CN102400200A - Simple electroplating/electrodeposition device - Google Patents
Simple electroplating/electrodeposition device Download PDFInfo
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- CN102400200A CN102400200A CN2011104162552A CN201110416255A CN102400200A CN 102400200 A CN102400200 A CN 102400200A CN 2011104162552 A CN2011104162552 A CN 2011104162552A CN 201110416255 A CN201110416255 A CN 201110416255A CN 102400200 A CN102400200 A CN 102400200A
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- stainless steel
- plastic
- electrode
- salt bridge
- round tube
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- 238000004070 electrodeposition Methods 0.000 title abstract description 7
- 238000009713 electroplating Methods 0.000 title abstract description 7
- 239000004033 plastic Substances 0.000 claims abstract description 74
- 229910001220 stainless steel Inorganic materials 0.000 claims abstract description 49
- 239000010935 stainless steel Substances 0.000 claims abstract description 41
- 238000006243 chemical reaction Methods 0.000 claims abstract description 7
- 238000007747 plating Methods 0.000 claims description 24
- 210000000867 larynx Anatomy 0.000 claims description 21
- 238000005260 corrosion Methods 0.000 claims description 16
- 230000007797 corrosion Effects 0.000 claims description 16
- 238000009434 installation Methods 0.000 claims description 11
- 239000003292 glue Substances 0.000 claims description 9
- 230000008859 change Effects 0.000 claims description 8
- 230000001681 protective effect Effects 0.000 claims description 8
- 239000000853 adhesive Substances 0.000 claims description 6
- 230000001070 adhesive effect Effects 0.000 claims description 6
- 238000009826 distribution Methods 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 3
- 238000012423 maintenance Methods 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims description 2
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 abstract description 7
- 239000002184 metal Substances 0.000 abstract description 7
- 239000002390 adhesive tape Substances 0.000 abstract 2
- NJPPVKZQTLUDBO-UHFFFAOYSA-N novaluron Chemical compound C1=C(Cl)C(OC(F)(F)C(OC(F)(F)F)F)=CC=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F NJPPVKZQTLUDBO-UHFFFAOYSA-N 0.000 abstract 1
- 238000002474 experimental method Methods 0.000 description 14
- 238000000034 method Methods 0.000 description 13
- 230000008569 process Effects 0.000 description 9
- 238000000151 deposition Methods 0.000 description 6
- 230000008021 deposition Effects 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 230000001105 regulatory effect Effects 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 238000007789 sealing Methods 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 238000005273 aeration Methods 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000006392 deoxygenation reaction Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 238000006424 Flood reaction Methods 0.000 description 1
- 241000973497 Siphonognathus argyrophanes Species 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 230000007123 defense Effects 0.000 description 1
- 238000001978 electrochemical passivation Methods 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000003075 superhydrophobic effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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- Prostheses (AREA)
- Electroplating Methods And Accessories (AREA)
Abstract
The invention relates to a simple electroplating/electrodeposition device, which comprises a fixed pedestal and an electrode fixing device; the fixed base frame consists of a plastic circular tube, a stainless steel hose clamp and a plastic roller, wherein the stainless steel hose clamp and the plastic roller are sleeved on the plastic circular tube; waterproof adhesive tape layers are arranged among the stainless steel hose clamp, the plastic roller and the plastic circular tube, and the waterproof adhesive tape layers fix the wires laid in the grooves on the outer circumference of the plastic circular tube; the electrode fixing device consists of two stainless steel clamps fixed in the groove through stainless steel hose clamps, and the two stainless steel clamps are symmetrical and vertical to ensure that two flat electrodes fixed by the stainless steel clamps are parallel; the top of the plastic circular tube is provided with a salt bridge, the salt bridge is connected with the reference electrode, and the salt bridge extends into the solution at the bottom through a salt bridge channel inside the plastic circular tube, so that the reference electrode and the other two electrodes form a three-electrode system; the beaker serves as a reaction tank and supports the whole device at the same time; the lead is connected with an external power supply of the electrochemical workstation through the led-out metal sheet to form a loop. The device is reasonable in structure and standard in layout, and solves the problems that the electrode is unstable in fixation, difficult to disassemble, polish and clean, and the electrode area is not easy to control and the like.
