CN101541180A - Suspension concentrates for improving the root absorption of agrochemical active ingredients - Google Patents
Suspension concentrates for improving the root absorption of agrochemical active ingredients Download PDFInfo
- Publication number
- CN101541180A CN101541180A CNA2007800435497A CN200780043549A CN101541180A CN 101541180 A CN101541180 A CN 101541180A CN A2007800435497 A CNA2007800435497 A CN A2007800435497A CN 200780043549 A CN200780043549 A CN 200780043549A CN 101541180 A CN101541180 A CN 101541180A
- Authority
- CN
- China
- Prior art keywords
- spp
- composition
- agent
- oxyalkylated
- reactive compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring
Landscapes
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Agronomy & Crop Science (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
According to the invention, the absorption of active ingredients from plant protection agents can be increased by suitable adjuvants, thus improving the action of the plant protection agents. The invention also relates to the corresponding adjuvants, methods and compositions.
Description
Thereby the present invention relates to by using proper auxiliary agent to absorb the biological action that improves water-based farmingization colloidal suspending agent (suspension concentrate) in the soil application with the root that improves reactive compound; And relate to the purposes that described colloidal suspending agent is used to prevent and treat harmful insect or plant pathogen.
The advantage of the inventive method is, the effect that the composition of the application of the invention can reduce the amount of application of reactive compound or can be improved when rate of application is constant.In addition, it also can reduce to water consumption minimum.
In this article, auxiliary agent is a kind ofly to improve the biological action of reactive compound in the present composition and itself does not show the component of biological action.Auxiliary agent is preferably sneaked in the concentrate formulation of farmingization reactive compound (canned preparation (in-can formulation)).These finished product preparation help avoid dose error and help to improve the farmingization product safety of user when using.In addition, use with the bucket method of mixing and to compare, can avoid the unnecessary use of packaging material.
The farmingization reactive compound can be used in every way with the control pest.Except that cauline leaf is handled, also can be by for example (showerdrenching) executed, sprayed to spraying, pour water (watering), side on soil, the built on stilts mode of watering (overhead drenching) or using irrigation system to use (drip irrigation) of sprinkling is handled cultivation matrix.Described matrix not only can be soil, also can be the special matrix based on following material, and particularly: peat moss, coconut fibre, rock wool are for example
Float stone, expanded clay as
Or
Soil clay particle (clay granule) for example
Foamed plastics as
Vermiculite, perlite, synthetic soil as
Or the combination of these matrix.Hereinafter, these cultivation matrixes all are called soil.Except that can handling cultivation matrix, another kind of relevant method of application is for directly adding root aqueous phase on every side by for example buoyancy tank method or rice field method with reactive compound.By being applied to reactive compound in the soil or on the soil or directly be applied to aqueous phase, the pest that survives in soil/water being contacted with reactive compound, and cause the absorption of the internal absorption reactive compound of root.
The several formulations that is used to improve the farmingization reactive compound effect of leaf portion is known.For example, DE-A 10 129 855 has put down in writing the oil base colloidal suspending agent and can improve absorption by the blade epidermis by adding bleeding agent.The also known water base colloidal suspending agent that improves the absorption of leaf portion.For example, WO05/036963 has put down in writing such preparation, and it also comprises at least a bleeding agent except comprising some bactericide.Be suitable for the bleeding agent described in the preparation that leaf portion uses at these and can infiltrate the epidermis of plant and be defined from water-based spray liquid and/or spraying liquid layer, thereby can improve the animal migration of reactive compound in epidermis by them.Can adopt and be documented in document (131-152) method in is measured this characteristic for Baur et al.1997, Pesticide Science 51.Also known illustrated blade epidermis is to the mechanism of reactive compound absorption.Mode that can example is mentioned following publication: Hull, H.M. (1970) Residue Reviews 31,1-150; Hartley, G.S., Graham-Bryce, I.L. (1980) Academic Press, London; Price, C.E., Anderson, N.H. (1985) Pestic.Sci., 16,369-377; Kirkwood, R.C. (1993) Pestic.Sci.38,93-102; Holloway, P.J., Rees, R.T., Stock, D. (eds.) Springer-Verlag, Berlin (1994);
J., Baur P. (1994) Pesticide Sci.42,185-208.The also known used additives that makes improves the animal migration of reactive compound in soil system.Griffith and Miller (McMullan, P.M. (ed.) 1998, Adjuvants for Agrochemicals.Proceedings of the 5th International Symposium on Adjuvants forAgrochemicals (1998), the Memphis, the U.S., 233-239 page or leaf and 291-297 page or leaf) adding of having put down in writing surfactant can influence the interaction between soil mineral and the water, thus improve water and the permeability by the defeated reactive compound of water transport.Various this purpose non-ionic surface active agents that are applicable to have been mentioned.Other people has put down in writing surfactant and how to have reduced the spray liquid surface tension and improve the soil permeability effect.Howell (McMullan, P.M. (ed.) 1998, Adjuvantsfor Agrochemicals.Proceedings of the 5th International Symposium onAdjuvants for Agrochemicals (1998), the Memphis, U.S. 247-253 page or leaf) put down in writing the effect of trisilalkane surfactant, it reduces to below the 30mN/m static surface tension of the permethrin (permethrin) that has horizontal and vertical animal migration in polytype soil.By improving capillarity, obtained to have the soil in more thinner holes.Chung (PesticideScience (1993), 38 (2-3), 250-252 page or leaf) has put down in writing similarly and has improved the mechanism that atrazine (atrazine) acts on by adding auxiliary agent.
, auxiliary agent does not still have record to the farming reactive compound so far by the influence of the absorption of root system.Described document same not mentioned absorption and Related Mechanism (Plant rootsGrowth, activity and interactions with soils, Peter Gregory by root system; BlackwellPublishing (2006)).
An object of the present invention is to provide the farmingization composition, it comprises the auxiliary agent that is suitable for increasing the reactive compound absorption of being undertaken by root system.In addition, these compositions should have enough stable storings and have good biologic activity.
Therefore, the invention provides suitable auxiliary agents and be used to improve the purposes that reactive compound absorbs by root system.Therefore, the present invention also provides the preparation that comprises these auxiliary agents.The present invention also provides these auxiliary agents or these farm chemical preparations to be used to improve the purposes of soil application substantial increase in the number of middle peasants composition effect, described use by for example to soil spray, pour water, side is executed, spray, built on stilts sprinkling watered or used irrigation system to use the mode of (drip irrigation), and directly use under the situation in water and it is directly contacted with this water and carry out.In addition, the present invention also provides these preparations to be used to prevent and treat the purposes that soil passes pest and leaf insects.
The present invention now provides new water-based colloidal suspending agent, and it comprises:
Be the farming reactive compound that is selected from insecticide and/or bactericide of solid under-at least a room temperature,
-at least a auxiliary agent,
-at least a non-ionic surface active agent and/or at least a anion surfactant,
-at least a antifreezing agent, and
-one or more are selected from the additive of defoamer, preservative, antioxidant, spreader-sticker, colouring agent and/or thickener.
Because colloidal suspending agent reality of the present invention does not comprise organic solvent, in any case all less than 7.5g/l, so they are called as water-based.
Suitable non-ionic surface active agent is usually used in this compounds of farmingization composition for all.Can preferably mention the polyethylene/polypropylene oxides block copolymer, the polyglycol ether of straight chain alcohol, the product of fatty acid and oxirane and/or expoxy propane, and polyvinyl alcohol, polyvinylpyrrolidone, the mixed polymer of polyvinyl alcohol and polyvinylpyrrolidone, the mixed polymer of polyvinyl acetate and PVP(polyvinyl pyrrolidone), and the copolymer of (methyl) acrylic acid and (methyl) acrylate, and can be randomly by phosphorylation, and the alkyl ethoxylate and the alkyl aryl ethoxylates that can randomly be neutralized by alkali, polyoxy amine derivative and nonyl phenol ethoxylate.
Suitable anion surfactant is such material of all Chemical composition thats that are often used in agriculture.The alkali metal salt of preferred alkyl sulfonic acid or alkyl aryl sulphonic acid and alkali salt.
Another kind of preferred anionic surfactants surfactant or dispersant are the salt and the lignosulphonates of condensation product of salt, naphthalene sulfonic acids, phenol sulfonic acid and the formaldehyde of poly styrene sulfonate, polyvinylsulfonic acid salt, naphthalene sulfonic acids/formaldehyde condensation products.
Suitable antifreezing agent is usually used in such material of farmingization composition for all.Preferred urea, glycerine and propane diols (propanediol, propylene glycol).Particularly preferably, colloidal suspending agent of the present invention comprises a kind of antifreezing agent that is selected from polyglycereol and polyglycereol derivative.Polyglycereol and polyglycereol derivative are recorded among the DE-A 100 23 153.Preferred extremely especially brand name is
The polyglycereol of GL and polyglycereol derivative.
Optional other additive that is selected from defoamer, preservative, antioxidant, spreader-sticker, colouring agent and/or thickener that comprises of composition of the present invention.
Suitable defoamer is usually used in the material of farmingization composition for this purpose for all.Preferred silicone oil and dolomol.
Suitable preservative is usually used in the material of farmingization composition for this purpose for all.The example that can mention has
(Bayer joint-stock company) and
Suitable antioxidant is usually used in the material of farmingization composition for this purpose for all.The example that can mention has: and butylated hydroxytoluene (2,6 di tert butyl 4 methyl phenol, BHT), propyl gallate, gallate monooctyl ester, gallate ten diester, butylated hydroxyanisol, propylparaben, Sodium Benzoate and nordihydroguaiaretic acid.Preferred Yoshinox BHT (2,6 di tert butyl 4 methyl phenol, BHT).
Suitable spreader-sticker is usually used in the material of farmingization composition for this purpose for all.Preferred, polyethers modification or organically-modified polysiloxanes.
Suitable colouring agent is usually used in the material of farmingization composition for this purpose for all.The example that can mention has titanium dioxide, pigment-level carbon black, zinc oxide and blue pigment and permanent red FGR.
Suitable thickening is usually used in this type of material of farmingization composition for all.Preferred silicate (for example, originates from Engelhard's
50) or xanthans (for example, originate from Kelko's
S).
In the context of the invention, auxiliary agent is the material that improves the farming reactive compound absorption of plant root in a kind of described hereinafter test system:
Selected crop plants (tomato plant with conventional quantity (greater than 40), cultivated species rentita) seed is sowed in the hole of expanded polystyrene plate (tablet) individually, and this expanded polystyrene plate is filled by the specific sowing soil based on the peat cultivation matrix.The plate that will float places and is equipped with based on 0.1% then
The container of nutrient solution in, and cultivate until reaching required plant size down in 25 ℃, 80% relative atmospheric humidity and illumination in 12 hours (Na gas lamp).The solution that will comprise reactive compound and (possible) auxiliary agent directly adds in the nutrient solution of each container, then this plate is put into.Handle after 12 and 19 days the tomato sprout and be the acetonitrile of 80: 20 (v/v) of gathering: water extraction, and the use HPLC-MS/MS content of detection by quantitative Imidacloprid and related degradation product by rights with ratio.
For this reason, for example, described extraction sample uses Applied Biosystems API4000QTrap
HPLC-MS/MSDetect with MRM pattern (mould).This HPLC system is made up of Agilent 1100 pumps, column oven, degasser and a CTC-PAL automatic sampler.Sample adopts gradient elution (flowing phase is made up of the formic acid of acetonitrile/water/0.1%) to carry out chromatography by reverse mode at Phenomenex GEMINI 3 μ m posts (long 50mm, internal diameter 2.1mm).The mass spectrum condition that is used for detection by quantitative: 256.1＞209.2 (ESI+; Imidacloprid) and 155.9＞111.9 (ESI-; 6-CNA).The peak integrated value adopts external standard method and calibration curve (required correlation coefficient r＞0.99) to measure.Matrix effect takes in by the analyte that adds a kind of known quantity in untreated sample.For every kind of analyte, detection by quantitative limit=1ng/ml.
Use 4 liters of nutrient solutions in each case.The concentration of Imidacloprid is 0.1 μ g Imidacloprid/ml nutrient solution (0.1ppm).The concentration of auxiliary agent to be measured is between 2.5 μ g/ml and 0.1mg/ml (2.5 and 100ppm) in the nutrient solution.
In contrast, carry out identical test and do not add any possibility auxiliary agent.When using auxiliary agent of the present invention, to compare with check experiment, the reactive compound shown in this test absorbs has increased at least 20%.
In this test, the root of plant only contacts with nutrient solution.This other character of having got rid of auxiliary agent for example the distribution in cultivation matrix, CONCENTRATION DISTRIBUTION etc. to root absorb have an influence may.
In addition, find that composition of the present invention also can be by being mixed with each other component, if desired, formed suspension is ground and prepare.Therefore, the present invention also provides a kind of method for preparing the present composition, and it comprises the following component of mixing, and if desired, grinds formed suspension:
Be the farming reactive compound that is selected from insecticide and/or bactericide of solid under-at least a room temperature,
-at least a auxiliary agent,
-at least a non-ionic surface active agent and/or at least a anion surfactant,
-at least a antifreezing agent, and
-one or more are selected from the additive of defoamer, preservative, antioxidant, spreader-sticker, colouring agent and/or thickener.
Extremely surprisingly, colloidal suspending agent of the present invention absorbs the farming reactive compound that is undertaken by root system and has positive effect.Based on the plant root performance of document record, this point is unforeseen.
The auxiliary agent that also surprisingly utilizes described test system to select can produce suitable effect in complicated more soil or in other cultivation matrix.
In addition, also surprisingly the decline of the effect of multiple auxiliary agent and spray liquid static surface tension is irrelevant, so it does not rely on the animal migration of spray liquid in soil.
In addition, also surprisingly promote the auxiliary agent that absorbs by root system not necessarily can increase the absorption of being undertaken by the blade epidermis, this has shown the different mechanism of action.
In addition, also surprisingly polyethylene glycol is used in combination with auxiliary agent of the present invention as antifreezing agent and shows a kind of synergistic effect, the absorption of being undertaken by root system is not had effect although find independent polyethylene glycol.
At last, colloidal suspending agent extremely surprisingly of the present invention has splendid stability.Employed auxiliary agent---for example the dispersant of water base colloidal suspending agent---has surface-active, and this can cause itself and dispersant competition usually.Particularly, can cause the colloidal suspending agent instability in high storage temperature or after storing under the temperature condition of variation.The excellent stability of colloidal suspending agent of the present invention can be described by for example viscosity of dispersion stabilization, particle diameter distribution or preparation.
The preferred embodiment of theme of the present invention is described below.
In principle, the advantageous effects of preparation of the present invention is applicable to all farmingization reactive compounds, but is specially adapted to be selected from the insecticidal active compound of anabasine, pyrethroid, butenolide class, keto-enol class, Phenylpyrazole (fiprole) class, anthranilamide-based, mectin class, multiple killing teichomycin (spinosyn) class, organophosphorus compounds and carbamates.
Anabasine can be described by formula (II):
Wherein
Het represents a kind of heterocycle that is selected from following heterocyclic group:
2-chloropyridine-5-base, 2-picoline-5-base, 1-oxo bridge-3-pyridine subbase (1-oxido-3-pyridinio), 2-chloro-1-oxo bridge-5-pyridine subbase, 2,3-two chloro-1-oxo bridges-5-pyridine subbase, oxolane-3-base, 5-methyltetrahydrofuran-3-base, 2-diuril azoles-5-base
R represents hydrogen, C
1-C
6Alkyl, C
2-C
6Thiazolinyl, C
2-C
6Alkynyl ,-C (=O)-CH
3Or benzyl, perhaps with R
2Represent one of following group together:
-CH
2-CH
2-,-CH
2-CH
2-CH
2-,-CH
2-O-CH
2-,-CH
2-S-CH
2-,-CH
2-NH-CH
2-,-CH
2-N (CH
3)-CH
2-, and
X represents N-NO
2, N-CN or CH-NO
2,
The A represent methylidene ,-N (R
1) (R
2) or S (R
2),
Wherein
R
1Represent hydrogen, C
1-C
6Alkyl, phenyl-C
1-C
4Alkyl, C
3-C
6Cycloalkyl, C
2-C
6Thiazolinyl or C
2-C
6Alkynyl, and
R
2Represent C
1-C
6Alkyl, C
2-C
6Thiazolinyl, C
2-C
6Alkynyl ,-C (=O)-CH
3Or benzyl,
(referring to, for example, EP-A1-192 606, EP-A 2-580 533, EP-A 2-376 279, EP-A 2-235 725).
