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CN101358320A - Steel for controlled rolling and controlled cooling platform and production method thereof - Google Patents

Steel for controlled rolling and controlled cooling platform and production method thereof Download PDF

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Publication number
CN101358320A
CN101358320A CNA2008101195069A CN200810119506A CN101358320A CN 101358320 A CN101358320 A CN 101358320A CN A2008101195069 A CNA2008101195069 A CN A2008101195069A CN 200810119506 A CN200810119506 A CN 200810119506A CN 101358320 A CN101358320 A CN 101358320A
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controlled
percent
steel
temperature
rolling
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CNA2008101195069A
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CN101358320B (en
Inventor
江卫华
沈一平
刘振宇
姜中行
麻庆申
刘学一
吴斌
李战军
何元春
狄国标
杨春卫
沈开照
王国栋
田鹏
石树东
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Shougang Group Co Ltd
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Shougang Corp
Qinhuangdao Shouqin Metal Materials Co Ltd
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Publication of CN101358320B publication Critical patent/CN101358320B/en
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Abstract

The invention relates to steel used for controlled rolling and cooling offshore platform, and a production method thereof. The invention belongs to the technical field of low-alloy high-strength steel. The steel was produced through slab continuous casting and TMCP processes after steel making and refining. The components of the slab are as follows: 0.05 percent to 0.09 percent of C, 1.20 percent to 1.60 percent of Mn, 0.20 percent to 0.50 percent of Si, 0.03 percent to 0.05 percent of Nb, 0.010 percent to 0.020 percent of Ti, 0.03 percent to 0.06 percent of V, equal to or less than 0.005 percent of S, 0.020 percent to 0.040 percent of Als, equal to or less than 0.015 percent of P, and the rest are Fe and impurities. Molten steel which is smelt by the component is cast into the slab which is 220mm to 250mm thick; the ingot is put into a slap heating furnace to be heated and rolled when being discharged. The initial billet temperature for rough rolling is 1060 DEG C to 1160 DEG C, the initial billet temperature for fine rolling is 840 DEG C to 940 DEG C, and the finishing temperature is 780 DEG C to 820 DEG C; the thickness of the rolled steel sheet is 10mm to 60mm. The starting cooling temperature is 760 DEG C to 810 DEG C; the finishing cooling temperature is 550 DEG C to 650 DEG C; the cooling speed is 10 DEG C/s to 17 DEG C/s. The production method has the advantages of simplified procedures and cost saving.

