CN102766542A - Detergent containing tea saponin - Google Patents
Detergent containing tea saponin Download PDFInfo
- Publication number
- CN102766542A CN102766542A CN2012102419133A CN201210241913A CN102766542A CN 102766542 A CN102766542 A CN 102766542A CN 2012102419133 A CN2012102419133 A CN 2012102419133A CN 201210241913 A CN201210241913 A CN 201210241913A CN 102766542 A CN102766542 A CN 102766542A
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- CN
- China
- Prior art keywords
- detergent
- tea saponin
- detergency
- saponin
- ethylenedinitrilo
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000001397 quillaja saponaria molina bark Substances 0.000 title claims abstract description 31
- 229930182490 saponin Natural products 0.000 title claims abstract description 31
- 150000007949 saponins Chemical class 0.000 title claims abstract description 31
- 241001122767 Theaceae Species 0.000 title claims abstract description 27
- 239000003599 detergent Substances 0.000 title claims abstract description 23
- 239000007788 liquid Substances 0.000 claims description 12
- 239000004094 surface-active agent Substances 0.000 abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 abstract description 5
- 238000005187 foaming Methods 0.000 abstract description 5
- 235000005976 Citrus sinensis Nutrition 0.000 abstract description 4
- 240000002319 Citrus sinensis Species 0.000 abstract description 4
- 239000010502 orange oil Substances 0.000 abstract description 4
- -1 coco-glucoside Natural products 0.000 abstract description 3
- 235000019832 sodium triphosphate Nutrition 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 3
- 238000004945 emulsification Methods 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 150000003839 salts Chemical class 0.000 abstract description 2
- BDOYKFSQFYNPKF-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-(carboxymethyl)amino]acetic acid;sodium Chemical compound [Na].[Na].OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O BDOYKFSQFYNPKF-UHFFFAOYSA-N 0.000 abstract 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- 150000008051 alkyl sulfates Chemical class 0.000 abstract 1
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 abstract 1
- 229940080421 coco glucoside Drugs 0.000 abstract 1
- 239000012263 liquid product Substances 0.000 abstract 1
- 108700004121 sarkosyl Proteins 0.000 abstract 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 abstract 1
- 235000010234 sodium benzoate Nutrition 0.000 abstract 1
- 239000004299 sodium benzoate Substances 0.000 abstract 1
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 abstract 1
- 229940045885 sodium lauroyl sarcosinate Drugs 0.000 abstract 1
- 238000009736 wetting Methods 0.000 abstract 1
- 235000013616 tea Nutrition 0.000 description 23
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
- 239000013543 active substance Substances 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- 238000005406 washing Methods 0.000 description 6
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 5
- 238000005202 decontamination Methods 0.000 description 5
- 230000003588 decontaminative effect Effects 0.000 description 5
- 150000008131 glucosides Chemical class 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 230000007613 environmental effect Effects 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 235000019198 oils Nutrition 0.000 description 4
- 150000007524 organic acids Chemical class 0.000 description 4
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- TWCMVXMQHSVIOJ-UHFFFAOYSA-N Aglycone of yadanzioside D Natural products COC(=O)C12OCC34C(CC5C(=CC(O)C(O)C5(C)C3C(O)C1O)C)OC(=O)C(OC(=O)C)C24 TWCMVXMQHSVIOJ-UHFFFAOYSA-N 0.000 description 3
- PLMKQQMDOMTZGG-UHFFFAOYSA-N Astrantiagenin E-methylester Natural products CC12CCC(O)C(C)(CO)C1CCC1(C)C2CC=C2C3CC(C)(C)CCC3(C(=O)OC)CCC21C PLMKQQMDOMTZGG-UHFFFAOYSA-N 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 3
- 230000000844 anti-bacterial effect Effects 0.000 description 3
- 238000004851 dishwashing Methods 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- 229930182478 glucoside Natural products 0.000 description 3