Description
Technical field
The present invention relates to a kind ofly to be applied to electroplate/the simple and easy plating/electric deposition device of electrodeposition, belong to electrochemical field.
Background technology
These electrochemical techniques of plating/galvanic deposit are widely used in all trades and professions of modern society.Its important application is exactly the metal corrosion protection.Along with the quickening of process of industrialization, metallic substance is used on a large scale, and chemistry, electrochemistry or physical action take place between metal and its residing surrounding medium, causes going bad and degenerating of metal, is called metallic corrosion.The metallic corrosion problem spreads all over each department of national economy and national defense construction, and annual all have a large amount of hardwares and equipment to scrap because of corrosion.It is reported that at present China has 30% iron and steel to scrap because of corrosion every year approximately, wherein about 10% thoroughly scraps because of becoming iron rust, and nearly 1,000 ten thousand tons of the steel of therefore annual and loss are equivalent to the output of Baosteel whole year.Except the Direct Loss that corrosion causes, the indirect loss that metallic corrosion causes is often even more serious, for example polluted product, collapse, life and property loss not count enable especially that blast etc. causes.According to foreign statistic, the year loss of metallic corrosion is considerably beyond the summation of floods, fire, disaster caused by a windstorm and earthquake (MV) loss.Therefore, metallic corrosion has caused people's very big concern.Research shows, to carrying out electrochemical passivation or modify in the metallic surface, metal or various resists such as nonmetal protect quilt metal and corrosive medium to separate coverings in, are the effective ways that prevent metallic corrosion.This process will be passed through plating/electrodeposition process usually and realized.This technological great advantage is that reaction process is controlled, coating even and adhere firmly, and the alloy layer that obtains has corrosion stability, magnetic, the weldability of good physical properties, excellence and can heat-treat.It is not only through generating resist from directly blocking-up corrosion physically, can also construct in the metallic surface with the contact angle of water to reduce the contact area with environment less than 10 ° super hydrophobic surface greater than 150 °, roll angle, and then the reduction erosion levels.
Another important application of plating/galvanic deposit is to carry out decorative electroplating.Decorative electroplating is an electro-plating method of giving aesthetic appearance, and for example plastic electroplating, imitation gold plating because their costs are low, have the good effect of beautifying again, has been penetrated into industries such as artwork making, five metals production and automobile making at present.Improving constantly of Along with people's standard of living, also increasingly high to the requirement of ornamental, decorative electroplating has wide practical use.
Existing small-sized plating/electric deposition device great majority are based on cell design and form, and it has a lot of shortcomings.It not only needs the reaction soln of big volume; Apparatus structure is complicated, not easy to operate, and electrode is fixing insecure, polishing, calcination, cleaning difficulty; Electrode area is wayward; And what relate in a lot of processes all is two electrode systems, and the dynamic corresponding relation that this is unfavorable for accurately studying between electrical signal such as electric current, voltage in the plating/electrodeposition process and the coating physical features also is unfavorable for meticulous production very much.
Summary of the invention
To the existing problem of present plating/electric deposition device, the present invention provides a kind of stable and effective simple and easy plating/electric deposition device.This device is a kind ofly to design based on electrochemical principle; Fixedly plate electrode such as platinized platinum, steel plate is respectively as working electrode and supporting electrode; Constitute a kind of compact construction of three-electrode system, respond well device with reference electrode again, can be applicable to electroplate, material surface processing technology and relevant theoretical investigation such as galvanic deposit.
