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CN101718801B - Micro-accelerometer based on high electron mobility transistor (HEMT) - Google Patents

Micro-accelerometer based on high electron mobility transistor (HEMT) Download PDF

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CN101718801B
CN101718801B CN2009102279174A CN200910227917A CN101718801B CN 101718801 B CN101718801 B CN 101718801B CN 2009102279174 A CN2009102279174 A CN 2009102279174A CN 200910227917 A CN200910227917 A CN 200910227917A CN 101718801 B CN101718801 B CN 101718801B
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hemt
electron mobility
high electron
mobility transistor
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CN101718801A (en
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唐军
马游春
刘俊
张文栋
苏淑靖
薛晨阳
张斌珍
熊继军
侯婷婷
刘国文
崔兢
贾晓娟
谭振新
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North University of China
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Abstract

本发明涉及微加速度计领域,具体是一种基于高电子迁移率晶体管HEMT的微加速度计。适应了微加速度计应用领域对高灵敏度微加速度计的需要,实现高电子迁移率晶体管HEMT力电转换机理在微加速度计上的应用,所述微加速度计采用以下步骤加工制造:1、应用分子束外延技术在GaAs衬底上生长出如下表1所示材料层结构的薄膜;2、应用微机电器件加工技术在薄膜上加工高电子迁移率晶体管HEMT;3、应用微机电器件加工技术加工微加速度计结构。有效利用高电子迁移率晶体管HEMT的力电转换机理,实现了高电子迁移率晶体管HEMT在微加速度计上的应用,灵敏度高、线性度好,完全可以适应微加速度计应用领域的实际需要。

The invention relates to the field of micro-accelerometers, in particular to a micro-accelerometer based on high electron mobility transistor HEMT. It adapts to the needs of high-sensitivity micro-accelerometers in the application field of micro-accelerometers, and realizes the application of high electron mobility transistor HEMT force-electricity conversion mechanism on micro-accelerometers. The micro-accelerometers are manufactured by the following steps: 1. Apply molecular Beam epitaxy technology grows thin films with the material layer structure shown in Table 1 on the GaAs substrate; 2. Apply MEMS device processing technology to process high electron mobility transistor HEMT on the film; 3. Apply MEMS device processing technology to process micro Accelerometer structure. Effective use of the force-to-electricity conversion mechanism of the high electron mobility transistor HEMT realizes the application of the high electron mobility transistor HEMT in the micro-accelerometer, with high sensitivity and good linearity, which can fully meet the actual needs of the micro-accelerometer application field.

Description

基于高电子迁移率晶体管HEMT的微加速度计Microaccelerometer Based on High Electron Mobility Transistor HEMT

技术领域technical field

本发明涉及微加速度计领域,具体是一种基于高电子迁移率晶体管HEMT的微加速度计。The invention relates to the field of micro-accelerometers, in particular to a micro-accelerometer based on high electron mobility transistor HEMT.

背景技术Background technique

现有微加速度计多为硅压阻式加速度计,基于硅压阻器件的压阻效应实现,利用硅压阻器件随外压力的线性响应实现检测,因其结构简单、工艺成熟、工作频带宽等诸多优点而成为微惯性器件领域的研究热点之一。但由于硅压阻器件压阻系数的限制,很难进一步提高响应灵敏度;另外,硅压阻器件的电阻率变化受温度的影响较大,随温度的升高迅速变小,上述缺点皆限制了硅压阻器件在高灵敏度传感器上的应用。Most of the existing micro-accelerometers are silicon piezoresistive accelerometers, which are realized based on the piezoresistive effect of silicon piezoresistive devices, and use the linear response of silicon piezoresistive devices to external pressure to realize detection, because of their simple structure, mature technology, and wide operating frequency band And many other advantages, it has become one of the research hotspots in the field of micro-inertial devices. However, due to the limitation of the piezoresistive coefficient of silicon piezoresistive devices, it is difficult to further improve the response sensitivity; in addition, the resistivity change of silicon piezoresistive devices is greatly affected by temperature, and rapidly decreases with the increase of temperature. Application of silicon piezoresistive devices in high-sensitivity sensors.

因此,为适应微加速度计应用领域对高灵敏度微加速度计的迫切需要,近年来,各国科学家相继开始将场效应晶体管应用于微机械传感结构的研究,并在研究当中,证明了将场效应晶体管应用于微加速度计的可行性,验证了应用场效应晶体管的微加速度计所具备的高灵敏特性。根据国内外的相关报道显示,目前各国科学家的研究方向多集中在场效应晶体管中的金属-半导体场效应晶体管(Metal-Semiconductor Field-Effect Transistor,MESFET)、金属-氧化层-半导体-场效晶体管(Metal-Oxide-Semiconductor Field-Effect Transistor,MOSFET)。还未见将高电子迁移率晶体管应用在微加速度计上的相关研究。Therefore, in order to meet the urgent need for high-sensitivity micro-accelerometers in the application field of micro-accelerometers, in recent years, scientists from various countries have begun to apply field-effect transistors to the research of micro-mechanical sensing structures. The feasibility of applying transistors to micro-accelerometers has verified the high sensitivity characteristics of micro-accelerometers using field-effect transistors. According to relevant reports at home and abroad, the current research directions of scientists from various countries are mostly focused on metal-semiconductor field-effect transistors (Metal-Semiconductor Field-Effect Transistor, MESFET), metal-oxide layer-semiconductor-field-effect transistors ( Metal-Oxide-Semiconductor Field-Effect Transistor, MOSFET). There is no relevant research on the application of high electron mobility transistors in micro accelerometers.

