CN103520070A - Highly-elastic non-supported environmentally-friendly gel mask and preparation method thereof - Google Patents
Highly-elastic non-supported environmentally-friendly gel mask and preparation method thereof Download PDFInfo
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- CN103520070A CN103520070A CN201310464365.5A CN201310464365A CN103520070A CN 103520070 A CN103520070 A CN 103520070A CN 201310464365 A CN201310464365 A CN 201310464365A CN 103520070 A CN103520070 A CN 103520070A
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Abstract
The invention relates to a highly-elastic non-supported environmentally-friendly gel mask and a preparation method thereof. The gel mask is formed by dissolving an olefin monomer M1, a biological polymer M2, a chemical cross-linking agent M3, a physical cross-linking agent M4, plant extract essential oil, whitening components and anti-ageing active components in water, and polymerizing. The preparation method comprises the following steps: 1, preparing aqueous solutions of the M1, M2, M3 and M4; 2, preparing an essence liquid; 3, mixing to prepare a prepolymer liquid; 4, preparing the gel mask; and 5, packaging the gel mask. The gel mask prepared through the method has the advantages of moderate viscosity, good elasticity, good ductility and toughness, no need of the application of a non-woven fabric to improve the mechanic strength, carrying convenience, adjustable thickness, and repeatable use, and allows the viscoelasticity, the skin endophilicity and the moisture retention performance of the mask to be adjusted by adjusting the monomer concentration, the feeding ratio, the whitening and anti-ageing active components, the reaction temperature, the water content and the feeding sequence. The gel mask can be used in the fields of skin care, moisture retention, beauty treatment, anti-ageing and the like.
Description
Technical field
The present invention relates to macromolecular material, cosmetics and biomedicine field, be specifically related to a kind of high resiliency without supporting environment-friendly type gel mask and preparation method thereof.
Background technology
Facial film, is a classification in skin care item, and it is substantially the most also that most important object is to make up makeup removing and the still cleaning of deficiency that washes one's face, and realizes on this basis other maintenance function, for example replenishing water and preserving moisture, whitening, defying age etc.The principle of facial film, utilize exactly the blink that covers face, extraneous air and the pollution of temporary transient isolation, improves skin temperature, the pore expansion of skin, promote sweat gland secretion and metabolism, make the oxygen content of skin increase, be conducive to the oil substances that skin is got rid of the metabolic product of epidermis cell and accumulation, the moisture in facial film infiltrates the horny layer of epidermis, it is soft that skin becomes, and skin naturally light is flexible.
The form of facial film mainly contains four kinds, mud cream type, tear-pull, gel-type, wet paper towel type.Mud cream profile film common are seaweed mask, sludge facial film etc., and tear-pull facial film is modal is exactly that the special-purpose nose of blackhead pastes, and gel-type is the most famous with sleep facial film, and wet paper towel formula is exactly generally the face paper that is infiltrating beautifying liquid of mmic package.But mud paste smearing mask need to be smeared layer by layer in face, use very inconveniently, with the rear water of also wanting, clean waste water resource.The facial film of applying ointment or plaster of the non-woven fabrics dipping nutritional solution of wet paper towel type need to take out while using from packaging bag, and the nutritional solution water clock of dipping, can pollute other article, uses inconvenience; Secondly, the facial film adhesiveness of applying ointment or plaster of non-woven fabrics dipping nutritional solution is bad, and easily perk Huo Cong face comes off; Moreover the ability of very thin layer of non-woven fabric dipping nutritional solution is limited, some nutrient or active component are difficult to be attached to above non-woven fabrics.
From the material of facial film, weave cotton cloth, cotton, biological fiber, need washing gluey and need remove pasty state etc.The advantage of weaving cotton cloth is to adsorb a large amount of essences, and is difficult for drippage, but shortcoming is to apply when of a specified duration, the moisture content resorption of skin can be walked.The advantage of cotton is that comfort level, air permeability are good, is difficult for causing sensitivity, but shortcoming is absorption affinity deficiency, and the essence of slightly walking about just easily drips.Needing the gluey advantage of washing is to adjust consumption according to skin quality or mood, and shortcoming is to apply rear 10-15 minute need wash.The effect that the advantage that need remove pasty state is exfoliation, remove deep layer dirt is good, can not espressiove when shortcoming is dry, otherwise easily have wrinkle to produce.To sum up analyze, be necessary to prepare a kind of adsorptivity, good permeability, without cleaning, have certain elasticity and can be directly used in facial facial film.