- PFOARMALXZGCHY-UHFFFAOYSA-N homoegonol Natural products C1=C(OC)C(OC)=CC=C1C1=CC2=CC(CCCO)=CC(OC)=C2O1 PFOARMALXZGCHY-UHFFFAOYSA-N 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- SRBFZHDQGSBBOR-IOVATXLUSA-N D-xylopyranose Chemical compound O[C@@H]1COC(O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-IOVATXLUSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 101710194948 Protein phosphatase PhpP Proteins 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 229960000583 acetic acid Drugs 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 125000002252 acyl group Chemical group 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 230000006870 function Effects 0.000 description 2
- 238000005304 joining Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 230000000638 stimulation Effects 0.000 description 2
- 230000008719 thickening Effects 0.000 description 2
- 229930182493 triterpene saponin Natural products 0.000 description 2
- WBYWAXJHAXSJNI-VOTSOKGWSA-M .beta-Phenylacrylic acid Natural products [O-]C(=O)\C=C\C1=CC=CC=C1 WBYWAXJHAXSJNI-VOTSOKGWSA-M 0.000 description 1
- VCNKUCWWHVTTBY-UHFFFAOYSA-N 18alpha-Oleanane Natural products C1CCC(C)(C)C2CCC3(C)C4(C)CCC5(C)CCC(C)(C)CC5C4CCC3C21C VCNKUCWWHVTTBY-UHFFFAOYSA-N 0.000 description 1
- MIJYXULNPSFWEK-GTOFXWBISA-N 3beta-hydroxyolean-12-en-28-oic acid Chemical compound C1C[C@H](O)C(C)(C)[C@@H]2CC[C@@]3(C)[C@]4(C)CC[C@@]5(C(O)=O)CCC(C)(C)C[C@H]5C4=CC[C@@H]3[C@]21C MIJYXULNPSFWEK-GTOFXWBISA-N 0.000 description 1
- WCKQPPQRFNHPRJ-UHFFFAOYSA-N 4-[[4-(dimethylamino)phenyl]diazenyl]benzoic acid Chemical compound C1=CC(N(C)C)=CC=C1N=NC1=CC=C(C(O)=O)C=C1 WCKQPPQRFNHPRJ-UHFFFAOYSA-N 0.000 description 1
- 244000061520 Angelica archangelica Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- WBYWAXJHAXSJNI-SREVYHEPSA-N Cinnamic acid Chemical compound OC(=O)\C=C/C1=CC=CC=C1 WBYWAXJHAXSJNI-SREVYHEPSA-N 0.000 description 1
- IAJILQKETJEXLJ-UHFFFAOYSA-N Galacturonsaeure Natural products O=CC(O)C(O)C(O)C(O)C(O)=O IAJILQKETJEXLJ-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 235000001287 Guettarda speciosa Nutrition 0.000 description 1
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 1
- 206010040880 Skin irritation Diseases 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- IAJILQKETJEXLJ-QTBDOELSSA-N aldehydo-D-glucuronic acid Chemical compound O=C[C@H](O)[C@@H](O)[C@H](O)[C@H](O)C(O)=O IAJILQKETJEXLJ-QTBDOELSSA-N 0.000 description 1
- WQZGKKKJIJFFOK-PHYPRBDBSA-N alpha-D-galactose Chemical compound OC[C@H]1O[C@H](O)[C@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-PHYPRBDBSA-N 0.000 description 1
- 230000003110 anti-inflammatory effect Effects 0.000 description 1
- 230000001139 anti-pruritic effect Effects 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 239000003908 antipruritic agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- PYMYPHUHKUWMLA-UHFFFAOYSA-N arabinose Natural products OCC(O)C(O)C(O)C=O PYMYPHUHKUWMLA-UHFFFAOYSA-N 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- SRBFZHDQGSBBOR-UHFFFAOYSA-N beta-D-Pyranose-Lyxose Natural products OC1COC(O)C(O)C1O SRBFZHDQGSBBOR-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- JFSHUTJDVKUMTJ-QHPUVITPSA-N beta-amyrin Chemical class C1C[C@H](O)C(C)(C)[C@@H]2CC[C@@]3(C)[C@]4(C)CC[C@@]5(C)CCC(C)(C)C[C@H]5C4=CC[C@@H]3[C@]21C JFSHUTJDVKUMTJ-QHPUVITPSA-N 0.000 description 1
- 230000004071 biological effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 1
- 235000013985 cinnamic acid Nutrition 0.000 description 1
- 229930016911 cinnamic acid Natural products 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 238000009963 fulling Methods 0.000 description 1
- AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 description 1
- 229930182830 galactose Natural products 0.000 description 1
- 239000012362 glacial acetic acid Substances 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 229940097043 glucuronic acid Drugs 0.000 description 1
- 229930182470 glycoside Natural products 0.000 description 1
