CN103141939A - Interception agent for reducing phenol content in cigarette smoke and filter stick provided with interception agent - Google Patents
Interception agent for reducing phenol content in cigarette smoke and filter stick provided with interception agent Download PDFInfo
- Publication number
- CN103141939A CN103141939A CN2013100624759A CN201310062475A CN103141939A CN 103141939 A CN103141939 A CN 103141939A CN 2013100624759 A CN2013100624759 A CN 2013100624759A CN 201310062475 A CN201310062475 A CN 201310062475A CN 103141939 A CN103141939 A CN 103141939A
- Authority
- CN
- China
- Prior art keywords
- filter stick
- capsule
- smoke
- trapping agent
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 title claims abstract description 55
- 235000019504 cigarettes Nutrition 0.000 title claims abstract description 34
- 239000000779 smoke Substances 0.000 title claims abstract description 21
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 43
- 239000002775 capsule Substances 0.000 claims abstract description 25
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 21
- 238000000034 method Methods 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 230000008569 process Effects 0.000 claims abstract description 10
- 238000002360 preparation method Methods 0.000 claims abstract description 3
- 235000011187 glycerol Nutrition 0.000 claims description 9
- 230000015572 biosynthetic process Effects 0.000 claims description 5
- 239000003814 drug Substances 0.000 claims description 2
- 230000000391 smoking effect Effects 0.000 abstract description 13
- 239000000203 mixture Substances 0.000 abstract description 9
- 239000002994 raw material Substances 0.000 abstract description 2
- 238000002156 mixing Methods 0.000 abstract 2
- 239000011162 core material Substances 0.000 abstract 1
- 239000000686 essence Substances 0.000 abstract 1
- 239000000796 flavoring agent Substances 0.000 abstract 1
- 235000019634 flavors Nutrition 0.000 abstract 1
- 238000003756 stirring Methods 0.000 abstract 1
- 229960003742 phenol Drugs 0.000 description 26
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 22
- 239000003546 flue gas Substances 0.000 description 22
- 150000002989 phenols Chemical class 0.000 description 8
- 230000009467 reduction Effects 0.000 description 8
- 230000009471 action Effects 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- 241000208125 Nicotiana Species 0.000 description 4
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 4
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 230000000711 cancerogenic effect Effects 0.000 description 2
- 231100000315 carcinogenic Toxicity 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 239000003906 humectant Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- -1 vehicle exhaust Substances 0.000 description 2
- 150000005208 1,4-dihydroxybenzenes Chemical class 0.000 description 1
- 241000522254 Cassia Species 0.000 description 1
- 241000124008 Mammalia Species 0.000 description 1
- 235000006679 Mentha X verticillata Nutrition 0.000 description 1
- 235000002899 Mentha suaveolens Nutrition 0.000 description 1
- 235000001636 Mentha x rotundifolia Nutrition 0.000 description 1
- 235000019082 Osmanthus Nutrition 0.000 description 1
- 241000333181 Osmanthus Species 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 230000017531 blood circulation Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000004925 denaturation Methods 0.000 description 1
- 230000036425 denaturation Effects 0.000 description 1
- 231100000507 endocrine disrupting Toxicity 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 229940011871 estrogen Drugs 0.000 description 1
- 239000000262 estrogen Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 231100000025 genetic toxicology Toxicity 0.000 description 1
- 230000001738 genotoxic effect Effects 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 210000004400 mucous membrane Anatomy 0.000 description 1
- 231100000350 mutagenesis Toxicity 0.000 description 1
- 238000002703 mutagenesis Methods 0.000 description 1
- 150000002931 p-cresols Chemical class 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000001850 reproductive effect Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
Landscapes
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
Abstract
The invention discloses an interception agent for reducing the phenol content in cigarette smoke, which is prepared by blending water, glycerol and essence in a volume ratio of 2.5:(1.2-5):(0.1-0.125), stirring and evenly mixing the mixture. The invention further discloses a filter stick provided with the interception agent, which is prepared by the following steps: (1), adopting a preparation technology for an officinal capsule, taking the interception agent as the capsule core material and wrapping the agent inside the capsule; and (2), applying one or more capsules in fixed positions in a shred forming process, applying a universal filter stick forming technology , and obtaining the filter stick formed once and provided with a total addition quantity of the interception agent ranging from 0.01 mg to 0.5 mg. The interception agent and the filter stick can reduce the phenol content in the cigarette smoke remarkably, improve the cigarette smoke moisture simultaneously, enhance the moist feeling of the smoke, improve the quantity and the quality of the smoke, and endow the smoke with special aroma and smoking flavor, and have the advantages of simple formula, wide raw material source and low cost.