Macromolecule hydrogel is the high polymer that a class has three-dimensional net structure, because it has unique hydrophilic, water conservation and good biocompatibility is widely used in the fields such as biological engineering, medicines and health protection and beauty treatment.Hydrogel facial film is to using hydrophilic gel as mask matrix, and the required nutritional labeling of a large amount of skin and moisture are rich in inside, and stronger applicating property is non-stimulated to skin.If any following effect: deep layer moisturizing supplements the nutrients, accelerate metabolism; Improve skin coarse, intense darkness without light pool; Desalination fossil pigments, desalinates black, xanthelasma; Keratodermatitis moisturizing, activating cell, subtracts light microgroove, and skin compacts.
Chinese patent CN102370585A discloses a kind of method of preparing gel mask matrix, and formula adjoins pyrrolidone, wetting agent, cross-linking agent, EDTA, antibacterial, deionized water and PH regulator by carbomer, polyacrylic resin, polyvinyl alcohol, sodium carboxymethylcellulose, polyethylene and forms.Yet this formula has the following disadvantages: 1. its cross-linking agent is unicity physical crosslinking agent aluminum glycinate or clad aluminum salt, and made mask matrix elasticity, water-retaining property and intensity are poor; 2. there is potential safety hazard as benzoic acid in the composition of antibacterial, and human body skin may produce anaphylaxis to it; 3. formula gained solution need to regulate its Acidity of Aikalinity with alkaline PH regulator, regulates like this one side wayward, can cause the residual of harmful components on the other hand.
Chinese utility model patent CN202044533U discloses a kind of far infrared gel mask, comprises facial film main body and is arranged on eyelet, the ,Zui hole, nostril in facial film main body, and described facial film main body comprises far infrared emission layer and thermoplastic gel layer.Far infrared releasing layer produces thermogenetic effect by the releasing far infrared face that makes, gel layer is sealed Far-infrared ray tepid effect is produced to the effect of gathering by skin, make skin, cell and micromolecule that a series of variations occur simultaneously, be conducive to penetrating and absorbing of far infrared, thereby strengthen repair function.
Chinese invention patent CN1883438 discloses a kind of temperature responsive intelligent facial mask and preparation method thereof, adopting chitosan-modified temperature sensitivity N-isopropylacrylamide/polyurethane copolymer hydrogel to graft on cellulosic fabric forms, its advantage is, can near body temperature, there is reversible swelling and contraction in intelligent aqueous gel capable, and the introducing of polyurethane has suppressed the high temperature dehydration phenomenon of PNIPAM itself, by PNIPAM and polyurethane grafted in cellulosic nonwoven fabric surface, non-woven fabrics plays the effect of supporter, improved the intensity of gel, natural alkaline polysaccharide chitosan is coupled to gel film outer surface, not only improved the comfort level of facial film, skin affinity, and give facial film antibiotic property.But due to N-isopropylacrylamide and polyurethane expensive, preparation method is complicated, is difficult to large-scale production.In addition, because non-woven fabrics is as support, make facial film not all to be fitted in face, leave part space.
The present invention has considered the function of facial film, the humectant properties of macromolecule hydrogel and mechanical strength; and environment friendly; facial film technology and gel characteristic are mutually combined; give on the one hand skin affinity, moisture retention and the low-carbon (LC) that facial film is good; when not using non-woven fabrics, realize on the other hand gel mask preparation technology's nontoxicization, production high efficiency; and production scale, promote the maintenance to female face.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, provide a kind of high resiliency without supporting environment-friendly type gel mask and preparation method thereof, because facial film material is gel, itself have good moisture retention, high combination outlet capacity, is easy to fit with skin.Gel mask viscosity of the present invention is moderate, elasticity is high, stretch bending is turned round etc. under distortion not easy fracture, thereby without non-woven fabrics as support, the gel mask of preparation can directly be used, there is good biocompatibility and skin of face affinity, and Reusability, has the advantages such as environmental protection and low-carbon (LC) for a long time.
