CN1031516C - Cleaning agent for flush toilet - Google Patents
Cleaning agent for flush toilet Download PDFInfo
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- CN1031516C CN1031516C CN 89104849 CN89104849A CN1031516C CN 1031516 C CN1031516 C CN 1031516C CN 89104849 CN89104849 CN 89104849 CN 89104849 A CN89104849 A CN 89104849A CN 1031516 C CN1031516 C CN 1031516C
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- 239000012459 cleaning agent Substances 0.000 title abstract description 4
- 229920001807 Urea-formaldehyde Polymers 0.000 claims abstract description 16
- GZCGUPFRVQAUEE-SLPGGIOYSA-N aldehydo-D-glucose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O GZCGUPFRVQAUEE-SLPGGIOYSA-N 0.000 claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000011230 binding agent Substances 0.000 claims abstract description 7
- 239000003599 detergent Substances 0.000 claims abstract description 6
- 239000003960 organic solvent Substances 0.000 claims abstract description 5
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 28
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 26
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 19
- -1 alkylbenzene sulfonate Chemical class 0.000 claims description 15
- 239000004202 carbamide Substances 0.000 claims description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 9
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 9
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 9
- 239000002253 acid Substances 0.000 claims description 7
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 6
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 claims description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 5
- 229910000365 copper sulfate Inorganic materials 0.000 claims description 5
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 5
- MEIRRNXMZYDVDW-MQQKCMAXSA-N (2E,4E)-2,4-hexadien-1-ol Chemical compound C\C=C\C=C\CO MEIRRNXMZYDVDW-MQQKCMAXSA-N 0.000 claims description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 4
- FPIPGXGPPPQFEQ-OVSJKPMPSA-N all-trans-retinol Chemical compound OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-OVSJKPMPSA-N 0.000 claims description 4
- 239000003945 anionic surfactant Substances 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 239000004094 surface-active agent Substances 0.000 claims description 4
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims description 4
- SVPKNMBRVBMTLB-UHFFFAOYSA-N 2,3-dichloronaphthalene-1,4-dione Chemical group C1=CC=C2C(=O)C(Cl)=C(Cl)C(=O)C2=C1 SVPKNMBRVBMTLB-UHFFFAOYSA-N 0.000 claims description 3
- 229920001353 Dextrin Polymers 0.000 claims description 3
- 239000004375 Dextrin Substances 0.000 claims description 3
- 241000233855 Orchidaceae Species 0.000 claims description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 3
- 229920013701 VORANOL™ Polymers 0.000 claims description 3
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims description 3
- BEHLMOQXOSLGHN-UHFFFAOYSA-N benzenamine sulfate Chemical compound OS(=O)(=O)NC1=CC=CC=C1 BEHLMOQXOSLGHN-UHFFFAOYSA-N 0.000 claims description 3
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 3
- 235000019425 dextrin Nutrition 0.000 claims description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 3
- 229940059574 pentaerithrityl Drugs 0.000 claims description 3
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 3
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims description 3
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 claims description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 2
- 235000000177 Indigofera tinctoria Nutrition 0.000 claims description 2
- 239000011717 all-trans-retinol Substances 0.000 claims description 2
- 235000019169 all-trans-retinol Nutrition 0.000 claims description 2
- CUBCNYWQJHBXIY-UHFFFAOYSA-N benzoic acid;2-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=CC=C1.OC(=O)C1=CC=CC=C1O CUBCNYWQJHBXIY-UHFFFAOYSA-N 0.000 claims description 2
- UIVLIZYJHYWOBB-UHFFFAOYSA-N ethane-1,2-diol;hex-1-ene Chemical compound OCCO.CCCCC=C UIVLIZYJHYWOBB-UHFFFAOYSA-N 0.000 claims description 2
- 235000019253 formic acid Nutrition 0.000 claims description 2
- 235000011187 glycerol Nutrition 0.000 claims description 2
- 230000002209 hydrophobic effect Effects 0.000 claims description 2
- 229940097275 indigo Drugs 0.000 claims description 2
- COHYTHOBJLSHDF-UHFFFAOYSA-N indigo powder Natural products N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 claims description 2
- 235000006408 oxalic acid Nutrition 0.000 claims description 2
- 229920000191 poly(N-vinyl pyrrolidone) Polymers 0.000 claims description 2
