Nothing Special   »   [go: up one dir, main page]

CN101796245B - 织物与织物叠层 - Google Patents

织物与织物叠层 Download PDF

Info

Publication number
CN101796245B
CN101796245B CN200880106549.1A CN200880106549A CN101796245B CN 101796245 B CN101796245 B CN 101796245B CN 200880106549 A CN200880106549 A CN 200880106549A CN 101796245 B CN101796245 B CN 101796245B
Authority
CN
China
Prior art keywords
fabric
yarn
fabrics
gap
barrier layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN200880106549.1A
Other languages
English (en)
Other versions
CN101796245A (zh
Inventor
W·斯图比格
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
WL Gore and Associates GmbH
Original Assignee
WL Gore and Associates GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by WL Gore and Associates GmbH filed Critical WL Gore and Associates GmbH
Publication of CN101796245A publication Critical patent/CN101796245A/zh
Application granted granted Critical
Publication of CN101796245B publication Critical patent/CN101796245B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/28—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer impregnated with or embedded in a plastic substance
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/245—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it being a foam layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/45—Oxides or hydroxides of elements of Groups 3 or 13 of the Periodic Table; Aluminates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/47—Oxides or hydroxides of elements of Groups 5 or 15 of the Periodic Table; Vanadates; Niobates; Tantalates; Arsenates; Antimonates; Bismuthates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/68—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/244—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0006—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using woven fabrics
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
    • D06N3/0022—Glass fibres
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/047—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with fluoropolymers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/128—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with silicon polymers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02—Synthetic macromolecular fibres
    • B32B2262/0276—Polyester fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/06—Vegetal fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/14—Mixture of at least two fibres made of different materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2266/00—Composition of foam
    • B32B2266/02—Organic
    • B32B2266/0214—Materials belonging to B32B27/00
    • B32B2266/0221—Vinyl resin
    • B32B2266/0235—Vinyl halide, e.g. PVC, PVDC, PVF, PVDF
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/724—Permeability to gases, adsorption
    • B32B2307/7242—Non-permeable
    • B32B2307/7244—Oxygen barrier
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/724—Permeability to gases, adsorption
    • B32B2307/7242—Non-permeable
    • B32B2307/7246—Water vapor barrier
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/726—Permeability to liquids, absorption
    • B32B2307/7265—Non-permeable
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/12—Permeability or impermeability properties
    • D06N2209/121—Permeability to gases, adsorption
    • D06N2209/123—Breathable
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/12—Permeability or impermeability properties
    • D06N2209/121—Permeability to gases, adsorption
    • D06N2209/125—Non-permeable
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/12—Permeability or impermeability properties
    • D06N2209/126—Permeability to liquids, absorption
    • D06N2209/128—Non-permeable
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00—Specially adapted uses
    • D06N2211/10—Clothing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24851—Intermediate layer is discontinuous or differential
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
    • Y10T428/249962—Void-containing component has a continuous matrix of fibers only [e.g., porous paper, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
    • Y10T428/249981—Plural void-containing components
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2139—Coating or impregnation specified as porous or permeable to a specific substance [e.g., water vapor, air, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2164—Coating or impregnation specified as water repellent
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2352—Coating or impregnation functions to soften the feel of or improve the "hand" of the fabric
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2369—Coating or impregnation improves elasticity, bendability, resiliency, flexibility, or shape retention of the fabric
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2418—Coating or impregnation increases electrical conductivity or anti-static quality
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/259—Coating or impregnation provides protection from radiation [e.g., U.V., visible light, I.R., micscheme-change-itemave, high energy particle, etc.] or heat retention thru radiation absorption
    • Y10T442/2598—Radiation reflective
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/259—Coating or impregnation provides protection from radiation [e.g., U.V., visible light, I.R., micscheme-change-itemave, high energy particle, etc.] or heat retention thru radiation absorption
    • Y10T442/2607—Radiation absorptive
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2631—Coating or impregnation provides heat or fire protection
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2631—Coating or impregnation provides heat or fire protection
    • Y10T442/2656—Antimony containing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2631—Coating or impregnation provides heat or fire protection
    • Y10T442/2664—Boron containing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2631—Coating or impregnation provides heat or fire protection
    • Y10T442/2672—Phosphorus containing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2762—Coated or impregnated natural fiber fabric [e.g., cotton, wool, silk, linen, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2861—Coated or impregnated synthetic organic fiber fabric
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2861—Coated or impregnated synthetic organic fiber fabric
    • Y10T442/2869—Coated or impregnated regenerated cellulose fiber fabric
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2861—Coated or impregnated synthetic organic fiber fabric
    • Y10T442/2885—Coated or impregnated acrylic fiber fabric
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2861—Coated or impregnated synthetic organic fiber fabric
    • Y10T442/2893—Coated or impregnated polyamide fiber fabric
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2861—Coated or impregnated synthetic organic fiber fabric
    • Y10T442/291—Coated or impregnated polyolefin fiber fabric

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Laminated Bodies (AREA)
  • Woven Fabrics (AREA)

Abstract

本发明提供了一种由吸水性降低的纱线构成的织物和织物结构。所述织物包括纱线和纱线间的间隙，纱线间的间隙的平均宽度大于100微米。至少一种纱线由多纤维构成。所述至少一种纱线包括纤维间的空穴，所述空穴中填充有聚合物材料。所述间隙保持开放，间隙大小与处理之前相同。纤维间的空穴中填充聚合物材料能够防止水分吸收进入所述空穴，从而降低所述织物的吸水性。所述聚合物材料基本上仅位于纱线空穴内并将所述纤维包埋在所述纱线的外表面之内。