The present invention is achieved by the following technical solutions:
A kind of high resiliency without support environment-friendly type gel mask by olefin monomer M1, biopolymer M2, chemical cross-linking agent M3, physical crosslinking agent M4, plant extraction quintessence oil, whitening composition and activity of fighting against senium composition is water-soluble is polymerized.
Described olefin monomer M1 is acrylamide, Methacrylamide, NIPA, N hydroxymethyl acrylamide, 2-(dimethylamino) ethyl-Methacrylamide, 2-hydroxyethyl methacrylate, NVP, acrylic acid, methacrylic acid, tert-butyl acrylate, sodium acrylate, 2-acrylamide-2-methyl isophthalic acid-propane sulfonic acid, Polyethyleneglycol methacrylate, its inorganic salt, with and composition thereof.
Described biopolymer M2 is the mixture of a kind of or any two kinds of compositions in sodium alginate, chitosan, xanthan gum, humic acid, cellulose, polylactic acid, polylysine, polyglutamic acid, polyvinyl alcohol, polyhydroxyalkanoate, polyanhydride, collagen protein, sericin shape globulin.
Described chemical cross-linking agent M3 is N, any one in N '-methylene-bisacrylamide, two (methyl) acrylic acid glycol ester, diglycidyl ether, epoxychloropropane and glutaraldehyde.
Described physical crosslinking agent M4 is any one in magnesium hectorite, hectorite, magnesium soap stone, sauconite or lithium magnesium silicate.
The described extraction quintessence oil of planting is any one in Flos Rosae Rugosae quintessence oil, Herba Lysimachiae foenum-graeci quintessence oil, Flos Lilii viriduli quintessence oil.
Described whitening composition is one or more in Margarita powder, aloe juice, natural complex C, Semen Tritici aestivi germ oil.
Described activity of fighting against senium composition is one or more in natural Vitamin E, epithelical cell growth factor EGF, superoxide dismutase SOD, hyaluronic acid, wrinkle removal peptide, grape polyphenols, ursolic acid.
A kind of high resiliency of the present invention comprises the steps: without the preparation method that supports environment-friendly type gel mask
1) preparation of A liquid: olefin monomer M1, biopolymer M2, chemical cross-linking agent M3 and physical crosslinking agent M4 are joined in deionized water successively, be mixed with the solution that mass concentration is 10-15%, often add function monomer one time, stir 5-25min, until form the mixed solution of thick homogeneous;
2) preparation of B liquid: essence (planting extraction quintessence oil, whitening composition, activity of fighting against senium composition) is joined in deionized water successively, and magnetic agitation 3-10min, until form the dispersion of homogeneous;
3) being mixed of pre-polymerization liquid: by step 2) the B liquid of preparation is poured step 1 into) in the A liquid that makes, magnetic agitation 5-15min, when presenting homogeneous thick, add immediately initiator ammonium persulfate or potassium peroxydisulfate, catalyst tetramethylethylenediamine or sodium sulfite, make pre-polymerization liquid;
4) it is in 0.1-5mm, the mould corresponding with human body face shape that the pre-polymerization liquid preparation of gel mask: by step 3) making is poured thickness into, in temperature, be at 40-70 ℃, to carry out polyreaction 1～4h, can make high resiliency without supporting environment-friendly type gel mask;
5) packing of gel mask: the high resiliency making is carried out to heat sealed package without supporting environment-friendly type gel mask.
Step 1 of the present invention) in, each constituent mass percentage ratio of A liquid is: olefin monomer M1:10-15%, biopolymer M2:1.5-3%, chemical cross-linking agent M3:0-0.1 ‰, physical crosslinking agent M4:0-10 ‰, deionized water: 85%-90%.
Step 2 of the present invention) in, each constituent mass ratio of B liquid is: plant extraction quintessence oil: 0-1%, whitening composition 0-2%, activity of fighting against senium composition 0-3%, deionized water: 94-99%.
Step 3 of the present invention) initiator in and catalyst are 1% and 3 ‰ of olefin monomer M1.
Step 4 of the present invention) mould in is relative with human body face shape, leaves the position of eyes, nose and face, can not cause that the visual field is unclear, hypopnea, dysphagia.
Step 5 of the present invention) heat sealed package in is for directly sealing composite membrane by gel mask laminating.
