CN100575501C - 糖类的结晶 - Google Patents
糖类的结晶 Download PDFInfo
- Publication number
- CN100575501C CN100575501C CN03818058A CN03818058A CN100575501C CN 100575501 C CN100575501 C CN 100575501C CN 03818058 A CN03818058 A CN 03818058A CN 03818058 A CN03818058 A CN 03818058A CN 100575501 C CN100575501 C CN 100575501C
- Authority
- CN
- China
- Prior art keywords
- fructose
- wood sugar
- sugar
- nanofiltration
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- 238000010306 acid treatment Methods 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 150000001323 aldoses Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000005349 anion exchange Methods 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 238000002419 base digestion Methods 0.000 description 1
- 102000006995 beta-Glucosidase Human genes 0.000 description 1
- 108010047754 beta-Glucosidase Proteins 0.000 description 1
- XZKRXPZXQLARHH-UHFFFAOYSA-N buta-1,3-dienylbenzene Chemical compound C=CC=CC1=CC=CC=C1 XZKRXPZXQLARHH-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 159000000007 calcium salts Chemical group 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- VDTNNGKXZGSZIP-UHFFFAOYSA-N carbutamide Chemical compound CCCCNC(=O)NS(=O)(=O)C1=CC=C(N)C=C1 VDTNNGKXZGSZIP-UHFFFAOYSA-N 0.000 description 1
- 238000009903 catalytic hydrogenation reaction Methods 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229940112822 chewing gum Drugs 0.000 description 1
- 235000015218 chewing gum Nutrition 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- HEBKCHPVOIAQTA-NGQZWQHPSA-N d-xylitol Chemical compound OC[C@H](O)C(O)[C@H](O)CO HEBKCHPVOIAQTA-NGQZWQHPSA-N 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000000502 dialysis Methods 0.000 description 1
- 230000002478 diastatic effect Effects 0.000 description 1
- 235000005911 diet Nutrition 0.000 description 1
- 230000037213 diet Effects 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 210000000959 ear middle Anatomy 0.000 description 1
- 230000002255 enzymatic effect Effects 0.000 description 1
- 238000006911 enzymatic reaction Methods 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- BJHIKXHVCXFQLS-UYFOZJQFSA-N fructose group Chemical group OCC(=O)[C@@H](O)[C@H](O)[C@H](O)CO BJHIKXHVCXFQLS-UYFOZJQFSA-N 0.000 description 1
- 125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 235000011073 invertase Nutrition 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- 150000008040 ionic compounds Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 125000000468 ketone group Chemical group 0.000 description 1
- 150000002584 ketoses Chemical class 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229940096405 magnesium cation Drugs 0.000 description 1
- 229910001425 magnesium ion Inorganic materials 0.000 description 1
- JESHZQPNPCJVNG-UHFFFAOYSA-L magnesium;sulfite Chemical compound [Mg+2].[O-]S([O-])=O JESHZQPNPCJVNG-UHFFFAOYSA-L 0.000 description 1
- VQHSOMBJVWLPSR-WUJBLJFYSA-N maltitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H]([C@H](O)CO)O[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O VQHSOMBJVWLPSR-WUJBLJFYSA-N 0.000 description 1
- 229940035436 maltitol Drugs 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000005374 membrane filtration Methods 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 238000001471 micro-filtration Methods 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 239000010413 mother solution Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 238000006384 oligomerization reaction Methods 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000011045 prefiltration Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000012488 sample solution Substances 0.000 description 1
- 238000007423 screening assay Methods 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 235000020374 simple syrup Nutrition 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 159000000000 sodium salts Chemical group 0.000 description 1