Description
Technical field
The present invention relates to technical field of cigarettes, refer to particularly a kind of filter stick that reduces the trapping agent of phenol content in cigarette smoke and have this trapping agent.
Background technology
Phenolic compound is the common compounds of occurring in nature, and the existence of phenolic compound is arranged in water, fuel, vehicle exhaust, air, wine and cigarette smoke.The phenolic compounds in cigarette smoke of having reported has kind more than 50, and wherein topmost phenolic compound comprises phenol, catechol, resorcinol, hydroquinones, o, m, 7 kinds of compositions such as p-cresols.
Phenolic compound can by directly entering blood circulation with contacting of skin, mucous membrane, cause protein denaturation, cytoclasis and lose vigor.And induced by alkyl hydroxybenzene has endocrine disrupting activity, and mammal and hydrobiological reproductive development are impacted, and is called as the phenols environmental estrogens, and the part phenols component has genotoxicity and carcinogenic or promotion mutagenesis.Above 7 kinds of phenols components all are put in EPA harmful components list, and catechol is classified as the carcinogenic composition of 2B level by IARC.State Bureau's key research project that Zhengzhou tobacco research institute bears " cigarette harmfulness Research on Index System " project finds that by the relation of research harmful components burst size and flue gas BA phenol is to affect one of topmost harmful components of cigarette mainstream flue gas harmfulness.
At present, what in the reduction flue gas, the method for phenol mainly adopted is the method for absorption, because phenol is present in the granule phase substance of flue gas, can be retained down from flue gas by the method for physical absorption.The adsorbent that prior art is used is mainly the larger porous material of surface area, when absorption, holding back phenol, aroma component and the flue gas moisture that also can adsorb part in flue gas, easily produce stimulation, perfume quantity deficiency, the decline of fragrance matter when causing cigarette smoking, have a strong impact on cigarette smoking quality.
Water and glycerine are all the materials that must add in cigarette, and water can be regulated the moistening degree of cigarette shreds, is convenient to rolling of pipe tobacco.Glycerine is humectant commonly used in cigarette, is used for ensureing that the moisture of pipe tobacco can too fastly not scatter and disappear, so that prop up at the condition last volume tobacco curing of certain moisture content, moistening, the difficult generation of cigarette smoke is stimulated.
Summary of the invention
Above-mentioned deficiency for prior art, the purpose of this invention is to provide a kind of filter stick that reduces the trapping agent of phenol content in cigarette smoke and have this trapping agent, to make it be not by adsorption but come to be combined with phenol by hydrogen bond action, reaches the purpose of holding back phenol in flue gas.
For achieving the above object, the trapping agent of phenol content in reduction cigarette smoke provided by the invention, its special character is: it be with water, glycerine and essence take volume ratio as 2.5:1.2 ~ 5:0.1 ~ 0.125 ratio allocates, is uniformly mixed to form.
The present invention also provides a kind of filter stick with above-mentioned trapping agent, and its special character is: it prepares with following step:
(1) adopt the preparation technology of capsule for medicine, trapping agent as the capsule core, is wrapped in capsule;
(2) locate the capsule that applies more than or in the wire-beam forming process, the total addition level that adopts general filter stick formation technology to obtain one-shot forming and trapping agent is the filter stick of 0.01 ~ 0.5mg.
The consumer pinches brokenly capsule in filter stick before cigarette smoking, discharges the trapping agent that wraps up in capsule, then aspirates, and when flue gas passed through, trapping agent played the effect that effective reduction phenol improves cigarette smoking quality.