Description

织物与织物叠层
技术领域
本申请涉及由高空气渗透性而吸水性降低的多纤丝纱线构成的改良织物。并且，本申请涉及包括阻挡层的织物结构，所述织物结构具有高空气渗透性或高水蒸气渗透性并且吸水性降低。
发明背景
人们需要接触水后吸水能力降低的服饰织物。织物纱线可由多纤丝或切断纤维构成。这些纤维/纤丝束形式的纱线在纤维/纤丝间包括空穴。在纱线接触诸如水等液体的情况下，大多数液体芯吸进入纱线空穴内。这种芯吸过程导致织品润湿、变重并且常常非常难以干燥。
克服这种缺陷的一种可能方式是提供具有通常基于氟碳的疏水覆面的织物。但该织物在几次洗涤后即丧失其斥水性。
W.L.戈尔有限公司(W.L.Gore&Associates GmbH)的EP1264036Bl中揭示了如何处理织品使其斥水的另一种可能方式。EP1264036Bl描述了一种由纤丝构成的纱线组成的织物，该织物在纱线间具有间隙。纱线被硅酮涂层基本上完全涂覆，但硅酮涂层不能完全填充纱线间的开口/间隙。纱线表面以及纱线交叉点被硅酮完全覆盖。由于所用硅酮疏水，所以经涂覆的织品高度斥水。另一方面，纱线的完全涂覆导致织物丧失织品性质。织物的柔软织品手感不再存在，所得涂覆织物的胶粘手感并不总是需要的。
授予泰斯德克应用有限公司(Nextec Applications，Inc.)的US5,418,051A涉及一种包含硅酮聚合物组合物内涂层的柔性多孔网材。该网材可包含单纤丝、纱线、切断纤维等形式的纤维。该网材可以是织造或非织造的织物，纤维可以是任何所需的组成。该网材包含可固化的硅酮聚合物浸渍剂，该浸渍剂以薄膜、涂层或网材内包裹至少一部分网材纤维的层的形式存在。内涂层区域中的间隙大多被浸渍剂填充或栓塞。网材外表面基本上不含浸渍剂。基本上完全包裹网材纤维并形成内层的硅酮聚合物意味着，该硅酮聚合物大多位于网材内部纤维的表面部分上。基于内涂层，网材外表面的纤维未涂覆，因而能够将水芯吸到网材内。为了避免这种现象，在施加硅酮聚合物之前采用氟化合物浸渍网材。已知这种经浸渍的网材在几次洗涤后即丧失其斥水性。而且，这种具有内涂层的网材不是空气渗透性的，因为内层区域内的间隙被硅酮聚合物填充。
本发明克服了上述缺陷。
本发明的一个目的是提供一种吸水率非常低的改良织物和织物结构。
本发明的另一个目的是提供一种吸水率非常低而具有高空气渗透性的织物。
本发明的另一个目的是提供一种吸水率非常低、具有高空气渗透性和柔软织品手感的织物。
本发明的另一个目的是提供一种吸水率非常低、具有高水蒸气渗透性和防水性的织物和织物结构。
发明概述
本发明提供了如权利要求1所述的织物，如权利要求41所述的织物结构和如权利要求52所述的方法。从属权项表示所述织物和所述织物结构的实施方式。
在本发明的第一方面，提供了一种织物，该织物包括纱线和纱线间的间隙，所述纱线间的间隙的平均宽度大于100微米。至少一种纱线由多纤维构成。所述至少一种纱线具有纤维间的空穴，所述空穴填充有聚合物材料。所述间隙保持开放，间隙大小与处理之前相同。
根据本发明可处理织物本身，或者连接于阻挡层形成织物结构的织物，例如叠层形式(本发明的第六方面)。
在一个实施方式中，所有织物纱线由多纤维构成，纤维间具有被聚合物材料填充的空穴。
纤维间的空穴中填充聚合物材料能够防止水分吸收进入所述空穴。聚合物材料基本上仅位于纱线空穴内并将所述纤维包埋在所述纱线的外表面之内。因此，所述纱线外表面基本上保持不变且至少部分地不含聚合物材料。至少部分地不含聚合物材料意味着，浸渍工艺后少部分聚合物材料可保留在纱线的部分外表面上作为非常薄的层。这可形成织品手感基本不变的织物，意味着织物的织品性质/特征被保留，织物本身柔软、感觉良好、牢固夹丝且没有胶粘触感。
具有所述已填充空穴的这种纱线及各织物可防止液体芯吸进入纱线。液体仅贴附于纱线外表面而不能润湿纱线内的空穴体积。因此，织物的吸水率非常低。根据Bundesmann测试(DIN EN29865，1991)，织物的吸水性小于50%，小于40%，小于30%，小于20%或小于10%。
为确保空气渗透性和水蒸气渗透性，所选织物的纱线间具有平均宽度大于100微米的间隙，所述间隙即使在至少一种纱线的填充工艺之后仍然保持开放。在另一个实施方式中，所述间隙的平均宽度为150-250微米。间隙宽度基本不变，即使在空穴填充之后仍然保持开放。这就产生本发明织物的高空气渗透性和水蒸气渗透性。
在一个实施方式中，空气渗透性大于300l/m2/s。在另一个实施方式中，空气渗透性大于500l/m2/s，甚至大于1000l/m2/s。
而且，所述织物的化学物质径流率(chemical run-off rate)大于90%(EN-ISO6530)。
在本发明的第二方面，提供了一种织物，该织物包括纱线和纱线间的间隙，所述纱线间的间隙的平均宽度大于100微米。至少一种纱线由多纤维构成。所述至少一种纱线具有纤维间的空穴，所述空穴中填充有聚合物材料而间隙保持开放，根据随后DIN EN29865(1991)所述的10分钟Bundesmann雨水测试，所述织物的吸水率小于20%。在一个实施方式中，经处理织物的吸水性小于10%。
在本发明的第三方面，提供了一种织物，该织物包括纱线和纱线间的间隙，所述纱线间的间隙的平均宽度大于100微米。至少一种纱线由多纤维构成。所述至少一种纱线具有纤维间的空穴，所述空穴中填充有聚合物材料而间隙保持开放，根据随后DIN EN29865(1991)所述的10分钟Bundesmann雨水测试，所述织物的吸水率小于20%，所述织物的空气渗透性(EN ISO9237，1995)大于500l/m2/s。在另一个实施方式中，织物的空气渗透性大于1000l/m2/s。
在本发明的第四方面，提供了一种织物，该织物包括纱线和纱线间的间隙，所述纱线间的间隙的平均宽度大于100微米。至少一种纱线由多纤维构成。所述至少一种纱线包括纤维间的空穴，所述空穴中填充有聚合物材料。水蒸气可渗透层与所述织物的一侧相邻，可形成织物结构。水蒸气可渗透层可以是水蒸气可渗透的阻挡层或水蒸气可渗透的织品层。所述阻挡层也可以是液体不可渗透的和/或气体不可渗透的。在大多数实施方式中，阻挡层是膜或薄膜，与至少一种背衬织品层组合。
术语“水蒸气可渗透层”表示可确保水蒸气透过所述层的任何层。它可以是本文所述的织品层或阻挡层。以抗水蒸气透过性(Ret)测定的阻挡层的水蒸气渗透性小于20m2Pa/W。
本文所用术语“阻挡层”定义为在最低程度上能够阻挡空气穿透，理想状态下能够阻挡许多其他气体，例如气体化学攻击的薄膜、膜或涂层。阻挡层是空气不可渗透的和/或气体不可渗透的。如果空气渗透性小于251/m2/s，在具体的实施方式中，空气渗透性小于51/m2/s(EN ISO9237，1995)，则认为该阻挡层是空气不可渗透的。在另一个实施方式中，阻挡层在最低程度上还能阻挡液体水穿透，理想状态能够阻挡许多液体化学攻击。如果能够在至少0.13巴的压力下防止液体水透过则认为该层是液体不可渗透的。基于ISO811所述的相同条件，在本文所述阻挡层的样品上测定水透过压力。
在一个实施方式中，阻挡层包括至少一个水蒸气可渗透且空气不可渗透的膜以提供空气不可渗透而水蒸气可渗透(透气)特性。优选地，该膜也是液体不可渗透的，至少水不可渗透的。
本文采用的合适的水不可渗透且水蒸气可渗透的柔性膜在美国专利3,953,566中揭示，该专利揭示了一种多孔膨胀型聚四氟乙烯(PTFE)材料。膨胀型多孔PTFE的显微结构的特征为原纤维互连结点。如果需要，可以用疏水和/或疏油涂料涂覆膨胀型PTFE来提高水不可渗透性。
