CN102293212B - Weeding composition containing rimsulfuron and triazine - Google Patents
Weeding composition containing rimsulfuron and triazine Download PDFInfo
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- CN102293212B CN102293212B CN201110179967.7A CN201110179967A CN102293212B CN 102293212 B CN102293212 B CN 102293212B CN 201110179967 A CN201110179967 A CN 201110179967A CN 102293212 B CN102293212 B CN 102293212B
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- rimsulfuron
- terbutryn
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- piperazine humulone
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Abstract
The invention relates to a weeding composition containing rimsulfuron and triazine. The weeding composition contains an active component A, an active component B, auxiliaries and other excipients, wherein the active component A is rimsulfuron, and the active component B is one compound selected from metribuzin and terbutryn. The weeding composition is characterized by comprising 1-60wt% of the active component A and 1-80wt% of the active component B; the weeding composition can be prepared into a wettable pulvis, a water dispersible granule, a suspending agent, a suspend emulsion formulation and a micron emulsion for controlling corn weeds, and has characteristics of pesticide drug dose reduction, pesticide residual reduction, good environmental compatibility and safety for human and livestock.
Description
Technical field
The invention belongs to technical field of pesticide, be specifically related to a kind of Herbicidal combinations containing rimsulfuron and triazines, for control of maize field weed.
Background technology
The direction of pesticide developing was to embody efficient, low toxicity, low-residual and pollution-free in recent years.Be embodied in pursuit " three height ", (1) is safe, and this not only requires toxicity low, residual low, and nuisanceless; (2) biologically active is high; (3) selectivity is high.Therefore continue to improve the performance of current Pesticidal products, reach efficient, low toxicity, free of contamination requirement.So, select the agricultural chemicals of composite mixture just to become current first-selection and a kind of effectively approach, make the agricultural chemicals of performance complement obtain best synergistic effect by adjusting the proportioning of different agricultural chemicals.
Rimsulfuron (rimsulfuron), molecular formula: C
14h
17n
5o
7s
2, chemical name: 1-(4,6-SDM-2-yl)-3-(3-ethyl sulfenyl-2-pyridine radicals sulfenyl) urea.Rimsulfuron is the sulfonylurea herbicide kind of du pont company exploitation, has the advantages such as high selectivity, efficient, low toxicity, is a kind of important corn field herbicide.This medicine is amino acid compound inhibitor, thereby by suppressing necessary valine and the biosynthesis of isoleucine, Cell Differentiation and plant growth is stopped.Absorbed by root leaf, conduct to very soon meristematic tissue.This medicine can effectively be prevented and kill off great majority and perennial weed in corn field, also can be used for potato and tomato Tanaka.
Piperazine humulone (metribuzin), molecular formula: C
8h
14n
4oS, chemical name: 4-amino-6-tertiary butyl-4,5-dihydro-3-methyl mercapto-1,2,4-triazine-5 (4H)-one.Piperazine humulone is selective herbicide, and active ingredient is conducted to top with transpiration current by weeds Root Absorption, also can be absorbed and do in vivo limited conduction by blade.Main by suppressing the photosynthesis performance removing activity of sensitive plant, after dispenser each susceptible weeds sprout emerge unaffected, the rear blade chlorisis of emerging, last nutrition is exhausted and dead.Piperazine humulone can be used as sprouting front or sprouts post processing, prior to seeding or after planting seedling previous crops soil treatment, soil has the absorption that suitable humidity is conducive to root, if antecedent soil moisture should be after dispenser shallow mixed soil, more remarkable as seedling post processing herbicidal effect, dosage will reduce as one sees fit, otherwise can produce poisoning to broad leaf crop, due to the resistance poor stability of soybean seedling, piperazine humulone only should be sprouted pre-treatment to soybean.Weeding usefulness and the be absorbed with impact of crop on medicine on piperazine humulone of the soil organic matter and structure, if soil contains a large amount of clay soils and humus, dose will improve as one sees fit, otherwise reduces.Herbicidal effect and the crop safety of temperature to piperazine humulone also has certain influence, the regional dosage low compared with temperature that temperature is high is low, the lasting effect of piperazine humulone in soil looked weather conditions and soil types and difference, and general condition half-life is about 28 days, can not produce poisoning to succession crop.
Terbutryn (terbuthylazine), molecular formula: C
10h
16n
5cl, the special fourth amino-6-of the chloro-4-of chemical name: 2-ethylamino-1,3,5-triazines.Terbutryn is triazine herbicide, has interior absorption conduction.Before belonging to selectivity bud and post-emergence herbicide.Can be used for winter wheat, barley, jowar, sunflower, peanut, soybean, pea, potatoes and other crops field, prevent and kill off the chickweed sprouted in perennial naked barley grass, perennial ryegrass and autumn, german chamomile, opium poppy, amur foxtail, lady's-grass, green foxtail etc.
