CN102849950A - Glass glaze paste for protecting surface of thick film circuit, and preparation technology thereof - Google Patents
Glass glaze paste for protecting surface of thick film circuit, and preparation technology thereof Download PDFInfo
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- CN102849950A CN102849950A CN2012103772565A CN201210377256A CN102849950A CN 102849950 A CN102849950 A CN 102849950A CN 2012103772565 A CN2012103772565 A CN 2012103772565A CN 201210377256 A CN201210377256 A CN 201210377256A CN 102849950 A CN102849950 A CN 102849950A
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Abstract
The invention relates to a glass glaze paste for protecting the surface of a thick film circuit, and a preparation technology of the glass glaze paste; the glass glaze paste is formed by mixing three components (A, B and C), wherein the content of the component A is 30-62%, the content of the component B is 24-56%, and the content of the component C is 38-47%; each part of component A comprises 50-70 SiO2, 4-12 LiCO3, 4-9 ZnO, 4-10 K2SiF6 and 10-25 B2O3; each part of component B comprises 45-55 ZnO, 10-25 B2O3, 1-5 Cr2O3, 1-4 NiO, 0-8 CuO, 0-3 MnO2, 0-3 Co2O3 and 0-3 Al2O3; and the component C is a water-based adhesive. The lead-free water-based glass glaze paste is environment-friendly, low in pollution, low in material price and simple in preparation technology. The glazed surface sintered by the glass glaze paste has excellent binding force and matching linear expansion coefficient with 95-99% of an aluminum oxide ceramic substrate.
Description
Technical field
The present invention relates to the thick film circuit technique field, particularly relate to a kind of thick film circuit surface protection glass glaze slurry and preparation technology thereof.
Background technology
The utilisation technology that the low temperature flux is made the field at thick film integrated circuit is very ripe, be mainly used in the glass binder of the printing slurry of the thick film elements such as conduction band, resistance, electric capacity, inductance as thick film circuit, also be used for the piece of surface covering glass glaze of thick film conduction band and thick film element.
In the conventional art, glass glaze prescription as surface coverage is normally such: prepare first a class and have the flux of good characteristic as basic recipe, add metal, the nonmetallic compound that a class is adjusted performance (such as the new softening temperature of determining, linear expansivity, relevant mechanical properties, tear crystalline substance, goods color etc. open) according to the requirement of specific product again, the viscosity that requires according to the glaze slurry at last adds tackiness agent, through mixing the glaze printing slurry that becomes certain fineness with ball milling.
But, traditional flux powder (base side), mostly contain a certain amount of lead, the Pb-Si-O network is that this class flux has the key of stability, other flux is all introduced a large amount of low melting point prices higher expensive metal or nonmetallic compound basically except more or less leaded.
On January 27th, 2012, European Parliament and the instruction 2002/95/EC of senate " be limited in electric and electronics in use certain objectionable impurities " (ROHS), require to guarantee that the product that on July 1st, 2006 rose to put goods on the market does not contain certain objectionable impurities.Lead is one of heavy noxious metals material of belonging to of ROHS appointment, and plumbous limiting the quantity of in correlated product only is 1000ppm, and since then, product unleaded become a for many years big hot topic problem of novel material and index of correlation technical study.In addition, plumbous heavy corrosion has high corrosion failure to glass smelting equipment and utensil.This has increased the cost of product from another point of view.
In addition, thick film conduction band, element, the common prescription of glass-glazed printing slurry are formed by the abundant hybrid modulation of tackiness agent that solid powder and organic, water-fast oil, ester, Mierocrystalline cellulose form, this class slurry when construction, contains strong impulse toxicity smell and gas usually.Construction process is seriously polluted to equipment, clamping apparatus, human body and dress ornament, and it is large to cause cleaning intensity, and maintenance cost is high, and this class printing ink is once construction, and the printing ink that expends beyond the construction workpiece is owing to the chemical reason is difficult to reclaim.
Therefore, not enough for prior art, provide a kind of thick film circuit surface protection functional, low-cost, environmental protection very necessary with glass glaze slurry and preparation technology thereof.
Summary of the invention
The object of the invention is to avoid the deficiencies in the prior art part and provide a kind of thick film circuit surface protection with glass glaze slurry and preparation technology thereof, this thick film circuit surface protection with glass glaze slurry and preparation technology thereof have functional, cost is low, the characteristics of environmental protection.
One object of the present invention realizes by following technical measures.
A kind of thick film circuit surface protection glass glaze slurry is mixed by A, B and three kinds of component materials of C, take the content of weight part A, B and three kinds of component materials of C as:
A:30-62；
B:24-56；
C:38-47；
Wherein, in weight part:
Every part of A component materials consists of the following composition:
SiO
2 ： 50-70；
LiCO
3： 4-12；
ZnO : 4-9；
K
2SiF
6: 4-10；
B
2O
3: 10-25；
Every part of B component materials consists of the following composition:
ZnO : 45-55；
B
2O
3 : 35-50；
Cr
2O
3 : 1-5；
NiO: 1-4；
CuO: 0-8；
MnO2: 0-3；
Co2O3 : 0-4；
Al2O3 : 0-3；
The C component materials is aqueous binder, and the concrete composition of every part of described C component materials is:
Carboxymethyl cellulose: 2-6;
Glycerol: 1-8;
Water: 100; Perhaps
The concrete composition of every part of described C component materials is:
Methylcellulose gum: 2-6;
Glycerol: 1-3;
Water: 100; Perhaps
The concrete composition of every part of described C component materials is:
Polyvinyl alcohol: 3-10;
Glycerol: 0-3;
Water: 100; Perhaps
The concrete composition of every part of described C component materials is:
Sulfuric acid magnalium: 2-5;
Glycerol: 0-3;
Water: 100; Perhaps
The mixture that is consisted of by the two or more materials in carboxymethyl cellulose, methylcellulose gum, polyvinyl alcohol, the sulfuric acid magnalium: 2-10;
Glycerol: 0-8;
Water: 100.