水不可渗透而水蒸气可渗透的膜也可以是微孔材料，例如高分子量微孔聚乙烯或聚丙烯，微孔聚氨酯或聚酯，或亲水整体聚合物如聚氨酯。
阻挡层与本发明织物的组合提供的衣服具有优良的舒适性并有利于防水。“衣服”表示适合穿戴的任何制品，包括鞋袜、帽子、手套、衬衣、外套、裤子等。
在本发明的第五方面，提供了一种织物，该织物包括纱线和纱线间的间隙，所述纱线间的间隙的平均宽度大于100微米。至少一种纱线由多纤维构成。所述至少一种纱线包括纤维间的空穴，所述空穴中填充有由至少一种硅酮构成的聚合物材料。由多孔膨胀型聚四氟乙烯(ePTFE)构成的水蒸气可渗透而液体水不可渗透的膜与织物一侧相邻。在一个实施方式中，采用至少一种不连续的粘合剂将该膜层压到至少一个背衬织品层上。
在本发明的第六方面，提供了一种包括至少两层的织物结构。第一层是一种织物，该织物包括纱线和纱线间的间隙，所述纱线间的间隙的平均宽度大于100微米。至少一种纱线由多纤维构成。第二层是与所述第一层的一侧相连的水蒸气可渗透的阻挡层。所述纱线包括纤维间的空穴，所述空穴中填充有聚合物材料。阻挡层也可以是液体不可渗透的和/或气体不可渗透的。采用至少一种粘合剂将这两层粘结在一起而形成织物叠层。
聚合物材料可选自下组：硅酮、非溶胀型聚氨酯、无定形全氟聚合物或其混合物。聚合物材料的粘度应非常低以通过毛细作用力芯吸到纱线空穴内。而且，低粘度可防止在织物间隙间形成闭合薄膜。
因此，在处理后间隙保持开放。填充空穴之前所采用的可能的聚合物材料的粘度小于3000mPa/s。在另一个实施方式中，聚合物材料的粘度小于2000mPa/s。在另一个实施方式中，聚合物材料的粘度小于1000mPa/s。而且，聚合物材料在液体中基本上不具有溶胀和/或溶解性质。聚合物材料可以交联或不交联。
已知的市售无定形全氟聚合物是Teflon
Figure GDA0000480363550000051
AF(杜邦公司(DuPont))、Hyflon
Figure GDA0000480363550000052
AD(索尔韦索莱克斯公司(Solvay Solexis))和Cytop(旭玻璃公司(AsahiGlass))。Teflon
Figure GDA0000480363550000054
AF是杜邦公司出品的无定形氟聚合物家族成员，由2,2-二-三氟甲基-4,5-二氟-1,3-间二氧杂环戊烯(PDD)与其他含氟单体共聚制备。目前，市售TeflonAF级是PDD和四氟乙烯(TFE)的共聚物，称为Teflon
Figure GDA0000480363550000056
AF1600和Teflon
Figure GDA0000480363550000057
AF2400。
在具体实施方式中，聚合物材料由至少一种硅酮构成。
本发明描述了一种具有较高的舒适性和保护性质的改良织物。基于纱线内填充的空穴以及纱线间的开放间隙，织物不再芯吸水，并具有非常低的吸水率，较快的再干燥过程，无冷桥(cold bridge)，雨后重量增加非常小。而且，基于开放的间隙，织物具有较高的水蒸气渗透性。
经浸渍的本发明织物还具有耐燃性和非熔化性质。非熔化性质在消防员织物应用中非常有用。折边测试(NFPA1971)证明了非熔化性质。
经浸渍的本发明织物与未处理织物相比耐燃性提高。硅酮作为填充材料可维持这种提高的耐燃性，因为所用硅酮的LOI(极限氧指数)较高。硅酮的LOI约为24-35。德国/欧洲标准DIN-EN532(1994)中描述中了确定经涂覆的织物的耐燃性的一种方法，该标准描述了一种在织品和织品材料上对火焰传播进行测定的方法。
在本发明的第七方面，提供了一种尽可能减小织物的水蒸气吸收率的方法，该方法包括以下步骤：
a)提供一种织物，该织物包括纱线和纱线间的间隙，所述间隙的平均宽度大于100微米，至少一种纱线由多纤维构成，纤维间具有空穴；
b)提供粘度小于3000mPa/s的液体聚合物材料；
c)用所述聚合物材料填充空穴而间隙保持开放。
进一步的步骤d)包括在步骤c)之后固化所述织物。也可以在步骤d)之后处理织物使其疏水。
附图简要说明
图1示出了未处理的多纤维纱线的截面图。
图2示出了未处理的多纤维纱线接触液体后的截面图。
图3示出了本发明的织物。
图4示出了经处理的本发明纱线的截面图。
图5示出了经处理的本发明纱线接触液体后的截面图。
图6示出了阻挡层连接于织物的本发明的一个实施方式。
图6A示出了本发明的一个实施方式，其中阻挡层与织品层组合。
图6B示出了本发明的一个实施方式，其中形成了包括两层叠层的织物结构。
图6C示出了本发明的一个实施方式，其中形成了包括三层叠层的织物结构。
图7示出了织物中未处理纱线截面的扫描电镜照片(SEM)。
图8以放大的比例尺示出了图7所示相同的未处理纱线截面的SEM。
图9示出了图7和8所示相同织物的经处理纱线截面的SEM。
图10以放大的比例尺示出了图9所示相同的经处理纱线截面的SEM。
图11示出了图9和10所示经处理织物表面的SEM。
图12示出了织物叠层截面的SEM。
图13以放大的比例尺示出了图12所示织物叠层截面的SEM。
具体实施方式
本发明描述了一种织物10，由于织物10中所用纱线20的斥水性提高，导致纱线20的吸水性降低。具体说，本发明描述了一种织物10，经处理能够防止由多纤维构成的至少一种纱线20的开放空穴中储存任何液体，所述织物10由所述纱线20制成。本发明尤其能够防止织物10中使用的至少一种纱线20的毛细管润湿。
吸水性表示当织物10浸没在水中保持预定的时间后织物10吸收的水量。织物10吸收的水的重量与干燥织物重量之比为吸水率。
图1示出了用于织物的典型纱线的示意性截面图，纱线本身由纤维或纤丝束50构成。
“织物”表示由纱线制成的材料。具体说，本文所用术语“织物”表示由纱线构成的片状结构(织造或非织造)，纱线间具有间隙。
本文所用术语“纱线”表示许多束状纤维、纤丝等构成的连续股，例如适用于针织、机织或以其他方式形成织物。纱线可以是许多加捻在一起的纤丝(细纱)或者许多铺置在一起而无纽捻的纤丝(零-加捻纱)。纱线包括许多缔合或相互接合的纤维，纤维间限定有空穴。纱线也可以包括单一的单纤丝。
本文所用术语“空穴”表示纱线的纤维或纤丝间的空洞空间/体积。空穴空间也可以描述为纱线内纤维间的毛细空间。通常空穴中充满空气。空穴的平均尺寸可以是0-10微米，取决于纱线内纤维/纤丝排列的紧密程度。
本文所用术语“纤维”表示长、柔韧、粘着的天然或人造螺纹样物体，例如单纤丝、切断纤维、纤丝等。纤维可视作由已知技术等方法形成的单元形式。
本文所用术语“纤丝”表示不确定长度的纤维。
本文所用术语“叠层”表示至少两个独立的层，各层通过粘合剂或其他方式粘结在一起。
本文所用术语“织物结构”表示至少与至少一个水蒸气可渗透的层相邻的织物。所述水蒸气可渗透的层可垂悬而未粘结于织物。在一个具体的实施方式中，至少一个水蒸气可渗透的层连接于织物的至少一侧。在一个具体的实施方式中，织物与包括本文所述阻挡层的叠层相邻。在另一个具体的实施方式中，织物结构是由织物和至少一个本文所述阻挡层形成的叠层。
图1所示纱线20包括许多纤维50，纱线20的单根纤维50之间具有一些空穴60。当纱线20与诸如水等液体接触时，液体首先停留在纱线20的外表面22上，然后透过纤维50之间并填充到纱线20的空穴体积内。