The chemical composition of each weed killer herbicide, formation and physic-chemical property are all distinguishing.Their herbicide ability and scope are also different, and some weed killer herbicide herbicide spectrum is narrower, but has one's own knack, and can eradicate other weed killer herbicide and be difficult to the weeds of eliminating.Therefore, the composite mixed important directions that also becomes domestic and international research new herbicides of weed killer herbicide, China also comparatively payes attention to aspect the mixed research of weed killer herbicide, is extensively recognized as one of important measures of rationally use of weed killer herbicide, work out a series of Herbicidal compositions, obtained greater advance.
My company is also devoted to the research and development of Herbicidal compositions.At present, have no report about rimsulfuron to the relevant composite product of piperazine humulone, terbutryn.
Summary of the invention
The object of this invention is to provide a kind of Herbicidal combinations containing rimsulfuron and triazines of control of maize field weed.
Technical scheme of the present invention is:
Containing a Herbicidal combinations for rimsulfuron and triazines, comprise active components A, active component B, auxiliary agent and other excipient surpluses.It is characterized in that: the weight percentage of active components A is 1%～60%, the weight percentage of active component B is 1%～80%, and described active components A is selected from rimsulfuron, and active component B is selected from the one in piperazine humulone, terbutryn.
Described Herbicidal combinations, is characterized in that: the weight percentage of Herbicidal combinations active components A is 1%～40%, and the weight percentage of active component B is 7%～75%.
Described Herbicidal combinations, is characterized in that: the weight percentage of rimsulfuron is 2%～25%, and the weight percentage of piperazine humulone is 15%～65%.
Described Herbicidal combinations, is characterized in that: the weight percentage of rimsulfuron is 2%～25%, and the weight percentage of terbutryn is 15%～65%.
Described Herbicidal combinations, is characterized in that: composition is made wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion.
Described Herbicidal combinations is for the application of control of maize field weed.
Described Herbicidal combinations is used for preventing and treating that knotweed, lamb's-quarters, amaranth, shepherd's purse, deaf nettle, pivot hold, kitchen garden, wild radish, charlock, chickweed, ox chickweed, corn-bind, elscholtiza, the application of green foxtail, lady's-grass, barnyard grass, wild oat, lolium temulentum, clearvers, Amaranthus retroflexus, naked barley grass, perennial ryegrass, nutgrass flatsedge.
Described Herbicidal combinations, is characterized in that: while making wetting powder, comprise following constituent content: rimsulfuron 1%～60%, active component B 1%～80%, dispersant 5%～10%, wetting agent 2%～10%, filler 8%～92%.
Effective active composition A, active component B, dispersant, wetting agent, filler are mixed, in mixed cylinder, mix, after airslide disintegrating mill is pulverized, mix again, can be made into wetting powder product of the present invention.
Described Herbicidal combinations, is characterized in that: when composition is made water dispersible granules, comprise following constituent content: rimsulfuron 1%～60%, active component B 1%～80%, dispersant 3%～12%, wetting agent 1%～8%, disintegrant 1%～10%, filler 10%～95%.
Rimsulfuron, active component B, dispersant, wetting agent, disintegrant, filler etc. are obtained to the particle diameter needing through air-flow crushing together, obtain the materials of granulating.By item quantitatively send in fluidized bed granulation dryer through granulation and dry after, can be made into water dispersible granules product of the present invention.
Described Herbicidal combinations, is characterized in that: when composition is made suspending agent, comprise following constituent content: rimsulfuron 1%～50%, active component B 1%～50%, dispersant 2%～10%, wetting agent 2%～10%, defoamer 0.1%～2%, thickener 0.1%～2%, emulsifier 0.5%～8%, deionized water add to 100%.
Dispersant, wetting agent, defoamer, thickener, antifreeze in above-mentioned batching are mixed through high speed shear, add rimsulfuron, active component B, ball milling 2～3 hours in ball mill, makes diameter of particle all below 5 μ m, can be made into suspending agent product of the present invention.
Described Herbicidal combinations, it is characterized in that: when composition is made suspension emulsion, comprise following constituent content: rimsulfuron 1%～50%, active component B 1%～50%, emulsifier 2%～12%, dispersant 2%～10%, defoamer 0.1%～2%, thickener 0.1%～2%, antifreeze 0.1%～8%, stabilizing agent 0.05%～3%, deionized water add to 100%.
