CN103267830B - Method for evaluating ablation characteristic of solid energetic material under plasma jet action - Google Patents
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Abstract
本发明提供一种评价固体含能材料在等离子体射流作用下烧蚀特性的方法:1)通过实验获得等离子体射流与含能材料的作用时间,等离子体射流的压强与温度,以及烧蚀质量;2)通过联立求解含能材料内部的热传导方程与等离子体射流对含能材料烧蚀模型获得该能量流条件下等离子体射流作用下含能材料的表面温度、表面侵入深度与作用过程总的烧蚀质量等信息;3)调整输入的等离子体射流能量流数据,直到计算得到的烧蚀质量与实验测得的烧蚀质量一致,由此确定出来自等离子体射流的实际能量流;4)采用计算获得的实际能量流作为输入条件,获得实际的含能材料表面温度、表面侵入深度等信息,实现对等离子体射流与含能材料作用特性的评估。
The invention provides a method for evaluating the ablation characteristics of a solid energetic material under the action of a plasma jet: 1) Obtain the interaction time between the plasma jet and the energetic material, the pressure and temperature of the plasma jet, and the ablation quality through experiments ; 2) By simultaneously solving the heat conduction equation inside the energetic material and the ablation model of the energetic material by the plasma jet, the surface temperature, surface penetration depth and the total action process of the energetic material under the action of the plasma jet under the energy flow condition are obtained. 3) Adjust the input plasma jet energy flow data until the calculated ablation quality is consistent with the experimentally measured ablation quality, thereby determining the actual energy flow from the plasma jet; 4 ) using the calculated actual energy flow as the input condition to obtain information such as the actual surface temperature of the energetic material, the surface penetration depth, etc., and realize the evaluation of the interaction characteristics between the plasma jet and the energetic material.
Description
技术领域technical field
本发明涉及评估等离子体射流与含能材料作用特性的方法,具体涉及一种评估电热化学炮中等离子体射流与含能材料作用特性的方法。The invention relates to a method for evaluating the interaction characteristics of plasma jets and energetic materials, in particular to a method for evaluating the interaction characteristics of plasma jets and energetic materials in an electrothermal chemical gun.
背景技术Background technique
等离子体射流作为常用的对固体含能材料进行点火与助燃的手段,具有十分广泛的应用。例如当含能材料为发射药时,等离子体射流可用于电热化学炮中的等离子体点火源,而当含能材料为推进剂时,等离子体射流可用于航天器推进装置的点火与辅助燃烧手段。Plasma jet, as a commonly used means to ignite and support solid energetic materials, has a very wide range of applications. For example, when the energetic material is a propellant, the plasma jet can be used as a plasma ignition source in an electrothermal chemical gun, and when the energetic material is a propellant, the plasma jet can be used as a means of ignition and auxiliary combustion of a spacecraft propulsion device .
等离子体射流与固体含能材料的作用过程通常可分为起燃前阶段、起燃阶段与稳定燃烧阶段。其中在起燃前阶段,固体含能材料主要受到等离子体射流的烧蚀作用的影响,这一过程决定了起燃阶段的初始条件,影响着含能材料点火的许多重要参数,包括固体含能材料表面温度以及周围环境中气相含能材料的含量,因此对等离子体射流与固体含能材料的综合作用效果具有十分重要的影响。然而目前还没有一种有效的评价固体含能材料在等离子体射流作用下烧蚀特性的方法。The interaction process between plasma jet and solid energetic material can usually be divided into pre-ignition stage, ignition stage and stable combustion stage. Among them, in the stage before ignition, the solid energetic material is mainly affected by the ablation effect of the plasma jet. This process determines the initial conditions of the ignition stage and affects many important parameters of the ignition of energetic materials, including solid energetic The surface temperature of the material and the content of the energetic material in the gas phase in the surrounding environment have a very important influence on the comprehensive effect of the plasma jet and the solid energetic material. However, there is no effective method to evaluate the ablation characteristics of solid energetic materials under the action of plasma jets.
发明内容Contents of the invention
本发明的目的在于提供一种评价固体含能材料在等离子体射流作用下烧蚀特性的方法。The purpose of the present invention is to provide a method for evaluating the ablation characteristics of solid energetic materials under the action of plasma jets.
