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CN103526384B - Anti-mite chitin fabric - Google Patents

Anti-mite chitin fabric Download PDF

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Publication number
CN103526384B
CN103526384B CN201310533663.5A CN201310533663A CN103526384B CN 103526384 B CN103526384 B CN 103526384B CN 201310533663 A CN201310533663 A CN 201310533663A CN 103526384 B CN103526384 B CN 103526384B
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Prior art keywords
mite
fiber
chitin
weight portion
fabric
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CN201310533663.5A
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CN103526384A (en
Inventor
袁娟
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Guangdong Kaidi Garments Co ltd
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Shanghai Wanjing Textile Technology Co Ltd
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Abstract

The invention discloses a kind of anti-mite chitin fabric, the raw material hybrid woven adopting following weight portion to form forms: 10-30 part chitin fiber, 70-90 part mite-assistant fiber.Anti-mite chitin fabric of the present invention, has good antibacterial bacteriostatic characteristic, and has good anti-mite and drive mite effect.

Description

Anti-mite chitin fabric
Technical field
The present invention relates to a kind of fabric, particularly relate to a kind of anti-mite chitin fabric.
Background technology
Mite class is the monoid of most species in Arthropoda arachnid, and mite class existing on the earth can have 500,000 kinds more than, and their form, habit and habitat are varied, can find the trace of mite class on earth Anywhere.Medical domain is studied the disease that the dirt mite be distributed in people's living environment causes, research shows that it is a kind of strong sensibiligen, the people in the whole world nearly 1/10 suffers from anaphylactia, and wherein the morbidity of asthma, allergic rhinitis and atopical dermatitis etc. is all closely bound up with existing of house dust mite.
Along with the development of world architecture technology and the abundant of people's material life, indoor living environment has a very large change, the improvement of house airtight performance, indoor pollution is assembled, improper ventilation adds the growth that indoor humidity is also conducive to mould and house dust mite simultaneously, thus making dirt mite become allergen the most general in living environment, the change of life style and working method then makes the time of people 80% spend in indoor.The change of environment facilitates dirt mite and grows, and people too increase the contact with dust mite allergen in the prolongation of indoor residence time, and the incidence of disease of the diseases such as dust mite allergy asthma increases thereupon.Therefore, the control of dirt mite receives the extensive concern of countries in the world researcher.
Because the textiles in room is the main place of dirt mite evil life, there is the chemical reagent that kills mite or drive mite effect give the anti-mite of textiles by adding in textiles and drive mite function, in the process using textiles, realize anti-mite drive mite, become a kind of new trend.
Summary of the invention
For the deficiencies in the prior art, technical problem to be solved by this invention is to provide a kind of anti-mite chitin fabric.
For solving the problems of the technologies described above, the present invention is achieved through the following technical solutions:
A kind of anti-mite chitin fabric, the raw material hybrid woven adopting following weight portion to form forms: 10-30 part chitin fiber, 70-90 part mite-assistant fiber.
Anti-mite chitin fabric of the present invention can adopt industry universal method first chitin fiber and mite-assistant fiber to be carried out blending, obtained blended yarn, then adopts industry universal method to be woven into anti-mite chitin fabric this blended yarn.The preparation method of obvious described blended yarn woven fabric itself does not have originality, is only to adopt prior art, and innovation of the present invention is the difference of fabric blend fibre raw material and proportioning.