Can specifically mention the compound (II-1) to (II-7) of following preferred anabasine:
● thiophene worm piperazine (thiamethoxam) (II-1) has a following formula structure and be known in EP A20 580 553
● thiophene worm amine (clothianidin) (II-2) has a following formula structure and be known in EP A2 0 376279
● thiophene worm quinoline (thiacloprid) (II-3) has a following formula structure and be known in EP A2 0 235725
● MTI-446 (dinotefuran) (II-4) has a following formula structure and be known in EP A1 0 649845
● Acetamiprid (acetamiprid) (II-5) has a following formula structure and be known in WO A191/04965
● Nitenpyram (nitenpyram) (II-6) has a following formula structure and be known in EP-A 0,302 389
● Imidacloprid (imidacloprid) (II-7) has a following formula structure and be known in EP-A 0 192060
Pyrethroid insecticidal active compound that can be used according to the invention comprises, for example, and material (III-1) to (III-24):
(III-1) be known in the acrinathrin (acrinathrin) of EP-A-048 186
(III-2) be known in the alpha-cypermethrin (alpha-cypermethrin) of EP-A-067 461
(III-3) be known in the betacyfluthrin (betacyfluthrin) of EP-A-206 149
(III-4) be known in the gamma-cyhalothrin (gamma-cyhalothrin) of DE-A-2 802 962
(III-5) be known in the cypermethrin (cypermethrin) of DE-A-2 326 077
(Iu-6) be known in the decis (deltamethrin) of DE-A-2 326 077
(III-7) be known in the S-sumicidin (esfenvalerate) of DE-A-2 737 297
(III-8) be known in the ether chrysanthemum ester (ethofenprox) of DE-A-3 117 510
(III-9) be known in the fenpropathrin (fenpropathrin) of DE-A-2 231 312
(III-10) be known in the sumicidin (fenvalerate) of DE-A-2 335 347
(III-11) be known in the flucythrinate (flucythrinate) of DE-A-2 757 066
(III-12) be known in the gamma cyhalothrin (lambda-cyhalothrin) of EP-A-106 469
(III-13) be known in the permethrin of DE-A-2 326 077
(III-14) be known in the taufluvalinate (taufluvalinate) of EP-A-038 617
(III-15) be known in the tralomethrin (tralomethrin) of DE-A-2 742 546
(III-16) be known in the own body cypermethrin (zeta-cypermethrin) of EP-A-026 542
(III-17) be known in the cyfloxylate (cyfluthrin) of DE-A-27 09 264
(III-18) be known in the Biphenthrin (bifenthrin) of EP-A-049 977
(III-19) be known in the cycloprothrin (cycloprothrin) of DE-A-2653189
(III-20) be known in the eflusilanate of DE-A-36 04 781
(III-21) be known in the halfenprox (fubfenprox) of DE-A-37 08 231
(III-22) be known in agricultural chemicals handbook (The Pesticide Manual), 1997, the 11 editions, 1056 pages pyrethrin (pyrethrin)
R
3=-CH
3Or-CO
2CH
3
R
4=-CH=CH
2Or-CH
3Or-CH
2CH
3,
(III-23) be known in the resmethrin (resmethrin) of GB-A-1 168 797
And
(III-24) be known in the tefluthrin (tefluthrin) of EP-A1 31 199
Formula (IV) provides the broad definition of the insecticidal active compound that is selected from butenolide class (being known in EP-A 0 539 588) that can be used according to the invention:
Wherein
R
5Represent methylidene or cyclopropyl.
Can specifically mention compound (IV-1) and (IV-2)
Formula (V) provides the broad definition of the insecticidal active compound of keto-enol class (being known in EP-A 0 539588) that can be used according to the invention:
Wherein
W represents hydrogen, alkyl, thiazolinyl, alkynyl, halogen, alkoxyl, haloalkyl, halogenated alkoxy or cyano group,
X represents halogen, alkyl, thiazolinyl, alkynyl, alkoxyl, alkoxyl alkoxyl, haloalkyl, halogenated alkoxy or cyano group,
Y represents hydrogen, halogen, alkyl, thiazolinyl, alkynyl, alkoxyl, cyano group, haloalkyl, halogenated alkoxy, and perhaps substituted phenyl or heteroaryl are chosen in representative separately wantonly,
Z represents hydrogen, halogen, alkyl, haloalkyl, cyano group, alkoxyl or halogenated alkoxy,
One of following group of CKE representative
Wherein
A represents hydrogen, representative is optional separately by the alkyl of halo, thiazolinyl, alkoxyalkyl, alkylthio alkyl, saturated or unsaturated wherein replaced by hetero atom and the optional substituted cycloalkyl of at least one annular atoms randomly, perhaps optional separately aryl, aryl alkyl or the heteroaryl that is replaced by halogen, alkyl, haloalkyl, alkoxyl, halogenated alkoxy, cyano group or nitro
B represents hydrogen, alkyl or alkoxyalkyl, perhaps
A and B represent saturated or unsaturated at least one heteroatomic unsubstituted or ring of replacing that randomly contains with the carbon atom that they were connected,
D represents hydrogen or the optional substituted group that is selected from following radicals: cycloalkyl, aryl alkyl, aryl, heteroaryl alkyl or heteroaryl that alkyl, thiazolinyl, alkynyl, alkoxyalkyl, saturated or unsaturated randomly one or more ring members are replaced by hetero atom, perhaps
A and D represent A, D part not replace with the atom that they were connected or replace and randomly comprise at least one (when CKE=8 for more a plurality of) heteroatomic saturated or unsaturated ring, perhaps
A and Q
1Representative is optional by hydroxyl and/or optional separately substituted alkyl, alkoxyl, alkylthio group, cycloalkyl, alkane two bases or alkene two bases that benzyloxy or aryl replaced, perhaps together
D and Q
1Represent D, Q with the atom that they connected
1It is that part replaces or replaces and randomly comprise at least one heteroatomic saturated or unsaturated ring,
Q
1Represent hydrogen, alkyl, alkoxyalkyl, optional substituted cycloalkyl (wherein randomly a methylene by oxygen or sulfur) or optional substituted phenyl,
Q
2, Q
4, Q
5And Q
6Represent hydrogen or alkyl independently of one another,
Q
3Represent hydrogen, the optional substituted alkyl of representative, alkoxyalkyl, alkylthio alkyl, optional substituted cycloalkyl (wherein randomly a methylene by oxygen or sulfur) or optional substituted phenyl, perhaps
Q
1And Q
2With the carbon atom that they connected represent unsubstituted or replace randomly comprise heteroatomic ring, perhaps
Q
3And Q
4Represent saturated or the unsaturated heteroatomic unsubstituted or ring that replaces that randomly comprises with the carbon atom that they connected,
G represents one of hydrogen (a) or the following group of representative
Wherein
E representation metal ion equivalent (equivalent) or ammonium ion,
L represents oxygen or sulphur,
M represents oxygen or sulphur,
R
6Representative is optional separately by the alkyl of halo, thiazolinyl, alkoxyalkyl, alkylthio alkyl, poly-alkoxyalkyl or the optional cycloalkyl that can be interrupted by at least one hetero atom that is replaced by halogen, alkyl or alkoxyl, optional separately substituted phenyl, benzene alkyl, heteroaryl, phenoxyalkyl or heteroaryloxy alkyl
R
7Representative is optional separately by the alkyl of halo, thiazolinyl, alkoxyalkyl, poly-alkoxyalkyl or representative optional separately substituted cycloalkyl, phenyl or benzyl,
R
8, R
9And R
10Representative is optional separately by the alkyl of halo, alkoxyl, alkyl amino, dialkyl amido, alkylthio group, alkenylthio group, cycloalkyl sulfenyl independently of one another, and perhaps substituted diphenyl, benzyl, phenoxy group or thiophenyl are chosen in representative separately wantonly,
R
11And R
12Represent hydrogen, optional by the alkyl of halo, cycloalkyl, thiazolinyl, alkoxyl, alkoxyalkyl separately independently of one another, the optional substituted phenyl of representative, the optional substituted benzyl of representative is perhaps represented randomly by the ring of oxygen or sulphur interruption with the N atom that they connected.
Can specifically mention compound (V-1) to (V-5):
The insecticidal active compound of phenyl pyrazoles that can be used according to the invention be fluorine worm nitrile (fipronil) (VI-1) and second worm nitrile (ethiprole) (VI-2)
(VI-1) fluorine worm nitrile
Anthranilamide-based insecticidal active compound that can be used according to the invention is, for example, and (VII-1) to (VII-23)
The insecticidal active compound of mectine class that can be used according to the invention is, for example,
(VIII-1) Avermectin (abamectin)
(VIII-2) emaricin (emamectin)
(VIII-3) emamectin-benzoate (emamectin-benzoate)
(VIII-4) Olivomitecidin (ivermectin)
(VIII-5)lepimectin
(VIII-6) milbemycin (milbemycin).
The insecticidal active compound of multiple killing teichomycin class that can be used according to the invention is, for example, and (IX-1) pleocidin (spinosad).
The insecticidal active compound of organophosphorus compounds that can be used according to the invention is; For example; Orthene (acephate); Azamethiphos (azamethiphos); Azinphos-methyl (azinphos-methyl); Triazotion (azinphos-ethyl); Rilariol (bromophos-ethyl); Bromobenzene alkene phosphorus (bromfenvinfos (methyl)); Special Pyrimitate (butathiofos); Cadusafos (cadusafos); Carbophenothion (carbophenothion); Chlorethoxyfos (chlorethoxyfos); Chlorfenviphos (chlorfenvinphos); Chlormephos (chlormephos); Chlopyrifos (methyl/ethyl) (chlorpyrifos (methyl/-ethyl)); Resistox (coumaphos); Surecide (cyanofenphos); Cynock (cyanophos); Chlorfenviphos (chlorfenvinphos); Demeton-methyl (demeton-S-methyl); Metilomerkaptofosoksid (demeton-S-methylsulphone); Dialifos (dialifos); Basudin (diazinon); Dichlofenthion (dichlofenthion); DDVP (dichlorvos/DDVP); Carbicron (dicrotophos); Rogor (dimethoate); Dimethylvinphos (dimethylvinphos); Salithion (dioxabenzofos); Disulfoton (disulfoton); EPN (EPN); Ethodan (ethion); Phonamiphos (ethoprophos); Etrimfos (etrimfos); Famphur (famphur); Fenamiphos (fenamiphos); Fenifrothion (fenitrothion); Fensulfothion (fensulfothion); Entex (fenthion); Pyrrole fluorine sulphur phosphorus (flupyrazofos); Fonofos (fonofos); Formothion (formothion); Fosmethilan (fosmethilan); Lythidathion (fosthiazate); Heptenophos (heptenophos); Iodfenphos (iodofenphos); IBP (iprobenfos); Isazofos (isazofos); Isofenphos (isofenphos); The O-isopropyl salicylate; Oxazoline (isoxathion); Malathion (malathion); Afos (mecarbam); Methacrifos (methacrifos); Acephatemet (methamidophos); Methidathion (methidathion); Menite (mevinphos); Azodrin (monocrotophos); 2-dichloroethylk dimethyl phosphate (naled); Flolimat (omethoate); Oxydemeton_methyl (oxydemeton-methyl); Parathion-methyl (parathion-methyl); Parathion (parathion-ethyl); Phenthoate dimephenthoate cidial (phenthoate); Thimet (phorate); Phosalone (phosalone); Phosmet (phosmet); Phosphamidon (phosphamidon); The second third phosphorus prestige (phosphocarb); Phoxim (phoxim); Actellic (pirimiphos-methyl); Pirimiphos ethyl (pirimiphos-ethyl); Profenofos (profenofos); Kayaphos (propaphos); Propetamphos (propetamphos); Toyodan (prothiofos); Prothoate (prothoate); Pyraclofos (pyraclofos); Pyridaphethione (pyridaphenthion); The sulphur phosphorus (pyridathion) of rattling away; Quinalphos (quinalphos); Cadusafos (sebufos); Sulfotep (sulfotep); Sulprofos (sulprofos); Butyl pyrimidine phosphorus (tebupirimfos); Swebate (temephos); Terbufos (terbufos); Ravap (tetrachlorvinphos); Thiometon (thiometon); Hostathion (triazophos); Metrifonate (triclorfon) and vamidothion (vamidothion), preferred.
(IX-1) chlopyrifos (methyl/ethyl),
(IX-2) cadusafos,
(IX-3) orthene,
(IX-4) fenamiphos,
(IX-5) lythidathion and
(IX-6) phonamiphos.
The insecticidal active compound of carbamates that can be used according to the invention is, for example, alanycarb (alanycarb), Aldicarb (aldicarb), aldoxycarb (aldoxycarb), allyxycarb (allyxycarb), aminocarb (aminocarb) Evil worm prestige (bendiocarb), Benfuracard micro (benfuracarb), must restrain lice (bufencarb), butacarb (butacarb), butocarboxim (butocarboxim), butanone sulfone prestige (butoxycarboxim), carbaryl (carbaryl), carbofuran (carbofuran), carbosulfan (carbosulfan), cloethocarb (cloethocarb), dimetilan (dimetilan), ethiofencarb (ethiofencarb); Osbac (fenobucarb); fenothiocarb (fenothiocarb); Carzol (formetanate); furathiocarb (furathiocarb); Mobucin (isoprocarb); metham-sodium (metam-sodium); methiocarb (methiocarb); Methomyl (methomyl); meta-tolyl-N-methylcarbamate (MTMC) (metolcarb); oxamyl (oxamyl); Aphox (pirimicarb); Carbamult (promecarb); unden (propoxur); the two prestige (thiodicarb) of sulphur; thiofanox (thiofanox); Landrin (trimethacarb); XMC; Meobal (xylylcarb) and triaguron (triazamate), preferred
(XI-1) carbofuran,
(XI-2) Aldicarb and
(XI-3) oxamyl.
