CN103421550B - A kind of environment protection type biological liquid fuel and preparation method thereof - Google Patents
A kind of environment protection type biological liquid fuel and preparation method thereof Download PDFInfo
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- CN103421550B CN103421550B CN201310391234.9A CN201310391234A CN103421550B CN 103421550 B CN103421550 B CN 103421550B CN 201310391234 A CN201310391234 A CN 201310391234A CN 103421550 B CN103421550 B CN 103421550B
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Abstract
The invention discloses a kind of environment protection type biological liquid fuel and preparation method thereof, environment protection type biological liquid fuel of the present invention is made up of the material of following mass percent: vegetable and animals oils 55 ~ 75%, carbon 5 15 ~ 20%, methylal 10 ~ 12%, fatty acid methyl ester 5 ~ 10, triethylamine 0.5 ~ 3.0%, mask agent 0.1 ~ 2.0%, hydrazine 0.05 ~ 1.5%.This fuel process is as follows: 1. get vegetable and animals oils, methylal and fatty acid methyl ester in mass ratio, and it fully mixed; 2. take carbon five and hydrazine in mass ratio, and it is fully mixed; 3. the mixed solution of gained in 1. step is mixed with the mixed solution of 2. step gained; 4. add triethylamine, mask agent successively in mass ratio again, make after being fully uniformly mixed.Product leading indicator reaches solar oil national standard, both can be used as boiler oil and also can be used as power fuel.
Description
Technical field
The invention belongs to field of renewable energy technology.
Background technology
Since 20 century 70 outburst oil crisises, stone oil supplying is more and more nervous, and oil price hits new peak repeatly, breaches the high point of 100 dollars/barrel at the end of 2007 especially.According to estimates, to the year two thousand thirty, the petroleum demand of world every day will reach 117.6 MMbbl.The demand in additional 31.7 MMbbl/sky is equivalent to 3 Saudi oil day output.From the situation of China, in recent years along with the fast development of national economy, China is to the demand sustainable growth of petroleum resources, even if by the prediction of slow consumption rate of growth, the oil supply breach to 2010 and the year two thousand twenty will be respectively 1.5 × 10
8t and 2.5 × 10
8t, China's oil external dependence degree will reach 45% and 54% respectively when the time comes, and Oil Safety will inevitably become an important component part of national security.In addition, " 12 " period, China is still in industrialization and urbanization accelerated development stage, and along with the further expansion of economic scale, energy demand also can continue very fast increase, estimates that the Energy situation faced during " 12 " is still severe.The energy has become in quite long at present and in the future period of China, the outstanding bottleneck of restriction economy and social development.By the impact of above factor, there is serious shortage phenomenon in oil supply both domestic and external, great inconvenience is brought to expanding economy and people's lives, in order to fossil energy problem in short supply can be solved, country has put into effect many relevant policies to encourage the development of renewable energy source, and biological liquid fuel is exactly one of them.
Sick dead pig or the poultry that dies of illness can be converted into vegetable and animals oils (productive rate about 45 ~ 85%) by high temperature pyrolysis technology, vegetable and animals oils is a kind of red or brown liquid, be light yellow after desolventing technology, the much cards of calorific value 9000, can directly as the raw material of biofuel, CO during biofuel burning
2discharge be zero, SO
2, NOx discharge also significantly reduce relative to fossil oil, can find out that vegetable and animals oils is very good selection as the raw material of biofuel.
Although the vegetable and animals oils of present method process as the raw material of biofuel, can have environmental protection and recyclability simultaneously, the production technology also Shortcomings part of biofuel.Domestic production of biodiesel technology many employings chemical method, chemical method investment of production is large, it is slow to take effect, and production process relates to High Temperature High Pressure, and production method generally adopts sulfuric acid, caustic soda etc. as catalyzer, and production process has discharge of wastewater, can cause secondary pollution to environment.And chemical method produce there is density in biofuel, viscosity is higher, can not the disadvantages such as Motor vehicles be directly used in.
Summary of the invention
The object of the invention is to the deficiency existed for existing biodiesel technology, provide a kind of environment protection type biological liquid fuel and preparation method thereof, product index reaches 0# ,-10# and the-20# derv fuel oil standard of GB252-2011 standard.The vegetable and animals oils that biological liquid fuel main raw material of the present invention adopts sick dead pig or the poultry that dies of illness to obtain through Pintsch process, auxiliary material adopts the fatty acid methyl ester etc. of oil refinery offal carbon five, bioenergy company, raw materials enjoy stable sources, extensive.
Object of the present invention realizes by following technical measures:
Environment protection type biological liquid fuel of the present invention is made up of the material of following mass ratio, wherein:
Preparation method of the present invention comprises the following steps:
1. get vegetable and animals oils, methylal and fatty acid methyl ester in mass ratio, and it is fully mixed;
2. take carbon five and hydrazine in mass ratio, and it is fully mixed;
3. the mixed solution of gained in 1. step is mixed with the mixed solution of 2. step gained, then add triethylamine, mask agent successively in mass ratio, after being fully uniformly mixed, can this product be obtained.