为达到上述目的,本发明采用了以下技术方案:To achieve the above object, the present invention adopts the following technical solutions:
1)首先通过实验获得等离子体射流与含能材料的作用时间、含能材料表面处等离子体射流的压强与温度以及含能材料的烧蚀质量;1) First, the interaction time between the plasma jet and the energetic material, the pressure and temperature of the plasma jet at the surface of the energetic material, and the ablation quality of the energetic material are obtained through experiments;
2)经过步骤1)后,通过联立求解含能材料内部的热传导方程与等离子体射流对含能材料的烧蚀模型计算给定能量流条件下含能材料在等离子体射流作用下的表面温度、烧蚀率以及烧蚀质量;2) After step 1), the surface temperature of the energetic material under the action of the plasma jet is calculated by simultaneously solving the heat conduction equation inside the energetic material and the ablation model of the plasma jet on the energetic material , ablation rate and ablation quality;
3)调整给定的能量流条件,直到计算得到的烧蚀质量与实验获得的烧蚀质量一致,由此确定等离子体射流的实际能量流;3) Adjust the given energy flow conditions until the calculated ablation mass is consistent with the experimentally obtained ablation mass, thereby determining the actual energy flow of the plasma jet;
4)采用实际能量流作为输入条件,按照步骤2)所述的方法,计算给定能量流条件为实际能量流时,含能材料的表面温度以及烧蚀率,实现对等离子体射流与含能材料作用特性的评估。4) Using the actual energy flow as the input condition, according to the method described in step 2), calculate the surface temperature and ablation rate of the energetic material when the given energy flow condition is the actual energy flow, and realize the comparison between the plasma jet and the energetic Evaluation of material action properties.
所述步骤2)中,为了真实反映含能材料表面的温度,需要在计算中考虑含能材料表面在等离子体射流烧蚀作用下被不断侵入的过程,以表征侵入过程对表面温度与烧蚀率结果的影响。具体方法为:In the above step 2), in order to truly reflect the temperature of the surface of the energetic material, it is necessary to consider the process of the surface of the energetic material being continuously invaded under the action of plasma jet ablation in the calculation, so as to characterize the impact of the invasion process on the surface temperature and ablation impact on rate results. The specific method is:
为了对方程进行求解,将含能材料离散为N层,并用表示第j个时间步长内计算域中第i层含能材料所在位置的温度值,而代表着第j个时间步长的表面温度。在开始计算第j个时间步长时,需要利用公式(8),根据当前的烧蚀质量mj与此前已被烧蚀掉的含能材料层数,来估算出该时间步长中新被烧蚀掉的含能材料层数nj。由于前nj层的含能材料已被烧蚀,则上一时间步长中的第nj层含能材料便成为当前时间步长中含能材料的表面层(第0层),相应地上一时间步长中第nj层的温度值也就成为了第j个时间步长中新的表面温度在公式(8)中“integer()”表示对括号内的数值仅保留整数部分(因含能材料的层数只能取整数),公式(8)如下所示,其中ml为单层含能材料的质量:To solve the equation, the energetic material is discretized into N layers, and the Indicates the temperature value of the location of the i-th layer of energetic material in the computational domain within the j-th time step, and represents the surface temperature at the jth time step. When starting to calculate the jth time step, it is necessary to use formula (8) to estimate the newly ablated layer in this time step according to the current ablation mass m j and the number of energetic material layers that have been ablated before. The number n j of energetic material layers ablated. Since the energetic material of the previous n j layers has been ablated, the n jth layer of energetic material in the previous time step becomes the surface layer (layer 0) of the energetic material in the current time step, and accordingly the upper The temperature value of layer n j in a time step which becomes the new surface temperature at the jth time step In the formula (8), "integer()" means that only the integer part is reserved for the value in the brackets (because the number of layers of the energetic material can only be an integer), the formula (8) is as follows, where m l is the energy content of a single layer Quality of material:
所述含能材料表面在等离子体射流烧蚀作用下被不断侵入的过程采用表面侵入深度进行评价,每个时间步长内表面侵入深度的计算方法为:将该时间步长中被烧蚀的层数nj乘以每层含能材料的厚度。The process of the continuous intrusion of the surface of the energetic material under the action of plasma jet ablation is evaluated by the surface intrusion depth, and the calculation method of the inner surface intrusion depth in each time step is: The number of layers n j is multiplied by the thickness of each layer of energetic material.