Dispersant, defoamer, thickener, antifreeze, stabilizing agent in above-mentioned formulation material are mixed through high speed shear, add the former medicine of rimsulfuron, ball milling 2～3 hours in ball mill, make diameter of particle all below 5 μ m, make rimsulfuron suspending agent, then by active component B, emulsifier and various auxiliary agent with the direct emulsification of high speed agitator in suspending agent, can be made into suspension emulsion product of the present invention.
Described Herbicidal combinations, is characterized in that: when composition is made aqueous emulsion, comprise following constituent content: rimsulfuron 1%～50%, active component B 1%～50%, solvent 0%～20%, emulsifier 1%～15%, co-emulsifier 0%～8%, antifreeze 0%～10%, thickener 0.1%～2%, defoamer 0.01%～2%, deionized water are supplied surplus.
Above-mentioned formula is mixed, active ingredient, solvent, emulsifier, co-emulsifier are added together, make to be dissolved into even oil phase; Water, antifreeze, thickener, defoamer are mixed, become homogeneous water.Under high-speed stirred, water is added to oil phase, can be made into aqueous emulsion product of the present invention.
Described Herbicidal combinations, it is characterized in that: when composition is made microemulsion, comprise following constituent content: rimsulfuron 1%～50%, active component B 1%～50%, solvent 0%～20%, emulsifier 3%～20%, co-emulsifier 0%～12%, antifreeze 0%～10%, thickener 0.1%～2%, defoamer 0.01%～2%, stabilizing agent 0%～4%, deionized water is supplied surplus.
Rimsulfuron and the former medicine of active component B are dissolved in the homogenizer that solvent and cosolvent are housed; After emulsifier, stabilizing agent and antifreeze, water being joined in the homogenizer that above-mentioned solution is housed, give strong mixing and homogenize, finally obtain the as clear as crystal microemulsion product of the present invention of outward appearance.
Described dispersant is selected from alkylnaphthalene sulfonate, two (alkyl) naphthalenesulfonate formaldehyde condensation compound, naphthalene sulfonic acid-formaldehyde condensation product, aryl phenol polyoxyethylene succinate sulfonate, octylphenol polyethylene oxyethylene group ether sulfate, polycarboxylate, lignosulfonates, the phonetic formaldehyde condensation products sulphate of alkylphenol-polyethenoxy, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol-polyethenoxy is phonetic, aliphatic amine polyoxyethylene is phonetic, polyoxyethylene carboxylate, one or more during ester polyoxyethylene is phonetic.
Described wetting agent is selected from: lauryl sodium sulfate, neopelex, Nekal BX, washing powder, agriculture breast 2000
#series, sldium lauryl sulfate, wetting and penetrating agent F, wetting agent T, spaonin powder, tea are withered, one or more in silkworm excrement, soapberry powder.
Described disintegrant is selected from: one or more in bentonite, urea, ammonium sulfate, aluminium chloride, glucose.
Described emulsifier is selected from: agriculture breast 500
#(alkyl benzene calcium sulfonate), OP series phosphate (polyoxyethylene nonylphenol ether phosphate), 600
#phosphate (phenyl phenol polyoxy ethyl ether phosphate), styrene polyoxyethylene ether ammonium sulfate salt, alkyl biphenyl ether disulfonic acid magnesium salts, triethanolamine salt, agriculture breast 400
#(benzyl dimethyl phenol polyoxy ethyl ether), agriculture breast 600
#(phenyl phenol polyoxy ethyl ether), Nongru-700
#(alkylphenol-formaldehyde resin polyoxy ethyl ether), agriculture breast 36
#(phenethyl fluosite polyoxy ethyl ether), agriculture breast 1600
#(phenethyl phenol polyoxy ethyl polypropylene-base ether), ethylene oxide-propylene oxide block copolymer, OP series (polyoxyethylene nonylphenol ether), By series (castor oil polyoxyethylene ether), agriculture breast 33
#(alkylaryl polyoxyethylene polyoxypropylene ether), agriculture breast 34
#one or more in (alkylaryl polyoxyethylene poly-oxygen propylene aether), sapn series (sorbitan monostearate), tween series (sorbitan fatty acid ester APEO), EO series (fat alcohol alcohol APEO).
Described antifreeze is selected from: one or more in ethylene glycol, propane diols, glycerine, polyethylene glycol.
Described defoamer is selected from: silicone, C
8～10aliphatic alcohols, C
10～20one or more in saturated fat acids (as capric acid) and acid amides, silicone oil, silicone compound.
Described thickener is selected from: one or more in xanthans, CMC, hydroxyethylcellulose, methylcellulose, Magnesiumaluminumsilicate, polyvinyl alcohol.
Described filler is selected from: one or more in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, precipitated calcium carbonate, vegetable oil.