- 235000019353 potassium silicate Nutrition 0.000 claims description 2
- 235000013772 propylene glycol Nutrition 0.000 claims description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 2
- 239000011592 zinc chloride Substances 0.000 claims description 2
- 235000005074 zinc chloride Nutrition 0.000 claims description 2
- 239000004480 active ingredient Substances 0.000 claims 3
- UXNRLSAOXOLGPD-UHFFFAOYSA-N 2-chlorophenol copper Chemical compound ClC1=C(C=CC=C1)O.[Cu] UXNRLSAOXOLGPD-UHFFFAOYSA-N 0.000 claims 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 1
- 125000001931 aliphatic group Chemical group 0.000 claims 1
- 230000001954 sterilising effect Effects 0.000 abstract description 7
- 230000001877 deodorizing effect Effects 0.000 abstract description 3
- 239000002781 deodorant agent Substances 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 239000002304 perfume Substances 0.000 abstract description 2
- 230000000844 anti-bacterial effect Effects 0.000 abstract 1
- 239000003899 bactericide agent Substances 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000003086 colorant Substances 0.000 abstract 1
- 230000000249 desinfective effect Effects 0.000 abstract 1
- 239000003085 diluting agent Substances 0.000 abstract 1
- 239000002736 nonionic surfactant Substances 0.000 abstract 1
- 238000003825 pressing Methods 0.000 abstract 1
- 239000000470 constituent Substances 0.000 description 14
- 230000000694 effects Effects 0.000 description 11
- 239000011149 active material Substances 0.000 description 8
- 238000004659 sterilization and disinfection Methods 0.000 description 7
- 235000013599 spices Nutrition 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 5
- 238000004332 deodorization Methods 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 235000019198 oils Nutrition 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 241000220317 Rosa Species 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000013270 controlled release Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 2
- 241000723346 Cinnamomum camphora Species 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000001045 blue dye Substances 0.000 description 2
- 229960000846 camphor Drugs 0.000 description 2
- 229930008380 camphor Natural products 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000013268 sustained release Methods 0.000 description 2
- 239000012730 sustained-release form Substances 0.000 description 2
- 229960004418 trolamine Drugs 0.000 description 2
- 241000218645 Cedrus Species 0.000 description 1
- 235000019501 Lemon oil Nutrition 0.000 description 1
- 235000019082 Osmanthus Nutrition 0.000 description 1
- 241000333181 Osmanthus Species 0.000 description 1
- 229930040373 Paraformaldehyde Natural products 0.000 description 1
- 244000270673 Pelargonium graveolens Species 0.000 description 1
- 235000017927 Pelargonium graveolens Nutrition 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 235000016639 Syzygium aromaticum Nutrition 0.000 description 1
- 244000223014 Syzygium aromaticum Species 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- QZZKKJZOZWWTEX-UHFFFAOYSA-N copper;2,3,4-trichlorophenol Chemical compound [Cu].OC1=CC=C(Cl)C(Cl)=C1Cl QZZKKJZOZWWTEX-UHFFFAOYSA-N 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 230000008034 disappearance Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000010648 geranium oil Substances 0.000 description 1
- 235000011167 hydrochloric acid Nutrition 0.000 description 1
- 239000003317 industrial substance Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000010501 lemon oil Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229960003511 macrogol Drugs 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 229920002866 paraformaldehyde Polymers 0.000 description 1
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 230000003578 releasing effect Effects 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000008371 vanilla flavor Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a cleaning agent for a flush toilet, which adopts urea-formaldehyde resin as a carrier and is added with the following active components: deodorant, detergent, bactericide, binder, catalyst, colorant, diluent or organic solvent, nonionic surfactant, and perfume. Pressing into block by hydraulic press, directly putting into water tank of toilet, automatically deodorizing, descaling, sterilizing, and disinfecting, and has long service life, and the block weight of 40-45 g can be used for more than one month. The production process is simple and the cost is low. The product is suitable for hotels, restaurants, hospitals and partial families to improve the living and working environment.
