CN103070477A - Application of aminopropanol compound - Google Patents
Application of aminopropanol compound Download PDFInfo
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- CN103070477A CN103070477A CN201310015296XA CN201310015296A CN103070477A CN 103070477 A CN103070477 A CN 103070477A CN 201310015296X A CN201310015296X A CN 201310015296XA CN 201310015296 A CN201310015296 A CN 201310015296A CN 103070477 A CN103070477 A CN 103070477A
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Abstract
The invention discloses application of an aminopropanol compound. The aminopropanol compound is used as a cigarette filter additive for reducing the content of aldehyde substances in mainstream smoke of a cigarette. The aminopropanol compound can selectively reduce the content of the aldehyde substances in mainstream smoke of the cigarette, and especially the content of formaldehyde can be reduced up to 84.9 percent.
Description
Technical field
The present invention relates to the application of aminopropanol compounds, belong to the preparing technical field of cigarette filter.
Background technology
Cigarette produces a large amount of chemical substances in combustion process, wherein the part material in the flue gas is harmful to human body, mainly comprises carbon monoxide, hydrogen cyanide, volatile aldehyde, ammonia, nitrosamine, BaP and aldehydes matter etc.Studies show that, found in the components in cigarette smoke gas phase composition that more than 20 plant aldehyde material, what wherein content was the highest is formaldehyde, acetaldehyde, propionic aldehyde, methacrylaldehyde, crotonaldehyde and furfural, these volatile aldehyde materials especially formaldehyde, methacrylaldehyde and crotonaldehyde are the toxin of respiratory tract cilium, can cause PUD D.Wherein, crotonaldehyde was classified as one of seven kinds of harmful components in the cigarette mainstream flue gas in 2008 by State Tobacco Monopoly Bureau especially.
In order to increase the security of sucking of cigarette, lot of domestic and international expert has done a lot of work in the reducing tar and reducing harm field of cigarette.But remove the method for harmful components by common method of falling Jiao, easily cause the loss of useful component in the flue gas, and reduce the suction quality of cigarette.Therefore the harmful components that optionally reduce in the flue gas are problems that receive much concern.The report of aldehyde material is quite a few in the selectivity reducing cigarette fume at present.The acetate silk that US3359990 discloses at cigarette filter rod applies water miscible hydrazides monomer to reduce the technique of the harmful aldehyde material of cigarette smoke.CN101116540A discloses a kind of tobacco additive agent for reducing content of group compounds of aldehydes and ketones in the cigarette smoke, and this invention declares to reduce the group compounds of aldehydes and ketones in the flue gas.CN1612699 declares the basic amino acid aqueous solution is added the content that can reduce the aldehyde material in the cigarette smoke in the cigarette filter.US4753250 discloses L-AA has been made absorption additive, with CuSO
45H
2O is catalyst, by direct adding acetate silk and the technique that loads on adding cigarette filter rod on other carrier, can reduce the harmful substance in the flue gas, especially the content of formaldehyde.US7942154B2 discloses a class and has contained amino polysaccharose substance such as shitosan and make the cigarette filter medium, with joining in the cigarette filter rod after the polar solvent dissolving, can optionally reduce the formaldehyde in the cigarette smoke, and can obviously not improve the nicotine in the flue gas and tar filter efficiency.More described achievements in research, although obtaining certain achievement aspect the reduction aldehydes material in smoke of cigarette content, the processing technology of partial monopoly is more complicated still, is difficult to realize industrial applications.The objective of the invention is to utilize be simple and easy to additive raw material, develop simple processing technology, reach the effect that reduces aldehydes material in smoke of cigarette.At present, have not yet to see aminopropanol compounds report as the reduction aldehyde compound in cigarette filter.
Summary of the invention
The object of the present invention is to provide the aminopropanol compounds as the application in the content of the aldehyde material of cigarette filter-tip additive agent in reducing cigarette mainstream flue gas, the aminopropanol compounds optionally reduces the content of aldehydes material in smoke of cigarette, the content of formaldehyde particularly, and raw material is simple and easy to, and can effectively reduce the harmful components in the cigarette mainstream flue gas.
The invention provides the application of aminopropanol compounds, this application is with the cigarette filter-tip additive agent of aminopropanol compounds as the content that reduces the aldehyde material in the cigarette mainstream flue gas.
Described aminopropanol compounds is that 1-amino-2-propyl alcohol, 3-aminopropanol, 2-methyl-2-amino-1-propyl alcohol, DAP or 3-are amino-1, in 2-two propyl alcohol one or more.