所述高电子迁移率晶体管(High Electronic Mobility Transistor,简称HEMT)是20世纪80年代初发展起来的,是基于调制掺杂而建立的一种新型晶体管。高电子迁移率晶体管HEMT采用调制掺杂结构,在异质结窄带隙半导体材料一侧不掺杂,而在宽带隙半导体材料一侧掺杂施主杂质,这样施主杂质电离产生电子和带正电荷的施主电离杂质中心。在高电子迁移率晶体管HEMT中n型掺杂的宽带隙半导体材料的费米能级靠近导带,而窄带隙半导体材料的费米能级基本在禁带的中间位置,由于异质结两侧材料的费米能级位置不同,电子将从费米能级相对较高的宽带隙材料一侧转移到较低的窄带隙材料一侧,使沟道中的电子和施主电离杂质空间分离,在沟道内形成二维电子气(2DEG)。同时,由空间电荷建立起一个强电场,在强电场的作用下,异质结界面附近的能带发生弯曲。在外加电场作用下,能带弯曲加大,这样就可以形成狭窄的反型层势阱,在沟道内形成量子阱。由于量子阱的宽度和电子的德布罗意波波长可比,在垂直于异质结界面的z方向上能量发生量子化,2DEG在z方向的运动失去自由度,只在平行于界面的X、Y方向上可以自由运动。2DEG具有许多引人注目的特点,其电子迁移率μ远高于体材料的电子迁移率。通过在掺杂层和沟道之间生长非掺杂隔离层,使2DEG与施主电离杂质中心进一步空间分离,减少了电离杂质散射的影响,进一步提高了迁移率。低温下,电离杂质散射的影响减小,2DEG的电子输运特性更为优越。The high electron mobility transistor (High Electronic Mobility Transistor, referred to as HEMT) was developed in the early 1980s and is a new type of transistor based on modulation doping. High electron mobility transistor HEMT adopts a modulated doping structure. The side of the heterojunction narrow-bandgap semiconductor material is not doped, and the side of the wide-bandgap semiconductor material is doped with donor impurities, so that the ionization of the donor impurities generates electrons and positively charged The donor ionizes the impurity centers. In the high electron mobility transistor HEMT, the Fermi level of the n-type doped wide bandgap semiconductor material is close to the conduction band, while the Fermi level of the narrow bandgap semiconductor material is basically in the middle of the forbidden band. The position of the Fermi level of the material is different, and the electrons will be transferred from the side of the wide bandgap material with a relatively high Fermi level to the side of the lower narrow bandgap material, so that the electrons in the channel and the donor ionized impurities are spatially separated. Two-dimensional electron gas (2DEG) is formed in the channel. At the same time, a strong electric field is established by the space charge, and under the action of the strong electric field, the energy band near the heterojunction interface is bent. Under the action of an external electric field, the energy band bending increases, so that a narrow inversion layer potential well can be formed, and a quantum well can be formed in the channel. Since the width of the quantum well is comparable to the wavelength of the De Broglie wave of the electron, the energy is quantized in the z direction perpendicular to the heterojunction interface, and the movement of the 2DEG in the z direction loses the degree of freedom, only in the X and Y directions parallel to the interface. can move freely. 2DEG has many attractive features, and its electron mobility μ is much higher than that of bulk materials. By growing an undoped isolation layer between the doped layer and the channel, the 2DEG is further spatially separated from the donor ionized impurity center, which reduces the impact of ionized impurity scattering and further improves the mobility. At low temperature, the impact of ionized impurity scattering is reduced, and the electron transport properties of 2DEG are more superior.

和普通的场效应晶体管相比,HEMT的沟道传输利用了量子尺寸效应。由于在一维方向上利用异质结的带边能量差对电子进行限制,使电子在纵向运动的能量量子化,形成了很高浓度的二维电子气(2DEG)。沟道内2DEG在横向方向上的运动不受限制,并且沟道电子和施主离子空间上相互分离,因而沟道电子在横向传输时几乎不受杂质离子散射作用,因而具有很高的迁移率。而HEMT的沟道电导强烈的依赖于沟道内2DEG的浓度,当沟道部分材料受到应力作用时,半导体材料的能带结构发生相应变化,会导致限制作用变化,影响到沟道2DEG的浓度,如利用该纳米效应来实现力电转换,可以极大地提高微传感器的探测灵敏度。Compared with ordinary field effect transistors, the channel transmission of HEMTs utilizes the quantum size effect. Since the electrons are confined in the one-dimensional direction by using the band edge energy difference of the heterojunction, the energy of the electrons moving in the longitudinal direction is quantized, and a high concentration two-dimensional electron gas (2DEG) is formed. The movement of 2DEG in the lateral direction in the channel is not restricted, and the channel electrons and donor ions are spatially separated from each other, so the channel electrons are hardly affected by the scattering of impurity ions during lateral transport, so they have high mobility. However, the channel conductance of HEMT strongly depends on the concentration of 2DEG in the channel. When the material in the channel is subjected to stress, the energy band structure of the semiconductor material changes accordingly, which will lead to a change in the confinement effect and affect the concentration of 2DEG in the channel. If the nanometer effect is used to realize electromechanical conversion, the detection sensitivity of the microsensor can be greatly improved.

发明内容Contents of the invention

本发明为了适应微加速度计应用领域对高灵敏度微加速度计的需要,实现高电子迁移率晶体管HEMT力电转换机理在微加速度计上的应用,提供了一种基于高电子迁移率晶体管HEMT的微加速度计。In order to meet the needs of high-sensitivity micro-accelerometers in the application field of micro-accelerometers, and to realize the application of the force-to-electricity conversion mechanism of high-electron-mobility transistor HEMTs in micro-accelerometers, the present invention provides a micro-accelerometer based on high-electron mobility transistor HEMTs. Accelerometer.

