CN101538463A - Light-storable self luminous transparent film - Google Patents
Light-storable self luminous transparent film Download PDFInfo
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- CN101538463A CN101538463A CN200810084321A CN200810084321A CN101538463A CN 101538463 A CN101538463 A CN 101538463A CN 200810084321 A CN200810084321 A CN 200810084321A CN 200810084321 A CN200810084321 A CN 200810084321A CN 101538463 A CN101538463 A CN 101538463A
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Abstract
The invention relates to a light-storable self luminous transparent film, which comprises a transparent organic resin film, light-storable self luminous transparent granules, and accessional materials, wherein the light-storable self luminous transparent granules of which the diameter range is between 5 nanometers and 300 meshes are evenly distributed in the transparent organic resin film.
Description
Invention field:
The present invention relates to the organic resin membrane product, particularly the transparent film made from light-accumulating luminous material and organic resin material.
Background technology:
Chinese patent ZL98101173.X " a kind of light-accumulative luminous plastics " discloses following content: the present invention is grouped into by resin, light-accumulative luminous powder, glass powder or three kinds of one-tenth of glass microballon, its preparation method is to be carrier with the resin, use glass powder or glass microballon to be filler, with three kinds of compositions heating mixing, fusion, granulation both light-accumulative luminous material.
Chinese patent ZL200410051865.7 " light-accumulated luminous self adhesive foil of color fluorescence and preparation method thereof " discloses following content: this self adhesive foil is based on common self adhesive foil, increase the light-accumulated luminous layer of one deck color fluorescence, the light-accumulated luminous layer of this fluorescence contains the fluorescent material of 10-35% and the light-accumulated luminous powder of 10-35%.
Chinese patent ZL200410015259.X " light accumulating luminous paper " discloses following content: the luminescent layer that has the overlength afterglow luminescent properties in the spraying of the surface of the senior pure white paper of import with gum, described luminescent layer is made of quartzy varnish, thinner, solidifying agent, light-accumulated luminous powder, and these four kinds of raw materials mix the back by a certain percentage and divide on the surface that is sprayed on pure white paper for four times.
Above-mentioned patent does not relate to mixes the manufacturing membrane technique with light-accumulating luminous particle and transparent organic resin, and light-accumulating luminous material is melted in transparent SiO
2The manufacturing membrane technique is mixed in the back in particle or transparent inorganic glass particle or the transparent organic resin particle with transparent organic resin.Do not relate to light-accumulating luminous uniform particles and be distributed in technology in the transparent adhesive film, not relating to light-accumulating luminous uniform particles is distributed in the transparent adhesive film, cover the transparent organic resin membrane technique on the transparent adhesive film, do not relate to and contain light-accumulating luminous material braiding air-permeable envelope technology, do not relate to the gluing technology on the light-accumulating luminous material gluing transparent organic resin film that contains.
Summary of the invention:
The objective of the invention is: 1, light-accumulating luminous uniform particles is distributed in the transparent organic resin film or light-accumulating luminous uniform particles is distributed in the transparent adhesive film, covers the transparent organic resin film on the transparent adhesive film., after rayed, light-accumulating luminous particle can continue luminous.Be used for plastic sheeting for farm use, can prolong the light application time of plant, improve plant biomass.Be used for building and car and boat, solve illumination at night problem.2, light-accumulating luminous material is included in transparent SiO
2In particle or transparent inorganic glass particle or the transparent organic resin particle, solve the easy oxidation of light-accumulating luminous material, the problem that easily absorbs water, the work-ing life of improving light-accumulating luminous film.3, light-accumulating luminous material is included in spherical transparent SiO
2In particle or spherical transparent inorganic glass particle or the transparent organic resin particle, increase the brightness and the transparency of light-accumulating luminous material, prevent because of light-accumulating luminous material and spherical transparent SiO
2The uneven problem of particle or spherical transparent inorganic glass particle or the spherical transparent organic resin particle light that skewness causes in organic resin glass.4, add phase-changing energy storage material in the light-accumulating luminous transparent sponge film, improve the utilization ratio of solar thermal energy, save energy.5, contain the air-permeable envelope that light-accumulating luminous material and attached material (as: TiO2 or Ag nano particle) are woven into, have luminous and sterilization functions.6, contain light-accumulating luminous material and attached material (as: fluorescent grain), the suitable road sign of making.7, gluing or double spread on light-accumulating luminous transparent organic resin film are suitablely made light-accumulating luminous transparent dressing film glass or are made light-accumulating luminous transparent doubling glass.