Preferably, the content of above-mentioned A, B and three kinds of components of C is:
A:45-62；
B:38-56；
C:39-47。
Another is preferred, and the content of above-mentioned A, B and three kinds of components of C is:
A:48-60；
B:40-50；
C:40-45。
Further, every part of A component materials consists of the following composition:
SiO
2 ： 55-65；
LiCO
3： 6-10；
ZnO : 6-8；
K
2SiF
6: 6-8；
B
2O
3: 15-20；
Every part of B component materials consists of the following composition:
ZnO : 48-52；
B
2O
3 : 38-48；
Cr
2O
3 : 2-4；
NiO: 2-3；
CuO: 2-6；
MnO2: 1-2；
Co2O3 : 1-2；
Al2O3 : 1-2；
The C component materials is aqueous binder, and the concrete composition of every part of described C component materials is:
Carboxymethyl cellulose: 3-5;
Glycerol: 3-6;
Water: 100; Perhaps
The concrete composition of every part of described C component materials is:
Methylcellulose gum: 3-5;
Glycerol: 2-2.5;
Water: 100; Perhaps
The concrete composition of every part of described C component materials is:
Polyvinyl alcohol: 5-8;
Glycerol: 0-3;
Water: 100; Perhaps
The concrete composition of every part of described C component materials is:
Sulfuric acid magnalium: 3-4;
Glycerol: 0-3;
Water: 100; Perhaps
The mixture that is consisted of by the two or more materials in carboxymethyl cellulose, methylcellulose gum, polyvinyl alcohol, the sulfuric acid magnalium: 3-8;
Glycerol: 2-6;
Water: 100.
Further, every part of A component materials consists of the following composition:
SiO
2 ： 58-60；
LiCO
3： 7-9；
ZnO : 6.5-7.5；
K
2SiF
6: 6.5-7.5；
B
2O
3: 16-18；
Every part of B component materials consists of the following composition:
ZnO : 49-50；
B
2O
3 : 40-46；
Cr
2O
3 : 2.5-3.5；
NiO: 2-3；
CuO: 3-5；
MnO2: 1.5-1.8；
Co
2O
3 : 1.5-1.8；
Al
2O
3 : 1.5-1.8；
The C component materials is aqueous binder, and the concrete composition of every part of described C component materials is:
Carboxymethyl cellulose: 3.5-4;
Glycerol: 4-5;
Water: 100; Perhaps
The concrete composition of every part of described C component materials is:
Methylcellulose gum: 3.5-4.5;
Glycerol: 2.2-2.4;
Water: 100; Perhaps
The concrete composition of every part of described C component materials is:
Polyvinyl alcohol: 6-7;
Glycerol: 0-3;
Water: 100; Perhaps
The concrete composition of every part of described C component materials is:
Sulfuric acid magnalium: 3.2-3.8;
Glycerol: 0-3;
Water: 100; Perhaps
The mixture that is consisted of by the two or more materials in carboxymethyl cellulose, methylcellulose gum, polyvinyl alcohol, the sulfuric acid magnalium: 4-7;
Glycerol: 3-5;
Water: 100.
Another is preferred, and the content of A, B and three kinds of components of C is:
A : 30.9；
B : 24.7；
C : 44.4；
Wherein, in weight part,
Every part of A component materials consists of the following composition:
SiO
2 ： 60；
LiCO
3： 6；
ZnO : 8；
K
2SiF
6: 10；
B
2O
3: 16；
Every part of B component materials consists of the following composition:
ZnO : 45；
B
2O
3 : 45；
Cr
2O
3 : 3；
NiO: 1；
CuO: 6；
Every part of C component materials consists of the following composition:
Carboxymethyl cellulose: 3;
Glycerol: 3;
Water: 100.
Another is preferred, and the content of A, B and three kinds of components of C is:
A : 30.0；
B : 25.5；
C : 44.5；
Wherein, in weight part,
Every part of A component materials consists of the following composition:
SiO
2 ： 58；
LiCO
3： 7；
ZnO : 9；
K
2SiF
6: 10；
B
2O
3: 16；
Every part of B component materials consists of the following composition:
ZnO : 47；
B
2O
3 : 45；
MnO
2: 1；
Co
2O
3 : 4；
Al
2O
3: 2；
NiO: 1；
Every part of C component materials consists of the following composition:
Carboxymethyl cellulose: 3;
Glycerol: 3;
Water: 100.
Another object of the present invention realizes by following technical measures.
A kind of thick film circuit surface protection is with the preparation technology of glass glaze slurry, for the preparation of the as above described thick film circuit surface protection glass glaze slurry of any one, comprises following process:
1) preparation A component, B component and C component,
The detailed process that wherein prepares the A component is:
Composition and ratio according to the A component takes by weighing starting material;
Place stirrer to stir 10-20 second the starting material that take by weighing, then pack into and found vessel;
To found vessel and place melting furnace, according to 300-500
oC/ hour speed is warming up to 1000-1100
oC also is incubated 15-30 minute, obtains the glass metal of melting;
The glass metal of above-mentioned melting come out of the stove rapidly, and pouring out quenches in cooling or the filling liquid makes glass particle;
Again above-mentioned glass particle is placed disintegrating apparatus to pulverize the glass powder of wearing into 3-5 μ granularity, obtain the A component materials;
The detailed process that wherein prepares the B component is:
Composition and ratio according to the B component takes by weighing starting material;
Place the starting material that take by weighing pulverising apparatus to mix and grind 2-4 hour, produce the powder of 3-5 μ granularity, obtain the B component materials;
The detailed process that wherein prepares the C component is:
Composition and ratio according to the C component takes by weighing starting material;
Put water in vessel in heating to 50-60
oC slowly is sprinkled into gluing powder, and heat temperature raising or use immersion method is stirred well to gluing powder and fully dissolves formation glue, when the C component does not contain the glycerol starting material, namely obtains the C component materials this moment; When the C component contained the glycerol starting material, also needed to add glycerol this moment, then stirs and make the C component materials;
2) mix
Take by weighing A component, B component and C component according to the thick film circuit surface protection with the composition and ratio of glass glaze slurry, then placed the pulverising apparatus ball milling 4-8 hour, make slurry mixing fine grinding, make thick film circuit surface protection glass glaze slurry.
Preferably, 1) preparation A component, B component and C component;
The detailed process of preparation A component is:
Composition and ratio according to the A component takes by weighing starting material;
Place stirrer to stir for 15 seconds the starting material that take by weighing, in the crucible of then packing into;
Crucible is placed melting furnace, according to 400
oC/ hour speed is warming up to 1050
oC also is incubated 20 minutes, obtains the glass metal of melting;
The glass metal of above-mentioned melting come out of the stove rapidly, and pouring out quenches in cooling or the filling liquid makes glass particle;
Again above-mentioned glass particle is placed pulverizer to pulverize the glass powder of wearing into 3-5 μ granularity, obtain the A component materials;
The detailed process that wherein prepares the B component is:
Composition and ratio according to the B component takes by weighing starting material;
Place the starting material that take by weighing ball mill to mix and grind 3 hours, produce the powder of 3-5 μ granularity, obtain the B component materials;
The detailed process that wherein prepares the C component is:
Composition and ratio according to the C component takes by weighing starting material;
Put water in vessel in heating to 55
oC slowly is sprinkled into gluing powder, and heat temperature raising or use immersion method is stirred well to gluing powder and fully dissolves formation glue, when the C component does not contain the glycerol starting material, namely obtains the C component materials this moment; When the C component contained the glycerol starting material, also needed to add glycerol this moment, then stirs and make the C component materials;
2) mix;
Take by weighing A component, B component and C component according to the thick film circuit surface protection with the composition and ratio of glass glaze slurry, then placed the ball mill ball milling 5 hours, make slurry mixing fine grinding, make thick film circuit surface protection glass glaze slurry.