In principle, the advantageous effects of these preparations of the present invention also is applicable to all sterilization farmingization reactive compounds.Fungicidal active compound that can be used according to the invention is, for example:
The nucleic acid synthetic inhibitor
M 9834 (benalaxyl), efficient M 9834 (benalaxyl-M), bupirimate (bupirimate), chiralaxyl, clozylacon, dimethirimol (dimethirimol), the phonetic phenol of second (ethirimol), furalaxyl (furalaxyl), dislike mould spirit (hymexazol), efficient metalaxyl (mefenoxam), metalaxyl (metalaxyl), efficient metalaxyl (metalaxyl-M), ofurace (ofurace), Wakil (oxadixyl), oxolinic acide (oxolinic acid)
Mitosis and cell division inhibitor
Benomyl (benomyl), carbendazim (carbendazim), the mould prestige of second (diethofencarb), furidazol (fuberidazole), probenazole (thiabendazole), thiophanate-methyl (thiophanate-methyl)
Respiratory chain complex II inhibitor
Boscalid (boscalid), carboxin (carboxin), fenfuram (fenfuram), flutolanil (flutolanil), furan pyrrole bacterium amine (furametpyr), seed dressing amine (furmecyclox), mebenil (mepronil), oxycarboxin (oxycarboxin)
Respiratory chain complex III inhibitor
Fluoxastrobin (azoxystrobin), cyanogen frost azoles (cyazofamid), ether bacterium amine (dimoxystrobin), enestrobin, Famoxate (famoxadone), Fenamidone (fenamidone), fluoxastrobin (fluoxastrobin), kresoxim-methyl (kresoxim-methyl), SSF 126 (metominostrobin), orysastrobin (orysastrobin), pyraclostrobin (pyraclostrobin), ZEN 90160 (picoxystrobin), oxime bacterium ester (trifloxystrobin)
The ATP formation inhibitor
Fentin acetate (fentin acetate), triphenyl tin chloride (fentinchloride), fentin hydroxide (fentin hydroxide)
Synthetic and the protein biosynthesis inhibitor of amino acid bio
Amine puts out (andoprim), cyprodinil (cyprodinil), kasugarnycin (kasugamycin), kasugarnycin one hydrochloride hydrate (kasugamycinhydrochloride hydrate), phonetic mould amine (pyrimethanil)
Signal transduction inhibitor
Fludioxonil (fludioxonil), benzene oxygen quinoline (quinoxyfen)
Lipid and film synthetic inhibitor
Chlozolinate (chlozolinate), iprodione (iprodione), procymidone (procymidone)
Ammonia propyl-phosphine acid (ampropylfos), ammonia propyl-phosphine acid potassium (potassium-ampropylfos), edifenphos (edifenphos), Grandox fumigant (etridiazole), iprobenfos (iprobenfos, IBP), Isoprothiolane (isoprothiolane), pyrazophos (pyrazophos)
Biphenyl
Iodocarb, Propamocarb (propamocarb), propamocarb (propamocarb hydrochloride), Propamocarb ethyl phosphine hydrochlorate (propamocarb-fosetylate)
Ergosterol biosynthesis inhibitor
Oxygen ring azoles (azaconazole), bitertanol (bitertanol), bromuconazole (bromuconazole), Cyproconazole (cyproconazole), diclobutrazol (diclobutrazole), Difenoconazole (difenoconazole), alkene azoles alcohol (diniconazole), alkene azoles alcohol-M (diniconazole-M), fluorine ring azoles (epoxiconazole), etaconazole (etaconazole), Fenarimol (fenarimol), RH-7592 (fenbuconazole), Fluquinconazole (fluquinconazole), flurprimidol (flurprimidole), Flusilazole (flusilazole), Flutriafol (flutriafol), furconazole (furconazole), furconazole_cis (furconazole-cis), own azoles alcohol (hexaconazole), press down mould azoles (imazalil), IMAZALIL (imazalil-sulphate), glyoxalin (imibenconazole), plant bacterium azoles (ipconazole), metconazole (metconazole), nitrile bacterium azoles (myclobutanil), nuarimol (nuarimol), dislike imidazoles (oxpoconazole), paclobutrazol (paclobutrazole), penconazole (penconazole), pefurazoate (pefurazoate), Prochloraz (prochloraz), propiconazole (propiconazole), prothioconazoles (prothioconazole), pyrifenox (pyrifenox), simeconazoles (simeconazole), Tebuconazole (tebuconazole), tetraconazole (tetraconazole), triazolone (triadimefon), Triadimenol (triadimenol), fluorine bacterium azoles (triflumizole), triforine (triforine), triticonazole (triticonazole), uniconazole P (uniconazole), voriconazole (voriconazole), alkene frost benzyl azoles (viniconazole)
Cartap (aldimorph), dodemorph (dodemorph), dodemorph acetate, fenpropidin (fenpropidin), butadiene morpholine
(fenpropimorph), volution bacterium amine (spiroxamine), tridemorph (tridemorph),
Naftifine (naftifine), pyributicarb (pyributicarb), Terbinafine (terbinafine)
The cell wall synthetic inhibitor
Benzene metsulfovax (benthiavalicarb), bialaphos (bialaphos), dimethomorph (dimethomorph), flumorph (flumorph), iprovalicarb (iprovalicarb), mandipropamid amine (mandipropamid), polyoxin (polyoxins), Polyoxin (polyoxorim)
The melanin biosynthesis inhibitor
Ring propionyl imines (capropamid), two chlorine zarilamid (diclocymet), zarilamid (fenoxanil), Rabcide (phthalid), pyroquilon (pyroquilon), tricyclazole (tricyclazole)
The induction of resistance material
Diazosulfide (acibenzolar-S-methyl), probenazole (probenazole), tiadinil (tiadinil)
Other bactericide
Amibromdol, benthiozole (benthiazole), bethoxazin, capsimycin (capsimycin), carvol (carvone), chloropicrin (chloropicrin), cufraneb (cufraneb), frost urea cyanogen (cymoxanil), dazomet (dazomet), debacarb (debacarb), diclomezin (diclomezine), difenzoquat (difenzoquat), benzene enemy fast (difenzoquat methylsulphate), dimetomough, dithiofencarb, ferimzone (ferimzone), fluorine acyl bacterium amine (flumetover), flusulfamide (flusulfamide), fluorine pyrrole bacterium amine (fluopicolide), fluoromide (fluoroimide), phosethyl-Al (fosetyl-aluminium), ethane phosphonic acid calcium (fosetyl-calcium), ethane phosphonic acid sodium (fosetyl-sodium), hexachloro-benzene (hexachlorobenzene), oxine (8-hydroxyquinoline sulphate), people's metamycin (irumamycin), methasulfocarb (methasulfocarb), metrafenone (metrafenone), Trapex (methyl isothiocyanate), midolthromycin (mildiomycin), myprozine (natamycin), Sankel (nickeldimethyl dithiocarbamate), octhilinone (octhilinone), oxamocarb, oxyfenthiin, pentachlorophenol (pentachlorophenol) and salt thereof, 2-phenylphenol and salt thereof, disease is spent spirit (piperalin), propanosine-sodium, pyribencarb, pyrrolnitrin (pyrrolnitrin), Quintozene (quintozene), tecloftalam (tecloftalam), tecnazene (tecnazene), trichlamide (trichlamide), valiphenal, zarilamid (zarilamid)
2-(2-{[6-(3-chloro-2-methylphenoxy)-5-fluorine pyrimidine-4-yl] the oxygen base } phenyl)-2-(methoxyimino)-N-methylacetamide,
2-[[[[1-[3-(1-fluoro-2-phenylethyl) oxygen base] phenyl] ethylidene] amino] the oxygen base] methyl]-α-(methoxyimino)-N-methyl-α-phenyl acetamide,
Suitable-1-(4-chlorphenyl)-2-(1H-1,2,4-triazol-1-yl) suberol,
1-[(4-methoxyl group phenoxy group) methyl]-2,2-dimethyl propyl-1H-imidazoles-1-formic acid,
2,3,5,6-tetrachloro-4-(mesyl) pyridine,
2-butoxy-6-iodo-3-propyl group chromene-4-ketone,
2-chloro-N-(2,3-dihydro-1,1,3-trimethyl-1H-indenes-4-yl)-3-pyridine carboxamide,
3,4,5-three chloro-2,6-pyridine dintrile,
3,4-two chloro-N-(2-cyano-phenyl) isothiazole-5-formamide (different metsulfovax (isotianil)),
3-[5-(4-chlorphenyl)-2,3-dimethyl isoxazole alkane-3-yl] pyridine,
5-chloro-6-(2,4, the 6-trifluorophenyl)-N-[(1R)-1,2,2-trimethyl propyl group] [1,2,4] triazol [1,5-a] pyrimidine-7-amine,
5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl) [1,2,4] triazols [1,5-a] pyrimidine,
5-chloro-N-[(1R)-1, the 2-dimethyl propyl]-6-(2,4, the 6-trifluorophenyl) [1,2,4] triazols [1,5-a] pyrimidine-7-amine,
2-[[[cyclopropyl-[(4-methoxyphenyl) imino group] methyl] sulfo-] methyl]-α-(methoxyl group methylene) methyl phenylacetate,
1-(2,3-dihydro-2,2-dimethyl-1H-indenes-1-yl)-1H-imidazole-5-carboxylic acid methyl esters,
N-(3 ', 4 '-two chloro-5-fluorine xenyl-2-yls)-3-(difluoromethyl)-1-methyl isophthalic acid H-pyrazole-4-carboxamide,
N-(3-ethyl-3,5,5-trimethylcyclohexyl)-3-formoxyl amino-2-hydroxybenzamide,
N-(4-chloro-2-nitrobenzophenone)-N-ethyl-4-methyl benzenesulfonamide,
N-(4-benzyl chloride base)-3-[3-methoxyl group-4-(third-2-alkynes-1-base oxygen base) phenyl] propionamide,
The N-[(4-chlorphenyl) (cyano group) methyl]-3-[3-methoxyl group-4-(third-2-alkynes-1-base oxygen base) phenyl] propionamide,
N-(5-bromo-3-chloro-pyridine-2-yl) methyl-2,4-two chloro-nicotinamides,
N-[1-(5-bromo-3-chloro-pyridine-2-yl) ethyl]-2,4-two chloro-nicotinamides,
(2S)-and N-[2-[4-[[3-(4-chlorphenyl)-2-propynyl] oxygen]-the 3-methoxyphenyl] ethyl]-3-methyl-2-[(methyl sulphonyl) amino] butyramide,
N-{ (Z)-[(cyclo propyl methoxy) imino group] [6-(difluoro-methoxy)-2,3-difluorophenyl] methyl }-the 2-phenyl acetamide,
N-{2-[1,1 '-two (cyclopropyl)-2-yls] phenyl }-3-(difluoromethyl)-1-methyl isophthalic acid H-pyrazole-4-carboxamide,
N-{2-[3-chloro-5-(trifluoromethyl) pyridine-2-yl] ethyl }-2-(trifluoromethyl) benzamide,
N-ethyl-N-methyl-N '-and 2-methyl-5-(trifluoromethyl)-4-[3-(trimethyl silyl) propoxyl group] phenyl } the imino group formamide,
O-[1-[(4-methoxyl group phenoxy group) methyl]-2, the 2-dimethyl propyl]-1H-imidazoles-1-carbothioic acid,
2-amino-4-methyl-N-phenyl-5-thiazole carboxamides,
2,4-dihydro-5-methoxyl group-2-methyl-4-[[[[1-[3-(trifluoromethyl) phenyl] ethylidene] amino] the oxygen base] methyl] phenyl]-3H-1,2,3-triazole-3-ketone (CAS number: 185336-79-2),
N-(6-methoxyl group-3-pyridine radicals) encircles propyl formamide,
Can bactericide preferably used according to the invention be
Grandox fumigant, phosethyl-Al, propamocarb, metalaxyl, efficient metalaxyl, efficient M 9834, Fluoxastrobin, dimetomorph, phonetic mould amine, carbendazim, dithiofencarb, thiophanate-methyl, Prochloraz, Boscalid, oxime bacterium ester, fluoxastrobin, iprodione, Propamocarb ethyl phosphine hydrochlorate, prothioconazoles, triticonazole, Fluquinconazole, Triadimenol, iprovalicarb, fluorine pyrrole bacterium amine, N-{2-[1,1 '-two (cyclopropyl)-2-yl] phenyl }-3-(difluoromethyl)-1-methyl isophthalic acid H-pyrazole-4-carboxamide, N-[2-(1, the 3-dimethylbutyl) phenyl]-5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide, N-(3 ', 4 '-two chloro-5-fluoro-1,1 '-diphenyl-2-yl)-3-(difluoromethyl)-1-methyl isophthalic acid H-pyrazole-4-carboxamide, N-{2-[3-chloro-5-(trifluoromethyl)-2-pyridine radicals] ethyl }-the 2-trifluoromethyl benzamide, 5-chloro-6-(2,4, the 6-trifluorophenyl)-N-[(1R)-1,2,2-trimethyl propyl group] [1,2,4] triazol [1,5-a] pyrimidine-7-amine, 5-chloro-N-[(1R)-1, the 2-dimethyl propyl]-6-(2,4, the 6-trifluorophenyl) [1,2,4] triazol [1,5-a] pyrimidine-7-amine and 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl) [1,2,4] triazol [1,5-a] pyrimidine.
The example of the auxiliary agent of the present invention that can mention is specially following material and composition:
(I-1) the oxyalkylated straight chain alcohol of the oxyalkylated fatty alcohol of endcapped and endcapped, commercially available getting, for example,
Series of products; Straight chain alcohol ethoxylation and/or butoxyization of preferred fatty alcohol ethoxylation and/or butoxyization and endcapped (wherein, herein or hereinafter, the meaning of " endcapped " is interpreted as terminal oh group by alkylating),
(I-2) have the tributyl phenol polyglycol ether (wherein EO finger ring oxidative ethane) of 10 to 15 EO unit, commercially available getting, for example,
Series of products,
(I-3) formula CH
3-(CH
2)
t-CH
2-O-(CH
2-CH
2-O)
uThe branched alkanol alcoxylates of-H, wherein t represents 9 to 10.5 numeral, and u represents 6 to 25 numeral (preferred 8 to 12), and t and u be mean value, commercially available getting, for example,
Series of products,
(I-4) triglycerides of poly-alkoxylation, wherein said triglycerides preferably derives from plant, commercially available getting, for example,
Series of products,
(I-5) oxyalkylated fatty amine, commercially available getting, for example,
Series of products,
(I-6) lauryl (polyoxyethylene) ether sodium sulfate, commercially available getting, for example,
Series of products,
(I-7) oxyalkylated terpene can get, for example
Series of products,
(I-8) comprise the composition of corn syrup, methylate soya-bean oil and nonionic emulsifier, commercially available getting, for example,
Series of products.
The composition that is applicable to the inventive method comprises:
The reactive compound and/or at least a reactive compound that is selected from above-mentioned bactericide of-at least a anabasine that is selected from desinsection, pyrethroid, butenolide class, keto-enol class, phenyl pyrazoles, anthranilamide-based, mectin class, multiple killing teichomycin class, organophosphorus compounds and carbamates
-at least a auxiliary agent,
-at least a non-ionic surface active agent and/or at least a anion surfactant,
-at least a antifreezing agent, and
-one or more are selected from the additive of defoamer, preservative, antioxidant, spreader-sticker, colouring agent and/or thickener.
In a kind of preferred embodiment, composition of the present invention comprises:
The reactive compound of the reactive compound of the reactive compound of the reactive compound of-at least a general formula (II) and/or at least a being selected from (III-1) to (III-24) and/or the reactive compound of at least a general formula (IV) and/or at least a general formula (V) and/or at least a being selected from (VI-1) and reactive compound (VI-2) and/or at least a being selected from (VII-1) to (VII-23) and/or at least a being selected from (VIII-1) to (VIII-6) and/or the reactive compound of reactive compound (IX-1) and/or at least a organophosphorus compounds and/or the reactive compound of at least a carbamates
-at least a auxiliary agent,
-at least a non-ionic surface active agent and/or at least a anion surfactant,
-at least a antifreezing agent, and
-one or more are selected from the additive of defoamer, preservative, antioxidant, spreader-sticker, colouring agent and/or thickener.
In another preferred embodiment, composition of the present invention comprises:
-at least a the bactericide that is selected from following material: Grandox fumigant, phosethyl-Al, propamocarb, metalaxyl, efficient metalaxyl, efficient M 9834, Fluoxastrobin, dimetomorph, phonetic mould amine, carbendazim, dithiofencarb, thiophanate-methyl, Prochloraz, Boscalid, oxime bacterium ester, fluoxastrobin, iprodione, Propamocarb ethyl phosphine hydrochlorate, prothioconazoles, triticonazole, Fluquinconazole, Triadimenol, iprovalicarb, fluorine pyrrole bacterium amine, N-{2-[1,1 '-two (cyclopropyl)-2-yl] phenyl }-3-(difluoromethyl)-1-methyl isophthalic acid H-pyrazole-4-carboxamide, N-[2-(1, the 3-dimethylbutyl) phenyl]-5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide, N-(3 ', 4 '-two chloro-5-fluoro-1,1 '-diphenyl-2-yl)-3-(difluoromethyl)-1-methyl isophthalic acid H-pyrazole-4-carboxamide, N-{2-[3-chloro-5-(trifluoromethyl)-2-pyridine radicals] ethyl }-the 2-trifluoromethyl benzamide, 5-chloro-6-(2,4, the 6-trifluorophenyl)-N-[(1R)-1,2,2-trimethyl propyl group] [1,2,4] triazol [1,5-a] pyrimidine-7-amine, 5-chloro-N-[(1R)-1, the 2-dimethyl propyl]-6-(2,4, the 6-trifluorophenyl) [1,2,4] triazol [1,5-a] pyrimidine-7-amine and 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl) [1,2,4] triazol [1,5-a] pyrimidine
-at least a auxiliary agent,
-at least a non-ionic surface active agent and/or at least a anion surfactant,
-at least a antifreezing agent, and
-one or more are selected from the additive of defoamer, preservative, antioxidant, spreader-sticker, colouring agent and/or thickener.
In a kind of particularly preferred embodiment, composition of the present invention comprises:
The reactive compound of the reactive compound of the reactive compound of the reactive compound of the reactive compound of-at least a general formula (II) and/or at least a being selected from (III-1) to (III-24) and/or the reactive compound of at least a general formula (IV) and/or at least a general formula (V) and/or at least a being selected from (VI-1) and reactive compound (VI-2) and/or at least a being selected from (VII-1) to (VII-23) and/or at least a being selected from (VIII-1) to (VIII-6) and/or reactive compound (IX-1) and/or at least a being selected from (X-1) to (X-6) and/or the reactive compound of at least a being selected from (XI-1) to (XI-3)
The material or the composition of-at least a being selected from (I-1) to (I-8),
-at least a non-ionic surface active agent and/or at least a anion surfactant,
-at least a antifreezing agent, and
-one or more are selected from the additive of defoamer, preservative, antioxidant, spreader-sticker, colouring agent and/or thickener.
In another kind of particularly preferred embodiment, composition of the present invention comprises:
-at least a the bactericide that is selected from following material: Grandox fumigant, phosethyl-Al, propamocarb, metalaxyl, efficient metalaxyl, efficient M 9834, Fluoxastrobin, dimetomorph, phonetic mould amine, carbendazim, dithiofencarb, thiophanate-methyl, Prochloraz, Boscalid, oxime bacterium ester, fluoxastrobin, iprodione, Propamocarb ethyl phosphine hydrochlorate, prothioconazoles, triticonazole, Fluquinconazole, Triadimenol, iprovalicarb, fluorine pyrrole bacterium amine, N-{2-[1,1 '-two (cyclopropyl)-2-yl] phenyl }-3-(difluoromethyl)-1-methyl isophthalic acid H-pyrazole-4-carboxamide, N-[2-(1, the 3-dimethylbutyl) phenyl]-5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide, N-(3 ', 4 '-two chloro-5-fluoro-1,1 '-diphenyl-2-yl)-3-(difluoromethyl)-1-methyl isophthalic acid H-pyrazole-4-carboxamide, N-{2-[3-chloro-5-(trifluoromethyl)-2-pyridine radicals] ethyl }-the 2-trifluoromethyl benzamide, 5-chloro-6-(2,4, the 6-trifluorophenyl)-N-[(1R)-1,2,2-trimethyl propyl group] [1,2,4] triazol [1,5-a] pyrimidine-7-amine, 5-chloro-N-[(1R)-1, the 2-dimethyl propyl]-6-(2,4, the 6-trifluorophenyl) [1,2,4] triazol [1,5-a] pyrimidine-7-amine and 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl) [1,2,4] triazol [1,5-a] pyrimidine
The material or the composition of-at least a being selected from (I-1) to (I-8),
-at least a non-ionic surface active agent and/or at least a anion surfactant,
-at least a antifreezing agent, and
-one or more are selected from the additive of defoamer, preservative, antioxidant, spreader-sticker, colouring agent and/or thickener.