The light-storable self luminous transparent film that the present invention proposes, comprise: the transparent organic resin film, light-accumulating luminous transparent grain, attached material, diameter range are that the light-accumulating luminous uniform particles of 5nm-300 order is distributed in the transparent organic resin film or is evenly distributed in the transparent adhesive film.Wherein: 5nm-0.1 μ m is a nano-scale particle, 0.1-1 μ m super-fine powder grade particles, when adopting nano-scale particle or adopting the super-fine powder grade particles, light can be walked around particle, influences the transparence of light-storable self luminous transparent film hardly.Be used for plastic sheeting for farm use, light-storable self luminous transparent film through daylight penetrate hold energy storage capacity after, night is still luminous, prolongs the light application time of plant, improves plant biomass.Be used for building, car and boat on the road markings, solve illumination at night problem.
For increasing light-accumulating luminous particulate luminance brightness and prevent light-accumulating luminous particulate oxidation, suction in the work-ing life of improving light-accumulating luminous material, is included in transparent SiO with flame method or chemical method or spray pattern with light-accumulating luminous material
2In particle or transparent inorganic glass particle or the transparent organic resin particle, then, be evenly distributed in the transparent organic resin film and be evenly distributed in the transparent adhesive film, produce light-storable self luminous transparent film.
For preventing light-accumulating luminous particulate oxidation, suction improves light-accumulating luminous material work-ing life, and the luminous uniform particles is distributed in the transparent adhesive film, one or both sides cover the transparent organic resin film on the transparent adhesive film, prevent light-accumulating luminous material oxidation, suction in the transparent adhesive film.
Be to improve the heat-insulating property and the sound insulation property of light-storable self luminous transparent film, light-accumulating luminous material or contain the transparent SiO of light-accumulating luminous material
2Particle or transparent inorganic glass particle or transparent organic resin particle or phase-changing energy storage material add in the transparent organic resin foam films; behind foaming; make the transparent sponge film that contains light-accumulating luminous material, or make the transparent SiO that contains light-accumulating luminous material
2The transparent sponge film of particle or transparent inorganic glass particle or transparent organic resin particulate or contain the light-accumulating luminous transparent sponge film of phase-changing energy storage material.Phase-changing energy storage material can be stored at the heat that sunlight absorbs in the phase-changing energy storage material, when cold, by phase transformation heat is emitted.
For preventing that sponge film surface from absorbing dust or rainwater, improve sponge film tensile strength and survivability, the transparent organic resin of the covering up and down film of light-accumulating luminous transparent sponge, transparent organic resin film and light-accumulating luminous transparent sponge film are combined into one.
The another kind of structure of light-storable self luminous transparent film is to draw wire with the transparent organic resin that contains light-accumulating luminous material, is woven into the porous air-permeable envelope with transparent silk.The porous air-permeable envelope has lighting function and airing function.With contain light-accumulating luminous material and attached material as: the transparent organic resin of TiO2 or Ag nano particle draws wire, and the air-permeable envelope that is woven into has luminous and sterilization functions, and appropriate architecture or hospital use.
The another kind of structure of light-storable self luminous transparent film is at gluing of the transparent organic resin film that contains light-accumulating luminous material or double spread; pasting protective film on the glue; gummed transparent organic resin film sticks on transparent adhesive film on glass or light-accumulating luminous and sticks on glass; paste the transparent organic resin film on the glued membrane, be used to make light-accumulating luminous transparent dressing film glass.Contain light-accumulating luminous transparent hot melt film and stick between upper strata glass and the lower floor's glass, be used to make light-accumulating luminous transparent doubling glass.
