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CN101980003A - Open long-path broad-spectrum gas measurement system - Google Patents

Open long-path broad-spectrum gas measurement system Download PDF

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Publication number
CN101980003A
CN101980003A CN201010506002.XA CN201010506002A CN101980003A CN 101980003 A CN101980003 A CN 101980003A CN 201010506002 A CN201010506002 A CN 201010506002A CN 101980003 A CN101980003 A CN 101980003A
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CN
China
Prior art keywords
telescope
measurement system
spectrum
open long
optical fiber
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CN201010506002.XA
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Chinese (zh)
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CN101980003B (en
Inventor
魏永杰
陈文亮
杜振辉
徐可欣
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Hebei University of Technology
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XIANSHI OPTICAL TECHNOLOGY Co Ltd TIANJIN CITY
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Priority to CN201010506002.XA priority Critical patent/CN101980003B/en
Publication of CN101980003A publication Critical patent/CN101980003A/en
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • G01N21/31Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
    • G01N21/39Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using tunable lasers
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • G01N21/31Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • G01N21/31Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
    • G01N21/314Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry with comparison of measurements at specific and non-specific wavelengths
    • G01N2021/3155Measuring in two spectral ranges, e.g. UV and visible
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • G01N21/31Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
    • G01N21/35Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light
    • G01N21/3504Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light for analysing gases, e.g. multi-gas analysis
    • G01N2021/3513Open path with an instrumental source
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N2201/00Features of devices classified in G01N21/00
    • G01N2201/08Optical fibres; light guides

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  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Analytical Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Optics & Photonics (AREA)
  • Investigating Or Analysing Materials By Optical Means (AREA)

Abstract

The invention provides an open long-path broad-spectrum gas measurement system, which solves the problems of narrow measurement spectrum range and a few measurable gas components of the conventional open long-path broad-spectrum gas measurement system. The measurement system comprises a plurality of light sources, a multiple transceiving fiber bundle structure, a telescope and a spectrometer, wherein the light sources can be light sources capable of transmitting continuous spectrums and tunable laser, and are respectively coupled to independent transmission fiber incident ends; and the light is emitted through the public ends of the transmission fibers, is collimated through a spherical mirror in the telescope, is reflected in the original direction after the light reaches a cube-corner retroreflector on the other end of the long path of the telescope, enters the public ends of the transceiving fibers through focusing of the spherical mirror, is emitted through the independent receiving fiber exit ends, and is subjected to spectrum detection by the spectrometer. The system only requires one concave mirror inside the telescope, has a simple structure and high spectrum utilization efficiency, and can complete absorption spectrum measurement of various gases from an ultraviolet waveband to an infrared waveband.

