Background technology
Cylinder sleeve is the liner of cylinder, adopts grey cast-iron, spheroidal graphite cast-iron to be prepared from usually, directly contacts with piston ring during engine operation, and behind the cylinder body casting, processing is pressed into wherein.
Because cylinder wall bears the stress that the side-thrust of gases at high pressure and piston causes, and because the thermal stress that high-temperature gas causes, cylinder jacket material must have higher structural strength and fatigue strength, to avoid cylinder-liner distortion or material premature fatigue to destroy, cylinder sleeve also must have good wearability and bite-resistant performance.In addition, the engine cylinder prepareding gap determines and affects the important parameter of engine power, exhaust gas pressure, fuel consume and fuel economy index.Cast iron, steel cylinder jacket material and aluminium piston alloy material thermophysical property compatibility are poor, are difficult to further dwindle cylinder prepareding gap, solution high power, high economy engine power technical problem that can not high-efficiency and economic.And high-volume fractional SiC particle-Al alloy composite has thermal coefficient of expansion is advantage low, that heat-conductive characteristic good, elevated temperature strength is high and wearability is good.Use the cylinder sleeve and the hypereutectic Al-Si alloy piston material thermophysical property compatibility of this material preparation good, can significantly dwindle cylinder prepareding gap, the shortcoming that can solve or overcome cast iron, steel cylinder sleeve is with not enough.
Up to the present, the preparation method of particles reiforced metal-base composition mainly contains powder metallurgic method, pressure method of impregnation and stirring casting method and (sees 5~8 pages of " modern Manufacturing Engineering " 2005 the 9th phases, " the preparation progress of particles reiforced metal-base composition ", author Cheng Xueli etc.).Wherein, PM technique, impregnation technology and spray deposition can obtain to have the composite that high-volume fractional strengthens body, but complex process, cost height, and equipment is required high.Grain volume fraction is generally below 20% in the external particle-Al alloy composite of stirring casting method preparation, and porosity is higher, and centrifugal casting technique (is seen 280~282 pages of " foundry engieering " 2008 the 2nd phases through being usually used in preparing Cast iron liner, " the automobile cylinder sleeve is produced in centrifugal casting ", author Zhou Chaomei, Xie Shengze), in forming process, change G parameter (centrifugal acceleration/acceleration of gravity) and obtain different briquetting pressures.
Above present situation shows that existing process is difficult to satisfy the needs of high volume SiC particle-Al alloy composite cylinder sleeve industrial applications, presses for the technology of preparing of the new high volume SiC particle-Al alloy composite cylinder sleeve of invention.
The specific embodiment
Below in conjunction with drawings and Examples the present invention is described in further detail.
Referring to Fig. 1 and Fig. 2.The preparation method's of SiC particle of the present invention-Al alloy composite cylinder sleeve step is as follows:
1. use stirring casting method to prepare SiC particle-Al alloy composite slurry, be heated to 700-750 ℃ of heat preservation for standby use;
2. the preheating cylindrical die is to 350-500 ℃, and the method for utilization centrifugal casting is that SiC particle-Al alloy composite slurry pours in the cylindrical die under the condition of 50-100g in the G parameter;
3. obtain the tubular foundry goods after the cooled and solidified, this foundry goods is made of near aluminium alloy ring-type band 1 two parts that do not have the SiC particle fully that are positioned near the high volume SiC particle-Al alloy composite endless belt 2 the tubular foundry goods external diameter and be positioned at the tubular foundry goods internal diameter;
4. use the method for machining to remove the aluminium alloy ring-type band 1 that is distributed near the no SiC particle of tubular foundry goods internal diameter, obtain the tubular spare that constitutes by high volume SiC particle-Al alloy composite;
5. the high volume SiC particle-Al alloy composite tubular spare that is obtained makes the cylinder sleeve part after machining, heat treatment, inboard wall of cylinder liner chemical etching.
Embodiment 1
Raw material: average grain diameter is 15.8 μ mSiC particles, and aluminium alloy is the AlSi9Mg alloy.The volume ratio of SiC particle and AlSi9Mg alloy is 10: 90.