- 229940093915 gynecological organic acid Drugs 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 230000002949 hemolytic effect Effects 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- SIOMFBXUIJKTMF-UHFFFAOYSA-N hypoglauterpenic acid Natural products C1CC(O)C(C)(C)C2=CCC3(C)C4(C)CCC5(C(O)=O)CCC(C)(C)CC5C4=CCC3C21C SIOMFBXUIJKTMF-UHFFFAOYSA-N 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- BPAWXSVOAOLSRP-UHFFFAOYSA-N oleanane Natural products CCCCCCCCCCCCCCCC(=O)OC1CCC2(C)C(CCC3(C)C2CC=C4C5CC(C)(C)CCC5(C)C(O)CC34C)C1(C)C BPAWXSVOAOLSRP-UHFFFAOYSA-N 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- HLBBKKJFGFRGMU-UHFFFAOYSA-M sodium formate Chemical compound [Na+].[O-]C=O HLBBKKJFGFRGMU-UHFFFAOYSA-M 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 229930185549 teaseedsaponin Natural products 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
The invention discloses detergent containing tea saponin and belongs to the technical field of daily chemical detergents. The detergent is a liquid product produced with ammonium ethoxylated alkyl sulfate, sodium lauroyl sarcosinate, ethylenedinitrilo-tetraacetic acid disodium, tea saponin, coco-glucoside, citric acid, coco amidopropyl betaine, sweet orange oil, sodium benzoate, refined salt and water according to a certain proportion by the conventional production method. The content of surfactant in the detergent reaches 18.5% which is 3.5% higher than that in national standard of China, and detergency of the detergent is increased by 50%. The ethylenedinitrilo-tetraacetic acid disodium and the tea saponin replace sodium tripolyphosphate, and accordingly the detergent is phosphorus-free, and water can be saved by more than 30%. The detergent is fine in detergency, foaming power, wetting ability, dispersibility and emulsification.
Description
Technical field
The invention belongs to the washing composition technical field of daily-use chemical industry, further is the articles for washing adaptable across productive life, is a kind of liquid detergent that contains tea saponin.
Background technology
The thirties in last century, Japanese scholar isolates saponin from the tea seed, and the sixties, physicochemical property and the separation method to tea saponin carried out more deep research.China is later to the research of tea saponin, starts from the end of the fifties in last century, and bigger progress is just arranged the eighties, realizes suitability for industrialized production.In recent years, various places are more and more paid attention to the research of tea saponin, have proposed various working method and technology and, decolouring refining to it and have also carried out more deep research.At first, tea saponin is only made emulsifying agent and is used, and over nearly 20 years, the development research progress of its surfactivity, biological activity and pharmacologically active is accelerated.But the surfactant properties of utilizing tea saponin is done the domestic and international rare report of liquid detergent.
The tradition dish washing detergent is raw material with the synthetic surfactant mainly, and they are phosphorous mostly, and existence is difficult for degraded maybe can't degrade, environment is polluted, and to skin irritation, the negative impact of the bad grade of human safety.
The progressively enhancing of Along with people's environmental consciousness, dish washing detergent development in future direction will be to be main flow with the environment-friendly and green type.Except have strong detersive power, gentle to human body safety, bactericidal properties, be prone to the function of rinsing, low residue, also should degrade easily, free from environmental pollution.The development of environment-protection type tableware washing composition is slower at home.
Summary of the invention
The objective of the invention is to overcome the weak point of prior art, a kind of strong detergency is provided, human body safety, gentle, the easy rinsing of bactericidal properties, low residue are prone to degraded, free of contamination a kind of liquid detergent that contains tea saponin.