In light-storable self luminous transparent film, add attached material, can give the light-storable self luminous transparent film property, improve the light-storable self luminous transparent film sunlight control characteristics, ultraviolet resistance, anti-infrared performance, pollution-proof performance, sterilizing function, the photoelectricity fluorescence property is made versicolor light-storable self luminous transparent film.Attached material package is drawn together fluorescent grain, TiO
2, ZnO, Cu
2O, CuO, CdO, Co
2O
3, Ni
2O
3, MnO
2, AgCl, iron protoxide, dichromate, ferric oxide, tin indium oxide, europium sesquioxide, yttrium oxide, terbium sesquioxide, cerium oxide, rare earth, magnetic particle, coupling agent, stopper, gold and silver, copper, tin, platinum, titanium, magnesium, chromium, stainless steel, above-mentioned element metallic compound, coupling agent, stopper or silicon solar material.
Add TiO in the light-storable self luminous transparent film
2Have bacteriostasis antibiosis, gas pollutant formaldehyde, toluene function in the decontamination chamber, anti-light-storable self luminous transparent film pollutes function, function of shielding ultraviolet radiation.Add ZnO and have function of shielding ultraviolet radiation.Add Cu
2O makes light-storable self luminous transparent film have redness.Adding CuO makes light-storable self luminous transparent film have blue-greenish colour.It is light yellow that interpolation CdO has light-storable self luminous transparent film.Add Co
2O
3Make light-storable self luminous transparent film have blueness.Add Ni
2O
3It is blackish green that light-storable self luminous transparent film is had.Add MnO
2Make light-storable self luminous transparent film have purple.Adding AgCl makes light-storable self luminous transparent film have light sensitive characteristic.Add iron protoxide and absorb infrared rays and part visible light, add dichromate, ferric oxide absorbs ultraviolet ray and part visible light, adds europium sesquioxide, yttrium oxide, terbium sesquioxide, cerium oxide, makes light-storable self luminous transparent film have the characteristics of luminescence.The interpolation rare earth is made the variable color light-storable self luminous transparent film, interpolation magnetic particle makes light-storable self luminous transparent film have magnetic, manufactures the magnetic light-storable self luminous transparent film.Add fluorescent grain, manufacture the fluorescence light-storable self luminous transparent film.Add the silicon solar material; as: mono-crystalline silicon solar particle, polycrystalline silicon solar particle, non-crystal silicon solar energy granule manufacture become the photoelectricity light-storable self luminous transparent film, add coupling agent spherical transparent SiO2 particle or spherical transparent inorganic glass particle or spherical transparent organic resin particle and transparent organic resin are better merged.Adding stopper does not reunite spherical transparent SiO2 particle or spherical transparent inorganic glass particle or spherical transparent organic resin particle.Add extremely metallic compound of titanium, magnesium, chromium or stainless steel, making has suitable transmissivity to visible light, and infrared rays is had higher reflectivity, ultraviolet ray is had the heat reflection light-storable self luminous transparent film of higher absorption rate.Add gold and silver, copper, tin, its metallic compound of platinode, making has high transmittance to visible light, and infrared rays is had very high reflectivity, has the low radiation light-storable self luminous transparent film of good heat-proof quality.
Light-accumulating luminous material comprises: the light-accumulating luminous particle of rare earth aluminate, as: glow color is that hepatic europium, neodymium activate CaAl2O4:Eu, Nb particle, glaucous europium, activated by dysprosium Sr4Al14O25:Eu, the Dy particle, yellowish green europium, activated by dysprosium SrAl2O4:Eu, Dy particle.The light-accumulating luminous particle of rare earth silicate, as: the pyrosilicate blue-light-emitting particle of europium, activated by dysprosium, europium, neodymium activated aluminate blue-light-emitting particle, the white luminous particle of the orthosilicate of magnesium activated.The light-accumulating luminous type light-emitting particles of sulfide, as: yellowish green ZnS:Cu series particle, blue CaS:Bi series particle, red CaS:Eu series particle.Can use a kind of light-accumulating luminous type luminescent material in the light-storable self luminous transparent film, also can be used by multiple light-accumulating luminous type luminescent material.