Description

Steel for controlled rolling and controlled cooling platform and production method thereof
Technical field
The invention belongs to the Hi-Stren steel technical field, particularly a kind of steel for controlled rolling and controlled cooling platform and production method thereof are a kind of 40kg, Z35 rank TMCP (controlled rolling adds the process system of controlled chilling) ocean platform steel.
Background technology
Along with rising steadily of international petroleum price, pay close attention to oceanic resources exploitation in countries in the world, oceanology classified as one of 12 new and high technologies of country as Japan and given priority to.In view of current the pressing for of China to the energy strategy deposit, research and development have high strength, the high tenacity ocean platform Plate Steel of independent intellectual property right, for improving China's energy system, suppressing the predation of surrounding countries to China's marine site resource, the stand-alone development oceanic resources guarantee that national energy security is significant.
Ocean platform is the ultra-large type welded steel structure of exploitation oceanic resources, is applied in the severe ocean Working environment such as wave, tide, storm and cold floating ice, supports platform and drilling outfit that gross weight surpasses hundreds of tons.These use characteristic have determined ocean platform must have high strength, high tenacity, anti-lamellar tearing, good performance index such as weldability with Plate Steel, so that guarantee personnel's safety and work, living condition, the work-ing life of improving ocean platform simultaneously better.
Ocean platform uses steel with TMCP and two kinds of explained hereafter of hot rolling+thermal treatment.TMCP explained hereafter ocean platform has characteristics such as simplifying working process, save cost and delivery cycle weak point with steel, the steel plate of TMCP state delivery simultaneously can adapt to large-line energy welding requirements and few preheating or not requirement such as pre-thermo-welding, helps reducing investment outlay, improving operating efficiency in building the ocean platform process, shorten the construction period.Ocean platform is higher to every index requests such as low-temperature flexibility, anti-lamellar tearing performances with steel.The raising ocean platform is important research direction with low-temperature flexibility, the Z of steel to technical indicators such as performance and welding propertys.
Summary of the invention
The object of the present invention is to provide a kind of steel for controlled rolling and controlled cooling platform and production method thereof.Ocean platform with the subject matter that steel and production technology thereof exist is at present: life cycle of the product length, complex process, the production cost height of the delivery of (1) as-normalized condition; (2) the product alloying element content height of controlled rolling and controlled cooling state delivery, the controlled chilling effect afterwards of rolling is brought into play abundant inadequately, and production cost is higher.
For satisfying every performance requriements, adopt the composition design of low-carbon (LC)+Nb, V, Ti combined microalloying, directly utilize TMCP explained hereafter ocean platform steel, reduce cost.Low-carbon (LC) can reduce the carbon equivalent of steel, improves the low-temperature flexibility and the welding property of steel plate; Can alleviate simultaneously the defectives such as center component segregation of continuous casting steel billet, be easy to obtain the continuous casting steel billet of better quality, help guaranteeing the heart portion quality of thicker specification ocean platform with steel plate, reduce the probability that defectives such as " layering ", " different bright band " appear in steel plate tension specimen fracture, improve product percent of pass.Handle by carrying out microalloying, in conjunction with the TMCP Technology, utilize Nb delayed deformation austenite recrystallization refinement steel plate tissue, and the precipitating reinforcing effect that in the cooling control after rolling phase transition process, utilizes V to produce, improve armor plate strength, toughness and plasticity, thereby obtain good comprehensive performances.Nb, V are except playing the effect of refined crystalline strengthening and precipitation strength, still be fixation of C, the strong carbon of N interstitial atom, nitride forming element simultaneously, Ti also can play the effect of fixation of C, N interstitial atom, reduce " Ke Shi air mass ", " Shi Nuoke air mass " generation probability, improve even elimination strain aging phenomenon.TiN can effectively hinder austenite crystal and grow up when heat, can suppress microstructure coarsening in the welding process simultaneously, improves welding property.
Ocean platform of the present invention with steel composition by weight percentage is: C 0.05~0.09%, Mn 1.20~1.60%, Si 0.20~0.50%, Nb 0.03~0.05%, and Ti 0.010~0.020%, and V 0.03~0.06%, S≤0.005%, Als 0.020~0.040%, P≤0.015%, and all the other are Fe and unavoidable impurities.
The chemical ingredients of steel of the present invention also must satisfy:
Nb+V+Ti≤0.12%;
Ceq=C+Mn/6+ (Cr+Mo+V)/5+ (Ni+Cu)/15≤0.40% ("/" expression division arithmetic in the formula).
Steel plate thickness range of the present invention is 10~60mm.
The production method of steel for controlled rolling and controlled cooling platform of the present invention is: blast-melted → molten iron pre-desulfurization → converter smelting → LF+RH refining → sheet billet continuous casting → blank check → slab heating → controlled rolling → controlled chilling.