本发明的有益效果体现在:The beneficial effects of the present invention are reflected in:
本发明利用等离子体射流与固体含能材料相互作用过程中可利用通常实验手段获取的外部参数(放电电压、含能材料表面压强,以及含能材料烧蚀质量等),依据等离子体与固体含能材料作用理论来获得等离子体射流与含能材料作用过程中更为直接的、难以通过实验直接测量的参数,包括含能材料的表面温度、烧蚀率以及来自等离子体的平均能量流等,由此实现了对等离子体射流作用下固体含能材料烧蚀特性的更为全面的评价。The present invention utilizes external parameters (discharge voltage, surface pressure of energetic material, and ablation quality of energetic material, etc.) The interaction theory of energetic materials is used to obtain more direct parameters that are difficult to measure directly through experiments during the interaction between plasma jets and energetic materials, including the surface temperature of energetic materials, ablation rate, and the average energy flow from the plasma, etc. In this way, a more comprehensive evaluation of the ablation characteristics of solid energetic materials under the action of plasma jets is realized.
本发明提出了考虑含能材料表面在等离子体射流烧蚀作用下被不断侵入过程的方法,可以考虑到等离子体射流作用下固体含能材料表面的实际侵入过程,从而更符合作用理论,也使得计算结果更符合客观实际。The present invention proposes a method for considering the continuous intrusion process of the surface of the energetic material under the ablation action of the plasma jet, which can consider the actual intrusion process of the surface of the solid energetic material under the action of the plasma jet, so that it is more in line with the action theory and also makes The calculation results are more in line with the objective reality.
附图说明Description of drawings
图1为实验中获得的不同电压下等离子体放电电压;Fig. 1 is the plasma discharge voltage under different voltages obtained in the experiment;
图2为实验中获得的不同电压下含能材料表面等离子体射流压强及由其推算得到的数密度;Figure 2 shows the plasma jet pressure on the surface of the energetic material under different voltages obtained in the experiment and the number density calculated from it;
图3为处理含能材料表面侵入方法的示意图;Fig. 3 is a schematic diagram of a method for dealing with surface intrusion of energetic materials;
图4为考虑与不考虑含能材料表面侵入对等离子射流与SF3发射药作用计算结果的差异;Figure 4 shows the difference in the calculation results of the plasma jet and SF3 propellant with and without considering the surface intrusion of energetic materials;
图5为获得作用过程中来自等离子体射流平均能量流的流程图;Fig. 5 is the flowchart of obtaining the average energy flow from the plasma jet during the action;
图6为利用不同含能材料计算得到的等离子体射流平均能量流;Figure 6 shows the average energy flow of the plasma jet calculated using different energetic materials;
图7为不同含能材料在等离子体射流作用下的表面侵入深度。Figure 7 shows the surface penetration depths of different energetic materials under the action of plasma jets.
具体实施方式Detailed ways
下面结合附图和实施例对本发明作进一步说明。The present invention will be further described below in conjunction with drawings and embodiments.
本发明包括以下步骤:The present invention comprises the following steps:
(1)首先通过实验获得等离子体射流与含能材料的作用时间,含能材料表面处等离子体射流的压强与温度,以及含能材料的烧蚀质量;(1) First, the interaction time between the plasma jet and the energetic material, the pressure and temperature of the plasma jet on the surface of the energetic material, and the ablation quality of the energetic material are obtained through experiments;
(2)基于上述实验数据,并输入预测的来自等离子射流的能量流,通过联立求解含能材料内部的热传导方程与等离子体射流对含能材料烧蚀模型获得该能量流条件下等离子体射流作用下含能材料的表面温度、烧蚀率、表面侵入深度与作用过程总的烧蚀质量等信息;(2) Based on the above experimental data and inputting the predicted energy flow from the plasma jet, the plasma jet under this energy flow condition is obtained by simultaneously solving the heat conduction equation inside the energetic material and the ablation model of the energetic material by the plasma jet Information such as surface temperature, ablation rate, surface penetration depth and total ablation quality of energetic materials under action;
(3)调整输入的预测能量流数据,直到计算得到的总烧蚀质量与实验测得的烧蚀质量一致,由此确定出来自等离子体射流的实际能量流;(3) Adjust the input predicted energy flow data until the calculated total ablation mass is consistent with the experimentally measured ablation mass, thereby determining the actual energy flow from the plasma jet;
(4)采用计算获得的实际能量流作为输入条件,利用步骤2中所述的方法对作用过程进行重新计算,获得实际的含能材料表面温度、烧蚀率与表面侵入深度等信息,实现对等离子体射流与含能材料作用特性的评估。(4) Using the calculated actual energy flow as the input condition, use the method described in step 2 to recalculate the action process to obtain information such as the actual surface temperature, ablation rate, and surface penetration depth of the energetic material, so as to realize the Evaluation of the interaction properties of plasma jets with energetic materials.