Weigh 5.0kgAlSi9Mg alloy and 0.66kgSiC particle, the SiC particle carried out the oxidation processes of 1000 ℃ * 5h, be cooled to then 250 ℃ stand-by; Use resistance-heated furnace melting 5kgAlSi9Mg alloy, after it is carried out degasification, slagging-off and handles, it is cooled to 585 ℃, then agitator is put into melt, under the 200rpm condition, constantly stir melt, the evenly Temperature Distribution of melt; Agitator speed is adjusted to 800rpm, treat stabilization of speed after, the pretreated SiC particle of process is added in the AlSi9Mg alloy melt gradually, can obtain SiC particle-AlSi9Mg alloy composite materials semi solid slurry after stirring certain hour; Reduce mixing speed to 350rpm, heating SiC particle-AlSi9Mg alloy composite materials slurry to 700 ℃; The utilization centre spinning method is with the SiC of tundish taking-up 0.5kg
p/ Al composite material sizing agent will be heated to 700 ℃ composite material sizing agent and be poured into and be preheated in 350 ℃ of cylindrical dies under the G parameter is the condition of 50g; Can obtain the tubular foundry goods after the cooled and solidified, the foundry goods that is obtained comprises two parts, a part is SiC particle-Al alloy composite of 35% for being distributed near the tubular foundry goods external diameter mean volume fraction, and another part is near two the part formations of the aluminium alloy ring-type band that does not have the SiC particle fully that are distributed in the tubular foundry goods internal diameter; The method of utilization machining is removed the aluminium alloy ring-type band portion that is distributed near the no SiC particle of tubular foundry goods internal diameter, and acquisition is SiC particle-Al alloy composite tubular spare of 35% by mean volume fraction; SiC particle-Al alloy composite tubular the spare that is obtained carries out machining, heat treatment and to after the inboard wall of cylinder liner utilization 10%NaOH solution etching 2 minutes, makes SiC particle-AlSi9Mg cylinder sleeve part.Prepared SiC particle-Al alloy composite cylinder sleeve linear expansion coefficient is lower than 16 * 10
-6/ ℃, the coefficient of heat conduction reaches 210Wm
-1K
-1
Embodiment 2
Raw material: average grain diameter is 15.8 μ mSiC particles, and aluminium alloy is the AlSi9Mg alloy.The volume ratio of SiC particle and AlSi9Mg alloy is 15: 85.
Weigh 5.0kgAlSi9Mg alloy and 1kgSiC particle, the SiC particle carried out the oxidation processes of 1000 ℃ * 5h, be cooled to then 250 ℃ stand-by; Use resistance-heated furnace melting 5kgAlSi9Mg alloy, after it is carried out degasification, slagging-off and handles, it is cooled to 585 ℃, then agitator is put into melt, under the 200rpm condition, constantly stir melt, the evenly Temperature Distribution of melt; Agitator speed is adjusted to 800rpm, treat stabilization of speed after, the pretreated SiC particle of process is added in the AlSi9Mg alloy melt gradually, can obtain SiC particle-AlSi9Mg alloy composite materials semi solid slurry after stirring certain hour; Reduce mixing speed to 350rpm, heating SiC particle-AlSi9Mg alloy composite materials slurry to 730 ℃; The utilization centre spinning method is with the SiC of tundish taking-up 0.5kg
p/ Al composite material sizing agent, the composite material sizing agent that will be heated to 730 ℃ under the G parameter is the condition of 70g is poured in the cylindrical die that is preheated to 400 ℃; Can obtain the tubular foundry goods after the cooled and solidified, the tubular foundry goods that is obtained comprises two parts, a part is SiC particle-Al alloy composite of 45% for being distributed near the tubular foundry goods external diameter mean volume fraction, and another part is near two the part formations of the aluminium alloy ring-type band that does not have the SiC particle fully that are distributed in the tubular foundry goods internal diameter; The method of utilization machining is removed the aluminium alloy ring-type band portion that is distributed near the no SiC particle of tubular foundry goods internal diameter, and acquisition is SiC particle-Al alloy composite tubular spare of 45% by mean volume fraction; SiC particle-Al alloy composite tubular the spare that is obtained carries out machining, heat treatment and to after the inboard wall of cylinder liner utilization 10%NaOH solution etching 2 minutes, makes SiC particle-AlSi9Mg cylinder sleeve part.Prepared SiC particle-Al alloy composite cylinder sleeve linear expansion coefficient is lower than 15.5 * 10
-6/ ℃, the coefficient of heat conduction reaches 200Wm
-1K
-1
Embodiment 3
Raw material: average grain diameter is 8.7 μ mSiC particles, and aluminium alloy is the AlSi9Cu2Mg alloy.The volume ratio of SiC particle and AlSi9Mg alloy is 20: 80.