Steel of the present invention adopts sheet billet continuous casting and TMCP technology to produce; Processing step is:
(1) will smelt good molten steel casting by above chemical composition design and become 220~250mm heavy slab; With pack into bar plate heating stove heating of blank, 1120~1220 ℃ of Heating temperatures, heat-up time 3~5h; Come out of the stove then and be rolled;
(2) the roughing start rolling temperature is controlled at 1060~1160 ℃; Intermediate blank is treated temperature (it is rolling to treat that temperature is meant that slab rough rolling stops behind the certain thickness, and equitemperature drops to the process that certain value carries out finish rolling again) thickness 40~150mm; The finish rolling start rolling temperature is controlled at 840~940 ℃; Finishing temperature is controlled at 780~820 ℃;
(3) begin to cool down temperature and be controlled at 760~810 ℃; Stop cooling temperature and be controlled at 550~650 ℃; Rate of cooling is controlled at 10~17 ℃/s.
The product microtexture of explained hereafter of the present invention is ferrite+perlite, product possesses good comprehensive mechanical properties: yield strength 420~520, tensile strength reaches 545~650MPa, unit elongation reaches 22.0~31.0%,-40 ℃ of summers are more vertical on average more than the 200J, laterally more than the 180J than impact absorbing energy, on average more than 40%, cold-bending property is good to the stretching relative reduction in area for Z.
The invention has the advantages that, simplify working process, save characteristics such as cost, the welding requirements of product adaptation large-line energy and delivery cycle weak point, be applicable to large ocean engineering structure steel such as ocean platform.
Embodiment
Embodiment 1
Steel for controlled rolling and controlled cooling platform design mix by weight percentage is: C 0.085%, Mn1.42%, and Si 0.36%, and Nb 0.034%, Ti 0.012%, and V 0.066%, and S 0.003%, Als 0.030%, and P 0.010%, and all the other are Fe and unavoidable impurities.
TMCP technology comprises heating, roughing, finish rolling, cooling, is specially:
To smelt good molten steel casting by above chemical composition design and become the 250mm heavy slab; With pack into bar plate heating stove heating of blank, 1200 ℃ of Heating temperatures, heat-up time 4h; Come out of the stove then and be rolled.The roughing start rolling temperature is controlled at 1060~1120 ℃; Intermediate blank is treated temperature thickness 90mm; The finish rolling start rolling temperature is controlled at 850~870 ℃; Finishing temperature is controlled at 780~815 ℃.Begin to cool down temperature and be controlled at 770~800 ℃; Stop cooling temperature and be controlled at 580~600 ℃; Rate of cooling is controlled at 12~16 ℃/s.Product thickness is 30mm.
The product yield strength 510MPa that produces, tensile strength 600MPa, unit elongation 25%,-60 ℃ of impact of collision averages are at 225J, and the transverse impact average is at 189J, and-60 ℃ of vertical timeliness are impacted average at 114J, 55.0%, cold-bending property is good to stretching relative reduction in area average for Z.
Embodiment 2
Steel for controlled rolling and controlled cooling platform design mix by weight percentage is: C0.065%, and Mn1.31%, Si 0.39%, and Nb 0.037%, Ti 0.014%, and V 0.05%, and S 0.002%, Als 0.038%, and P 0.008%, and all the other are Fe and unavoidable impurities.
TMCP technology comprises heating, roughing, finish rolling, cooling, is specially:
To smelt good molten steel casting by above chemical composition design and become the 250mm heavy slab; With pack into bar plate heating stove heating of blank, 1180 ℃ of Heating temperatures, heat-up time 4h; Come out of the stove then and be rolled.The roughing start rolling temperature is controlled at 1070~1120 ℃; Intermediate blank is treated temperature thickness 100mm; The finish rolling start rolling temperature is controlled at 845~860 ℃; Finishing temperature is controlled at 780~805 ℃.Begin to cool down temperature and be controlled at 770~795 ℃; Stop cooling temperature and be controlled at 580~595 ℃; Rate of cooling is controlled at 11~15 ℃/s.Product thickness is 40mm.
The product yield strength 485MPa that produces, tensile strength 590MPa, unit elongation 27.5% ,-60 ℃ of impact of collision averages are at 247J, and the transverse impact average is at 184J, and-60 ℃ of vertical timeliness are impacted 187J, and 45.4%, cold-bending property is good to the relative reduction in area average for Z.
Embodiment 3
Steel for controlled rolling and controlled cooling platform design mix by weight percentage is: C0.071%, and Mn1.35%, Si 0.38%, and Nb 0.041%, Ti 0.012%, and V 0.051%, and S 0.002%, Als 0.034%, and P 0.007%, and all the other are Fe and unavoidable impurities.
TMCP technology comprises heating, roughing, finish rolling, cooling, is specially:
To smelt good molten steel casting by above chemical composition design and become the 250mm heavy slab; With pack into bar plate heating stove heating of blank, 1200 ℃ of Heating temperatures, heat-up time 4h; Come out of the stove then and be rolled.The roughing start rolling temperature is controlled at 1080~1120 ℃; Intermediate blank is treated temperature thickness 150mm; The finish rolling start rolling temperature is controlled at 840~855 ℃; Finishing temperature is controlled at 780~800 ℃.Begin to cool down temperature and be controlled at 770~790 ℃; Stop cooling temperature and be controlled at 570~590 ℃; Rate of cooling is controlled at 10~14 ℃/s.Product thickness is 60mm.
The product yield strength 465MPa that produces, tensile strength 575MPa, unit elongation 24.5% ,-40 ℃ of impact of collision averages are at 212J, and the transverse impact average is at 182J, and-40 ℃ of vertical timeliness are impacted 127J, and Z is 46.7% to relative reduction in area, cold-bending property is good.