纱线选自：聚烯烃、聚酰胺、聚酯、再生纤维素、醋酸纤维素、人造丝、乙酸酯、芳族聚酰胺、玻璃、改性聚丙烯腈纤维、棉花、羊毛、丝、亚麻、黄麻以及它们的混合物。纱线纤维包括连续的多纤丝、切断纤维或其组合。用于形成织物的纤维未卷曲变形。在本发明的一个实施方式中，纱线包括由聚酯制成的纤丝。在另一个实施方式中，纱线包括50%聚酯切断纤维和50%再生纤维素切断纤维如天丝(Lyocell)。用于形成织物的纱线可采用许多现有领域的技术进行制备。填充或浸渍工艺之前，所用纱线的线密度优选为80-300分特。
例如，纱线20包括未卷曲变形的聚酯或聚酰胺，但捻度水平约为600圈/米。
织物也可以包括由单一的单纤丝构成的纱线。这种由单一的单纤丝构成的纱线没有空穴，因而不能填充。织物可包括由多纤维构成的纱线和由单一的单纤丝构成的纱线的混合物。
在一个具体的实施方式中，所有织物纱线由多纤维构成。
图2示出了多纤维50构成的纱线20，其中纱线20的空穴体积被诸如水等液体40完全填充。结果，纱线20比之前增重，纱线20制成的织物10获得不需要的重量。在许多情况下，吸水量可能超过100克/米2。几乎不可能从空穴60中快速去除这些液体。
图3示出了本发明的织物10。织物10由纱线20构成，经向和纬向的纱线机织成形。在该实施方式中，所有纱线20本身是纤维或纤丝50的束，纱线20间具有间隙30。织物10被构造成即使填充工艺之后，纱线20间的间隙30仍保持未填充，因而能够为穿戴者提供舒适性，因为水汽能够通过间隙30从身体转运到外部。这些间隙30应大于100微米以确保高的水蒸气渗透性和空气渗透性。在一个实施方式中，间隙30确保空气渗透性至少为300l/m2/s。在另一个实施方式中，间隙30确保空气渗透性至少为500l/m2/s。
在本发明中，纱线20填充/浸渍有聚合物材料70，该聚合物材料70穿透各纱线20的纤维或纤丝50之间并填充到其间的空穴体积内(见图4)。在一个实施方式中，纱线20的空穴60被聚合物材料70完全填充。在另一个实施方式中，空穴60被聚合物材料70基本填充，因而一些空穴，尤其是纱线20中心的空穴60可能保持未填充。在一个具体的实施方式中，至少纱线20外表面22内的纤维50被包埋在聚合物材料70中。在该实施方式中，纱线20的表面22基本上不含聚合物材料70。
在另一个实施方式中，聚合物材料70围绕纱线20的外表面22至少部分地形成薄外皮。
由于纱线空穴60的填充，诸如水等液体不能渗透到纱线纤维50或纤丝50之间。因此，织物10的吸水性显著降低。
聚合物材料70由至少一种硅酮构成。在另一个实施例中，聚合物材料70由至少一种非溶胀型聚氨酯构成。在另一实施方式中，聚合物材料70由无定形全氟聚合物如Teflon AF
Figure GDA0000480363550000091
构成。
聚合物材料70在填充空穴60之前以粘度(起始粘度)小于3000mPa/s的液体存在。在另一实施方式中，聚合物材料70在填充空穴60之前以粘度小于2000mPa/s的液体存在。在另一实施方式中，聚合物材料70在填充空穴60之前以粘度小于1000mPa/s的液体存在。聚合物材料70的粘度小于3000mPa/s，小于2000mPa/s，小于1000mPa/s可确保聚合物材料70能够渗透到纤维或纤丝50之间填充空穴60，同时保持间隙30空白。聚合物材料70的低粘度可以采用诸如混合二甲苯（Xylol）或汽油等已知溶剂来实现。聚合物材料70中加入的溶剂的量是获得所需粘度需要的量。在一个实施方式中，采用硅酮作为聚合物材料70。所用硅酮可以是RTV-型、LSR-型或其混合物。这种硅酮由临用前混合在一起的两部分组成。
RTV(室温硫化)硅酮的固化过程在室温混合时开始，但随着温度提高而加速。优良的固化温度在120℃到180℃之间。LSR(液体硅橡胶)硅酮需要高温，即在160℃到200℃之间固化。
固化时间取决于纱线中硅酮的量、线速度、加热区长度以及加热区的选定温度。
聚合物材料70，尤其是硅酮，可包含一种或多种添加剂。所用添加剂可以是：反射剂、防霉剂、手感改变剂、粘度试剂、流变学试剂、柔性试剂、紫外试剂、填充剂、导电剂、导热剂、阻燃剂和辐射反射剂。阻燃剂可以是硼化合物、三水合氧化铝、具有含卤素化合物的氧化锑、氢氧化镁以及磷的有机和无机化合物。
未涂覆的织物用作施加聚合物材料70的基材。
织物10的织品重量为20-500g/m2。在一个实施方式中，织物10的重量为75-350g/m2。在另一个实施方式中，织物的未涂覆重量约为100g/m2。
织物10可以机织或针织。它由10-40纱线/厘米的经纱14和维纱16制成。
聚合物材料70的施加量约为35-55g/m2，取决于织物10的重量。留下的间隙30的平均直径与初始织物10相比基本不变，因为聚合物材料70仅仅位于纱线纤维或纤丝50之间的空穴60内。在一些实施方式中，聚合物材料的部分薄皮层可能保留在纱线30的外表面22周围，但这对间隙30直径的影响可忽略不计。
图3所示织物10是多纤维50组成的纱线20制成的机织织物12。机织纱线之间和纱线交叉点形成一些间隙30。这些间隙30的平均宽度大于100微米，确保本发明织物10具有高的水蒸气渗透性和空气渗透性。纱线20的截面显示每根纱线20由多根纤维或纤丝50构成。纤维50间的空穴60内填充有聚合物材料70(也可参见图4)以防止液体渗透进入纱线20的空穴体积内。聚合物材料可以由至少一种硅酮构成。
用聚合物材料70浸渍本发明织物10，使得聚合物材料70的主要用量填充纱线20的空穴体积。因此，与未处理的织物相比，织物10的织品特性保持不变。并且，间隙30的平均宽度保持基本不变，因而水蒸气渗透性(透气性)和空气渗透性的数值仍然非常高。另一方面，吸水率显著降低。
下面将描述制备浸渍的本发明织物的过程：提供液体聚合物材料作为浸渍溶液，粘度小于3000mPa/s。在一个具体实施方式中，聚合物材料包含溶剂以确保低粘度。浸渍溶液位于两个铬辊之间，其中只有一个辊在运动(施加辊)。另一上方的辊保持不动。通过精确设定上辊和其下方的施加辊之间的间距将溶液计量施加到施加辊上。辊间间距约为50-150微米，取决于织物的厚度。随着织物绕过施加辊而与浸渍溶液相接触，织物从施加辊“擦拭”去除所述溶液，然后所述溶液渗透到织物的纱线结构内。任何过量溶液将保留在施加辊上，保持纱线间的间隙开放而不含溶液。然后，在温度120-160℃的烘箱内固化约2分钟，在一些实施方式中固化1分钟。
任何粘度不高于3000mPa/s的聚合物材料可用作浸渍溶液。聚合物材料在接触织物之前以粘度(起始粘度)小于3000mPa/s的液体存在。在另一实施方式中，聚合物材料在接触织物之前以粘度小于2000mPa/s的液体存在。在另一实施方式中，聚合物材料在接触织物10之前以粘度小于1000mPa/s的液体存在。
图4示出了根据本发明一个实施方式的纱线20的截面图。纤维50间的空穴60被聚合物材料70填充。这导致纤维50被完全包埋在聚合物材料70中的截面。图4显示了本发明的一个实施方式，其中聚合物材料70集中在截面中央而纱线20的外表面22不含聚合物材料70。也可能外表面22至少部分地被聚合物70的薄外皮所覆盖。
图5显示了诸如水等液体40接触本发明织物10时的情况。因为织物10的纱线20的空穴60被聚合物材料70填充，液体仅仅接触纱线20的外表面22。纱线20经填充的空穴60可防止纱线吸收液体40。