本发明是采用如下技术方案实现的:基于高电子迁移率晶体管HEMT的微加速度计,采用以下步骤加工制造:The present invention is realized by adopting the following technical scheme: the micro accelerometer based on the high electron mobility transistor HEMT is processed and manufactured by the following steps:

1、应用分子束外延技术在GaAs衬底上生长出如下表1所示材料层结构的薄膜:1. Apply molecular beam epitaxy to grow a thin film with the material layer structure shown in Table 1 below on the GaAs substrate:

表1Table 1

Figure G2009102279174D00031
Figure G2009102279174D00031

2、应用微机电器件加工技术按如下步骤加工高电子迁移率晶体管HEMT:2. Apply micro-electromechanical device processing technology to process high electron mobility transistor HEMT according to the following steps:

a、按照待加工微加速度计结构的布局,以刻蚀工艺去掉GaAs衬底上除所需要加工高电子迁移率晶体管HEMT位置处薄膜外的所有薄膜;例如:加工四边四梁结构的微加速度计,则需要保留四块用于加工高电子迁移率晶体管HEMT的薄膜,且薄膜保留位置在GaAs衬底上呈“十”字分布(即薄膜保留位置分布在一个“十”字形的四个端部上);而加工单悬臂梁结构,则在GaAs衬底上仅保留单块薄膜即可;a. According to the layout of the micro-accelerometer structure to be processed, remove all the films on the GaAs substrate except the film at the HEMT position where the high electron mobility transistor needs to be processed by etching process; for example: process a micro-accelerometer with a four-sided four-beam structure , you need to reserve four thin films for processing high electron mobility transistor HEMT, and the film retention positions are distributed in a "cross" shape on the GaAs substrate (that is, the thin film retention positions are distributed at the four ends of a "cross" shape above); while processing a single cantilever beam structure, only a single film can be reserved on the GaAs substrate;

b、在GaAs衬底上各保留薄膜处分别加工高电子迁移率晶体管HEMT:b. Processing high electron mobility transistor HEMT at each reserved thin film on the GaAs substrate:

b1、在所述薄膜的欧姆接触层n-GaAs表面首先采用光刻工艺加工出高电子迁移率晶体管HEMT的源极和漏极的欧姆接触图形,然后采用电子束蒸发工艺在欧姆接触层n-GaAs表面形成

Figure G2009102279174D00041
厚的Au/Ge/Ni覆盖层,最后经剥离清洗后,以400℃高温在60s内快速合金,实现晶体管HEMT的源极、漏极金属化,使晶体管HEMT的源极、漏极与所述薄膜的欧姆接触层n-GaAs表面之间形成良好的欧姆接触,其中,高电子迁移率晶体管HEMT的源极为分离设置,即由两分离源极构成,且两分离源极的排列方向与漏极平行;b1. On the surface of the ohmic contact layer n-GaAs of the film, the ohmic contact patterns of the source and drain electrodes of the high electron mobility transistor HEMT are first processed by photolithography, and then the ohmic contact layer n- GaAs surface formation
Figure G2009102279174D00041
The thick Au/Ge/Ni covering layer, after peeling and cleaning, is quickly alloyed at a high temperature of 400°C within 60s to realize the metallization of the source and drain of the transistor HEMT, so that the source and drain of the transistor HEMT are connected to the A good ohmic contact is formed between the surfaces of the thin-film ohmic contact layer n-GaAs, wherein the source of the high electron mobility transistor HEMT is separated, that is, it is composed of two separated sources, and the arrangement direction of the two separated sources is the same as that of the drain. parallel;

b2、以刻蚀工艺在源极和漏极之间的薄膜上加工出与漏极平行、并贯穿整个薄膜的凹槽,且凹槽以薄膜的肖特基接触层n-AlGaAs表面为槽底面;然后以光刻工艺在凹槽槽底中间沿凹槽方向加工栅槽,并在栅槽加工过程中,实时检测源漏两极间的饱和电流,直至源漏两极间的饱和电流达到要求值,获得所需栅槽,随后采用电子束蒸发工艺在凹槽表面、栅槽内形成

Figure G2009102279174D00042
厚的Ti/Pt/Au覆盖层,以剥离法在栅槽处形成栅极,实现晶体管HEMT的栅极金属化,使晶体管HEMT的栅极与所述薄膜的肖特基接触层n-AlGaAs之间形成良好的肖特基势垒;b2. A groove parallel to the drain and running through the entire film is processed on the film between the source and drain by an etching process, and the groove uses the n-AlGaAs surface of the Schottky contact layer of the film as the bottom surface of the groove Then process the gate groove along the direction of the groove in the middle of the bottom of the groove by photolithography, and detect the saturation current between the source and drain poles in real time during the process of gate groove processing until the saturation current between the source and drain poles reaches the required value, Obtain the required grid groove, and then use the electron beam evaporation process to form on the surface of the groove and in the grid groove
Figure G2009102279174D00042
Thick Ti/Pt/Au capping layer, form the gate at the gate groove by lift-off method, realize the gate metallization of the transistor HEMT, make the gate of the transistor HEMT and the Schottky contact layer n-AlGaAs of the film A good Schottky barrier is formed between them;

b3、用PECVD淀积法在已加工出高电子迁移率晶体管HEMT源极、漏极、栅极的薄膜上以230℃温度淀积

Figure G2009102279174D00051
厚的Si3N4钝化层,然后以光刻工艺刻蚀所述Si3N4钝化层,使Si3N4钝化层区域仅覆盖在源极和漏极之间、以及源极和漏极正对侧的边沿处;b3. Use the PECVD deposition method to deposit at 230°C on the film that has processed the source, drain, and gate of the high electron mobility transistor HEMT
Figure G2009102279174D00051
Thick Si 3 N 4 passivation layer, and then etch the Si 3 N 4 passivation layer by photolithography, so that the Si 3 N 4 passivation layer area only covers between the source and drain, and the source and the edge on the side opposite to the drain;

b4、在两分离源极之间加工连接两分离源极的空气桥:①、在已覆盖Si3N4钝化层的薄膜上涂敷光刻胶,并应用光刻工艺在两分离源极正上方形成分别以两分离源极上表面为槽底面的两个桥墩状凹槽,然后采用电子束蒸发工艺或溅射工艺在光刻胶表面和桥墩状凹槽内覆盖