Thick film circuit surface protection of the present invention is not leaded with the formation component of glass glaze slurry, adopts aqueous binder, has the characteristics of environmental protection, minimumization of pollution.In addition, it is cheap to consist of the component price, and the consume material recycling is characteristics simply and easily, are a kind of functional, cheap environmental protection glass glaze slurries.
Thick film circuit surface protection of the present invention with the preparation technology of glass glaze slurry have that preparation technology is simple, the equipment that adopts in the preparation process is general, technological process is controlled easily characteristics.Prepared slurry is not leaded, has the characteristics of environmental protection, minimumization of pollution.
Embodiment
The invention will be further described with the following Examples.
Embodiment 1.
A kind of thick film circuit surface protection glass glaze slurry is mixed by A, B and three kinds of component materials of C, take the content of weight part A, B and three kinds of component materials of C as:
A:30-62；
B:24-56；
C:38-47。
Wherein, in weight part:
Every part of A component materials consists of the following composition:
SiO
2 ： 50-70；
LiCO
3： 4-12；
ZnO : 4-9；
K
2SiF
6: 4-10；
B
2O
3: 10-25。
Every part of B component materials consists of the following composition:
ZnO : 45-55；
B
2O
3 : 35-50；
Cr
2O
3 : 1-5；
NiO: 1-4；
CuO: 0-8；
MnO2: 0-3；
Co
2O
3 : 0-4；
Al
2O
3 : 0-3。
The C component materials is aqueous binder, and the concrete composition of every part of C component materials is:
Carboxymethyl cellulose: 2-6;
Glycerol: 1-8;
Water: 100; Perhaps
The concrete composition of every part of described C component materials is:
Methylcellulose gum: 2-6;
Glycerol: 1-3;
Water: 100; Perhaps
The concrete composition of every part of described C component materials is:
Polyvinyl alcohol: 3-10;
Glycerol: 0-3;
Water: 100; Perhaps
The concrete composition of every part of described C component materials is:
Sulfuric acid magnalium: 2-5;
Glycerol: 0-3;
Water: 100; Perhaps
The mixture that is consisted of by the two or more materials in carboxymethyl cellulose, methylcellulose gum, polyvinyl alcohol, the sulfuric acid magnalium: 2-10;
Glycerol: 0-8;
Water: 100.
This thick film circuit surface protection glass glaze slurry, its preparation technology specifically comprises the steps:
(1) preparation A component.
Composition and ratio according to the A component takes by weighing starting material; Place stirrer to stir 10-20 second the starting material that take by weighing, then pack into and found vessel; To found vessel and place melting furnace, according to 300-500
oC/ hour speed is warming up to 1000-1100
oC also is incubated 15-30 minute, obtains the glass metal of melting; The glass metal of above-mentioned melting come out of the stove rapidly, and pouring out quenches in cooling or the filling liquid makes glass particle; Again above-mentioned glass particle is placed disintegrating apparatus to pulverize the glass powder of wearing into 3-5 μ granularity, obtain the A component materials.
Prepared A component is that lead-free softening temperature is at 520-580
oThe environmental protection glass powder of C.
(2) preparation B component.
Composition and ratio according to the B component takes by weighing starting material; Place the starting material that take by weighing pulverising apparatus to mix and grind 2-4 hour, produce the powder of 3-5 μ granularity, obtain the B component materials;
Prepared B component is used for adjusting glass-glazed softening temperature, linear expansivity and glass-glazed color.The B component is not only so that glass-glazed softening temperature is 500-550
oC, and glass-glazed linear expansivity and 95-99% alumina crystal substrate coupling, the simultaneously glass-glazed Color expression light green of B composition regulation or light blue.
(3) preparation C component.
Put water in vessel in heating to 50-60
oC slowly is sprinkled into gluing powder, and heat temperature raising or use immersion method is stirred well to gluing powder and fully dissolves formation glue, when the C component does not contain the glycerol starting material, namely obtains the C component materials this moment; When the C component contained the glycerol starting material, also needed to add glycerol this moment, then stirs and make the C component materials.
The C component is aqueous binder, can be so that A component and B component be evenly mixed, and form can be for the aqueous, environmental protective slurry of printing or spraying so that A component, B component and C component materials are mixed.
Need to prove, the preparation of A component, B component and C component sequentially is not limited only to prepare successively first the order of A component, B component and C component, it is standby that the preparation process of A component, B component and three kinds of materials of C component can be upset sequential system, as preparing first B component or C component, also can prepare simultaneously A component, B component and C component.The preparation order of A component, B component and three kinds of materials of C component can be adjusted flexibly.
(4) preparation thick film circuit surface protection glass glaze slurry.
In weight part, take by weighing A component, B component, C component according to said ratio.Then place the pulverising apparatus ball milling 4-8 hour, and made slurry mixing fine grinding, make thick film circuit surface protection glass glaze slurry.
Need to prove, can adjust by the C component viscosity of slurry, prepare the printing or the water paste that are suitable for various application scenarios.
Printing or this thick film circuit surface protection that is sprayed on the workpiece can by rapid drying, then be rapidly heated to 500-600 with the glass glaze slurry
oThe C sintering makes glass glaze.Wherein, rapid drying belongs to common process to those of ordinary skills, the workpiece that scribbles the glass glaze slurry directly can be positioned in the baker and dry, also the workpiece that scribbles the glass glaze slurry can be put on an iron plate, iron plate placed on the electric furnace toast, observe the glass glaze slurry of workpiece surface during oven dry and stop to get final product after to be dried.The technique that is rapidly heated also is the common process of this area, specifically according to the situation of employed sintering oven, the heating-up time is set get final product, and usually is set to get final product with interior in 15 minutes.
Need to prove; this thick film circuit surface protection can be arranged at the thick film circuit surface by the printing coating processes with the glass glaze slurry; also can reach by the adjustment to slurry viscosity the adjustment to thick film circuit protection printing coated mask and production technique; take spraying coating process, reach the efficient that improves batch production.
Need to prove, the raw-material concrete quantity of above-mentioned prescription can be in limited range any number, such as any number in numerical value, intermediate point numerical value or the scope of two-end-point, those of ordinary skills can mix corresponding compositing formula according to this prescription, do not enumerate one by one at this.
