CN103387785A - Water-resistance finishing paint for pleasure boats, and preparation method thereof - Google Patents
Water-resistance finishing paint for pleasure boats, and preparation method thereof Download PDFInfo
- Publication number
- CN103387785A CN103387785A CN2013102838042A CN201310283804A CN103387785A CN 103387785 A CN103387785 A CN 103387785A CN 2013102838042 A CN2013102838042 A CN 2013102838042A CN 201310283804 A CN201310283804 A CN 201310283804A CN 103387785 A CN103387785 A CN 103387785A
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- CN
- China
- Prior art keywords
- parts
- water
- acrylic acid
- pleasure
- boat
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003973 paint Substances 0.000 title claims abstract description 16
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 30
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 29
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 22
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims abstract description 16
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000004342 Benzoyl peroxide Substances 0.000 claims abstract description 15
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims abstract description 15
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229920000180 alkyd Polymers 0.000 claims abstract description 15
- 235000019400 benzoyl peroxide Nutrition 0.000 claims abstract description 15
- 239000006229 carbon black Substances 0.000 claims abstract description 15
- 239000003822 epoxy resin Substances 0.000 claims abstract description 15
- 239000000178 monomer Substances 0.000 claims abstract description 15
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 7
- 229910052882 wollastonite Inorganic materials 0.000 claims abstract description 7
- 239000010456 wollastonite Substances 0.000 claims abstract description 7
- 239000000463 material Substances 0.000 claims description 18
- ZXDDPOHVAMWLBH-UHFFFAOYSA-N 2,4-Dihydroxybenzophenone Chemical compound OC1=CC(O)=CC=C1C(=O)C1=CC=CC=C1 ZXDDPOHVAMWLBH-UHFFFAOYSA-N 0.000 claims description 14
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 14
- 239000004698 Polyethylene Substances 0.000 claims description 14
- 150000001408 amides Chemical class 0.000 claims description 14
- 235000019241 carbon black Nutrition 0.000 claims description 14
- 239000000460 chlorine Substances 0.000 claims description 14
- 229910052801 chlorine Inorganic materials 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 14
- -1 polyethylene Polymers 0.000 claims description 14
- 229920000573 polyethylene Polymers 0.000 claims description 14
- 235000010215 titanium dioxide Nutrition 0.000 claims description 14
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims description 8
- 238000007599 discharging Methods 0.000 claims description 6
- 230000008030 elimination Effects 0.000 claims description 6
- 238000003379 elimination reaction Methods 0.000 claims description 6
- 239000012535 impurity Substances 0.000 claims description 6
- 229920005989 resin Polymers 0.000 claims description 6
- 239000011347 resin Substances 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 238000000034 method Methods 0.000 claims 1
- 230000006750 UV protection Effects 0.000 abstract description 2
- 239000005711 Benzoic acid Substances 0.000 abstract 1
- 239000004709 Chlorinated polyethylene Substances 0.000 abstract 1
- 239000004952 Polyamide Substances 0.000 abstract 1
- 235000010233 benzoic acid Nutrition 0.000 abstract 1
- 230000014759 maintenance of location Effects 0.000 abstract 1
- 229920002647 polyamide Polymers 0.000 abstract 1
- 230000001681 protective effect Effects 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 230000004224 protection Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
- Physical Water Treatments (AREA)
Abstract
The invention relates to a water-resistance finishing paint for pleasure boats, and a preparation method thereof. The finishing paint consists of the following components in parts by mass: 15-30 parts of an acrylic modified alkyd resin, 20-35 parts of an epoxy resin, 10-25 parts of high chlorinated polyethylene, 5-13 parts of an acrylic acid monomer, 10-20 parts of titanium dioxide, 5-13 parts of carbon black, 20-40 parts of wollastonite, 12-30 parts of polyamide, 0.3-0.72 part of benzoyl peroxide, 0.5-1.2 parts of 2, 4-dihydroxy benaophenonel, 7-13 parts of cyclohexanone, 3-8 parts of benzoic acid and 6-13 parts of butanols. The water-resistance finishing paint provided by the invention has bright and rich color, excellent performances of gloss retention, water resistance, ultraviolet resistance, wear resistant and durability, and excellent decorative and protective effects on the pleasure boats.