The invention has the advantages that:
One, trapping agent of the present invention can with flue gas in phenol produce hydrogen bond action, the phenol in the effectively catching flue gas is realized the purpose of elective reduction phenol after ratio that deduction tar changes;
Two, the water in trapping agent can increase flue gas moisture, and simultaneously glycerine is good humectant, can keep the moisture of flue gas to exceed lost, improves moist feeling and the mildness of flue gas, reduces dry sensation and excitant that suction produces;
Three, the essence in trapping agent can promote flue gas matter and exhaust gas volumn, enriches the style and features of cigarette, improves cigarette smoking quality;
Four, trapping agent adding technology process of the present invention is simple, and raw material sources used are extensive, and are with low cost, easy to utilize.
The specific embodiment
The present invention is described in further detail below in conjunction with specific embodiment.
Embodiment 1:
Press listed proportioning configuration trapping agent in table 1.
Table 1 trapping agent proportioning
| Composition | Ratio |
| Water | 1 |
| Glycerine | 1 |
| Mint Essence | 0.02 |
Trapping agent is wrapped in capsule, and the location applies a capsule in the wire-beam forming process, and the total addition level that adopts general filter stick formation technology one-shot forming one meta structure and trapping agent is the filter stick of 0.01mg.Through before cigarette smoking, the capsule in filter stick being crumbed, discharge trapping agent wherein, in the cigarette smoking process, flue gas attenuate greasy soft, stronger cooling taste is arranged, the suction quality of cigarette has obtained lifting.In flue gas the variation of the composition such as tar, phenol see Table 2, table 3.
Table 2 smoke components test result
Table 3 tarry matters in smoke, phenol reduced rate
| Sample number into spectrum | The tar reduced rate | The phenol reduced rate | The elective reduction rate |
| Blank | — | — | — |
| Contrast | 6.2% | 67.2% | 61% |
Embodiment 2:
Press listed proportioning configuration trapping agent in table 4.
Table 4 trapping agent proportioning
| Composition | Ratio |
| Water | 1 |
| Glycerine | 2 |
| Osmanthus flower fragrance | 0.05 |
Trapping agent is wrapped in capsule, and the location applies a capsule in the wire-beam forming process, and the total addition level that adopts general filter stick formation technology one-shot forming one meta structure and trapping agent is the filter stick of 0.3mg.Through before cigarette smoking, the capsule in filter stick being crumbed, discharge trapping agent wherein, in the cigarette smoking process, flue gas attenuate greasy soft, stronger fragrant and sweet sense is arranged, the suction quality of cigarette has obtained lifting.In flue gas the variation of the composition such as tar, phenol see Table 5, table 6.
Table 5 smoke components test result
Table 6 tarry matters in smoke, phenol reduced rate
| Sample number into spectrum | The tar reduced rate | The phenol reduced rate | The elective reduction rate |
| Blank | — | — | — |
| Contrast | 6.8% | 55.8% | 49% |
Embodiment 3:
Press listed proportioning configuration trapping agent in table 7.
Table 7 trapping agent proportioning
| Composition | Ratio |
| Water | 2.5 |
| Glycerine | 1.2 |
| Chinese cassia tree essence | 0.1 |
Trapping agent is wrapped in capsule, and the location applies two capsules in the wire-beam forming process, and the total addition level that adopts general filter stick formation technology one-shot forming one meta structure and trapping agent is the filter stick of 0.5mg.Through before cigarette smoking, the capsule in filter stick being crumbed, discharge trapping agent wherein, in the cigarette smoking process, flue gas strength increases, and satisfaction strengthens, and the suction quality of cigarette has obtained lifting.In flue gas the variation of the composition such as tar, phenol see Table 8, table 9.
Table 8 smoke components test result
Table 9 tarry matters in smoke, phenol reduced rate
| Sample number into spectrum | The tar reduced rate | The phenol reduced rate | The elective reduction rate |
| Blank | — | — | — |
| Contrast | 2.6% | 69.0% | 66.4% |
Operation principle of the present invention: according to the organic chemistry basic theories, the chemical property of phenol is mainly manifested in the hydrogen bond action with certain OH-, and water and glycerine are all the polar substances that can produce hydrogen bond action.This novel trapping agent is added in filter stick with the form that is wrapped in capsule, before cigarette smoking, by filter stick is pushed gently, make capsule material broken, discharge trapping agent wherein, when flue gas passes through, hydrogen bond action produces, the effect of performance harm reduction flavouring.