Prepare the glass glaze glaze sample on 30 thick film circuit surfaces by above-mentioned prescription and complete processing, random selection 20 linear expansivity tests of adopting German DIL402PC linear expansion coefficient tester to carry out glaze wherein, asking its mean value is 75.2*10
-7Mm/
oC.As seen, thick film circuit surface protection of the present invention is very little with the linear expansivity of the prepared glaze of glass glaze slurry, can with the alumina crystal substrate matched well.
This thick film circuit surface protection is not leaded with its composition of glass glaze slurry, is the leadless environment-friendly material, meets the regulation of ROHS.This thick film circuit surface protection is not mercurous with glass glaze slurry, cadmium, sexavalent chrome, Polybrominated biphenyl and six kinds of objectionable impuritiess of polybromodiphenyl ether, so all meet ROHS to the regulation of other heavy metals and objectionable impurities.
This thick film circuit surface protection is a kind of scentless water paste with the glass glaze slurry; glaze sintering from the printing of the preparation of slurry, slurry or spraying, product surface all causes the pollution of minimum level to product, equipment, environment place, ambiance, human body etc.
In addition, thick film circuit surface protection of the present invention is good with the chemical stability of glass glaze slurry, and linear expansivity is little, and linear expansivity is easy to adjust by the component improvement.
This thick film circuit surface protection with the glass glaze slurry not because interconnected reactions, the volatilization of chemical solvents cause the slurry ageing failure, the slurry long preservative period after the modulation, simply reclaiming utilization of waste material.In the construction environment of cleaning, the slurry of scrapping is as long as replenish and viscosity monitoring, just recyclable recycling through moisture.
Thick film circuit surface protection glass glaze slurry of the present invention, its composition material is with low cost, preparation technology is simple, strong to the protectiveness of environment, has significant economic benefit and social benefit, is functional, cheap environment-friendly materials.
Embodiment 2.
A kind of thick film circuit surface protection glass glaze slurry, other technical characterictic is identical with embodiment 1, and difference is: preparation technology is specific as follows:
1) preparation A component, B component and C component.
The detailed process of preparation A component is:
Composition and ratio according to the A component takes by weighing starting material;
Place stirrer to stir for 15 seconds the starting material that take by weighing, in the crucible of then packing into;
Crucible is placed melting furnace, according to 400
oC/ hour speed is warming up to 1050
oC also is incubated 20 minutes, obtains the glass metal of melting;
The glass metal of above-mentioned melting come out of the stove rapidly, and pouring out quenches in cooling or the filling liquid makes glass particle;
Again above-mentioned glass particle is placed pulverizer to pulverize the glass powder of wearing into 3-5 μ granularity, obtain the A component materials;
The detailed process that wherein prepares the B component is:
Composition and ratio according to the B component takes by weighing starting material;
Place the starting material that take by weighing ball mill to mix and grind 3 hours, produce the powder of 3-5 μ granularity, obtain the B component materials.
The detailed process that wherein prepares the C component is:
Composition and ratio according to the C component takes by weighing starting material;
Put water in vessel in heating to 55
oC slowly is sprinkled into gluing powder, and heat temperature raising or use immersion method is stirred well to gluing powder and fully dissolves formation glue, when the C component does not contain the glycerol starting material, namely obtains the C component materials this moment; When the C component contained the glycerol starting material, also needed to add glycerol this moment, then stirs and make the C component materials.
2) mix;
Take by weighing A component, B component and C component according to the thick film circuit surface protection with the composition and ratio of glass glaze slurry, then placed the ball mill ball milling 5 hours, make slurry mixing fine grinding, make thick film circuit surface protection glass glaze slurry.
Embodiment 3.
A kind of thick film circuit surface protection glass glaze slurry, other technical characterictic is identical with embodiment 1, and difference is:
The content of A, B and three kinds of components of C is:
A:45-62；
B:38-56；
C:39-47。
Wherein, every part of A component materials consists of the following composition:
SiO
2 ： 55-65；
LiCO
3： 6-10；
ZnO : 6-8；
K
2SiF
6: 6-8；
B
2O
3: 15-20；
Every part of B component materials consists of the following composition:
ZnO : 48-52；
B
2O
3 : 35-50；
Cr
2O
3 : 2-4；
NiO: 2-3；
CuO: 2-6；
MnO2: 1-2；
Co
2O
3 : 1-2；
Al
2O
3 : 1-2；
The C component materials is aqueous binder, and the concrete composition of every part of described C component materials is:
Carboxymethyl cellulose: 3-5;
Glycerol: 3-6;
Water: 100; Perhaps
The concrete composition of every part of described C component materials is:
Methylcellulose gum: 3-5;
Glycerol: 2-2.5;
Water: 100; Perhaps
The concrete composition of every part of described C component materials is:
Polyvinyl alcohol: 5-8;
Glycerol: 0-3;
Water: 100; Perhaps
The concrete composition of every part of described C component materials is:
Sulfuric acid magnalium: 3-4;
Glycerol: 0-3;
Water: 100; Perhaps
The mixture that is consisted of by the two or more materials in carboxymethyl cellulose, methylcellulose gum, polyvinyl alcohol, the sulfuric acid magnalium: 3-8;
Glycerol: 2-6;
Water: 100.
The glass glaze glaze sample on the thick film circuit surface of preparing by above-mentioned prescription and complete processing, it is 75.3*10 that the linear expansivity of its glaze is not more than mean value
-7Mm/
oC.
This thick film circuit surface protection is not leaded with its composition of glass glaze slurry, is the leadless environment-friendly material, meets the regulation of ROHS.
This thick film circuit surface protection is a kind of scentless water paste with the glass glaze slurry; glaze sintering from the printing of the preparation of slurry, slurry or spraying, product surface all causes minimum pollution to product, equipment, environment place, ambiance, human body etc.
In addition, thick film circuit surface protection of the present invention is good with the chemical stability of glass glaze slurry, and linear expansivity is little, and linear expansivity is easy to adjust by the component improvement.
This thick film circuit surface protection with the glass glaze slurry not because interconnected reactions, the volatilization of chemical solvents cause the slurry ageing failure, the slurry long preservative period after the modulation, simply reclaiming utilization of waste material.In the construction environment of cleaning, the slurry of scrapping is convenient to recycling.
Thick film circuit surface protection glass glaze slurry of the present invention, its composition material is with low cost, preparation technology is simple, strong to the protectiveness of environment, has significant economic benefit and social benefit, is functional, cheap environment-friendly materials.
Embodiment 4.