Figure G2009102279174D00052
厚的TiAu或TiW双元金属层;②、在TiAu或TiW双元金属层表面涂敷光刻胶,再次应用光刻工艺在两分离源极正上方形成以TiAu或TiW双元金属层为槽底面的桥形凹槽,然后采用电镀工艺在TiAu或TiW双元金属层上电镀2~5μm厚的Au层;③、用有机溶剂溶解TiAu或TiW双元金属层上方的光刻胶,然后腐蚀掉Au层下方TiAu或TiW双元金属层外的所有TiAu或TiW双元金属层,最后用有机溶剂溶解所述薄膜上残余的光刻胶,即得到所述空气桥,完成所述薄膜上的高电子迁移率晶体管HEMT加工;b4. Process the air bridge connecting the two separated sources between the two separated sources: ①. Coat photoresist on the thin film covered with Si 3 N 4 passivation layer, and apply photolithography technology on the two separated sources Two pier-shaped grooves with the upper surface of the two separated source electrodes as the bottom surface of the groove are formed directly above, and then the surface of the photoresist and the pier-shaped groove are covered by an electron beam evaporation process or a sputtering process.
Figure G2009102279174D00052
Thick TiAu or TiW binary metal layer; ②. Coating photoresist on the surface of TiAu or TiW binary metal layer, and then applying photolithography process to form grooves with TiAu or TiW binary metal layer directly above the two separated sources The bridge-shaped groove on the bottom surface, and then use the electroplating process to electroplate a 2-5 μm thick Au layer on the TiAu or TiW binary metal layer; ③, dissolve the photoresist above the TiAu or TiW binary metal layer with an organic solvent, and then etch Remove all TiAu or TiW binary metal layers outside the TiAu or TiW binary metal layer under the Au layer, and finally dissolve the remaining photoresist on the film with an organic solvent to obtain the air bridge and complete the film on the film. High electron mobility transistor HEMT processing;

3、应用微机电器件加工技术按如下步骤加工微加速度计结构:3. Apply micro-electromechanical device processing technology to process the micro-accelerometer structure according to the following steps:

应用刻蚀工艺将GaAs衬底刻蚀成由外围基座、悬臂梁、以及通过悬臂梁支悬于外围基座中央的质量块构成的微加速度计结构,并使所述加工有高电子迁移率晶体管HEMT的薄膜位于悬臂梁与外围基座的连接处。The GaAs substrate is etched into a micro-accelerometer structure consisting of a peripheral base, a cantilever beam, and a mass block suspended in the center of the peripheral base through the cantilever beam by using an etching process, and the processing has high electron mobility The thin film of the transistor HEMT is located at the junction of the cantilever beam and the peripheral base.

另外,所述微加速度计的加工还包含分别与高电子迁移率晶体管HEMT源极、漏极、栅极对应的引出焊盘的加工,而相应引出焊盘的具体加工为本领域技术人员所公知,因此未在本发明所述加工步骤中进行描述。In addition, the processing of the micro-accelerometer also includes the processing of the lead-out pads corresponding to the high electron mobility transistor HEMT source, drain, and gate respectively, and the specific processing of the corresponding lead-out pads is well known to those skilled in the art , so it is not described in the processing steps of the present invention.

当本发明所述微加速度计感受加速度运动时,质量块产生偏移,带动悬臂梁产生扭曲或弯曲等变形,会使悬臂梁根部设置的高电子迁移率晶体管HEMT沟道中产生应力变化,半导体材料的能带结构将发生相应变化,导致二维电子气2DEG限制作用变化,影响到沟道内2DEG的浓度,最终反映到HEMT的I-V特性变化(如图7所示),利用适当的外围电路将这种变化转换为可测量信号,如电压、电流等形式输出,经过标定就可建立输出信号与被测加速度之间的关系,从而测量外界加速度。本发明所述分子束外延技术、微机电器件加工技术中的刻蚀工艺、光刻工艺、PECVD淀积法等都是公知、成熟的加工工艺。When the micro-accelerometer of the present invention feels the acceleration movement, the mass block will shift, which will cause the cantilever beam to be twisted or bent, which will cause stress changes in the channel of the high electron mobility transistor HEMT arranged at the root of the cantilever beam. The energy band structure of the HEMT will change accordingly, resulting in a change in the confinement of the two-dimensional electron gas 2DEG, affecting the concentration of 2DEG in the channel, and finally reflecting the change in the I-V characteristics of the HEMT (as shown in Figure 7). This change can be converted into a measurable signal, such as output in the form of voltage, current, etc. After calibration, the relationship between the output signal and the measured acceleration can be established to measure the external acceleration. The molecular beam epitaxy technology described in the present invention, the etching technology, the photolithography technology, the PECVD deposition method and the like in the micro-electromechanical device processing technology are all well-known and mature processing technologies.

针对本发明所述微加速度计及其上设置的高电子迁移率晶体管HEMT分别进行了如下所示的一系列测试实验:A series of test experiments as shown below have been carried out respectively for the micro-accelerometer of the present invention and the high electron mobility transistor HEMT provided thereon:

1、对微加速度计上设置的高电子迁移率晶体管HEMT进行半导体参数测试实验:利用半导体参数特性分析仪安捷伦4156C分析高电子迁移率晶体管HEMT的电学特性,VGS为-2.3~0.7V,步长为0.5V,高电子迁移率晶体管HEMT的输出特性曲线和转移特性曲线分别如图3和图4所示。测试结果表明,微加速度计上设置的高电子迁移率晶体管HEMT性能良好,其阈值电压约为-2.8V,满足设计要求;1. Conduct semiconductor parameter testing experiments on the high electron mobility transistor HEMT set on the micro accelerometer: use the semiconductor parameter characteristic analyzer Agilent 4156C to analyze the electrical characteristics of the high electron mobility transistor HEMT, V GS is -2.3 ~ 0.7V, step by step As long as 0.5V, the output characteristic curve and transfer characteristic curve of high electron mobility transistor HEMT are shown in Fig. 3 and Fig. 4 respectively. The test results show that the high electron mobility transistor HEMT set on the micro accelerometer has good performance, and its threshold voltage is about -2.8V, which meets the design requirements;

2、对微加速度计进行静态压力实验,验证微加速度计在静态加压的条件下,微加速度计的I-V特性和转移特性的变化情况。加压前后的输出特性曲线和转移特性曲线分别如图7和图8所示。2. Conduct static pressure experiments on the micro-accelerometer to verify the changes of the micro-accelerometer's I-V characteristics and transfer characteristics under static pressure conditions. The output characteristic curves and transfer characteristic curves before and after pressurization are shown in Fig. 7 and Fig. 8, respectively.