Composition of the present invention comprises:
-be generally 1 to 60 weight %, be preferably 5 to 50 weight %, be preferably the farming reactive compound that one or more of 10 to 30 weight % can be used according to the invention especially,
-be generally 1 to 50 weight %, be preferably 2 to 30 weight %, be preferably the auxiliary agent at least a of the present invention of 5 to 20 weight % especially,
-be generally 1 to 20 weight %, be preferably at least a non-ionic and/or at least a anionic surfactant of 2.5 to 10 weight %,
-be generally 1 to 20 weight %, be preferably the antifreezing agent of 5 to 15 weight %,
-be generally 0.1 to 20 weight %, be preferably the additive that is selected from defoamer, preservative, antioxidant, spreader-sticker, colouring agent and/or thickener of 0.1 to 15 weight %.
Generally speaking, the preferably listed reactive compound and the bond of auxiliary agent in some following tables, wherein every kind of bond itself all is preferred:
| # | Reactive compound | Auxiliary agent |
| 1 | (II-7) | Oxyalkylated fatty amine |
| 2 | (II-7) | Oxyalkylated terpene |
| 3 | (II-7) | The oxyalkylated fatty alcohol of endcapped and the oxyalkylated straight chain alcohol of endcapped |
| 4 | (II-7) | Lauryl (polyoxyethylene) ether sodium sulfate |
| 5 | (II-7) | The triglycerides of poly-alkoxylation |
| 6 | (II-7) | Tributyl phenol polyglycol ether with 10 to 15 EO unit |
| 7 | (II-7) | Formula CH 3-(CH 2) t-CH 2-O-(-CH 2-CH 2-O-) uThe branched alkanol alcoxylates of-H, wherein t represents 9 to 10.5 numeral, and u represents 6 to 25 numeral |
| 8 | (II-7) | Comprise corn syrup, the composition of methylate soya-bean oil and nonionic emulsifier |
| 9 | (IV-1) | Oxyalkylated fatty amine |
| 10 | (IV-1) | Oxyalkylated terpene |
| 11 | (IV-1) | The oxyalkylated fatty alcohol of endcapped and the oxyalkylated straight chain alcohol of endcapped |
| 12 | (IV-1) | Lauryl (polyoxyethylene) ether sodium sulfate |
| 13 | (IV-1) | The triglycerides of poly-alkoxylation |
| 14 | (IV-1) | Tributyl phenol polyglycol ether with 10 to 15 EO unit |
| # | Reactive compound | Auxiliary agent |
| 15 | (IV-1) | Formula CH 3-(CH 2) t-CH 2-O-(-CH 2-CH 2-O-) uThe branched alkanol alcoxylates of-H, wherein t represents 9 to 10.5 numeral, and u represents 6 to 25 numeral |
| 16 | (IV-1) | Comprise corn syrup, the composition of methylate soya-bean oil and nonionic emulsifier |
| 17 | (V-3) | Oxyalkylated fatty amine |
| 18 | (V-3) | Oxyalkylated terpene |
| 19 | (V-3) | The oxyalkylated fatty alcohol of endcapped and the oxyalkylated straight chain alcohol of endcapped |
| 20 | (V-3) | Lauryl (polyoxyethylene) ether sodium sulfate |
| 21 | (V-3) | The triglycerides of poly-alkoxylation |
| 22 | (V-3) | Tributyl phenol polyglycol ether with 10 to 15 EO unit |
| 23 | (V-3) | Formula CH 3-(CH 2) t-CH 2-O-(-CH 2-CH 2-O-) uThe branched alkanol alcoxylates of-H, wherein t represents 9 to 10.5 numeral, and u represents 6 to 25 numeral |
| 24 | (V-3) | Comprise corn syrup, the composition of methylate soya-bean oil and nonionic emulsifier |
| 25 | (VI-1) | Oxyalkylated fatty amine |
| 26 | (VI-1) | Oxyalkylated terpene |
| 27 | (VI-1) | The oxyalkylated fatty alcohol of endcapped and the oxyalkylated straight chain alcohol of endcapped |
| 28 | (VI-1) | Lauryl (polyoxyethylene) ether sodium sulfate |
| 29 | (VI-1) | The triglycerides of poly-alkoxylation |
| 30 | (VI-1) | Tributyl phenol polyglycol ether with 10 to 15 EO unit |
| 31 | (VI-1) | Formula CH 3-(CH 2) t-CH 2-O-(-CH 2-CH 2-O-) uThe branched alkanol alcoxylates of-H, wherein t represents 9 to 10.5 numeral, and u represents 6 to 25 numeral |
| 32 | (VI-1) | Comprise corn syrup, the composition of methylate soya-bean oil and nonionic emulsifier |
Colloidal suspending agent of the present invention prepares by described component is mixed with each other with required concrete ratio.Described component can be mixed with each other in random order.Be that described solid constituent is used with the state that grinds very carefully easily.Yet, also component can be mixed the formed suspension in back roughly grind earlier afterwards finish grind so that its average grain diameter less than 20 μ m.Preferred wherein solid particle average grain diameter is the colloidal suspending agent of 1 to 10 μ m.
When implementing the inventive method, temperature can change in a certain scope.Generally speaking, this method is implemented under the temperature between 10 ℃ to 60 ℃, between preferred 15 ℃ to 40 ℃.
What be applicable to enforcement the inventive method is conventional mixer and the grinder that is used to produce farm chemical preparation.
Even composition of the present invention is a stable formulation still after long term storage under temperature that raises or the low temperature, owing to do not observe crystal growth.By dilute with water, they can be converted into uniform spray liquid.
The rate of application of the present composition can change in wide relatively scope.It depends on farming reactive compound and their content in composition of being discussed.
Pesticidal combination of the present invention is owing to have good plant tolerance concurrently and to favourable toxicity of warm blooded animal and high Environmental compatibility; be applicable to protective plant and plant organ, raising gather productive rate, the quality of improving harvested material and control animal nuisance, more especially insect, arachnid, worm, nematode and the mollusk that runs in agricultural, gardening, forest, park and the leisure facilities.It is preferably used as crop protection agents.They to common sensitivity and resistance species and all or some developmental stage have activity.Above-mentioned nuisance comprises:
Anoplura (Anoplura, Phthiraptera), for example Damalinia (Damalinia spp.), Haematopinus (Haematopinus spp.), Linognathus (Linognathus spp.), lice belong to (Pediculus spp.), Trichodectes (Trichodectes spp.).
Arachnids (Arachnida), for example, Acarus siro (Acarus siro), oranges and tangerines aceria (Aceria sheldoni), peronium Eriophyes (Aculops spp.), acupuncture Eriophyes (Aculus spp.), Amblyomma (Amblyomma spp.), Argas (Argas spp.), Boophilus (Boophilus spp.), short whisker Acarapis (Brevipalpus spp.), Bryobia praetiosa (Bryobia praetiosa), Chorioptes (Chorioptes spp.), Dermanyssus gallinae (Dermanyssus gallinae), beginning Tetranychus (Eotetranychus spp.), goitre mite on the pears (Epitrimerus pyri), true Tetranychus (Eutetranychus spp.), Eriophyes (Eriophyes spp.), half tarsonemid belongs to (Hemitarsonemus spp.), Hyalomma (Hyalomma spp.), hard tick belongs to (Ixodes spp.), latrodectus mactans (Latrodectusmactans), Metatetranychus spp., the unguiculus mite belongs to (Oligonychus spp.), Ornithodoros (Ornithodoros spp.), Panonychus citri belongs to (Panonychus spp.), the tangerine rust mite (Phyllocoptruta oleivora) that rues, Polyphagotarsonemus latus Banks (Polyphagotarsonemus latus), Psoroptes (Psoroptes spp.), Rh (Rhipicephalus spp.), the root mite belongs to (Rhizoglyphus spp.), itch mite belongs to (Sarcoptes spp.), Middle East gold scorpion (Scorpio maurus), Stenotarsonemus spp., tarsonemid belongs to (Tarsonemus spp.), Tetranychus (Tetranychus spp.), Vasateslycopersici.
Bivalve (Bivalva) guiding principle, for example, the decorations shellfish belongs to (Dreissena spp.).
Lip foot order (Chilopoda), for example, DIWUGONG belongs to (Geophilus spp.), Scutigeraspp..
Coleoptera (Coleoptera), for example, acanthoscelides obtectus (Acanthoscelides obtectus), the beak rutelian belongs to (Adoretus spp.), willow firefly chrysomelid (Agelastica alni), click beetle belongs to (Agriotes spp.), the potato melolonthid (Amphimallon solstitialis), furniture death watch beetle (Anobium punctatum), longicorn beetle belongs to (Anoplophora spp.), flower resembles genus (Anthonomus spp.), Anthrenus (Anthrenus spp.), Ah gill cockchafer belongs to (Apogonia spp.), Atomaria spp., moth-eaten belong to (the Attagenus spp.) of fur, dislike bar bean weevil (Bruchidius obtectus), bean weevil belongs to (Bruchus spp.), tortoise resembles genus (Ceuthorhynchus spp.), Cleonus mendicus, wide chest Agriotes spp (Conoderus spp.), collar resembles genus (Cosmopolites spp.), the brown New Zealand rib wing melolonthid (Costelytra zealandica), Curculio (Curculio spp.), the latent beak of Yang Gan resembles (Cryptorhynchus lapathi), khapra beetle belongs to (Dermestes spp.), chrysomelid genus (Diabrotica spp.), epilachna genus (Epilachna spp.), tobacco boring worm (Faustinus cubae), globose spider beetle (Gibbium psylloides), black different pawl sugarcane cockchafer (Heteronychus arator), Hylamorpha elegans, North America house longhorn beetle (Hylotrupes bajulus), alfalfa leaf resembles (Hypera postica), Hypothenemusspp., the big brown hock gill cockchafer of sugarcane (Lachnosterna consanguinea), colorado potato beetle (Leptinotarsa decemlineata), rice root weevil (Lissorhoptrus oryzophilus), the tube beak resembles genus (Lixus spp.), moth-eaten belong to (the Lyctus spp.) of powder, pollen beetle (Meligethes aeneus), the west melolonthid in May (Melolontha melolontha), Migdolus spp., China ink day Bos (Monochamus spp.), Naupactusxanthographus, golden spider beetle (Niptus hololeucus), coconut palm moth rhinoceros cockchafer (Oryctesrhinoceros), saw-toothed grain beetle (Oryzaephilus surinamensis), black grape ear image (Otiorrhynchus sulcatus), little blue and white cockchafer (Oxycetonia jucunda), horseradish daikon leaf beetle (Phaedon cochleariae), food phyllobranchia cockchafer belongs to (Phyllophaga spp.), Japan popillia flavosellata fairmaire (Popillia japonica), Premnotrypes spp., rape golden head flea beetle (Psylliodes chrysocephala), Ptinus (Ptinus spp.), dark-coloured ladybug (Rhizobius ventralis), lesser grain borer (Rhizopertha dominica), grain weevil belongs to (Sitophilus spp.), point Rhynchophorus (Sphenophorus spp.), stem resembles genus (Sternechus spp.), Symphyletes spp., yellow mealworm (Tenebrio molitor), Tribolium (Tribolium spp.), the spot khapra beetle belongs to (Trogoderma spp.), seed resembles genus (Tychius spp.), ridge tiger day Bos (Xylotrechus spp.), belong to (Zabrusspp.) apart from ground beetle.
Collembola (Collembola), for example, arms Onychiurus arcticus (Onychiurus armatus).
Dermaptera (Dermaptera), for example, European earwig (Forficula auricularia).
Doubly sufficient order (Diplopoda), for example, Blaniulus guttulatus.
Diptera (Diptera), for example, Aedes (Aedes spp.), Anopheles (Anophelesspp.), garden march fly (Bibio hortulanus), calliphora erythrocephala (Calliphoraerythrocephala), Mediterranean Ceratitis spp (Ceratitis capitata), Carysomyia (Chrysomyia spp.), Callitroga (Cochliomyia spp.), people torsalo (Cordylobiaanthropophaga), Culex (Culex spp.), Cuterebra (Cuterebra spp.), the big trypetid of olive (Dacus oleae), human botfly (Dermatobia hominis), Drosophila (Drosophila spp.), Fannia (Fannia spp.), Gasterophilus (Gastrophilus spp.), Hylemyia (Hylemyia spp.), Hyppobosca spp., Hypoderma (Hypoderma spp.), liriomyza bryoniae belongs to (Liriomyza spp.), Lucilia (Lucilia spp.), Musca (Muscaspp.), Bemisia spp (Nezara spp.), Oestrus (Oestrus spp.), Oscinella frit (Oscinella frit), lamb's-quarters spring fly (Pegomyia hyoscyami), grass Hylemyia (Phorbiaspp.), Genus Stomoxys (Stomoxys spp.), Gadfly (Tabanus spp.), Tannia spp., Europe daddy-longlegs (Tipula paludosa), Wohlfahrtia (Wohlfahrtia spp.).
Gastropoda (Gastropoda), for example, Arion spp., Biomphalaria (Biomphalariaspp.), little Bulinus (Bulinus spp.), Deroceras spp., native snail belong to (Galba spp.), Lymnaea (Lymnaea spp.), Katayama (Oncomelania spp.), amber spiro spp (Succinea spp.).
The worm guiding principle, for example, Ancylostoma duodenale (Ancylostoma duodenale), Sri Lanka hook worm (Ancylostoma ceylanicum), ancylostoma braziliense (Acylostoma braziliensis), Ancylostoma (Ancylostoma spp.), seemingly draw ascarid nematode (Ascaris lubricoides), Ascaris (Ascaris spp.), cloth Shandong, Malaysia nematode (Brugia malayi), cloth Shandong, Timor nematode (Brugia timori), Bunostomum (Bunostomum spp.), Chabertia belongs to (Chabertia spp.), branch testis fluke belongs to (Clonorchis spp.), Cooperia (Cooperia spp.), Dicrocoelium (Dicrocoelium spp.), dictyocaulus filaria (Dictyocaulus filaria), fish tapeworm (Diphyllobothrium latum), Guinea worm (Dracunculusmedinensis), Echinococcus granulosus (Echinococcus granulosus), Echinococcus multilocularis (Echinococcus multilocularis), pinworm (Enterobiusvermicularis), Faciola spp., blood Trichinella (Haemonchus spp.), Heterakis (Heterakis spp.), short and smallly nibble shell tapeworm (Hymenolepis nana), Metastrongylus apri belongs to (Hyostrongulus spp.), loa loa (Loa Loa), Nematodirus (Nematodirus spp.), oesophagostomum (Oesophagostomum spp.), Opisthorchis (Opisthorchis spp.), Onchocerca caecutiens (Onchocerca volvulus), this off-line Eimeria (Ostertagia spp.) difficult to understand, Paragonimus (Paragonimus spp.), Schistosomen spp., Fu Shi quasi-colubriformis (Strongyloides fuelleborni), strongyloides intestinalis (Strongyloides stercoralis), excrement Strongylus (Stronyloides spp.), taeniarhynchus saginatus (Taenia saginata), taeniasis suis (Taenia solium), trichina(Trichinella spiralis) (Trichinella spiralis), local hair shape nematode (Trichinella nativa), strain Bu Shi trichina (Trichinella britovi), south trichina (Trichinella nelsoni), Trichinella pseudopsiralis, Trichostrongylus (Trichostrongulus spp.), ascaris trichiurus (Trichuris trichuria), wuchereria bancrofti (Wuchereriabancrofti).
In addition, also can prevent and treat protozoa, for example eimeria (Eimeria).
Heteroptera (Heteroptera), for example, squash bug (Anasa tristis), intend beautiful stinkbug and belong to (Antestiopsis spp.), the soil chinch bug belongs to (Blissus spp.), pretty fleahopper belongs to (Calocorisspp.), Campylomma livida, different back of the body chinch bug belongs to (Cavelerius spp.), Cimex (Cimex spp.), Creontiades dilutus, pepper coried (Dasynus piperis), Dichelops furcatus, the long excellent lace bug (Diconocoris hewetti) of Hou Shi, red cotton bug belongs to (Dysdercus spp.), the America stinkbug belongs to (Euschistus spp.), Eurygasterspp belongs to (Eurygasterspp.), Heliopeltis spp., Horcias nobilellus, Leptocorisa spp belongs to (Leptocorisaspp.), leaf beak coried (Leptoglossus phyllopus), lygus bug belongs to (Lygus spp.), sugarcane is deceived chinch bug (Macropes excavatus), Miridae (Miridae), Bemisia spp, Oebalusspp., Pentomidae, side butt stinkbug (Piesma quadrata), the wall stinkbug belongs to (Piezodorusspp.), cotton pseudo-spot leg fleahopper (Psallus seriatus), Pseudacysta persea, Rhodnius (Rhodnius spp.), the brown fleahopper of coconut palm clothing (Sahlbergella singularis), black stinkbug belongs to (Scotinophora spp.), pear crown network pentatomidae (Stephanitis nashi), Tibraca spp., Triatoma (Triatoma spp.).
