CN103142423A - Soap-based cleansing cream not generating soap scum - Google Patents
Soap-based cleansing cream not generating soap scum Download PDFInfo
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- CN103142423A CN103142423A CN2013101082343A CN201310108234A CN103142423A CN 103142423 A CN103142423 A CN 103142423A CN 2013101082343 A CN2013101082343 A CN 2013101082343A CN 201310108234 A CN201310108234 A CN 201310108234A CN 103142423 A CN103142423 A CN 103142423A
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- soap scum
- facial cleaning
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Abstract
The invention relates to a soap-based cleansing cream not generating soap scum. The soap-based cleansing cream is characterized by comprising the following components in percentage by weight: 18-38% of fatty acid, 8-28% of polybasic alcohol, 3-9% of potassium hydroxide, 0.5-4.5% of a polyoxyethylene polyoxypropylene ether block copolymer, and the balance of water and auxiliary components. The soap-based cleansing cream has the advantage of not generating the soap scum, and then has the beneficial effects of convenience, cleanliness, environmental friendliness, water conservation and the like.
Description
Technical field
The present invention relates to cosmetic composition, especially a kind of soap base facial cleaning cream that does not produce soap scum.
Background technology
In the market in clean product, soap base class facial cleaning cream is maximum at the clean sale proportion that appears on the market of China, and clean product of soap base class has foaming fast, the abundant exquisiteness of foam, cleaning dermal sensation afterwards is salubrious, such clean the product of most of Chinese Consumer's preference.
Soap base class facial cleaning cream main body consists of by fatty acid soaps, and general multiplex fatty acid and potassium hydroxide neutralization form, and in order to satisfy the requirement of product moisturizing and molding, needs to add appropriate polyhydric alcohol.In fatty acid and potassium hydroxide and the fatty acid potassium soap that forms when washing, fatty acid anion can with tap water in the metal ions such as calcium, magnesium form fatty acid calcium and fatty acid magnesium, i.e. usually said soap scum, this composition is water insoluble.Because the light specific gravity of fatty acid calcium and fatty acid magnesium can be at water surface drawout after forming, the final dirt that sticks on vessel surface that forms; If use towel in clean process, soap scum also can be attached on towel in a large number, makes the not only hard but also coarse of towel change.This brings huge trouble for later stage cleaning container and towel, usually needs to consume more labour, and it is removed by mechanical means, and is not only unclean, nor environmental protection.Therefore, seeking a solution, do not form soap scum after soap base class facial cleaning cream is used, is very valuable.
Summary of the invention
The technical problem to be solved in the present invention is, the soap base facial cleaning cream that does not produce soap scum after a kind of the use is provided, and has the beneficial effect of cleaning, environmental protection.
For solving the problems of the technologies described above, the technical solution used in the present invention is: a kind of soap base facial cleaning cream that does not produce soap scum is characterized in that: by weight percentage, comprise following component:
Fatty acid 18～38%;
Polyhydric alcohol 8～28%;
Potassium hydroxide 3～9%;
Polyoxyethylene poly-oxygen propylene aether block copolymer 0.5～4.5%;
Water and auxiliary element surplus.
As of the present invention preferred, a kind of soap base facial cleaning cream that does not produce soap scum is characterized in that: by weight percentage, comprise following component:
Fatty acid 18～38%;
Polyhydric alcohol 8～28%;
Potassium hydroxide 3～9%;
Polyoxyethylene poly-oxygen propylene aether block copolymer 1.6～2.4%;
Water and auxiliary element surplus.
Described fatty acid is selected from a kind of in lauric acid, myristic acid, Palmic acid, stearic acid, behenic acid or their mixture.
Described polyhydric alcohol is selected from a kind of in glycerol, 1,3 butylene glycol, 1,2-PD, 1,3-PD, dipropylene glycol or their mixture.
The HLB of described polyoxyethylene poly-oxygen propylene aether block copolymer is 12-18.
The mean molecule quantity of described polyoxyethylene poly-oxygen propylene aether block copolymer is 2500-3500.