Claims (4)

1, a kind of steel for controlled rolling and controlled cooling platform, it is characterized in that, chemical ingredients by weight percentage: C 0.05~0.09%, Mn 1.20~1.60%, Si 0.20~0.50%, Nb 0.03~0.05%, and Ti 0.010~0.020%, and V 0.03~0.06%, S≤0.005%, Als 0.020~0.040%, P≤0.015%, and all the other are Fe and unavoidable impurities.
2, according to the described steel for controlled rolling and controlled cooling platform of claim 1, it is characterized in that Ceq=C+Mn/6+ (Cr+Mo+V)/5+ (Ni+Cu)/15≤0.40%; Nb+V+Ti≤0.12%.
3, the method for the described steel for controlled rolling and controlled cooling platform of a kind of production claim 1 is characterized in that, adopts sheet billet continuous casting and TMCP technology to produce; Processing step is:
(1) good molten steel casting becomes 220~250mm heavy slab will according to chemical composition to design smelting; With pack into bar plate heating stove heating of blank, 1120~1220 ℃ of Heating temperatures, heat-up time 3~5h; Come out of the stove then and be rolled;
(2) the roughing start rolling temperature is controlled at 1060~1160 ℃; Intermediate blank is treated temperature thickness 40~150mm; The finish rolling start rolling temperature is controlled at 840~940 ℃; Finishing temperature is controlled at 780~820 ℃;
(3) begin to cool down temperature and be controlled at 760~810 ℃; Stop cooling temperature and be controlled at 550~650 ℃; Rate of cooling is controlled at 10~17 ℃/s.
4, in accordance with the method for claim 3, it is characterized in that described chemical composition design weight percent is: C 0.05~0.09%, Mn 1.20~1.60%, Si 0.20~0.50%, Nb 0.03~0.05%, and Ti 0.010~0.020%, and V 0.03~0.06%, S≤0.005%, Als 0.020~0.040%, P≤0.015%, and all the other are Fe and unavoidable impurities.
CN2008101195069A 2008-09-02 2008-09-02 Steel for controlled rolling and controlled cooling platform and production method thereof Expired - Fee Related CN101358320B (en)

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Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101775559A (en) * 2010-03-17 2010-07-14 北京科技大学 Easily welded high-strength-and-toughness ship plate steel and production process
CN101792888A (en) * 2010-03-17 2010-08-04 首钢总公司 High-strength weathering steel and method for producing same
CN101812636A (en) * 2010-04-28 2010-08-25 南京钢铁股份有限公司 Q390D-Z35 low-alloy high-strength plank with thickness of 75mm and manufacturing method thereof
CN101838770A (en) * 2010-06-13 2010-09-22 攀钢集团钢铁钒钛股份有限公司 High-strength steel for transmission towers and production method thereof
CN101845593A (en) * 2010-05-19 2010-09-29 首钢总公司 Steel for 20 control Cr nuclear power and production method thereof
CN102011050A (en) * 2010-07-15 2011-04-13 秦皇岛首秦金属材料有限公司 Steel for 36kg-grade ocean platform and production method thereof
CN102051525A (en) * 2010-12-07 2011-05-11 秦皇岛首秦金属材料有限公司 Method for producing steel plate used for Q420qE bridge at low cost
CN102337460A (en) * 2011-11-14 2012-02-01 首钢总公司 Ultrahigh-strength structural steel board for ocean engineering and production method thereof
CN102691018A (en) * 2012-06-11 2012-09-26 南京钢铁股份有限公司 Low-compression ratio super-strength steel plate for ocean engineering and manufacturing method thereof
CN102747285A (en) * 2012-07-11 2012-10-24 秦皇岛首秦金属材料有限公司 Ultrathick steel plate for ships and ocean platforms and production method thereof
CN103722023A (en) * 2013-12-26 2014-04-16 秦皇岛首秦金属材料有限公司 Method for controlling plate shape of TMCP (thermal mechanical control processing) high-strength ship plate
CN103938104A (en) * 2014-05-12 2014-07-23 武汉钢铁(集团)公司 Offshore drilling platform steel with fatigue strength of at least 560MPa and production method thereof
CN104561486A (en) * 2015-01-22 2015-04-29 首钢总公司 Thick hot continuous rolling steel strip with excellent ultralow temperature CTOD (China railway high speed) performance and production method thereof
CN104674117A (en) * 2015-03-19 2015-06-03 山东钢铁股份有限公司 420 MPa grade steel plate for ocean engineering, and manufacturing method thereof
CN105256234A (en) * 2015-10-29 2016-01-20 首钢总公司 Low-carbon microalloyed steel, preparing method and application of low-carbon microalloyed steel, ventilator blade and ventilator
CN105779865A (en) * 2016-05-30 2016-07-20 山东钢铁股份有限公司 Thin gauge steel plate used for marine engineering and preparation method thereof
WO2022022066A1 (en) * 2020-08-17 2022-02-03 莱芜钢铁集团银山型钢有限公司 Steel board for polar marine engineering and preparation method therefor
WO2022236961A1 (en) * 2021-05-14 2022-11-17 南京钢铁股份有限公司 Api 2w-50 steel plate for offshore oil platform, and production method therefor