Wetting powder the key technical indexes of the present invention:
Water dispersible granules the key technical indexes of the present invention:
Suspending agent the key technical indexes of the present invention:
Suspension emulsion the key technical indexes of the present invention:
Aqueous emulsion the key technical indexes of the present invention:
Microemulsion the key technical indexes of the present invention:
Herbicidal combinations of the present invention compared with prior art, produces following beneficial effect:
(1) expand herbicide spectrum, improve preventive effect, and improve this season crop yield;
(2) extend the optimum period for applying fertilizer, reduce poisoning, reduce residual activity, delay the drug-fast generation of weed killer herbicide and development;
(3) knotweed to corn field, lamb's-quarters, amaranth, shepherd's purse, deaf nettle, pivot hold, kitchen garden, wild radish, charlock, chickweed, ox chickweed, corn-bind, elscholtiza, the weeds such as green foxtail, lady's-grass, barnyard grass, wild oat, lolium temulentum, clearvers, Amaranthus retroflexus, naked barley grass, perennial ryegrass, nutgrass flatsedge are remarkably productive.
Embodiment
The embodiment of the present invention is the method that adopts indoor biological activity determination and field trial to combine.First by indoor biological activity determination, the E-E after clear and definite two kinds of medicaments are composite by a certain percentage
0value, on this basis, then carries out field trial.
Test method: adopt potted plant cauline leaf facture (NY/T 1155.4-2006): at the in-built quantitative soil of polypots of high 6cm, diameter 9cm, will be for 15～20 sowings of examination target weed seed in polypots, after covering the fine earth that 0.5～1cm is thick, be placed on cultivation in greenhouse, treat that weeds grew to for 2～4 leaf phases and carry out cauline leaf spraying processing, every alms bowl spraying liquid 1mL, every processing repeats 4 times, and establishes the not contrast that is treated to containing medicament.Processing is placed in greenhouse cultivates, and the growing state of routine observation target weeds is estimated target be injured symptom and growth inhibition situation, and claimed acrial part fresh weight or strain fresh weight after 15d, evaluate the toxicity action of medicament to target weeds with form fresh weight inhibiting rate.
Investigation method:
Test is processed and is estimated target be injured symptom and growth inhibition situation after 15d, and claims acrial part fresh weight, calculates fresh weight inhibiting rate (%).
Synergy evaluation method:
Evaluate weed killer herbicide mode of application (NY/T 1155.7-2006) according to Gowing method, its formula is as follows:
E
0＝X+Y-XY/100
In formula, X is rimsulfuron fresh weight inhibiting rate to target weeds when alone with certain dosage;
Y is active component B or the fresh weight inhibiting rate to target weeds when alone with certain dosage;
E
0theoretical value to target weeds fresh weight inhibiting rate during for rimsulfuron and active component B or two kinds of pharmacy mix;
Measured value to target weeds fresh weight inhibiting rate when E is rimsulfuron and active component B or two kinds of pharmacy mix.
Evaluation criterion: work as E-E
0when > 10%, be expressed as synergistic effect, as-10%≤E-E
0≤ 10% time, be expressed as summation action, work as E-E
0when <-10%, be expressed as antagonism.
In formula: active component B is selected from following any one compound, the one in piperazine humulone, terbutryn.
Implementation of an application example one: rimsulfuron and piperazine humulone, terbutryn and mixture thereof combine the biological activity determination test report to corn field weed
Test objective: measured rimsulfuron and piperazine humulone, terbutryn and different blended combo thereof and close the herbicidal effect to kitchen garden, amur foxtail under greenhouse pot culture condition, and evaluated its synergy, for formulation development and the agriculture chemical registration field control effectiveness test of Mixed Pharmacy provide scientific basis.
For trying target: kitchen garden, amur foxtail
Test medicine: rimsulfuron (rimsulfuron) 99% former medicine; piperazine humulone (metribuzin) 95% former medicine; terbutryn (terbuthylazine) 97% former medicine, provides by Shaanxi Welch Crop Protection Co., Ltd..
Medicament configuration:
Rimsulfuron solution: accurately take the former medicine of 0.0103g 99% rimsulfuron, dissolve with 1mL cyclohexanone, add the clear water 400mL containing 0.1% agriculture breast 600#, stir, be configured to rimsulfuron 40g (a.i.)/ha solution, then with clear water be diluted to 20,10g (a.i.)/ha concentration is for subsequent use.
Piperazine humulone solution: accurately take the former medicine of 0.0802g 95% piperazine humulone, dissolve with 1mL cyclohexanone, add the clear water 400mL containing 0.1% agriculture breast 600#, stir, be configured to piperazine humulone 300g (a.i.)/ha solution, then with clear water be diluted to 200,120g (a.i.)/ha concentration is for subsequent use.