Technical scheme of the present invention is following:
A kind of simple and easy plating/galvanic deposit experimental installation comprises stationary base mount, electrode fixing device, lead etc.; Wherein, described stationary base mount is made up of plastic round tube and cover stainless steel larynx hoop and plastic roller in the above; Be the waterproof glue belt between stainless steel larynx hoop, plastic roller and the plastic round tube, the waterproof glue belt will be laid on two lead fixed in the groove on the plastic round tube excircle; Electrode fixing device is made up of two stainless steel folders that are fixed on through stainless steel larynx hoop in the groove, and these two stainless steel folder symmetries and maintenance are vertical, to guarantee its fixed plate electrode keeping parallelism; The plastic round tube top is provided with salt bridge, and salt bridge is connected with reference electrode, and salt bridge stretches in the bottom solution through the inner salt bridge passage of plastic round tube, makes reference electrode and other two electrodes constitute three-electrode system; Lower part of electrode fixing device and stationary base mount is arranged in the beaker, and beaker serves as reaction tank, supports whole device simultaneously; Lead links to each other with the extraneous power supply of electrochemical workstation through the tinsel of drawing, and constitutes the loop.
Two groups of grooves that symmetrical distribution is arranged on the described plastic round tube excircle, and pipe length slightly is shorter than an end that contains Luggin capillary on the salt bridge.
Described two stainless steels folder symmetry, vertical fixing can guarantee two plate electrode keeping parallelisms and approaching of its clamping basically, and salt bridge one end that contains Luggin capillary reaches between two electrodes, and port points to working electrode.
Described two stainless steels folder is wrapped adhesive waterproof tape earlier with the wire bonds place, fixes with stainless steel larynx hoop again, and stainless steel larynx hoop is enclosed with rubber hose on every side, in case cause short circuit and corroded.
Described plastic member is tetrafluoroethylene material, resistance to chemical attack.
Described plastic roller external diameter is 55mm, and internal diameter is 27mm.
Described beaker is 80mL for maximum mark scale, and actual volume is the beaker of 100mL, makes to contact closely with plastic roller, creates closed environment, and device is kept vertically.
End 5mL centrifuge tube is equipped with on described salt bridge passage top, and it has lid, presses when device is idle, in case extraneous dirt gets into the salt bridge passage.
There is plastic protective sleeve said tinsel and extraneous power supply junction, to stablize connection and to prevent solution corrosion.
Said two stainless steels folder upper edge to plastic round tube upper end portion all is tied with adhesive waterproof tape, with fixing cord, and entangles plastic roller firm.
Can change the position of plastic roller on plastic round tube through the stainless steel larynx hoop that moves up and down the upper end, thereby change the area that stretches into electrode in the solution.
Working electrode of the present invention and supporting electrode symmetry are fixing; Reference electrode (like SCE) is connected through salt bridge with this device; Salt bridge inserts from the inner center-aisle of plastic round tube; Luggin capillary is connected with extraneous power supplys such as electrochemical workstations, thereby constitutes three electrode loop systems over against working electrode.This device uses with the collocation of 100mL glass beaker, not only saves solution (generally only needing 20mL), also has good sealing effectiveness.
During experiment, in beaker, pour earlier an amount of solution into, whether decision adopts the aeration deoxygenation according to the experiment needs.Plate electrode is separately fixed on two stainless steel folders of symmetrical distribution, then device is put on the beaker, plastic roller lower edge and beaker port close proximity can play certain sealing function like this.Confirm anode and cathode according to goal in research, and be connected on the extraneous power supplys such as electrochemical workstation with reference electrode (like SCE).When connecting this device, the clamp tinsel that carry with extraneous power outlets such as electrochemical workstations wraps them in the plastic protective sleeve then; In order to avoid contact with liquid on the experiment table; Corrosion clip and tinsel, normally carrying out of influence experiment can also guarantee stable the connection simultaneously.Open the lid on centrifuge tube top; An end that has Luggin capillary on the salt bridge is stretched in the solution via the inner salt bridge passage of plastic round tube; And with kapillary port subtend working electrode, salt bridge links to each other with reference electrodes such as SCEs again, has so just constituted three-electrode system.Through extraneous power supplys such as electrochemical workstations suitable parameters is set, running experiment is accomplished plating/electrodeposition process.After experiment finished, open-circuit line connected, and will install from beaker to hold up; And electrode taken off from the stainless steel clip; Press the lid on centrifuge tube top, avoid the dirt in the environment to get into the salt bridge passage, lead is wound into the middle portion of plastic roller together with plastic protective sleeve, tinsel.Reclaim the solution in the beaker or outwell, wash, to treat the usefulness of experiment next time.