The objective of the invention is to realize through following scheme:
A kind of liquid detergent that contains tea saponin is characterized in that being made up of the component of following weight per-cent:
Above-mentioned each component concentration percentage ratio sum equals 100%
A kind of liquid detergent that contains tea saponin is characterized in that being made up of the component of following weight per-cent:
Above-mentioned each component concentration percentage ratio sum equals 100%
The working method of above-mentioned materials of weight proportions being processed liquid detergent of the present invention is:
1, batching: take by weighing each raw material by the above-mentioned raw materials consumption;
2, feedstock fat polyoxyethylenated alcohol sodium sulfate (active matter content 70%), sodium lauroyl sareosine (active matter content 30%), YD 30 two is received (EDTA) and water adds agitator kettle, stir and be warmed up to 65-75 ℃ of stirring and dissolving;
3, add again after raw material tea saponin (active matter content 60%), cocoyl glucoside (active matter content 50%) keep 65-75 ℃ to stir; Add Hydrocerol A, and cool to 40-45 ℃;
4, joining stirrer after mixing raw material cocounut oil acyl CAB (active matter content 30%) and sweet orange oil stirs;
5, joining stirrer to benzene feedstock sodium formiate and refined salt stirs;
6, filter discharging, check, packing.
The present invention has following beneficial effect:
1, according to above prescription, surfactant content (surfactant content=active matter content * actives consumption) reaches 18.5%, improves 3.5 percentage points than national standard, and detersive power has improved 50%.YD 30 two is received (EDTA two receives) and tea saponin replaces STPP (STPP) in the prescription, and without phosphorus in the liquid detergent, water-saving rate reaches 30%; Used the cocoyl glucoside in the prescription,, can reduce the content of the tensio-active agent that is difficult to degrade though cost is increased, play the protection environment, reduce pollute, the effect of not residual, strong detergency;
2, utilize the surfactivity effect preparation liquid detergent of tea saponin, in washing composition, behind a certain proportion of tea saponin of adding, have good detersive power, foaming power, wettability, dispersiveness and emulsifying effect; Have decontamination, sterilization, anti-inflammatory, function such as antipruritic; Do not have and can produce fulling milling, the advantage that fabric can not tarnish; Have without phosphorus, easy degraded, water saving and efficient energy-saving green environment protection advantage;
3, do not adopt traditional surfactant, gentle more, cleaning, do not hinder hand; The tensio-active agent readily biodegradable that this product adopted, human body and environmental safety are high;
4, adopt sweet orange oil as perfume compound, nontoxic, harmless, environmental protection.
Embodiment
Embodiment: a kind of liquid detergent that contains tea saponin is characterized in that being made up of the component of following weight per-cent:
Above-mentioned each component concentration percentage ratio sum equals 100%
Property of raw material
1, tea saponin
Tea saponin is a type in the saponin, is a kind of glycoside compound that from the plant of theaceae seed, puts forward, and extensively is present in the various teas plants, and its basic system comprises joins machine, sugared body and organic acid.Tea saponin belongs to the pentacyclic triterpene saponin.Its aglycone of β-amyrin derivatives, basic carbon price oleanane, at present, has been isolated and identified seven kinds of tea seed saponin aglycone, four kinds of tea saponin aglycone; sugar moieties are A E glucose, xylose, galactose and glucuronic acid; organic acids include angelica acid, Ti chromic acid, acetic acid and cinnamic acid.Combining form in organic acid and the glucoside unit is that hydroxyl and the organic acid in the glucoside unit forms ester.
The tea saponin belongs to the triterpene saponin, has the general general character of saponin, and bitter, pungent stimulates nasal membrane to cause sneeze.Its highly finished product are the fine crystallization of white; The aqueous solution is dark brown, and it is acid that paramethyl red is, and is insoluble in anhydrous methanol, ethanol; Be insoluble in organic solvents such as ether, acetone, benzene, sherwood oil, be soluble in aqueous methanol, aqueous ethanol, propyl carbinol and Glacial acetic acid min. 99.5, aceticanhydride, pyridine etc.Add hydrochloric acid in the tea saponin solution, when being acidity, saponin is deposition just.Very strong latherability is arranged, have water absorbability, strong hemolytic action is arranged.
2, cocoyl glucoside
Be a kind of nonionogenic tenside of plant origin, mild low-stimulation, can also reduce other tensio-active agent simultaneously stimulates; Foam performance own, detergency ability are good; The degerming performance is good, and thickening simultaneously is good, and better with the collaborative detersive power of other tensio-active agent; Can save 20% tensio-active agent, biological degradation and human safety are good.