The liquid product that vegetable and animals oils system sick dead pig of the present invention or the poultry that dies of illness obtain through Pintsch process.
Mask agent of the present invention is flower of Greenish Lily essence, lavender fragrance, lemon flavour, jasmine flower essence or Rose essence.
The present invention's tool compared with existing biological liquid fuel technology has the following advantages:
1. the present invention makes full use of sick dead pig or the poultry that dies of illness obtains the vegetable and animals oils of gained as main raw material through Pintsch process, belongs to waste resource recycling, has both fully solved sick dead pig or the poultry that dies of illness deals with the harm caused society improperly, protects environment again;
2. the biological liquid fuel stable performance prepared of the present invention, for a long time not stratified, never degenerate;
3. the biological liquid fuel prepared of the present invention is without methyl alcohol or crude carbinol, and science adopts methylal, fatty acid methyl ester, eliminates the emulsifying agent of great number, product cost is reduced greatly;
4. the present invention adopts the byproduct carbon five of refinery as raw material, greatly reduces density and the viscosity of biological liquid fuel;
5. the present invention adopts essence as mask agent, makes the taste of biological liquid fuel more be tending towards fossil fuel;
6. whole preparation technology carries out at normal temperatures and pressures, does not relate to High Temperature High Pressure, produces without " three wastes ", environmentally friendly;
7. the biological liquid fuel sufficient combustion prepared of the present invention, without carbon distribution, smokeless, SOx, NOx discharge capacity is less than 0.08ppm;
8. the biological liquid fuel price prepared of the present invention is lower than ordinary petroleum fuel, can be used as power fuel and boiler oil uses.
Embodiment
Embodiment 1
Take vegetable and animals oils 69%, carbon 5 15%, methylal 10%, fatty acid methyl ester 5%, triethylamine 0.5%, mask agent 0.2%, hydrazine 0.3% in mass ratio.
1. get vegetable and animals oils, methylal and fatty acid methyl ester in mass ratio, and it is fully mixed;
2. take carbon five and hydrazine in mass ratio, and it is fully mixed;
3. the mixed solution of gained in 1. step is mixed with the mixed solution of 2. step gained, add triethylamine, mask agent successively in mass ratio again, after being fully uniformly mixed, environment protection type biological liquid fuel of the present invention can be obtained, environment protection type biological liquid fuel steady quality prepared by the present invention, calorific value are high, can deposit more than 5 years not stratified, never degenerate.
Embodiment 2
Take vegetable and animals oils 63%, carbon 5 18%, methylal 10%, fatty acid methyl ester 8%, triethylamine 0.6%, mask agent 0.1%, hydrazine 0.4% in mass ratio.
1. get vegetable and animals oils, methylal and fatty acid methyl ester in mass ratio, and it is fully mixed;
2. take carbon five and hydrazine in mass ratio, and it is fully mixed;
3. the mixed solution of gained in 1. step is mixed with the mixed solution of 2. step gained, add triethylamine, mask agent successively in mass ratio again, after being fully uniformly mixed, environment protection type biological liquid fuel of the present invention can be obtained, environment protection type biological liquid fuel steady quality prepared by the present invention, calorific value are high, can deposit more than 5 years not stratified, never degenerate.
Embodiment 3
Take vegetable and animals oils 60%, carbon 5 20%, methylal 12%, fatty acid methyl ester 7%, triethylamine 0.6%, mask agent 0.2%, hydrazine 0.2% in mass ratio.
1. get vegetable and animals oils, methylal and fatty acid methyl ester in mass ratio, and it is fully mixed;
2. take carbon five and hydrazine in mass ratio, and it is fully mixed;
3. the mixed solution of gained in 1. step is mixed with the mixed solution of 2. step gained, add triethylamine, mask agent successively in mass ratio again, after being fully uniformly mixed, environment protection type biological liquid fuel of the present invention can be obtained, environment protection type biological liquid fuel steady quality prepared by the present invention, calorific value are high, can deposit more than 5 years not stratified, never degenerate.
Embodiment 4
Take vegetable and animals oils 56%, carbon 5 20%, methylal 12%, fatty acid methyl ester 10%, triethylamine 0.8%, mask agent 0.3%, hydrazine 0.9% in mass ratio.
1. get vegetable and animals oils, methylal and fatty acid methyl ester in mass ratio, and it is fully mixed;
2. take carbon five and hydrazine in mass ratio, and it is fully mixed;
3. the mixed solution of gained in 1. step is mixed with the mixed solution of 2. step gained, add triethylamine, mask agent successively in mass ratio again, after being fully uniformly mixed, environment protection type biological liquid fuel of the present invention can be obtained, environment protection type biological liquid fuel steady quality prepared by the present invention, calorific value are high, can deposit more than 5 years not stratified, never degenerate.