Auxiliary element in formula can comprise anion surfactant, cationic surfactant, nonionic emulsifier, non-ionic surface active agent, amphoteric surfactant, thickening agent, wetting agent, antiseptic, essence, pigment, skin conditioning agent etc.
The preferred mean molecule quantity of the present invention is 2500-3500, HLB is that 12 to 18 polyoxyethylene poly-oxygen propylene aether block copolymer is as the soap scum inhibitor, utilize its specific molecular size and suitable HLB value, what after disperseing in water, energy was strong forms stable composite micelle jointly with water-soluble rear free fatty acid anion out, bring into play its block polymer macromole space steric effect, avoid the formation of soap scum material, namely avoid the formation of fatty acid calcium and fatty acid magnesium and separate out.
If the selection molecular weight because its strand is too small, can not be brought into play the macromole space steric effect less than 2500 polyoxyethylene poly-oxygen propylene aether block copolymer, can not stop soap scum to produce.If the selection molecular weight is greater than 3500 polyoxyethylene poly-oxygen propylene aether block copolymer, because strand is long, sterically hindered excessive, can't jointly form stable composite micelle with fatty acid anion, fatty acid anion is free on and can not stops soap scum to produce in water.
If selection HLB value is less than 12 polyoxyethylene poly-oxygen propylene aether block copolymer, its dissolubility in aqueous solution is less, is difficult to reach critical micelle concentration (CMC), can't form stable micelle in water.The HLB value is greater than 18, and is excessive in aqueous solubilities, and critical micelle concentration (CMC) is very high, form to stablize the content that micelle need to be very high, lacks in actual applications to be worth.
In sum, soap base facial cleaning cream of the present invention does not produce soap scum after having advantages of use, and then has the beneficial effects such as facility, cleaning, environment-friendly water-saving.
The specific embodiment
The following example is used for exemplary illustration, but the scope that does not limit the present invention in any way.
Embodiment 1:
A kind of soap base facial cleaning cream that does not produce soap scum takes material as following weight percent:
| The material sequence number | Material name | Ratio | Classification |
| 1 | Lauric acid | 2.00% | Fatty acid |
| 2 | Myristic acid | 20.00% | Fatty acid |
| 3 | Palmic acid | 8.00% | Fatty acid |
| 4 | Stearic acid | 6.00% | Fatty acid |
| 5 | Behenic acid | 2.00% | Fatty acid |
| 6 | Ceteareth-30 | 0.50% | Nonionic emulsifier |
| 7 | Deionized water | 17.09% | Water |
| 8 | Glycerol | 28.00% | Polyhydric alcohol |
| 9 | Potassium hydroxide (90% purity) | 9.00% | Potassium hydroxide |
| 10 | Methyl hydroxybenzoate | 0.30% | Antiseptic |
| 11 | Glycyrrhizic acid dipotassium | 0.10% | The skin conditioner |
| 12 | The polyoxyethylene poly-oxygen propylene aether block copolymer | 4.50% | The soap scum inhibitor |
| 13 | Cocos nucifera oil acyl glycine potassium | 2.00% | Anion surfactant |
| 14 | Essence | 0.50% | Essence |
| 15 | Pigment | 0.01% | Pigment |
| Add up to | 100.00% |
Manufacturing process:
A. above-mentioned material 1-6 is added the emulsifying pot, be heated to 70 ℃, stir after thawing;
B. above-mentioned material 7-11 is added kettle, be heated to 70 ℃, stir;
C. with kettle material suction emulsifying pot, stir with 20rpm rotating speed scraping, stirred 1 hour, then be cooled to 50 ℃;