Description
Technical field
The present invention relates to a kind of coating and preparation method thereof, relate in particular to a kind of pleasure-boat and paint and preparation method thereof with water-fast guarantor's light.
Background technology
All be provided with pleasure-boat in a lot of parks, tourist attractions, for the visitor, play and view and admire landscape.The pleasure-boat waterline is under salt fog and uv irradiating for a long time with upper part, and the underwater position is in water for a long time, and again due to its distinctive purposes of pleasure-boat, its surperficial coating color is more bright-coloured.Therefore, that the japanning that is coated in the pleasure-boat surface will possess is water-fast, uvioresistant, guarantor's light, wear-resisting character.But existing pleasure-boat will lose original gloss with japanning after pleasure-boat uses for some time, and is water-fast also not high with wear resisting property.
Summary of the invention
The technical problem that solves:Water-fast with japanning for existing pleasure-boat, as to protect light, wear resisting property deficiency shortcoming, the invention provides a kind of pleasure-boat and paint and preparation method thereof with water-fast guarantor's light.
Technical scheme:Pleasure-boat is painted with water-fast guarantor's light, in mass parts, contains following composition:
15～30 parts of acrylic acid modified alkyd resins
20～35 parts of epoxy resin
10～25 parts of high chlorine polyethylene
5～13 parts of Acrylic Acid Monomers
10～20 parts of titanium dioxides
5～13 parts of carbon blacks
20～40 parts of wollastonites
12～30 parts of polymeric amide
0.3～0.72 part of benzoyl peroxide
0.5～1.2 part of 2,4 dihydroxyl benzophenone
7～13 parts of pimelinketone
3～8 parts, phenylformic acid
6～13 parts, butanols.
Pleasure-boat described above is painted with water-fast guarantor's light, in mass parts, contains following composition:
18～25 parts of acrylic acid modified alkyd resins
25～32 parts of epoxy resin
13～20 parts of high chlorine polyethylene
6～11 parts of Acrylic Acid Monomers
15～20 parts of titanium dioxides
7～12 parts of carbon blacks
25～35 parts of wollastonites
15～25 parts of polymeric amide
0.5～0.7 part of benzoyl peroxide
0.7～1 part of 2,4 dihydroxyl benzophenone
8.5～11 parts of pimelinketone
4.5～7 parts, phenylformic acid
8～12 parts, butanols.
Pleasure-boat described above is as follows with the preparation process of water-fast guarantor's light japanning:
The first step: acrylic acid modified alkyd resin, epoxy resin, pimelinketone, phenylformic acid and butanols are joined in there-necked flask, after adding under 60～70 ℃ of water bath condition and stirring and to make resin dissolves, with 254 mesh count/cm(100 order) standard sieve elimination impurity obtains base-material;
Second step: the base-material that obtains in the first step is joined in reactor, add titanium dioxide, carbon black, wollastonite, high chlorine polyethylene and Acrylic Acid Monomer, be uniformly mixed in rear input shredder and grind, after fineness≤50 μ m, discharging obtains mixture;
The 3rd step: the material of second step is mixed with polymeric amide, benzoyl peroxide, 2,4 dihydroxyl benzophenone, namely obtain pleasure-boat and paint with water-fast guarantor's light.
Beneficial effect:Pleasure-boat provided by the invention is with water-fast guarantor's light japanning and preparation method thereof, and this coating bright in color is plentiful, has excellent guarantor's light, water-fast, uvioresistant, wear-resisting, durable performance, can play good decoration and provide protection to pleasure-boat.