Described high resiliency regulates by adjusting monomer concentration, rate of charge, cross-linking agent kind and consumption, whitening and activity of fighting against senium composition, reaction temperature, water content and charging sequence without the viscosity, elasticity, skin affinity and the performance of keeping humidity that support environment-friendly type gel mask.
Compare with preparation method with existing gel mask, the present invention has following advantage:
1, moderate, the good springiness of viscosity, has good ductility and toughness, and stretch bending is turned round etc. under foreign object effect not cracky, and can resile fast.
2, do not add the chemical components that antibacterial, PH regulator and antiseptic etc. may be harmful, added natural, the green harmless compositions such as biopolymer of biocompatibility and skin excellent affinity, completely harmless to human body.
3, the non-woven fabrics that do not need to fit improves gel mask mechanical strength, and need not have on layer of non-woven fabric in use again, causes face stiff, greatly simplifies thus manufacturing procedure, reduces production costs, and is convenient to consumer and uses.
4, easy to carry, thickness is adjustable, reusable.Described high resiliency is lightweight, easy to carry without supporting environment-friendly type gel mask, can adjust shape and thickness according to consumer's custom.In addition, after gel mask is dry, it is directly immersed in to 0.5-1h in essence, can reuses.
5, preparation method of the present invention is simple, raw material is easy to get, easy and simple to handle, the response time is short, reaction condition is gentle, on original synthesis device, can make.
Accompanying drawing explanation
Fig. 1 is that high resiliency is without supporting environment-friendly type gel mask
Specific embodiments
The present invention can summarize with other the concrete form without prejudice to spirit of the present invention and principal character.Therefore; following specific embodiments is only not used in and limits the scope of the invention for the present invention is described; other any do not run counter to change, the modification done under spirit of the present invention and principle, substitutes, combination, simplify; all should be equivalent substitute mode, within being included in protection scope of the present invention.In addition should be understood that those skilled in the art can make various changes or modifications the present invention after having read the content of the present invention's instruction, these equivalent form of values fall within the application's appended claims limited range equally.
Embodiment 1
1) preparation of A liquid: by 0.6g acrylamide, 0.09g sodium alginate, 0.01g sericin, 0.0006gN, N '-methylene-bisacrylamide and 0.003g lithium magnesium silicate join in deionized water successively, be mixed with mass concentration and be 13% aqueous solution, often add primary material, all stir 10min, until form the thick solution of homogeneous;
2) preparation of B liquid: 0.025g Flos Lilii viriduli quintessence oil, 0.005g Margarita powder, 0.02g natural Vitamin E are joined in 5g deionized water successively, and magnetic agitation 7min, until form the dispersion of homogeneous;
3) being mixed of pre-polymerization liquid: by step 2) the B liquid of preparation is poured step 1 into) in the A liquid that makes, magnetic agitation 5min, when presenting homogeneous thick, adds 0.006g Ammonium persulfate., 0.001g tetramethylethylenediamine immediately, makes pre-polymerization liquid;
4) it is in 1mm, the mould corresponding with human body face shape that the pre-polymerization liquid preparation of gel mask: by step 3) making is poured thickness into, in temperature, is at 50 ℃, to carry out polyreaction 3h, can make high resiliency without supporting environment-friendly type gel mask;
5) packing of gel mask: the high resiliency making is carried out to heat sealed package without supporting environment-friendly type gel mask.
Embodiment 2
1) preparation of A liquid: 1g n-methylolacrylamide, 0.05g sodium alginate, 0.05g polylysine, 0.0001g glutaraldehyde and 0.002g magnesium hectorite are added in deionized water successively, be mixed with mass concentration and be 11% aqueous solution, add again and often add primary material, all stir 20min, until form uniform solution;
2) preparation of B liquid: 0.01g Herba Lysimachiae foenum-graeci quintessence oil, 0.02g aloe juice, 0.02g epithelical cell growth factor EGF are joined in 2g deionized water successively, and magnetic agitation 5min, until form the dispersion of homogeneous;
3) being mixed of pre-polymerization liquid: by step 2) the B liquid of preparation is poured step 1 into) in the A liquid that makes, magnetic agitation 8min, when presenting homogeneous thick, adds 0.01g potassium peroxydisulfate, 0.002g tetramethylethylenediamine immediately, makes pre-polymerization liquid;
4) it is in 0.5mm, the mould corresponding with human body face shape that the pre-polymerization liquid preparation of gel mask: by step 3) making is poured thickness into, in temperature, is at 70 ℃, to carry out polyreaction 1h, can make high resiliency without supporting environment-friendly type gel mask;
5) packing of gel mask: the high resiliency making is carried out to heat sealed package without supporting environment-friendly type gel mask.