Described mite-assistant fiber, material is terylene, also drives mite agent containing 0.05-0.15wt%.Describedly drive mite agent and be made up of 30-50 weight portion Fenamidone, 30-50 weight portion decis and 10-30 weight portion lauryl carboxymethyl sodium form imidazoline acetate.
Fenamidone, CAS:161326-34-7.Decis, CAS:52918-63-5.Lauryl carboxymethyl sodium form imidazoline acetate, CAS:64041-76-5.
Described mite-assistant fiber, is prepared from by following step:
(1) by terylene with drive mite agent and mix, extrude, cut into slices, obtainedly drive mite terylene chips, wherein terylene is 100:0.05-100:0.15 with the mass ratio driving mite agent;
(2) drive mite terylene chips heating and melting by described, extruding, spray silk is shaping.
Further, the coupling agent of described mite-assistant fiber also containing 0.02-0.10wt%.
Described coupling agent is titanate coupling agent.
Described coupling agent is made up of 60-80wt% isopropyl three (dioctylphyrophosphoric acid acyloxy) titanate esters and 20-40wt% bis-(triethanolamine) metatitanic acid diisopropyl ester.
Isopropyl three (dioctylphyrophosphoric acid acyloxy) titanate esters, CAS:67691-13-8.Two (triethanolamine) metatitanic acid diisopropyl ester, CAS:36673-16-2.
Described mite-assistant fiber, is prepared from by following step:
(1) mixed with terylene by coupling agent, obtain modified dacron, wherein the mass ratio of terylene and coupling agent is 100:0.02-100:0.10;
(2) by modified dacron with drive mite agent and mix, extrude, cut into slices, obtainedly drive mite terylene chips, wherein terylene is 100:0.05-100:0.15 with the mass ratio driving mite agent;
(3) drive mite terylene chips heating and melting by described, extruding, spray silk is shaping.
Below main raw material fiber of the present invention is introduced:
Chitin fiber processes from the shell of marine organisms shrimp, crab etc. a kind of natural high polymer fiber be polymerized through degreasing, decalcification etc., has excellent biologically active, biocompatibility and bacteriostasis property, have very strong nursing function to human body skin.The physical index of chitin fiber: fiber number 1.5-3.0 dawn; Fibrous fracture intensity >=1.5cN/dtex; Fracture strength irregularity≤12%; Elongation at break >=15%.Chitin fiber of the present invention can buy 1.5D × 38mm chitin fiber from Qingdao JiFa Group Co., Ltd.
Terylene is an important kind in synthetic fiber, is the trade name of China's polyester fiber.It is with p-phthalic acid (PTA) or dimethyl terephthalate (DMT) (DMT) and ethylene glycol (EG) for raw material is through esterification or ester exchange and polycondensation reaction and obtained fiber-forming polymer---polyethylene terephthalate (PET), through the fiber that spinning and post processing are made.
Anti-mite chitin fabric of the present invention, mite-proof agent is embedded in fibrous inside, wearing and washing the process of textiles, surface one deck mite-proof agent is washed off, new mite-proof agent is had again to supplement from interior stripping, form again the new anti-mite layer of one deck at fabric face, play anti-mite effect, thus embody excellent washability.
Anti-mite chitin fabric of the present invention, has good antibacterial bacteriostatic characteristic, and has good anti-mite and drive mite effect.
Detailed description of the invention
Embodiment 1:
(1) 0.06 weight portion coupling agent is mixed with 100 weight portion terylene, obtain modified dacron;
Described coupling agent is made up of 70wt% isopropyl three (dioctylphyrophosphoric acid acyloxy) titanate esters and 30wt% bis-(triethanolamine) metatitanic acid diisopropyl ester;
(2) above-mentioned modified dacron and 0.1 weight portion are driven mite agent to mix, extrude, cut into slices, obtain and drive mite terylene chips;
Describedly drive mite agent and be made up of 40wt% Fenamidone, 40wt% decis and 20wt% lauryl carboxymethyl sodium form imidazoline acetate;
(3) drive mite terylene chips heating and melting by above-mentioned, extruding, spray silk is shaping, obtained mite-assistant fiber.