为了真实反映含能材料表面的温度,需要在计算中考虑进含能材料表面在等离子体射流烧蚀作用下的不断侵入过程。In order to truly reflect the temperature of the surface of the energetic material, the continuous intrusion process of the surface of the energetic material under the action of plasma jet ablation needs to be taken into account in the calculation.
本发明对固体含能材料在等离子体射流作用下烧蚀特性的评价具体步骤如下:In the present invention, the specific steps for evaluating the ablation characteristics of solid energetic materials under the action of plasma jets are as follows:
(1)首先通过实验获得等离子体射流与固体含能材料的作用时间,固体含能材料表面附近等离子体射流的压强与温度,以及固体含能材料的烧蚀质量。参见图1中5kV与7kV充电电压下获得的典型等离子体放电电压,放电电压用于确定等离子体射流与固体含能材料的作用时间,通常通过电压曲线的终止时刻来获取。对应图1中的数据,5kV与7kV下等离子体射流与固体含能材料的作用时间分别为4.4ms与5.5ms。图2中给出了与图1相同实验条件下获得的典型等离子体射流压强数据,以及利用状态方程(式(1))获得的等离子体射流数密度。(1) First, the interaction time between the plasma jet and the solid energetic material, the pressure and temperature of the plasma jet near the surface of the solid energetic material, and the ablation quality of the solid energetic material are obtained through experiments. Refer to the typical plasma discharge voltages obtained at 5kV and 7kV charging voltages in Figure 1. The discharge voltage is used to determine the interaction time between the plasma jet and the solid energetic material, and is usually obtained through the termination time of the voltage curve. Corresponding to the data in Figure 1, the interaction time between the plasma jet and the solid energetic material at 5kV and 7kV is 4.4ms and 5.5ms, respectively. Figure 2 shows the typical plasma jet pressure data obtained under the same experimental conditions as in Figure 1, and the plasma jet number density obtained using the equation of state (Equation (1)).
P2=n2kT2 (1)P 2 =n 2 kT 2 (1)
其中P2、n2与T2分别为等离子体的压强、数密度与温度,而k是玻尔兹曼常数,取值为1.38×10-23J·K-1。由于空气电弧等离子体的温度基本上都在104K数量级且变化不大,因此为了简化起见,可将等离子体的温度假设为常数,由此便可以根据实验测得的等离子体射流压强获得等离子体射流的数密度。Among them, P 2 , n 2 and T 2 are the pressure, number density and temperature of the plasma respectively, and k is Boltzmann's constant, which is 1.38×10 -23 J·K -1 . Since the temperature of the air arc plasma is basically on the order of 10 4 K and does not change much, for the sake of simplicity, the temperature of the plasma can be assumed to be constant, so that the plasma jet pressure can be obtained according to the experimentally measured The number density of the body jet.
(2)基于前一步骤获得的实验数据,输入预测的来自等离子射流的能量流,通过联立求解固体含能材料内部的热传导方程与等离子体射流对固体含能材料烧蚀模型获得该能量流条件下等离子体射流作用下含能材料的表面温度、烧蚀率、表面侵入深度与作用过程总的烧蚀质量等信息;(2) Based on the experimental data obtained in the previous step, input the predicted energy flow from the plasma jet, and obtain the energy flow by simultaneously solving the heat conduction equation inside the solid energetic material and the ablation model of the solid energetic material by the plasma jet Information such as the surface temperature, ablation rate, surface penetration depth and total ablation quality of the energetic material under the action of the plasma jet under certain conditions;
含能材料内部的热传导模型如式(2)所示,而其边界条件如式(3)所示。其中T(x,t)为t时刻含能材料内部x位置处的温度,而q为来自等离子体射流的能量流,Tr为环境温度,L为计算区域内含能材料的厚度,λ、Cp、ρ与ΔH分别含能材料的热导率、比热、密度与烧蚀焓。The heat conduction model inside the energetic material is shown in formula (2), and its boundary conditions are shown in formula (3). where T(x,t) is the temperature at position x inside the energetic material at time t, and q is the energy flow from the plasma jet, Tr is the ambient temperature, L is the thickness of the energetic material in the calculation area, λ, C p , ρ and ΔH are the thermal conductivity, specific heat, density and ablation enthalpy of energetic materials, respectively.