D. add material 12-13, stirred 30 minutes with 20rpm rotating speed scraping, continue to cool to 33 ℃;
E. add material 14-15, namely get the soap base facial cleaning cream that does not produce soap scum after stirring.
Embodiment 2:
A kind of soap base facial cleaning cream that does not produce soap scum takes material as following weight percent:
| The material sequence number | Material name | Ratio | Classification |
| 1 | Lauric acid | 2.00% | Fatty acid |
| 2 | Myristic acid | 6. 00% | Fatty acid |
| 3 | Stearic acid | 10. 00% | Fatty acid |
| 4 | Ceteareth-20 | 2. 00% | Nonionic emulsifier |
| 5 | Deionized water | 57.30% | Water |
| 6 | Glycerol | 6.00% | Polyhydric alcohol |
| 7 | 1,3 butylene glycol | 1.00% | Polyhydric alcohol |
| 8 | Dipropylene glycol | 1.00% | Polyhydric alcohol |
| 9 | Potassium hydroxide (90% purity) | 3.00% | Potassium hydroxide |
| 10 | Methyl hydroxybenzoate | 0.20% | Antiseptic |
| 11 | Allantoin | 0.10% | The skin conditioner |
| 12 | The polyoxyethylene poly-oxygen propylene aether block copolymer | 0.50% | The soap scum inhibitor |
| 13 | Cocos nucifera oil acyl both sexes guanidine-acetic acid sodium | 10.00% | Amphoteric surfactant |
| 14 | Imidazolidinyl urea | 0.20% | Antiseptic |
| 15 | Essence | 0.68% | Essence |
| 16 | Pigment | 0.02% | Pigment |
| Add up to | 100.00% |
Manufacturing process:
A. above-mentioned material 1-4 is added the emulsifying pot, be heated to 70 ℃, stir after thawing;
B. above-mentioned material 5-11 is added kettle, be heated to 70 ℃, stir;
C. with kettle material suction emulsifying pot, stir with 20rpm rotating speed scraping, stirred 1 hour, then be cooled to 50 ℃;
D. add material 12-13, stirred 30 minutes with 20rpm rotating speed scraping, continue to cool to 33 ℃;
E. add material 14-16, namely get the soap base facial cleaning cream that does not produce soap scum after stirring.
Embodiment 3:
A kind of soap base facial cleaning cream that does not produce soap scum takes material as following weight percent:
| Sequence number | Material name | Ratio | Classification |
| 1 | Myristic acid | 18.000% | Fatty acid |
| 2 | Palmic acid | 4.000% | Fatty acid |
| 3 | Behenic acid | 7.000% | Fatty acid |
| 4 | Hydroxyethyl-cellulose | 0.100% | Thickening agent |
| 5 | Deionized water | 29.685% | Water |
| 6 | Glycerol | 8.000% | Polyhydric alcohol |
| 7 | 1,2 propylene glycol | 6.000% | Polyhydric alcohol |
| 8 | 1,3 propylene glycol | 6.000% | Polyhydric alcohol |
| 9 | Potassium hydroxide (90% purity) | 6.800% | Potassium hydroxide |
| 10 | The polyoxyethylene poly-oxygen propylene aether block copolymer | 2.400% | The soap scum inhibitor |
| 11 | Sodium lauroyl sarcosine | 3.500% | Anion surfactant |
| 12 | The lauryl hydroxyl sulfo betaine | 2.500% | Non-ionic surface active agent |
| 13 | Octyl group/decyl glucoside | 2.000% | Non-ionic surface active agent |
| 14 | Cocos nucifera oil acyl both sexes guanidine-acetic acid sodium | 2.000% | Amphoteric surfactant |
| 15 | Polyquaternary ammonium salt-39 | 0.500% | Cationic surfactant |
| 16 | Phenoxyethanol | 0.800% | Antiseptic |
| 17 | Tocopherol acetas | 0.200% | The skin conditioner |
| 18 | Methylisothiazolinone | 0.005% | Antiseptic |
| 19 | Essence | 0.500% | Essence |
| 20 | Pigment | 0.010% | Pigment |
| Add up to | 100.000% |
Manufacturing process:
A. above-mentioned material 1-4 is added the emulsifying pot, be heated to 70 ℃, stir after thawing;
B. above-mentioned material 5-9 is added kettle, be heated to 70 ℃, stir;
C. with kettle material suction emulsifying pot, stir with 20rpm rotating speed scraping, stirred 1 hour, then be cooled to 50 ℃;
