CN103435776A - Preparation method of environment-friendly PU plastic for race tracks - Google Patents
Preparation method of environment-friendly PU plastic for race tracks Download PDFInfo
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- CN103435776A CN103435776A CN2013103422388A CN201310342238A CN103435776A CN 103435776 A CN103435776 A CN 103435776A CN 2013103422388 A CN2013103422388 A CN 2013103422388A CN 201310342238 A CN201310342238 A CN 201310342238A CN 103435776 A CN103435776 A CN 103435776A
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Abstract
The invention discloses a preparation method of environment-friendly PU plastic for race tracks. The preparation method is characterized in that the PU plastic comprises the components of polyether polyol, diphenyl methane diisocyanate, 1,4-butanediol and an organic composite rare-earth catalyst; the preparation method comprises the steps of prepolymerization, removal of air bubbles in vacuum, pouring, curing and finished product forming. The PU plastic prepared by the preparation method has low toxicity and good mechanical property; a plastic race track prepared with the PU plastic is safe, environment-friendly and free from defects such as bubbles and depression.
Description
Technical field
The present invention relates to the plastic cement preparing technical field, particularly relate to the preparation method of a kind of runway with environment-friendly type PU plastic cement.
Background technology
The polyurethane plastic runway overwhelming majority of laying at present is mixed type, its basic recipe is the TDI(tolylene diisocyanate)-MOCA(3,3 '-bis-chloro-4,4 '-diaminodiphenyl-methane)-heavy metal catalyst system, cause be laid to plastic cement race track to have the problem of poisoning and laying high cost.TDI belongs to II level poisonous substance, it is suspicious human carcinogen's thing, international movement runway technology association (IST) just proposed the suggestion of " not accepting to use the motion runway containing the polyurethane system of TDI composition " as far back as 1994, MOCA belongs to arylamine ester class chemical, toxicity is larger, can cause bladder cancer, take organic mercury/lead or organic mercury/zinc composite catalyst as main heavy metal catalyst system harmful to human, contaminate environment.
Summary of the invention
The technical problem that the present invention mainly solves is to provide the preparation method of a kind of runway with environment-friendly type PU plastic cement, can solve the large problem of conventional P U plastic cement race track toxicity.
For solving the problems of the technologies described above, the technical scheme that the present invention adopts is: the preparation method of environment-friendly type PU plastic cement for a kind of runway, and component comprises: polyether glycol, diphenylmethanediisocyanate, BDO, organic composite rare earth catalyst; Preparation method's step is: prepolymerization-vacuum outgas bubble-cast-solidify-finished product.
In a preferred embodiment of the present invention, described organic composite rare earth catalyst is isooctoate of rare earth metal and isocaprylic acid zinc, and proportioning is 2:1.
In a preferred embodiment of the present invention, described prepolymerization method is: in reaction vessel, add polyether glycol, stirring is warmed up to certain temperature, and vacuumize stirring dehydration l h, after having dewatered, be cooled to temperature required, add the diphenylmethanediisocyanate that becomes certain proportioning with polyether glycol, BDO, finally add the organic RE composite catalyst.
In a preferred embodiment of the present invention, the technique of described vacuum outgas bubble is: vacuum tightness 0.02~0.05MPa, time 2h.
In a preferred embodiment of the present invention, described curing process is: 140 ℃ of solidification values, set time 4h.
In a preferred embodiment of the present invention, the temperature that described stirring heats up is 110~120 ℃.
In a preferred embodiment of the present invention, described temperature required be 50~60 ℃.
In a preferred embodiment of the present invention, the quality proportioning of described polyether glycol, diphenylmethanediisocyanate, BDO is 100:50:15.
The invention has the beneficial effects as follows: the preparation method of environment-friendly type PU plastic cement for a kind of runway of the present invention, the PU plastic cement toxicity of preparation is low, and mechanical property is good, and the plastic cement race track prepared with it is safety and environmental protection not only, and there is no the defects such as bubble, depression.
The accompanying drawing explanation
Fig. 1 is the schematic flow sheet of a kind of runway of the present invention by the preparation method of environment-friendly type PU plastic cement.
Embodiment
Below in conjunction with accompanying drawing, preferred embodiment of the present invention is described in detail, thereby so that advantages and features of the invention can be easier to be it will be appreciated by those skilled in the art that, protection scope of the present invention is made to more explicit defining.
Refer to Fig. 1, the embodiment of the present invention comprises:
Agitator is being housed, in 3 mouthfuls of flasks of vacuum meter and thermometer, add 100g polyether glycol 3010, stirring is warmed up to 110~120 ℃, and vacuumize and stir dehydration 1h, after having dewatered, be cooled to 50~60 ℃, add diphenylmethanediisocyanate 50g, then add 1, 4-butyleneglycol 15g, the organic RE composite catalyst 5g that isooctoate of rare earth metal and isocaprylic acid zinc proportioning are 2:1, by said mixture de-bubbled 2h under the vacuum tightness of 0.02~0.05MPa, promptly be poured into and scribble estersil and be preheating in the mould of 80 ℃, solidify 4 h under 140 ℃ after, obtain the PU plastic cement.
