CN103520022A - Antibacterial hand sanitizer and preparation method thereof - Google Patents
Antibacterial hand sanitizer and preparation method thereof Download PDFInfo
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- CN103520022A CN103520022A CN201310495775.6A CN201310495775A CN103520022A CN 103520022 A CN103520022 A CN 103520022A CN 201310495775 A CN201310495775 A CN 201310495775A CN 103520022 A CN103520022 A CN 103520022A
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Abstract
The invention discloses an antibacterial hand sanitizer and a preparation method thereof. The antibacterial hand sanitizer comprises (A) 0.05-12% of fungicide coconut oil alcohol polyether ester sulfate zinc; (B) 5-20% of anionic surfactant; (C) 5-20% of ampholytic surfactant; (D) 1-10% of humectants; (E) 0.05-0.5% of chelating agent; (F) the balance of water in the weight of a composition. The antibacterial hand sanitizer containing the fungicide coconut oil alcohol polyether ester sulfate zinc disclosed by the invention has the advantages of being low in thrill, strong in hard water resistance, high in detersive power and the like besides the bacteriostatic efficacy. The influence of the fungicide coconut oil alcohol polyether ester sulfate zinc on the surfactant is small, so that the selectable surfactant in the formula is less limited; the formula can be simply adjusted, so as to adapt to variable market requirements.
Description
Technical field
The present invention relates to a kind of detergent, belong to daily chemical products technical field, particularly relate to a kind of bacteriostatic hand sanitizer.
Background technology
Because fancy soap solids is easy to be infected with dirt and antibacterial to hand, become secondary pollution source, and the contact surface of handwashing liquid and hands is general only at the pump head of bottle, can avoid preferably the probability of cross infection.Pretend the substitute products for traditional hand-washing article fancy soap, handwashing liquid has many advantages, and its liquid characteristic can be added all kinds of adjuvant very easily, as antibacterial, emollient, wetting agent etc., adapts to all kinds of crowds' demand.Handwashing liquid kind is in the market more, but most of function singleness.The antibacterial that bacteriostatic hand sanitizer is used is again that the bacteriostasis of these two kinds of antibacterial is had a greatly reduced quality under Surfactant Effect to chlorine ortho-methyl phenol and o-phenyl phenol mostly.
The common handwashing liquid in market adds anti-inhibiting-bacteria preparation, example more at present: chloroxylenol, o-phenyl phenol, benzalkonium chloride and cationic quaternary ammonium salt etc.These antibacterial are more common in the disinfectant of the sanitary units uses such as hospital, be main sterilization component, but these antibacterial major functions are single in disinfectant, can only sterilize and can not play the function of cleaning skin.
For China Patent Publication No., be interpolation TCC and the 1-hydroxy-4-methyl-6-(2 mentioning in CN101475879A, 4,4, tri-methyl-amyl)-2-(IH) handwashing liquid of-pyridone-2-ethylaminoethanol salt, these two kinds of antibacterial only have sterilizing function in formula.And these two kinds of antibacterial add the outward appearance that has limited handwashing liquid matrix in surfactant system, for example the handwashing liquid of transparent system cannot be used TCC.
It for China Patent Publication No., is the neutral sterilizing skin moistening liquid soap of mentioning in CN101785749A, although it is neutral that formula is, that but antibacterial is still used is TCC and 1-hydroxy-4-methyl-6-(2,4,4, tri-methyl-amyl)-2-(IH)-pyridone-2-ethylaminoethanol salt is that the outward appearance that has limited handwashing liquid matrix is selected equally.
The handwashing liquid of chloroxylenol that has been the interpolation mentioned in CN102772335A for China Patent Publication No., this also just plays sterilizing function chloroxylenol in handwashing liquid.Even if its outward appearance that can not limit handwashing liquid is selected, still due to the particularity of structure, limited again the selection of surfactant in formula.
Summary of the invention
The object of the present invention is to provide a kind of new bacteriostatic hand sanitizer that contains cocoanut oil alcohol polyether thiourea acid esters zinc, this handwashing liquid is except having bacteriostasis efficacy, take into account zest low, resistance to hard water is strong, detergency advantages of higher, because antibacterial cocoanut oil alcohol polyether thiourea acid esters zinc is subject to Surfactant Effect little, so the optional surfactant of filling a prescription is limited little, can simply adjust formula, to adapt to changeable market demands.