Terbutryn solution: accurately take 0.0891g 97% terbutryn, dissolve with 1mL cyclohexanone, add the clear water 400mL containing 0.1% agriculture breast 600#, stir, be configured to terbutryn 340g (a.i.)/ha solution, then with clear water be diluted to 240,160g (a.i.)/ha concentration is for subsequent use.
Blank solution: 1mL vegetable oil adds the water of 400mL 0.1% agriculture breast 600#.
Determination of activity report one
Table 1 rimsulfuron and piperazine humulone and mixture combination thereof the biological activity determination report to kitchen garden
Evaluating drug effect: rimsulfuron and piperazine humulone and mixture composition thereof to the herbicidal effect measurement result of kitchen garden in table 1.Visible, rimsulfuron and piperazine humulone show synergistic effect to kitchen garden, its E-E with 10+120,10+200,10+300,20+120,20+200,20+300,40+120,40+200 mixture composition
0value is respectively 12.05,14.54,15.11,17.24,20.37,14.19,12.44,11.24, with 40+300 mixture composition, kitchen garden is shown to addition, wherein best to the effect of kitchen garden with the mixture composition of 20+200, its E-E
0value is 20.37.
Determination of activity report two
Table 2 rimsulfuron and terbutryn and mixture combination thereof the biological activity determination report to amur foxtail
Evaluating drug effect: rimsulfuron and terbutryn and mixture composition thereof to the herbicidal effect measurement result of amur foxtail in table 2.Visible, rimsulfuron and terbutryn show synergistic effect to amur foxtail, its E-E with 10+160,10+240,10+340,20+160,20+240,20+340,40+160,40+240 mixture composition
0value is respectively 13.55,15.67,17.28,18.06,21.25,14.23,12.01,10.34, with 40+340 mixture composition, amur foxtail is shown to addition, wherein best to the effect of amur foxtail with the mixture composition of 20+240, its E-E
0value is 21.25.
Application Example two: rimsulfuron and piperazine humulone, the composite product embodiments of terbutryn.(following content is folding hundred percentage compositions)
Embodiment 1 63% rimsulfuron piperazine humulone wetting powder
Rimsulfuron 5%, piperazine humulone 58%, octylphenol polyethylene oxyethylene group ether sulfate 4.5%, silkworm excrement 3.5%, silicone 1.5%, kaolin adds to 100%, and mixture carries out air-flow crushing, makes 63% rimsulfuron piperazine humulone wetting powder.
Embodiment 2 78% rimsulfuron piperazine humulone wetting powders
Rimsulfuron 2%, piperazine humulone 76%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 3.8%, spaonin powder 2.5%, white carbon 6%, bentonite adds to 100%, and mixture carries out air-flow crushing, makes 78% rimsulfuron piperazine humulone wetting powder.
Embodiment 3 60% rimsulfuron terbutryn wetting powders
Rimsulfuron 5%, terbutryn 55%, aryl phenol polyoxyethylene succinate sulfonate 4.8%, sldium lauryl sulfate 4.2%, wetting agent T2.5%, kaolin add to 100%, mixture carries out air-flow crushing, makes 60% rimsulfuron terbutryn wetting powder.
Embodiment 4 82% rimsulfuron terbutryn wetting powders
Rimsulfuron 2%, terbutryn 80%, polycarboxylate 4.5%, neopelex 2%, wetting and penetrating agent F 2.8%, white carbon 3.8%, kaolin adds to 100%, makes 82% rimsulfuron terbutryn wetting powder.
Embodiment 5 62% rimsulfuron piperazine humulone water dispersible granules
Rimsulfuron 6%, piperazine humulone 56%, two (alkyl) naphthalenesulfonate formaldehyde condensation compound 4.5%, Nekal BX 2.8%, urea 3.6%, xanthans 1.5%, bentonite add to 100%, mix and make 62% rimsulfuron piperazine humulone water dispersible granules.
Embodiment 6 72% rimsulfuron piperazine humulone water dispersible granules
Rimsulfuron 4%, piperazine humulone 68%, wetting and penetrating agent F 6.5%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 2.6%, ammonium sulfate 3.7%, polyvinyl alcohol 4.5%, white carbon 3.7%, starch add to 100%, mix and make 72% rimsulfuron piperazine humulone water dispersible granules.
Embodiment 7 54% rimsulfuron terbutryn water dispersible granules
Rimsulfuron 6%, terbutryn 48%, aliphatic amine polyoxyethylene are phonetic 4.5%, tea is withered 4.2%, ammonium sulfate 2.5%, kaolin add to 100%, mix and make 54% rimsulfuron terbutryn water dispersible granules.