Description

A kind of wide spectrum gas measurement system of open long light path
[technical field]:
The present invention relates to a kind of wide spectrum gas measurement system of open long light path, especially measure the monitoring system of trace gas in the air.
[background technology]:
In the gas-monitoring in atmospheric pollution, can respectively different gas employing point type instruments be sampled and analyze, but this method can only be understood the atmospheric pollution situation and the long-run average in the sampling period of sample space, monitoring point, the space-time representativeness is relatively poor, and a point type monitoring instrument generally can only be monitored a kind of gas.The gas absorption spectra measuring technique of utilizing open long light path method with its on a large scale, many components detect, the metering system of real-time online is just becoming environmental pollution monitoring continuously ideal tools.Adopt open long light path technology to monitor several pollutants simultaneously at same spectral absorption wave band, can realize complete noncontact online auto monitoring, the highly sensitive monitoring result of instrument has more representativeness than the single-point monitoring.
Open long light path method monitoring system is because the restriction of measuring method and sensitivity of spectrograph, generally be confined to adopt a kind of method and a spectrometer to measure, so the component of measurement gas is fewer, generally can only measure the gas that has characteristic absorption spectrum in some wavelength band, as monitoring CO, CO simultaneously at infrared band 2, CH 4, in ultraviolet or advance ultraviolet band and monitor O simultaneously 3, SO 2, NO 2, but above all gas generally can not all be monitored simultaneously.
[summary of the invention]:
The objective of the invention is to solve existing open long light path measuring system or point measurement instrument and can not monitor multiple gases composition and concentration and the representative relatively poor problem of point measurement instrument space-time simultaneously, a kind of wide spectrum gas measurement system of open long light path is provided.
The wide spectrum gas measurement system of a kind of open long light path of the wide spectrum of open long light path provided by the invention, comprise multiple light courcess, multi beam transmitting-receiving fiber bundle structure, telescope and spectrometer, this multi beam transmitting-receiving fiber bundle structure comprises at least two group launching fibers and the corresponding reception optical fiber of at least two groups, wherein an end is fixed together becomes transmitting-receiving optical fiber common port, the other end of launching fiber is corresponding with a light source respectively, light source can adopt the light source (as xenon lamp) that can send continuous spectrum respectively simultaneously, tunable laser, the light that light source sends is coupled to independently launching fiber incident end respectively, common port by these launching fibers penetrates, spherical reflector collimation in telescope, atmosphere by one section opening, reflected along former direction behind the prism of corner cube of the arrival telescope light path other end, focus on through spherical reflector once more and enter transmitting-receiving optical fiber common port, after independently receive the optical fiber exit end and penetrate, carry out spectral detection by spectrometer.
This system needs a concave mirror inner of telescope, and is simple in structure, spectrum utilization ratio height, and the multiple gases absorption spectrum that can finish from the ultraviolet to the infrared band is measured.
The intrafascicular transmitting-receiving optical fiber common port of above-mentioned multi beam transmitting-receiving structured optical fiber is positioned on the telescopical optical axis, and the radius of establishing spherical reflector is R, and then receiving and dispatching the optical fiber common port is 1/2R apart from the distance of spherical reflector.
Transmitting-receiving optical fiber common port in the multi beam transmitting-receiving fibre bundle can be installed on the three-dimensional mobile platform and can carry out three-dimensional adjustment.
Advantage of the present invention and good effect:
In the wide spectrum gas measurement system of open long light path provided by the invention, the fibre bundle with public port is adopted in spectrum transmitting-receiving, in the telescope only with a reflecting sphere mirror; Measure when the maximum characteristics of this system are to have realized from ultraviolet to infrared band gas characteristic absorption spectrum, and can realize light that multiple light courcess is sent, after gas absorption, measure simultaneously.Compare with existing typical open long optical distance spectrum absorptiometry system, reduced lens or reflector group, avoided light beam, improved the spectrum utilization ratio the blocking of transmission course midplane mirror; Compare with the point measurement instrument, have more the space-time representativeness.This system only needs carry out three-dimensional adjustment to multi beam transmitting-receiving fibre bundle common port, thereby has simplified instrument adjustment and centering process in adjustment and centering process.
[description of drawings]:
Fig. 1 is the wide spectrum gas measurement system structural representation of a kind of open long light path provided by the invention.
[embodiment]:
Figure 1 shows that the wide spectrum gas measurement system of a kind of open long light path provided by the invention, this system comprises pointolite (xenon lamp) 1, tunable laser source 2 (or light source of other type), telescope and the spectrometer (not drawing among the figure) that can send wide spectral composition.Wherein telescope comprises: spherical reflector 6, and the prism of corner cube 7 of the telescope light path other end.This system also comprises transmitting-receiving integrated fiber bundle structure in addition, (this routine launching fiber is two groups to this fiber bundle structure by launching fiber 10,11, also can be more) and receive optical fiber 12,13 formations, wherein an end is fixed together becomes transmitting-receiving optical fiber common port 5, this common port is positioned on the telescope optic axis, the radius of supposing spherical reflector 6 is R, then multi beam transmitting-receiving optical fiber common port is 1/2R apart from the distance of spherical reflector, and this transmitting-receiving optical fiber common port can be installed in and also can carry out the three-dimensional adjustment on the existing three-dimensional mobile platform.
During detection, by xenon lamp 1, the spectrum that tunable laser source 2 (or other light source) sends at first enters launching fiber 10 respectively after coupling, 11 incident port 3 and 4, the other end by launching fiber, promptly receiving and dispatching optical fiber common port 5 penetrates, spherical reflector 6 collimations in telescope, atmosphere by one section opening, arrive the prism of corner cube 7 of the telescope light path other end, reflected along former direction then, the reflected light that carries dusty gas information in the atmosphere returns along former direction, spherical reflector in telescope 6 focuses on and enters transmitting-receiving optical fiber common port 5 once more, after receive optical fiber 12,13 another port 8, import the pairing spectrometer of each light source after 9 outgoing respectively and carry out spectral detection.But spectrometer obtains the concentration of trace gas in the air according to the characteristic absorption spectrum inverting of gas.

Claims (3)

1. the wide spectrum gas measurement system of an open long light path, comprise multiple light courcess, multi beam transmitting-receiving fiber bundle structure, telescope and spectrometer, this multi beam transmitting-receiving fiber bundle structure comprises at least two group launching fibers and the corresponding reception optical fiber of at least two groups, wherein an end is fixed together becomes transmitting-receiving optical fiber common port, the other end of launching fiber is corresponding with a light source respectively, the light that light source sends is coupled to independently launching fiber incident end respectively, common port by these launching fibers penetrates, spherical reflector collimation in telescope, atmosphere by one section opening, reflected along former direction behind the prism of corner cube of the arrival telescope light path other end, focus on through spherical reflector once more and enter transmitting-receiving optical fiber common port, after independently receive the optical fiber exit end and penetrate, carry out spectral detection by spectrometer.
2. the wide spectrum gas measurement system of open long light path according to claim 1 is characterized in that light source can adopt the light source or the tunable laser that can send continuous spectrum respectively simultaneously.
3. the wide spectrum gas measurement system of open long light path according to claim 1 and 2 is characterized in that adopting many spectrometers, and the gas componant that adopts different spectroscopic analysis methods to finish simultaneously from the ultraviolet to the infrared band detects.
CN201010506002.XA 2010-10-14 2010-10-14 Open long-path broad-spectrum gas measurement system Expired - Fee Related CN101980003B (en)