从图7可以看出,加压后I-V特性曲线发生了上移,变化较为明显的区域是饱和区,而且栅压越大曲线上移越明显;从图8可以看出,加压后转移特性曲线斜率变大,且曲线变化趋势与I-V特性曲线变化趋势一致。It can be seen from Figure 7 that the I-V characteristic curve shifts up after pressurization, and the area where the change is more obvious is the saturation region, and the larger the gate voltage is, the more obvious the upward shift of the curve is; it can be seen from Figure 8 that the transfer characteristic after pressurization The slope of the curve becomes larger, and the change trend of the curve is consistent with the change trend of the I-V characteristic curve.

3、对微加速度计进行压阻系数重力实验:应用Agilent 4156C半导体特性分析仪测试微加速度计在平行于高电子迁移率晶体管HEMT生长方向(Z方向)加速度为±1g时高电子迁移率晶体管HEMT的I-V特性曲线对比图,其中,栅源电压从-2.3~0.7V,步长为0.6V,如图5所示,表明±1g时高电子迁移率晶体管HEMT的电流发生变化;应用Polytec微系统分析仪测出本发明所述微加速度计微悬臂梁-质量块结构真实尺寸,将数据带入ANSYS软件进行Z方向加速度为1g的应力仿真分析,估算得悬臂梁最大应力,根据压阻系数公式 π = ΔI Iσ = ( 1.72 ± 0.33 ) × 10 - 7 Pa - 1 , 其中,σ为应力,I为电流值,ΔI为电流的变化值。3. Piezoresistive gravity gravity experiment on the micro accelerometer: use the Agilent 4156C semiconductor characteristic analyzer to test the high electron mobility transistor HEMT when the micro accelerometer is parallel to the growth direction of the high electron mobility transistor HEMT (Z direction) and the acceleration is ±1g The comparison chart of the IV characteristic curve, in which, the gate-source voltage is from -2.3 to 0.7V, and the step size is 0.6V, as shown in Figure 5, which shows that the current of the high electron mobility transistor HEMT changes at ±1g; the application of the Polytec microsystem The analyzer measures the real size of the micro-accelerometer micro-cantilever beam-mass structure of the present invention, and the data is brought into ANSYS software to carry out stress simulation analysis where the acceleration in the Z direction is 1g, and the maximum stress of the cantilever beam is estimated, according to the piezoresistive coefficient formula π = ΔI Iσ = ( 1.72 ± 0.33 ) × 10 - 7 Pa - 1 , Among them, σ is the stress, I is the current value, and ΔI is the change value of the current.

另经分析验证,绘制高电子迁移率晶体管HEMT漏极电压与压阻系数的关系图如图6所示,表明高电子迁移率晶体管HEMT不同偏压下压阻系数不同,饱和区的变化比线性区明显,且GaAs材料HEMT的最大压阻系数比SI(硅)材料压敏电阻高出三个数量级,说明高电子迁移率晶体管HEMT非常有益于在高灵敏且阻值可调的微/纳机电压阻性器件上应用。In addition, after analysis and verification, the relationship between the drain voltage of the high electron mobility transistor HEMT and the piezoresistive coefficient is drawn as shown in Figure 6, which shows that the piezoresistive coefficient of the high electron mobility transistor HEMT is different under different bias voltages, and the change ratio in the saturation region is linear The region is obvious, and the maximum piezoresistive coefficient of GaAs material HEMT is three orders of magnitude higher than that of SI (silicon) material piezoresistor, indicating that high electron mobility transistor HEMT is very beneficial in highly sensitive and adjustable resistance micro/nano machine applications on voltage resistive devices.

此外,将本发明所述微加速度计接入外围电路,进行静态加压触发实验,由示波器记录触发输出如图9所示,表明所述微加速度计响应较好,且较为稳定。In addition, the micro accelerometer of the present invention was connected to the peripheral circuit, and the static pressurization trigger experiment was carried out, and the trigger output recorded by the oscilloscope is shown in Figure 9, which shows that the micro accelerometer has a better response and is relatively stable.

充分说明了本发明所述微加速度计上设置的高电子迁移率晶体管HEMT具有明显的力电转换特性。It fully demonstrates that the high electron mobility transistor HEMT arranged on the micro accelerometer of the present invention has obvious electromechanical conversion characteristics.

4、对微加速度计进行灵敏度特性实验:将微加速度计固定于VR8500振动台测试系统的振动台上,通过振动台施加正弦激励信号,测试得微加速度计的输出信号如图10、11所示,图10为滤波前的电压输出信号,图11为滤波后的电压输出信号;并获得微加速度计电压输出与加速度的线性拟合关系,如图12所示,可以发现:微加速度计输出的测试点都在线性拟合线的附近摆动,表现出较好的线性度,拟合后微加速度计的灵敏度为10.68mV/g。充分说明本发明所述微加速度计能够实现高灵敏检测。4. Carry out sensitivity characteristic experiments on the micro-accelerometer: fix the micro-accelerometer on the vibration table of the VR8500 vibration table test system, apply a sinusoidal excitation signal through the vibration table, and test the output signal of the micro-accelerometer as shown in Figures 10 and 11 , Figure 10 is the voltage output signal before filtering, and Figure 11 is the voltage output signal after filtering; and the linear fitting relationship between the micro-accelerometer voltage output and acceleration is obtained, as shown in Figure 12, it can be found that: the micro-accelerometer output The test points all swing near the linear fitting line, showing good linearity, and the sensitivity of the micro accelerometer after fitting is 10.68mV/g. It fully demonstrates that the micro-accelerometer of the present invention can realize high-sensitivity detection.

本发明有效利用高电子迁移率晶体管HEMT的力电转换机理,实现了高电子迁移率晶体管HEMT在微加速度计上的应用,本发明所述微加速度计在试验过程中表现出了灵敏度高、线性度好等特点,完全可以适应微加速度计应用领域的实际需要。The present invention effectively utilizes the electromechanical conversion mechanism of the high electron mobility transistor HEMT, and realizes the application of the high electron mobility transistor HEMT on the micro-accelerometer, and the micro-accelerometer of the present invention shows high sensitivity, linear Good accuracy and other characteristics, can fully adapt to the actual needs of the micro-accelerometer application field.