D. add material 10-14, stirred 30 minutes with 20rpm rotating speed scraping, continue to cool to 33 ℃;
E. add material 15-20, namely get the soap base facial cleaning cream that does not produce soap scum after stirring.
Embodiment 4:
A kind of soap base facial cleaning cream that does not produce soap scum takes material as following weight percent:
| Sequence number | Material name | Ratio | Classification |
| 1 | Lauric acid | 2.000% | Fatty acid |
| 2 | Myristic acid | 10.000% | Fatty acid |
| 3 | Palmic acid | 3.000% | Fatty acid |
| 4 | Stearic acid | 7.000% | Fatty acid |
| 5 | The PEG-100 stearate | 0.500% | Nonionic emulsifier |
| 6 | PEG-8 | 5.000% | Wetting agent |
| 7 | Hydroxypropyl emthylcellulose | 1.200% | Thickening agent |
| 8 | Deionized water | 38.985% | Water |
| 9 | Dipropylene glycol | 8.000% | Polyhydric alcohol |
| 10 | 1,2 propylene glycol | 4.000% | Polyhydric alcohol |
| 11 | 1,3 butanediol | 4.000% | Polyhydric alcohol |
| 12 | Potassium hydroxide (90% purity) | 5.400% | Potassium hydroxide |
| 13 | The polyoxyethylene poly-oxygen propylene aether block copolymer | 1.600% | The soap scum inhibitor |
| 14 | The laureth potassium phosphate | 3.500% | Anion surfactant |
| 15 | The Natrulon H-10 laurate | 2.000% | Non-ionic surface active agent |
| 16 | Cocos nucifera oil acyl both sexes guanidine-acetic acid sodium | 2.000% | Amphoteric surfactant |
| 17 | Polyquaternary ammonium salt-7 | 0.500% | Cationic surfactant |
| 18 | Phenoxyethanol | 0.800% | Antiseptic |
| 19 | Tocopherol acetas | 0.200% | The skin conditioner |
| 20 | Methylisothiazolinone | 0.005% | Antiseptic |
| 21 | Essence | 0.300% | Essence |
| ? | Add up to | 100.000% | ? |
Manufacturing process:
A. above-mentioned material 1-7 is added the emulsifying pot, be heated to 70 ℃, stir after thawing;
B. above-mentioned material 8-12 is added kettle, be heated to 70 ℃, stir;
C. with kettle material suction emulsifying pot, stir with 20rpm rotating speed scraping, stirred 1 hour, then be cooled to 50 ℃;
D. add material 13-16, stirred 30 minutes with 20rpm rotating speed scraping, continue to cool to 33 ℃;
E. add material 17-21, namely get the soap base facial cleaning cream that does not produce soap scum after stirring.
Claims (6)
1. soap base facial cleaning cream that does not produce soap scum, it is characterized in that: by weight percentage, it comprises following component:
Fatty acid 18～38%;
Polyhydric alcohol 8～28%;
Potassium hydroxide 3～9%;
Polyoxyethylene poly-oxygen propylene aether block copolymer 0.5～4.5%;
Water and auxiliary element surplus.
2. the soap base facial cleaning cream that does not produce soap scum according to claim 1, it is characterized in that: by weight percentage, it comprises following component:
Fatty acid 18～38%;
Polyhydric alcohol 8～28%;
Potassium hydroxide 3～9%;
Polyoxyethylene poly-oxygen propylene aether block copolymer 1.6～2.4%;
Water and auxiliary element surplus.
3. the soap base facial cleaning cream that does not produce soap scum according to claim 1, it is characterized in that: the HLB of described polyoxyethylene poly-oxygen propylene aether block copolymer is 12-18.
4. the soap base facial cleaning cream that does not produce soap scum according to claim 1, it is characterized in that: the mean molecule quantity of contained polyoxyethylene poly-oxygen propylene aether block copolymer is 2500-3500.
5. the soap base facial cleaning cream that does not produce soap scum according to claim 1 is characterized in that: described fatty acid is selected from a kind of in lauric acid, myristic acid, Palmic acid, stearic acid, behenic acid or their mixture.