Embodiment 3
1) preparation of A liquid: 0.8gN-N-isopropylacrylamide, 0.3g polyvinyl alcohol, 0.0001g glycidyl ether and 0.01g hectorite are added in deionized water successively, be mixed with mass concentration and be 12% aqueous solution, add again and often add primary material, all stir 15min, until form uniform solution;
2) preparation of B liquid: 0.035g Flos Rosae Rugosae quintessence oil, 0.007g natural complex C, 0.07g superoxide dismutase SOD are joined in 7g deionized water successively, and magnetic agitation 5min, until form the dispersion of homogeneous;
3) being mixed of pre-polymerization liquid: by step 2) the B liquid of preparation is poured step 1 into) in the A liquid that makes, magnetic agitation 10mmin, when presenting homogeneous thick, adds 0.02g Ammonium persulfate., 0.005g sodium sulfite immediately, makes pre-polymerization liquid;
4) it is in 1mm, the mould corresponding with human body face shape that the pre-polymerization liquid preparation of gel mask: by step 3) making is poured thickness into, in temperature, is at 40 ℃, to carry out polyreaction 4h, can make high resiliency without supporting environment-friendly type gel mask;
5) packing of gel mask: the high resiliency making is carried out to heat sealed package without supporting environment-friendly type gel mask.
Embodiment 4
1) preparation of A liquid: by 1.2g 2-hydroxyethyl methacrylate, 0.3g sericin shape globulin, 0.0001gN, N '-methylene-bisacrylamide and 0.02g lithium magnesium silicate add in deionized water successively, be mixed with mass concentration and be 14% aqueous solution, add again and often add primary material, all stir 20min, until form uniform solution;
2) preparation of B liquid: 0.015g Flos Lilii viriduli quintessence oil, 0.003g Semen Tritici aestivi germ oil, 0.03g hyaluronic acid are joined in 3g deionized water successively, and magnetic agitation 5min, until form the dispersion of homogeneous;
3) being mixed of pre-polymerization liquid: by step 2) the B liquid of preparation is poured step 1 into) in the A liquid that makes, magnetic agitation 12min, when presenting homogeneous thick, adds 0.01g potassium peroxydisulfate, 0.002g sodium sulfite immediately, makes pre-polymerization liquid;
4) it is in 1.5mm, the mould corresponding with human body face shape that the pre-polymerization liquid preparation of gel mask: by step 3) making is poured thickness into, in temperature, is at 60 ℃, to carry out polyreaction 2h, can make high resiliency without supporting environment-friendly type gel mask;
5) packing of gel mask: the high resiliency making is carried out to heat sealed package without supporting environment-friendly type gel mask.
Embodiment 5
1) preparation of A liquid: 1.5g sodium acrylate, 0.15g collagen protein, 0.05g chitosan, 0.0002g epoxychloropropane and 0.002g hectorite are added in deionized water successively, be mixed with mass concentration and be 13% aqueous solution, add again and often add primary material, all stir 15min, until form uniform solution;
2) preparation of B liquid: 0.04g Herba Lysimachiae foenum-graeci quintessence oil, 0.12g Margarita powder, 0.08g grape polyphenols are joined in 8g deionized water successively, and magnetic agitation 5min, until form the dispersion of homogeneous;
3) being mixed of pre-polymerization liquid: by step 2) the B liquid of preparation is poured step 1 into) in the A liquid that makes, magnetic agitation 15min, when presenting homogeneous thick, adds 0.01g Ammonium persulfate., 0.001g tetramethylethylenediamine immediately, makes pre-polymerization liquid;
4) it is in 2mm, the mould corresponding with human body face shape that the pre-polymerization liquid preparation of gel mask: by step 3) making is poured thickness into, in temperature, is at 60 ℃, to carry out polyreaction 2h, can make high resiliency without supporting environment-friendly type gel mask;
5) packing of gel mask: the high resiliency making is carried out to heat sealed package without supporting environment-friendly type gel mask.
