CN102977748B - A kind of not containing the UV furniture spray paint light top coat top coat of volatile organic solvent - Google Patents
A kind of not containing the UV furniture spray paint light top coat top coat of volatile organic solvent Download PDFInfo
- Publication number
- CN102977748B CN102977748B CN201210451196.7A CN201210451196A CN102977748B CN 102977748 B CN102977748 B CN 102977748B CN 201210451196 A CN201210451196 A CN 201210451196A CN 102977748 B CN102977748 B CN 102977748B
- Authority
- CN
- China
- Prior art keywords
- top coat
- monomer
- flow agent
- diacrylate monomer
- good
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Paints Or Removers (AREA)
Abstract
Not containing a UV furniture spray paint light top coat top coat for volatile organic solvent, spraying method is used to carry out spraying application; It is made up of the raw material of following weight part: polyester acrylic resin, polyurethane acroleic acid resin, Tricyclodecane Dimethanol diacrylate monomer, tri (propylene glycol) diacrylate monomer, Viscoat 295 monomer, light trigger organosilicon flow agent, vinylformic acid flow agent and defoamer.Paint film structure is tough and tensile, scratch resistance, good hand touch and lasting, high fullness ratio, high brightness, is the coating products of the permanently effective anti-furniture surface of guarantor of a kind of energy, and provides excellent decorative effect, and zero VOC discharge in process of production, and curing speed is fast, and efficiency is high.
Description
Technical field
The present invention is a kind of is the one-pack type ultraviolet-curing paint that a kind of 100%UV resin, UV monomer, UV light trigger and various auxiliary agent form not containing the UV furniture spray paint light top coat top coat of volatile organic solvent, adopts spraying method to construct during construction.
Background technology
Currently available technology, UV coating also claims ultraviolet-curing paint (Ultraviolet curingcoatings), paint with filmogen naming method different from PU, PE, NC etc., UV coating is the curing mode name of painting, it utilizes ultraviolet as the solidification energy, the at normal temperatures cold coating of Quick cross-linking film forming.UV coating has that fast, the suitable large batch of pipelining of curing speed, capacity usage ratio are high, i.e. curable, film excellent combination property under room temperature.Paint film fullness ratio high, makes it be widely used in the field such as furniture, electronics.
The general viscosity of currently marketed UV coating is higher, be only suitable for roller coat or showering construction, because the viscosity of UV monomer is general higher, only add UV monomer and viscosity cannot be reduced to the viscosity that can spray, volatile organic solvent must be added to reduce viscosity to reach spraying application requirement with this, like this, the pollution to environment can be caused, a large amount VOC discharge is also unfavorable for environmental protection, and because organic solvent does not participate in film forming, must treat after having sprayed that organic solvent thoroughly volatilizees can solidify completely, affect production efficiency.
Summary of the invention
The object of the invention is: provide a kind of not containing the UV furniture spray paint light top coat top coat of volatile organic solvent, after UV solidification, form one deck excellent performance protective membrane on the surface of furniture, and excellent decorative effect is provided.
The present invention is achieved in that a kind of not containing the UV furniture spray paint light top coat top coat of volatile organic solvent, and use spraying method to carry out spraying application, it is made up of the raw material of following weight part:
Polyester acrylic resin 20-30,
Polyurethane acroleic acid resin 10-15,
Tricyclodecane Dimethanol diacrylate monomer 10-20,
Tri (propylene glycol) diacrylate monomer 25-35,
Viscoat 295 monomer 20-30,
Light trigger 3-8, organosilicon flow agent 0.1-0.5,
Vinylformic acid flow agent 0.1-0.5, defoamer 0.1-0.5.
Described is a kind of not containing in the UV furniture spray paint light top coat top coat of volatile organic solvent, and described polyester acrylate is 6 functionality polyester acrylic resins, and its viscosity is low, and have weather resisteant good, sticking power is good, and reactive behavior is strong.
Described is a kind of not containing in the UV furniture spray paint light top coat top coat of volatile organic solvent, and described polyurethane acroleic acid resin is 2 functionality aliphatic polyurethane acrylic resins, and snappiness, sticking power are good.
Described is a kind of not containing in the UV furniture spray paint light top coat top coat of volatile organic solvent, and described Tricyclodecane Dimethanol diacrylate monomer is 2 functionality acrylic ester monomers, has dilution capacity strong, lower shrinkage, and curing speed is fast, high rigidity.
Described is a kind of not containing in the UV furniture spray paint light top coat top coat of volatile organic solvent, and described tri (propylene glycol) diacrylate monomer is 2 functionality acrylic ester monomers, has snappiness good, low volatilization.