Virtual electrode area in reaction can be regulated aspect following two.The one, regulate through the degree of stainless steel folder holding electrode, the 2nd, regulate through the stainless steel larynx hoop of plastic roller top.The stainless steel larynx hoop here not only plays fixing effect of twining the waterproof glue belt of lead, and can keep the upper-lower position of plastic roller.Can change the height of plastic roller on plastic round tube through moving the position of stainless steel larynx hoop, stretch into the length in the beaker, the final area that immerses the solution electrode that changes thereby change this device lower end.
This device is compact to design, and Stability Analysis of Structures is easy to operate, but the fixed electorde kind is various; Dismounting easily, convenient polishing and cleaning, electrode area is controlled; Required liquor capacity is little, is applicable to fields such as experimental study, small-scale fine chemistry industry production or artwork making, and market outlook are wide.
Description of drawings
Fig. 1 is the simple and easy plating of the present invention/electric deposition device front view;
Fig. 2 is the vertical view of Fig. 1;
Fig. 3 is the upward view of Fig. 1.
Wherein: 1. beaker, 2. stainless steel folder, 3. stainless steel larynx hoop, 4. plastic roller, 5. centrifuge tube, 6. salt bridge passage,
7. plastic round tube, 8. waterproof glue belt, 9. lead, 10. plastic protective sleeve, 11. tinsels, 12. rubber hoses, 13. is recessed
Groove.
Embodiment
Below in conjunction with accompanying drawing the making processes and the method for use of this device are done further to set forth, but protection scope of the present invention is not limited thereto.
Making processes:
1. get a segment length and be 90cm plastic round tube 7 (De24*6), four grooves 13 are arranged on its tube wall excircle, and be symmetrically distributed in twos, the top is that patty is protruding.
2. with hacksaw one 5mL plastic centrifuge tube rounded bottom is removed, polished with the round file pair cross-section again, it is filled in plastic round tube 7 tops, remained basically stable in the centrifuge tube mouth of pipe and plastic round tube 7 upper ends.
3. get two sections and respectively be the copper wire lead 9 of 30cm, their ends weld together with a tinsel 11 respectively, and put plastic protective sleeve 10, and the other end welds with stainless steel folder 2 respectively again, and tightly wraps the junction with adhesive waterproof tape.
4. two stainless steel folders 2 that connected lead are placed on 13 li of two grooves on plastic round tube 7 excircles vertically, symmetrically, the side and the groove walls that connect lead are adjacent to, and along groove 13 laying upper conductors.Earlier stainless steel is pressed from both sides 2 top leads and be fastened on plastic round tube 7, again with the stainless steel larynx hoop that is with rubber hose 12 3 fixing two stainless steels folders 2 with adhesive waterproof tape.
5. plastic roller 4 is enclosed within on the waterproof glue belt 8, the thickness of waterproof glue belt 8 is moderate, can entangle roller 4 firm just.Add a stainless steel larynx hoop 3 again in plastic roller 4 upper edges.
