CN103524067A - Bentonite anti-seepage and anti-salt corrosion cement concrete additive - Google Patents
Bentonite anti-seepage and anti-salt corrosion cement concrete additive Download PDFInfo
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- CN103524067A CN103524067A CN201310426910.1A CN201310426910A CN103524067A CN 103524067 A CN103524067 A CN 103524067A CN 201310426910 A CN201310426910 A CN 201310426910A CN 103524067 A CN103524067 A CN 103524067A
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- Prior art keywords
- wilkinite
- water reducer
- mud
- soil additive
- cement soil
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- 239000004568 cement Substances 0.000 title claims abstract description 47
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 title claims abstract description 42
- 239000000654 additive Substances 0.000 title claims abstract description 30
- 230000000996 additive effect Effects 0.000 title claims abstract description 30
- 239000004567 concrete Substances 0.000 title abstract description 21
- 229910000278 bentonite Inorganic materials 0.000 title abstract description 8
- 239000000440 bentonite Substances 0.000 title abstract description 8
- 238000005260 corrosion Methods 0.000 title abstract 5
- 230000007797 corrosion Effects 0.000 title abstract 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 36
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 14
- 239000000203 mixture Substances 0.000 claims abstract description 6
- 230000003628 erosive effect Effects 0.000 claims description 31
- 239000000843 powder Substances 0.000 claims description 24
- 239000002689 soil Substances 0.000 claims description 20
- 230000001112 coagulating effect Effects 0.000 claims description 19
- 239000000463 material Substances 0.000 claims description 12
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 10
- 229910052710 silicon Inorganic materials 0.000 claims description 9
- 239000010703 silicon Substances 0.000 claims description 9
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 6
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 6
- 239000011707 mineral Substances 0.000 claims description 6
- 229910052901 montmorillonite Inorganic materials 0.000 claims description 6
- 239000002131 composite material Substances 0.000 claims description 5
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 4
- DGVVJWXRCWCCOD-UHFFFAOYSA-N naphthalene;hydrate Chemical compound O.C1=CC=CC2=CC=CC=C21 DGVVJWXRCWCCOD-UHFFFAOYSA-N 0.000 claims description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 3
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 3
- 229910021417 amorphous silicon Inorganic materials 0.000 claims description 3
- 239000011575 calcium Substances 0.000 claims description 3
- 229910052791 calcium Inorganic materials 0.000 claims description 3
- 239000006229 carbon black Substances 0.000 claims description 3
- 229920005610 lignin Polymers 0.000 claims description 3
- 229910052744 lithium Inorganic materials 0.000 claims description 3
- IIACRCGMVDHOTQ-UHFFFAOYSA-M sulfamate Chemical compound NS([O-])(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-M 0.000 claims description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- 229920000877 Melamine resin Polymers 0.000 claims description 2
- 241000158728 Meliaceae Species 0.000 claims description 2
- 239000004411 aluminium Substances 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 238000009776 industrial production Methods 0.000 claims description 2
- 239000011777 magnesium Substances 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 2
- 229920005646 polycarboxylate Polymers 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 9
- 238000002156 mixing Methods 0.000 abstract description 7
- 239000002994 raw material Substances 0.000 abstract description 6
- 239000003795 chemical substances by application Substances 0.000 abstract description 5
- 238000009826 distribution Methods 0.000 abstract description 3
- 230000003750 conditioning effect Effects 0.000 abstract 2
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 description 12
- 238000010276 construction Methods 0.000 description 7
- 235000012216 bentonite Nutrition 0.000 description 6
- 229940092782 bentonite Drugs 0.000 description 5
- 238000000227 grinding Methods 0.000 description 5
- 230000004048 modification Effects 0.000 description 5
- 238000012986 modification Methods 0.000 description 5
- 230000008961 swelling Effects 0.000 description 5
- 235000013312 flour Nutrition 0.000 description 4
- 239000011229 interlayer Substances 0.000 description 4
- 229910021647 smectite Inorganic materials 0.000 description 4
- 208000013201 Stress fracture Diseases 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 229910001579 aluminosilicate mineral Inorganic materials 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- -1 carboxylate salt Chemical class 0.000 description 2