A kind of thick film circuit surface protection glass glaze slurry, other technical characterictic is identical with embodiment 1 or 2, and difference is:
The content of A, B and three kinds of components of C is:
A:48-60；
B:40-50；
C:40-45。
Wherein, every part of A component materials consists of the following composition:
SiO
2 ： 58-60；
LiCO
3： 7-9；
ZnO : 6.5-7.5；
K
2SiF
6: 6.5-7.5；
B
2O
3: 16-18；
Every part of B component materials consists of the following composition:
ZnO : 49-50；
B
2O
3 : 39-47；
Cr
2O
3 : 2.5-3.5；
NiO: 2-3；
CuO: 3-5；
MnO2: 1.5-1.8；
Co
2O
3 : 1.5-1.8；
Al
2O
3 : 1.5-1.8；
The C component materials is aqueous binder, and the concrete composition of every part of described C component materials is:
Carboxymethyl cellulose: 3.5-4;
Glycerol: 4-5;
Water: 100; Perhaps
The concrete composition of every part of described C component materials is:
Methylcellulose gum: 3.5-4.5;
Glycerol: 2.2-2.4;
Water: 100; Perhaps
The concrete composition of every part of described C component materials is:
Polyvinyl alcohol: 6-7;
Glycerol: 2-3;
Water: 100; Perhaps
The concrete composition of every part of described C component materials is:
Sulfuric acid magnalium: 3.2-3.8;
Glycerol: 1-3;
Water: 100; Perhaps
The mixture that is consisted of by the two or more materials in carboxymethyl cellulose, methylcellulose gum, polyvinyl alcohol, the sulfuric acid magnalium: 4-7;
Glycerol: 3-5;
Water: 100.
The glass glaze glaze sample on the thick film circuit surface of preparing by above-mentioned prescription and complete processing, it is 75.3*10 that the linear expansivity of its glaze is not more than mean value
-7Mm/
oC.
Embodiment 5.
A kind of thick film circuit surface protection glass glaze slurry, other technical characterictic is identical with embodiment 1 or 2 or 3, and difference is:
The content of A, B and three kinds of components of C is:
A:54；
B:45；
C:42。
Wherein, every part of A component materials consists of the following composition:
SiO
2 ： 59；
LiCO
3： 8；
ZnO : 7；
K
2SiF
6:7；
B
2O
3: 17；
Every part of B component materials consists of the following composition:
ZnO : 49.5；
B
2O
3 : 45；
Cr
2O
3 : 3.0；
NiO: 2.5；
CuO: 4；
MnO2: 1.7；
Co2O3 : 1.7；
Al
2O
3 : 1.7；
The C component materials is aqueous binder, and the concrete composition of every part of described C component materials is:
Carboxymethyl cellulose: 3.8;
Glycerol: 4.5;
Water: 100; Perhaps
The concrete composition of every part of described C component materials is:
Methylcellulose gum: 3.8;
Glycerol: 2.3;
Water: 100; Perhaps
The concrete composition of every part of described C component materials is:
Polyvinyl alcohol: 6.5;
Water: 100; Perhaps
The concrete composition of every part of described C component materials is:
Sulfuric acid magnalium: 3.5;
Water: 100; Perhaps
The mixture that is consisted of by the two or more materials in carboxymethyl cellulose, methylcellulose gum, polyvinyl alcohol, the sulfuric acid magnalium: 6;
Glycerol: 4;
Water: 100.
The glass glaze glaze sample on the thick film circuit surface of preparing by above-mentioned prescription and complete processing, it is 75.0*10 that the linear expansivity of its glaze is not more than mean value
-7Mm/
oC.
Embodiment 6.
A kind of thick film circuit surface protection glass glaze slurry, other technical characterictic is identical with embodiment 1 or 2 or 3 or 4, and difference is:
The content of A, B and three kinds of components of C is:
A:49；
B:45；
C:42。
Wherein, every part of A component materials consists of the following composition:
SiO
2 ： 59；
LiCO
3： 8；
ZnO : 7；
K
2SiF
6: 7；
B
2O
3: 17；
Every part of B component materials consists of the following composition:
ZnO : 49.5；
B
2O
3 : 46；
Cr
2O
3 : 3；
NiO: 2.5；
CuO: 4；
MnO2: 1.6；
Co2O3 : 1.65；
Al
2O
3 : 1.7；
The C component materials is aqueous binder, and the concrete composition of every part of described C component materials is:
Carboxymethyl cellulose: 3.8;
Glycerol: 4.5;
Water: 100; Perhaps
The concrete composition of every part of described C component materials is:
Methylcellulose gum: 4;
Glycerol: 2.3;
Water: 100; Perhaps
The concrete composition of every part of described C component materials is:
Polyvinyl alcohol: 6.5;
Water: 100; Perhaps
The concrete composition of every part of described C component materials is:
Sulfuric acid magnalium: 3.6;
Water: 100; Perhaps
The mixture that is consisted of by the two or more materials in carboxymethyl cellulose, methylcellulose gum, polyvinyl alcohol, the sulfuric acid magnalium: 5;
Glycerol: 4;
Water: 100.
The glass glaze glaze sample on the thick film circuit surface of preparing by above-mentioned prescription and complete processing, it is 75.30*10 that the linear expansivity of its glaze is not more than mean value
-7Mm/
oC.
Embodiment 7.
A kind of thick film circuit surface protection glass glaze slurry is mixed by A, B and three kinds of component materials of C, take the content of weight part A, B and three kinds of components of C as:
A : 30.9；
B : 24.7；
C : 44.4。
Wherein, in weight part, every part of A component contains:
SiO
2 ： 60；
LiCO
3： 6；
ZnO : 8；
K
2SiF
6: 10；
B
2O
3: 16。
In weight part, every part of B component contains:
ZnO : 45；
B
2O
3 : 45；
Cr
2O
3 : 3；
NiO: 1；
CuO: 6。
In weight part, every part of C component contains:
Carboxymethyl cellulose: 3;
Glycerol: 3;
Water: 100.
This thick film circuit surface protection glass glaze slurry, its preparation technology specifically comprises the steps:
(1) preparation A component
Composition and ratio according to above-mentioned A component weighs up starting material, places stirrer to stir 10-20 second in the material for preparing, and then packs into to found crucible and place melting furnace, by 400
oThe C/ speed at one hour rating is warming up to 1050
oC also is incubated 30 minutes, and crucible is taken out in blowing out fast, and the glass metal of melting is poured into water the generation beads that quenches, and the oven dry of beads draining is placed on to pulverize in the broken glass machine machine ball mill grind the A component glass powder of making 3-5 μ granularity.
Prepared A component is that lead-free softening temperature is at 520-580
oThe environmental protection glass powder of C.