Homoptera (Homoptera), for example, no net long tube Aphis (Acyrthosipon spp.), Aeneolamia spp., grand arteries and veins Psylla spp (Agonoscena spp.), Aleurodes spp., sugarcane Aleyrodes (Aleurolobus barodensis), Aleurothrixus spp. Mango fruit leafhopper belongs to (Amrasca spp.), Anuraphis cardui, the kidney Aspidiotus belongs to (Aonidiella spp.), Soviet Union bloom aphid (Aphanostigma piri), Aphis (Aphis spp), grape leafhopper (Arboridia apicalis), the roundlet armored scale belongs to (Aspidiella spp.), Aspidiotus belongs to (Aspidiotus spp.), Atanus spp., the eggplant ditch does not have net aphid (Aulacorthum solani), Aleyrodes (Bemisia spp.), Lee's short-tail aphid (Brachycaudus helichrysii), Brachycolus spp., cabbage aphid (Brevicoryne brassicae), little brown back rice plant hopper (Calligypona marginata), a beautiful Huang cicadellid (Carneocephala fulgida), cane powder angle aphid (Ceratovacuna lanigera), Cercopidae (Cercopidae), lecanium belongs to (Ceroplastes spp.), strawberry nail aphid (Chaetosiphon fragaefolii), sugarcane yellow snow armored scale (Chionaspis tegalensis), tea green leafhopper (Chlorita onukii), walnut blackspot aphid (Chromaphis juglandicola), dark brown Aspidiotus (Chrysomphalus ficus), corn leafhopper (Cicadulina mbila), Coccomytilus halli, soft a red-spotted lizard belongs to (Coccusspp.), the tea Fischer conceals knurl aphid (Cryptomyzus ribis), Dalbulus spp., Dialeurodesspp., Diaphorina spp., white back of the body armored scale belongs to (Diaspis spp.), Doralis spp., carry out giant coccid and belong to (Drosicha spp.), west rounded tail Aphis (Dysaphis spp.), the ash mealybug belongs to (Dysmicoccus spp.), Empoasca flavescens (Empoasca spp.), woolly aphid belongs to (Eriosomaspp.), Erythroneura spp., Euscelis bilobatus, coffee ground mealybug (Geococcuscoffeae), phony disease of peach poison leafhopper (Homalodisca coagulata), mealy plum aphid (Hyalopterus arundinis), cottonycushion scale belongs to (Icerya spp.), sheet angle leafhopper belongs to (Idiocerus spp.), flat beak leafhopper belongs to (Idioscopus spp.), small brown rice planthopper (Laodelphaxstriatellus), Lecanium spp., lepidosaphes shimer (Lepidosaphes spp.), radish aphid (Lipaphis erysimi), long tube Aphis (Macrosiphum spp.), Mahanarvafimbriolata, sorghum aphid (Melanaphis sacchari), Metcalfiella spp., wheat does not have net aphid (Metopolophium dirhodum), the black flat wing spot of edge aphid (Monellia costalis), Monelliopsis pecanis, tumor aphid genus (Myzus spp.), lettuce is patched up Macrosiphus spp (Nasonoviaribisnigri), rice leafhopper belongs to (Nephotettix spp.), brown planthopper (Nilaparvatalugens), Oncometopia spp., Orthezia praelonga, red bayberry edge aleyrodid (Parabemisia myricae), Paratrioza spp., the sheet armored scale belongs to (Parlatoria spp.), the goitre woolly aphid belongs to (Pemphigus spp.), corn plant hopper (Peregrinus maidis), continuous mealybug belongs to (Phenacoccus spp.), Yang Ping wing woolly aphid (Phloeomyzus passerinii), phorodon aphid (Phorodon humuli), grape phylloxera belongs to (Phylloxera spp.), brown point of sago cycas and armored scale (Pinnaspis aspidistrae), stern line mealybug belongs to (Planococcus spp.), the former giant coccid of pyriform (Protopulvinaria pyriformis), white mulberry scale (Pseudaulacaspispentagona), mealybug belongs to (Pseudococcus spp.), Psylla spp (Psylla spp.), tiny golden wasp belongs to (Pteromalus spp.), Pyrilla spp., the large bamboo hat with a conical crown and broad brim Aspidiotus belongs to (Quadraspidiotusspp.), Quesada gigas, flat thorn mealybug belongs to (Rastrococcus spp.), Rhopalosiphum (Rhopalosiphum spp.), black bourch belongs to (Saissetia spp.), Scaphoides titanus, greenbug (Schizaphis graminum), sago cycas thorn Aspidiotus (Selenaspidusarticulatus), long clypeus plant hopper belongs to (Sogata spp.), white-backed planthopper (Sogatellafurcifera), Sogatodes spp., Stictocephala festina, Tenalapharamalayensis, Tinocallis caryaefoliae, wide chest froghopper belongs to (Tomaspis spp.), sound Aphis (Toxoptera spp.), greenhouse whitefly (Trialeurodes vaporariorum), individual Psylla spp (Trioza spp.), jassids belongs to (Typhlocyba spp.), the point armored scale belongs to (Unaspisspp.), grape root nodule lice (Viteus vitifolii).
Hymenoptera (Hymenoptera), for example, pine sawfoy belongs to (Diprion spp.), real tenthredinidae (Hoplocampa spp.), the hair ant belongs to (Lasius spp.), MonomoriumMayr (Monomoriumpharaonis), Vespa (Vespa spp.).
Isopoda (Isopoda), for example, pillworm (Armadillidium vulgare), comb beach louse (Oniscus asellus), ball pillworm (Porcellio scaber).
Isoptera (Isoptera), for example, Reticulitermes (Reticulitermes spp.).
Lepidoptera (Lepidoptera), for example, Sang Jian Autographa spp (Acronicta major), tired noctuid (Aedia leucomelas), Agrotis (Agrotis spp.), cotton leaf ripple noctuid (Alabama argillacea), do very Noctua (Anticarsia spp.), Barathrabrassicae, cotton lyonetid (Bucculatrix thurberiella), loose looper (Bupaluspiniarius), the yellow volume of flax moth (Cacoecia podana), Capua reticulana, codling moth (Carpocapsa pomonella), winter geometrid moth (Cheimatobia brumata), straw borer spp (Chilo spp.), spruce bunworm (Choristoneura fumiferana), grape codling moth (Clysia ambiguella) (Clysia ambiguella), Cnaphalocerus spp., earias insulana (Eariasinsulana), Anagasta kuehniella (Ephestia kuehniella), pornography and drug moth (Euproctischrysorrhoea), root eating insect belongs to (Euxoa spp.), the dirty Noctua (Feltia spp.) of cutting, greater wax moth (Galleria mellonella), genus heliothis (Helicoverpa spp.), Heliothis (Heliothis spp.), brownly knit moth (Hofmannophila pseudospretella), tea long paper moth (Homona magnanima), apple ermine moth (Hyponomeuta padella), greedy Noctua (Laphygma spp.), the thin moth of apple (Lithocolletis blancardella), green fruit winter noctuid (Lithophane antennata), the grand in vain root eating insect (Loxagrotis albicosta) of beans, Euproctis (Lymantria spp.), malacosoma neustria (Malacosoma neustria), tomato moth (Mamestra brassicae), rice hair shin noctuid (Mocis repanda), mythimna separata (Mythimna separata), Oria spp., Oulema oryzae (Oulema oryzae), small noctuid (Panolis flammea), Pectinophora gossypiella (Pectinophora gossypiella), tangerine lyonetid (Phyllocnistis citrella), Pieris spp (Pieris spp.), diamond-back moth (Plutellaxylostella), prodenia litura belongs to (Prodenia spp.), Pseudaletia spp., soybean noctuid (Pseudoplusia includens), corn borer (Pyrausta nubilalis), Spodoptera (Spodoptera spp.), Thermesia gemmatalis, bag rain moth (Tineapellionella), curtain rain moth (Tineola bisselliella), the green volume of oak moth (Tortrix viridana), powder Noctua (Trichoplusia spp.).
Orthoptera (Orthoptera), for example, tame Xi (Acheta domesticus), oriental cockroach (Blatta orientalis), blatta germanica (Blattella germanica), Gryllotalpa spp (Gryllotalpa spp.), leucophaea maderae (Leucophaea maderae), migratory locusts belong to (Locusta spp.), black locust belongs to (Melanoplus spp.), American cockroach (Periplanetaamericana), desert locust (Schistocerca gregaria).
Siphonaptera (Siphonaptera), for example, Ceratophyllus (Ceratophyllus spp.), Xanthopsyllacheopis (Xenopsylla cheopis).
Comprehensive order (Symphyla), for example, kahikatea worm (Scutigerella immaculata).
Thrips (Thysanoptera), for example, rice thrips (Baliothrips biformis), Enneothrips flavens, flower thrips belong to (Frankliniella spp.), net Thrips (Heliothrips spp.), greenhouse bar hedge thrips (Hercinothrips femoralis), card Thrips (Kakothrips spp.) grape thrips (Rhipiphorothrips cruentatus), hard Thrips (Scirtothrips spp.), Taeniothrips cardamoni, Thrips (Thripsspp.).
Thysanoptera (Thysanura), for example, silverfish (Lepisma saccharina).
Plant nematode comprises, for example, eel Turbatrix (Anguina spp.), Aphelenchoides (Aphelenchoides spp.), thorn Turbatrix (Belonoaimus spp.), umbrella Aphelenchoides (Bursaphelenchus spp.), fuller's teasel stem eelworm (Ditylenchus dipsaci), ball Heterodera (Globodera spp.), helix Eimeria (Heliocotylenchus spp.), Heterodera (Heterodera spp.), minute hand Turbatrix (Longidorus spp.), Meloidogyne (Meloidogyne spp.), Pratylenchidae belongs to (Pratylenchus spp.), similar similes thorne (Radopholus similis), shallow bid revolves Turbatrix (Rotylenchusspp.), burr Turbatrix (Trichodorus spp.), Pratylenchidae (Tylenchorhynchusspp.), pulvinulus sword Turbatrix (Tylenchulus spp.), the nematode (Tylenchulussemipenetrans) of partly puncturing, Xiphinema (Xiphinema spp.).
Remove at least a above-mentioned active ingredient beyond the region of objective existence, composition of the present invention also can comprise other reactive compound, for example insecticide, attractant, disinfectant, bactericide, miticide, nematocide, fungicide, growth regulator, weed killer herbicide, safener, fertilizer or semiochemicals.
Particularly advantageous blending ingredients has, for example following component:
Bactericide:
Bronopol (bronopol), antiphen, trichloromethyl pyridine (nitrapyrin), Sankel, kasugarnycin, octhilinone, furancarboxylic acid (furancarboxylic acid), terramycin (oxytetracyclin), probenazole, streptomycin (streptomycin), tecloftalam, copper sulphate and other copper agent.
Insecticide/miticide/nematocide:
Sodium channel modulators/voltage-dependent sodium channel blockers
DDT
The oxadiazine class,
Indenes worm prestige (indoxacarb) for example
Semicarbazone class,
For example the cyanogen sulfluramid (metaflumizone, BAS3201)
Acetyl choline receptor agonists/antagonist
Nicotine (nicotine), bensultap (bensultap), Padan (cartap)
The controlled chloride channel antagonist of GABA
The organochlorine class,
For example, toxaphene (camphechlor), Niran (chlordane), 5a,6,9,9a-hexahydro-6,9-methano-2,4 (endosulfan), lindane (gamma-HCH), hexachlorcyclohexane (HCH), heptachlor (heptachlor), lindane (lindane), methoxychlor (methoxychlor) phenyl pyrazoles
For example, second phthalein worm nitrile (acetoprole), second worm nitrile, fluorine worm nitrile, pyrafluprole, pyriprole, fluorine pyrazoles worm (vaniliprole)
Juvenile hormone analogies class,
For example, difenolan (diofenolan), protect young ether (epofenonane), fenoxycarb (fenoxycarb), hydroprene (hydroprene), kinoprene (kinoprene), methoprene (methoprene), pyrrole propyl ether (pyriproxifen), triprene (triprene)
Ecdysone agonist/agent interfering class,
The diacyl hydrazide class,
For example, ring worm hydrazides (chromafenozide), chlorine worm hydrazides (halofenozide), methoxyfenozide (methoxyfenozide), worm hydrazides (tebufenozide) chitin biosynthesis inhibitor class
Benzoyl area kind,
For example, two three flufenoxurons (bistrifluron), fluorine pyridine urea (chlofluazuron), diflubenzuron (diflubenzuron), fluazuron (fluazuron), flucycloxuron (flucycloxuron), flufenoxuron (flufenoxuron), fluorine bell urea (hexaflumuron), Acarus tritici urea (lufenuron), fluorine uride (novaluron), noviflumuron (noviflumuron), penfluron (penfluron), fluorobenzene urea (teflubenzuron), kill bell urea (triflumuron) Buprofezin (buprofezin)
Fly eradication amine (cyromazine)
Oxidative phosphorylation inhibitor class, ATP agent interfering class
Butyl ether urea (diafenthiuron)
The organic tin compound,
For example azacyclotin (azocyclotin), plictran (cyhexatin), fenbutatin oxide (fenbutatin-oxide)
By interrupting the oxidative phosphorylation uncoupler class pyroles that the H-proton gradient works,
Capillary (chlorfenapyr) for example
Dinitrophenols,
For example binapacryl (binapacyrl), dinobuton (dinobuton), karathane (dinocap), dnoc (DNOC)
Site-I electronics transfer inhibitor class
The METI class,
For example fenazaquin (fenazaquin), azoles mite ester (fenpyroximate), pyrimidifen (pyrimidifen), pyridaben (pyridaben), tebufenpyrad (tebufenpyrad), azoles insect amide (tolfenpyrad)
Hydramethylnon Bait (hydramethylnon)
Dicofol (dicofol)
Site-II electronics transfer inhibitor class
Rotenone (rotenone)
Site-III electronics transfer inhibitor class
Mite quinone (acequinocyl), fluacrypyrim (fluacrypyrim) go out
Insect gut membrane micro agent interfering class
Bacillus thuringiensis,Bt (Bacillus thuringiensis) bacterial strain
Lipid synthetic inhibitor class
Tetramic acid (tetramic acid) class,
For example, suitable-3-(2, the 5-3,5-dimethylphenyl)-4-hydroxyl-8-methoxyl group-1-azaspiro [4.5] last of the ten Heavenly stems-3-alkene-2-ketone
Benzamide type,
Flonicamid (flonicamid) for example
The octopaminergic agonist class,
Amitraz (amitraz) for example
Magnesium stimulates the atpase inhibitor class,
Alkynes mite spy (propargite)
The similar thing of nereistoxin,
For example thiocyclam oxalate (thiocyclam hydrogen oxalate), dimehypo (thiosultap-sodium)
Biologic product class, steroids or pheromones class
Nimbin (azadirachtin), bacillus kind (Bacillus spec.), Beauveria kind (Beauveria spec.), Pherocon CM (codlemone), green muscardine fungus belong to kind of (Metarrhizium spec.), a paecilomyces kind (Paecilomycesspec.), enemy Bei Te (thuringiensin), Verticillium dahliae genus kind of (Verticilliumspec.)
Unknown or the indefinite reactive compound class of the mechanism of action
The fumigant class,
For example, aluminum phosphate, Celfume, vikane
The anti-feedant class,
For example, ice crystal (cryolite), flonicamid, pyrrole aphid ketone (pymetrozine) mite growth inhibitor class,
For example, four mite piperazines (clofentezine), second mite azoles (etoxazole), Hexythiazox (hexythiazox)
Amidoflumet, benclothiaz, Citrazon (benzoximate), Bifenazate (bifenazate), fenisobromolate (bromopropylate), Buprofezin (buprofezin), mite manganese (chinomethionat) goes out, galecron (chlordimeform), chlorobenzilate (chlorobenzilate), chloropicrin, clothiazoben, cycloprene, fourth fluorine mite ester (cyflumetofen), CGA 183893 (dicyclanil), fenoxacrim, fluorine nitre diphenylamines (fentrifanil), thiazole mite (flubenzimine), flufenerim, fluorine mite piperazine (flutenzin), gossyplure (gossyplure), Hydramethylnon Bait, japonilure, metoxadiazone (metoxadiazone), oil, Butacide (piperonyl butoxide), potassium oleate, pyridalyl (pyridalyl), sulfluramid (sulfluramid), tetradiphon (tetradifon), kill mite thioether (tetrasul), triarathene (triarathene), synergy alkynes ether (verbutin).