Described is a kind of not containing in the UV furniture spray paint light top coat top coat of volatile organic solvent, and described Viscoat 295 monomer is 3 functionality acrylic ester monomers, and have cross-linking density high, hardness is good, and wear resistance is good.
Described is a kind of not containing in the UV furniture spray paint light top coat top coat of volatile organic solvent, and described light trigger is fragrant ketone, bitter almond oil camphor and derivative thereof or their mixture.
Described is a kind of not containing in the UV furniture spray paint light top coat top coat of volatile organic solvent, and described organosilicon flow agent is polyether-modified polydimethylsiloxane solution.
Described is a kind of not containing in the UV furniture spray paint light top coat top coat of volatile organic solvent, and described vinylformic acid flow agent is polyacrylate solution.
Described is a kind of not containing in the UV furniture spray paint light top coat top coat of volatile organic solvent, and described defoamer is organic polymer class, not containing organosilicon.
Embodiment
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1
Not containing a UV furniture spray paint light top coat top coat for volatile organic solvent, use spraying method to carry out spraying application, it is made up of the raw material of following weight part:
Polyester acrylic resin 20, polyurethane acroleic acid resin 10,
Tricyclodecane Dimethanol diacrylate monomer 10,
Tri (propylene glycol) diacrylate monomer 25
Viscoat 295 monomer 20,
Light trigger 3, organosilicon flow agent 0.1
Vinylformic acid flow agent 0.1 defoamer 0.1.
Embodiment 2
Not containing a UV furniture spray paint light top coat top coat for volatile organic solvent, spraying method is used to carry out spraying application.It is made up of the raw material of following weight part:
Polyester acrylic resin 30, polyurethane acroleic acid resin 15,
Tricyclodecane Dimethanol diacrylate monomer 20,
Tri (propylene glycol) diacrylate monomer 35,
Viscoat 295 monomer 30,
Light trigger 8, organosilicon flow agent 0.5,
Vinylformic acid flow agent 0.5, defoamer 0.5.
Embodiment 3
Not containing a UV furniture spray paint light top coat top coat for volatile organic solvent, spraying method is used to carry out spraying application.It is made up of the raw material of following weight part:
Polyester acrylic resin 25, polyurethane acroleic acid resin 12,
Tricyclodecane Dimethanol diacrylate monomer 15,
Tri (propylene glycol) diacrylate monomer 30,
Viscoat 295 monomer 25,
Light trigger 6, organosilicon flow agent 0.3,
Vinylformic acid flow agent 0.3, defoamer 0.3.
In above-mentioned enforcement component: described polyester acrylic resin and polyurethane acroleic acid resin can adopt CYTEC company, BASF AG, SARTOMER company, Changxing company or their mixture;
Described Tricyclodecane Dimethanol diacrylate monomer, tri (propylene glycol) diacrylate monomer and Viscoat 295 monomer can adopt CYTEC company, BASF AG, SARTOMER company, Changxing company or their mixture;
Described light trigger is fragrant ketone, bitter almond oil camphor and derivative thereof or their mixture, the BP produced as BASF, 1173,184 or their mixture;
Described organosilicon flow agent is polyether-modified polydimethylsiloxane solution, the TEGO-432 that BYK-333, EVONIK company as the production of Bi Ke company produces or their mixture
Described vinylformic acid flow agent is polyacrylate solution, the TEGO-300 that BYK-361N, EVONIK company as the production of Bi Ke company produces or their mixture;
Described defoamer is organic polymer, not containing organosilicon, and the TEGO-920 that BYK-055, EVONIK company as the production of Bi Ke company produces or their mixture.
During preparation, polyester acrylic resin, polyurethane acroleic acid resin, Tricyclodecane Dimethanol diacrylate monomer, tri (propylene glycol) diacrylate monomer, Viscoat 295 monomer, organosilicon flow agent, vinylformic acid flow agent and defoamer to be added successively and after disperseing, add light trigger to be fully uniformly dispersed, control coating material temperature and be no more than 60 DEG C.
During coating application, suitable UV monomer can be added as the case may be as Tricyclodecane Dimethanol diacrylate monomer, tri (propylene glycol) diacrylate monomer or Viscoat 295 monomer, or control coating material temperature regulates working viscosity, by the mode of spraying, paint is coated furniture surface, standing levelling 1-2 minute namely curable.