T(L,t)=Tr T(L,t)=T r
在给定含能材料烧蚀率Γ与等离子体射流能流q的情况下就可以通过求解式(2)来获得含能材料表面的温度T(0,t),以下记为T0。而含能材料烧蚀率可通过动力学烧蚀模型,式(4)—(7)来进行求解。其中(4)—(6)组成了以Y1、Y2、α为待求变量的封闭方程组。对其进行求解便可以进一步通过式(7)获得含能材料烧蚀率Γ。Given the ablation rate Γ of the energetic material and the energy flow q of the plasma jet, the surface temperature T(0,t) of the energetic material can be obtained by solving equation (2), which is denoted as T 0 below. The ablation rate of energetic materials can be solved through the dynamic ablation model, equations (4)-(7). Among them, (4)-(6) form a closed equation system with Y 1 , Y 2 , and α as the variables to be obtained. By solving it, the energetic material ablation rate Γ can be further obtained through formula (7).
其中T2、n2与m2分别为等离子体射流的温度、数密度与平均粒子质量。其中n2与m2可通过T2与P2计算得到。n0与m0分别为含能材料表面的数密度与平均粒子质量,利用含能材料表面温度T0,结合含能材料的饱和蒸汽压P0计算得到。若含能材料的成分一定,则饱和蒸汽压P0通常是T0的单值函数,可通过对含能材料各组分的饱和蒸汽压做质量平均来获得。erfc(α)为关于α的误差函数,γ表示等离子体的比热比。求解烧蚀模型可以获得等离子体射流对含能材料的烧蚀率,以确定式(3)中的边界条件,由此实现与热传导模型的耦合。Where T 2 , n 2 and m 2 are the temperature, number density and average particle mass of the plasma jet, respectively. Among them, n 2 and m 2 can be calculated by T 2 and P 2 . n 0 and m 0 are the number density and average particle mass on the surface of the energetic material, respectively, which are calculated by using the surface temperature T 0 of the energetic material and the saturated vapor pressure P 0 of the energetic material. If the composition of the energetic material is constant, the saturated vapor pressure P 0 is usually a single-valued function of T 0 , which can be obtained by taking the mass average of the saturated vapor pressure of each component of the energetic material. erfc(α) is an error function about α, and γ represents the specific heat ratio of the plasma. Solving the ablation model can obtain the ablation rate of the plasma jet on the energetic material to determine the boundary conditions in formula (3), thereby realizing the coupling with the heat conduction model.