Composition of the present invention also can comprise synergist.Synergist not necessarily has active compound for the synergist that effect added itself that improves reactive compound.
Composition of the present invention also can comprise reducing uses the inhibitor that the back reactive compound is degraded.
Preparation of the present invention uses with the usual manner that is suitable for it.The present composition used according to the invention carries out in the mode of soil treatment the processing of plant and plant parts, and is for example as indicated above.
As indicated above, can handle all plants and position thereof according to the present invention.In a kind of preferred embodiment, wild plant kind and plant cultivars have been handled or the plant species that obtains by the biological breeding method of routine (for example hybridization or protoplast merge) and the position of plant cultivars and described plant species and plant cultivars.In another kind of preferred embodiment, if handled by suitable genetically modified plants and the plant cultivars (genetically modified organisms) and the position thereof that also can combine and obtain of genetic engineering method with conventional method.
Plant preferred especially, handle commercially available separately or the plant cultivars used according to the present invention.The implication of plant cultivars is interpreted as by conventional breeding, by mutagenesis or the plant with new features (" feature ") that obtains by recombinant DNA technology.They can be cultivated species, biotype and genotype.
According to plant species or plant cultivars, its plantation place and growth conditions (soil, weather, vegetation period, nutrition), processing of the present invention also can produce superadditivity (" working in coordination with ") effect.Thus, for example can obtain the following effect that surpasses actual desired: can reduce the rate of application of the present composition and/or widen its activity profile and/or improve its activity, improve vegetation growth state, improve high temperature or cold tolerance, raising to arid or to the tolerance of salt content in the water or in the soil, improve the quality of blooming, make simpler and easy, the hasting of maturity of gathering, raising gather productive rate, improve the quality of the product of gathering and/or improve its nutritive value, improve storage characteristic and/or its processing characteristics of the product of gathering.
Genetically modified plants or the plant cultivars (by genetic engineering obtain) preferred pending according to the present invention comprise all plants of accepting genetic material by genetic modification, and described genetic material is given described plant with particularly advantageous, useful feature.The example of described feature have improve vegetation growth state, improve high temperature or cold tolerance, raising to arid or to the tolerance of salt content in the water or in the soil, improve the quality of blooming, make simpler and easy, the hasting of maturity of gathering, raising gather productive rate, improve the quality of the product of gathering and/or improve its nutritive value, improve bin stability and/or its processing characteristics of the product of gathering.Other lay special stress on example of described feature has and improves the resistance of plant to animal and microorganism nuisance, for example to the resistance of insect, acarid, phytopathogenic fungi, bacterium and/or virus, and improve the tolerance of plant to some weeding active compound.The example of the genetically modified plants that can propose is important crop plants, such as grain (wheat, rice), corn, soybean, potato, beet, tomato, pea and other vegetable variety, cotton, tobacco, rape and fruit plant (fruit is apple, pears, citrus fruits and grape), ben is corn, soybean, potato, cotton, tobacco and rape.The feature of being emphasized especially is by form toxin in plant corpus, particularly the toxin that is formed in plant corpus by the genetic material of bacillus thuringiensis,Bt (for example by gene C ryIA (a), CryIA (b), CryIA (c), CryIIA, CryIIIA, CryIIIB2, Cry9c, Cry2Ab, Cry3Bb and CryIF and in conjunction with) improves the resistance (hereinafter referred to as " Bt plant ") of plant to insect, arachnid, nematode, slug and gastropod.Also ben being characterized as by systemic acquired resistance (SAR), systemin, phytoalexin, stimulin (elicitor) and resistant gene and corresponding marking protein and toxin improved the resistance of plant to fungi, bacterium and virus.Also ben being characterized as improved plant to some weeding active compound tolerance of imidazolone type, sulfonylurea, glyphosate (glyphosate) or careless fourth phosphine (phosphinotricin) (for example " PAT " gene) for example.The existence that also can in the genetically modified plants body, mutually combine of the gene of giving described required feature.The example of " the Bt plant " that can propose is that commercially available brand name is YIELD
(for example corn, cotton, soybean),
(for example corn),
(for example corn),
(cotton),
(cotton) and
The corn variety of (potato), cotton variety, soybean varieties and potato kind.The example of the plant with herbicide tolerant that can propose is that commercially available brand name is Roundup
(having glyphosate tolerant, for example corn, cotton, soybean), Liberty
(having careless fourth phosphine tolerance, for example rape),
(having the imidazolone type tolerance) and
Corn variety, cotton variety and the soybean varieties of (having the sulfonylureas tolerance, for example corn).The plant with Herbicid resistant that can propose (with the plant of the herbicide tolerant mode breeding of routine) comprises by name
Commercially available kind (for example corn).Certainly, more than narration also is applicable to the plant cultivars that has described hereditary feature or still wait to develop hereditary feature, and described plant cultivars will be developed and/or goes on the market in future.
Listed plant can particularly advantageous mode be handled according to the present invention with composition of the present invention.Above-mentioned preferable range also is applicable to the processing to these plants.The processing that lay special stress on carries out plant with the concrete composition that proposes of this paper.
In family expenses, health and storage product protection; composition of the present invention also is suitable for preventing and treating the animal nuisance of finding in the enclosure space; particularly insect, arachnid and acarid, described enclosure space is residence, factory floor, office, vehicles chamber (vehicle cabin) etc. for example.They can be separately or combine with other reactive compounds and auxiliary agent and be used for the described insect of family expenses desinsection product control.They are to sensitivity and resistance species and all the developmental stage all has activity.Described insect comprises:
Scorpionida (Scorpionidea), for example yellow scorpion (Buthus occitanus) in Mediterranean.
Acarina (Acarina), for example adobe tick (Argas persicus), argas reflexus (Argas reflexus), tongue mite subspecies (Bryobia ssp.), Dermanyssus gallinae, sweet mite (Glyciphagus domesticus) is had a liking for by family, tampan tick (Ornithodorus moubat), brown dog tick (Rhipicephalus sanguineus), eutrombicula alfreddugesi (Trombiculaalfreddugesi), Neutrombicula autumnalis, the spy has a liking for skin mite (Dermatophagoides pteronissimus), method is had a liking for skin mite (Dermatophagoidesforinae).
Araneida (Araneae), for example catching bird spider (Aviculariidae), circle spider (Araneidae).
Opiliones (Opiliones), for example chelifer (Pseudoscorpiones chelifer), the blind spider of the Chang Shin of Pseudoscorpiones cheiridium, (Opiliones phalangium).
Isopoda, for example comb beach louse, ball pillworm.
Doubly sufficient order, for example Blaniulus guttulatus, mountain cricket worm (Polydesmus spp.).
Lip foot order, for example DIWUGONG (Geophilus spp.).
Silverfish order (Zygentoma), for example the comb silverfish belongs to (Ctenolepisma spp.), silverfish, robber fireworm (Lepismodes inquilinus).
Blattaria, for example oriental cockroach, blatta germanica, Asia Lian (Blattella asahinai), leucophaea maderae, angle abdomen Lian belong to (Panchlora spp.), wooden Lian belongs to (Parcoblatta spp.), Australian cockroach (Periplaneta australasiae), American cockroach, big brown big Lian (Periplanetabrunnea), smoke Perilpaneta americana (Periplaneta fuliginosa), brown belt blattaria (Supellalongipalpa).
Saltatoria (Saltatoria), for example tame Xi.
Dermaptera, for example European earwig.
Isoptera, for example kalotermitid belongs to (Kalotermes spp.), Reticulitermes.
Corrodentia (Psocoptera), for example Lepinatus spp., powder corrodent belong to (Liposcelisspp.).
Coleoptera (Coleptera), for example Anthrenus, the moth-eaten genus of fur, khapra beetle genus, a long ostomatid (Latheticus oryzae), latent instep cuckoo Eimeria (Necrobia spp.), Ptinus, lesser grain borer, grain weevil (Sitophilus granarius), rice weevil (Sitophilus oryzae), corn weevil (Sitophilus zeamais), Stegobium paniceum (Stegobium paniceum).
Diptera, for example Aedes aegypti (Aedes aegypti), aedes albopictus (Aedesalbopictus), aedes taeniorhynchus (Aedes taeniorhynchus), Anopheles, calliphora erythrocephala, great number fiber crops horsefly (Chrysozona pluvialis), five band Culex pipiens pallens (Culexquinquefasciatus), northern house (Culex pipiens), ring beak culex (Culextarsalis), Drosophila, Fannia canicularis (Fannia canicularis), housefly (Muscadomestica), owl midge (Phlebotomus spp.), flesh fly (Sarcophaga carnaria), Simulium (Simulium spp.), tatukira (Stomoxys calcitrans), the Europe daddy-longlegs.
Lepidoptera, for example lesser wax-moth (Achroia grisella), greater wax moth, Indian meal moth (Plodiainterpunctella), stopper rain moth (Tinea cloacella), bag rain moth, curtain rain moth.
Siphonaptera, for example ctenocephalides canis (Ctenocephalides canis), ctenocephalides felis (Ctenocephalides felis), Pulex irritans (Pulex irritans), chigo (Tungapenetrans), Xanthopsyllacheopis.
Hymenoptera for example blazons hunchbacked ant (Camponotus herculeanus), black smelly ant (Lasius fuliginosus), black ant (Lasius niger), Lasius umbratus, MonomoriumMayr, Paravespula spp., Pavement Ant (Tetramorium caespitum).
Anoplura, for example head louse (Pediculus humanus capitis), body louse (Pediculushumanus corporis), Pemphigus spp., Phylloera vastatrix, crab louse (Phthirus pubis).
Heteroptera, for example cimex hemipterus (Cimex hemipterus), bed bug (Cimexlectularius), phodnius prolixus (Rhodinus prolixus), invasion triatomid (Triatomainfestans).
In the family expenses field of pesticides, they can be used in combination separately or with other suitable reactive compounds, and described suitable reactive compound is phosphoric acid ester, carbamates, pyrethroid, anabasine, growth regulator or other known insecticides class reactive compounds for example.
Bactericidal composition of the present invention also has splendid bactericidal property, and can be used for preventing and treating plant pathogen, described plant pathogen is plasmodiophora brassicae (Plasmodiophoromycetes), oomycetes (Oomycetes), chytrid (Chytridiomycetes), zygomycete (Zygomycetes), sac fungi (Ascomycetes), basidiomycetes (Basidiomycetes) and imperfect fungus (Deuteromycetes) etc. for example.
Some that are included into above-mentioned generic name below as an example can unrestriced mode proposing cause the pathogene of fungal disease:
By the disease that the powdery mildew pathogene causes, described pathogene for example
Bu Shi Erysiphe (Blumeria) bacterial classification, for example grass family Bu Shi powdery mildew (Blumeriagraminis);
Podosphaera (Podosphaera) bacterial classification, for example white cross hair list softgel shell (Podosphaera leucotricha);
Single softgel shell belongs to (Sphaerotheca) bacterial classification, for example garden balsam list softgel shell (Sphaerothecafuliginea);
Uncinula (Uncinula) bacterial classification, for example grape snag shell (Uncinula necator);
By the disease that the rust pathogene causes, described pathogene for example
Glue Rust (Gymnosporangium) bacterial classification, for example brown size rest fungus (Gymnosporangium sabinae);
Camel spore rust belongs to (Hemileia) bacterial classification, for example coffee camel spore rest fungus (Hemileiavastatrix);
Phakopsora (Phakopsora) bacterial classification, for example yam bean layer rest fungus (Phakopsorapachyrhizi) and mountain horseleech layer rest fungus (Phakopsora meibomiae);
Handle rest fungus (Puccinia) bacterial classification, for example Puccinia recondita (Puccinia recondita) or puccinia triticinia (Puccinia triticina);
Uromyces (Uromyces) bacterial classification, for example wart top uromyce (Uromycesappendiculatus);
By the disease that Oomycete class pathogene causes, described pathogene for example
Dish downy mildew (Bremia) bacterial classification, for example lettuce dish downy mildew (Bremia lactucae);
Downy mildew (Peronospora) bacterial classification, for example pea downy mildew (Peronospora pisi) or Cruciferae downy mildew (P.brassicae);
Epidemic disease mould (Phytophthora) bacterial classification, for example phytophthora infestans (Phytophthorainfestans);
Axle downy mildew (Plasmopara) bacterial classification, for example grape is given birth to axle downy mildew (Plasmoparaviticola);
False downy mildew (Pseudoperonospora) bacterial classification, the false downy mildew (Pseudoperonosporacubensis) of for example careless false downy mildew (Pseudoperonospora humuli) or Cuba;
Rotten mould (Pythium) bacterial classification, for example ultimate corruption mould (Pythium ultimum);
The sick disease of leaf spot blight that causes by for example following pathogene and leaf withering,
Alternaria (Alternaria) bacterial classification, for example early blight chain lattice spore (Alternariasolani);
Cercospora (Cercospora) bacterial classification, Li such as Chard dish are given birth to tail spore (Cercosporabeticola);
Cladosporium (Cladiosporum) bacterial classification, for example cucumber branch spore (Cladiosporiumcucumerinum);
Cochliobolus belongs to (Cochliobolus) bacterial classification, for example standing grain cochliobolus (Cochliobolussativus) (conidial form: De Shi mould (Drechslera), Syn: the long spore bacterium (Helminthosporium) that wriggles);
Colletotrichum (Colletotrichum) bacterial classification, for example Colletotrichumlindemuthanium;
Cycloconium bacterial classification, for example Cycloconium oleaginum;
Between the seat shell belong to (Diaporthe) bacterial classification, seat shell (Diaporthe citri) between citrus for example;
Elsinoe (Elsinoe) bacterial classification, for example citrus Elsinochrome (Elsinoe fawcettii);
Coil long spore and belong to (Gloeosporium) bacterial classification, for example please the long spore of colour disk (Gloeosporiumlaeticolor);
Small cluster shell belongs to (Glomerella) bacterial classification, for example encloses small cluster shell (Glomerellacingulata);
Ball seat Pseudomonas (Guignardia) bacterial classification, for example grape Guignardia (Guignardiabidwelli);
Leptosphaeria (Leptosphaeria) bacterial classification, for example Pyricularia oryzae (Leptosphaeriamaculans);
Ruin shell greatly and belong to (Magnaporthe) bacterial classification, for example grey is ruined shell (Magnaporthegrisea) greatly;
Mycosphaerella (Mycosphaerella) bacterial classification, for example standing grain green-ball chamber bacterium (Mycosphaerelle graminicola);
Phaeosphaeria bacterial classification, for example wheat glume blight bacterium (Phaeosphaerianodorum);
Nuclear cavity Pseudomonas (Pyrenophora) bacterial classification, for example round nuclear cavity bacteria (Pyrenophorateres);
Ramularia (Ramularia) bacterial classification, for example Ramularia collo-cygni;
Rhynchosporium spp (Rhynchosporium) bacterial classification, for example rye beak spore (Rhynchosporiumsecalis);
The pin spore belongs to (Septoria) bacterial classification, for example Septoria apii (Septoria apii);
Nuclear coral Pseudomonas (Typhula) bacterial classification, for example meat spore nuclear coral bacterium (Typhula incarnata);
Venturia (Venturia) bacterial classification, for example apple black star bacteria (Venturiainaequalis);
It is harmful by root and stem disease that for example following pathogene causes,
Corticium (Corticium) bacterial classification, for example Corticium graminearum;
Fusarium (Fusarium) bacterial classification, for example sharp sickle spore (Fusarium oxysporum);
Softgel shell bacterium (Gaeumannomyces) bacterial classification, for example take-all (Gaeumannomyces graminis);
Rhizoctonia (Rhizoctonia) bacterial classification, for example Rhizoctonia solani Kuhn (Rhizoctoniasolani).