图6显示了根据本发明一个实施方式的织物10，其中至少一个水蒸气可渗透层90与所述织物10的一侧相邻而形成织物结构。可以将背衬织品层86添加到水蒸气可渗透层90的至少一侧。背衬织品层86可以在服饰中形成指向穿戴者的最内层。背衬织品层86可附连于层90的至少一侧或者可以垂悬非粘结地毗邻该层90。在本发明的一个实施方式中，水蒸气可渗透层90可以是阻挡层。在本发明的另一个实施方式中，水蒸气可渗透层90可以是至少一个织品层。所述织品层可以通过至少一种缝线或至少一种粘合剂连接于织物10的一侧。优选地，服饰中的最内层可以由所述织品层形成，而最外层可以由所述本发明织物10形成。织品层的作用主要是吸收穿戴者汗水，可以是所谓的推挽式织物。
阻挡层可以是包含聚四氟乙烯(PTFE)、膨胀型PTFE、聚氨酯或其他合适的基材的膜、薄膜或叠层。
织物在与形成未来服饰外侧相对的一侧可与另一层相邻而形成多层复合材料。在一个实施例中，织物层压到另一层或用另一层涂覆。例如，织物的一侧可以附连于或者粘附于阻挡层如水不可渗透的、水蒸气可渗透的薄膜或膜，例如整体型透气性聚氨酯或聚酯聚醚薄膜或多孔、尤其是微孔聚乙烯或聚丙烯，或聚氨酯。膜或薄膜的一个实施方式由U.S.3,953,566所述的膨胀型聚四氟乙烯(ePTFE)膜构成，其具有特征为原纤维互连结点的多孔显微结构。该膜抵抗液体水通过但水蒸气可渗透其中。膜重量为1-100g/m2。在含有ePTFE的膜或薄膜中，ePTFE可浸渍有疏水浸渍剂。ePTFE上可具有U.S.4,194,041所述类型的防水、水蒸气可渗透材料如水蒸气可渗透聚氨酯的薄膜或涂层的连续层。该连续的水蒸气可渗透的聚合物层在转运水分子方面是亲水聚合物，在这里称为亲水聚合物。亲水层选择性地通过扩散转运水，但不支持压力驱动的液体或气流。因此，可转运湿气(即水蒸气)，但聚合物的连续层将阻碍液体水和气载颗粒、微生物、油或其他污染物等物质通过。
在一个实施方式中，水蒸气可渗透的阻挡层可以直接连接于织物10的一侧。阻挡层与织物10的直接连接可以采用不连续粘合剂层的方式进行。在其他实施方式中，连接可以采用诸如粘合剂接缝、焊接接缝或缝线接缝等至少一种接缝方式进行。
本发明的织物10可以与水蒸气可渗透的阻挡层组合以提供空气不可渗透特性和/或液体不可渗透特性。
在本发明的一个实施方式中，阻挡层至少是空气不可渗透的。术语“空气不可渗透的”表示阻挡层或与阻挡层组合的织物10的空气渗透性小于251/m2/s，在一些实施方式中小于51/m2/s。
在其他实施方式中，阻挡层是液体不可渗透的。术语“液体不可渗透的”表示阻挡层或与阻挡层组合的织物10的进水压力大于0.13巴。
在另一实施方式中，经处理的织物10连接于空气不可渗透、液体不可渗透而水蒸气可渗透的阻挡层。
图6A显示了本发明的一个实施方式中，其中形成的织物结构80包括织物层10和水蒸气可渗透层90。水蒸气可渗透层90由阻挡层92和至少一个背衬织品层86形成。背衬织品层86可以是机织、非机织或者针织的，可以由各种材料如聚酯、聚酰胺、聚烯烃等制成。背衬织品层86可附连于阻挡层92的一侧。
在本发明的一个实施方式中，阻挡层92和背衬织品层86形成多层叠层，即构成叠层的各个层可以通过粘合剂粘结或者可以其他方式连接。
在另一实施方式中，阻挡层92除背衬织品层86外还可具有另一织品层，该织品层在与背衬织品层86相对的阻挡层92的一侧通过粘合剂粘结于阻挡层92。这种三层叠层也可垂悬非粘结地毗邻织物层10或者通过粘合剂连接于织物10。
图6B示出了本发明的一个实施方式，其中形成了包括两层叠层85的织物结构80。叠层85包括水蒸气可渗透的阻挡层92和机织浸渍的本发明织物层10。阻挡层92和织物层10间的粘结是通过不连续的粘合剂95实现的，例如粘合剂点、粘合剂网或者粘合剂粉末。
在本发明的另一实施例中，采用未经处理的织物层形成叠层85，然后用本发明的聚合物材料浸渍叠层。因此，织物中纱线的空穴被聚合物材料填充而织物层10的间隙保持开放并且阻挡层92保持未处理。
图6C显示了在阻挡层92的另一侧设置背衬织品层86的图6B的叠层85。在该实施方式中，背衬织品层86通过不连续的粘合剂95粘结于阻挡层92，形成三层叠层。背衬织品层86可以在本发明浸渍工艺之前或之后粘结于阻挡层9。
服饰可以是短裤、夹克、帽子或手套等形式。为了制备服饰或服饰零件，经处理的织物10和水蒸气可渗透层90可以是独立零件，或者水蒸气可渗透的阻挡层90可以附连于经处理的织物10。
实施例1
采用由100%聚酯(PES)制成的织物。织物是由捻度水平约为600圈/米且dtex100f36x2的纤丝纱线制成的机织织品。纱线是非卷曲变形的。经向和纬向纱线间间隙的直径约为180-230微米。这种机织织品可以从德国SR-韦白塔克有限公司(SR-Webatex GmbH)获得。
图7和8显示了不同放大倍数的实施例1的纱线的截面在浸渍之前的SEM。
图7显示了机织结构中纤维束形式的一些未处理纱线20的SEM，纱线20之间具有间隙30。每根纱线20包括多根纤丝形式的纤维50。
图8显示了放大比例更大的多纤维50构成的图7所示未处理纱线20截面的SEM。纱线20的纤维50之间以及纱线20的截面内存在一些不同尺寸的空穴60。
采用上述工艺，用硅酮溶液浸渍织物10。硅酮溶液是德国维科化学有限公司(Wacker Chemie AG)的SilGel612，粘度1000mPa/s。施加辊上硅酮溶液的厚度约为70微米(等于辊之间的间距)。处理后织物10在160℃的固化时间约为1分钟。
图9显示了机织织品的经处理纱线20。纱线的外表面22部分地覆盖有非常薄的硅酮材料的外皮。纱线20的截面显示纤维50间的空穴60被起聚合物材料70作用的硅酮材料填充。纱线20间的间隙30开放，未填充硅酮材料。
图10显示了较高放大倍数下图10所示的经处理的纱线。纤维50间的空穴60被硅酮材料(聚合物材料)70填充，基本没有留下开放的空穴体积。所有纤维50被包埋在聚合物材料70中。因此，诸如液体等其他材料不能吸收到纱线20内纤维50之间。
图11显示了根据该实施例的经处理的浸渍机织织物12的表面的图片。经纱14和纬纱16形成机织织物12，纱线14、16间具有间隙30。织物12的间隙30开放，未被硅酮材料闭合。因此，织物仍然是水蒸气可渗透且空气可渗透的。而且，可见每根纱线20的纤维束结构。因此，只有外表面22内的纤维50被包埋在硅酮材料70中，外表面22至少部分地不含聚合物材料70。
表1显示了处理前后织物10的技术特征：
表1
用作聚合物材料70的硅酮的施加量约为30-40g/m2。经处理织物10的水蒸气渗透性(透气性)降低但仍然较高。降低的原因在于，纱线20的空穴60不再是水蒸气可透过的，因为空穴60被聚合物材料70闭合。水蒸气透过只有通过纱线20间的间隙30来完成。未处理和经处理织物10的空气渗透性相同，因为经处理织物的间隙30的宽度与未处理织物材料的相同。
表2显示了根据两种方法测定的未处理和经处理织物的吸水率：
表2
测试I和测试II的主要区别在于，测试II中织物在Bundesmann测试之后进行震摇以去除附着于织物表面的诸如液滴等液体。在测试I中，经处理织物的吸水性下降到10%以下。即使在几次家用洗涤循环后，吸水性仍然低于20%。测试II显示，经处理织物基本上不吸水。
用“滑动测试”测定本发明的织物。结果见表3。
表3显示了“滑动测试”的结果。
表3