Transparent organic resin comprises: any in PMMA, transparent PP, PC, PET, PETG, PVB, PSF (polysulfones), MMA (fluorinated polyimide), poly-fragrant fat, polyarylsulphone, the transparent anti-impact resin of butylbenzene, organosilicon transparent resin, ADC (allyl diglycol carbonates), PEN (PEN), Resins, epoxy, bulk alicyclic polyene resin or the PC-PMMA blend transparent resin.
Advantage of the present invention is: 1, light-accumulating luminous uniform particles is distributed in the transparent organic resin film or light-accumulating luminous uniform particles is distributed in the transparent adhesive film, after rayed, prolongs the fluorescent lifetime of transparent organic resin film.Be used for plastic sheeting for farm use, can prolong the light application time of plant, improve plant biomass.Be used for building and car and boat and road markings, solve illumination at night problem.2, light-accumulating luminous material is included in transparent SiO
2In particle or transparent inorganic glass particle or the transparent organic resin particle, solve the easy oxidation of light-accumulating luminous material, the problem that easily absorbs water, the work-ing life of improving light-accumulating luminous film.3, light-accumulating luminous material is included in spherical transparent SiO
2In particle or spherical transparent inorganic glass particle or the transparent organic resin particle, increase the brightness and the transparency of light-accumulating luminous material.4, light-accumulating luminous transparent sponge film improves heat-insulating property and sound insulation property.5, add phase-changing energy storage material in the light-accumulating luminous transparent sponge film, improve the utilization ratio of solar thermal energy, save energy.6, contain light-accumulating luminous material and attached material as: the air-permeable envelope that TiO2 or Ag nano particle are woven into has luminous and sterilization functions.7, on the light-accumulating luminous transparent resin film sticking glass or on the light-accumulating luminous transparent adhesive film sticking glass, paste the transparent organic resin film on the glued membrane, make light-accumulating luminous transparent dressing film glass, light-accumulating luminous transparent adhesive film is used between the layer glass, makes light-accumulating luminous transparent doubling glass.
Description of drawings:
Below in conjunction with Figure of description and embodiment the present invention is further described.
Fig. 1 is the light-accumulating luminous transparent organic resin film cross-section structure with feature of the present invention.
Fig. 2 is the transparent organic resin film cross-section structure with the light-accumulating luminous material transparent organic resin granule manufacture of parcel with feature of the present invention.
Fig. 3 has the light-accumulating luminous material of feature of the present invention and the transparent organic resin bactericidal film cross-section structure of TiO2 granule manufacture.
Fig. 4 is the transparent organic resin sponge film cross-section structure with light-accumulating luminous material manufacturing of usefulness of feature of the present invention.
Fig. 5 has the air-permeable envelope cross-section structure that the transparent silk of light-accumulating luminous material of containing of feature of the present invention is woven into.
The light-accumulating luminous transparent organic resin that Fig. 6 has feature of the present invention is coated with the bond paper facing cross-section structure.
Fig. 7 has the light-accumulating luminous transparent organic resin pad pasting glass cross-section structure of feature of the present invention.
Fig. 8 has the light-accumulating luminous organic resin double-side membrane of feature of the present invention cross-section structure.
Fig. 9 has the doubling glass cross-section structure of the light-accumulating luminous transparent adhesive film manufacturing of feature of the present invention.
Figure 10 has the two glued membrane cross-section structures of the light-accumulating luminous organic resin of feature of the present invention.
Embodiment:
Embodiment 1:
A kind of light-accumulating luminous transparent organic resin film cross-section structure as shown in Figure 1, wherein: the 1st, the PMMA organic resin film, the 2nd, the light-accumulating luminous particle of rare earth aluminate, the light-accumulating luminous particle 2 of rare earth aluminate is evenly distributed in the fusion PMMA organic resin, produces with film balance and contains the light-accumulating luminous particulate PMMA of rare earth aluminate organic resin film.