Tapesia bacterial classification, for example Tapesia acuformis;
Thiclaviopsis (Thielaviopsis) bacterial classification, for example thielaviopsis sp (Thielaviopsisbasicola);
The spadix and panicled spike (the comprising corncob) disease that cause by for example following pathogene,
Alternaria bacterial classification, for example Alternaria kind (Alternaria spp.);
Aspergillus (Aspergillus) bacterial classification, for example aspergillus flavus (Aspergillus flavus);
Cladosporium bacterial classification, for example Cladosporium;
Claviceps (Claviceps) bacterial classification, for example ergot (Claviceps purpurea);
The Fusarium bacterial classification, for example yellow sickle spore (Fusarium culmorum);
Gibberella (Gibberella) bacterial classification, for example Gibberella zeae (Gibberella zeae);
The Monographella bacterial classification is for example avenged rotten bright shuttle spore and is belonged to (Monographella nivalis);
By the disease that smut causes, described smut for example
Axle Ustilago (Sphacelotheca) bacterial classification, for example axle Ustilago (Sphacelothecareiliana);
Tilletia (Tilletia) bacterial classification, for example wheat net fungus tilletia (Tilletia caries);
Urocystis (Urocystis) bacterial classification, for example latent bar smut (Urocystisocculta);
Smut (Ustilago) bacterial classification, for example naked smut (Ustilago nuda);
The fruit rot that causes by for example following pathogene,
Aspergillus bacterium, for example aspergillus flavus;
Botrytis (Botrytis) bacterial classification, for example Botrytis cinerea (Botrytis cinerea);
Penicillium (Penicillium) bacterial classification, for example penicillium expansum (Penicillium expansum);
Sclerotinia (Sclerotinia) bacterial classification, for example sclerotinite (Sclerotiniasclerotiorum);
Verticillium dahliae belongs to (Verticilium) bacterial classification, for example black and white Verticillium dahliae (Verticiliumalboatrum);
That the kind that is caused by for example following pathogene passes and soil passes rots and wilting disease and seedling disease,
The Fusarium bacterial classification, for example yellow sickle spore;
Phytophthora kind, for example Phytophthora cactorum (Phytophthora cactorum);
The pythium spp kind, for example ultimate corruption is mould;
Rhizoctonia bacterial classification, for example Rhizoctonia solani Kuhn;
Bulbil belongs to (Sclerotium) bacterial classification, for example Sclerotium rolfsii (Sclerotium rolfsii);
The ulcer disease, mycoceicidum and the witches' broom that cause by for example following pathogene,
Nectria (Nectria) bacterial classification, for example a kind of fruit, such as apple, pear, etc. is done the red shell bacterium of cancer clump (Nectriagalligena);
The wilting disease that causes by for example following pathogene,
Chain sclerotinia sclerotiorum belongs to (Monilinia) bacterial classification, for example drupe chain sclerotinia sclerotiorum (Monilinialaxa);
The deformity of leaf, flower and the fruit that causes by for example following pathogene,
Exoascus (Taphrina) bacterial classification, for example peach external capsule bacterium (Taphrina deformans);
The deterioration disease of the woody plant that causes by for example following pathogene,
Esca bacterial classification, for example Phaemoniella clamydospora;
The flower that causes by for example following pathogene and the disease of seed,
Botrytis bacterial classification, for example Botrytis cinerea;
The plant tuber disease that causes by for example following pathogene,
Rhizoctonia bacterial classification, for example Rhizoctonia solani Kuhn;
The disease that causes by for example following bacterial pathogens,
Yellow unit cell (Xanthomonas) bacterial classification, for example pathogenic mutation (Xanthomonas campestris pv.oryzae) of xanthomonas campestris paddy rice;
False unit cell (Pseudomonas) bacterial classification, for example pathogenic mutation (Pseudomonas syringae pv.lachrymans) of pseudomonas syringae cucumber;
Ou Wenshi (Erwinia) bacterial classification is for example separated starch Erwinia (Erwiniaamylovora).
The following soybean diseases of preferred control:
The fungal disease of leaf, stem, beanpod and the seed that causes by following pathogene, for example:
Wheel line leaf spot (alternaria leaf spot) (Alternaria kind Alternaria tenuissima (Alternariaspec.atrans tenuissima)), anthracnose (Colletotrichum gloeosporoidesdematium var.truncatum), brown spot (the brown line septoria musiva of soybean (Septoriaglycines)), peach leaf shothole disease and leaf blight (soybean purple speck bacterium (Cercospora kikuchii)), Choanephora leaf blight (choanephora leaf blight) (funnel hairpin mould (Choanephorainfundibulifera trispora (Syn.))), imperfect fungus leaf spot (dactuliophora leafspot) (Dactuliophora glycines), downy mildew (green soy bean reveals bacterium germ (Peronosporamanshurica)), interior navel Helminthosporium leaf blight (drechslera blight) (Drechsleraglycini), frog eye (frogeye leaf spot) (grey speck of soybean bacterium (Cercospora sojina)), flax spot Pseudomonas leaf spot (leptosphaerulina leaf spot) (clover helminthosporium leaf spot bacterium (Leptosphaerulina trifolii)), phyllosticta leaf spot (phyllostica leaf spot) (soybean grey scab bacterium (Phyllosticta sojaecola)), powdery mildew (scattered cross hair shell (Microsphaera diffusa)), YRENOCHAETA leaf spot (pyrenochaeta leaf spot) (Pyrenochaeta glycines), sclerotium acrial part fusarium wilt (aerial blight), leaf blight and damping off (Rhizoctonia solani Kuhn), rust (yam bean layer rest fungus), shot hole (soybean scab circle spore (Sphaceloma glycines)), the mould leaf blight of the handle of crawling (stemphylium leaf blight) (the handle spore of crawling mould (Stemphylium botryosum)), target spot (target spot) (Corynespora cassicola bacterium (Corynespora cassiicola));
The root that causes by following pathogene and the fungal disease of basal part of stem, for example:
Black root rot (Caionectria bacterium (Calonectria crotalariae)), charcoal rot (Kidney bean shell ball spore bacterium (Macrophomina phaseolina)), sickle spore fusarium wilt or wilting, root rot and pod and root neck rot (sharp sickle spore, straight beak sickle spore (Fusarium orthoceras), half-naked sickle spore (Fusarium semitectum), scouring rush's sickle spore (Fusarium equiseti)), the mould root rot of lotus spore (mycoleptodiscus root rot) (water hyacinth spore mould (Mycoleptodiscus terrestris)), new red shell bacterium disease (neocosmospora) (invading the new red shell bacterium of arteries and veins (Neocosmopsporavasinfecta)), pod blight and cane blight (soybean stem ulcer bacteria (Diaporthephaseolorum)), stem canker (soybean north stem canker germ (Diaporthe phaseolorumvar.caulivora)), epidemic disease mould rotten sick (big male epidemic disease mould (Phytophthora megasperma)), brown stem rot (brown stem rot bacterium (Phialophora gregata)), rotten mildew (pythiumrot) (melon and fruit corruption mould (Pythium aphanidermatum), abnormal female corruption mould (Pythiumirregulare), pythium debaryanum (Pythium debaryanum), group's knot rotten mould (Pythiummyriotylum), ultimate corruption is mould), the rhizoctonia root rot, stem rot and damping off (Rhizoctonia solani Kuhn), sclerotinite stem rot (Sclerotinia stem decay) (sclerotinite), sclerotinite southern blight (neat bulbil bacterium (Sclerotinia rolfsii)), thielaviopsis sp root rot (thielaviopsis sp).
Various auxiliary agents absorb detection---the enforcement of auxiliary agent of the present invention of validity to the Imidacloprid root
Example
The seed of 45 tomato plants (Sorte Rentita) is sowed at respectively in the hole of expanded polystyrene plate, and this expanded polystyrene plate is used based on the specific sowing soil of peat cultivation matrix and is filled.Then this kickboard is placed and be equipped with based on 0.1%
The container of nutrient solution in, and cultivate until reaching required plant size down in 25 ℃, 80% relative atmospheric humidity and illumination in 12 hours.Suitable solution is directly added in the nutrient solution of each case, introduce this plate then.Handle after 12 and 19 days, gather tomato sprout and extraction use HPLC-MS/MS to analyze the content of Imidacloprid then.
Auxiliary agent of the present invention is defined as to compare with control group to make to absorb to improve and surpasses those materials of 20%.
Table 1: the improvement that the plant Imidacloprid absorbs behind every strain tomato plant adding 0.008mg Imidacloprid and the 8mg auxiliary agent.Amount when adding mixture is respectively 8mg.
Preparation embodiment
For the preparation colloidal suspending agent, at first all liq component is mixed with each other.Then add solid, and stir the mixture until forming uniform suspension.Uniform suspension is roughly ground correct grinding more earlier, obtain wherein 90% the solution of solid particle granularity below 10 μ m.Add under the stirring at room subsequently
S and water.Obtain uniform colloidal suspending agent.
Following examples explanation the present invention, and never in any form to its restriction.All data are percetage by weight.
Table 2a: the composition of preparation of the present invention
Table 2b: the composition of preparation of the present invention
Table 2c: the composition of preparation of the present invention
The comparative example
(colloidal suspending agent that contains surfactant, described surfactant is not an auxiliary agent of the present invention, in this example is for the preparation comparison example
SDS is equally referring to table 1), at first all liq component is mixed with each other.Then add solid, and stir the mixture until forming uniform suspension.Uniform suspension is roughly ground correct grinding more earlier, obtain wherein 90% the solution of solid particle granularity below 10 μ m.Add under the stirring at room subsequently
S and water.Obtain uniform colloidal suspending agent.
Table 3: the composition of Comparative formulation (in weight %)
The mensuration of static surface tension
This test uses a kind of commercially available tensometer and platinum loop available from Kruess GmbH (hamburger/Germany) to carry out according to OECD criterion No.115.Before measuring, clean the trace chemistry material that adheres on measuring vessel and the platinum loop with acetone.Remove any surface reactive material of trace on the platinum loop again by abundant heating.All samples is measured after preparation immediately.In order to detect, the sample (non-foam) that 1cm is high is at least added in the measurement device.Sample is heated up measure temperature (25 ℃) until reaching.Then platinum loop is immersed (about 5mm) in the sample.By reducing sample platform (sample bench), platinum loop is shifted out from sample liquid with the constant speed of 5mm/min according to OECD criterion No.115 then.The required pulling force of continuous measurement.The maximum of required pulling force is recorded as measured value.And then platinum loop immersed below the surface, and duplicate measurements.This test is carried out 5 times altogether, and the mean value that will all measure is recorded as surface tension [mN/m].
Table 4: the static surface tension of preparation of the present invention (under 25 ℃, 27mg SC (8mg reactive compound) is in 1000ml water).
| Preparation | Surface tension (mN/m) |
| Embodiment 1 | 57 |
| Embodiment 2 | 53 |
| Embodiment 3 | 40 |
| Embodiment 4 | 43 |
| Embodiment 5 | 59 |
| Embodiment 6 | 60 |
| Embodiment 7 | 45 |
| Embodiment 8 | 55 |
| Embodiment 9 | 50 |
| Water | 72 |
The bin stability of preparation of the present invention
For detecting bin stability, with 100ml preparation stored temperature condition (TW) and 54 ℃ of following eight weeks in variation.The temperature condition that changes be 30 ℃ 48 hours, with 22.5 hours to-15 ℃ ,-15 ℃ of 2 ℃ of/hour coolings 75 hours, with 2 ℃ of/hour intensifications 22.5 hours to 30 ℃.After the storage, sample is returned to room temperature, detect dispersiveness, granularity and viscosity.
Dispersed (DISP) measures according to CIPAC MT 180 methods, and granularity (Part) is measured by Malvern Mastersizer 2000, dynamic viscosity (Visc) by the RheoStress RS 150 of Haake with 20s
-1Measure.
Table 5: the bin stability of preparation of the present invention
Preparation of the present invention use test
Uniform cultivated species is for the pimento of " Feher " arrives cotyledon period in case grow, and just they migrated to the 3 liters of plastic tanks (in 13.5 * 13.5 * 23.5cm) that fill natural arable soil or coconut fibre matrix.After the transplanting plant is cultivated under the condition of 24 ℃, 70% relative atmospheric humidity and 12h illumination (sodium lamp).Every jar is used a dropper to carry out feed and water.Every day, every basin was used the fertilizer solution of about 3 * 20ml.At stop supplies fertilizer after 1 day, promptly sow 29 days after, use the leaching liquor (drench solution) that contains insecticide or insecticide and auxiliary agent.The volume of this leaching liquor is about 60ml/ jar.Using a pipette to turn-take around the base portion of rice shoot leaching liquor is applied on the matrix.Described leaching liquor comprises 0.355mg Imidacloprid/strain plant.Use leaching liquor after one day, recover described plant is carried out the supply of water and fertilizer solution.
In order to detect activity (black peach aphid drug effect), infect pimento plant (the 3-leaf phase is sowed after 25 days, before spray is used 4 days) with the mixed population of black peach aphid at black peach aphid (Myzus persicae).How long can produce drug effect in order to calculate, (plant that grew 30-36 days) detected the lethality in % after spray is used 2 days.The results are shown in table 6 and 8.In order to calculate persistence, the plant that will grow 67 days after spray is used 38 days inoculates with black peach aphid once more as mentioned above, and has detected the black peach aphid lethality in % of the rice shoot first half and Lower Half after 7 days respectively in inoculation.The results are shown in the table 7.Selected testing program is only used female aphid, when these female aphids arrive the adult stage, all can produce new black peach aphid larva basic every day.This can cause the rapid growth of black peach aphid population.
The number of remaining black peach aphid has determined whether the black peach aphid population can rebuild on the treated plant.Therefore, the obvious difference of black peach aphid test only is embodied on the concentration in the greenhouse, and its concentration is compared very low with practical application.The amount of the reactive compound that uses with the 0.355mg/ strain is higher 5 times than the threshold value in the greenhouse test of using the standard preparation that does not contain auxiliary agent.Therefore, 5% difference is significant in the activity.In addition, when drug effect greater than 95% the time, the black peach aphid number on the treated plant is less than 10; 5% drug effect difference can be known identification in this scope because, for example 10 female black peach aphids (90-95% drug effect) can ratio such as the only female black peach aphid of 2-3 (＞98% drug effect) rebuild population with faster speed.
In order to detect the activity at liriomyza trifolii (Liriomyza trifolii (leaf-mining fly)), spray is used after 6 days under transparent cylinder the liriomyza trifolii adult is released on the pimento plant (growing 35 days) and is laid eggs.Spray is used after 13,16 and 20 days the drug effect (purposes embodiment 3, table 9) in the % of impaired blade area that detects the hatching larva.
In order to detect the activity at beet armyworm (Spodoptera exigua (small mottledwillow)), spray is used the 3rd blade cutting every strain pimento plant after 20 days, places petri diss, and inserts beet exigua larvae.Behind required time, the drug effect of this larva is detected (purposes embodiment 4, table 10) in the % lethality.
In contrast, adopt comparative example's (surfactant that contains a kind of non-auxiliary agent of the present invention) and adopt a kind of commercial preparation that does not contain auxiliary agent of the present invention (prior art,
2F, Baeyer farming section) carries out identical test.In this test, compare with check experiment, when using auxiliary agent of the present invention, observe the lethality of increase.Here, described lethality not necessarily all increases at each time point; May only increase to some extent on effect or the long-term effect in the early stage.
Purposes embodiment 1:Black peach aphid in the arable soil
Table 6:
| Lethality/% | |
| Prior art | 60 |
| The comparative example | 70 |
| Embodiment 2 | 75 |
| Embodiment 4 | 72.5 |
| Embodiment 8 | 67.5 |
Table 7:
Purposes embodiment 2:Black peach aphid in the coconut fibre
Table 8:
| Lethality/% | |
| Prior art | 88.75 |
| The comparative example | 93.25 |
| Embodiment 2 | 93.25 |
| Embodiment 6 | 93.75 |
| Embodiment 8 | 94.5 |
Purposes embodiment 3:Liriomyza trifolii in the coconut fibre
Table 9:
Fate after dat=handles (measuring when 13dat=handles back 13 days)
Purposes embodiment 4:Beet armyworm in the arable soil
Table 10:
| Lethality/% | |
| Prior art | 0 |
| Embodiment 1 | 30 |
| Embodiment 2 | 30 |
| Embodiment 3 | 45 |
| Embodiment 4 | 30 |
| Embodiment 6 | 70 |
| Embodiment 7 | 70 |
| Embodiment 8 | 30 |
| Embodiment 9 | 30 |
Claims (13)
1. thereby by use a kind of farming composition control animal nuisance of at least a farmingization reactive compound or method of plant pathogen of comprising to cultivation of plants matrix, described method is characterised in that uses a kind of composition that comprises at least a auxiliary agent.
2. the control animal nuisance of claim 1 or the method for plant pathogen, it is by using a kind of organic solvent content less than 7.5g/l and comprise that the water-based colloidal suspending agent of at least a farmingization reactive compound carries out to cultivation of plants matrix, described method is characterised in that uses a kind of composition that comprises at least a auxiliary agent, described auxiliary agent is characterised in that, when tomato plant a kind of when not having cultivation in the soil series system and described nutrient solution and comprising the Imidacloprid of 0.1ppm and 2.5 to 100ppm auxiliary agent, it can increase the absorption of the rice shoot of described plant to Imidacloprid.
3. claim 1 or 2 method is characterized in that described auxiliary agent is selected from following material:
The oxyalkylated fatty alcohol of-endcapped and the oxyalkylated straight chain alcohol of endcapped,
-have a tributyl phenol polyglycol ether (wherein EO finger ring oxidative ethane) of 10 to 15 EO unit,
-Shi CH
3-(CH
2)
t-CH
2-O-(CH
2-CH
2-O)
uThe branched alkanol alcoxylates of-H, wherein t represents 9 to 10.5 numeral, and u represents 6 to 25 numeral, and t and u be mean value,
The triglycerides of-poly-alkoxylation,
-oxyalkylated fatty amine,
-lauryl (polyoxyethylene) ether sodium sulfate,
-oxyalkylated terpene, and
-comprise corn syrup, the composition of methylate soya-bean oil and nonionic emulsifier.