“滑动测试”是为了阐述根据本发明的织物或叠层的织物层改良的织品手感(特性)而开发的。
比较织物根据EP1264036所述制备。这种织物包括由纱线制成的机织织品，纱线间具有间隙。纱线被硅酮涂层基本上完全涂覆，但硅酮涂层不能完全填充纱线间的间隙。纱线表面被硅酮完全涂覆。
未处理织物和实施例1的经处理织物在织品手感/特性方面的性质在“滑动测试”之后基本上相同。因此，用硅酮材料浸渍后保留了本发明织物的织品感觉。作为比较，纱线被硅酮材料完全涂覆的织物显示测试结果高大约三倍数值，表明织品特性非常差。
实施例2
采用实施例1所述的未处理织物。采用标准层压工艺将织物层压到防水且水蒸气可渗透的阻挡层。使用由ePTFE制成的多孔膜作为阻挡层90。根据美国专利3,953,566和4,187,390所述制造膜，根据U.S.4,194,041所述用水蒸气可渗透的亲水聚氨酯的连续层涂覆。在后文中，得到的膜将称为涂覆的ePTFE膜。为了产生两层叠层，采用U.S.4,532,316所述的聚氨酯粘合剂的点状图案将实施例1的织物层压到经涂覆的ePTFE的ePTFE侧。所得叠层是水不可渗透而水蒸气可渗透的叠层。
用粘度1000mPa/s的德国维科化学有限公司的SilGel612硅酮溶液浸渍叠层。采用与实施例1所述相同的工艺。在浸渍工艺中，叠层的织品侧指向施加辊以接触用于浸渍的硅酮溶液。
图12和13显示了不同放大倍数的经处理叠层的截面的SEM。
图12显示了用本发明的硅酮材料70浸渍的实施例2的两层叠层85的截面的SEM。机织织物12形成叠层85的第一层。涂覆的ePTFE膜84形成叠层85的第二层。采用以不连续形式施加的粘合剂将两层粘结在一起。纱线20的表面22基本上不含任何硅酮材料，但纤丝50间的空穴中填充有硅酮材料70。纱线20间的间隙30和涂覆的ePTFE膜84的表面不含硅酮材料70，因此在浸渍工艺后叠层85仍然是水蒸气可渗透的。
图13显示了较高放大倍数下图12所示的经处理纱线20的SEM。纤维50间的空穴被硅酮材料70填充，没有留下开放的空穴体积。因此，诸如液体等其他材料不能吸收到纱线20内和纤维50之间。
表4显示了处理前后叠层的技术特征：
Figure GDA0000480363550000171
表4
施加于叠层的硅酮的量约为30-40g/m2。经处理叠层的水蒸气渗透性(透气性)仍然非常高，接近未处理叠层的范围。经涂覆的ePTFE膜本身不具有空气渗透性，因此未处理和经处理状态下叠层都是空气不可渗透的。
表5显示了根据两种方法测定的未处理和经处理叠层的吸水率：
表5
根据测试I测定的本发明经处理叠层的吸水率小于20%，测试II显示小于10%的更好的吸水率。10次家用洗涤循环后，吸水性数值仍然低于20%。
测试方法
空气渗透性：
为测定织物(织品)的空气渗透性，采用可测量空气流动通过织物的测试仪器。将样品置于两个环之间，测试面积约为100cm2。空气以100Pa的恒定压力吸收通过样品。从而测定通过样品的空气量，以l/m2/s表示。测试方法如ENISO9237所述。
水蒸气透过率：
织物的MVTR测试方法：
根据EN ISO15496所述测定本发明织物的水蒸气透过率(MVTR)，以克/米2/24小时表示。为确定是水蒸气可渗透的，通常织物的水蒸气渗透性至少为1000，优选大于1500，更优选大于3000克/米2/24小时，可以超过15,000克/米2/24小时。
阻挡层的RET测试方法：
抗水蒸气透过性(Ret)是片状结构或复合材料的特定材料性质，可测定在恒定分压梯度下通过给定面积的潜热蒸发通量。如果本发明阻挡层的抗水蒸气透过性Ret低于150(m2×Pa)/W，则它是水蒸气可渗透的。优选阻挡层的Ret低于20(m2×Pa)/W。根据比尔顿克生理学机构(Bekleidungsphysiologisches)(服装生理学机构(Apparel Physiology Institute)]e.V.Hohenstein中标准测试规定BPI1.4(1987)所述，通过Hohenstein MDM干法测定水蒸气渗透性。
间隙宽度：
经处理织物的纱线间包括间隙，使得空气渗透性大于300l/m2/s，大于500l/m2/s，大于1000l/m2/s。这些间隙的宽度至少为100微米。宽度表示织物中两根纱线间的最小距离。因此，本发明间隙的最小可能尺寸为100×100微米。在一个实施方式中，间隙宽度为100-1000微米。
为测定间隙宽度，采用显微镜(例如蔡司显微镜)。将样品置于显微镜下，优选放大倍数50×测定宽度，结合电学测定程序测定距离。可使用任何进一步有用的放大倍数。
水不可渗透性：
根据国际标准ISO811测定水不可渗透性。在一个实施方式中，阻挡层的抗水压性最高至0.13巴。
吸水性：
测定织品结构吸水性的一种方法是采用根据Bundesmann测试(DIN EN29865)(1991)的雨水测试。雨水装置产生雨水，雨水由水体积、液滴大小以及雨水装置与测试样品间距离限定。测试运行10分钟。
根据以下方法测定织物和叠层的吸水性(测试I)：
1.测定样品(织物/叠层)重量
2.进行Bundesmann雨水测试10分钟
3.样品自旋15秒
4.测定样品重量
5.计算相对于Bundesmann雨水测试前的样品的重量增量，以%表示。
在另一吸水性测试的实施方式(测试II)中，根据以下方法处理样品：
1.测定样品(织物/叠层)重量
2.进行Bundesmann雨水测试10分钟
3.样品自旋15秒
4.垂直方向震摇样品5次
5.室温下(20℃/65%相对湿度)干燥样品5分钟
6.测定样品重量
7.计算相对于Bundesmann雨水测试前的样品的重量增量，以%表示。
对未处理织物和叠层样品、本发明的经处理织物和叠层样品、以及本发明的经处理织物和叠层在60℃10次家用洗涤循环后进行测试I和测试II的吸水性测定。
家用洗涤：
根据国际标准ISO6330/2A(1984)，通过60℃的家用洗涤循环进行洗涤。
滑动测试：
该测试主要显示材料表面对不同材料的抗性。在织物和织品领域，这种抗性称为“织品手感”或者换言之“织品粘着性”。这就表示，织品感觉越粘，与正常典型织品手感的差距越大。
测试装置包括底板(25×50cm)和重100克的金属板(10×10cm)，底板可以在0°-90°间运动，具有第一边缘和与第一边缘相对的第二边缘。如果底板运动，则第一边缘向下运动而第二边缘向上运动。
根据以下步骤进行滑动测试：
1.将尺寸25×50cm的样品固定到底板表面上。在样品是叠层的情况下，织物侧应为最外侧表面。
2.在样品表面划两条线，第一条线距离底板的第一边缘和样品5cm，第二条线距离底板的第一边缘和样品35cm。
3.将金属板在底板第二边缘区域内置于样品表面上。
4.使底板运动直到金属板开始沿样品表面滑动并在约5秒内通过两条线。
5.测定底板斜率。
6.重复测试3次。
底板斜率即样品抗性结果(重量)。高斜率表明样品对金属板的抗性高。这种样品的织品手感差。斜率低表明样品对金属板的抗性低，织品手感好。
聚合物材料的粘度
用旋转测定装置(粘度计)，例如Rheotec或Brookfield公司出品的粘度计来测定聚合物材料的粘度。
不希望限制本发明的范围，上述内容阐述了本发明的制备和使用过程。
虽然本文阐述和描述了本发明的具体实施方式，但本发明并不限于这些阐述和描述。应理解，改变或改进可在所附权利要求书的范围内包括和体现作为本发明的一部分。