In the above-mentioned application aminopropanol compounds is directly added (adding as adopting micro-syringe) in cigarette filter, be sprayed on the acetate silk base material of cigarette filter rod after perhaps mixing with the fine filter stick plasticizer of vinegar, perhaps be coated on the embossed paper of paper mouth rod.
In the above-mentioned application aminopropanol compounds and composite rear directly the adding in the cigarette filter of promoter (are added as adopting micro-syringe), or be sprayed on the acetate silk base material of cigarette filter rod after mixing with the fine filter stick plasticizer of vinegar, perhaps be coated on the embossed paper of paper mouth rod.
The quality of the fine filter stick plasticizer of additive and vinegar is 1:1 ~ 3 in the above-mentioned application.
In the above-mentioned application additive directly is coated on the embossed paper of paper mouth rod, again paper filter stick and cellulose acetate filter rod is combined into binary compound filter candle.
Described promoter is liquid state or solid state class promoter.
Described liquid state promoter comprises levulic acid or polyethylene glycol; Described solid state class promoter comprises in L-AA, class of department 40, class 60 of department or the sorbierite a kind of.
The molecular weight of described polyethylene glycol is 200 ~ 600.
Described composite be with aminopropanol compounds and liquid state promoter in mass ratio 2 ~ 9:1 be mixed directly and obtain complex additive; Or solid state class promoter is promoted the agent aqueous solution after being dissolved in deionized water in 1:2 ~ 5 in mass ratio, obtain complex additive after 4 ~ 6:3 ~ 5 mix in mass ratio with the promoter aqueous solution that obtains with the aminopropanol compounds.
The addition of described additive is every cigarette 2 ~ 10mg.
Described aldehyde material is the aldehyde compound that comprises formaldehyde, propionic aldehyde, methacrylaldehyde and crotonaldehyde.
Beneficial effect of the present invention: the advantage that aminopropanol compounds of the present invention is used is only need to aminopropanol compounds cheap and easy to get directly to be used, use after perhaps compound through simple process, selectively high to the aldehyde material in the cigarette mainstream flue gas, especially very good to the formaldehyde filter effect in the flue gas, the highlyest reduce by 84.9%.
The specific embodiment
Following examples are intended to illustrate the present invention, rather than to further restriction of the present invention.
Embodiment 1
Additive is a kind of in 1-amino-2-propyl alcohol, 3-aminopropanol and the 2-methyl-2-amino-1-propyl alcohol, directly joins in the cigarette filter with micro-syringe, and addition is every cigarette 5mg.
Embodiment 2
Additive is DAP or 3-amino-1, and 2-two propyl alcohol directly join in the cigarette filter with micro-syringe, and addition is every cigarette 10mg.
The content of aldehyde material in the cigarette analytical test cigarette mainstream flue gas that will prepare by embodiment 1 and embodiment 2, content of formaldehyde is the highest to reduce by 73.0%.Test result sees Table 1.
Table 1 adds the flue gas analysis testing result of different additive cigarette
Embodiment 3
Take by weighing 5g1-amino-2-propyl alcohol and 5g3-aminopropanol, both mix as additives of filter tip.
Embodiment 4
Take by weighing the 1gL-dissolution of ascorbic acid in the 3g deionized water, the gained L-AA aqueous solution and 5g1-amino-2-propyl alcohol are mixed prepare complex additive.
Embodiment 5
Take by weighing the 1g sorbierite, be dissolved in the 3g deionized water, gained sorbitol aqueous solution and 5g1-amino-2-propyl alcohol are mixed prepare complex additive.
Embodiment 6
Take by weighing 1g department class 40 and be dissolved in the deionized water of 3g heat, the turbid liquid of gained and 5g1-amino-2-propyl alcohol are mixed prepare complex additive.
Embodiment 7
Take by weighing 1g polyethylene glycol (400), 3g1-amino-2-propyl alcohol, both mix and prepare complex additive.
Embodiment 8
Take by weighing the 1g levulic acid, 9g2-methyl-2-amino-propyl alcohol, both mix and prepare complex additive.
Embodiment 3 ~ 8 described complex additives are directly joined in the cigarette filter, and every cigarette addition is 10mg, the content of aldehyde material in the analytical test cigarette mainstream flue gas.Analytical test result such as table 2.
Table 2 adds the flue gas analysis testing result of different complex additive cigarette
Embodiment 9
After 1-amino-2-propyl alcohol and cellulose acetate filter rod mixed in quality 1:1 ratio with plasticizer, be sprayed directly on the acetate silk in the cigarette filter tip shaping process, addition is that every cigarette additive amount of 7%(of filter rod quality is 5mg).The filter stick cigarette for preparing is become cigarette.