Embodiment 6
1) preparation of A liquid: by 2g methacrylic acid, 0.03g polyhydroxyalkanoate, 0.0001gN, N '-methylene-bisacrylamide and 0.01g lithium magnesium silicate add in deionized water successively, be mixed with mass concentration and be 12% aqueous solution, add again and often add primary material, all stir 25min, until form uniform solution;
2) preparation of B liquid: 0.002g Flos Rosae Rugosae quintessence oil, 0.04g aloe juice, 0.02g ursolic acid are joined in 2g deionized water successively, and magnetic agitation 10min, until form the dispersion of homogeneous;
3) being mixed of pre-polymerization liquid: by step 2) the B liquid of preparation is poured step 1 into) in the A liquid that makes, magnetic agitation 15min, when presenting homogeneous thick, adds 0.01g potassium peroxydisulfate, 0.002g sodium sulfite immediately, makes pre-polymerization liquid;
4) it is in 0.5mm, the mould corresponding with human body face shape that the pre-polymerization liquid preparation of gel mask: by step 3) making is poured thickness into, in temperature, is at 70 ℃, to carry out polyreaction 1h, can make high resiliency without supporting environment-friendly type gel mask;
5) packing of gel mask: the high resiliency making is carried out to heat sealed package without supporting environment-friendly type gel mask.
Claims (9)
- A high resiliency without support environment-friendly type gel mask by olefin monomer M1, biopolymer M2, chemical cross-linking agent M3, physical crosslinking agent M4, plant extraction quintessence oil, whitening composition and activity of fighting against senium composition is water-soluble is polymerized; Described olefin monomer M1 is acrylamide, Methacrylamide, NIPA, N hydroxymethyl acrylamide, 2-(dimethylamino) ethyl-Methacrylamide, 2-hydroxyethyl methacrylate, NVP, acrylic acid, methacrylic acid, tert-butyl acrylate, sodium acrylate, 2-acrylamide-2-methyl isophthalic acid-propane sulfonic acid, Polyethyleneglycol methacrylate, its inorganic salt, with and composition thereof; Described biopolymer M2 is the mixture of a kind of or any two kinds of compositions in sodium alginate, chitosan, xanthan gum, humic acid, cellulose, polylactic acid, polylysine, polyglutamic acid, polyvinyl alcohol, polyhydroxyalkanoate, polyanhydride, collagen protein, sericin shape globulin; Described chemical cross-linking agent M3 is N, any one in N '-methylene-bisacrylamide, two (methyl) acrylic acid glycol ester, diglycidyl ether, epoxychloropropane and glutaraldehyde; Described physical crosslinking agent M4 is any one in magnesium hectorite, hectorite, magnesium soap stone, sauconite or lithium magnesium silicate.
- 2. high resiliency according to claim 1 is without supporting environment-friendly type gel mask, it is characterized in that described planting extraction quintessence oil is any one in Flos Rosae Rugosae quintessence oil, Herba Lysimachiae foenum-graeci quintessence oil, Flos Lilii viriduli quintessence oil; Described whitening composition is one or more in Margarita powder, aloe juice, natural complex C, Semen Tritici aestivi germ oil.
- 3. high resiliency according to claim 1, without supporting environment-friendly type gel mask, is characterized in that described activity of fighting against senium composition is one or more in natural Vitamin E, epithelical cell growth factor EGF, superoxide dismutase SOD, hyaluronic acid, wrinkle removal peptide, grape polyphenols, ursolic acid.