Claims (55)

1.一种织物(10)，其包括：
a.纱线(20)和纱线间的间隙(30)；
b.纱线间的间隙(30)的平均宽度大于100微米；
c.至少一种纱线(20)由多纤维(50)构成；
d.所述至少一种纱线（20）具有纤维(50)间的空穴(60)；
e.所述空穴(60)中填充有聚合物材料(70)，并且所述纱线间的间隙保持开放，所述聚合物材料(70)由至少一种硅酮(75)构成。
2.如权利要求1所述的织物(10)，其特征在于，所述间隙(30)的平均宽度为150-250微米。
3.如前述权利要求中任一项所述的织物(10)，其特征在于，所述聚合物材料(70)包含一种或多种添加剂。
4.如权利要求3所述的织物(10)，其特征在于，所述添加剂选自下组：反射剂、防霉剂、手感改变剂、粘度试剂、流变学试剂、柔性试剂、紫外吸收剂、填充剂、导电剂、导热剂、辐射吸附剂、阻燃剂。
5.如权利要求4所述的织物（10），其特征在于，所述反射剂是辐射反射剂。
6.如权利要求4所述的织物(10)，其特征在于，所述阻燃剂是硼化合物、三水合氧化铝、具有含卤素化合物的氧化锑、氢氧化镁以及磷的有机或无机化合物。
7.如权利要求1所述的织物(10)，其特征在于，所述空穴(60)被所述聚合物材料(70)完全填充。
8.如权利要求1所述的织物(10)，其特征在于，所述至少一种纱线(20)具有外表面(22)，至少使所述外表面(22)内的纤维(50)被包埋在所述聚合物材料(70)中。
9.如权利要求8所述的织物(10)，其特征在于，所述外表面(22)至少部分地不含聚合物材料(70)。
10.如权利要求1所述的织物(10)，其特征在于，所述织物的吸水率小于50%。
11.如权利要求1所述的织物(10)，其特征在于，所述织物的吸水率小于20%。
12.如权利要求1所述的织物(10)，其特征在于，所述织物的吸水率小于10%。
13.如权利要求1所述的织物(10)，其特征在于，所述间隙(30)使得所述织物的空气渗透性大于300l/m2/s。
14.如权利要求1所述的织物(10)，其特征在于，所述织物的化学物质径流率大于90%。
15.如权利要求1所述的织物(10)，其特征在于，所述纤维(50)包括连续的多纤丝、切断纤维或其组合。
16.如权利要求1所述的织物(10)，其特征在于，所述织物(10)是针织或机织织物的形式。
17.如权利要求1所述的织物(10)，其特征在于，所述纱线(20)由多纤维(50)构成。
18.如权利要求1所述的织物(10)，其特征在于，所述至少一种纱线(20)选自下组：聚烯烃、聚酰胺、聚酯、再生纤维素、丙烯酸类、芳族聚酰胺、玻璃、改性聚丙烯腈纤维、棉花、羊毛、真丝、亚麻、黄麻以及它们的混合物。
19.如权利要求1所述的织物(10)，其特征在于，所述至少一种纱线(20)选自人造丝。
20.如权利要求1所述的织物(10)，其特征在于，所述至少一种纱线(20)选自醋酸纤维素。
21.如权利要求1所述的织物(10)，其特征在于，所述至少一种纱线(20)包括聚酯制成的纤丝。
22.如权利要求1所述的织物(10)，其特征在于，所述织物(10)的重量为20-500g/m2。
23.如权利要求1所述的织物(10)，其特征在于，所述织物(10)的重量为75-350g/m2。
24.如权利要求1所述的织物(10)，其特征在于，至少一个水蒸气可渗透层(90)与所述织物(10)的一侧相邻。
25.如权利要求24所述的织物(10)，其特征在于，所述水蒸气可渗透层(90)包括织品层。
26.如权利要求24所述的织物(10)，其特征在于，所述水蒸气可渗透层(90)包括至少一个水蒸气可渗透的阻挡层(92)。
27.如权利要求26所述的织物(10)，其特征在于，所述阻挡层(92)是气体不可渗透的。
28.如权利要求26所述的织物(10)，其特征在于，所述阻挡层(92)是空气不可渗透的。
29.如权利要求26所述的织物(10)，其特征在于，所述阻挡层(92)是液体不可渗透的。
30.如权利要求1所述的织物(10)，其特征在于，空气不可渗透、液体不可渗透而水蒸气可渗透的阻挡层(92)连接于所述织物(10)的一侧。
31.如权利要求28所述的织物(10)，其特征在于，所述阻挡层(92)是空气不可渗透的，空气渗透性小于251/m2/s。
32.如权利要求28所述的织物(10)，其特征在于，所述阻挡层(92)是空气不可渗透的，空气渗透性小于51/m2/s。
33.如权利要求29所述的织物(10)，其特征在于，所述阻挡层(92)是液体不可渗透的，进水压力为0.13巴。
34.如权利要求26所述的织物(10)，其特征在于，所述阻挡层(92)是膜。
35.如权利要求26所述的织物(10)，其特征在于，所述阻挡层(92)使用不连续粘合剂层附连于所述织物(10)的一侧。
36.如权利要求26所述的织物(10)，其特征在于，所述阻挡层(92)通过至少一种接缝附连于所述织物(10)的一侧。
37.如权利要求26所述的织物(10)，其特征在于，所述阻挡层(92)包括由膨胀型聚四氟乙烯(ePTFE)制成的多孔膜。
38.如权利要求1所述的织物(10)，其特征在于，所述聚合物材料(70)在填充所述空穴之前以粘度小于3000mPa/s的液体存在。
39.如权利要求1所述的织物(10)，其特征在于，所述聚合物材料(70)在填充所述空穴(60)之前以粘度小于2000mPa/s的液体存在。
40.如权利要求1所述的织物(10)，其特征在于，所述聚合物材料(70)在填充所述空穴(60)之前以粘度小于1000mPa/s的液体存在。
41.如权利要求1所述的织物(10)，其包括：
a.纱线(20)和纱线间的间隙(30)；
b.所述纱线间的间隙(30)的平均宽度大于100微米；
c.纱线(20)由多纤维(50)构成；
d.纱线(20)具有纤维(50)间的空穴(60)；所述空穴(60)中填充有聚合物材料(70)而所述纱线间的间隙(30)保持开放。
42.一种服饰，其包括如权利要求1所述的织物(10)。
43.一种织物结构(80)，其包括至少两层：
a.包括织物(10)的第一层，所述织物(10)包括：
i.纱线(20)和纱线间的间隙(30)；
ii.所述纱线(20)间的间隙(30)的平均宽度大于100微米；
iii.至少一种纱线(20)由多纤维(50)构成，纤维(50)间具有空穴(60)；
b.第二层，其包括与所述第一层的至少一侧相连的水蒸气可渗透的阻挡层(92)，
c.所述空穴(60)中填充有聚合物材料(70)，并且所述纱线间的间隙保持开放，所述聚合物材料(70)由至少一种硅酮(75)构成。
44.如权利要求43所述的织物结构(80)，其特征在于，所述第一层和第二层通过至少一种粘合剂连接在一起。
45.如权利要求43所述的织物结构(80)，其特征在于，所述阻挡层(92)是液体不可渗透的。
46.如权利要求43所述的织物结构(80)，其特征在于，所述阻挡层(92)是气体不可渗透的。
47.如权利要求43所述的织物结构(80)，其特征在于，所述阻挡层(92)是空气不可渗透的。
48.如权利要求43所述的织物结构(80)，其特征在于，所述阻挡层(92)包括由膨胀型聚四氟乙烯(ePTFE)制成的多孔膜。
49.如权利要求43所述的织物结构(80)，其特征在于，所述间隙(30)的平均宽度为150-250微米。
50.如权利要求43所述的织物结构(80)，其特征在于，所述织物结构的吸水率小于50%。
51.如权利要求43所述的织物结构(80)，其特征在于，所述织物结构的吸水率小于20%。
52.一种尽可能减小织物(10)的吸水率的方法，所述方法包括以下步骤：
a.提供一种织物，该织物包括纱线(20)和纱线(20)间的间隙(30)，所述间隙(30)的平均宽度大于100微米，至少一种所述纱线由多纤维(50)构成并且所述纤维(50)间具有空穴(60)，
b.提供粘度小于3000mPa/s的液体聚合物材料(70)，
c.用所述聚合物材料(70)填充空穴(60)而间隙(30)保持开放。
53.如权利要求52所述的方法，其特征在于，所述方法还包括步骤d：在步骤c之后固化所述织物（10）。
54.如权利要求52所述的方法，其特征在于，所述液体聚合物材料(70)的粘度小于2000mPa/s。
55.如权利要求52所述的方法，其特征在于，所述液体聚合物材料(70)的粘度小于1000mPa/s。
CN200880106549.1A 2007-09-10 2008-09-08 织物与织物叠层 Expired - Fee Related CN101796245B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP20070017629 EP2034088B1 (en) 2007-09-10 2007-09-10 Fabric and fabric laminate
EP07017629.2 2007-09-10
PCT/EP2008/007333 WO2009033626A1 (en) 2007-09-10 2008-09-08 Fabric and fabric laminate