(2) preparation B component
Composition and ratio according to above-mentioned B component weighs up starting material, and places ball mill mixing and vibration or ball milling 1-2 hour, grinds into the B component powder of 3-5 μ granularity.
Prepared B component is used for adjusting glass-glazed softening temperature, linear expansivity and glass-glazed color.The B component is not only so that glass-glazed softening temperature is 500-550
oC, and glass-glazed linear expansivity and 95-99% alumina crystal substrate coupling, the simultaneously glass-glazed Color expression light green of B composition regulation or light blue.
(3) preparation C component
Take by weighing starting material according to above-mentioned C component composition and ratio, put first water in vessel in heating to 50-60
oC slowly is sprinkled into the carboxymethyl cellulose gum powder in water, while stirring heating makes gluing powder be dissolved into even glue, adds at last glycerol and fully stirs, and makes the aqueous binder of C component.
The C component is aqueous binder, can be so that A component and B component be evenly mixed, and form can be for the aqueous, environmental protective slurry of printing or spraying so that A component, B component and C component are mixed.
(4) preparation thick film circuit surface protection glass glaze slurry
In weight part, take by weighing 30.9 parts of A components, take by weighing 24.7 parts of B components, take by weighing 44.4 parts of C components.The starting material that take by weighing were placed spheroidal graphite tank mixing and ball milling 2 hours, namely make required for the present invention want thick film circuit surface protection glass glaze slurry.This thick film circuit surface protection is light green with the glass glaze slurry.
Need to prove, can adjust by the C component viscosity of slurry, prepare the printing or the water paste that are suitable for various application scenarios.
Printing or this thick film circuit surface protection that is sprayed on the workpiece can by rapid drying, then be rapidly heated to 500-600 with the glass glaze slurry
oThe C sintering makes jade-green glass glaze.
Prepare the glass glaze glaze sample on 30 thick film circuit surfaces by above-mentioned prescription and complete processing, random selection 20 linear expansivity tests of adopting German DIL402PC linear expansion coefficient tester to carry out glaze wherein, asking its mean value is 75*10
-7Mm/
oC.As seen, thick film circuit surface protection of the present invention is very little with the linear expansivity of the prepared glaze of glass glaze slurry, can with the alumina crystal substrate matched well.
This thick film circuit surface protection is not leaded with its composition of glass glaze slurry, is the leadless environment-friendly material, meets the regulation of ROHS.
This thick film circuit surface protection is a kind of scentless water paste with the glass glaze slurry; glaze sintering from the printing of the preparation of slurry, slurry or spraying, product surface all causes minimum pollution to product, equipment, environment place, ambiance, human body etc.
In addition, thick film circuit surface protection of the present invention is good with the chemical stability of glass glaze slurry, and linear expansivity is little, and linear expansivity is easy to adjust by the component improvement.
This thick film circuit surface protection with the glass glaze slurry not because interconnected reactions, the volatilization of chemical solvents cause the slurry ageing failure, the slurry long preservative period after the modulation, simply reclaiming utilization of waste material.In the construction environment of cleaning, the slurry of scrapping is convenient to recycling.
Thick film circuit surface protection glass glaze slurry of the present invention, its composition material is with low cost, preparation technology is simple, strong to the protectiveness of environment, has significant economic benefit and social benefit, is functional, cheap environment-friendly materials.
Embodiment 8.
A kind of thick film circuit surface protection glass glaze slurry is mixed by A, B and three kinds of component materials of C, take the content of weight part A, B and three kinds of components of C as:
A : 30.0；
B : 25.5；
C : 44.5。
Wherein, in weight part, every part of A component contains:
SiO
2 ： 58；
LiCO
3： 7；
ZnO : 9；
K
2SiF
6: 10；
B
2O
3: 16。
In weight part, every part of B component contains:
ZnO : 47；
B
2O
3 : 45；
MnO
2: 1；
Co
2O
3 : 4；
Al
2O
3: 2；
NiO: 1。
In weight part, every part of C component contains:
Carboxymethyl cellulose: 3;
Glycerol: 3;
Water: 100.
This thick film circuit surface protection glass glaze slurry, its preparation technology specifically comprises the steps:
(1) preparation A component
Composition and ratio according to above-mentioned A component weighs up starting material, places stirrer to stir 10-20 second in the material for preparing, and then packs into to found crucible and place melting furnace, by 400
oThe C/ speed at one hour rating is warming up to 1050
oC also is incubated 30 minutes, and crucible is taken out in blowing out fast, and the glass metal of melting is poured into water the generation beads that quenches, and the oven dry of beads draining is placed on to pulverize in the broken glass machine machine ball mill grind the A component glass powder of making 3-5 μ granularity.
Prepared A component is that lead-free softening temperature is at 520-580
oThe environmental protection glass powder of C.
(2) preparation B component
Composition and ratio according to above-mentioned B component weighs up starting material, and places ball mill mixing and vibration or ball milling 1-2 hour, grinds into the B component powder of 3-5 μ granularity.
Prepared B component is used for adjusting glass-glazed softening temperature, linear expansivity and glass-glazed color.The B component is not only so that glass-glazed softening temperature is 500-550
oC, and glass-glazed linear expansivity and 95-99% alumina crystal substrate coupling, the simultaneously glass-glazed Color expression light green of B composition regulation or light blue.
(3) preparation C component
Take by weighing starting material according to above-mentioned C component composition and ratio, put first water in vessel in heating to 50-60
oC slowly is sprinkled into the carboxymethyl cellulose gum powder in water, while stirring heating makes gluing powder be dissolved into even glue, adds at last glycerol and fully stirs, and makes the aqueous binder of C component.
The C component is aqueous binder, can be so that A component and B component be evenly mixed, and form can be for the aqueous, environmental protective slurry of printing or spraying so that A component, B component and C component are mixed.
(4) preparation thick film circuit surface protection glass glaze slurry
In weight part, take by weighing 30.0 parts of A components, take by weighing 25.5 parts of B components, take by weighing 44.5 parts of C components.The starting material that take by weighing were placed spheroidal graphite tank mixing and ball milling 2 hours, namely make required for the present invention want thick film circuit surface protection glass glaze slurry.This thick film circuit surface protection is light green with the glass glaze slurry.
Need to prove, can adjust by the C component viscosity of slurry, prepare the printing or the water paste that are suitable for various application scenarios.
Printing or this thick film circuit surface protection that is sprayed on the workpiece can by rapid drying, then be rapidly heated to 500-600 with the glass glaze slurry
oThe C sintering makes glass glaze azury.