The object of the invention to solve the technical problems realizes by the following technical solutions.A kind of bacteriostatic hand sanitizer proposing according to the present invention, it mainly comprises: the antibacterial cocoanut oil alcohol polyether thiourea acid esters zinc that (A) accounts for composition weight 0.05% to 12%; (B) account for the anion surfactant of composition weight 5% to 20%; (C) account for the amphoteric surfactant of composition weight 5% to 20%; (D) account for the wetting agent of composition weight 1% to 10%; (E) account for the chelating agen of composition weight 0.05% to 0.5%; (F) surplus is water.
Unless otherwise indicated, all percent of the present invention all calculates with the weight of compositions, and all ratios are all percentage by weights.
The present invention's anionic surfactant concentration used accounts for composition weight 5.0% to 15%, is selected from least one in sodium lauryl sulphate, ammonium lauryl sulfate, aliphatic acid polyethenoxy ether sodium sulfate, AESA, alpha-olefin sodium sulfonate.
The present invention's amphoteric surfactant content used accounts for composition weight 3.0% to 9.0%, is selected from least one of both sexes betaines, imidazolines, both sexes acetate apoplexy due to endogenous wind.With above-mentioned anion surfactant interworking, can effectively reduce the zest of handwashing liquid, strengthen foaming characteristic and the stability of product simultaneously.
The present invention's wetting agent content used accounts for composition weight 1.0% to 4.0%, is selected from glycerol or propylene glycol.
The chelating agen content 0.05% to 0.1% that the present invention is used, is disodiumedetate, makes the washing under product adaptation hard water environment.
The present invention also includes the acceptable a small amount of thickening agent of handwashing liquid, pH adjusting agent, antiseptic, essence, pigment etc.PH adjusting agent is lactic acid, adjusts pH to 3.5～4.5.
In addition, the present invention also provides a kind of preparation method of above-mentioned bacteriostatic hand sanitizer, comprises the following steps:
1) appropriate water is joined in retort, add anion surfactant, amphoteric surfactant, wetting agent, chelating agen, be stirred well to completely and dissolve, add newborn acid for adjusting pH to 3.5～4.5;
2) continue to add antibacterial cocoanut oil alcohol polyether thiourea acid esters zinc, antiseptic, essence, finally by chlorate, be adjusted to required viscosity, fill after stirring.
This product is colorless transparent viscous liquid, can add as required suitable pigment and attract consumer.
By technique scheme, advantage and beneficial effect that the present invention has are:
The present invention's cocoanut oil alcohol polyether thiourea acid esters zinc used effectively solves the technical barrier of existing handwashing liquid.Cocoanut oil alcohol polyether thiourea acid esters zinc is a kind of anion surfactant, and because one end of its structure has linked zinc ion, so compare the anion surfactant of other salt, it has killing and inhibitory action antibacterial and fungus.So antibacterial that handwashing liquid of the present invention adds, not only can kill anti-bacteria and fungus, self also have skin clean function, in formula, the selection of the selection of matrix outward appearance and other surfactant all not had to restriction, the simple formula of adjusting, just can adapt to changeable market demands.
The specific embodiment
Be indefiniteness embodiment of the present invention below, providing of these examples is only used to illustration purpose, can not be interpreted as limitation of the invention, because without departing from the spirit and scope of the present invention, can carry out many changes to the present invention.
In following examples, all percent all calculates with the weight ratio of compositions.
embodiment 1
, each raw material components that it comprises following percentage by weight:
Sodium lauryl sulphate 6%; Lactic acid 0.1%;
Cocamido propyl betaine 4%; Antiseptic 0.1%;
Propylene glycol 3%; Sodium chloride 0.5%;
Cocoanut oil alcohol polyether thiourea acid esters zinc 2%; Essence 0.2%;
Disodiumedetate 0.1%; Deionized water adds to 100%.