Embodiment
Embodiment 1
The present embodiment provides a kind of pleasure-boat to paint with water-fast guarantor's light, in mass parts, contains following composition:
15 parts of acrylic acid modified alkyd resins
20 parts of epoxy resin
10 parts of high chlorine polyethylene
5 parts of Acrylic Acid Monomers
10 parts of titanium dioxides
5 parts of carbon blacks
20 parts of wollastonites
12 parts of polymeric amide
0.3 part of benzoyl peroxide
0.5 part of 2,4 dihydroxyl benzophenone
7 parts of pimelinketone
3 parts, phenylformic acid
6 parts, butanols.
Pleasure-boat is as follows with the preparation process of water-fast guarantor's light japanning:
The first step: acrylic acid modified alkyd resin, epoxy resin, pimelinketone, phenylformic acid and butanols are joined in there-necked flask, after adding under 60～70 ℃ of water bath condition and stirring and to make resin dissolves, with 254 mesh count/cm(100 order) standard sieve elimination impurity obtains base-material;
Second step: the base-material that obtains in the first step is joined in reactor, add titanium dioxide, carbon black, wollastonite, high chlorine polyethylene and Acrylic Acid Monomer, be uniformly mixed in rear input shredder and grind, after fineness≤50 μ m, discharging obtains mixture;
The 3rd step: the material of second step is mixed with polymeric amide, benzoyl peroxide, 2,4 dihydroxyl benzophenone, namely obtain pleasure-boat and paint with water-fast guarantor's light.
Embodiment 2
The present embodiment provides a kind of pleasure-boat to paint with water-fast guarantor's light, in mass parts, contains following composition:
18 parts of acrylic acid modified alkyd resins
25 parts of epoxy resin
13 parts of high chlorine polyethylene
6 parts of Acrylic Acid Monomers
15 parts of titanium dioxides
7 parts of carbon blacks
25 parts of wollastonites
15 parts of polymeric amide
0.5 part of benzoyl peroxide
0.7 part of 2,4 dihydroxyl benzophenone
8.5 parts of pimelinketone
4.5 parts, phenylformic acid
8 parts, butanols.
Pleasure-boat is as follows with the preparation process of water-fast guarantor's light japanning:
The first step: acrylic acid modified alkyd resin, epoxy resin, pimelinketone, phenylformic acid and butanols are joined in there-necked flask, after adding under 60～70 ℃ of water bath condition and stirring and to make resin dissolves, with 254 mesh count/cm(100 order) standard sieve elimination impurity obtains base-material;
Second step: the base-material that obtains in the first step is joined in reactor, add titanium dioxide, carbon black, wollastonite, high chlorine polyethylene and Acrylic Acid Monomer, be uniformly mixed in rear input shredder and grind, after fineness≤50 μ m, discharging obtains mixture;
The 3rd step: the material of second step is mixed with polymeric amide, benzoyl peroxide, 2,4 dihydroxyl benzophenone, namely obtain pleasure-boat and paint with water-fast guarantor's light.
Embodiment 3
The present embodiment provides a kind of pleasure-boat to paint with water-fast guarantor's light, in mass parts, contains following composition:
25 parts of acrylic acid modified alkyd resins
32 parts of epoxy resin
20 parts of high chlorine polyethylene
11 parts of Acrylic Acid Monomers
20 parts of titanium dioxides
12 parts of carbon blacks
35 parts of wollastonites
25 parts of polymeric amide
0.7 part of benzoyl peroxide
1 part of 2,4 dihydroxyl benzophenone
11 parts of pimelinketone
7 parts, phenylformic acid
12 parts, butanols.
Pleasure-boat is as follows with the preparation process of water-fast guarantor's light japanning:
The first step: acrylic acid modified alkyd resin, epoxy resin, pimelinketone, phenylformic acid and butanols are joined in there-necked flask, after adding under 60～70 ℃ of water bath condition and stirring and to make resin dissolves, with 254 mesh count/cm(100 order) standard sieve elimination impurity obtains base-material;
Second step: the base-material that obtains in the first step is joined in reactor, add titanium dioxide, carbon black, wollastonite, high chlorine polyethylene and Acrylic Acid Monomer, be uniformly mixed in rear input shredder and grind, after fineness≤50 μ m, discharging obtains mixture;
The 3rd step: the material of second step is mixed with polymeric amide, benzoyl peroxide, 2,4 dihydroxyl benzophenone, namely obtain pleasure-boat and paint with water-fast guarantor's light.