附图说明Description of drawings

图1为本发明的加工制造工艺流程图;Fig. 1 is a processing and manufacturing process flow chart of the present invention;

图2为本发明所述微加速度计上高电子迁移率晶体管HEMT的扫描电镜图;Fig. 2 is the scanning electron micrograph of high electron mobility transistor HEMT on the micro accelerometer of the present invention;

图3为本发明所述微加速度计上高电子迁移率晶体管HEMT的输出特性曲线;Fig. 3 is the output characteristic curve of high electron mobility transistor HEMT on the micro accelerometer of the present invention;

图4为本发明所述微加速度计上高电子迁移率晶体管HEMT的转移特性曲线;Fig. 4 is the transfer characteristic curve of high electron mobility transistor HEMT on the micro accelerometer of the present invention;

图5为本发明所述微加速度计上高电子迁移率晶体管HEMT在Z方向加速度为±1g时的I-V特性曲线对比图;Fig. 5 is the comparison chart of the I-V characteristic curve when the high electron mobility transistor HEMT on the micro accelerometer of the present invention is when the acceleration in the Z direction is ± 1g;

图6为本发明所述微加速度计上高电子迁移率晶体管HEMT漏极电压与压阻系数的关系图(栅压为-1.7V);Fig. 6 is the relationship diagram (grid voltage is-1.7V) of high electron mobility transistor HEMT drain voltage and piezoresistive coefficient on the micro accelerometer of the present invention;

图7为本发明所述微加速度计加压前后I-V特性曲线对比图;Fig. 7 is the comparison chart of I-V characteristic curve before and after micro-accelerometer pressurization of the present invention;

图8为本发明所述微加速度计加压前后转移特性曲线对比图;Fig. 8 is a comparison diagram of transfer characteristic curves before and after pressurization of the micro accelerometer according to the present invention;

图9为本发明所述微加速度计进行静态加压触发实验得到的触发输出图;Fig. 9 is the trigger output figure that the micro-accelerometer of the present invention carries out static pressure trigger experiment and obtains;

图10为本发明所述微加速度计的滤波前电压输出信号图;Fig. 10 is the voltage output signal diagram before filtering of the micro accelerometer of the present invention;

图11为本发明所述微加速度计的滤波后电压输出信号图;Fig. 11 is the voltage output signal diagram after filtering of the micro-accelerometer of the present invention;

图12为本发明所述微加速度计电压输出与加速度的线性拟合关系图;Fig. 12 is the linear fitting relationship diagram of micro-accelerometer voltage output and acceleration according to the present invention;

图中:1-GaAs衬底;2-薄膜;3-漏极;4-源极;5-凹槽;6-栅极;7-Si3N4钝化层;8-光刻胶;9-双元金属层;10-光刻胶;11-桥形凹槽;12-Au层;13-空气桥;14-外围基座;15-悬臂梁;16-质量块;17-高电子迁移率晶体管HEMT。In the figure: 1-GaAs substrate; 2-film; 3-drain; 4-source; 5-groove; 6-gate; 7-Si 3 N 4 passivation layer; 8-photoresist; 9 - binary metal layer; 10 - photoresist; 11 - bridge groove; 12 - Au layer; 13 - air bridge; 14 - peripheral base; 15 - cantilever beam; 16 - mass block; 17 - high electron mobility rate transistor HEMT.

具体实施方式Detailed ways

基于高电子迁移率晶体管HEMT的微加速度计,采用以下步骤加工制造:Microaccelerometers based on high electron mobility transistor HEMTs are manufactured using the following steps:

(1)、应用分子束外延技术在GaAs衬底1上生长出如下表1所示材料层结构的薄膜2:如图1中c所示(1) A thin film 2 with the material layer structure shown in Table 1 is grown on the GaAs substrate 1 by molecular beam epitaxy technology: as shown in c in Figure 1

表1Table 1

Figure G2009102279174D00091
Figure G2009102279174D00091

(2)、应用微机电器件加工技术按如下步骤加工高电子迁移率晶体管HEMT:(2) Apply the micro-electromechanical device processing technology to process the high electron mobility transistor HEMT according to the following steps:

a、按照待加工微加速度计结构的布局,以刻蚀工艺去掉GaAs衬底1上除所需要加工高电子迁移率晶体管HEMT位置处薄膜2外的所有薄膜;例如:加工四边四梁结构的微加速度计,则需要保留四块用于加工高电子迁移率晶体管HEMT的薄膜,且薄膜保留位置在GaAs衬底上呈“十”字分布(即薄膜保留位置分布在一个“十”字形的四个端部上),如图1中a所示;而加工单悬臂梁结构,则在GaAs衬底上仅保留单块薄膜即可;a. According to the layout of the micro-accelerometer structure to be processed, remove all the films on the GaAs substrate 1 except the film 2 at the position of the high electron mobility transistor HEMT that needs to be processed by etching process; For the accelerometer, it is necessary to reserve four thin films for processing the high electron mobility transistor HEMT, and the thin film retention positions are distributed in a "cross" shape on the GaAs substrate (that is, the thin film retention positions are distributed in four "cross" shaped end), as shown in a in Figure 1; while processing a single cantilever beam structure, only a single film can be reserved on the GaAs substrate;

b、在GaAs衬底1上各保留薄膜处分别加工高电子迁移率晶体管HEMT:b. Process the high electron mobility transistor HEMT at each reserved thin film on the GaAs substrate 1:

b1、在所述薄膜的欧姆接触层n-GaAs表面首先采用光刻工艺加工出高电子迁移率晶体管HEMT的源极4和漏极3的欧姆接触图形,如图1中b1-1所示,然后采用电子束蒸发工艺在欧姆接触层n-GaAs表面形成