Prepare the glass glaze glaze sample on 30 thick film circuit surfaces by above-mentioned prescription and complete processing, random selection 20 linear expansivity tests of adopting German DIL402PC linear expansion coefficient tester to carry out glaze wherein, asking its mean value is 74.9*10
-7Mm/
oC.As seen, thick film circuit surface protection of the present invention is very little with the linear expansivity of the prepared glaze of glass glaze slurry, can with the alumina crystal substrate matched well.
This thick film circuit surface protection is not leaded with its composition of glass glaze slurry, is the leadless environment-friendly material, meets the regulation of ROHS.
This thick film circuit surface protection is a kind of scentless water paste with the glass glaze slurry; glaze sintering from the printing of the preparation of slurry, slurry or spraying, product surface all causes minimum pollution to product, equipment, environment place, ambiance, human body etc.
In addition, thick film circuit surface protection of the present invention is good with the chemical stability of glass glaze slurry, and linear expansivity is little, and linear expansivity is easy to adjust by the component improvement.
This thick film circuit surface protection with the glass glaze slurry not because interconnected reactions, the volatilization of chemical solvents cause the slurry ageing failure, the slurry long preservative period after the modulation, simply reclaiming utilization of waste material.In the construction environment of cleaning, the slurry of scrapping is convenient to recycling.
Thick film circuit surface protection glass glaze slurry of the present invention, its composition material is with low cost, preparation technology is simple, strong to the protectiveness of environment, has significant economic benefit and social benefit, is functional, cheap environment-friendly materials.
Should be noted that at last; above embodiment is only in order to illustrate technical scheme of the present invention but not limiting the scope of the invention; although with reference to preferred embodiment the present invention has been done detailed description; those of ordinary skill in the art is to be understood that; can make amendment or be equal to replacement technical scheme of the present invention, and not break away from essence and the scope of technical solution of the present invention.
Claims (9)
1. thick film circuit surface protection glass glaze slurry is characterized in that: mixed by A, B and three kinds of component materials of C, take the content of weight part A, B and three kinds of components of C as:
A:30-62；
B:24-56；
C:38-47；
Wherein, in weight part:
Every part of A component materials consists of the following composition:
SiO
2 ： 50-70；
LiCO
3： 4-12；
ZnO : 4-9；
K
2SiF
6: 4-10；
B
2O
3: 10-25；
Every part of B component materials consists of the following composition:
ZnO : 45-55；
B
2O
3 : 35-50；
Cr
2O
3 : 1-5；
NiO: 1-4；
CuO: 0-8；
MnO
2: 0-3；
Co
2O
3 : 0-4；
Al
2O
3 : 0-3；
The C component materials is aqueous binder, and the concrete composition of every part of described C component materials is:
Carboxymethyl cellulose: 2-6;
Glycerol: 1-8;
Water: 100; Perhaps
The concrete composition of every part of described C component materials is:
Methylcellulose gum: 2-6;
Glycerol: 1-3;
Water: 100; Perhaps
The concrete composition of every part of described C component materials is:
Polyvinyl alcohol: 3-10;
Glycerol: 0-3;
Water: 100; Perhaps
The concrete composition of every part of described C component materials is:
Sulfuric acid magnalium: 2-5;
Glycerol: 0-3;
Water: 100; Perhaps
The mixture that is consisted of by the two or more materials in carboxymethyl cellulose, methylcellulose gum, polyvinyl alcohol, the sulfuric acid magnalium: 2-10;
Glycerol: 0-8;
Water: 100.
2. thick film circuit surface protection glass glaze slurry according to claim 1, it is characterized in that: the content of described A, B and three kinds of components of C is:
A:45-62；
B:38-56；
C:39-47。
3. thick film circuit surface protection glass glaze slurry according to claim 2 is characterized in that:
The content of described A, B and three kinds of components of C is:
A:48-60；
B:40-50；
C:40-45。
4. it is characterized in that according to claim 2 or 3 described thick film circuit surface protection glass glaze slurries:
Every part of A component materials consists of the following composition:
SiO
2 ： 55-65；
LiCO
3： 6-10；
ZnO : 6-8；
K
2SiF
6: 6-8；
B
2O
3: 15-20；
Every part of B component materials consists of the following composition:
ZnO : 48-52；
B
2O
3 : 38-48；
Cr
2O
3 : 2-4；
NiO: 2-3；
CuO: 2-6；
MnO
2: 1-2；
Co
2O
3 : 1-2；
Al
2O
3 : 1-2；
The C component materials is aqueous binder, and the concrete composition of every part of described C component materials is:
Carboxymethyl cellulose: 3-5;
Glycerol: 3-6;
Water: 100; Perhaps
The concrete composition of every part of described C component materials is:
Methylcellulose gum: 3-5;
Glycerol: 2-2.5;
Water: 100; Perhaps
The concrete composition of every part of described C component materials is:
Polyvinyl alcohol: 5-8;
Glycerol: 0-3;
Water: 100; Perhaps
The concrete composition of every part of described C component materials is:
Sulfuric acid magnalium: 3-4;
Glycerol: 0-3;
Water: 100; Perhaps
The mixture that is consisted of by the two or more materials in carboxymethyl cellulose, methylcellulose gum, polyvinyl alcohol, the sulfuric acid magnalium: 3-8;
Glycerol: 2-6;
Water: 100.
5. thick film circuit surface protection glass glaze slurry according to claim 4 is characterized in that:
Every part of A component materials consists of the following composition:
SiO
2 ： 58-60；
LiCO
3： 7-9；
ZnO : 6.5-7.5；
K
2SiF
6: 6.5-7.5；
B
2O
3: 16-18；
Every part of B component materials consists of the following composition:
ZnO : 49-50；
B
2O
3 : 40-46；
Cr
2O
3 : 2.5-3.5；
NiO: 2-3；
CuO: 3-5；
MnO
2: 1.5-1.8；
Co
2O
3 : 1.5-1.8；
Al
2O
3 : 1.5-1.8；
The C component materials is aqueous binder, and the concrete composition of every part of described C component materials is:
Carboxymethyl cellulose: 3.5-4;
Glycerol: 4-5;
Water: 100; Perhaps
The concrete composition of every part of described C component materials is:
Methylcellulose gum: 3.5-4.5;
Glycerol: 2.2-2.4;
Water: 100; Perhaps
The concrete composition of every part of described C component materials is:
Polyvinyl alcohol: 6-7;
Glycerol: 0-3;
Water: 100; Perhaps
The concrete composition of every part of described C component materials is:
Sulfuric acid magnalium: 3.2-3.8;
Glycerol: 0-3;
Water: 100; Perhaps
The mixture that is consisted of by the two or more materials in carboxymethyl cellulose, methylcellulose gum, polyvinyl alcohol, the sulfuric acid magnalium: 4-7;
Glycerol: 3-5;
Water: 100.