Embodiment 4
The present embodiment provides a kind of pleasure-boat to paint with water-fast guarantor's light, in mass parts, contains following composition:
21 parts of acrylic acid modified alkyd resins
29 parts of epoxy resin
16 parts of high chlorine polyethylene
8.5 parts of Acrylic Acid Monomers
17 parts of titanium dioxides
9.5 parts of carbon blacks
30 parts of wollastonites
20 parts of polymeric amide
0.6 part of benzoyl peroxide
0.85 part of 2,4 dihydroxyl benzophenone
9.3 parts of pimelinketone
5.7 parts, phenylformic acid
10 parts, butanols.
Pleasure-boat is as follows with the preparation process of water-fast guarantor's light japanning:
The first step: acrylic acid modified alkyd resin, epoxy resin, pimelinketone, phenylformic acid and butanols are joined in there-necked flask, after adding under 60～70 ℃ of water bath condition and stirring and to make resin dissolves, with 254 mesh count/cm(100 order) standard sieve elimination impurity obtains base-material;
Second step: the base-material that obtains in the first step is joined in reactor, add titanium dioxide, carbon black, wollastonite, high chlorine polyethylene and Acrylic Acid Monomer, be uniformly mixed in rear input shredder and grind, after fineness≤50 μ m, discharging obtains mixture;
The 3rd step: the material of second step is mixed with polymeric amide, benzoyl peroxide, 2,4 dihydroxyl benzophenone, namely obtain pleasure-boat and paint with water-fast guarantor's light.
The above-mentioned technical performance index of the pleasure-boat of embodiment 1～embodiment 4 with water-fast guarantor's light japanning of stating, its detected result is as follows:
Detected result
| Test item | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 |
| Gloss (60 ℃) | 62 | 63 | 65 | 68 |
| Water tolerance | 1100d | 1120d | 1125d | 1135d |
| The ultraviolet resistance irradiation time | 1022h | 1031h | 1046h | 1050h |
The above pleasure-boat that the embodiment of the present invention is provided is described in detail with water-fast guarantor's light japanning and preparation method thereof, for one of ordinary skill in the art, thought according to the embodiment of the present invention, all will change in specific embodiments and applications, in sum, this description should not be construed as limitation of the present invention.
Claims (3)
1. pleasure-boat is painted with water-fast guarantor's light, it is characterized in that containing following composition in mass parts:
15～30 parts of acrylic acid modified alkyd resins
20～35 parts of epoxy resin
10～25 parts of high chlorine polyethylene
5～13 parts of Acrylic Acid Monomers
10～20 parts of titanium dioxides
5～13 parts of carbon blacks
20～40 parts of wollastonites
12～30 parts of polymeric amide
0.3～0.72 part of benzoyl peroxide
0.5～1.2 part of 2,4 dihydroxyl benzophenone
7～13 parts of pimelinketone
3～8 parts, phenylformic acid
6～13 parts, butanols.
2. pleasure-boat according to claim 1 is painted with water-fast guarantor's light, it is characterized in that containing following composition in mass parts:
18～25 parts of acrylic acid modified alkyd resins
25～32 parts of epoxy resin
13～20 parts of high chlorine polyethylene
6～11 parts of Acrylic Acid Monomers
15～20 parts of titanium dioxides
7～12 parts of carbon blacks
25～35 parts of wollastonites
15～25 parts of polymeric amide
0.5～0.7 part of benzoyl peroxide
0.7～1 part of 2,4 dihydroxyl benzophenone
8.5～11 parts of pimelinketone
4.5～7 parts, phenylformic acid
8～12 parts, butanols.