- ONCZQWJXONKSMM-UHFFFAOYSA-N dialuminum;disodium;oxygen(2-);silicon(4+);hydrate Chemical compound O.[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Na+].[Na+].[Al+3].[Al+3].[Si+4].[Si+4].[Si+4].[Si+4] ONCZQWJXONKSMM-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 239000010865 sewage Substances 0.000 description 2
- 229910000280 sodium bentonite Inorganic materials 0.000 description 2
- 229940080314 sodium bentonite Drugs 0.000 description 2
- WPJGWJITSIEFRP-UHFFFAOYSA-N 1,3,5-triazine-2,4,6-triamine;hydrate Chemical compound O.NC1=NC(N)=NC(N)=N1 WPJGWJITSIEFRP-UHFFFAOYSA-N 0.000 description 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- 208000034189 Sclerosis Diseases 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229910001569 aluminium mineral Inorganic materials 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 235000021321 essential mineral Nutrition 0.000 description 1
- 229910001653 ettringite Inorganic materials 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000002522 swelling effect Effects 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Landscapes
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Soil Conditioners And Soil-Stabilizing Materials (AREA)
Abstract
The invention relates to a bentonite anti-seepage and anti-salt corrosion cement concrete additive. The anti-seepage and anti-salt corrosion cement concrete additive is prepared by mixing modified bentonite and a conditioning agent, wherein the conditioning agent is a mixture of active silicon dioxide power and a water reducing agent, and the mass ratio of all the components is as follows: modified bentonite: active silicon dioxide powder: water reducing agent=100: (3-30): (0.3-3.5). The anti-seepage and anti-salt corrosion cement concrete additive is used for preparing cement and concrete. The anti-seepage and anti-salt corrosion cement concrete additive provided by the invention has the advantages of large geological reserves of the used raw material bentonite, wide distribution range, wide range of sources, low cost, good economy and simple and convenient using method.
Description
Technical field
The present invention relates to a kind of coagulating cement soil additive, especially relate to a kind of impervious anti-salt erosion coagulating cement soil additive.
Background technology
Cement is most widely used hydraulic cementing materials, it is concrete consolidating material, after its sclerosis, leave a large amount of capillary porosity ducts and drying shrinkage, heat expansion microfracture, these micro-channels and crack provide path for the erosion of seepage and salt, created condition, cause cement or concrete product or concrete works seepage and salt erosion to destroy, especially impervious in the engineerings such as dam, tunnel, culvert, water channel, pond, tower, burrock, harbour and anti-salt erosion problem becomes a maximum engineering difficult problem.
The technological method of current solution cement concrete engineering leakage and salt erosion problem can be summarized as four large classes: the one, one or multi-channel impervious barrier layer is set; The 2nd, add swelling agent and as calcium sulfate, generate the expansions such as calcium sulphoaluminate and make it finer and close; The 3rd, add a large amount of expensive macromolecular material intentions and block duct and crack; The 4th, adopt special cement; Or adopt above-mentioned several class methods simultaneously.These methods are causing construction costs high in varying degrees, and maintenance cost is high.
Summary of the invention
The technical problem to be solved in the present invention is, overcome the deficiencies in the prior art, the impervious anti-salt erosion coagulating cement soil additive for cement that a kind of easy to use, low cost of manufacture is provided, is applied in cement or concrete, can effectively improve cement and concrete impervious anti-salt erosion performance.
The technical scheme that the present invention solves its technical problem employing is:
The present invention's the impervious anti-salt erosion coagulating cement soil additive of wilkinite, by modified alta-mud and wilkinite adjusting material, be mixed and make, described wilkinite adjusting material is the mixture of active silica powder and water reducer, the mass ratio of each component is, wilkinite: active silica: water reducer=100:3～30:0.3～3.5.
Described wilkinite is wilkinite or the modified alta-mud of montmorillonite mineral content >=80%.
Described modified alta-mud is that calcium base, sodium base, hydrogen are aluminium base, magnesium base, lithium base, organism modified alta-mud and inorganic organic composite modified alta-mud, preferred inorganic-organism composite modified bentonite.
Described active silica powder is silicon industrial residue " silicon ash ", or industrial production amorphous Si O
2powder (as white carbon black), or natural SiO
2the 80 μ m that mineral are made as silica, diatomite etc. tail over≤12% fine powder.