Embodiment 8 75% rimsulfuron terbutryn water dispersible granules
Rimsulfuron 4%, terbutryn 71%, lauryl sodium sulfate 3.6%, the phonetic formaldehyde condensation products sulphate 5.5% of alkylphenol-polyethenoxy, lignosulfonates 2.8%, aluminium chloride 3.4%, bentonite add to 100%, mix and make 75% rimsulfuron terbutryn water dispersible granules.
Embodiment 9 40% rimsulfuron piperazine humulone suspending agents
Rimsulfuron 5%, piperazine humulone 35%, polyoxyethylene carboxylate 4.6%, silkworm excrement 3.4%, polyvinyl alcohol 2.4%, C
8～10aliphatic alcohols 1.6%, deionized water add to 100%, mix and make 40% rimsulfuron piperazine humulone suspending agent.
Embodiment 10 44% rimsulfuron piperazine humulone suspending agents
Rimsulfuron 4%, piperazine humulone 40%, polycarboxylate 3.6%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 4.5%, silicone defoamer 1.8%, aluminium-magnesium silicate 1.2%, phenyl phenol polyoxy ethyl ether phosphate 3.4%, deionized water add to 100%, mix and make 44% rimsulfuron piperazine humulone suspending agent.
Embodiment 11 30% rimsulfuron terbutryn suspending agents
Rimsulfuron 5%, terbutryn 25%, alkylphenol-polyethenoxy are phonetic 3.7%, wetting and penetrating agent F 3.3%, C
8～10aliphatic alcohols 2.5%, sodium alginate 2.5%, deionized water add to 100%, mix and make 30% rimsulfuron terbutryn suspending agent.
Embodiment 12 49% rimsulfuron terbutryn suspending agents
Rimsulfuron 4%, terbutryn 45%, alkyl benzene sulfonate calcium salt 6.8%, pull open powder 3.5%, silicone oil 2.5%, PAA 1.5%, deionized water and add to 100%, make 49% rimsulfuron terbutryn suspending agent.
Embodiment 13 42% rimsulfuron piperazine humulone suspension emulsions
Rimsulfuron 5%, piperazine humulone 37%, lignosulfonates 6%, phenethyl phenol polyoxy ethyl polypropylene-base ether 5.6%, silicone compound 1.4%, polyethylene glycol 1.6%, ethylene glycol 2.4%, deionized water add to 100%, mix and make 42% rimsulfuron piperazine humulone suspension emulsion.
Embodiment 14 48% rimsulfuron piperazine humulone suspension emulsions
Rimsulfuron 3%, piperazine humulone 45%, octylphenol polyethylene oxyethylene group ether sulfate 4.8%, silkworm excrement 4.2%, polyvinylpyrrolidone 1.6%, agriculture breast 1600#4.2%, glycerine 1.5%, silicone oil 0.8%, deionized water add to 100%, make 48% rimsulfuron piperazine humulone suspension emulsion through mixing.
Embodiment 15 30% rimsulfuron terbutryn suspension emulsions
Rimsulfuron 4%, terbutryn 26%, polyoxyethylene carboxylate 3.2%, soapberry powder 2.8%, phenyl phenol polyoxy ethyl ether 2.2%, agriculture breast 34#3.8%, carboxymethyl cellulose 1.2%, glycerine 2%, deionized water add to 100%, mix and make 30% rimsulfuron terbutryn suspension emulsion.
Embodiment 16 39% rimsulfuron terbutryn suspension emulsions
Rimsulfuron 3%, terbutryn 36%, ester polyoxyethylene are phonetic 6%, phenyl phenol polyoxy ethyl ether 3%, AEO series 3.5%, carboxymethyl cellulose 1.5%, ethylene glycol 1.5%, deionized water add to 100%, mix and make 39% rimsulfuron terbutryn suspension emulsion.
Embodiment 17 28% rimsulfuron piperazine humulone microemulsions
Rimsulfuron 6.5%, piperazine humulone 21.5%, styrene polyoxyethylene ether ammonium sulfate salt 5.6%, ethanol 1.5%, polyethylene glycol 6.5%, silicone compound 2.4%, deionized water adds to 100%, makes 28% rimsulfuron piperazine humulone microemulsion through mixing.
Embodiment 18 40% rimsulfuron piperazine humulone microemulsions
Rimsulfuron 4%, piperazine humulone 36%, castor oil polyoxyethylene ether 6.4%, cyclohexanone 3.6%, aliphatic alcohol polyoxyvinethene phosphate 4.6%, triethylene glycol 2.5%, gelatin 1.5%, deionized water supplies 100%, mixes and makes 40% rimsulfuron piperazine humulone microemulsion.