4. be used for the farming composition of soil, comprise:
-at least a farmingization reactive compound,
-at least a the auxiliary agent that is selected from following material:
The oxyalkylated fatty alcohol of-endcapped and the oxyalkylated straight chain alcohol of endcapped,
-have a tributyl phenol polyglycol ether (wherein EO finger ring oxidative ethane) of 10 to 15 EO unit,
-Shi CH
3-(CH
2)
t-CH
2-O-(CH
2-CH
2-O)
uThe branched alkanol alcoxylates of-H, wherein t represents 9 to 10.5 numeral, and u represents 6 to 25 numeral, and t and u be mean value,
The triglycerides of-poly-alkoxylation,
-oxyalkylated fatty amine,
-lauryl (polyoxyethylene) ether sodium sulfate,
-oxyalkylated terpene, and
-comprise corn syrup, the composition of methylate soya-bean oil and nonionic emulsifier.
5. the composition of claim 4 is characterized in that it is the water-based colloidal suspending agent of a kind of organic solvent content less than 7.5 weight %.
6. claim 4 or 5 composition comprise:
-at least a non-ionic surface active agent and/or at least a anion surfactant,
-one or more are selected from the additive of antifreezing agent, defoamer, preservative, antioxidant, spreader-sticker, colouring agent and/or thickener.
7. each composition in the claim 4 to 6 comprises:
At least a farming reactive compound that is selected from insecticide and bactericide of-1 to 60 weight %,
At least a auxiliary agent of-1 to 50 weight %,
At least a non-ionic surface active agent and/or the anion surfactant of-1 to 20 weight %,
The antifreezing agent of-1 to 20 weight %, and
The additive that is selected from defoamer, preservative, antioxidant, spreader-sticker, colouring agent and/or thickener of-0.1 to 20 weight %.
8. each composition in the claim 4 to 7 is characterized in that described composition comprises at least a reactive compound that is selected from thiophene worm piperazine, thiophene worm amine, thiophene worm quinoline, MTI-446, Acetamiprid, Nitenpyram, Imidacloprid and following compound:
9. the composition of claim 6 is characterized in that it comprises that at least Imidacloprid is as reactive compound.
10. auxiliary agent is used for improving the purposes of crop protection agents in the soil application effect.
11. the purposes of claim 10 is characterized in that using at least a auxiliary agent that is selected from following material:
The oxyalkylated fatty alcohol of-endcapped and the oxyalkylated straight chain alcohol of endcapped,
-have a tributyl phenol polyglycol ether (wherein EO finger ring oxidative ethane) of 10 to 15 EO unit,
-Shi CH
3-(CH
2)
t-CH
2-O-(CH
2-CH
2-O)
uThe branched alkanol alcoxylates of-H, wherein t represents 9 to 10.5 numeral, and u represents 6 to 25 numeral, and t and u be mean value,
The triglycerides of-poly-alkoxylation,
-oxyalkylated fatty amine,
-lauryl (polyoxyethylene) ether sodium sulfate,
-oxyalkylated terpene, and
-comprise corn syrup, the composition of methylate soya-bean oil and nonionic emulsifier.
12. the purposes of claim 10 or 11 is characterized in that organic solvent content improves less than the effect of water-based colloidal suspending agent in soil application of 7.5g/l.
13. each purposes in the claim 10 to 12 is characterized in that the improvement that acts on obtains by the root absorption that increases described reactive compound.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP06020674 | 2006-09-30 | ||
| EP06020674.5 | 2006-09-30 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101541180A true CN101541180A (en) | 2009-09-23 |
Family
ID=37781833
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2007800435497A Pending CN101541180A (en) | 2006-09-30 | 2007-09-18 | Suspension concentrates for improving the root absorption of agrochemical active ingredients |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US20100099717A1 (en) |
| EP (1) | EP2068633A1 (en) |
| JP (1) | JP2010505755A (en) |
| KR (1) | KR20090064471A (en) |
| CN (1) | CN101541180A (en) |
| AR (1) | AR063056A1 (en) |
| AU (1) | AU2007302340A1 (en) |
| BR (1) | BRPI0717239A2 (en) |
| CL (1) | CL2007002818A1 (en) |
| CO (1) | CO6160270A2 (en) |
| MX (1) | MX2009003378A (en) |
| TW (1) | TW200836631A (en) |
| WO (1) | WO2008037379A1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103249303A (en) * | 2010-12-13 | 2013-08-14 | 阿克佐诺贝尔化学国际公司 | Adjuvants for insecticides |
| CN112055537A (en) * | 2018-04-13 | 2020-12-08 | 拜耳公司 | High load formulations containing ketoenol insecticides for instillation and drench applications |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8629086B2 (en) * | 2007-02-06 | 2014-01-14 | Oro Agri, Inc. | Compositions and methods for the control of nematodes and soil borne diseases |
| EP2071952A1 (en) * | 2007-12-21 | 2009-06-24 | Bayer CropScience AG | Use of tetramic acid derivatives for combating plant diseases through drench or drip application |
| WO2009118025A1 (en) * | 2008-03-27 | 2009-10-01 | Bayer Cropscience Aktiengesellschaft | Method for controlling animal pest and plant pathogenic fungi by applying an agrochemical composition into the culture medium, suitable formulation and use thereof |
| WO2009118027A1 (en) * | 2008-03-27 | 2009-10-01 | Bayer Cropscience Aktiengesellschaft | Suspension concentrates for improving root uptake of agrochemically active compounds |
| MX2010010114A (en) * | 2008-03-27 | 2010-09-30 | Bayer Cropscience Ag | Use of tetronic acid derivatives for fighting insects and red spider mites by watering on the ground, droplet application or immersion application. |
| US8404260B2 (en) | 2008-04-02 | 2013-03-26 | Bayer Cropscience Lp | Synergistic pesticide compositions |
| JP5378891B2 (en) * | 2009-06-29 | 2013-12-25 | 住友ゴム工業株式会社 | Puncture sealant |
| SG11201403661SA (en) * | 2012-01-23 | 2014-09-26 | Syngenta Ltd | Plant growth media wetting compositions |
| EP2811828B1 (en) * | 2012-01-23 | 2021-09-01 | Syngenta Participations AG | Adjuvant compositions |
| CN104968190B (en) * | 2012-09-13 | 2018-09-21 | 罗地亚经营管理公司 | Wettable peat moss, preparation method and application method |
| AU2017334547A1 (en) | 2016-09-29 | 2019-04-18 | Jrx Biotechnology, Inc. | Methods and compositions for modifying plant growth and reducing water consumption by plants |
| US11634368B2 (en) | 2018-03-28 | 2023-04-25 | Jrx Biotechnology, Inc. | Agricultural compositions |
| BR112020017813A2 (en) | 2018-04-13 | 2020-12-29 | Bayer Aktiengesellschaft | SOLID FORMULATION OF INSECTICID MIXTURES |
| KR20240116996A (en) * | 2021-12-22 | 2024-07-30 | 구미아이 가가쿠 고교 가부시키가이샤 | Prohexadione plant growth regulator composition |
Family Cites Families (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2096484A (en) * | 1934-11-30 | 1937-10-19 | Westinghouse Air Brake Co | Bypass valve for dirt collectors |
| JPS515450B1 (en) * | 1971-06-29 | 1976-02-20 | ||
| US4024163A (en) * | 1972-05-25 | 1977-05-17 | National Research Development Corporation | Insecticides |
| EG11383A (en) * | 1972-07-11 | 1979-03-31 | Sumitomo Chemical Co | Novel composition for controlling nixious insects and process for preparing thereof |
| US4220591A (en) * | 1975-11-26 | 1980-09-02 | Commonwealth Scientific And Industrial Research Organization | Insecticidal esters |
| JPS5324019A (en) * | 1976-08-18 | 1978-03-06 | Sumitomo Chem Co Ltd | Inspecticide comprising optically active isomer of alpha-cyano-3-phenoxybenzyl-2-(4-chlorophenyl)-isovalerate as an effective component |
| SE446527B (en) * | 1976-09-21 | 1986-09-22 | Roussel Uclaf | NEW CYCLOPROPANCARBOXYLIC ACID ESTERS WITH A POLYHALOGENATED SUBSTITUENT, SET FOR PREPARATION OF IT AND USE thereof IN PESTICIDE COMPOSITIONS |
| US4178460A (en) * | 1976-10-01 | 1979-12-11 | American Cyanamid Co. | 2-Haloalkyl(oxy-, thio-, sulfinyl-, or sulfonyl)-phenylalkanoic acids |
| US4183948A (en) * | 1977-01-24 | 1980-01-15 | Imperial Chemical Industries Limited | Halogenated esters |
| DE2709264C3 (en) * | 1977-03-03 | 1982-01-21 | Bayer Ag, 5090 Leverkusen | Substituted phenoxybenzyloxycarbonyl derivatives, processes for their preparation and their use as insecticides and acaricides and new intermediates |
| US4329518A (en) * | 1979-09-18 | 1982-05-11 | Fmc Corporation | Insecticidal [1,1'-biphenyl]-3-ylmethyl esters |
| US4254050A (en) * | 1979-09-27 | 1981-03-03 | Fmc Corporation | Preparation of esters |
| US4260633A (en) * | 1980-04-21 | 1981-04-07 | Zoecon Corporation | Pesticidal esters of amino acids |
| US4397864A (en) * | 1980-05-02 | 1983-08-09 | Mitsuitoatsu Chemicals Inc. | 2-Arylpropyl ether or thioether derivatives and insecticidal and acaricidal agents containing said derivatives |
| US4732903A (en) * | 1980-07-02 | 1988-03-22 | Roussel Uclaf | Certain cyclopropyl dicarboxylates having pesticidal and insecticidal activity |
| CA1162561A (en) * | 1981-05-26 | 1984-02-21 | Derek A. Wood | Preparation of cyanobenzyl cyclopropane carboxylates |
| DE3125447A1 (en) * | 1981-06-27 | 1983-01-13 | A. Nattermann & Cie GmbH, 5000 Köln | NEW NEMATICIDE COMPOSITION, METHOD FOR THE PRODUCTION AND USE THEREOF |
| GB8308507D0 (en) * | 1983-03-28 | 1983-05-05 | Ici Plc | Insecticidal product |
| DE3324274A1 (en) * | 1983-07-06 | 1985-01-24 | Leonhard Schmid Kg, 8900 Augsburg | CHOPPER FOR GARDEN WASTE AND THE LIKE |
| ATE67493T1 (en) * | 1985-02-04 | 1991-10-15 | Bayer Agrochem Kk | HETEROCYCLIC COMPOUNDS. |
| DE3522629A1 (en) * | 1985-06-25 | 1987-01-08 | Bayer Ag | METHOD FOR PRODUCING SPECIFIC ENANTIOMER PAIRS OF PERMETHRINIC ACID (ALPHA) CYANO-3-PHENOXY-4-FLUOR-BENZYL ESTERS |
| JPH0717621B2 (en) * | 1986-03-07 | 1995-03-01 | 日本バイエルアグロケム株式会社 | New heterocyclic compound |
| US4782094A (en) * | 1986-03-14 | 1988-11-01 | Mitsui Toatsu Chemicals, Inc. | Difluorobromomethoxyphenyl derivative and miticide comprising said derivative as active ingredient |
| DE3856493T2 (en) * | 1987-08-01 | 2002-05-23 | Takeda Chemical Industries, Ltd. | Alpha-unsaturated amines, their production and use |
| IE960441L (en) * | 1988-12-27 | 1990-06-27 | Takeda Chemical Industries Ltd | Guanidine derivatives, their production and insecticides |
| TW240163B (en) * | 1992-07-22 | 1995-02-11 | Syngenta Participations Ag | Oxadiazine derivatives |
| JP2766848B2 (en) * | 1993-10-26 | 1998-06-18 | 三井化学株式会社 | Furanyl insecticides |
| US6074987A (en) * | 1998-05-28 | 2000-06-13 | Bayer Corporation | Inhibiting phase separation in low viscosity water-based pesticide suspensions |
| CA2345296A1 (en) * | 1998-09-25 | 2000-04-06 | American Cyanamid Company | Non-aqueous suspension concentrate |
| FR2806878A1 (en) * | 2000-03-30 | 2001-10-05 | Aventis Cropscience Sa | NOVEL MONOPHASIC FLUIDIFIABLE CONCENTRATE AS A PESTICIDE AND / OR REGULATORY GROWTH COMPOSITION |
| DE10129855A1 (en) * | 2001-06-21 | 2003-01-02 | Bayer Ag | Suspension concentrates based on oil |
| DE102004011007A1 (en) * | 2004-03-06 | 2005-09-22 | Bayer Cropscience Ag | Suspension concentrates based on oil |
| DE102004011006A1 (en) * | 2004-03-06 | 2005-09-22 | Bayer Cropscience Ag | Suspension concentrates based on oil |
-
2007
- 2007-09-18 MX MX2009003378A patent/MX2009003378A/en not_active Application Discontinuation
- 2007-09-18 BR BRPI0717239-7A patent/BRPI0717239A2/en not_active Application Discontinuation
- 2007-09-18 US US12/442,514 patent/US20100099717A1/en not_active Abandoned
- 2007-09-18 JP JP2009529577A patent/JP2010505755A/en not_active Withdrawn
- 2007-09-18 CN CNA2007800435497A patent/CN101541180A/en active Pending
- 2007-09-18 AU AU2007302340A patent/AU2007302340A1/en not_active Abandoned
- 2007-09-18 WO PCT/EP2007/008101 patent/WO2008037379A1/en active Application Filing
- 2007-09-18 KR KR1020097008748A patent/KR20090064471A/en not_active Application Discontinuation
- 2007-09-18 EP EP07818206A patent/EP2068633A1/en not_active Withdrawn
- 2007-09-28 AR ARP070104315A patent/AR063056A1/en unknown
- 2007-09-28 CL CL200702818A patent/CL2007002818A1/en unknown
- 2007-09-28 TW TW096136079A patent/TW200836631A/en unknown
-
2009
- 2009-03-26 CO CO09031203A patent/CO6160270A2/en unknown
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103249303A (en) * | 2010-12-13 | 2013-08-14 | 阿克佐诺贝尔化学国际公司 | Adjuvants for insecticides |
| CN103249303B (en) * | 2010-12-13 | 2015-08-12 | 阿克佐诺贝尔化学国际公司 | Insecticide used additives |
| CN112055537A (en) * | 2018-04-13 | 2020-12-08 | 拜耳公司 | High load formulations containing ketoenol insecticides for instillation and drench applications |
Also Published As
| Publication number | Publication date |
|---|---|
| EP2068633A1 (en) | 2009-06-17 |
| TW200836631A (en) | 2008-09-16 |
| BRPI0717239A2 (en) | 2013-10-08 |
| CO6160270A2 (en) | 2010-05-20 |
| AR063056A1 (en) | 2008-12-23 |
| AU2007302340A1 (en) | 2008-04-03 |
| US20100099717A1 (en) | 2010-04-22 |
| KR20090064471A (en) | 2009-06-18 |
| WO2008037379A1 (en) | 2008-04-03 |
| JP2010505755A (en) | 2010-02-25 |
| MX2009003378A (en) | 2009-04-09 |
| CL2007002818A1 (en) | 2008-04-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101553115A (en) | Improvement to the biological efficacy of agrochemical compositions on application in the growth substrate suitable formulations and use thereof | |
| CN101541180A (en) | Suspension concentrates for improving the root absorption of agrochemical active ingredients | |
| CN101522031B (en) | Suspension concentrates | |
| JP5371761B2 (en) | Agrochemical formulations dispersible in water containing polyalkoxytriglycerides as penetration enhancers | |
| JP5300740B2 (en) | Spirocyclic tetronic acid derivatives | |
| MX2009001353A (en) | Use of tetramic acid derivatives with fertilizers. | |
| CN101484003A (en) | Synergistic insecticide and fungicidal mixtures | |
| BRPI0713936A2 (en) | synergistically insecticidal and fungicidal mixtures | |
| CN101588720A (en) | Synergistic active ingredient combination | |
| JP2009542737A (en) | Pyrethroid liquid formulation | |
| JP5220745B2 (en) | New formulation for sustained release of agrochemically active substances | |
| WO2009118027A1 (en) | Suspension concentrates for improving root uptake of agrochemically active compounds | |
| CN101505602A (en) | Formulations for the controlled release of agrochemical active agents | |
| WO2009118025A1 (en) | Method for controlling animal pest and plant pathogenic fungi by applying an agrochemical composition into the culture medium, suitable formulation and use thereof | |
| JP2010500979A (en) | Insecticidal heterocyclic carboxylic acid derivatives | |
| CN101460056A (en) | Active substance combinations with insecticidal properties |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20090923 |