Described water reducer is naphthalene water reducer, melamine system water reducer, modified lignin mahogany sulfonate based water reducer, carboxylate salt based water reducer or sulfamate based water reducer.
The preparation method of the impervious anti-salt erosion of wilkinite of the present invention coagulating cement soil additive: will described each component mixing, levigate to tail over < 12% powder of 80 μ m; Or each powdery components is mixed.
Usage: described impervious anti-salt erosion coagulating cement soil additive is allocated into when the cement grinding, or allocated in cement flour or chamotte powder evenly, or allocate into when mixing concrete, for the production of impervious anti-salt erosion cement or concrete; The amount of allocating into is the 3-15% of cement weight.
Described wilkinite is that the distribution of a kind of special inorganic silicon aluminium mineral material ， China is wide, and reserves are large.Research shows, bentonitic essential mineral composition is montmorillonite, montmorillonite is the special aluminosilicate mineral that a class has interlayer structure, the 2:1 type crystal structure that its structure is comprised of two silicon-oxy tetrahedron folder one deck alumina octahedrals, be different from common clay mineral, there is following significantly characteristic: the interlayer structure of (1) montmorillonite prosperity makes it have good swelling property, adsorptivity, ion exchangeable, available positively charged ion and polymer substance embed the abundant modification of its interlayer structure, and can be equipped with suitable material (as active silica flour, water reducer) adjust the performance of wilkinite in media environment, (2) utilize main aluminosilicate mineral in Water by Modified Bentonites mud to have and melt mutually preferably adsorptivity, can not affect strength of cement, (3) there are splendid plasticoviscosity and oilness, water-swellable, its glue medium, expansion capacity, swelling value are superior, in cement concrete media environment through suitable modified after, meet water and can effectively block and fill capillary porosity duct and microfracture, the hazardness expansion stress that but can not cause ettringite and magnesium oxide and so on swelling agent to produce.
Know-why of the present invention is: (1) utilizes wilkinite or modified alta-mud through the active SiO of adjusting material
2water reducer molecule synergy with high absorbability, in cement concrete media environment, the activity of modified rear performance and interlayer absorption exchange activity, improve the blending to cement hydration mineral, can improve concrete strength first, second can suppress and isolate the salt erosion impact of salt erosion environment moisture content; (2) utilize glue medium, expansion capacity, the swelling value characteristic of modified alta-mud excellence after modified, block in time capillary porosity duct and microfracture, and blocking-up and elimination salt erosion condition, the impervious anti-salt that can solve concrete works loses problem; (3) utilize colloid, breathing and the swelling characteristic of modified modified alta-mud can dissolve alternation of wetting and drying, heat expansion and the freeze-thaw cycle damaging influence to concrete structure; And as coagulating cement soil additive.
Beneficial effect of the present invention: (1) raw material wilkinite geologic reserve is large, distribution face width, source is wide, and cost is low; And lateral reactivity SiO
2source is wide, and water reducer is in large supply, good economy performance; (2) easy to use, can alleviate impervious anticorrosion Construction Technology difficulty, and betterment works quality.
Embodiment
Below in conjunction with embodiment, the present invention is described in further detail, but these embodiment must not be for explaining limiting the scope of the invention.
Embodiment 1:
Selecting chimney ash " silicon ash " and the naphthalene water reducer powder of commercially available modification sodium bentonite in powder (fineness 80 μ m tail over < 12%, smectite content 92.5%), silicon metal factory is raw material, press modification sodium bentonite in powder: silicon ash: naphthalene water reducer=100: 5: 1.6 mass ratio batchings, mix, make the impervious anti-salt erosion coagulating cement soil additive of wilkinite.
This additive is allocated in 42.5 class g cements, homogenizing, the amount of allocating into is equivalent to 5% of cement weight, for water channel construction, through 2 years, observes, and does not find seepage salt erosion sign.
Embodiment 2:
In suspension in Purification of Bentonite and modifying process, separately be added into the poly-carboxylic salt water reducer that accounts for wilkinite quality 0.3%, make the butt modified alta-mud (smectite content 91.3%) that simultaneously contains water reducer, alternative is made lateral reactivity carbonic acid gas raw material with silica, press modified alta-mud (wilkinite 100+ water reducer 0.3) 100.3: the mass ratio batching of silica 25, grinding is made the fine powder of fineness < 12%, obtains the impervious anti-salt erosion coagulating cement soil additive of wilkinite.