Claims (2)
1. trapping agent that reduces phenol content in cigarette smoke is characterized in that: it be with water, glycerine and essence take volume ratio as 2.5:1.2 ~ 5:0.1 ~ 0.125 ratio allocates, is uniformly mixed to form.
2. one kind has the filter stick of trapping agent as claimed in claim 1, and it is characterized in that: it prepares with following step:
(1) adopt the preparation technology of capsule for medicine, trapping agent as the capsule core, is wrapped in capsule;
(2) locate the capsule that applies more than or in the wire-beam forming process, the total addition level that adopts general filter stick formation technology to obtain one-shot forming and trapping agent is the filter stick of 0.01 ~ 0.5mg.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013100624759A CN103141939A (en) | 2013-02-27 | 2013-02-27 | Interception agent for reducing phenol content in cigarette smoke and filter stick provided with interception agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013100624759A CN103141939A (en) | 2013-02-27 | 2013-02-27 | Interception agent for reducing phenol content in cigarette smoke and filter stick provided with interception agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103141939A true CN103141939A (en) | 2013-06-12 |
Family
ID=48540498
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2013100624759A Pending CN103141939A (en) | 2013-02-27 | 2013-02-27 | Interception agent for reducing phenol content in cigarette smoke and filter stick provided with interception agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103141939A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106136312A (en) * | 2016-06-28 | 2016-11-23 | 云南瑞升烟草技术（集团）有限公司 | A kind of capsule filter stick reducing harmful substances from flue gases burst size |
| WO2017025924A1 (en) | 2015-08-13 | 2017-02-16 | Philip Morris Products S.A. | Flavor capsules for smoking articles |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5269329A (en) * | 1990-07-09 | 1993-12-14 | Kimberly-Clark Corporation | Method of producing tobacco flavored cigarette filter |
| US20070119467A1 (en) * | 2005-11-29 | 2007-05-31 | Akhmetshin Marsil R | Filter-tipped cigarette |
| CN101232825A (en) * | 2005-08-15 | 2008-07-30 | 菲利普莫里斯生产公司 | Liquid release device for a smoking article |
| WO2008110931A2 (en) * | 2007-03-09 | 2008-09-18 | Philip Morris Products S.A. | Smoking articles with restrictor and aerosol former |
| CN102108136A (en) * | 2009-12-25 | 2011-06-29 | 湖北中烟工业有限责任公司 | Tobacco additive dropping pill wrapping material, dropping pill wrapped thereby and application of dropping pill |
| CN102551211A (en) * | 2011-12-25 | 2012-07-11 | 云南正邦生物技术有限公司 | Preparation method for instant release type cigarette mouth rod |
-
2013
- 2013-02-27 CN CN2013100624759A patent/CN103141939A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5269329A (en) * | 1990-07-09 | 1993-12-14 | Kimberly-Clark Corporation | Method of producing tobacco flavored cigarette filter |
| CN101232825A (en) * | 2005-08-15 | 2008-07-30 | 菲利普莫里斯生产公司 | Liquid release device for a smoking article |
| US20070119467A1 (en) * | 2005-11-29 | 2007-05-31 | Akhmetshin Marsil R | Filter-tipped cigarette |
| WO2008110931A2 (en) * | 2007-03-09 | 2008-09-18 | Philip Morris Products S.A. | Smoking articles with restrictor and aerosol former |
| CN102108136A (en) * | 2009-12-25 | 2011-06-29 | 湖北中烟工业有限责任公司 | Tobacco additive dropping pill wrapping material, dropping pill wrapped thereby and application of dropping pill |
| CN102551211A (en) * | 2011-12-25 | 2012-07-11 | 云南正邦生物技术有限公司 | Preparation method for instant release type cigarette mouth rod |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2017025924A1 (en) | 2015-08-13 | 2017-02-16 | Philip Morris Products S.A. | Flavor capsules for smoking articles |
| US11147307B2 (en) | 2015-08-13 | 2021-10-19 | Philip Morris Products S.A. | Flavor capsules for smoking articles |
| CN106136312A (en) * | 2016-06-28 | 2016-11-23 | 云南瑞升烟草技术（集团）有限公司 | A kind of capsule filter stick reducing harmful substances from flue gases burst size |
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|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20130612 |