Description
The present invention relates to a kind of detergent for water closet, it is a kind of solid chemicals with deodorizing, scale removal, sterilization, disinfection.
U.S. Pat 4252785 provides a kind of " sustained release compound " (Controlled Release Composition), it is to be substrate material with the urea formaldehyde, be used for Controlled Release System, it contains the Precondensed UreaFormaldehyde Resin of 20-90% (weight ratio), and the mole ratio of its urea PARA FORMALDEHYDE PRILLS(91,95) is 2: 1-3.5: 1.And comprise a kind of active material at least.When described resin was in aqueous medium, active material can discharge from resin, and release continued to carry out in for some time.This patent has mainly proposed with Precondensed UreaFormaldehyde Resin to be used for Controlled Release System as matrix, has also proposed the usage ratio of Precondensed UreaFormaldehyde Resin and active material, but to the content of active material mention seldom, the usage ratio of each active material is not proposed yet.And the domestic product-free of the active agents that it exemplified.
In addition, what sell on the domestic market at present mainly is liquid deodorant, for water closet, uses very inconveniently, and consumption is big.At present on the world market though solid cleaning agent is arranged, the complex structure that has, the cost height, have because domestic industrial chemicals is incomplete, supply out of stock, the material expensive that has, inapplicable China's national situation.
The purpose of this invention is to provide a kind of non-corrosiveness, good deodorization effect has scale removal, effects such as sterilization, sterilization, and cost is low, the water closet solid cleaning agent of long service life.
The present invention is achieved in that
At first selected for use Precondensed UreaFormaldehyde Resin as carrier, used urea is the industrial utmost point, and formaldehyde is the technical grade solution of concentration 36-37%, and the mol ratio of urea and formaldehyde is 2: 1-2.5: 1.The ratio control of Precondensed UreaFormaldehyde Resin and active constituent is as follows: Precondensed UreaFormaldehyde Resin content is 30-70% (weight ratio), and the content of active constituent is 70-30%.Main points of the present invention are that the composition of active constituent and content are as follows:
Nonionic surface active agent: 3-10%
(weight ratio is based on the gross weight of sanitising agent each component, down
With)
Anion surfactant (scale remover): 5-20%
Reodorant: 5-15%
Sterilant: 2-10%
Binding agent: 1-10%
Thinner (or organic solvent): 1-10%
Catalyzer: 1-10%
Tinting material: 2-10%
In above-mentioned active constituent, can add spices, its consumption is controlled at 2-10%.
Preparation method of the present invention is as follows:
The first step: be 8-9 with the trolamine pH that neutralizes earlier with formaldehyde, add urea afterwards, it is molten entirely to be heated to urea, general controlled temperature is 40-80 ℃, and the time is 10-50 minute, and the ratio control of urea and formaldehyde is 2: 1-2.5: 1, in this proportional range, curing speed is fast, and stable performance is easy to discharge active constituent.
Second step: measure ready active constituent and urea soln as requested and mix, and add selected catalyzer, under constantly stirring, just its rapid polymerizing curable, when temperature is reduced to below 50 ℃, add selected spices, stir, can obtain fragrant detergent for water closet.
Control the ratio of Precondensed UreaFormaldehyde Resin and active constituent effectively, the effect after sustained release speed, and the component of remaining valid preferably discharges.The ratio that the present invention controls Precondensed UreaFormaldehyde Resin is 30-70%, and the amount of active constituent is 70-30%.Experiment shows that active material is too much, discharges too fast; Active material then not only discharges slow but also weak effect very little.
