CN101948302A - Totally transparent micropowder polished ceramic tile - Google Patents
Totally transparent micropowder polished ceramic tile Download PDFInfo
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- CN101948302A CN101948302A CN 201010281233 CN201010281233A CN101948302A CN 101948302 A CN101948302 A CN 101948302A CN 201010281233 CN201010281233 CN 201010281233 CN 201010281233 A CN201010281233 A CN 201010281233A CN 101948302 A CN101948302 A CN 101948302A
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- sand
- ceramic tile
- feldspar
- powder
- silica
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Abstract
The invention discloses a totally transparent micropowder polished ceramic tile which comprises the following chemical components: 66-72% of SiO2, 18-20% of Al2O3, 0.1-0.3% of Fe2O3, 0.1-0.2% of TiO2, 0.3-1.5% of CaO, 0.2-1.0% of MgO, 1.5-2.5% of K2O and 3-5% of Na2O. The tile is prepared from the following raw materials in percentage by weight: 10-20% of ball clay, 13-23% of selected sand, 20-25% of water-ground potassium feldspar powder, 27-37% water-washed soda feldspar, 15-25% of Hunan sand and 5-10% of silica. In the service process, the totally transparent micropowder polished ceramic tile has the characteristics of low water absorption rate, good anti-fouling performance, high ageing resistance, easy cleaning and maintenance, high corrosion resistance and long-term durability.
Description
Technical field
The present invention relates to a kind of building and ornament materials, particularly a kind of full impregnated micro-powdered polishing ceramic tile.
Background technology
Along with improving constantly of living standards of the people and aesthetic conceptions, share of market high-quality, multi-functional building material product increases gradually, and production development tends to diversification, personalization, fashion-orientation, environment protection healthization gradually.Natural marble had once won people's favor with its abundant colors, but its a large amount of exploitations have brought very big destruction, natural marble high specific gravity in addition to environment, to the load larrying member of the building higher requirement of having deducted a percentage itself, in addition, find most of natural stone beautiful in colour after deliberation, its radioactivity is very strong, have a strong impact on health of people, and lithotome is to form under normal pressure, and more bubble is arranged in its structure, so product impermeabilisation weak effect.Therefore, the client needs decorative effect, glossiness identical with lithotome, but radiation is low, and every performance index all are better than the product innovation of lithotome, though the polished tile of the natural-like stone that occurs on the market on decorative effect to a certain extent near lithotome, but still have a certain distance, and each enterprise constantly carries out technical renovation and exploration all the time, and expectation acquisition various aspects of performance is better, the product of lower-cost natural-like stone.
Summary of the invention
Purpose of the present invention be exactly a kind of brightness height will be provided, permeability resistance is strong, performance good, radiationless full impregnated micro-powdered polishing ceramic tile.
The present invention is achieved in that
The chemical constitution of full impregnated micro-powdered polishing ceramic tile brick face of the present invention is: SiO
266~72%, Al
2O
318~20%, Fe
2O
30.1~0.3%, TiO
20.1~0.2%, CaO 0.3~1.5%, MgO 0.2~1.0%, K
2O 1.5~2.5%, Na
2O 3~5%.
Described brick face is pressed column weight amount per-cent by following raw materials according and is made into: ball clay 10~20%, concentration sand 13~23%, water mill feldspar in powder 20~25%, washed sodium feldspar 27~37%, Hunan sand 15~25%, silica 5~10%.
In the production method of full impregnated micro-powdered polishing ceramic tile of the present invention, the face temperature in the sintering process: 1175 ℃~1180 ℃, end temperature: 1200 ℃~1210 ℃, firing period: 38~45min.
Among the present invention, concentration sand is that natural silica Sand is made through scouring, flotation, washing, classification, dioxide-containing silica in the concentration sand 〉=95%.
Full impregnated micro-powdered polishing ceramic tile of the present invention is by selecting raw material, proportioning and suitable complete processing, obtained density height, glossiness is good, stain resistance is strong ceramic tile, it in use has, and water-intake rate is low, didirtresistance good, ageing resistance cleans and maintain and have the characteristics of good corrosion resistance, durable by force, easily.
Embodiment
The present invention is raw materials used all to buy from market.
Embodiment 1
Adopting ball clay, concentration sand, water mill feldspar in powder, washed sodium feldspar, Hunan sand, silica is raw material, prepares burden in following ratio:
Ball clay 10%, concentration sand 15%, water mill feldspar in powder 20%, washed sodium feldspar 30%, Hunan sand 20%, silica 5%.