Embodiment 2:
Adopt the substantially identical method of embodiment 1 to prepare mite-assistant fiber, unique difference is: described coupling agent is two (triethanolamine) metatitanic acid diisopropyl ester, and addition is also 0.06 weight portion.
Embodiment 3:
Adopt the substantially identical method of embodiment 1 to prepare mite-assistant fiber, unique difference is: described coupling agent is isopropyl three (dioctylphyrophosphoric acid acyloxy) titanate esters, and addition is also 0.06 weight portion.
Embodiment 4:
Adopt the substantially identical method of embodiment 1 to prepare mite-assistant fiber, unique difference is: do not add any coupling agent.
Embodiment 5
The blending mass ratio of the mite-assistant fiber of chitin fiber, embodiment 1 is 20:80.
By the mite-assistant fiber of chitin fiber and embodiment 1, adopt artificial mixed in a small amount, volume made by opening picking machinery, and blended sliver made by carding machine;
By above-mentioned blended sliver, obtain described anti-mite chitin fabric by pre-drawing machine, drawing frame, Speed frames, fine spining machine and bobbin winder successively.Obtained blended yarn, number is 21 s, the twist is 330.
Again by above-mentioned obtained anti-mite chitin fabric, adopt conventional weaving process can obtain described anti-mite chitin fabric, plain cloth, fabric grammes per square metre is 180 grams/m.
Embodiment 6
The blending mass ratio of the mite-assistant fiber of chitin fiber, embodiment 2 is 20:80.The method of embodiment 5 is adopted to prepare anti-mite chitin fabric.
Embodiment 7
The blending mass ratio of the mite-assistant fiber of chitin fiber, embodiment 3 is 20:80.The method of embodiment 5 is adopted to prepare anti-mite chitin fabric.
Embodiment 8
The blending mass ratio of the mite-assistant fiber of chitin fiber, embodiment 4 is 20:80.The method of embodiment 5 is adopted to prepare anti-mite chitin fabric.
Test case 1:
" the anti-mite bedding of the FZ/T62012-2009 " standard of employing, to the anti-mite chitin fabric of above-mentioned employing embodiment 5-8, carry out anti-mite performance test:
Table 1: anti-mite performance test table
Test case 2:
Embodiment 1 drives mite agent (40wt% Fenamidone, 40wt% decis and 20wt% lauryl carboxymethyl sodium form imidazoline acetate) toxicity test:
(1) mite agent aqueous solution per os acute toxicity is driven; Get 1wt% and drive the Kunming kind standard small white mouse disposable per os gavage of the mite agent aqueous solution to 40 empty stomach 16h, drive mite agent aqueous solution dosage up to 20000mg/kg.Observe animal and poisoning manifestations every day, seven days terminate experiment, and each group animal used as test is in whole experimentation, and without any poisoning manifestations, diet and motion are all normal, none animal dead.
(2) to skin irritation: cut respectively by 10 Japan's large ear tag quasi-experiment backbone diamond wools of rabbit, 1wt% will be flooded drive the gauze of the mite agent aqueous solution, on the skin that exposes on right side of applying ointment or plaster.Observe application site skin after 24 hours, all do not occur the irritation such as erythema and oedema, according to skin irritatin strength grading standard, this drives mite agent and belongs to non-stimulated material to skin.
(3) to eye irritation: 1wt% to be driven the mite agent aqueous solution, the directly instillation Japan large ear tag quasi-experiment right eye of rabbit, left eye compares, passive closed 5 seconds, then clean with normal saline flushing, observe after 24 hours, eyes are all without exception, according to eye irritation strength grading standard, this drives mite agent and belongs to non-stimulated material to eyes.
Anti-mite chitin fabric of the present invention, mite-proof agent is embedded in fibrous inside, wearing and washing the process of textiles, surface one deck mite-proof agent is washed off, new mite-proof agent is had again to supplement from interior stripping, form again the new anti-mite layer of one deck at fabric face, play anti-mite effect, thus embody excellent washability.