A kind of transparent organic resin film cross-section structure such as Fig. 2 with the light-accumulating luminous material transparent organic resin granule manufacture of parcel shows, wherein: the 3rd, the PET organic resin film, the 4th, the light-accumulating luminous particle of rare earth aluminate, the 5th, the PMMA spherical resin, the light-accumulating luminous particle of rare earth aluminate is heated to 120 degree, be sprayed onto in the PMMA resin aerosol with nozzle, the thawing of PMMA resin is bonded at the light-accumulating luminous particle surface of rare earth aluminate, manufacture PMMA spherical resin 5, the light-accumulating luminous particle 4 of native aluminate of parcel PMMA resin is evenly distributed in the fusion PET organic resin, produces with film balance and contain the light-accumulating luminous particulate PET of rare earth aluminate organic resin film.The light-accumulating luminous particle of PMMA spherical resin protection rare earth aluminate, anti-oxidation or suction strengthen the light-accumulating luminous particle brightness of rare earth aluminate.
Transparent organic resin bactericidal film cross-section structure such as Fig. 3 of a kind of light-accumulating luminous material and TiO2 granule manufacture show, wherein: the 6th, the PET organic resin film, the 7th, the light-accumulating luminous particle of rare earth aluminate, the 8th, the PMMA spherical resin, the 9th, the TiO2 particle, the light-accumulating luminous particle of rare earth aluminate is heated to 120 degree, be sprayed onto in the PMMA resin aerosol with nozzle, the thawing of PMMA resin is bonded at the light-accumulating luminous particle surface of rare earth aluminate, manufacture PMMA spherical resin 8, the light-accumulating luminous particle 7 of native aluminate and the TiO2 particle 9 of parcel PMMA resin are evenly distributed in the fusion PET organic resin, produce the PET organic resin film that contains light-accumulating luminous particle of rare earth aluminate and TiO2 particle 9 with film balance.Containing light-accumulating luminous material and TiO2 particulate resin film has luminous and sterilization and self-cleaning action.
The transparent organic resin sponge film cross-section structure that the light-accumulating luminous material of a kind of usefulness is made as shown in Figure 4, wherein: the 10th, PET organic resin sponge, the 11st, the light-accumulating luminous particle of rare earth silicate, the 12nd, glass particle, the 13rd, upper strata PET film, the 14th, the PET of lower floor film.At first glass melting is become liquid, add the light-accumulating luminous particle of rare earth silicate, evenly stir, manufacture with spray method and to include the light-accumulating luminous particulate glass particle 14 of rare earth silicate, glass particle 14 and whipping agent add in the fused PET organic resin, contain the light-accumulating luminous particle PET of rare earth silicate organic resin sponge 10 with the manufacturing of foaming machine, be PET film 13 above the PET organic resin sponge 10, below PET organic resin sponge 10, be PET film 14, with the transparent organic resin sponge film that foaming in the PET circular membrane is made, the PET film is wrapped in around the transparent organic resin cavernous body.
A kind ofly contain air-permeable envelope cross-section structure that the transparent silk of light-accumulating luminous material is woven into as shown in Figure 5, wherein: the 15th, the air-permeable envelope that organic transparent silk is woven into, the 16th, the light-accumulating luminous particle of rare earth silicate, the 17th, Ag nano particle.At first organic resin is fused into liquid state, adds light-accumulating luminous particle 16 of rare earth silicate and Ag nano particle 17, draw wire, weave into air-permeable envelope 15 with braiding machine with drawing wire machine.Ag nano particle 17 has sterilization functions in the air-permeable envelope that is woven into, and the light-accumulating luminous particle 16 of the rare earth silicate in the air-permeable envelope that is woven into has the luminous effect of continuity, and the suitable hospital of this product uses.
