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CN102952980A - Wide-temperature range memory alloy and preparation method thereof - Google Patents

Wide-temperature range memory alloy and preparation method thereof Download PDF

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Publication number
CN102952980A
CN102952980A CN2012104713899A CN201210471389A CN102952980A CN 102952980 A CN102952980 A CN 102952980A CN 2012104713899 A CN2012104713899 A CN 2012104713899A CN 201210471389 A CN201210471389 A CN 201210471389A CN 102952980 A CN102952980 A CN 102952980A
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CN
China
Prior art keywords
memorial alloy
temperature
preparation
wide temperature
parts
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN2012104713899A
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Chinese (zh)
Inventor
高熠辉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
WUXI CHANG'AN GENERAL METAL PRODUCT CO Ltd
Original Assignee
WUXI CHANG'AN GENERAL METAL PRODUCT CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by WUXI CHANG'AN GENERAL METAL PRODUCT CO Ltd filed Critical WUXI CHANG'AN GENERAL METAL PRODUCT CO Ltd
Priority to CN2012104713899A priority Critical patent/CN102952980A/en
Publication of CN102952980A publication Critical patent/CN102952980A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a wide-temperature range memory alloy, which is prepared with the following components in parts by weight: 50 to 80 parts of Al, 20 to 30 parts of Mn, 5 to 10 parts of Ti, 5 to 10 parts of Fe, 20 to 30 parts of Cu, 2 to 8 parts of Ni, 0.1 to 0.5 parts of CaCO3 and 0.1 to 0.5 parts of MgO. The wide-temperature range memory alloy disclosed by the invention has extremely high memory properties, and the elastic deformation performance of the wide-temperature range memory alloy is extremely excellent.