6. the soap base facial cleaning cream that does not produce soap scum according to claim 1 is characterized in that: described polyhydric alcohol is selected from a kind of in glycerol, 1,3 butylene glycol, 1,2-PD, 1,3-PD, dipropylene glycol or their mixture.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310108234.3A CN103142423B (en) | 2013-04-01 | 2013-04-01 | Soap-based cleansing cream not generating soap scum |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310108234.3A CN103142423B (en) | 2013-04-01 | 2013-04-01 | Soap-based cleansing cream not generating soap scum |
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| CN103142423A true CN103142423A (en) | 2013-06-12 |
| CN103142423B CN103142423B (en) | 2014-09-03 |
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| Application Number | Title | Priority Date | Filing Date |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103919691A (en) * | 2014-04-16 | 2014-07-16 | 陈建婷 | High-performance skin cleaner |
| CN107854329A (en) * | 2017-12-11 | 2018-03-30 | 壹田（广州）生活健康用品有限公司 | A kind of easily antibacterial moisturizing foam hand cleanser of wash type and preparation method thereof |
| CN109010122A (en) * | 2018-09-26 | 2018-12-18 | 湖南御家化妆品制造有限公司 | A kind of Soap-base facial cleanser and preparation method thereof |
| CN109745236A (en) * | 2017-11-07 | 2019-05-14 | 陕西博鸿生物科技集团有限公司 | A kind of compound face cleaning cream and preparation method thereof |
| CN113616553A (en) * | 2021-09-08 | 2021-11-09 | 上海新高姿化妆品有限公司 | Mild and moisture-stable soap-based cleansing cream and preparation method thereof |
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| US6271191B1 (en) * | 1999-06-30 | 2001-08-07 | Basf Corporation | Hard surface cleaner containing anionic surfactant |
| US6342474B1 (en) * | 1999-06-30 | 2002-01-29 | Basf Corporation | Hard surface cleaner containing nonionic surfactants |
| CN1479784A (en) * | 2000-12-05 | 2004-03-03 | ������������ʽ���� | Method of laundering clothes and detergent composition thereof |
| CN101518505A (en) * | 2009-03-31 | 2009-09-02 | 徐艳萍 | Anti-acne facial cleanser composition |
| CN102178611A (en) * | 2011-04-22 | 2011-09-14 | 杭州珀莱雅控股股份有限公司 | High-pearly-lustre high-foam soap base cleansing cream and preparation method thereof |
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2013
- 2013-04-01 CN CN201310108234.3A patent/CN103142423B/en active Active
Patent Citations (5)
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| US6271191B1 (en) * | 1999-06-30 | 2001-08-07 | Basf Corporation | Hard surface cleaner containing anionic surfactant |
| US6342474B1 (en) * | 1999-06-30 | 2002-01-29 | Basf Corporation | Hard surface cleaner containing nonionic surfactants |
| CN1479784A (en) * | 2000-12-05 | 2004-03-03 | ������������ʽ���� | Method of laundering clothes and detergent composition thereof |
| CN101518505A (en) * | 2009-03-31 | 2009-09-02 | 徐艳萍 | Anti-acne facial cleanser composition |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103919691A (en) * | 2014-04-16 | 2014-07-16 | 陈建婷 | High-performance skin cleaner |
| CN109745236A (en) * | 2017-11-07 | 2019-05-14 | 陕西博鸿生物科技集团有限公司 | A kind of compound face cleaning cream and preparation method thereof |
| CN107854329A (en) * | 2017-12-11 | 2018-03-30 | 壹田（广州）生活健康用品有限公司 | A kind of easily antibacterial moisturizing foam hand cleanser of wash type and preparation method thereof |
| CN107854329B (en) * | 2017-12-11 | 2019-02-01 | 壹田（广州）生活健康用品有限公司 | A kind of antibacterial moisturizing foam hand cleanser of easy wash type and preparation method thereof |
| CN109010122A (en) * | 2018-09-26 | 2018-12-18 | 湖南御家化妆品制造有限公司 | A kind of Soap-base facial cleanser and preparation method thereof |
| CN113616553A (en) * | 2021-09-08 | 2021-11-09 | 上海新高姿化妆品有限公司 | Mild and moisture-stable soap-based cleansing cream and preparation method thereof |
| CN113616553B (en) * | 2021-09-08 | 2023-02-10 | 上海新高姿化妆品有限公司 | Mild and moisture-stable soap-based cleansing cream and preparation method thereof |
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