Publications (2)

Publication Number Publication Date
CN101796245A CN101796245A (zh) 2010-08-04
CN101796245B true CN101796245B (zh) 2014-06-25

Family

ID=39047605

Family Applications (1)

Application Number Title Priority Date Filing Date
CN200880106549.1A Expired - Fee Related CN101796245B (zh) 2007-09-10 2008-09-08 织物与织物叠层

Country Status (9)

Country Link
US (2) US20100255270A1 (zh)
EP (2) EP2034088B1 (zh)
JP (1) JP5199365B2 (zh)
KR (1) KR101244963B1 (zh)
CN (1) CN101796245B (zh)
CA (1) CA2699205C (zh)
PL (1) PL2034088T3 (zh)
RU (1) RU2435879C1 (zh)
WO (1) WO2009033626A1 (zh)

Families Citing this family (54)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007109837A1 (en) 2006-03-24 2007-10-04 Resmed Ltd Air delivery conduit
US9842518B2 (en) 2010-08-10 2017-12-12 Avery Dennison Retail Information Services, Llc Breathable heat transfer labels
US9885129B2 (en) 2007-12-19 2018-02-06 Coolcore, Llc Fabric and method of making the same
GB2470572A (en) * 2009-05-27 2010-12-01 Sealskinz Ltd A waterproof windprrof breathable and stretchable laminate
JP2010279451A (ja) * 2009-06-03 2010-12-16 Yamazaki Corp 携帯用拭具
US20100316822A1 (en) * 2009-06-12 2010-12-16 Malloy Cassie M Textile sleeve with high temperature abrasion resistant coating and methods of assembly, construction and curing thereof
EP2322710B1 (en) 2009-11-09 2014-12-17 W.L.Gore & Associates Gmbh Textile composite article
EP2415428A1 (en) * 2010-08-04 2012-02-08 Polymer Group, Inc. Breathable laminate and method of making the same
WO2012020824A1 (ja) * 2010-08-11 2012-02-16 東洋紡績株式会社 難燃性脱臭フィルタ
US8630908B2 (en) 2011-11-02 2014-01-14 Avery Dennison Corporation Distributed point of sale, electronic article surveillance, and product information system, apparatus and method
CN102677302A (zh) * 2012-05-29 2012-09-19 蔡紫林 色织面料
WO2014062731A1 (en) * 2012-10-16 2014-04-24 Tempnology, Llc Fabric and method of making the same
WO2014093549A1 (en) * 2012-12-11 2014-06-19 Hzo, Inc. Vapor ports for electronic devices
DE102013010554A1 (de) * 2013-06-15 2014-12-18 Volkswagen Aktiengesellschaft Schichtstruktur auf Silikonbasis mit oleophob-hydrophober Oberfläche, ein Verfahren zur Darstellung einer solchen sowie eine elektrische Maschine mit einer solchen
KR101447517B1 (ko) * 2013-07-01 2014-10-06 주식회사 휴비스 위장성능이 뛰어나고 투습방수성이 양호한 전투복용 직물
US20150079865A1 (en) * 2013-09-17 2015-03-19 W.L. Gore & Associates, Inc. Conformable Microporous Fiber and Woven Fabrics Containing Same
CN103526405A (zh) * 2013-10-23 2014-01-22 吴江市万盟纺织有限公司 一种耐腐蚀聚丙烯腈纤维面料
CN103806196A (zh) * 2014-02-18 2014-05-21 如皋市安国织造有限公司 一种棉花打包专用阻燃棉布袋及其制作方法
US20150361599A1 (en) * 2014-06-16 2015-12-17 W. L. Gore & Associates, Inc. Woven Fabrics Containing Expanded Polytetrafluoroethylene Fibers
US10710345B2 (en) 2014-08-27 2020-07-14 W. L. Gore & Associates Gmbh Waterproof and water vapor permeable laminate
MX367028B (es) * 2015-01-12 2019-08-01 Georgia Pacific Nonwovens Llc Estructura no tejida de alto rendimiento.
US10813462B2 (en) 2015-02-13 2020-10-27 L&P Property Management Company Pocketed spring comfort layer and method of making same
US9943173B2 (en) 2015-02-13 2018-04-17 L&P Property Management Company Pocketed spring comfort layer and method of making same
US9968202B2 (en) 2015-02-13 2018-05-15 L&P Property Management Company Pocketed spring comfort layer and method of making same
US10405665B2 (en) 2015-02-13 2019-09-10 L&P Property Management Company Pocketed spring comfort layer and method of making same
US11136697B2 (en) * 2015-03-16 2021-10-05 W. L. Gore & Associates, Inc. Fabrics containing conformable low density fluoropolymer fiber blends
KR101699162B1 (ko) * 2015-05-29 2017-01-23 (주) 정산인터내셔널 아크릴 소재를 이용한 난연성, 발수, 발오, 내일광성을 갖는 기능성 원단 제조 방법 및 이에 의해 제조된 원단
US9988758B2 (en) 2015-06-15 2018-06-05 W. L. Gore & Associates, Inc. Fabrics containing expanded polytetrafluoroethylene fibers
CN106218182A (zh) * 2015-10-30 2016-12-14 上海永利带业股份有限公司 一种防霉聚乙烯轻型输送带的制备方法
CN105501705B (zh) * 2015-12-26 2018-01-26 宁波远志立方能源科技有限公司 一种用于玻璃运输的包装材料
US10172472B2 (en) 2016-03-07 2019-01-08 L&P Property Management Company Pocketed spring assembly having multi-layered impermeable fabric
US10034553B2 (en) 2016-03-07 2018-07-31 L&P Property Management Company Multi-layered impermeable fabric for use in pocketed spring assembly
US10076193B2 (en) 2016-03-07 2018-09-18 L&P Property Management Company Multi-layered impermeable fabric for use in pocketed spring assembly
JP6677540B2 (ja) * 2016-03-15 2020-04-08 セーレン株式会社 車両用複合表皮材
CN105696352B (zh) * 2016-04-15 2018-04-10 广东聚合科技股份有限公司 一种硅丝棉产品及其制备方法
US11465388B2 (en) * 2017-01-15 2022-10-11 Honeywell International Inc. Peel strength between dissimilar fabrics
WO2018173074A1 (en) * 2017-03-23 2018-09-27 Council Of Scientific & Industrial Research A process for coating a biomedical implant with a biocompatible polymer and a biomedical implant therefrom
JP6913521B2 (ja) * 2017-06-09 2021-08-04 株式会社アズ 機能性布帛およびその製造方法
CA3067202A1 (en) * 2017-06-16 2018-12-20 Nitto Denko Corporation Multilayer film, laminate, airbag, and method of manufacturing laminate
MX2019014945A (es) 2017-06-16 2020-08-06 Nitto Denko Corp Procedimiento de fabricacion de laminado, laminado, y bolsa de aire.
CA3067205A1 (en) * 2017-06-16 2018-12-20 Nitto Denko Corporation Laminate and airbag
WO2018236496A1 (en) 2017-06-20 2018-12-27 L&P Property Management Company COMFORT LAYER WITH INSIDE SPRINGS AND METHOD OF MANUFACTURE
US12005688B2 (en) * 2017-11-10 2024-06-11 Chen-Cheng Huang Composite cloth
US11661683B2 (en) * 2018-03-29 2023-05-30 Milliken & Company Flame resistant textile
US10750877B2 (en) 2018-06-26 2020-08-25 L&P Property Management Company Pocketed spring comfort layer having at least one foam layer and method of making same
USD880214S1 (en) 2018-06-26 2020-04-07 L&P Property Management Company Pocketed spring comfort layer
US11103083B2 (en) 2019-03-13 2021-08-31 L&P Property Management Company Comfort layer having pocketed springs of different heights
US11103084B2 (en) 2019-03-13 2021-08-31 L&P Property Management Company Comfort layer having spacer pocketed springs
US11033115B2 (en) 2019-03-13 2021-06-15 L&P Property Management Company Comfort layer having repeating pattern of pocketed mini coil springs of different heights
RU191460U1 (ru) * 2019-05-06 2019-08-06 Федеральное Государственное Бюджетное Образовательное Учреждение Высшего Образования "Ивановская Пожарно-Спасательная Академия Государственной Противопожарной Службы Министерства Российской Федерации По Делам Гражданской Обороны, Чрезвычайным Ситуациям И Ликвидации Последствий Стихийных Бедствий" (Ф Объемный тканый огне-теплозащитный материал
US11033116B2 (en) 2019-08-23 2021-06-15 L&P Property Management Company Dual-sided vented pocketed spring comfort layer
RU2714520C1 (ru) * 2019-11-01 2020-02-18 Общество с ограниченной ответственностью "КАРО" Водоотталкивающая синтетическая ткань
EP4076939A1 (en) * 2019-12-20 2022-10-26 DSM IP Assets B.V. Multilayer composite comprising a backbone film
RU2728044C1 (ru) * 2020-03-18 2020-07-28 Общество с ограниченной ответственностью "Обнинская Текстильная Компания" Двуслойная ткань

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1989008553A1 (en) * 1988-03-14 1989-09-21 Sili-Tex, Inc. Silicone polymer fiber encapsulated webs
US5418051A (en) * 1988-03-14 1995-05-23 Fabric Coating Corporation Internally coated webs
CN1222882A (zh) * 1996-06-25 1999-07-14 W·L·戈尔有限公司 柔性防水防油复合材料
EP1264036A1 (en) * 2000-03-10 2002-12-11 W.L. GORE & ASSOCIATES GmbH Soil resistant cleanable clothing

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4587159A (en) * 1985-09-20 1986-05-06 Dow Corning Corporation Clear silicone coated fabric
US5846604A (en) * 1988-03-14 1998-12-08 Nextec Applications, Inc. Controlling the porosity and permeation of a web
JPH06200481A (ja) * 1992-12-28 1994-07-19 Tosuko Kk 撥水性でかつ透湿性の繊維織物
US5719399A (en) * 1995-12-18 1998-02-17 The Research Foundation Of City College Of New York Imaging and characterization of tissue based upon the preservation of polarized light transmitted therethrough
DE19625389A1 (de) * 1996-06-25 1998-01-02 Gore W L & Ass Gmbh Flexibler Verbundstoff
US5936739A (en) * 1997-01-29 1999-08-10 Sandia Corporation Gated frequency-resolved optical imaging with an optical parametric amplifier
US5912067A (en) * 1997-03-18 1999-06-15 Astral International S.A. Fabric particularly for mattresses and covers
AU3102699A (en) * 1998-03-19 1999-10-11 Board Of Regents, The University Of Texas System Fiber-optic confocal imaging apparatus and methods of use
US7006676B1 (en) * 2000-01-21 2006-02-28 Medical Optical Imaging, Inc. Method and apparatus for detecting an abnormality within a host medium utilizing frequency-swept modulation diffusion tomography
WO2001069302A2 (en) * 2000-03-13 2001-09-20 Genospectra, Inc. Fiber optic scanner
DE602005007403D1 (de) * 2004-03-25 2008-07-24 Olympus Corp Scannendes konfokales Mikroskop
US7189961B2 (en) * 2005-02-23 2007-03-13 University Of Washington Scanning beam device with detector assembly

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1989008553A1 (en) * 1988-03-14 1989-09-21 Sili-Tex, Inc. Silicone polymer fiber encapsulated webs
US5418051A (en) * 1988-03-14 1995-05-23 Fabric Coating Corporation Internally coated webs
CN1222882A (zh) * 1996-06-25 1999-07-14 W·L·戈尔有限公司 柔性防水防油复合材料
EP1264036A1 (en) * 2000-03-10 2002-12-11 W.L. GORE & ASSOCIATES GmbH Soil resistant cleanable clothing

Also Published As

Publication number Publication date
KR101244963B1 (ko) 2013-03-18
CA2699205A1 (en) 2009-03-19
PL2034088T3 (pl) 2013-04-30
US20100255270A1 (en) 2010-10-07
CN101796245A (zh) 2010-08-04
EP2034088A1 (en) 2009-03-11
RU2435879C1 (ru) 2011-12-10
KR20100080794A (ko) 2010-07-12
JP2010539338A (ja) 2010-12-16
CA2699205C (en) 2015-12-08
WO2009033626A1 (en) 2009-03-19
EP2195483A1 (en) 2010-06-16
US20130189431A1 (en) 2013-07-25
JP5199365B2 (ja) 2013-05-15
EP2034088B1 (en) 2012-11-07

Similar Documents

Publication Publication Date Title
CN101796245B (zh) 织物与织物叠层
CN102597363B (zh) 织物复合物制品
US20070093162A1 (en) Fabric and a method of making the fabric
EP3390037B1 (en) Fabrics containing expanded polytetrafluoroethylene fibers
GB2452568A (en) Fabric and fabric laminate
CA2951931A1 (en) Fabrics containing expanded polytetrafluoroethylene fibers
NL8201181A (nl) Materiaal voor het beschermen van het menselijke lichaam tegen schadelijke of giftige chemische stof.
KR20170122831A (ko) 정합성 저밀도 플루오로중합체 섬유 혼방을 함유하는 직물
JP6496012B2 (ja) 防水性かつ水蒸気透過性のラミネート
CN106757659A (zh) 一种含聚四氟乙烯的抗冰面料

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20140625

Termination date: 20170908

CF01 Termination of patent right due to non-payment of annual fee