Description

A kind of wide temperature memorial alloy and preparation method thereof
Technical field
The present invention relates to a kind of alloy material, particularly, relate to a kind of wide temperature memorial alloy and preparation method thereof.
Background technology
Memorial alloy is one of industrial indispensable visual plant, can the quality of its quality is determining safely, economical, produce constantly.The memorial alloy working conditions is harsh, and its working medium major part is the material inflammable, explosive, that perviousness is strong, and minimum operating temperature can reach 4K, and extreme service presure reaches 10MPa.The liquid nitrogen bottle that uses in utilizing the device of liquid nitrogen refrigerating at present has certain slit, even when environment on every side reaches needed low temperature, liquid nitrogen in the liquid nitrogen bottle also still continues to outflow, so in the working process of refrigeration, cause the very large waste of liquid nitrogen, and also reduced the working hour of refrigeration plant.Present memorial alloy can be applied in ultra-low temperature surroundings, such as the Working environment under the liquid nitrogen temperature.But but can not work in than under the wide temperature range.
Summary of the invention
The technical problem to be solved in the present invention is to overcome existing defective, and a kind of wide temperature memorial alloy is provided, and it has the operating temperature range of non-constant width, under this temperature range, and memory performance, its elastic deformation performance is extremely excellent.
In order to solve the problems of the technologies described above, the invention provides following technical scheme:
A kind of wide temperature memorial alloy, finished by the component preparation of following weight part:
Zn:20-30 part, Ti:8-16 part, Al:40-70 part, Fe:10-20 part, Cu:15-25 part, Cr:2-8 part, CaO:0.5-2 part, Ni:5-10 part; MgO:0.5-2 part.
Particularly, finished by the component preparation of following weight part:
Zn:25-30 part, Ti:10-15 part, Al:50-60 part, Fe:12-15 part, Cu:15-20 part, Cr:3-6 part, CaO:0.8-1.2 part, Ni:7-9 part; MgO:0.7-1.55 part.
Particularly, finished by the component preparation of following weight part:
Zn:28 part, Ti:12 part, Al:55 part, Fe:14 part, Cu:18 part, Cr:5 part, CaO:1 part, Ni:8 part; MgO:1.2 part.
The preparation method of wide temperature memorial alloy may further comprise the steps
(1) 20 mesh sieves is crossed in described former abrasive lapping;
(2) with raw material in 1500 degrees centigrade of lower meltings;
(3) after the melting when the aluminium alloy temperature reaches 1400 ℃, the insulation leave standstill 30min, then in vacuum induction furnace, pour into ingot casting; Carry out anneal after the ingot casting cooling, anneal is to be heated to 600 ℃ of insulations furnace cooling after 20 hours;
(4) surface is removed in turning processing after the cooling, forges extruding, 600 ℃ of temperature;
(5) cold or hot drawing material requested.
Beneficial effect of the present invention:
Wide temperature memorial alloy of the present invention just has the deformation function at a lower temperature, can make multiple temperature control device, can make temperature control circuit, temp .-control valve, and the pipeline of temperature control connects.Utilize memorial alloy of the present invention can make automatic fire hydrant--the temperature of catching fire raises, and the memorial alloy distortion makes valve opening, the water spray fire fighting; But the connection of production machinery part, the connection of pipeline; Utilize electrically heated to change temperature, the distortion of interface memorial alloy, can make interface closely drip (oil) do not leak; Can make the antenna of bootstrapping of the area hundreds of square meter of space station--make on the ground large-area parabola shaped or plain aerial first, be folded into one, take space to airship, temperature transition is from generate original big area and shape.
Embodiment
Embodiment 1
A kind of wide temperature memorial alloy, finished by the component preparation of following weight part:
Zn:20 part, Ti:8 part, Al:40 part, Fe:10 part, Cu:15 part, Cr:2 part, CaO:0.5 part, Ni:5 part; MgO:0.5 part.
The preparation method of wide temperature memorial alloy may further comprise the steps
(1) 20 mesh sieves is crossed in described former abrasive lapping;
(2) with raw material in 1500 degrees centigrade of lower meltings;
(3) after the melting when the aluminium alloy temperature reaches 1400 ℃, the insulation leave standstill 30min, then in vacuum induction furnace, pour into ingot casting; Carry out anneal after the ingot casting cooling, anneal is to be heated to 600 ℃ of insulations furnace cooling after 20 hours;
(4) surface is removed in turning processing after the cooling, forges extruding, 600 ℃ of temperature;
(5) cold or hot drawing material requested.
Embodiment 2
A kind of wide temperature memorial alloy, finished by the component preparation of following weight part:
Zn:30 part, Ti:16 part, Al:70 part, Fe:20 part, Cu:25 part, Cr:8 part, CaO:2 part, Ni:10 part; MgO:2 part.
The preparation method of wide temperature memorial alloy may further comprise the steps
(1) 20 mesh sieves is crossed in described former abrasive lapping;
(2) with raw material in 1500 degrees centigrade of lower meltings;
(3) after the melting when the aluminium alloy temperature reaches 1400 ℃, the insulation leave standstill 30min, then in vacuum induction furnace, pour into ingot casting; Carry out anneal after the ingot casting cooling, anneal is to be heated to 600 ℃ of insulations furnace cooling after 20 hours;
(4) surface is removed in turning processing after the cooling, forges extruding, 600 ℃ of temperature;
(5) cold or hot drawing material requested.
Embodiment 3
A kind of wide temperature memorial alloy, finished by the component preparation of following weight part:
Zn:28 part, Ti:12 part, Al:55 part, Fe:14 part, Cu:18 part, Cr:5 part, CaO:1 part, Ni:8 part; MgO:1.2 part.
The preparation method of wide temperature memorial alloy may further comprise the steps
(1) 20 mesh sieves is crossed in described former abrasive lapping;
(2) with raw material in 1500 degrees centigrade of lower meltings;
(3) after the melting when the aluminium alloy temperature reaches 1400 ℃, the insulation leave standstill 30min, then in vacuum induction furnace, pour into ingot casting; Carry out anneal after the ingot casting cooling, anneal is to be heated to 600 ℃ of insulations furnace cooling after 20 hours;
(4) surface is removed in turning processing after the cooling, forges extruding, 600 ℃ of temperature;
(5) cold or hot drawing material requested.
Wide temperature memorial alloy of the present invention just has the deformation function at a lower temperature, can make multiple temperature control device, can make temperature control circuit, temp .-control valve, and the pipeline of temperature control connects.Utilize memorial alloy of the present invention can make automatic fire hydrant--the temperature of catching fire raises, and the memorial alloy distortion makes valve opening, the water spray fire fighting; But the connection of production machinery part, the connection of pipeline; Utilize electrically heated to change temperature, the distortion of interface memorial alloy, can make interface closely drip (oil) do not leak; Can make the antenna of bootstrapping of the area hundreds of square meter of space station--make on the ground large-area parabola shaped or plain aerial first, be folded into one, take space to airship, temperature transition is from generate original big area and shape.
It should be noted that at last: the above only is the preferred embodiments of the present invention, be not limited to the present invention, although with reference to previous embodiment the present invention is had been described in detail, for a person skilled in the art, it still can be made amendment to the technical scheme that aforementioned each embodiment puts down in writing, and perhaps part technical characterictic wherein is equal to replacement.Within the spirit and principles in the present invention all, any modification of doing, be equal to replacement, improvement etc., all should be included within protection scope of the present invention.