The process of preparing of above-mentioned bacteriostatic hand sanitizer is:
Appropriate water is joined in retort, add sodium lauryl sulphate, cocamido propyl betaine, propylene glycol, disodiumedetate, be stirred well to completely and dissolve, add newborn acid for adjusting pH to 3.5～4.5; Continue to add antibacterial cocoanut oil alcohol polyether thiourea acid esters zinc, antiseptic, essence, finally by sodium chloride, be adjusted to required viscosity, fill after stirring.
embodiment 2
, each raw material components that it comprises following percentage by weight:
Sodium lauryl sulphate 6%; Lactic acid 0.05%;
Cocos nucifera oil both sexes sodium acetate 3%; Antiseptic 0.1%;
Propylene glycol 3%; Sodium chloride 1.0%;
Cocoanut oil alcohol polyether thiourea acid esters zinc 5%; Essence 0.2%;
Disodiumedetate 0.1%; Deionized water adds to 100%.
The process of preparing of above-mentioned bacteriostatic hand sanitizer is:
Appropriate water is joined in retort, add sodium lauryl sulphate, cocos nucifera oil both sexes sodium acetate, propylene glycol, second
diamidogentetraacethyl disodium, is stirred well to completely and dissolves, and adds newborn acid for adjusting pH to 3.5～4.5; Continue to add antibacterial cocoanut oil alcohol polyether thiourea acid esters zinc, antiseptic, essence, finally by sodium chloride, be adjusted to required viscosity, fill after stirring.
embodiment 3
, each raw material components that it comprises following percentage by weight:
Polyoxyethylenated alcohol sodium sulfate 5%; Lactic acid 0.05%;
Cocamido propyl betaine 5%; Antiseptic 0.1%;
Propylene glycol 3%; Sodium chloride 1.0%;
Cocoanut oil alcohol polyether thiourea acid esters zinc 5%; Essence 0.2%;
Disodiumedetate 0.1%; Deionized water adds to 100%.
The process of preparing of above-mentioned bacteriostatic hand sanitizer is:
Appropriate water is joined in retort, add polyoxyethylenated alcohol sodium sulfate, cocamido propyl betaine, propylene glycol, disodiumedetate, be stirred well to completely and dissolve, add newborn acid for adjusting pH to 3.5～4.5; Continue to add antibacterial cocoanut oil alcohol polyether thiourea acid esters zinc, antiseptic, essence, finally by sodium chloride, be adjusted to required viscosity, fill after stirring.
embodiment 4
, each raw material components that it comprises following percentage by weight:
Polyoxyethylenated alcohol sodium sulfate 5%; Lactic acid 0.05%;
Sodium lauryl sulphate 3%; Antiseptic 0.1%;
Cocamido propyl betaine 3%; Sodium chloride 1.0%;
Propylene glycol 3%; Essence 0.2%;
Cocoanut oil alcohol polyether thiourea acid esters zinc 3%; Deionized water adds to 100%;
Disodiumedetate 0.1%
The process of preparing of above-mentioned bacteriostatic hand sanitizer is:
Appropriate water is joined in retort, add polyoxyethylenated alcohol sodium sulfate, sodium lauryl sulphate, cocamido propyl betaine, propylene glycol, disodiumedetate, be stirred well to completely and dissolve, add newborn acid for adjusting pH to 3.5～4.5; Continue to add antibacterial cocoanut oil alcohol polyether thiourea acid esters zinc, antiseptic, essence, finally by sodium chloride, be adjusted to required viscosity, fill after stirring.
embodiment 5
, each raw material components that it comprises following percentage by weight:
Polyoxyethylenated alcohol sodium sulfate 5%; Lactic acid 0.05%;
Sodium lauryl sulphate 3%; Antiseptic 0.1%;
Cocos nucifera oil both sexes sodium acetate 3%; Sodium chloride 1.0%;
Propylene glycol 3%; Essence 0.2%;
Cocoanut oil alcohol polyether thiourea acid esters zinc 8%; Deionized water adds to 100%.
Disodiumedetate 0.1%;
The process of preparing of above-mentioned bacteriostatic hand sanitizer is:
Appropriate water is joined in retort, add polyoxyethylenated alcohol sodium sulfate, sodium lauryl sulphate, cocos nucifera oil both sexes sodium acetate, propylene glycol, disodiumedetate, be stirred well to completely and dissolve, add newborn acid for adjusting pH to 3.5～4.5; Continue to add antibacterial cocoanut oil alcohol polyether thiourea acid esters zinc, antiseptic, essence, finally by sodium chloride, be adjusted to required viscosity, fill after stirring.