To prepare burden stirs under normal temperature, handles through ball milling, drying process with atomizing and makes mixed powder, and the chemical constitution of gained powder is by weight percentage: SiO
271.07, Al
2O
318.16, Fe
2O
30.26, TiO
20.16 CaO 0.34, MgO 0.26, K
2O 2.10, Na
2O 4.99, and IL 2.59, the micro substance of surplus for not analyzing.
In the chemical constitution of the present invention, IL is meant loss on ignition.
With the gained mixed powder, carry out granulating working procedure after crossing 90 mesh sieves, after treatment batching is pressed into the ceramic tile that specification is 800 * 800mm specification through great tonnage press, handle through drying process.At last, the blank that will cross through above-mentioned art breading is inserted kiln, 1178 ℃ of face temperature, under 1210 ℃ of conditions of end temperature, be sintered into finished product through 45min, cool to normal temperature, the product behind the kiln discharge is finished deburring, corase grind, polishing through the automatic polishing line, at last by artificial classification and packing.
The full impregnated ceramic tile performance of making through above-mentioned technology can reach: the product water-intake rate is 0.01%, and glossiness is 59, modulus of rupture 39Mpa, and performance perameter is better than common polished tile.Radioassay: construction sanitary ceramic product quality supervision and inspection station, Hebei province, assay: I (Ra) is 0.1, I (r) is 0.2, conforms to quality requirements.
Embodiment 2
Adopting ball clay, concentration sand, water mill feldspar in powder, washed sodium feldspar, Hunan sand, silica is raw material, prepares burden in following ratio:
Ball clay 20%, concentration sand 13%, water mill feldspar in powder 20%, washed sodium feldspar 27%, Hunan sand 15%, silica 5%.
To prepare burden stirs under normal temperature, handles through ball milling, drying process with atomizing and makes mixed powder, and the chemical constitution of gained powder is by weight percentage: SiO
268.95, Al
2O
319.85, Fe
2O
30.27, TiO
20.2 CaO 0.3, MgO 0.3, K
2O 2.20, Na
2O 4.29 IL 3.61, the micro substance of surplus for not analyzing.
With the gained mixed powder, carry out granulating working procedure after crossing 90 mesh sieves, after treatment batching is pressed into the ceramic tile that specification is 800 * 800mm specification through great tonnage press, handle through drying process.At last, the blank that will cross through above-mentioned art breading is inserted kiln, 1180 ℃ of face temperature, under 1200 ℃ of conditions of end temperature, be sintered into finished product through 38min, cool to normal temperature, the product behind the kiln discharge is finished deburring, corase grind, polishing through the automatic polishing line, at last by artificial classification and packing.
The full impregnated micro-powdered polishing ceramic tile performance test data of making through above-mentioned technology: the product water-intake rate is 0.01%, and glossiness is 62, modulus of rupture 39Mpa, and above-mentioned performance perameter is better than common polished tile.Radioassay: construction sanitary ceramic product quality supervision and inspection station, Hebei province, assay: I (Ra) is 0.1, I (r) is 0.2, conforms to quality requirements.
Embodiment 3
Adopting ball clay, concentration sand, water mill feldspar in powder, washed sodium feldspar, Hunan sand, silica is raw material, prepares burden in following ratio:
Ball clay 10%, concentration sand 13%, water mill feldspar in powder 20%, washed sodium feldspar 37%, Hunan sand 15%, silica 5%.
To prepare burden stirs under normal temperature, handles through ball milling, drying process with atomizing and makes mixed powder, and the chemical constitution of gained powder is by weight percentage: SiO
271.06, Al
2O
318.35, Fe
2O
30.26, TiO
20.17 CaO 0.34, MgO 0.21, K
2O 2.11, Na
2O 4.89 IL 2.53, the micro substance of surplus for not analyzing.
With the gained mixed powder, carry out granulating working procedure after crossing 90 mesh sieves, after treatment batching is pressed into the ceramic tile that specification is 800 * 800mm specification through great tonnage press, handle through drying process.At last, the blank that will cross through above-mentioned art breading is inserted kiln, 1175 ℃ of face temperature, under 1205 ℃ of conditions of end temperature, be sintered into finished product through 40min, cool to normal temperature, the product behind the kiln discharge is finished deburring, corase grind, polishing through the automatic polishing line, at last by artificial classification and packing.
The full impregnated ceramic tile performance of making through above-mentioned technology can reach: the product water-intake rate is 0.01%, and glossiness is 63, modulus of rupture 39Mpa, and performance perameter is better than common polished tile.Radioassay: construction sanitary ceramic product quality supervision and inspection station, Hebei province, assay: I (Ra) is 0.1, I (r) is 0.2, conforms to quality requirements.