Method of use:
The present invention needs to use with 1 collocation of 100 mL glass beakers.During experiment, in beaker 1, pour earlier an amount of solution into, whether decision adopts the aeration deoxygenation according to the experiment needs.It is last 2 that plate electrode is separately fixed at two stainless steels folder of symmetrical distribution, then device is put on the beaker 1, and plastic roller 4 lower edges and beaker 1 port close proximity can play certain sealing function like this.Confirm anode and cathode according to goal in research, and be connected on the extraneous power supplys such as electrochemical workstation with reference electrode (like SCE).When connecting this device; The clamp tinsel 11 that will carry with extraneous power outlets such as electrochemical workstations; Then they are wrapped in the plastic protective sleeve, in order to avoid contact corrosion clip and tinsel with liquid on the experiment table; Normally carrying out of influence experiment can also guarantee stable the connection simultaneously.Open the lid on centrifuge tube 5 tops again; An end that has Luggin capillary on the salt bridge is stretched in the solution via plastic round tube 7 inner salt bridge passages 6; And with kapillary port subtend working electrode, salt bridge links to each other with reference electrodes such as SCEs again, has so just constituted three-electrode system.Through extraneous power supplys such as electrochemical workstations suitable parameters is set, running experiment is accomplished plating/electrodeposition process.After experiment finishes; Open-circuit line connects; To install and hold up, and electrode will be taken off from stainless steel clip 2, press the lid on centrifuge tube 5 tops from beaker; Avoid the dirt in the environment to get into salt bridge passage 6, lead 9 is wound into the middle portion of plastic roller 4 together with plastic protective sleeve 10, tinsel 11.Reclaim the solution in the beaker or outwell, wash, to treat the usefulness of experiment next time.
Virtual electrode area in reaction can be regulated aspect following two.The one, the degree of pressing from both sides 2 holding electrodes through stainless steel is regulated, and the 2nd, regulate through the stainless steel larynx hoop 3 of plastic roller 4 tops.The stainless steel larynx hoop 3 here not only plays fixing effect of twining the waterproof glue belt 8 of lead, and can keep the upper-lower position of plastic roller 4.Can change the height of plastic roller 4 on plastic round tube 7 through moving the position of stainless steel larynx hoop 3, stretch into the length in the beaker, the final area that immerses the solution electrode that changes thereby change this device lower end.
Claims (10)
1. simple and easy plating/galvanic deposit experimental installation is characterized in that, comprises stationary base mount, electrode fixing device, lead; Wherein, described stationary base mount is made up of plastic round tube and cover stainless steel larynx hoop and plastic roller in the above; Be the waterproof glue belt between stainless steel larynx hoop, plastic roller and the plastic round tube, the waterproof glue belt will be laid on two lead fixed in the groove on the plastic round tube excircle; Electrode fixing device is made up of two stainless steel folders that are fixed on through stainless steel larynx hoop in the groove, and these two stainless steel folder symmetries and maintenance are vertical, to guarantee its fixed two plate electrode keeping parallelisms; The plastic round tube top is provided with salt bridge, and salt bridge is connected with reference electrode, and salt bridge stretches in the bottom solution through the inner salt bridge passage of plastic round tube, makes reference electrode and other two electrodes constitute three-electrode system; Lower part of electrode fixing device and stationary base mount is arranged in the beaker, and beaker serves as reaction tank, supports whole device simultaneously; Lead links to each other with the extraneous power supply of electrochemical workstation through the tinsel of drawing, and constitutes the loop.
2. like the simple and easy plating of claim 1/galvanic deposit experimental installation, it is characterized in that, two groups of grooves of symmetrical distribution are arranged on the described plastic round tube excircle, and pipe is shorter in length than an end that contains Luggin capillary on the salt bridge.
3. like the simple and easy plating of claim 2/galvanic deposit experimental installation; It is characterized in that described two stainless steels folder symmetry, vertical fixing guarantee two plate electrode keeping parallelisms and approaching of its clamping; Salt bridge one end that contains Luggin capillary reaches between two plate electrodes, and port points to working electrode.
4. like the simple and easy plating of claim 1/galvanic deposit experimental installation; It is characterized in that described two stainless steels folder is wrapped adhesive waterproof tape earlier with the wire bonds place, fixes with stainless steel larynx hoop again; Be enclosed with rubber hose around the stainless steel larynx hoop, in case cause short circuit and corroded; Said two stainless steels folder upper edge to plastic round tube upper end portion all is tied with adhesive waterproof tape, with fixing cord, and entangles plastic roller firm.