The paint film structure that the present invention is formed is tough and tensile, scratch resistance, good hand touch and lasting, high fullness ratio, high brightness, be the coating products of the permanently effective anti-furniture surface of guarantor of a kind of energy, and excellent decorative effect is provided, and zero VOC discharge in process of production, curing speed is fast, efficiency is high, when current environmental requirement increasingly stringent, uses the traditional solvent reducible coatings of UV paint replacement, promotes that industrial upgrading is necessary.
Above-described is only preferred embodiments of the present invention.It should be pointed out that for the person of ordinary skill of the art, without departing from the principles of the present invention, can also make some improvement and modification, this is also considered as protection scope of the present invention.
A kind of each performance index not containing the UV furniture spray paint light top coat top coat of volatile organic solvent of the present invention are as follows:
Claims (1)
1., not containing a UV furniture spray paint light top coat top coat for volatile organic solvent, use spraying method to carry out spraying application; It is characterized in that: it is made up of the raw material of following weight part:
Polyester acrylate resin 20-30,
Polyurethane acrylic resin 10-15,
Tricyclodecane Dimethanol diacrylate monomer 10-20,
Tri (propylene glycol) diacrylate monomer 25-35,
Viscoat 295 monomer 20-30,
Light trigger 3-8, organosilicon flow agent 0.1-0.5,
Vinylformic acid flow agent 0.1-0.5, defoamer 0.1-0.5;
Described polyester acrylate is 6 functionality polyester acrylic resins, and its viscosity is low, and have weather resisteant good, sticking power is good, and reactive behavior is strong;
Described urethane acrylate is 2 functionality aliphatic urethane acrylate resins, and its snappiness, sticking power are good;
Described Tricyclodecane Dimethanol diacrylate monomer is 2 functionality acrylic ester monomers, has dilution capacity strong, lower shrinkage, and curing speed is fast, high rigidity;
Described tri (propylene glycol) diacrylate monomer is 2 functionality acrylic ester monomers, has snappiness good, low volatilization;
Described Viscoat 295 monomer is 3 functionality acrylic ester monomers, and have cross-linking density high, hardness is good, and wear resistance is good;
Described light trigger is fragrant ketone, bitter almond oil camphor and derivative thereof or their mixture;
Described organosilicon flow agent is polyether-modified polydimethylsiloxane solution;
Described vinylformic acid flow agent is polyacrylate solution;
Described defoamer is organic polymer class, not containing organosilicon;
During preparation, polyester acrylic resin, polyurethane acroleic acid resin, Tricyclodecane Dimethanol diacrylate monomer, tri (propylene glycol) diacrylate monomer, Viscoat 295 monomer, organosilicon flow agent, vinylformic acid flow agent and defoamer to be added successively and after disperseing, add light trigger to be fully uniformly dispersed, control coating material temperature and be no more than 60 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210451196.7A CN102977748B (en) | 2012-11-12 | 2012-11-12 | A kind of not containing the UV furniture spray paint light top coat top coat of volatile organic solvent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210451196.7A CN102977748B (en) | 2012-11-12 | 2012-11-12 | A kind of not containing the UV furniture spray paint light top coat top coat of volatile organic solvent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102977748A CN102977748A (en) | 2013-03-20 |
| CN102977748B true CN102977748B (en) | 2015-10-14 |
Family
ID=47852100
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210451196.7A Active CN102977748B (en) | 2012-11-12 | 2012-11-12 | A kind of not containing the UV furniture spray paint light top coat top coat of volatile organic solvent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102977748B (en) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103205146B (en) * | 2013-03-27 | 2016-02-24 | 中国科学院广州地球化学研究所 | A kind of ultraviolet curing type PET film surface treatment silane coupling agent and its preparation method and application |
| CN103275612B (en) * | 2013-05-15 | 2015-10-28 | 江门市国美化工有限公司 | A kind of environmental protection liniment and preparation method thereof |
| CN103589306B (en) * | 2013-10-24 | 2016-08-31 | 惠州市长润发涂料有限公司 | A kind of high osmosis UV priming paint |
| CN103589307A (en) * | 2013-11-14 | 2014-02-19 | 惠州市长润发涂料有限公司 | High-filling UV (ultraviolet) transparent primer |