Weigh 5.0kgAlSi9Cu2Al alloy and 1.5kgSiC particle; The SiC particle is carried out the oxidation processes of 1000 ℃ * 5h, be cooled to then 250 ℃ stand-by; Use resistance-heated furnace melting AlSi9Cu2Mg alloy, after it is carried out degasification, slagging-off and handles, it is cooled to 585 ℃, then agitator is put into melt, under the 200rpm condition, constantly stir melt, the evenly Temperature Distribution of melt; Agitator speed is adjusted to 800rpm, treat stabilization of speed after, the pretreated SiC particle of process is added in the AlSi9Cu2Mg alloy melt gradually, can obtain SiC particle-AlSi9Cu2Mg alloy composite materials semi solid slurry after stirring certain hour; Reduce mixing speed to 350rpm, heating SiC particle-AlSi9Cu2Mg alloy composite materials slurry to 730 ℃; The utilization centre spinning method is with the SiC of tundish taking-up 0.5kg
p/ Al composite material sizing agent, the composite material sizing agent that will be heated to 750 ℃ under the G parameter is the condition of 80g is poured in the cylindrical die that is preheated to 450 ℃; Can obtain the tubular foundry goods after the cooled and solidified, the foundry goods that is obtained comprises two parts, a part is SiC particle-Al alloy composite of 50% for being distributed near the tubular foundry goods external diameter mean volume fraction, and another part is near two the part formations of the aluminium alloy ring-type band that does not have the SiC particle fully that are distributed in the tubular foundry goods internal diameter; The method of utilization machining is removed the aluminium alloy ring-type band portion that is distributed near the no SiC particle of tubular foundry goods internal diameter, and acquisition is SiC particle-Al alloy composite tubular spare of 50% by mean volume fraction; SiC particle-Al alloy composite tubular the spare that is obtained carries out mechanical turning, heat treatment and to after the inboard wall of cylinder liner utilization 10%NaOH solution etching 1 minute, makes SiC particle-AlSi9Cu2Mg composite cylinder sleeve part.Prepared SiC particle-Al alloy composite cylinder sleeve linear expansion coefficient is lower than 13.5 * 10
-6/ ℃, the coefficient of heat conduction reaches 190Wm
-1K
-1
Embodiment 4
Raw material: average grain diameter is 8.7 μ mSiC particles, and aluminium alloy is the AlSi9Cu2Mg alloy.The volume ratio of SiC particle and AlSi9Mg alloy is 20: 80.
Weigh 5.0kgAlSi9Cu2Al alloy and 1.5kgSiC particle; The SiC particle is carried out the oxidation processes of 1000 ℃ * 5h, be cooled to then 250 ℃ stand-by; Use resistance-heated furnace melting AlSi9Cu2Mg alloy, after it is carried out degasification, slagging-off and handles, it is cooled to 585 ℃, then agitator is put into melt, under the 200rpm condition, constantly stir melt, the evenly Temperature Distribution of melt; Agitator speed is adjusted to 800rpm, treat stabilization of speed after, the pretreated SiC particle of process is added in the AlSi9Cu2Mg alloy melt gradually, can obtain SiC particle-AlSi9Cu2Mg alloy composite materials semi solid slurry after stirring certain hour; Reduce mixing speed to 350rpm, heating SiC particle-AlSi9Cu2Mg alloy composite materials slurry to 750 ℃; The utilization centre spinning method is with the SiC of tundish taking-up 0.5kg
p/ Al composite material sizing agent, the composite material sizing agent that will be heated to 750 ℃ under the G parameter is the condition of 100g is poured in the cylindrical die that is preheated to 500 ℃; Can obtain the tubular foundry goods after the cooled and solidified, the foundry goods that is obtained comprises two parts, a part is SiC particle-Al alloy composite of 55% for being distributed near the tubular foundry goods external diameter mean volume fraction, and another part is near two the part formations of the aluminium alloy ring-type band that does not have the SiC particle fully that are distributed in the tubular foundry goods internal diameter; The method of utilization machining is removed the aluminium alloy ring-type band portion that is distributed near the no SiC particle of tubular foundry goods internal diameter, and acquisition is SiC particle-Al alloy composite tubular spare of 55% by mean volume fraction; SiC particle-Al alloy composite tubular the spare that is obtained carries out mechanical turning, heat treatment and to after the inboard wall of cylinder liner utilization 10%NaOH solution etching 1 minute, makes SiC particle-AlSi9Cu2Mg composite cylinder sleeve part.Prepared SiC particle-Al alloy composite cylinder sleeve linear expansion coefficient is lower than 10 * 10
-6/ ℃, the coefficient of heat conduction reaches 180Wm
-1K
-1
Change the mixed proportion of aluminium alloy and SiC particle in aluminium substrate alloy, the SiC particle-Al alloy composite slurry among the present invention, all can use centre spinning to prepare SiC particle-Al alloy composite cylinder sleeve.Wherein, by the SiC particle in the poly-partially composite material sizing agent of centrifugal force near the external diameter of tubular foundry goods, both obtained more the Al alloy composite of high SiC grain volume fraction, also impel the SiC uniform particles to distribute, thereby guarantee high-quality SiC particle-Al alloy composite cylinder sleeve part of obtaining; Method to inboard wall of cylinder liner utilization chemical etching can highlight the SiC particle, improves the wear-resistant ability of inner surface of cylinder liner.
Need to prove at last, above embodiment is only unrestricted in order to technical scheme of the present invention to be described, although the present invention is had been described in detail with reference to preferred embodiment, those of ordinary skill in the art is to be understood that, can make amendment or be equal to replacement technical scheme of the present invention, and not breaking away from the aim and the scope of technical solution of the present invention, it all should be encompassed in the middle of the claim scope of the present invention.