Claims (4)

1. one kind wide temperature memorial alloy is characterized in that, is finished by the component preparation of following weight part:
Zn:20-30 part, Ti:8-16 part, Al:40-70 part, Fe:10-20 part, Cu:15-25 part, Cr:2-8 part, CaO:0.5-2 part, Ni:5-10 part; MgO:0.5-2 part.
2. described wide temperature memorial alloy according to claim 1 is characterized in that, is finished by the component preparation of following weight part:
Zn:25-30 part, Ti:10-15 part, Al:50-60 part, Fe:12-15 part, Cu:15-20 part, Cr:3-6 part, CaO:0.8-1.2 part, Ni:7-9 part; MgO:0.7-1.55 part.
3. described wide temperature memorial alloy according to claim 1 is characterized in that, is finished by the component preparation of following weight part:
Zn:28 part, Ti:12 part, Al:55 part, Fe:14 part, Cu:18 part, Cr:5 part, CaO:1 part, Ni:8 part; MgO:1.2 part.
4. the preparation method of each described wide temperature memorial alloy of claim 1-3 may further comprise the steps
(1) 20 mesh sieves is crossed in described former abrasive lapping;
(2) with raw material in 1500 degrees centigrade of lower meltings;
(3) after the melting when the aluminium alloy temperature reaches 1400 ℃, the insulation leave standstill 30min, then in vacuum induction furnace, pour into ingot casting; Carry out anneal after the ingot casting cooling, anneal is to be heated to 600 ℃ of insulations furnace cooling after 20 hours;
(4) surface is removed in turning processing after the cooling, forges extruding, 600 ℃ of temperature;
(5) cold or hot drawing material requested.
CN2012104713899A 2012-11-20 2012-11-20 Wide-temperature range memory alloy and preparation method thereof Pending CN102952980A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2012104713899A CN102952980A (en) 2012-11-20 2012-11-20 Wide-temperature range memory alloy and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2012104713899A CN102952980A (en) 2012-11-20 2012-11-20 Wide-temperature range memory alloy and preparation method thereof

Publications (1)

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CN102952980A true CN102952980A (en) 2013-03-06

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS627839A (en) * 1985-07-03 1987-01-14 Sumitomo Electric Ind Ltd Manufacture of niti alloy
JPS63190130A (en) * 1987-02-02 1988-08-05 Toyota Motor Corp Shape memory alloy
CN102758097A (en) * 2012-08-13 2012-10-31 镇江忆诺唯记忆合金有限公司 Low-aluminium high-manganese CuAlMn low-temperature memory alloy

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS627839A (en) * 1985-07-03 1987-01-14 Sumitomo Electric Ind Ltd Manufacture of niti alloy
JPS63190130A (en) * 1987-02-02 1988-08-05 Toyota Motor Corp Shape memory alloy
CN102758097A (en) * 2012-08-13 2012-10-31 镇江忆诺唯记忆合金有限公司 Low-aluminium high-manganese CuAlMn low-temperature memory alloy

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