| CN103602224B (en) * | 2013-11-20 | 2016-06-01 | 广东美涂士建材股份有限公司 | A kind of white solvent-free finish paint and its preparation method and construction technology |
| CN105086808A (en) * | 2015-07-30 | 2015-11-25 | 东莞英铭化工有限公司 | Anti-falling photocureable coating |
| CN105505198A (en) * | 2016-01-19 | 2016-04-20 | 卓达新材料科技集团有限公司 | Building UV coating with high gloss and preparation method thereof |
| CN111334168A (en) * | 2019-12-31 | 2020-06-26 | 河北蓝鸟家具股份有限公司 | UV spraying finish paint without volatile organic solvent |
| CN116179071B (en) * | 2022-11-17 | 2024-03-08 | 武汉瑞普赛技术有限公司 | PET (polyethylene terephthalate) base film primer for flexographic printing plate and preparation method and use method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101845263A (en) * | 2010-05-14 | 2010-09-29 | 上海长悦涂料有限公司 | UV (Ultraviolet) curing coatings with high weatherability |
| CN102031055A (en) * | 2010-12-15 | 2011-04-27 | 东莞大宝化工制品有限公司 | Volatile organic solvent-free UV spraying finish coat |
| CN102732129A (en) * | 2012-07-17 | 2012-10-17 | 东莞大宝化工制品有限公司 | Environment-friendly photo-cured electrostatic spray finish |
-
2012
- 2012-11-12 CN CN201210451196.7A patent/CN102977748B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101845263A (en) * | 2010-05-14 | 2010-09-29 | 上海长悦涂料有限公司 | UV (Ultraviolet) curing coatings with high weatherability |
| CN102031055A (en) * | 2010-12-15 | 2011-04-27 | 东莞大宝化工制品有限公司 | Volatile organic solvent-free UV spraying finish coat |
| CN102732129A (en) * | 2012-07-17 | 2012-10-17 | 东莞大宝化工制品有限公司 | Environment-friendly photo-cured electrostatic spray finish |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102977748A (en) | 2013-03-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102977748B (en) | A kind of not containing the UV furniture spray paint light top coat top coat of volatile organic solvent | |
| CN102161862B (en) | Ultraviolet (UV) light-curable polyurethane acrylic resin composite | |
| CN104194613B (en) | The ultraviolet curing chromatic that can recoat-painting silver powder coating and preparation method thereof | |
| CN102206463B (en) | Vacuum plating UV cured primer | |
| CN103602224B (en) | A kind of white solvent-free finish paint and its preparation method and construction technology | |
| CN106752785A (en) | Aqueous UV silver powder coatings and preparation method thereof | |
| CN104387945A (en) | Odorless staining-resistant anti-yellowing UV coated matt finish paint coating, and preparation method and construction technology thereof | |
| CN103589324B (en) | The anti-scratch matte varnish of a kind of UV | |
| CN102993908A (en) | UV (Ultraviolet) white primer for electrostatic spraying | |
| CN103073934A (en) | Ultraviolet curing anti-fingerprint coating for acrylic and composite material base material thereof | |
| CN100588691C (en) | Coating for UV cured plastic and use | |
| CN102516837A (en) | Ultraviolet (UV) cured roller coating embellishing clear finish coating | |
| CN102911582A (en) | Ultraviolet light cured antifogging coating | |
| CN102206436B (en) | Vacuum-plating ultraviolet curing intermediate paint | |
| CN102229784A (en) | UV paint with resistance to yellowing, and its preparation method and construction process | |
| CN103627300A (en) | Ultraviolet (UV) laser roller coating woodware matt finish | |
| CN104559698A (en) | Yellowing-resistant UV (ultraviolet) transparent primer for electrostatic spraying | |
| CN104673080A (en) | Antistatic water-borne UV coating | |
| CN103740237A (en) | UV (Ultraviolet) laser roller painting matte transparent finishing coat | |
| CN103756519A (en) | UV (Ultraviolet) white base paint with high covering power | |
| CN104479508A (en) | Preparation method of corrosion-resistant flame-retardant paint | |
| CN103305098A (en) | Water boiling-resistant UV (ultraviolet) high-adhesion primer on impregnated laminate flooring | |
| CN104293167A (en) | High-hardness and high-gloss ultraviolet light polymerization coating used for PVC floor tiles | |
| CN103589295A (en) | Leveling-free ultraviolet curing primer | |
| CN102977763A (en) | UV varnish topcoat used for preventing rust at welds of paint iron drum or iron can |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CP01 | Change in the name or title of a patent holder |
Address after: 528427 bards chemical company, Zhengxing industrial Second Road, Nantou Town, Zhongshan City, Guangdong Province Patentee after: Guangdong bards new materials Co.,Ltd. Address before: 528427 bards chemical company, Zhengxing industrial Second Road, Nantou Town, Zhongshan City, Guangdong Province Patentee before: GUANGDONG BADESE CHEMICAL Co.,Ltd. |
|
| CP01 | Change in the name or title of a patent holder |