3, sodium lauroyl sareosine
Be to derive from natural amino-type AS, to human body and environmental friendliness, can increase the surfactant dissolves degree, foaming, detergency ability is good, and especially degerming performance is good, highly water-soluble, reduces residual, easier rinsing, skin care, antibacterial, degerming.
4, cocounut oil acyl CAB
Be amphoterics, have good decontamination, foaming, foam enhancing, thickening characteristic, reduce the stimulation of other tensio-active agent to human body skin simultaneously, degerming is functional.
5, polyoxyethylenated alcohol sodium sulfate
Be AS, soluble in water, have good decontamination, emulsification, foam performance and anti-performance of hard water, gentle washing character can injured skin.Be widely used in washing cosmetic articles for use such as shampoo, body lotion, dish washing detergent, compound soap; Be used for textile industry wetting agent, sanitising agent etc.
6, YD 30 two is received (EDTA two receives)
Be metal chelator, phosphorus-free adjuvant.The decontamination of enhanced surface promoting agent, foaming power also strengthen the system antiseptic power, and reduce mineral substance residual on tableware.
7, Hydrocerol A
Be auxiliary agent, ability regulation system pH value reduces the stimulation to skin of tensio-active agent and alkaline matter, more is prone to rinsing.
8, sweet orange oil
Be the perfume oil that derives from fruit, make the product fragrance also can decontamination outward.
Claims (2)
1. liquid detergent that contains tea saponin is characterized in that it is made up of the component of following weight per-cent:
Above-mentioned each component concentration percentage ratio sum equals 100%
2. a kind of liquid detergent that contains tea saponin according to claim 1 is characterized in that it is made up of the component of following weight per-cent:
Above-mentioned each component concentration percentage ratio sum equals 100%
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN2012102419133A CN102766542A (en) | 2012-07-09 | 2012-07-09 | Detergent containing tea saponin |
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| Application Number | Priority Date | Filing Date | Title |
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| CN2012102419133A CN102766542A (en) | 2012-07-09 | 2012-07-09 | Detergent containing tea saponin |
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| CN102766542A true CN102766542A (en) | 2012-11-07 |
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| CN2012102419133A Pending CN102766542A (en) | 2012-07-09 | 2012-07-09 | Detergent containing tea saponin |
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| CN (1) | CN102766542A (en) |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103266031A (en) * | 2013-05-24 | 2013-08-28 | 厦门格林英日化科技有限公司 | Tea stain detergent and preparation method thereof |
| CN103484265A (en) * | 2013-09-26 | 2014-01-01 | 陈理敬 | Green antibacterial efficient cleanser essence and preparation method thereof |
| CN103805345A (en) * | 2014-02-25 | 2014-05-21 | 江苏紫石化工科技有限公司 | Sodium tripolyphosphate detergent |
| CN104017661A (en) * | 2014-06-16 | 2014-09-03 | 湖南农业大学 | Tea saponin dishwashing liquid and preparation method thereof |
| CN104629929A (en) * | 2015-03-14 | 2015-05-20 | 福建春辉生物工程有限公司 | Camellia saponin natural dishwashing liquid |
| CN105419991A (en) * | 2015-11-09 | 2016-03-23 | 重庆琥珀茶油有限公司 | Face-cleansing skin-moisturizing tea oil soap |
| CN105441215A (en) * | 2015-12-16 | 2016-03-30 | 泉州市福达科技咨询有限公司 | Environmentally friendly camellia seed detergent and preparation method thereof |
| CN105950312A (en) * | 2016-05-20 | 2016-09-21 | 西安文理学院 | Fruit and vegetable pesticide residue detergent and preparation method thereof |
| CN108060028A (en) * | 2017-12-05 | 2018-05-22 | 徐云丽 | Green fruit-vegetable detergent |