5. like the simple and easy plating of claim 1/galvanic deposit experimental installation, it is characterized in that described plastic round tube and plastic roller are tetrafluoroethylene material, resistance to chemical attack.
6. like the simple and easy plating of claim 1/galvanic deposit experimental installation, it is characterized in that described plastic roller external diameter is 55mm, internal diameter is 27mm.
7. like the simple and easy plating of claim 1/galvanic deposit experimental installation, it is characterized in that described beaker is 80mL for maximum mark scale, actual volume is the beaker of 100mL, makes to contact closely with plastic roller, creates closed environment, and device is kept vertically.
8. like the simple and easy plating of claim 1/galvanic deposit experimental installation, it is characterized in that end 5mL centrifuge tube is equipped with on described salt bridge passage top, it has lid, presses when device is idle, in case extraneous dirt gets into the salt bridge passage.
9. like the simple and easy plating of claim 1/galvanic deposit experimental installation, it is characterized in that there is plastic protective sleeve said tinsel and extraneous power supply junction, stable connection also prevents solution corrosion.
10. like the simple and easy plating of claim 1/galvanic deposit experimental installation, it is characterized in that the said stainless steel larynx hoop that is positioned at the upper end can move up and down with the position of change plastic roller on plastic round tube, thereby change the area that stretches into electrode in the solution.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011104162552A CN102400200B (en) | 2011-12-13 | 2011-12-13 | Simple electroplating/ electro-deposition device |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011104162552A CN102400200B (en) | 2011-12-13 | 2011-12-13 | Simple electroplating/ electro-deposition device |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102400200A true CN102400200A (en) | 2012-04-04 |
| CN102400200B CN102400200B (en) | 2013-11-20 |
Family
ID=45882825
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011104162552A Expired - Fee Related CN102400200B (en) | 2011-12-13 | 2011-12-13 | Simple electroplating/ electro-deposition device |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102400200B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110395627A (en) * | 2019-07-16 | 2019-11-01 | 大连新钢液压管件有限公司 | A kind of valve rod wind |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5277785A (en) * | 1992-07-16 | 1994-01-11 | Anglen Erik S Van | Method and apparatus for depositing hard chrome coatings by brush plating |
| CN101074487A (en) * | 2007-03-29 | 2007-11-21 | 上海交通大学 | Electrochemical experimental device |
| CN201053039Y (en) * | 2007-03-29 | 2008-04-30 | 上海大学 | Electrodeposition device for preparing spherical nano-crystal nickel-iron coat |
| CN202465924U (en) * | 2011-12-13 | 2012-10-03 | 山东大学 | Simple plating/electrodeposition device |
-
2011
- 2011-12-13 CN CN2011104162552A patent/CN102400200B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5277785A (en) * | 1992-07-16 | 1994-01-11 | Anglen Erik S Van | Method and apparatus for depositing hard chrome coatings by brush plating |
| CN101074487A (en) * | 2007-03-29 | 2007-11-21 | 上海交通大学 | Electrochemical experimental device |
| CN201053039Y (en) * | 2007-03-29 | 2008-04-30 | 上海大学 | Electrodeposition device for preparing spherical nano-crystal nickel-iron coat |
| CN202465924U (en) * | 2011-12-13 | 2012-10-03 | 山东大学 | Simple plating/electrodeposition device |
Non-Patent Citations (2)
| Title |
|---|
| 《电镀与涂饰》 20040225 吴海玲编辑 中国专利信息---电镀设备与装置专辑 第59-62页 1-10 第23卷, 第1期 * |
| 吴海玲编辑: "中国专利信息———电镀设备与装置专辑", 《电镀与涂饰》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110395627A (en) * | 2019-07-16 | 2019-11-01 | 大连新钢液压管件有限公司 | A kind of valve rod wind |
| CN110395627B (en) * | 2019-07-16 | 2024-03-29 | 大连新钢液压管件有限公司 | Valve rod winding device |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102400200B (en) | 2013-11-20 |
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