Claims (1)

1. an anti-mite chitin fabric, is characterized in that, the raw material hybrid woven adopting following weight portion to form forms: 10-30 part chitin fiber, 70-90 part mite-assistant fiber;
Described mite-assistant fiber, material is terylene, also drives mite agent containing 0.05-0.15wt%;
The coupling agent of described mite-assistant fiber also containing 0.02-0.10wt%;
Describedly drive mite agent and be made up of 30-50 weight portion Fenamidone, 30-50 weight portion decis and 10-30 weight portion lauryl carboxymethyl sodium form imidazoline acetate;
Described coupling agent is made up of 60-80wt% isopropyl three (dioctylphyrophosphoric acid acyloxy) titanate esters and 20-40wt% bis-(triethanolamine) metatitanic acid diisopropyl ester.
CN201310533663.5A 2013-10-31 2013-10-31 Anti-mite chitin fabric Active CN103526384B (en)

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Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105624817A (en) * 2014-11-06 2016-06-01 上海市小荷展示器材科技有限公司 Odorless eco-friendly fireproof display cloth
CN108783689A (en) * 2018-05-23 2018-11-13 苏州凤霓绣叶文化艺术有限公司 A kind of anti-mite ceremonial dress face fabric
CN113279097A (en) * 2021-06-07 2021-08-20 红豆集团无锡红豆童装有限公司 Preparation method of chitin natural colored cotton blended yarn

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CN2648840Y (en) * 2003-06-23 2004-10-20 上海天丝科技发展有限公司 Antibacterial mite-inhibiting body-warm-keeping underclothes
CN101168863A (en) * 2007-11-28 2008-04-30 盛虹集团有限公司 Efficient anti-mite polyester fiber
CN202154500U (en) * 2011-06-29 2012-03-07 南通华翰电子科技有限公司 Antibacterial anti-mite curtain
CN103361805A (en) * 2013-08-06 2013-10-23 上海婉静纺织科技有限公司 China-hemp, modal and Dacron blended fabric

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CL2007003743A1 (en) * 2006-12-22 2008-07-11 Bayer Cropscience Ag COMPOSITION THAT INCLUDES FENAMIDONA AND AN INSECTICIDE COMPOUND; AND METHOD TO CONTROL FITOPATOGENOS CULTURES AND INSECTS FACING OR PREVENTIVELY.

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Publication number Priority date Publication date Assignee Title
CN2648840Y (en) * 2003-06-23 2004-10-20 上海天丝科技发展有限公司 Antibacterial mite-inhibiting body-warm-keeping underclothes
CN101168863A (en) * 2007-11-28 2008-04-30 盛虹集团有限公司 Efficient anti-mite polyester fiber
CN202154500U (en) * 2011-06-29 2012-03-07 南通华翰电子科技有限公司 Antibacterial anti-mite curtain
CN103361805A (en) * 2013-08-06 2013-10-23 上海婉静纺织科技有限公司 China-hemp, modal and Dacron blended fabric

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陈建高.浅谈绿色贸易壁垒下甲壳素保健纺织品的开发前景.《江苏纺织》.2006,(第04期),第17-18页. *
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Inventor after: Ma Qingxuan

Inventor before: Yuan Juan

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Effective date of registration: 20160913

Address after: 515154, Heping Town, Heping Town, Chaoyang District, Guangdong, Shantou Province

Patentee after: Guangdong Kaidi Garments Co.,Ltd.

Address before: 201107 Shanghai city Minhang District Minhang Road 88 Lane No. 1-30 building twenty-second room T158

Patentee before: SHANGHAI WANJING TEXTILE SCIENCE & TECHNOLOGY Co.,Ltd.

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Denomination of invention: Anti-mite chitin fabric

Effective date of registration: 20220916

Granted publication date: 20150805

Pledgee: Industrial Bank Co.,Ltd. Shantou branch

Pledgor: Guangdong Kaidi Garments Co.,Ltd.

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Registration number: Y2022980015366

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Denomination of invention: Anti mite chitin fabric

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Pledgee: Industrial Bank Co.,Ltd. Shantou branch

Pledgor: Guangdong Kaidi Garments Co.,Ltd.

Registration number: Y2023980058367

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Granted publication date: 20150805

Pledgee: Industrial Bank Co.,Ltd. Shantou branch

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Registration number: Y2023980058367