Embodiment 19 24% rimsulfuron terbutryn microemulsions
Rimsulfuron 6%, terbutryn 18%, agriculture breast 500#4.8%, ester polyoxyethylene are phonetic 2.4%, agriculture breast 36#3.6%, 3-methyl cyclohexanol ketenes 2.8%, N, dinethylformamide 1.5%, deionized water supplies 100%, mixes and makes 24% rimsulfuron terbutryn microemulsion.
Embodiment 20 35% rimsulfuron terbutryn microemulsions
Rimsulfuron 3%, terbutryn 32%, 3-methyl cyclohexanol ketenes 3.8%, polyvinyl alcohol 3.5%, tween series 6.2%, alkylbenzenesulfonate 2.5%, acetone 1.5%, deionized water supplies 100%, makes 35% rimsulfuron terbutryn microemulsion.
Embodiment 21 40% rimsulfuron piperazine humulone aqueous emulsions
Rimsulfuron 3%, piperazine humulone 37%, ethylene oxide-propylene oxide block copolymer 2.8%, OP series 3.2%, gelatin 1.5%, glycerine 1.8%, sodium carbonate 2.5%, silicone compound 1.2%, deionized water supplies 100%, makes 40% rimsulfuron piperazine humulone aqueous emulsion.
Embodiment 22 48% rimsulfuron piperazine humulone aqueous emulsions
Rimsulfuron 4%, piperazine humulone 44%, phenethyl phenol polyethenoxy ether 3.8%, alkylbenzenesulfonate 4.2%, agriculture breast 1600#5%, glycerine 2.4%, melon glue 2.8%, silicone 0.6%, deionized water supplies 100%, makes 48% rimsulfuron piperazine humulone aqueous emulsion.
Embodiment 23 26% rimsulfuron terbutryn aqueous emulsions
Rimsulfuron 4%, terbutryn 22%, alkyl biphenyl ether disulfonic acid magnesium salts 3.6%, agriculture breast 500#3.8%, butanols 3%, glycerine 5%, C
10～20saturated fat acids 3%, deionized water adds to 100%, makes 26% rimsulfuron terbutryn aqueous emulsion.
Embodiment 24 38% rimsulfuron terbutryn aqueous emulsions
Rimsulfuron 3%, terbutryn 35%, naphthalene sulfonic acid-formaldehyde condensation product 4.2%, alkylbenzenesulfonate 3.8%,, 600# phosphate 3.4%, polyethylene glycol 3.6%, gelatin 2.5%, silicone 0.5%, deionized water supplies 100%, makes 38% rimsulfuron terbutryn aqueous emulsion.
Application Example three: rimsulfuron and piperazine humulone, terbutryn control of maize field weed field control effectiveness test
Control medicament: rimsulfuron and piperazine humulone, terbutryn complex composition, produced by Shaanxi Welch Crop Protection Co., Ltd.'s research and development.
Contrast medicament: 25% rimsulfuron water dispersible granules (commercial); 480 grams per liter piperazine humulone suspending agents (commercial); 50% terbutryn suspending agent (commercial);
If artificial weeding and clear water control treatment.
Using method: every mu be watered 30 liters after evenly cauline leaf sparge in each community.
Spraying time: in the corn 2-4 leaf phase, the weeds in field 2-4 leaf phase, carry out cauline leaf spraying 1 time.
Investigation method and drug effect are calculated:
Investigation weeds object: the weeds such as kitchen garden, knotweed, nutgrass flatsedge, amur foxtail, lady's-grass, chickweed, investigate latter 15 days, 30 days strain preventive effects to weeds and the fresh weight preventive effect of 30 days.
Visual test medicament occurs without poisoning corn.
Test of pesticide effectiveness report one
The table 3 rimsulfuron piperazine humulone built composition for preventing and controlling corn field weed test of pesticide effectiveness
As shown in Table 3, rimsulfuron and piperazine humulone are composite has good control efficiency to corn field kitchen garden, knotweed, nutgrass flatsedge, and corn is had to certain volume increase, preventive effect is better than single dose preventive effect, with contrast medicament, artificial weeding, with respect to significant difference between the rate of growth of clear water control treatment, and there is good quick-acting and lasting effect, in this test scope of medication, to corn safety.
Test of pesticide effectiveness report two
The table 4 rimsulfuron terbutryn built composition for preventing and controlling corn field weed test of pesticide effectiveness
As shown in Table 4, rimsulfuron and terbutryn are composite has good control efficiency to weeds such as corn field amur foxtail, lady's-grass, chickweeds, and corn is had to certain volume increase, preventive effect is better than single dose preventive effect, with contrast medicament, artificial weeding, with respect to significant difference between the rate of growth of clear water control treatment, and there is good quick-acting and lasting effect, in this test scope of medication, to corn safety.