| CN109576080A (en) * | 2018-12-28 | 2019-04-05 | 北京绿伞化学股份有限公司 | A kind of kitchen heavy oil dirt micro emulsion cleaning agent and preparation method thereof |
| CN110669596A (en) * | 2019-09-04 | 2020-01-10 | 张卓 | Environment-friendly heavy oil stain cleaning agent and preparation method thereof |
| CN111690474A (en) * | 2019-03-11 | 2020-09-22 | 中国科学院青岛生物能源与过程研究所 | Low-foaming tea saponin detergent and preparation method thereof |
| CN111690472A (en) * | 2020-07-15 | 2020-09-22 | 华东理工大学 | Anacardol polyoxyethylene ether borate-containing detergent based on waste liquid of amino acid surfactant production and preparation method thereof |
| CN112143581A (en) * | 2020-09-27 | 2020-12-29 | 枣庄学院 | A kind of antibacterial and antiviral natural detergent and preparation method thereof |
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| CN102010798A (en) * | 2010-11-27 | 2011-04-13 | 郴州邦尔泰苏仙油脂有限公司 | Detergent for washing tableware or vegetables and fruits by hands |
| CN102293719A (en) * | 2011-09-05 | 2011-12-28 | 郴州邦尔泰苏仙油脂有限公司 | Sanitizer |
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| CN102010798A (en) * | 2010-11-27 | 2011-04-13 | 郴州邦尔泰苏仙油脂有限公司 | Detergent for washing tableware or vegetables and fruits by hands |
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Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103266031A (en) * | 2013-05-24 | 2013-08-28 | 厦门格林英日化科技有限公司 | Tea stain detergent and preparation method thereof |
| CN103484265A (en) * | 2013-09-26 | 2014-01-01 | 陈理敬 | Green antibacterial efficient cleanser essence and preparation method thereof |
| CN103805345A (en) * | 2014-02-25 | 2014-05-21 | 江苏紫石化工科技有限公司 | Sodium tripolyphosphate detergent |
| CN104017661A (en) * | 2014-06-16 | 2014-09-03 | 湖南农业大学 | Tea saponin dishwashing liquid and preparation method thereof |
| CN104017661B (en) * | 2014-06-16 | 2015-06-17 | 湖南农业大学 | Tea saponin dishwashing liquid and preparation method thereof |
| CN104629929A (en) * | 2015-03-14 | 2015-05-20 | 福建春辉生物工程有限公司 | Camellia saponin natural dishwashing liquid |
| CN105419991B (en) * | 2015-11-09 | 2018-11-09 | 重庆琥珀茶油有限公司 | A kind of clean face skin-wetting soap of tea oil |
| CN105419991A (en) * | 2015-11-09 | 2016-03-23 | 重庆琥珀茶油有限公司 | Face-cleansing skin-moisturizing tea oil soap |
| CN105441215A (en) * | 2015-12-16 | 2016-03-30 | 泉州市福达科技咨询有限公司 | Environmentally friendly camellia seed detergent and preparation method thereof |
| CN105950312A (en) * | 2016-05-20 | 2016-09-21 | 西安文理学院 | Fruit and vegetable pesticide residue detergent and preparation method thereof |
| CN105950312B (en) * | 2016-05-20 | 2018-09-07 | 西安文理学院 | A kind of garden stuff pesticide residue cleaning agent and preparation method thereof |
| CN108060028A (en) * | 2017-12-05 | 2018-05-22 | 徐云丽 | Green fruit-vegetable detergent |
| CN109576080A (en) * | 2018-12-28 | 2019-04-05 | 北京绿伞化学股份有限公司 | A kind of kitchen heavy oil dirt micro emulsion cleaning agent and preparation method thereof |
| CN111690474A (en) * | 2019-03-11 | 2020-09-22 | 中国科学院青岛生物能源与过程研究所 | Low-foaming tea saponin detergent and preparation method thereof |
| CN110669596A (en) * | 2019-09-04 | 2020-01-10 | 张卓 | Environment-friendly heavy oil stain cleaning agent and preparation method thereof |
| CN111690472A (en) * | 2020-07-15 | 2020-09-22 | 华东理工大学 | Anacardol polyoxyethylene ether borate-containing detergent based on waste liquid of amino acid surfactant production and preparation method thereof |
| CN111690472B (en) * | 2020-07-15 | 2021-09-10 | 华东理工大学 | Anacardol polyoxyethylene ether borate-containing detergent based on waste liquid of amino acid surfactant production and preparation method thereof |
| CN112143581A (en) * | 2020-09-27 | 2020-12-29 | 枣庄学院 | A kind of antibacterial and antiviral natural detergent and preparation method thereof |
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Application publication date: 20121107 |