A kind of light-accumulating luminous transparent organic resin is coated with the bond paper facing cross-section structure as shown in Figure 6, wherein: the 18th, organic resin film, the 19th, hot melt adhesive film, the 20th, the light-accumulating luminous particle of nano rare earth silicate, the 21st, protective membrane.Light-accumulating luminous pearl glue 20 uniform mixing of nano rare earth silicate are in hot melt adhesive film 19; hot melt adhesive film 19 one sides stick on the organic resin film 18; another side sticks on the protective membrane 21; the light-accumulating luminous particle 20 of nano rare earth silicate makes organic resin film 18 have lighting function; protective membrane 21 prevents glue stain, during use, protective membrane 21 is torn; hot melt adhesive film 19 sticks on the goods, manufactures the light-accumulating luminous goods with characteristics of luminescence.
Embodiment 7:
Light-accumulating luminous transparent organic resin pad pasting glass cross-section structure as shown in Figure 7, wherein: the 22nd, glass, the 23rd, UV transparent optical solidified glue film, the 24th, the light-accumulating luminous particle of rare earth silicate, the 25th, organic resin film, UV transparent optical solidified glue film 23 one sides that contain the light-accumulating luminous particle 24 of rare earth silicate stick on the glass 22, another side sticks on the organic resin film 25, pressurization, after the exhaust, after the UV-lamp irradiation, contain the organic resin film 25 and glass 22 firm bonding together of the light-accumulating luminous particle 24 of rare earth silicate, produce light-accumulating luminous transparent dressing film glass.
In the present embodiment, the transparent optic-solidified adhesive of UV can substitute with hot melt adhesive.
A kind of light-accumulating luminous transparent organic resin double-side membrane cross-section structure as shown in Figure 8, wherein: the 26th, the upper strata organic resin film, the 27th, hot melt adhesive film, the 28th, the light-accumulating luminous particle of rare earth silicate, the 29th, lower floor's organic resin film, hot melt adhesive film 27 one sides that contain the light-accumulating luminous particle 28 of rare earth silicate stick on the upper strata organic resin film 26, and another side sticks on lower floor's organic resin film 29.
The advantage of present embodiment is: the light-accumulating luminous particle of rare earth silicate is clipped in the middle by organic resin film, is difficult for meeting water and loses efficacy, and suitable luminous especially plastic sheeting for farm use uses.
Embodiment 9:
The doubling glass cross-section structure that a kind of light-accumulating luminous transparent adhesive film is made as shown in Figure 9, wherein: the 30th, upper strata glass, the 31st, UV photocuring transparent adhesive film, the 32nd, the light-accumulating luminous particle of rare earth silicate, the 33rd, lower floor's glass, the light-accumulating luminous particle 32 of rare earth silicate is evenly distributed in the UV photocuring transparent adhesive film 31, UV photocuring transparent adhesive film 31 is placed on 33 in upper strata glass 30 and lower floor's glass, pressurization, after the exhaust, shine with UV-lamp, the UV photocuring transparent adhesive film 31 that is mixed with the light-accumulating luminous particle 32 of rare earth silicate bonds together upper strata glass 30 and lower floor's glass 33, makes light-accumulating luminous doubling glass.
Embodiment 10:
The two glued membrane cross-section structures of a kind of light-accumulating luminous organic resin as shown in figure 10; wherein: the 34th, the upper strata organic resin film; the 35th, contain the light-accumulating luminous particulate hot melt adhesive film of rare earth silicate; the 36th, the light-accumulating luminous particle of rare earth silicate; the 37th, lower floor's organic resin film; the 38th, hot melt adhesive film, the 39th, release protective membrane.Containing light-accumulating luminous particle hot melt adhesive film 35 one sides of rare earth silicate sticks on the upper strata organic resin film 34; another side sticks on lower floor's organic resin film 37; the another side of lower floor's organic resin film 37 is pasted hot melt adhesive film 38, pastes release protective membrane 39 on the hot melt adhesive film 38.During use, release protective membrane 39 is torn, hot melt adhesive film 38 sticks on the goods, manufactures the light-accumulating luminous goods with characteristics of luminescence.