effects applications test example
The effect evaluation to above-described embodiment 1-5 below:
1, sensory evaluation
30 testers are equally divided into 6 groups, by " double blinding " test, give at random test group sample, requiring tester to wash one's hands by self daily custom of washing one's hands (is handwashing liquid consumption, Handwashing ways, the bath time does not limit), foaming characteristic, dirt-removing power, zest, the flushing difficulty when evaluating successively handwashing liquid and washing one's hands and the salubrious sense of washing one's hands.Tester marks according to own feeling, standards of grading adopt 5 minutes systems, wherein foaming characteristic, dirt-removing power, to wash rear salubrious sense the poorest with 1 minute, preferably calculating in 5 minutes; Zest, to rinse difficulty best with 1 minute, the poorest calculating in 5 minutes, and the sensory effects scoring of finally recording each embodiment with mean values, sees the following form shown in 1.
The sensory evaluation of table 1 handwashing liquid hand-washing effect (unit: minute)
| ? | Foaming characteristic | Dirt-removing power | Zest | Rinse difficulty | Wash rear salubrious sense |
| Embodiment 1 | 3.8 | 4.3 | 1.6 | 1.7 | 3.8 |
| Embodiment 2 | 4.2 | 4.6 | 1.2 | 1.1 | 4.2 |
| Embodiment 3 | 4.0 | 4.5 | 1.6 | 1.2 | 3.8 |
| Embodiment 4 | 4.0 | 4.5 | 1.8 | 1.3 | 3.6 |
| Embodiment 5 | 4.5 | 4.7 | 1.4 | 2.0 | 4.0 |
From the content of above-mentioned table 1,5 embodiment are little in the score difference on aspect 5 evaluations.The formula of embodiment forms not to be affected on the basis of antibacterial cocoanut oil alcohol polyether thiourea acid esters zinc fungistatic effect, and the selection conditionality of surfactant is smaller.
2. fungistatic effect evaluation
Following table 2 is data of bacteriostatic hand sanitizer bacteriostasis property of the present invention.
The bacteriostasis property of table 2 bacteriostatic hand sanitizer (50% diluent)
From the content of above-mentioned table 2, bacteriostatic hand sanitizer bacteriostasis property performance after 1:1 dilution is efficient.
The above, it is only preferred embodiment of the present invention, not the present invention is done to any pro forma restriction, therefore every, do not depart from technical solution of the present invention content, any simple modification, equivalent variations and the modification above embodiment done according to technical spirit of the present invention, all still belong in the scope of technical solution of the present invention.
Claims (7)
1. a bacteriostatic hand sanitizer, is characterized in that, each raw material components that it comprises following percentage by weight:
(A) account for the antibacterial cocoanut oil alcohol polyether thiourea acid esters zinc of composition weight 0.05% to 12%;
(B) account for the anion surfactant of composition weight 5% to 20%;
(C) account for the amphoteric surfactant of composition weight 3% to 10%;
(D) account for the wetting agent of composition weight 1% to 5%;
(E) account for the chelating agen of composition weight 0.05% to 0.5%;
(F) surplus is water.
2. bacteriostatic hand sanitizer according to claim 1, it is characterized in that: described anionic surfactant concentration accounts for composition weight 5.0% to 15%, be selected from the above mixture of at least one or both in sodium lauryl sulphate, ammonium lauryl sulfate, aliphatic acid polyethenoxy ether sodium sulfate, AESA, alpha-olefin sodium sulfonate.
3. bacteriostatic hand sanitizer according to claim 1, it is characterized in that: described amphoteric surfactant content accounts for composition weight 3.0% to 9.0%, be selected from least one or both above mixture of both sexes betaines, imidazolines, both sexes acetate apoplexy due to endogenous wind.
4. bacteriostatic hand sanitizer according to claim 1, is characterized in that: described wetting agent content accounts for composition weight 1.0% to 4.0%, is selected from glycerol or propylene glycol or both mixture.
5. bacteriostatic hand sanitizer according to claim 1, is characterized in that: described chelating agen content accounts for 0.05% to 0.1% of composition weight, is disodiumedetate.
6. bacteriostatic hand sanitizer according to claim 1, is characterized in that: also include the acceptable a small amount of thickening agent of handwashing liquid, PH regulator, antiseptic, spice, pigment.