Embodiment 4
Adopting ball clay, concentration sand, water mill feldspar in powder, washed sodium feldspar, Hunan sand, silica is raw material, prepares burden in following ratio:
Ball clay 10%, concentration sand 17%, water mill feldspar in powder 20%, washed sodium feldspar 28%, Hunan sand 15%, silica 10%.
To prepare burden stirs under normal temperature, handles through ball milling, drying process with atomizing and makes mixed powder, and the chemical constitution of gained powder is by weight percentage: SiO
271.54, Al
2O
318.38, Fe
2O
30.25, TiO
20.16 CaO 0.32, MgO 0.21, K
2O 2.17, Na
2O 4.38 IL 2.55, the micro substance of surplus for not analyzing.
With the gained mixed powder, carry out granulating working procedure after crossing 90 mesh sieves, after treatment batching is pressed into the ceramic tile that specification is 800 * 800mm specification through great tonnage press, handle through drying process.At last, the blank that will cross through above-mentioned art breading is inserted kiln, 1175 ℃ of face temperature, under 1205 ℃ of conditions of end temperature, be sintered into finished product through 40min, cool to normal temperature, the product behind the kiln discharge is finished deburring, corase grind, polishing through the automatic polishing line, at last by artificial classification and packing.
The full impregnated ceramic tile performance of making through above-mentioned technology can reach: the product water-intake rate is 0.01%, and glossiness is 65, modulus of rupture 39Mpa, and performance perameter is better than common polished tile.Radioassay: construction sanitary ceramic product quality supervision and inspection station, Hebei province, assay: I (Ra) is 0.1, I (r) is 0.2, conforms to quality requirements.
Embodiment 5
Adopting ball clay, concentration sand, water mill feldspar in powder, washed sodium feldspar, Hunan sand, silica is raw material, prepares burden in following ratio:
Ball clay 10%, concentration sand 23%, water mill feldspar in powder 20%, washed sodium feldspar 27%, Hunan sand 15%, silica 5%.
To prepare burden stirs under normal temperature, handles through ball milling, drying process with atomizing and makes mixed powder, and the chemical constitution of gained powder is by weight percentage: SiO
271.76, Al
2O
318.07, Fe
2O
30.26, TiO
20.16 CaO 0.31, MgO 0.21, K
2O 2.15, Na
2O 4.29 IL 2.73, the micro substance of surplus for not analyzing.
All the other technologies are with embodiment 4
The full impregnated ceramic tile performance of making through above-mentioned technology can reach: the product water-intake rate is 0.01%, and glossiness is 65, modulus of rupture 38Mpa, and performance perameter is better than common polished tile.Radioassay: construction sanitary ceramic product quality supervision and inspection station, Hebei province, assay: I (Ra) is 0.1, I (r) is 0.2, conforms to quality requirements.
Embodiment 6
Adopting ball clay, concentration sand, water mill feldspar in powder, washed sodium feldspar, Hunan sand, silica is raw material, prepares burden in following ratio:
Ball clay 10%, concentration sand 13%, water mill feldspar in powder 20%, washed sodium feldspar 27%, Hunan sand 25%, silica 5%.
To prepare burden stirs under normal temperature, handles through ball milling, drying process with atomizing and makes mixed powder, and the chemical constitution of gained powder is by weight percentage: SiO
270.71, Al
2O
318.55, Fe
2O
30.26, TiO
20.17 CaO 0.36, MgO 0.22, K
2O 2.07, Na
2O 4.99 IL 2.58, the micro substance of surplus for not analyzing.
All the other technologies are with embodiment 4
The full impregnated ceramic tile performance of making through above-mentioned technology can reach: the product water-intake rate is 0.01%, and glossiness is 62, modulus of rupture 39Mpa, and performance perameter is better than common polished tile.Radioassay: construction sanitary ceramic product quality supervision and inspection station, Hebei province, assay: I (Ra) is 0.1, I (r) is 0.2, conforms to quality requirements.
Embodiment 7
Adopting ball clay, concentration sand, water mill feldspar in powder, washed sodium feldspar, Hunan sand, silica is raw material, prepares burden in following ratio:
Ball clay 10%, concentration sand 13%, water mill feldspar in powder 25%, washed sodium feldspar 27%, Hunan sand 15%, silica 10%.
To prepare burden stirs under normal temperature, handles through ball milling, drying process with atomizing and makes mixed powder, and the chemical constitution of gained powder is by weight percentage: SiO
271.53, Al
2O
318.28, Fe
2O
30.25, TiO
20.15 CaO 0.33, MgO 0.22, K
2O 2.50, Na
2O 4.36 IL 2.32, the micro substance of surplus for not analyzing.