Figure G2009102279174D00101
厚的Au/Ge/Ni覆盖层,最后经剥离清洗后,以400℃高温在60s内快速合金,实现晶体管HEMT的源极4、漏极3金属化,使晶体管HEMT的源极4、漏极3与所述薄膜的欧姆接触层n-GaAs表面之间形成良好的欧姆接触,其中,高电子迁移率晶体管HEMT的源极为分离设置,即由两分离源极4构成,如图1中b4-1所示,且两分离源极4的排列方向与漏极3平行,如图1中b1-2所示,图1中b4-1为b1-2的右视图;b1. On the surface of the ohmic contact layer n-GaAs of the thin film, the ohmic contact pattern of the source electrode 4 and the drain electrode 3 of the high electron mobility transistor HEMT is first processed by a photolithography process, as shown in b1-1 in Fig. 1, Then the electron beam evaporation process is used to form the ohmic contact layer n-GaAs surface
Figure G2009102279174D00101
The thick Au/Ge/Ni covering layer, after peeling and cleaning, is quickly alloyed at a high temperature of 400°C within 60s to realize the metallization of the source 4 and drain 3 of the transistor HEMT, so that the source 4 and drain of the transistor HEMT 3 form a good ohmic contact with the n-GaAs surface of the ohmic contact layer of the thin film, wherein the source of the high electron mobility transistor HEMT is separated, that is, it is composed of two separated sources 4, as shown in b4- 1, and the arrangement direction of the two separated source electrodes 4 is parallel to the drain electrode 3, as shown in b1-2 in Figure 1, and b4-1 in Figure 1 is the right view of b1-2;

b2、以刻蚀工艺在源极4和漏极3之间的薄膜上加工出与漏极平行、并贯穿整个薄膜的凹槽5,且凹槽5以薄膜的肖特基接触层n-AlGaAs表面为槽底面,如图1中b2-1所示;然后以光刻工艺在凹槽5槽底中间沿凹槽5方向加工栅槽,并在栅槽加工过程中,实时检测源漏两极间的饱和电流,直至源漏两极间的饱和电流达到要求值,获得所需栅槽,随后采用电子束蒸发工艺在凹槽表面、栅槽内形成

Figure G2009102279174D00102
厚的Ti/Pt/Au覆盖层,以剥离法在栅槽处形成栅极6,实现晶体管HEMT的栅极金属化,如图1中b2-2所示,使晶体管HEMT的栅极与所述薄膜的肖特基接触层n-AlGaAs之间形成良好的肖特基势垒;b2. A groove 5 parallel to the drain electrode and running through the entire film is processed on the thin film between the source electrode 4 and the drain electrode 3 by an etching process, and the groove 5 is formed by the Schottky contact layer n-AlGaAs of the thin film The surface is the bottom of the groove, as shown in b2-1 in Figure 1; then, the gate groove is processed along the direction of the groove 5 in the middle of the bottom of the groove 5 by photolithography, and the gap between the source and drain electrodes is detected in real time during the processing of the gate groove. Saturation current until the saturation current between the source and drain reaches the required value, and the required grid groove is obtained, and then the electron beam evaporation process is used to form on the surface of the groove and in the grid groove
Figure G2009102279174D00102
Thick Ti/Pt/Au covering layer, form the gate 6 at the gate groove by the lift-off method, realize the gate metallization of the transistor HEMT, as shown in b2-2 in Figure 1, make the gate of the transistor HEMT and the described A good Schottky barrier is formed between the Schottky contact layer n-AlGaAs of the film;

b3、用PECVD淀积法在已加工出高电子迁移率晶体管HEMT源极4、漏极3、栅极6的薄膜上以230℃温度淀积

Figure G2009102279174D00111
厚的Si3N4钝化层7,如图1中b3-1所示,然后以光刻工艺刻蚀所述Si3N4钝化层7,使Si3N4钝化层7区域仅覆盖在源极4和漏极3之间、以及源极4和漏极3正对侧的边沿处,如图1中b3-2所示;b3. Use the PECVD deposition method to deposit at 230°C on the thin film that has processed the source 4, drain 3, and gate 6 of the high electron mobility transistor HEMT
Figure G2009102279174D00111
thick Si 3 N 4 passivation layer 7 , as shown in b3-1 in Fig. Covering between the source electrode 4 and the drain electrode 3, and at the edge of the side directly opposite the source electrode 4 and the drain electrode 3, as shown in b3-2 in FIG. 1;

b4、在两分离源极4之间加工连接两分离源极的空气桥13:①、在已覆盖Si3N4钝化层7的薄膜上涂敷光刻胶8,并应用光刻工艺在两分离源极4正上方形成分别以两分离源极4上表面为槽底面的两个桥墩状凹槽,然后采用电子束蒸发工艺或溅射工艺在光刻胶表面和桥墩状凹槽内覆盖

Figure G2009102279174D00112
厚的TiAu或TiW双元金属层9,如图1中b4-2所示;②、在TiAu或TiW双元金属层9表面涂敷光刻胶10,再次应用光刻工艺在两分离源极正上方形成以TiAu或TiW双元金属层为槽底面的桥形凹槽11,如图1中b4-3所示,然后采用电镀工艺在TiAu或TiW双元金属层9上电镀2~5μm厚的Au层12,如图1中b4-4所示;③、用有机溶剂溶解TiAu或TiW双元金属层9上方的光刻胶10,然后腐蚀掉Au层下方TiAu或TiW双元金属层9外的所有TiAu或TiW双元金属层,最后用有机溶剂溶解所述薄膜上残余的光刻胶8,即得到所述空气桥13,如图1中b4-5所示,完成所述薄膜上的高电子迁移率晶体管HEMT加工;b4. Process the air bridge 13 between the two separated source electrodes 4 to connect the two separated source electrodes: ①. Apply a photoresist 8 on the film covered with the Si 3 N 4 passivation layer 7, and apply a photolithography process on the Two pier-shaped grooves are formed directly above the two separated source electrodes 4, with the upper surface of the two separated source electrodes 4 as the bottom surface of the groove, and then the surface of the photoresist and the pier-shaped groove are covered by electron beam evaporation or sputtering.
Figure G2009102279174D00112
Thick TiAu or TiW binary metal layer 9, as shown in b4-2 in Figure 1; ②, coating photoresist 10 on the surface of TiAu or TiW binary metal layer 9, and applying photolithography process again to separate the source A bridge-shaped groove 11 with the TiAu or TiW binary metal layer as the bottom surface of the groove is formed directly above, as shown in b4-3 in Figure 1, and then the TiAu or TiW binary metal layer 9 is electroplated with a thickness of 2 to 5 μm by using an electroplating process Au layer 12, as shown in b4-4 in Figure 1; ③, dissolve the photoresist 10 above the TiAu or TiW binary metal layer 9 with an organic solvent, and then etch away the TiAu or TiW binary metal layer 9 below the Au layer All the TiAu or TiW binary metal layers outside, and finally dissolve the remaining photoresist 8 on the film with an organic solvent to obtain the air bridge 13, as shown in b4-5 in Figure 1, and complete the film on the film. HEMT processing of high electron mobility transistors;