This additive is allocated in 52.5 class g cements, homogenizing, the amount of allocating into is equivalent to 3% of cement weight, for the construction of seashore burrock, through 2 years, observes, and does not find seepage salt erosion sign.
Embodiment 3:
Select commercially available organism modified alta-mud powder (tail over < 12% smectite content 91% of fineness 80 μ m) and the front product silica flour (being commonly called as white carbon black) of industry and Powdered melamine water reducer, press organism modified alta-mud powder: silica flour: water reducer=100: 10:: 0.8 mass ratio batching, homogenizing, makes the impervious anti-salt erosion water coagulation soil additive of wilkinite.
This additive is replaced to 5% ground-slag and allocate in chamotte powder, blend into 42.5 class g cements, for culvert construction, through 2 years, observe, do not find seepage salt erosion sign.
Embodiment 4:
Selecting the block wilkinite drying after villager's picking is base-material (detecting smectite content 91%), and selecting sulfamate water reducer and diatomite concentrate is that raw material is adjusting material, commercially available ZC-R for alternative<sub TranNum="82">1</sub>the agent of type Composite Modification of Montmorillonite, as bentonite modified dose, is prepared burden block wilkinite, diatomite, water reducer in mass ratio at 100: 30: 1.2, enters the powder process of grinding machine grinding, presses ZC-R in grinding process<sub TranNum="83">1</sub>bentonite modified dose of specification sheets requirement of type, adds ZC-R continuously<sub TranNum="84">1</sub>bentonite modified dose of type, the fineness 80 μ m that make tail over<12% finished powder, be the impervious anti-salt erosion coagulating cement soil additive of wilkinite.
This additive is allocated in the concrete of mixing when the mixing concrete, and the amount of allocating into is equivalent to 6% of cement weight, for sewage lagoon, processes engineering construction, through 2 years, observes, and does not find seepage salt erosion sign.
Embodiment 5:
Selecting commercially available modification lithium base one amino modified bentonite in powder (entangling de-stone content 89.7%, fineness < 12%), silicon ash, Powdered modified lignosulfonate water reducing agent is raw material, bentonite in powder 100 in mass ratio: silicon ash 11.8: modified lignin resin water reducer 3.2 batchings, homogenizing, the finished powder of making, the i.e. impervious anti-salt erosion coagulating cement soil additive of wilkinite.
This additive is allocated into during with mortar in mixing bathroom, and the amount of allocating into is equivalent to 3% of cement weight, for sewage lagoon, processes engineering construction, through 2 years, observes, and does not find seepage salt erosion sign.
Claims (7)
1. the impervious anti-salt erosion of a wilkinite coagulating cement soil additive, is characterized in that, by modified alta-mud with wilkinite adjusting material is composite makes; Described wilkinite adjusting material is the mixture of active silica powder and water reducer, and the mass ratio of each component is, modified alta-mud: active silica powder: water reducer=100: 3 ~ 30: 3 ~ 3.5.
2. the impervious anti-salt erosion coagulating cement soil additive of wilkinite according to claim 1, is characterized in that: described modified alta-mud is the modified alta-mud of montmorillonite mineral content >=80%.
3. the impervious anti-salt of wilkinite according to claim 2 loses coagulating cement soil additive, it is characterized in that: described modified alta-mud is that calcium base, sodium base, hydrogen are aluminium base, magnesium base, lithium base or organism modified alta-mud, or inorganics-organism composite modified bentonite.
4. the impervious anti-salt erosion coagulating cement soil additive of wilkinite according to claim 1, is characterized in that: described active silica powder is silicon industrial residue " silicon ash ", Industrial products amorphous Si O
2powder, or natural SiO
2the 80 μ m that mineral are made tail over≤12% fine powder.
5. the impervious anti-salt erosion coagulating cement soil additive of wilkinite according to claim 4, is characterized in that: described industrial production amorphous Si O
2powder is white carbon black.
6. the impervious anti-salt erosion coagulating cement soil additive of wilkinite according to claim 4, is characterized in that: described natural SiO
2mineral are silica or diatomite.