The 3rd step:, become piece with the hydropress die mould with the completely crued material mould of packing into.Pressure to the medicine piece is 6-20kgf/cm
2The diameter of mould can change with the size of solid piece, and once available a plurality of moulds are die mould simultaneously, to boost productivity, packs at last.
Effect to each active constituent reaches selected being described as follows below:
1. the effect of nonionic surface active agent is to make hydrophobic material enter solution, to keep its even release, also has cleaning, deodorization simultaneously.The nonionogenic tenside that the present invention selects for use is glycerine, tetramethylolmethane, sorbyl alcohol, peregal etc.
2. anion surfactant (scale remover) has the effect of removing and prevention dirt, can select alkylaryl sulphonate, fatty alcohol sulfonate, alkene sulfuric acid ester salt, higher alcohols sulfuric acid ester salt etc. for use.
3. reodorant can play deodorization effectively, also must be mixed and fed into carrier equably with carrier, also must slowly dissolve simultaneously simultaneously with carrier, to keep slowly releasing effect uniformly, can select the hydrochloride of Voranol EP 2001, para-dichlorobenzene, Acetylacetone, zinc oxide, copper sulfate, low-grade aliphatic amine etc. for use.
4. sterilant plays sterilization, can select copper sulfate, zineb, trichlorophenol copper, dichloro naphthoquinone, aniline sulfonic acid, phenylformic acid, Salicylanlide etc. for use.
5. binding agent can make carrier and each component be tightly linked mutually, and binding agent must be water-soluble, and can keep lasting dissolution rate slowly.The binding agent that the present invention selects has dextrin, polyoxyethylene glycol, water glass etc.
6. thinner or organic solvent can be controlled the release rate of active constituent, and experiment shows that the amount of thinner the more discharges sooner, and add-on is fewer, discharges more slowly.Thinner or organic solvent can be selected ethanol, propyleneglycoles, hexene ethylene glycol and ethylene glycol etc. for use.
7. when the preparation Precondensed UreaFormaldehyde Resin, must add catalyzer when its polymerizing curable, catalyzer can be selected mineral acid, organic acid and acid-salt etc. for use, all example hydrochloric acids, sulfuric acid, formic acid, acetate, oxalic acid, citric acid, Whitfield's ointment, tosic acid, Tai-Ace S 150 etc.
8. for going out detergent for water closet, side timely whether uses up, must select for use the appropriate colouring agent as indicator, tinting material must can be water-soluble and do not add any auxiliary agent, and it does not allow carrier yet, react withs such as active material, or only dye things such as carrier and do not discharge color simultaneously.According to above-mentioned requirements, can select acid blue dye for use, as active orchid, acid pyridine orchid etc.When the control component discharged, it discharged pale blue simultaneously, when control component end of life, and pale blue that is disappearance.
9. select suitable spices can increase its fragrance, generally can select cloves rose, osmanthus flower fragrance, rose compound, Cedrus deoclar (Roxb.) G. Don oil, white oil of camphor, Oleum Cinnamomi, sandal oil, lemon oil, Rose geranium oil Algerian, vanilla flavor etc. for use.These spices can singly be used, and also can two kinds use with.
Advantage of the present invention is a non-corrosiveness, good deodorization effect, and the effect that has scale removal, sterilization, sterilizes, puts perfume.It is low also to have cost simultaneously, long service life, manufacturing process characteristic of simple.The present invention is used for the toilet water closet, and block medicament is directly dropped in the water tank, can automatically play deodorizing, scale removal, sterilization, put fragrant effect.A sanitising agent of heavy 40-45 gram can use more than one month, applicable to hotel, boarding house, restaurant, hospital, office and urban family, can play the effect of improvement work and living environment.