(3)、应用微机电器件加工技术按如下步骤加工微加速度计结构:如图1中d所示,应用刻蚀工艺将GaAs衬底1刻蚀成由外围基座14、悬臂梁15、以及通过悬臂梁15支悬于外围基座14中央的质量块16构成的微加速度计结构,并使所述加工有高电子迁移率晶体管HEMT17的薄膜位于悬臂梁15与外围基座14的连接处。(3), apply the micro-electromechanical device processing technology to process the micro-accelerometer structure according to the following steps: as shown in d in Figure 1, the GaAs substrate 1 is etched into a peripheral base 14, a cantilever beam 15, and The micro accelerometer structure is formed by the mass block 16 suspended in the center of the peripheral base 14 by the cantilever beam 15 , and the thin film processed with the high electron mobility transistor HEMT17 is located at the junction of the cantilever beam 15 and the peripheral base 14 .

Claims (1)

1. job operation based on the micro-acceleration gauge of high electron mobility transistor (HEMT) is characterized in that adopting the following steps processing and manufacturing:
(1), use molecular beam epitaxy technique grows material layer structures as shown in table 1 below on GaAs substrate (1) film (2):
Table 1
Figure FSB00000365406200011
(2), use the micro electro mechanical device process technology and process high electron mobility transistor (HEMT) as follows:
A, according to the layout of micro-acceleration gauge structure to be processed, remove GaAs substrate (1) with etching technics and go up all films except that required processing high electron mobility transistor (HEMT) position film (2);
B, on GaAs substrate (1), respectively keep the film place and process high electron mobility transistor (HEMT) respectively:
B1, at first adopt photoetching process to process the source electrode (4) of high electron mobility transistor (HEMT) and the Ohmic contact figure of drain electrode (3) on the ohmic contact layer n-GaAs surface of described film, adopt electron beam evaporation process to form then on ohmic contact layer n-GaAs surface
Figure FSB00000365406200012
Thick Au/Ge/Ni overlayer, after after peeling off cleaning, with 400 ℃ of high temperature quick alloy in 60s, realize source electrode (4), drain electrode (3) metallization of transistor HEMT, make between the ohmic contact layer n-GaAs surface of source electrode (4), drain electrode (3) and described film of transistor HEMT and form good Ohmic contact, wherein, the source electrode of high electron mobility transistor (HEMT) is provided with for separating, promptly constitute, and the orientation of two separated source (4) is parallel with drain electrode (3) by two separated source (4);
B2, process on the film between (3) at source electrode (4) and drain electrode and drain parallel and run through the groove (5) of whole film, and groove (5) is a groove bottom with the schottky contact layer n-AlGaAs surface of film with etching technics; In the middle of groove (5) bottom land, process the grid groove with photoetching process then along groove (5) direction, and in grid groove process, detection resources is leaked the saturation current of two interpolars in real time, the saturation current that leaks two interpolars until the source reaches required value, obtain required grid groove, adopt electron beam evaporation process in groove surfaces, grid groove, to form subsequently
Figure FSB00000365406200021
Thick Ti/Pt/Au overlayer forms grid (6) to peel off method at grid groove place, realize the gate metalized of transistor HEMT, the good Schottky barrier of formation between the grid that makes transistor HEMT and the schottky contact layer n-AlGaAs of described film;
B3, with the PECVD sedimentation on the film that processes high electron mobility transistor (HEMT) source electrode (4), drain electrode (3), grid (6) with 230 ℃ of temperature deposits Thick Si 3N 4Passivation layer (7) is then with the described Si of photoetching process etching 3N 4Passivation layer (7) makes Si 3N 4Passivation layer (7) zone only covers between source electrode (4) and the drain electrode (3) and the source electrode (4) and (3) edge over against side that drains;
1., covering Si b4, processing connects the air bridges (13) of two separated source between two separated source (4): 3N 4Apply photoresist (8) on the film of passivation layer (7), and to use that photoetching process forms directly over two separated source (4) be two bridge pier shape grooves of groove bottom with two separated source (4) upper surface respectively, adopts electron beam evaporation process or sputtering technology to cover in the surperficial and bridge pier shape groove at photoresist then
Figure FSB00000365406200023
Thick TiAu or TiW double base metal level (9); 2., at TiAu or TiW double base metal level (9) surface applied photoresist (10), using once more that photoetching process forms directly over two separated source with TiAu or TiW double base metal level is the bridge connected in star (11) of groove bottom, adopts electroplating technology to go up at TiAu or TiW double base metal level (9) then and electroplates the thick Au layer (12) of 2~5 μ m; 3., with the photoresist (10) above organic solvent dissolution TiAu or the TiW double base metal level (9), erode Au layer below TiAu or outer all TiAu or the TiW double base metal level of TiW double base metal level (9) then, use photoresist (8) remaining on the described film of organic solvent dissolution at last, promptly obtain described air bridges (13), finish high electron mobility transistor (HEMT) (17) processing on the described film;
(3), use the micro electro mechanical device process technology and process the micro-acceleration gauge structure as follows:
Use etching technics and GaAs substrate (1) is etched into by peripheral pedestal (14), semi-girder (15) and by semi-girder (15) is suspended from the micro-acceleration gauge structure that the mass (16) of peripheral pedestal (14) central authorities constitutes, and make the described film that is processed with high electron mobility transistor (HEMT) (17) be positioned at the junction of semi-girder (15) and peripheral pedestal (14).
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