7. according to the impervious anti-salt erosion coagulating cement soil additive of the wilkinite one of claim 1-6 Suo Shu, it is characterized in that: described water reducer is: naphthalene water reducer, melamine system water reducer, polycarboxylate based water reducer, sulfamate based water reducer or modified lignin mahogany sulfonate based water reducer.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310426910.1A CN103524067B (en) | 2013-09-18 | 2013-09-18 | Bentonite anti-seepage and anti-salt corrosion cement concrete additive |
| PCT/CN2013/087626 WO2015032131A1 (en) | 2013-09-06 | 2013-11-21 | Bentonite modifier, and modified bentonite and application thereof |
| US14/379,791 US9944557B2 (en) | 2013-09-06 | 2013-11-21 | Bentonite modifier, modified bentonite, and use thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310426910.1A CN103524067B (en) | 2013-09-18 | 2013-09-18 | Bentonite anti-seepage and anti-salt corrosion cement concrete additive |
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| Publication Number | Publication Date |
|---|---|
| CN103524067A true CN103524067A (en) | 2014-01-22 |
| CN103524067B CN103524067B (en) | 2014-08-06 |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104556775A (en) * | 2015-02-09 | 2015-04-29 | 孙宁 | Concrete additive |
| CN105669073A (en) * | 2016-01-08 | 2016-06-15 | 海南瑞泽新型建材股份有限公司 | Admixture for improving marine concrete impervious and anti-cracking performance |
| CN111116079A (en) * | 2019-12-30 | 2020-05-08 | 庐江县新创新型材料有限公司 | Bentonite anti-permeability and anti-salt corrosion concrete additive |
| CN112707405A (en) * | 2021-01-08 | 2021-04-27 | 北京建筑材料科学研究总院有限公司 | Modified phyllosilicate, preparation method and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102617073A (en) * | 2012-01-20 | 2012-08-01 | 北京新奥混凝土集团有限公司 | Plastic concrete for cutoff wall |
| CN102643059A (en) * | 2012-04-27 | 2012-08-22 | 中国水电顾问集团成都勘测设计研究院 | Bonding treating agent for concrete inorganic interface |
| CN103145365A (en) * | 2013-02-06 | 2013-06-12 | 北京中防元大建材科技有限公司 | Concrete anti-cracking repairing agent and concrete applying the same |
-
2013
- 2013-09-18 CN CN201310426910.1A patent/CN103524067B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102617073A (en) * | 2012-01-20 | 2012-08-01 | 北京新奥混凝土集团有限公司 | Plastic concrete for cutoff wall |
| CN102643059A (en) * | 2012-04-27 | 2012-08-22 | 中国水电顾问集团成都勘测设计研究院 | Bonding treating agent for concrete inorganic interface |
| CN103145365A (en) * | 2013-02-06 | 2013-06-12 | 北京中防元大建材科技有限公司 | Concrete anti-cracking repairing agent and concrete applying the same |
Non-Patent Citations (2)
| Title |
|---|
| 张涛: "膨润土改善塑性混凝土性能的作用机理", 《人民黄河》, 20 November 2007 (2007-11-20) * |
| 靳忠才: "塑性混凝土防渗配合比试验研究", 《太原理工大学学报》, 15 July 2012 (2012-07-15) * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104556775A (en) * | 2015-02-09 | 2015-04-29 | 孙宁 | Concrete additive |
| CN105669073A (en) * | 2016-01-08 | 2016-06-15 | 海南瑞泽新型建材股份有限公司 | Admixture for improving marine concrete impervious and anti-cracking performance |
| CN111116079A (en) * | 2019-12-30 | 2020-05-08 | 庐江县新创新型材料有限公司 | Bentonite anti-permeability and anti-salt corrosion concrete additive |
| CN111116079B (en) * | 2019-12-30 | 2022-01-25 | 庐江县新创新型材料有限公司 | Bentonite anti-permeability and anti-salt corrosion concrete additive |
| CN112707405A (en) * | 2021-01-08 | 2021-04-27 | 北京建筑材料科学研究总院有限公司 | Modified phyllosilicate, preparation method and application thereof |
| CN112707405B (en) * | 2021-01-08 | 2023-01-17 | 北京建筑材料科学研究总院有限公司 | Modified phyllosilicate, and preparation method and application thereof |
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