- 4. high resiliency, without a preparation method that supports environment-friendly type gel mask, comprises the steps:1) preparation of A liquid: olefin monomer M1, biopolymer M2, chemical cross-linking agent M3 and physical crosslinking agent M4 are joined in deionized water successively, be mixed with the solution that mass concentration is 10-15%, often add function monomer one time, stir 5-25min, until form the mixed solution of thick homogeneous;2) preparation of B liquid: essence (planting extraction quintessence oil, whitening composition, activity of fighting against senium composition) is joined in deionized water successively, and magnetic agitation 3-10min, until form the dispersion of homogeneous;3) being mixed of pre-polymerization liquid: by step 2) the B liquid of preparation is poured step 1 into) in the A liquid that makes, magnetic agitation 5-15min, when presenting homogeneous thick, add immediately initiator ammonium persulfate or potassium peroxydisulfate, catalyst tetramethylethylenediamine or sodium sulfite, make pre-polymerization liquid;4) it is in 0.1-5mm, the mould corresponding with human body face shape that the pre-polymerization liquid preparation of gel mask: by step 3) making is poured thickness into, in temperature, be at 40-70 ℃, to carry out polyreaction 1～4h, can make high resiliency without supporting environment-friendly type gel mask;5) packing of gel mask: the high resiliency making is carried out to heat sealed package without supporting environment-friendly type gel mask.
- 5. high resiliency according to claim 4, without the preparation method that supports environment-friendly type gel mask, is characterized in that described step 1) in each constituent mass percentage ratio of A liquid be: olefin monomer M1:10-15%, biopolymer M2:1.5-3%, chemical cross-linking agent M3:0-0.1 ‰, physical crosslinking agent M4:0-10 ‰, deionized water: 85%-90%; Step 2) in, each constituent mass ratio of B liquid is: plant extraction quintessence oil: 0-1%, whitening composition 0-2%, activity of fighting against senium composition 0-3%, deionized water: 94-99%; Step 3) initiator in and catalyst are 1% and 3 ‰ of olefin monomer M1.
- 6. high resiliency according to claim 4 is without the preparation method that supports environment-friendly type gel mask, it is characterized in that step 4) in mould relative with human body face shape, leave the position of eyes, nose and face, can not cause that the visual field is unclear, hypopnea, dysphagia.
- 7. high resiliency according to claim 4, without the preparation method that supports environment-friendly type gel mask, is characterized in that step 5) in heat sealed package for directly gel mask laminating being sealed to composite membrane.
- 8. high resiliency according to claim 4 is without the preparation method that supports environment-friendly type gel mask, it is characterized in that prepared hydrogel can be by temperature, pH value, the degree of cross linking, dye strength, gel volume, nanoclay or biopolymer consumption and kind to the adsorbance of water soluble ion dyestuff and the rate of adsorption, and reactant feeds intake and recently regulates.
- 9. high resiliency according to claim 4, without the preparation method that supports environment-friendly type gel mask, is characterized in that described high resiliency regulates by adjusting monomer concentration, rate of charge, cross-linking agent kind and consumption, whitening and activity of fighting against senium composition, reaction temperature, water content and charging sequence without the viscosity, elasticity, skin affinity and the performance of keeping humidity that support environment-friendly type gel mask.10. high resiliency according to claim 4, without the preparation method that supports environment-friendly type gel mask, is characterized in that not needing to fit non-woven fabrics raising gel mask mechanical strength, and need not have on layer of non-woven fabric in use again.
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| CN105616170A (en) * | 2014-10-29 | 2016-06-01 | 林宇岳 | Colloid mask with local carrier and making method thereof |
| CN104971011A (en) * | 2015-07-13 | 2015-10-14 | 吕铝淼 | Anti-aging hydrating mask and preparation technology thereof |
| CN105147543A (en) * | 2015-08-25 | 2015-12-16 | 李康 | Preparation method of temperature-sensitive hydrogel containing rose essence oil |
| CN105147543B (en) * | 2015-08-25 | 2018-03-16 | 佛山市万盈化妆品有限公司 | A kind of preparation method of the temperature sensitive type water gel comprising Rosa Damascana |
| CN107496203A (en) * | 2017-08-29 | 2017-12-22 | 北京华信佳音医疗科技发展有限责任公司 | A kind of preparation and application of liquid facial mask |
| CN109662922A (en) * | 2017-10-17 | 2019-04-23 | 陈静 | A kind of whitening and moisturizing gel mask |
| CN108113957A (en) * | 2018-03-05 | 2018-06-05 | 湖南科技大学 | A kind of preparation method of novel whitening freckle-removing mask |
| CN109498830A (en) * | 2018-10-22 | 2019-03-22 | 江阴奔翔生物科技有限公司 | A kind of method of the sodium alginate-modified acellular dermal matrix of epoxy |
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