | 2017-11-07 | 深圳市芭田生态工程股份有限公司 | A kind of preparation method of the organic liquid compound fertilizer rich in N P and K |
| CN104529676A (en) * | 2014-12-19 | 2015-04-22 | 深圳市芭田生态工程股份有限公司 | Preparation method of organic liquid compound fertilizer rich in nitrogen, phosphorus and potassium |
| CN105819968A (en) * | 2015-04-02 | 2016-08-03 | 贵州芭田生态工程有限公司 | Fertilizer additive containing organically complexed medium and trace elements and preparation method of additive |
| CN105859399A (en) * | 2015-04-21 | 2016-08-17 | 贵州芭田生态工程有限公司 | Fertilizer additive containing organic complexed medium trace elements and preparation method thereof |
| CN105859397A (en) * | 2015-04-21 | 2016-08-17 | 贵州芭田生态工程有限公司 | Complexing agent for complexing medium trace elements, preparation method thereof and application thereof |
| CN104860781A (en) * | 2015-05-05 | 2015-08-26 | 宁夏共享生物化工有限公司 | Lychee special fertilizer containing biochemical humic acid and preparation method thereof |
| CN105294319A (en) * | 2015-12-02 | 2016-02-03 | 江苏远山生物技术有限公司 | Method for preparing liquid fertilizer by using beneficial microorganism fermentation liquor |
| CN105461451A (en) * | 2015-12-24 | 2016-04-06 | 北京沃土天地生物科技股份有限公司 | Microbial fermentation water-soluble fertilizer and preparation method thereof |
| CN105777353A (en) * | 2016-03-17 | 2016-07-20 | 广州甘蔗糖业研究所 | Bioactive organic chelate liquid fertilizer and preparation method thereof |
| CN106134873A (en) * | 2016-06-22 | 2016-11-23 | 广西壮族自治区农业科学院农业资源与环境研究所 | A kind of green manure paddy rice crop rotation produces the method for selenium-rich rice |
| CN106518332A (en) * | 2016-10-31 | 2017-03-22 | 嘉善弘欣化工厂（普通合伙） | Formula and production method for humus acid liquid fertilizer |
| CN107628838A (en) * | 2017-10-24 | 2018-01-26 | 山东省农业科学院 | A kind of Eco-friendly foliar fertilizer for being applied to vegetables or fruit and preparation method thereof |
| CN113087560A (en) * | 2019-12-23 | 2021-07-09 | 纪忠孝 | Liquid organic fertilizer and preparation method thereof |
| CN112778045A (en) * | 2021-01-06 | 2021-05-11 | 陕西科技大学 | Humic acid liquid fertilizer and method for preparing same by utilizing fracturing flowback fluid of oil and gas field |
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Application publication date: 20140205 |