The advantage of this product is: the light-accumulating luminous particle of rare earth silicate is pressed from both sides by organic resin film In the centre, be difficult for meeting water and lost efficacy, hot melt adhesive film sticks on the goods, especially suitable outdoor road Indicateing arm causes usefulness.
Claims (10)
1, a kind of light-storable self luminous transparent film comprises: the transparent organic resin film, and light-accumulating luminous transparent grain, attached material is characterized in that diameter range is that the light-accumulating luminous uniform particles of 5nm-300 order is distributed in the transparent organic resin film.
2, light-storable self luminous transparent film as claimed in claim 1 is characterized in that light-accumulating luminous uniform particles is distributed in the transparent adhesive film.
3, light-storable self luminous transparent film as claimed in claim 1 is characterized in that light-accumulating luminous uniform particles is distributed in the transparent adhesive film, and one or both sides cover the transparent organic resin film on the transparent adhesive film.
4,, it is characterized in that light-accumulating luminous material is included in transparent SiO as claim 1,2,3 described light-storable self luminous transparent films
2In particle or transparent inorganic glass particle or the transparent organic resin particle.
5, light-storable self luminous transparent film as claimed in claim 1 is characterized in that light-storable self luminous transparent film is by containing the air-permeable envelope that the transparent silk of light-accumulating luminous material is woven into.
6, light-storable self luminous transparent film as claimed in claim 1 is characterized in that containing gluing of light-accumulating luminous material transparent organic resin film or double spread, pasting protective film on the glue.
7, light-storable self luminous transparent film as claimed in claim 1, it is characterized in that containing a gummed transparent organic resin of light-accumulating luminous material film sticks on plane of glass, or contain light-accumulating luminous particulate transparent adhesive film and stick on plane of glass, paste the transparent organic resin film on the glued membrane, or the transparent organic resin glue-film stickup that contains light-accumulating luminous material is between upper strata glass and lower floor's glass.
8,, it is characterized in that attached material package draws together fluorescent grain, TiO as claim 1,2,3 described light-storable self luminous transparent films
2, ZnO, Cu
2O, CuO, CdO, Co
2O
3, Ni
2O
3, MnO
2, AgCl, iron protoxide, dichromate, ferric oxide, tin indium oxide, europium sesquioxide, yttrium oxide, terbium sesquioxide, cerium oxide, rare earth, magnetic particle, coupling agent, stopper, gold and silver, copper, tin, platinum, titanium, magnesium, chromium, stainless steel, above-mentioned element metallic compound, coupling agent, stopper or silicon solar material.
9, light-storable self luminous transparent film as claimed in claim 1 is characterized in that light-accumulating luminous material comprises: light-accumulating luminous particle of rare earth aluminate or the light-accumulating luminous particle of rare earth silicate or the light-accumulating luminous type light-emitting particles of sulfide.
10, light-storable self luminous transparent film as claimed in claim 1 is characterized in that transparent organic resin comprises: any in PMMA, transparent PP, PC, PET, PETG, PVB, PSF (polysulfones), MMA (fluorinated polyimide), poly-fragrant fat, polyarylsulphone, the transparent anti-impact resin of butylbenzene, organosilicon transparent resin, ADC (allyl diglycol carbonates), PEN (PEN), Resins, epoxy, bulk alicyclic polyene resin or the PC-PMMA blend transparent resin.
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| CN200810084321A CN101538463A (en) | 2008-03-18 | 2008-03-18 | Light-storable self luminous transparent film |
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|---|---|---|---|
| CN200810084321A CN101538463A (en) | 2008-03-18 | 2008-03-18 | Light-storable self luminous transparent film |
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| CN103299868A (en) * | 2012-03-09 | 2013-09-18 | 薛华 | Ecological weeding insect-expelling water-saving disease-resistant functional film |
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| CN103105937A (en) * | 2012-12-07 | 2013-05-15 | 大连奥林匹克电子城利辉通讯器材商行 | Fluorescence polycarbonate keyboard film |
| CN103092356B (en) * | 2012-12-07 | 2016-08-17 | 大连一加致诚科技发展有限公司 | A kind of keyboard film with massage function |
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