Be embodiments of the invention below:
Embodiment 1:
Get urea 26 gram and join in the formaldehyde solutions of 14 grams (being 8-9 with formaldehyde with the trolamine pH that neutralizes earlier), on electric furnace, be heated to 40-80 ℃, about 10-50 of period minute, urea is dissolved fully till.Active constituent is as follows: 1, nonionogenic tenside: 6 grams 2, fatty alcohol sulfonate: 10 grams 3, copper sulfate: 5 grams 4, sterilant: 10 grams 5, thinner: 10 grams 6, dextrin: 5 grams 7, acid blue dye: 6 grams 8, catalyzer: 5 grams 9, spices: 3 grams
Embodiment 2:
Press the method for embodiment 1, with urea 20 grams, formaldehyde 11 grams, preparation Precondensed UreaFormaldehyde Resin.Active constituent is as follows: 1, sorbyl alcohol: 10 grams 2, alkylsulfonate: 20 grams 3, ethylene glycol: 3 grams
4, polyoxyethylene glycol: 6 grams
5, dichloro naphthoquinone: 8 grams
6, Acetylacetone: 8 grams
7, tosic acid: 5 grams
8, acid blue look stain: 5 grams
9, spices: 4 grams
Embodiment 3:
Press the method for embodiment 1, with urea 38 grams, formaldehyde 22 grams, preparation Precondensed UreaFormaldehyde Resin.Active constituent is as follows: 1, sorbyl alcohol: 5 grams 2, fatty alcohol sulfonate: 10 grams 3, ethanol: 5 grams 4, phenylformic acid: 4 grams 5, Voranol EP 2001: 6 grams 6, active blue: 3 grams 7, macrogol: 2 grams 8, white oil of camphor: 2 grams 9, citric acid: 3 grams
Embodiment 4:
Press the method for embodiment 1, with urea 42 grams, formaldehyde 28 grams, preparation Precondensed UreaFormaldehyde Resin.Active constituent is as follows: 1, higher alcohols sulfuric acid ester: 5 grams 2, tetramethylolmethane: 3 grams 3, ethylene glycol: 2 grams 4, aniline sulfonic acid: 2 grams 5, zinc chloride: 5 grams 6, acid indigo: 2 grams 7, sodium sulfate: 3 grams 8, rose compound: 2 grams 9, Tai-Ace S 150: 6 grams
Claims (1)
1. detergent for water closet, it is that mole ratio by urea and formaldehyde is 2: 1-2.5: 1 Precondensed UreaFormaldehyde Resin, the block that releasable active ingredient is formed, the content that it is characterized in that releasable active ingredient is 30-70% (weight ratio), the content of Precondensed UreaFormaldehyde Resin is 70-30%, the composition and the content of active ingredient are as follows: (weight ratio is based on the gross weight of sanitising agent each component, down for nonionic surface active agent: 3-10%
With)
Anion surfactant (scale remover): 5-20%
Reodorant: 5-15%
Sterilant: 2-10%
Binding agent: 1-10%
Thinner: 1-10%
Catalyzer: 1-10%
Tinting material: 2-10%
Wherein can make hydrophobic material all enter solution and keep its nonionic surface active agent that evenly discharges is tetramethylolmethane, sorbyl alcohol, peregal or glycerine,
Wherein anion surfactant (scale remover) is alkylbenzene sulfonate, fatty alcohol sulfonate, alkene sulfuric acid ester salt or higher alcohols sulfuric acid ester salt,
Wherein reodorant is the hydrochloride of Voranol EP 2001, para-dichlorobenzene, Acetylacetone, zinc chloride, copper sulfate or lower aliphatic ammonium,
Wherein sterilant is dichloro naphthoquinone, two chlorophenol copper, aniline sulfonic acid, phenylformic acid, Salicylanlide, copper sulfate or zineb,
Wherein binding agent is dextrin, polyoxyethylene glycol or water glass,
Wherein thinner or organic solvent are ethanol, ethylene glycol, propyleneglycoles or hexene ethylene glycol,