Claims (5)
1. a preparation method for environment protection type biological liquid fuel, is characterized in that: it is mixed by the material of following mass ratio, wherein:
2. the preparation method of a kind of environment protection type biological liquid fuel as claimed in claim 1, is characterized in that: carry out mixing the liquid product that used vegetable and animals oils system sick dead pig or the poultry that dies of illness obtain through Pintsch process.
3. the preparation method of a kind of environment protection type biological liquid fuel as claimed in claim 1, is characterized in that: carry out mixing that used mask agent is flower of Greenish Lily essence, lavender fragrance, lemon flavour, jasmine flower essence or Rose essence.
4. the preparation method of a kind of environment protection type biological liquid fuel as claimed in claim 1, is characterized in that: the process of carrying out mixing comprises the steps: successively
1. get vegetable and animals oils, methylal and fatty acid methyl ester in mass ratio, and it is fully mixed;
2. take carbon five and hydrazine in mass ratio, and it is fully mixed;
3. the mixed solution of gained in 1. step is mixed with the mixed solution of 2. step gained, then add triethylamine, mask agent successively in mass ratio, after being fully uniformly mixed, can this product be obtained.
5. the environment protection type biological liquid fuel prepared by any one method described in claim 1-4, is characterized in that: this fuel is made up of the material comprising following mass ratio, wherein:
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| CN201310391234.9A CN103421550B (en) | 2013-09-02 | 2013-09-02 | A kind of environment protection type biological liquid fuel and preparation method thereof |
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|---|---|---|---|
| CN201310391234.9A CN103421550B (en) | 2013-09-02 | 2013-09-02 | A kind of environment protection type biological liquid fuel and preparation method thereof |
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| CN103421550A CN103421550A (en) | 2013-12-04 |
| CN103421550B true CN103421550B (en) | 2015-11-25 |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105505485B (en) * | 2015-12-10 | 2017-06-30 | 邰万富 | A kind of compound method of environmental protection and energy saving high cleanness methanol diesel |
| CN111408298B (en) * | 2020-04-03 | 2022-06-03 | 贵州六维新能源股份有限公司 | Biological liquid fuel and preparation system and method thereof |
| CN111944566A (en) * | 2020-07-23 | 2020-11-17 | 成都国丰新能源科技有限公司 | New energy mixed biological methyl ester fuel and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1462795A (en) * | 2002-05-31 | 2003-12-24 | 中国石油化工股份有限公司 | Additive compsn. for stability of diesel oil |
| CN1928035A (en) * | 2006-10-23 | 2007-03-14 | 姜彬 | Environmental protection energy-saving diesel oil |
| CN101469282A (en) * | 2007-12-25 | 2009-07-01 | 史国兴 | Biodiesel |
| CN101643668A (en) * | 2009-08-26 | 2010-02-10 | 河北中振石化贸易有限公司 | Bio-diesel |
| CN102108313A (en) * | 2010-06-18 | 2011-06-29 | 上海纽孚尔能源技术有限公司 | Biological emulsified diesel oil |
-
2013
- 2013-09-02 CN CN201310391234.9A patent/CN103421550B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1462795A (en) * | 2002-05-31 | 2003-12-24 | 中国石油化工股份有限公司 | Additive compsn. for stability of diesel oil |
| CN1928035A (en) * | 2006-10-23 | 2007-03-14 | 姜彬 | Environmental protection energy-saving diesel oil |
| CN101469282A (en) * | 2007-12-25 | 2009-07-01 | 史国兴 | Biodiesel |
| CN101643668A (en) * | 2009-08-26 | 2010-02-10 | 河北中振石化贸易有限公司 | Bio-diesel |
| CN102108313A (en) * | 2010-06-18 | 2011-06-29 | 上海纽孚尔能源技术有限公司 | Biological emulsified diesel oil |
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| CN103421550A (en) | 2013-12-04 |
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Effective date of registration: 20151008 Address after: Liu village Jiyuan city Henan province 459000 Shaoyuan Applicant after: HENAN LONGZHENG BIOENERGY CO.,LTD. Applicant after: Chen Rongxia Address before: Liu village Jiyuan city Henan province 459000 Shaoyuan Applicant before: HENAN LONGZHENG BIOENERGY CO.,LTD. |
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Effective date of registration: 20230829 Address after: Room 506, Unit 1, Building 4, No. 26 Dongqing Street, Zhengzhou High tech Industrial Development Zone, Zhengzhou City, Henan Province, 450001 Patentee after: Henan Guangyue New Energy Technology Co.,Ltd. Address before: 459000 Liugou village, Shaoyuan Town, Jiyuan City, Henan Province Patentee before: HENAN LONGZHENG BIOENERGY CO.,LTD. Patentee before: Chen Rongxia |
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