6. thick film circuit surface protection glass glaze slurry according to claim 1 is characterized in that:
The content of A, B and three kinds of components of C is:
A : 30.9；
B : 24.7；
C : 44.4；
Wherein, in weight part,
Every part of A component materials consists of the following composition:
SiO
2 ： 60；
LiCO
3： 6；
ZnO : 8；
K
2SiF
6: 10；
B
2O
3: 16；
Every part of B component materials consists of the following composition:
ZnO : 45；
B
2O
3 : 45；
Cr
2O
3 : 3；
NiO: 1；
CuO: 6；
Every part of C component materials consists of the following composition:
Carboxymethyl cellulose: 3;
Glycerol: 3;
Water: 100.
7. thick film circuit surface protection glass glaze slurry according to claim 1, it is characterized in that: the content of A, B and three kinds of components of C is:
A 30.0；
B 25.5；
C 44.5；
Wherein, in weight part,
Every part of A component materials consists of the following composition:
SiO
2 ： 58；
LiCO
3： 7；
ZnO : 9；
K
2SiF
6: 10；
B
2O
3: 16；
Every part of B component materials consists of the following composition:
ZnO : 47；
B
2O
3 : 45；
MnO
2: 1；
Co
2O
3 : 4；
Al
2O
3: 2；
NiO: 1；
Every part of C component materials consists of the following composition:
Carboxymethyl cellulose: 3;
Glycerol: 3;
Water: 100.
8. a thick film circuit surface protection is characterized in that with the preparation technology of glass glaze slurry: for the preparation of such as the described thick film circuit surface protection glass glaze slurry of claim 1 to 7 any one, it is characterized in that:
Comprise following process:
1) preparation A component, B component and C component,
The detailed process that wherein prepares the A component is:
Composition and ratio according to the A component takes by weighing starting material;
Place stirrer to stir 10-20 second the starting material that take by weighing, then pack into and found vessel;
To found vessel and place melting furnace, according to 300-500
oC/ hour speed is warming up to 1000-1100
oC also is incubated 15-30 minute, obtains the glass metal of melting;
The glass metal of above-mentioned melting come out of the stove rapidly, and pouring out quenches in cooling or the filling liquid makes glass particle;
Again above-mentioned glass particle is placed disintegrating apparatus to pulverize the glass powder of wearing into 3-5 μ granularity, obtain the A component materials;
The detailed process that wherein prepares the B component is:
Composition and ratio according to the B component takes by weighing starting material;
Place the starting material that take by weighing pulverising apparatus to mix and grind 2-4 hour, produce the powder of 3-5 μ granularity, obtain the B component materials;
The detailed process that wherein prepares the C component is:
Composition and ratio according to the C component takes by weighing starting material;
Put water in vessel in heating to 50-60
oC slowly is sprinkled into gluing powder, and heat temperature raising or use immersion method is stirred well to gluing powder and fully dissolves formation glue, when the C component does not contain the glycerol starting material, namely obtains the C component materials this moment; When the C component contained the glycerol starting material, also needed to add glycerol this moment, then stirs and make the C component materials;
2) mix
Take by weighing A component, B component and C component according to the thick film circuit surface protection with the composition and ratio of glass glaze slurry, then placed the pulverising apparatus ball milling 4-8 hour, make slurry mixing fine grinding, make thick film circuit surface protection glass glaze slurry.
9. thick film circuit surface protection according to claim 8 is characterized in that with the preparation technology of glass glaze slurry:
1) preparation A component, B component and C component;
The detailed process of preparation A component is:
Composition and ratio according to the A component takes by weighing starting material;
Place stirrer to stir for 15 seconds the starting material that take by weighing, in the crucible of then packing into;
Crucible is placed melting furnace, according to 400
oC/ hour speed is warming up to 1050
oC also is incubated 20 minutes, obtains the glass metal of melting;
The glass metal of above-mentioned melting come out of the stove rapidly, and pouring out quenches in cooling or the filling liquid makes glass particle;
Again above-mentioned glass particle is placed pulverizer to pulverize the glass powder of wearing into 3-5 μ granularity, obtain the A component materials;
The detailed process that wherein prepares the B component is:
Composition and ratio according to the B component takes by weighing starting material;
Place the starting material that take by weighing ball mill to mix and grind 3 hours, produce the powder of 3-5 μ granularity, obtain the B component materials;
The detailed process that wherein prepares the C component is:
Composition and ratio according to the C component takes by weighing starting material;
Put water in vessel in heating to 55
oC slowly is sprinkled into gluing powder, and heat temperature raising or use immersion method is stirred well to gluing powder and fully dissolves formation glue, when the C component does not contain the glycerol starting material, namely obtains the C component materials this moment; When the C component contained the glycerol starting material, also needed to add glycerol this moment, then stirs and make the C component materials;
2) mix;
Take by weighing A component, B component and C component according to the thick film circuit surface protection with the composition and ratio of glass glaze slurry, then placed the ball mill ball milling 5 hours, make slurry mixing fine grinding, make thick film circuit surface protection glass glaze slurry.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106252272A (en) * | 2016-10-13 | 2016-12-21 | 珠海市华晶微电子有限公司 | The connecting process of laminate patch multilayer thick film circuit |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5298330A (en) * | 1987-08-31 | 1994-03-29 | Ferro Corporation | Thick film paste compositions for use with an aluminum nitride substrate |
| CN101062835A (en) * | 2007-05-29 | 2007-10-31 | 成都光明光电股份有限公司 | Environment-protection crown fire stone optical glass |
| CN101148322A (en) * | 2007-06-29 | 2008-03-26 | 清华大学 | Microcrystal glass sealing material used for solid oxide fuel battery and sealing method thereof |
-
2012
- 2012-10-08 CN CN201210377256.5A patent/CN102849950B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5298330A (en) * | 1987-08-31 | 1994-03-29 | Ferro Corporation | Thick film paste compositions for use with an aluminum nitride substrate |
| CN101062835A (en) * | 2007-05-29 | 2007-10-31 | 成都光明光电股份有限公司 | Environment-protection crown fire stone optical glass |
| CN101148322A (en) * | 2007-06-29 | 2008-03-26 | 清华大学 | Microcrystal glass sealing material used for solid oxide fuel battery and sealing method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106252272A (en) * | 2016-10-13 | 2016-12-21 | 珠海市华晶微电子有限公司 | The connecting process of laminate patch multilayer thick film circuit |
| CN106252272B (en) * | 2016-10-13 | 2019-01-15 | 珠海市华晶微电子有限公司 | The connecting process of laminate patch multilayer thick film circuit |
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| CN102849950B (en) | 2014-12-31 |
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