Embodiment 10
After 3-aminopropanol and cellulose acetate filter rod mixed in quality 1:2 ratio with plasticizer, be sprayed directly on the acetate silk in the cigarette filter tip shaping process, addition is that every cigarette additive amount of 7%(of filter rod quality is 3mg).The filter stick cigarette for preparing is become cigarette.
Embodiment 11
After 2-methyl-2-amino-1-propyl alcohol and cellulose acetate filter rod mixed in quality 1:1 ratio with plasticizer, be sprayed directly on the acetate silk in the cigarette filter tip shaping process, addition is that every cigarette additive amount of 7%(of filter rod quality is 5mg).The filter stick cigarette for preparing is become cigarette.
The content of aldehyde material in the cigarette analytical test cigarette mainstream flue gas that embodiment 9 ~ 11 is made.Analytical test result such as table 3.
The flue gas analysis testing result of table 3 spraying additive cigarette
Embodiment 12
1-amino-2-propyl alcohol with being coated in after the ethanol dilution on the cigarette paper using mouth rod embossed paper through cutting, is processed into papery base rod, then is combined into the binary filter stick with cellulose acetate filter rod, the filter stick cigarette is become cigarette, the additive capacity of every cigarette is 10mg.The content of aldehyde material in the cigarette analytical test cigarette mainstream flue gas, content of formaldehyde reduces by 58.4%.
Claims (10)
1. the application of aminopropanol compounds is characterized in that, with the cigarette filter-tip additive agent of aminopropanol compounds as the content that reduces the aldehyde material in the cigarette mainstream flue gas.
2. application according to claim 1 is characterized in that, described aminopropanol compounds is that 1-amino-2-propyl alcohol, 3-aminopropanol, 2-methyl-2-amino-1-propyl alcohol, DAP or 3-are amino-1, in 2-two propyl alcohol one or more.
3. application according to claim 1 and 2, it is characterized in that, the aminopropanol compounds is directly added in the cigarette filter, be sprayed on the acetate silk base material of cigarette filter rod after perhaps mixing with the fine filter stick plasticizer of vinegar, perhaps be coated on the embossed paper of paper mouth rod.
4. application according to claim 1 and 2, it is characterized in that, directly add in the cigarette filter afterwards with aminopropanol compounds and promoter are composite, or be sprayed on the acetate silk base material of cigarette filter rod after mixing with the fine filter stick plasticizer of vinegar, perhaps be coated on the embossed paper of paper mouth rod.
5. application according to claim 4 is characterized in that, described promoter is liquid state or solid state class promoter.
6. application according to claim 5 is characterized in that, described liquid state promoter comprises levulic acid or polyethylene glycol; Described solid state class promoter comprises in L-AA, class of department 40, class 60 of department or the sorbierite a kind of.
7. application according to claim 6 is characterized in that, the molecular weight of described polyethylene glycol is 200 ~ 600.
8. each described application is characterized in that according to claim 4 ~ 7, described composite be with aminopropanol compounds and liquid state promoter in mass ratio 2 ~ 9:1 be mixed directly and obtain complex additive; Or solid state class promoter is promoted the agent aqueous solution after being dissolved in deionized water in 1:2 ~ 5 in mass ratio, obtain complex additive after 4 ~ 6:3 ~ 5 mix in mass ratio with the promoter aqueous solution that obtains with the aminopropanol compounds.
9. application according to claim 1 and 2 is characterized in that, the addition of described additive is every cigarette 2 ~ 10mg.
10. application according to claim 1 and 2 is characterized in that, described aldehyde material is the aldehyde compound that comprises formaldehyde, propionic aldehyde, methacrylaldehyde and crotonaldehyde.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310015296.XA CN103070477B (en) | 2013-01-16 | 2013-01-16 | Application of aminopropanol compound |
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| CN201310015296.XA CN103070477B (en) | 2013-01-16 | 2013-01-16 | Application of aminopropanol compound |
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| CN103070477A true CN103070477A (en) | 2013-05-01 |
| CN103070477B CN103070477B (en) | 2014-06-11 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109646426A (en) * | 2019-01-09 | 2019-04-19 | 成都倍特药业有限公司 | A kind of composition and 1- amino -2- propyl alcohol purity and the detection method in relation to substance |
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| CN109646426A (en) * | 2019-01-09 | 2019-04-19 | 成都倍特药业有限公司 | A kind of composition and 1- amino -2- propyl alcohol purity and the detection method in relation to substance |
| CN109646426B (en) * | 2019-01-09 | 2022-01-25 | 成都倍特药业股份有限公司 | Composition and method for detecting purity and related substances of 1-amino-2-propanol |
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