The foregoing is only embodiments of the invention; not thereby limit the scope of the claims of the present invention; every equivalent structure or conversion of equivalent flow process that utilizes specification sheets of the present invention and accompanying drawing content to do; or directly or indirectly be used in other relevant technical fields, all in like manner be included in scope of patent protection of the present invention.
Claims (8)
1. the preparation method of a runway use environment-friendly type PU plastic cement, is characterized in that, component comprises: polyether glycol, diphenylmethanediisocyanate, BDO, organic composite rare earth catalyst; Preparation method's step is: prepolymerization-vacuum outgas bubble-cast-solidify-finished product.
2. the preparation method of environment-friendly type PU plastic cement for runway according to claim 1, is characterized in that, described organic composite rare earth catalyst is isooctoate of rare earth metal and isocaprylic acid zinc, and proportioning is 2:1.
3. the preparation method of environment-friendly type PU plastic cement for runway according to claim 1, it is characterized in that, described prepolymerization method is: add polyether glycol in reaction vessel, stir and be warmed up to certain temperature, and vacuumize stirring dehydration l h, after having dewatered, be cooled to temperature requiredly, add the diphenylmethanediisocyanate that becomes certain proportioning with polyether glycol, 1, the 4-butyleneglycol, finally add the organic RE composite catalyst.
4. the preparation method of environment-friendly type PU plastic cement for runway according to claim 1, is characterized in that, the technique of described vacuum outgas bubble is: vacuum tightness 0.02~0.05MPa, time 2h.
5. the preparation method of environment-friendly type PU plastic cement for runway according to claim 1, is characterized in that, described curing process is: 140 ℃ of solidification values, set time 4h.
6. the preparation method of environment-friendly type PU plastic cement for runway according to claim 3, is characterized in that, the temperature that described stirring heats up is 110~120 ℃.
7. the preparation method of environment-friendly type PU plastic cement for runway according to claim 3, is characterized in that, described temperature required be 50~60 ℃.
8. the preparation method of environment-friendly type PU plastic cement for runway according to claim 3, is characterized in that, the quality proportioning of described polyether glycol, diphenylmethanediisocyanate, BDO is 100:50:15.
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103709923A (en) * | 2013-12-18 | 2014-04-09 | 黎明化工研究设计院有限责任公司 | Wear-resistant spraying polyurethane resin composition, and preparation method and construction method thereof |
CN104725659A (en) * | 2015-03-13 | 2015-06-24 | 华南理工大学 | Polyurethane using rare earth as foaming aid and preparation method thereof |
CN105949751A (en) * | 2016-07-06 | 2016-09-21 | 苏州亚科塑胶有限公司 | Preparation method of anti-skid, abrasion-resistant and high-elasticity composite plastic runway surface layer |
CN106977679A (en) * | 2017-03-28 | 2017-07-25 | 江苏耐斯坦铺装材料有限公司 | A kind of composite catalyst and plastic cement race track adhesive based on based on organic RE material |
CN107216800A (en) * | 2017-06-28 | 2017-09-29 | 吕超 | A kind of hydrophobically modified nano barium sulfate fills the preparation method of aqueous polyurethane coating |
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CN1580163A (en) * | 2004-05-19 | 2005-02-16 | 深圳市奥顺达实业有限公司 | Environmentally friendly track rubber, and its production method and track construction method using same |
CN101245184A (en) * | 2007-02-15 | 2008-08-20 | 天津市景鸿体育设施技术有限公司 | Nano-environment protection type polyurethane paving material for athletic ground and manufacture method thereof |
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103709923A (en) * | 2013-12-18 | 2014-04-09 | 黎明化工研究设计院有限责任公司 | Wear-resistant spraying polyurethane resin composition, and preparation method and construction method thereof |
CN103709923B (en) * | 2013-12-18 | 2016-08-17 | 黎明化工研究设计院有限责任公司 | A kind of wear-resisting spraying polyurethane resin combination and preparation method thereof and construction method |
CN104725659A (en) * | 2015-03-13 | 2015-06-24 | 华南理工大学 | Polyurethane using rare earth as foaming aid and preparation method thereof |
CN104725659B (en) * | 2015-03-13 | 2018-02-23 | 华南理工大学 | A kind of polyurethane by the use of rare earth as blowing promotor and preparation method thereof |
CN105949751A (en) * | 2016-07-06 | 2016-09-21 | 苏州亚科塑胶有限公司 | Preparation method of anti-skid, abrasion-resistant and high-elasticity composite plastic runway surface layer |
CN106977679A (en) * | 2017-03-28 | 2017-07-25 | 江苏耐斯坦铺装材料有限公司 | A kind of composite catalyst and plastic cement race track adhesive based on based on organic RE material |
CN106977679B (en) * | 2017-03-28 | 2021-03-19 | 江苏耐斯坦建设有限公司 | Composite catalyst based on organic rare earth material and adhesive for plastic track |
CN107216800A (en) * | 2017-06-28 | 2017-09-29 | 吕超 | A kind of hydrophobically modified nano barium sulfate fills the preparation method of aqueous polyurethane coating |
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Application publication date: 20131211 |