3. pleasure-boat as claimed in claim 1 with the preparation method of water-fast guarantor's light japanning, is characterized in that the preparation process of the method is as follows:
The first step: acrylic acid modified alkyd resin, epoxy resin, pimelinketone, phenylformic acid and butanols are joined in there-necked flask, after adding under 60～70 ℃ of water bath condition and stirring and to make resin dissolves, with 254 mesh count/cm(100 order) standard sieve elimination impurity obtains base-material;
Second step: the base-material that obtains in the first step is joined in reactor, add titanium dioxide, carbon black, wollastonite, high chlorine polyethylene and Acrylic Acid Monomer, be uniformly mixed in rear input shredder and grind, after fineness≤50 μ m, discharging obtains mixture;
The 3rd step: the material of second step is mixed with polymeric amide, benzoyl peroxide, 2,4 dihydroxyl benzophenone, namely obtain pleasure-boat and paint with water-fast guarantor's light.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310283804.2A CN103387785B (en) | 2013-07-08 | 2013-07-08 | Water-resistance finishing paint for pleasure boats, and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310283804.2A CN103387785B (en) | 2013-07-08 | 2013-07-08 | Water-resistance finishing paint for pleasure boats, and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103387785A true CN103387785A (en) | 2013-11-13 |
| CN103387785B CN103387785B (en) | 2015-07-01 |
Family
ID=49532212
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310283804.2A Expired - Fee Related CN103387785B (en) | 2013-07-08 | 2013-07-08 | Water-resistance finishing paint for pleasure boats, and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103387785B (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103992734A (en) * | 2014-05-21 | 2014-08-20 | 珠海市威旗防腐科技有限公司 | Reflective water plane topcoat for ships and preparation method thereof |
| CN104371386A (en) * | 2014-11-13 | 2015-02-25 | 青岛厚科信息工程有限公司 | Quick-drying paint |
| CN104403530A (en) * | 2014-11-13 | 2015-03-11 | 青岛厚科信息工程有限公司 | Coating with acrylic modified alkyd resin |
| CN104449273A (en) * | 2014-10-23 | 2015-03-25 | 安徽省实防新型玻璃科技有限公司 | Ultraviolet-resistant water-based paint capable of reducing brightness of coating and applied to glass door and preparation method of ultraviolet-resistant water-based paint |
| CN106752796A (en) * | 2017-01-04 | 2017-05-31 | 安徽凤凰涂料科技有限公司 | Good alkyd paint of a kind of Gloss Retention and preparation method thereof |
| CN107964659A (en) * | 2017-11-22 | 2018-04-27 | 苏州兴禾源复合材料有限公司 | A kind of cleansing color coated steel sheet for purification and preparation method thereof |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103992734A (en) * | 2014-05-21 | 2014-08-20 | 珠海市威旗防腐科技有限公司 | Reflective water plane topcoat for ships and preparation method thereof |
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| CN104449273A (en) * | 2014-10-23 | 2015-03-25 | 安徽省实防新型玻璃科技有限公司 | Ultraviolet-resistant water-based paint capable of reducing brightness of coating and applied to glass door and preparation method of ultraviolet-resistant water-based paint |
| CN104371386A (en) * | 2014-11-13 | 2015-02-25 | 青岛厚科信息工程有限公司 | Quick-drying paint |
| CN104403530A (en) * | 2014-11-13 | 2015-03-11 | 青岛厚科信息工程有限公司 | Coating with acrylic modified alkyd resin |
| CN106752796A (en) * | 2017-01-04 | 2017-05-31 | 安徽凤凰涂料科技有限公司 | Good alkyd paint of a kind of Gloss Retention and preparation method thereof |
| CN107964659A (en) * | 2017-11-22 | 2018-04-27 | 苏州兴禾源复合材料有限公司 | A kind of cleansing color coated steel sheet for purification and preparation method thereof |
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| CN103387785B (en) | 2015-07-01 |
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