Wherein catalyzer is hydrochloric acid, sulfuric acid, formic acid, acetate, oxalic acid, citric acid, Whitfield's ointment, tosic acid or Tai-Ace S 150,
Wherein tinting material is active orchid or acid indigo.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 89104849 CN1031516C (en) | 1989-07-14 | 1989-07-14 | Cleaning agent for flush toilet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 89104849 CN1031516C (en) | 1989-07-14 | 1989-07-14 | Cleaning agent for flush toilet |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1048726A CN1048726A (en) | 1991-01-23 |
| CN1031516C true CN1031516C (en) | 1996-04-10 |
Family
ID=4855721
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 89104849 Expired - Fee Related CN1031516C (en) | 1989-07-14 | 1989-07-14 | Cleaning agent for flush toilet |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1031516C (en) |
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| CN1077596C (en) * | 1995-07-18 | 2002-01-09 | 上海合成洗涤剂厂 | Lumpy cleaning agent for automatic toilet flushing and its producing process |
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| CN1071376C (en) * | 1998-02-13 | 2001-09-19 | 吕秀娟 | High-molecular active solid detergent composition and making method thereof |
| CN1077595C (en) * | 1998-05-11 | 2002-01-09 | 吕秀娟 | Activating solid polymer composition as detergent and production thereof |
| CN1113091C (en) * | 1998-06-09 | 2003-07-02 | 邱宁波 | Deodouring detergent for lavatory |
| CN100381549C (en) * | 2004-04-27 | 2008-04-16 | 天津科技大学 | Cleaning agent for flush toilet |
| US11466235B2 (en) * | 2007-04-16 | 2022-10-11 | Fresenius Medical Care Deutschland Gmbh | Method for a simulation and evaluation system for medical treatment facilities |
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| CN102260598B (en) * | 2011-06-24 | 2013-04-24 | 东莞爱屋氏日用品有限公司 | Sterilizing toilet cleaning block |
| CN102441558B (en) * | 2011-10-28 | 2013-11-13 | 合肥市东方美捷分子材料技术有限公司 | Environment-induced material |
| JP5327727B2 (en) * | 2012-02-14 | 2013-10-30 | Ｔｏｔｏ株式会社 | Toilet equipment |
| CN105695185A (en) * | 2016-03-08 | 2016-06-22 | 宋德安 | Efficient and environment-friendly toilet cleaning block |
| CN105695135A (en) * | 2016-03-08 | 2016-06-22 | 宋德安 | Full-organic-component environment-friendly toilet cleaning agent |
| CN105724420A (en) * | 2016-04-09 | 2016-07-06 | 福建省金鹿日化股份有限公司 | Transparent closestool mosquito repelling and odor removing toilet cleaning wax and preparation method thereof |
| CN106190605A (en) * | 2016-07-18 | 2016-12-07 | 中山市海泓日用品有限公司 | Closestool cleaning ball and preparation method thereof |
| CN106833963A (en) * | 2017-01-23 | 2017-06-13 | 福建海西滤水龙头研究中心有限公司 | A kind of toilet deodorant cleansing tablet of solid and preparation method thereof |
| CN107338136A (en) * | 2017-05-26 | 2017-11-10 | 安徽肤彩生物科技有限公司 | A kind of natural plant detergent for toilet |
| CN109810799A (en) * | 2019-02-27 | 2019-05-28 | 孙义柱 | A kind of disposable deodorization and sterilization carpet cleaner |
| CN111996082A (en) * | 2020-08-05 | 2020-11-27 | 名臣健康用品股份有限公司 | Color-changing toilet cleaner composition and preparation method thereof |
-
1989
- 1989-07-14 CN CN 89104849 patent/CN1031516C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1048726A (en) | 1991-01-23 |
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| CF01 | Termination of patent right due to non-payment of annual fee |