在等离子体射流与含能材料的作用过程中,由于等离子体射流对含能材料持续的烧蚀作用,含能材料的表面会逐步侵入,使得原来位于内部的含能材料被暴露出来而成为含能材料的新表面,其温度也成为新的表面温度。对含能材料表面的侵入过程可利用图3中所示的方法进行处理。假设含能材料被离散为N层,则表示第j个时间步长内计算域中第i层含能材料所在位置的温度值,0号下标对应着含能材料表面处的温度值。在开始计算第j个时间步长时,需要利用式(8),根据当前的烧蚀质量mj与此前已被烧蚀掉的含能材料层数,来估算出当前时间步长中新被烧蚀掉的含能材料层数nj。然后将这nj(从0层至nj-1层)层含能材料自计算区域中移除,使得第nj层含能材料成为含能材料的表面。而为了避免因为考虑含能材料表面不断侵入造成含能材料消耗尽的问题,需要在计算区域的另一端(含能材料的背面)补足相应的层数,并将新补进的含能材料温度设为室温Tr。During the interaction between the plasma jet and the energetic material, due to the continuous ablation effect of the plasma jet on the energetic material, the surface of the energetic material will gradually invade, so that the original internal energetic material is exposed and becomes an energetic material. The new surface of the energy material, its temperature also becomes the new surface temperature. The process of intrusion into the surface of energetic materials can be processed using the method shown in Figure 3. Assuming that the energetic material is discretized into N layers, then Indicates the temperature value at the location of the i-th layer of energetic material in the calculation domain within the jth time step, and the subscript 0 corresponds to the temperature value at the surface of the energetic material. When starting to calculate the jth time step, it is necessary to use formula (8), according to the current ablation mass m j and the number of energetic material layers that have been ablated before, to estimate the newly ablated layer in the current time step The number n j of energetic material layers ablated. Then the n j (from layer 0 to layer n j −1) layers of energetic material are removed from the calculation area, so that the n jth layer of energetic material becomes the surface of the energetic material. In order to avoid the problem of exhaustion of energetic materials due to the continuous intrusion into the surface of energetic materials, it is necessary to make up the corresponding number of layers at the other end of the calculation area (the back of the energetic materials), and set the temperature of the newly added energetic materials to Let it be room temperature T r .
其中ml为单层含能材料的质量。where ml is the mass of a single layer of energetic material.
每个时间步长内表面侵入深度的计算方法为:将该时间步长中被烧蚀的层数nj乘以每层含能材料的厚度。The calculation method of the penetration depth of the inner surface at each time step is: multiply the number n j of layers ablated in the time step by the thickness of each layer of energetic material.
图4给出了考虑与不考虑含能材料表面侵入效应对SF3含能材料与等离子体射流作用特性的影响,从中可以看出忽略含能材料表面侵入会严重高估含能材料的表面温度与烧蚀率。Figure 4 shows the influence of considering and not considering the surface intrusion effect of energetic materials on the interaction characteristics of SF3 energetic materials and plasma jets, from which it can be seen that ignoring the surface intrusion of energetic materials will seriously overestimate the surface temperature and Ablation rate.
(3)上一步计算中采用的预测能量流应选取得足够小,使得计算获得的含能材料累积烧蚀质量小于实验值。此后则逐步提高预测能量流的数值,以使得计算获得的累积烧蚀质量逐步提升,直到获得的烧蚀质量超过实验值,如图5给出的流程图所示。此时便可以通过此前获得的预测能量流与累积烧蚀质量的关系,通过插值确定出实际来自等离子体射流的能量流。而图6给出了利用典型的实验结果获得的等离子体射流能量流信息。(3) The predicted energy flow used in the calculation in the previous step should be selected to be small enough so that the cumulative ablation mass of the energetic material obtained by calculation is smaller than the experimental value. Afterwards, the value of the predicted energy flow is gradually increased, so that the calculated cumulative ablation quality is gradually increased until the obtained ablation quality exceeds the experimental value, as shown in the flow chart in Figure 5. The actual energy flow from the plasma jet can now be determined by interpolation from the previously obtained relationship between the predicted energy flow and the cumulative ablated mass. Figure 6 shows the plasma jet energy flow information obtained using typical experimental results.
(4)采用计算获得的实际能量流对等离子体射流与含能材料的作用过程进行重新计算,联立求解含能材料中的热传导模型与含能材料的烧蚀模型,获得实际的含能材料表面温度、烧蚀率与表面侵入深度等信息,实现对等离子体射流与含能材料作用特性的评估。图7给出了计算获得的典型含能材料(SF3发射药与GR5发射药)在等离子体射流作用下的表面侵入深度。采用这一方法还可以对不同的等离子体放电条件与不同含能材料配方对作用过程的影响作出评估。(4) Using the calculated actual energy flow to recalculate the interaction process between the plasma jet and the energetic material, simultaneously solve the heat conduction model in the energetic material and the ablation model of the energetic material to obtain the actual energetic material Information such as surface temperature, ablation rate, and surface penetration depth can be used to evaluate the interaction characteristics of plasma jets and energetic materials. Figure 7 shows the calculated surface penetration depths of typical energetic materials (SF3 propellants and GR5 propellants) under the action of plasma jets. This method can also be used to evaluate the influence of different plasma discharge conditions and different energetic material formulations on the action process.
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