All the other technologies are with embodiment 4
The full impregnated ceramic tile performance of making through above-mentioned technology can reach: the product water-intake rate is 0.01%, and glossiness is 60, modulus of rupture 40Mpa, and performance perameter is better than common polished tile.Radioassay: construction sanitary ceramic product quality supervision and inspection station, Hebei province, assay: I (Ra) is 0.1, I (r) is 0.2, conforms to quality requirements.
Full impregnated micro-powdered polishing ceramic tile of the present invention, firing temperature is controlled to be: the face temperature: 1175 ℃~1180 ℃, and end temperature: 1200 ℃~1210 ℃, be lower than firing temperature (the face temperature: 1180 ℃~1185 ℃ of conventional brick, end temperature: 1210 ℃~1215 ℃) 5~10 ℃, played energy-saving and cost-reducing effect.
Claims (3)
1. a full impregnated micro-powdered polishing ceramic tile is characterized in that the chemical constitution of brick face is by weight percentage: SiO
266~72%, Al
2O
318~20%, Fe
2O
30.1~0.3%, TiO
20.1~0.2%, CaO0.3~1.5%, MgO 0.2~1.0%, K
2O 1.5~2.5%, Na
2O 3~5%.
2. full impregnated micro-powdered polishing ceramic tile according to claim 1, it is characterized in that described brick face is made into as following weight percent by following raw materials according: ball clay 10~20%, concentration sand 13~23%, water mill feldspar in powder 20~25%, washed sodium feldspar 27~37%, Hunan sand 15~25%, silica 5~10%.
3. the production method of claim 1 or 2 described full impregnated micro-powdered polishing ceramic tiles is characterized in that in its sintering process the face temperature: 1175 ℃~1180 ℃, and end temperature: 1200 ℃~1210 ℃, firing period: 38~45min.
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CN 201010281233 CN101948302B (en) | 2010-09-15 | 2010-09-15 | Totally transparent micropowder polished ceramic tile |
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CN 201010281233 CN101948302B (en) | 2010-09-15 | 2010-09-15 | Totally transparent micropowder polished ceramic tile |
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CN101948302A true CN101948302A (en) | 2011-01-19 |
CN101948302B CN101948302B (en) | 2013-06-05 |
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ID=43451952
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CN 201010281233 Expired - Fee Related CN101948302B (en) | 2010-09-15 | 2010-09-15 | Totally transparent micropowder polished ceramic tile |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102432276A (en) * | 2011-09-13 | 2012-05-02 | 苏州市亨文环保水业有限公司 | CaF2Application of sludge in ceramics |
CN102795846A (en) * | 2012-08-16 | 2012-11-28 | 广东宏陶陶瓷有限公司 | Formula of thin micro-powder polished tile |
CN108358601A (en) * | 2018-02-27 | 2018-08-03 | 合肥雅克丽新型建材有限公司 | Full-transparent polished ceramic tile and preparation method thereof |
CN110483010A (en) * | 2019-08-21 | 2019-11-22 | 蒙娜丽莎集团股份有限公司 | A kind of processability is good, high-strength large size ceramic plate and preparation method thereof |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101723652A (en) * | 2008-10-20 | 2010-06-09 | 林柱权 | Novel energy-saving ceramic tile |
-
2010
- 2010-09-15 CN CN 201010281233 patent/CN101948302B/en not_active Expired - Fee Related
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101723652A (en) * | 2008-10-20 | 2010-06-09 | 林柱权 | Novel energy-saving ceramic tile |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102432276A (en) * | 2011-09-13 | 2012-05-02 | 苏州市亨文环保水业有限公司 | CaF2Application of sludge in ceramics |
CN102432276B (en) * | 2011-09-13 | 2013-08-14 | 苏州市亨文环保水业有限公司 | Application of CaF2 sludge in ceramics |
CN102795846A (en) * | 2012-08-16 | 2012-11-28 | 广东宏陶陶瓷有限公司 | Formula of thin micro-powder polished tile |
CN108358601A (en) * | 2018-02-27 | 2018-08-03 | 合肥雅克丽新型建材有限公司 | Full-transparent polished ceramic tile and preparation method thereof |
CN110483010A (en) * | 2019-08-21 | 2019-11-22 | 蒙娜丽莎集团股份有限公司 | A kind of processability is good, high-strength large size ceramic plate and preparation method thereof |
CN110483010B (en) * | 2019-08-21 | 2022-10-28 | 蒙娜丽莎集团股份有限公司 | Large-size ceramic plate with good forming performance and high strength and preparation method thereof |
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CN101948302B (en) | 2013-06-05 |
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