Claims (5)
1. the Herbicidal combinations containing rimsulfuron and triazines, become by rimsulfuron, terbutryn, auxiliary agent and other vehicle group, it is characterized in that: the weight percentage of rimsulfuron is 1% ~ 60%, the weight percentage of terbutryn is 1% ~ 80%, and wherein the weight ratio of rimsulfuron and terbutryn is 10 ︰ 160,10 ︰ 240,10 ︰ 340,20 ︰ 160,20 ︰ 240,20 ︰ 340,40 ︰ 160,40 ︰ 240.
2. Herbicidal combinations according to claim 1, is characterized in that: the weight percentage of Herbicidal combinations rimsulfuron is 1% ~ 40%, and the weight percentage of terbutryn is 7% ~ 75%.
3. Herbicidal combinations according to claim 2, is characterized in that: the weight percentage of rimsulfuron is 2% ~ 25%, and the weight percentage of terbutryn is 15% ~ 65%.
4. Herbicidal combinations according to claim 1 is for the application of control of maize field weed.
5. application according to claim 4, is characterized in that: described weeds are that knotweed, lamb's-quarters, amaranth, shepherd's purse, deaf nettle, pivot hold, kitchen garden, wild radish, charlock, chickweed, corn-bind, elscholtiza, green foxtail, lady's-grass, barnyard grass, wild oat, lolium temulentum, clearvers, Amaranthus retroflexus, naked barley grass, perennial ryegrass or nutgrass flatsedge.
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| CN201110179967.7A CN102293212B (en) | 2011-06-29 | 2011-06-29 | Weeding composition containing rimsulfuron and triazine |
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| CN201110179967.7A CN102293212B (en) | 2011-06-29 | 2011-06-29 | Weeding composition containing rimsulfuron and triazine |
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| CN102293212B true CN102293212B (en) | 2014-06-18 |
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| WO2019135926A1 (en) * | 2018-01-03 | 2019-07-11 | Valent U.S.A. Llc | Herbicidal compositions and methods of use thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| BR102013030594B1 (en) * | 2013-11-28 | 2019-06-25 | Rotam Agrochem International Company Limited | HERBICIDAL COMPOSITIONS COMPRISING A HERBICIDE OF TRIAZINONE AND A HERBICIDE INHIBITOR OF ALS AND USES THEREOF |
| CN104285993B (en) * | 2014-09-19 | 2016-08-17 | 河南中天恒信生物化学科技有限公司 | A kind of compound herbicide containing rimsulfuron, haloxyfop-r-methyl and metribuzin and application thereof |
| CN104472523A (en) * | 2014-12-03 | 2015-04-01 | 广东中迅农科股份有限公司 | Weeding composition containing rimsulfuron, metribuzin and clethodim |
| PL3183966T3 (en) * | 2015-12-23 | 2021-11-29 | Rotam Agrochem International Co., Ltd | Method of controlling growth of als-tolerant plants |
| CN105851035B (en) * | 2016-04-30 | 2018-11-16 | 广东中迅农科股份有限公司 | It is a kind of containing rimsulfuron and metribuzin Yi Ji the Herbicidal combinations of Evil oxalic acid |
| US11684068B2 (en) * | 2018-01-03 | 2023-06-27 | Valent U.S.A., Llc | Herbicidal compositions and methods of use thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19947918A1 (en) * | 1999-10-06 | 2001-04-12 | Bayer Ag | Selective herbicides based on pyrimidine derivatives |
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19947918A1 (en) * | 1999-10-06 | 2001-04-12 | Bayer Ag | Selective herbicides based on pyrimidine derivatives |
Non-Patent Citations (3)
| Title |
|---|
| 《Broadleaf Weed Control and Potato Metribuzin, and Crop Safety with Postemergence Rimsulfuron Adjuvant Combinations》;PAMELA J. S. HUTCHINSON et al.;《Weed Technology》;20041231;第18卷(第3期);第750-756页 * |
| PAMELAJ.S.HUTCHINSONetal..《BroadleafWeedControlandPotatoMetribuzin and Crop Safety with Postemergence Rimsulfuron Adjuvant Combinations》.《Weed Technology》.2004 |
| 陈良.《宝成（bimsulfuron）、嗪草酮（metribuzin）和助剂APSA-80混用效应的研究》.《万方数据知识服务平台》.2004,摘要. * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2019135926A1 (en) * | 2018-01-03 | 2019-07-11 | Valent U.S.A. Llc | Herbicidal compositions and methods of use thereof |
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