Cited By (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101775559A (en) * 2010-03-17 2010-07-14 北京科技大学 Easily welded high-strength-and-toughness ship plate steel and production process
CN101792888A (en) * 2010-03-17 2010-08-04 首钢总公司 High-strength weathering steel and method for producing same
CN101812636A (en) * 2010-04-28 2010-08-25 南京钢铁股份有限公司 Q390D-Z35 low-alloy high-strength plank with thickness of 75mm and manufacturing method thereof
CN101845593A (en) * 2010-05-19 2010-09-29 首钢总公司 Steel for 20 control Cr nuclear power and production method thereof
CN101838770A (en) * 2010-06-13 2010-09-22 攀钢集团钢铁钒钛股份有限公司 High-strength steel for transmission towers and production method thereof
CN102011050A (en) * 2010-07-15 2011-04-13 秦皇岛首秦金属材料有限公司 Steel for 36kg-grade ocean platform and production method thereof
CN102051525A (en) * 2010-12-07 2011-05-11 秦皇岛首秦金属材料有限公司 Method for producing steel plate used for Q420qE bridge at low cost
CN102337460B (en) * 2011-11-14 2013-01-09 首钢总公司 Ultrahigh-strength structural steel board for ocean engineering and production method thereof
CN102337460A (en) * 2011-11-14 2012-02-01 首钢总公司 Ultrahigh-strength structural steel board for ocean engineering and production method thereof
CN102691018A (en) * 2012-06-11 2012-09-26 南京钢铁股份有限公司 Low-compression ratio super-strength steel plate for ocean engineering and manufacturing method thereof
CN102747285A (en) * 2012-07-11 2012-10-24 秦皇岛首秦金属材料有限公司 Ultrathick steel plate for ships and ocean platforms and production method thereof
CN103722023A (en) * 2013-12-26 2014-04-16 秦皇岛首秦金属材料有限公司 Method for controlling plate shape of TMCP (thermal mechanical control processing) high-strength ship plate
CN103722023B (en) * 2013-12-26 2015-11-25 秦皇岛首秦金属材料有限公司 The method of the high-strength deck of boat Strip Shape Control of a kind of TMCP
CN103938104B (en) * 2014-05-12 2016-08-17 武汉钢铁(集团)公司 The marine drilling platform steel of fatigue strength >=560MPa and production method
CN103938104A (en) * 2014-05-12 2014-07-23 武汉钢铁(集团)公司 Offshore drilling platform steel with fatigue strength of at least 560MPa and production method thereof
CN104561486A (en) * 2015-01-22 2015-04-29 首钢总公司 Thick hot continuous rolling steel strip with excellent ultralow temperature CTOD (China railway high speed) performance and production method thereof
CN104674117A (en) * 2015-03-19 2015-06-03 山东钢铁股份有限公司 420 MPa grade steel plate for ocean engineering, and manufacturing method thereof
CN104674117B (en) * 2015-03-19 2017-05-31 山东钢铁股份有限公司 A kind of 420MPa grades of steel plate for ocean engineering and its manufacture method
CN105256234A (en) * 2015-10-29 2016-01-20 首钢总公司 Low-carbon microalloyed steel, preparing method and application of low-carbon microalloyed steel, ventilator blade and ventilator
CN105779865A (en) * 2016-05-30 2016-07-20 山东钢铁股份有限公司 Thin gauge steel plate used for marine engineering and preparation method thereof
WO2022022066A1 (en) * 2020-08-17 2022-02-03 莱芜钢铁集团银山型钢有限公司 Steel board for polar marine engineering and preparation method therefor
WO2022236961A1 (en) * 2021-05-14 2022-11-17 南京钢铁股份有限公司 Api 2w-50 steel plate for offshore oil platform, and production method therefor

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Address after: 100041 Shijingshan Road, Shijingshan District, Shijingshan District, Beijing

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Granted publication date: 20110713