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Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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CN101980003A true CN101980003A (en) 2011-02-23
CN101980003B CN101980003B (en) 2012-11-07

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104220863A (en) * 2012-04-14 2014-12-17 德雷格安全股份两合公司 Gas detector system
CN105629464A (en) * 2016-02-18 2016-06-01 中国科学院国家空间科学中心 Diffraction-limiting imaging pseudo star source simulation system based on single reflector
NO20150765A1 (en) * 2015-06-11 2016-12-12 Neo Monitors As Gas monitor
CN108132142A (en) * 2018-01-31 2018-06-08 中国科学院西安光学精密机械研究所 Detection device and method for large-caliber reflection optical system
CN114112963A (en) * 2021-11-30 2022-03-01 青岛崂应海纳光电环保集团有限公司 Gas telemetering telescope

Citations (6)

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Publication number Priority date Publication date Assignee Title
WO1994016311A1 (en) * 1993-01-12 1994-07-21 Pollution Monitoring Systems Ltd. Gas analyser
JP2002228582A (en) * 2001-01-30 2002-08-14 Anritsu Corp Gas detection device
CN1908623A (en) * 2005-08-02 2007-02-07 德菲电气(北京)有限公司 Multi-component infrared online gas analyzer
EP1790969A1 (en) * 2005-11-23 2007-05-30 Tyco Electronics Raychem GmbH Gas sensor array with a light channel in the form of a conical section rotational member
CN101021474A (en) * 2006-12-05 2007-08-22 中国科学院安徽光学精密机械研究所 Opening gas multi-element monitoring instrument and monitoring method
CN101435773A (en) * 2008-12-02 2009-05-20 天津大学 Gas monitoring method and apparatus based on quasi continuous diode laser modulated spectrum

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1994016311A1 (en) * 1993-01-12 1994-07-21 Pollution Monitoring Systems Ltd. Gas analyser
JP2002228582A (en) * 2001-01-30 2002-08-14 Anritsu Corp Gas detection device
CN1908623A (en) * 2005-08-02 2007-02-07 德菲电气(北京)有限公司 Multi-component infrared online gas analyzer
EP1790969A1 (en) * 2005-11-23 2007-05-30 Tyco Electronics Raychem GmbH Gas sensor array with a light channel in the form of a conical section rotational member
CN101021474A (en) * 2006-12-05 2007-08-22 中国科学院安徽光学精密机械研究所 Opening gas multi-element monitoring instrument and monitoring method
CN101435773A (en) * 2008-12-02 2009-05-20 天津大学 Gas monitoring method and apparatus based on quasi continuous diode laser modulated spectrum

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Title
《CHINESE OPTICS LETTERS》 20090510 Hikmat H. Asadov ET AL Synthesis of corrected multi-wavelength spectrometers for atmospheric trace gases 361-363 1-3 第7卷, 第5期 2 *
《传感技术学报》 20090930 张学典等 基于DOAS方法烟道污染气体在线监测系统的设计 1963-1966 1-3 第20 卷, 第9 期 2 *
《重庆工学院学报(自然科学版)》 20070331 王帅等 多组分气体检测与识别技术进展 78-81,87 1-3 第21 卷, 第3 期 2 *

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104220863A (en) * 2012-04-14 2014-12-17 德雷格安全股份两合公司 Gas detector system
CN104220863B (en) * 2012-04-14 2017-03-01 德雷格安全股份两合公司 Gas detector system
NO20150765A1 (en) * 2015-06-11 2016-12-12 Neo Monitors As Gas monitor
CN105629464A (en) * 2016-02-18 2016-06-01 中国科学院国家空间科学中心 Diffraction-limiting imaging pseudo star source simulation system based on single reflector
CN108132142A (en) * 2018-01-31 2018-06-08 中国科学院西安光学精密机械研究所 Detection device and method for large-caliber reflection optical system
CN108132142B (en) * 2018-01-31 2024-04-05 中国科学院西安光学精密机械研究所 Device and method for detecting large-caliber reflection optical system
CN114112963A (en) * 2021-11-30 2022-03-01 青岛崂应海纳光电环保集团有限公司 Gas telemetering telescope

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