7. the preparation method of the bacteriostatic hand sanitizer described in any one in claim 1-6, is characterized in that comprising following steps:
1) appropriate water is joined in retort, add anion surfactant, amphoteric surfactant, wetting agent, chelating agen, be stirred well to completely and dissolve, add newborn acid for adjusting pH to 3.5～4.5;
2) continue to add antibacterial cocoanut oil alcohol polyether thiourea acid esters zinc, antiseptic, essence, finally by chlorate, be adjusted to required viscosity, fill after stirring.
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104188811A (en) * | 2014-07-30 | 2014-12-10 | 广州立白企业集团有限公司 | Foam type wash-free antibacterial liquid soap and using method thereof |
| CN104593164A (en) * | 2014-12-30 | 2015-05-06 | 安徽琪嘉日化有限责任公司 | Lemon liquid detergent |
| CN104823971A (en) * | 2015-03-21 | 2015-08-12 | 威海翔宇环保科技股份有限公司 | Sterilization synergist used for non-oxidative bactericide |
| CN105193652A (en) * | 2015-09-02 | 2015-12-30 | 铜陵梧桐树农业发展有限公司 | Hand sanitizer |
| CN105832573A (en) * | 2016-04-19 | 2016-08-10 | 南京巨鲨显示科技有限公司 | Amine antibacterial liquid soap |
| CN106667784A (en) * | 2017-02-27 | 2017-05-17 | 宁波圆明工业设计有限公司 | Hand sanitizer containing Daphenylline |
| CN106811342A (en) * | 2015-12-01 | 2017-06-09 | 深圳市海馨生物科技有限公司 | A kind of Efficient antibacterial Antibacterial soaps composition |
| CN107075555A (en) * | 2014-09-24 | 2017-08-18 | 高露洁-棕榄公司 | The bioavilability of metal ion |
| CN109055058A (en) * | 2018-08-24 | 2018-12-21 | 中山市洁莹生物科技有限公司 | A kind of plant bacteriostatic hand sanitizer and preparation method thereof |
| CN112515996A (en) * | 2020-11-30 | 2021-03-19 | 明尼苏达矿业制造医用器材（上海）有限公司 | Antibacterial hand sanitizer and preparation method thereof |
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| EP0498636A1 (en) * | 1991-02-05 | 1992-08-12 | Zeneca Limited | Cosmetic composition |
| CN101378787A (en) * | 2006-02-09 | 2009-03-04 | Gojo工业公司 | Antiviral method |
| CN101553202A (en) * | 2006-12-13 | 2009-10-07 | 森特尼尔投资有限公司 | Mild composition for skin disinfection |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104188811A (en) * | 2014-07-30 | 2014-12-10 | 广州立白企业集团有限公司 | Foam type wash-free antibacterial liquid soap and using method thereof |
| CN107075555A (en) * | 2014-09-24 | 2017-08-18 | 高露洁-棕榄公司 | The bioavilability of metal ion |
| CN104593164A (en) * | 2014-12-30 | 2015-05-06 | 安徽琪嘉日化有限责任公司 | Lemon liquid detergent |
| CN104823971A (en) * | 2015-03-21 | 2015-08-12 | 威海翔宇环保科技股份有限公司 | Sterilization synergist used for non-oxidative bactericide |
| CN105193652A (en) * | 2015-09-02 | 2015-12-30 | 铜陵梧桐树农业发展有限公司 | Hand sanitizer |
| CN106811342A (en) * | 2015-12-01 | 2017-06-09 | 深圳市海馨生物科技有限公司 | A kind of Efficient antibacterial Antibacterial soaps composition |
| CN105832573A (en) * | 2016-04-19 | 2016-08-10 | 南京巨鲨显示科技有限公司 | Amine antibacterial liquid soap |
| CN106667784A (en) * | 2017-02-27 | 2017-05-17 | 宁波圆明工业设计有限公司 | Hand sanitizer containing Daphenylline |
| CN109055058A (en) * | 2018-08-24 | 2018-12-21 | 中山市洁莹生物科技有限公司 | A kind of plant bacteriostatic hand sanitizer and preparation method thereof |
| CN112515996A (en) * | 2020-11-30 | 2021-03-19 | 明尼苏达矿业制造医用器材（上海）有限公司 | Antibacterial hand sanitizer and preparation method thereof |
| CN112515996B (en) * | 2020-11-30 | 2023-09-01 | 明尼苏达矿业制造医用器材（上海）有限公司 | Antibacterial hand sanitizer and preparation method thereof |
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