- 239000011122 softwood Substances 0.000 description 1
- 239000002594 sorbent Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- NIAGBSSWEZDNMT-UHFFFAOYSA-M tetraoxidosulfate(.1-) Chemical compound [O]S([O-])(=O)=O NIAGBSSWEZDNMT-UHFFFAOYSA-M 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000000207 volumetry Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D9/00—Crystallisation
- B01D9/02—Crystallisation from solutions
-
- C—CHEMISTRY; METALLURGY
- C13—SUGAR INDUSTRY
- C13B—PRODUCTION OF SUCROSE; APPARATUS SPECIALLY ADAPTED THEREFOR
- C13B30/00—Crystallisation; Crystallising apparatus; Separating crystals from mother liquors ; Evaporating or boiling sugar juice
- C13B30/02—Crystallisation; Crystallising apparatus
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
- B01D15/08—Selective adsorption, e.g. chromatography
- B01D15/26—Selective adsorption, e.g. chromatography characterised by the separation mechanism
- B01D15/36—Selective adsorption, e.g. chromatography characterised by the separation mechanism involving ionic interaction
- B01D15/361—Ion-exchange
- B01D15/362—Cation-exchange
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
- B01D15/08—Selective adsorption, e.g. chromatography
- B01D15/26—Selective adsorption, e.g. chromatography characterised by the separation mechanism
- B01D15/36—Selective adsorption, e.g. chromatography characterised by the separation mechanism involving ionic interaction
- B01D15/361—Ion-exchange
- B01D15/363—Anion-exchange
-
- C—CHEMISTRY; METALLURGY
- C13—SUGAR INDUSTRY
- C13B—PRODUCTION OF SUCROSE; APPARATUS SPECIALLY ADAPTED THEREFOR
- C13B20/00—Purification of sugar juices
- C13B20/12—Purification of sugar juices using adsorption agents, e.g. active carbon
-
- C—CHEMISTRY; METALLURGY
- C13—SUGAR INDUSTRY
- C13B—PRODUCTION OF SUCROSE; APPARATUS SPECIALLY ADAPTED THEREFOR
- C13B20/00—Purification of sugar juices
- C13B20/16—Purification of sugar juices by physical means, e.g. osmosis or filtration
- C13B20/165—Purification of sugar juices by physical means, e.g. osmosis or filtration using membranes, e.g. osmosis, ultrafiltration
-
- C—CHEMISTRY; METALLURGY
- C13—SUGAR INDUSTRY
- C13K—SACCHARIDES OBTAINED FROM NATURAL SOURCES OR BY HYDROLYSIS OF NATURALLY OCCURRING DISACCHARIDES, OLIGOSACCHARIDES OR POLYSACCHARIDES
- C13K11/00—Fructose
-
- C—CHEMISTRY; METALLURGY
- C13—SUGAR INDUSTRY
- C13K—SACCHARIDES OBTAINED FROM NATURAL SOURCES OR BY HYDROLYSIS OF NATURALLY OCCURRING DISACCHARIDES, OLIGOSACCHARIDES OR POLYSACCHARIDES
- C13K13/00—Sugars not otherwise provided for in this class
- C13K13/002—Xylose
-
- C—CHEMISTRY; METALLURGY
- C13—SUGAR INDUSTRY
- C13K—SACCHARIDES OBTAINED FROM NATURAL SOURCES OR BY HYDROLYSIS OF NATURALLY OCCURRING DISACCHARIDES, OLIGOSACCHARIDES OR POLYSACCHARIDES
- C13K7/00—Maltose
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Water Supply & Treatment (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Saccharide Compounds (AREA)
Abstract
Description
进料 | 渗透物 | |
PH | 5.0 | 5.2 |
DS,g/100g | 17.3 | 64.5 |
低聚糖,以DS计的% | 0.6 | 0.02 |
木糖 | 12.5 | 64.8 |
葡萄糖 | 1.9 | 3.2 |
半乳糖+鼠李糖 | 1.2 | 2.3 |
阿拉伯糖+甘露糖 | 1.3 | 3.0 |
木质酸 | 3.7 | 3.2 |
木二糖 | 0.1 | 0.0 |
乙酸 | 1.4 | 3.7 |
Na<sup>+</sup> | 0.0 | 0.1 |
K<sup>+</sup> | 0.2 | 3.1 |
Ca<sup>2+</sup> | 0.1 | 0.0 |
Mg<sup>2+</sup> | 2.7 | 0.5 |
SO<sub>3</sub><sup>-</sup> | <0.5 | 0.5 |
SO<sub>4</sub><sup>2-</sup> | 2.1 | 0.6 |
进入离心机的物料(克) | 929 |
洗涤(毫升) | 80 |
洗涤(%,以滤饼的DS计) | 28 |
滤饼(克) | 288 |
滤饼厚度(厘米) | 0.8 |
物料DS(重量%) | 85.1 |
物料纯度(%,按DS计) | 63.3 |
滤饼DS(重量%) | 98.7 |
滤饼纯度(%,按DS计) | 97.6 |
流出物纯度(%,按DS计) | 43.1 |
产率DS/DS(%) | 36 |
产率 木糖/木糖(%) | 55 |
最终结晶用物料 | 滤饼,90毫升洗涤 | 流出物,80毫升洗涤 | |
DS(重量%) | 85.1 | 98.7 | 72.8 |
DS为40-50%时的pH | 6.6 | 5.7 | 6.6 |
pH为5时的颜色 | 48400 | 310 | 74300 |
DS为10%时的导电率(mS/cm) | 6.44 | 0.05 | 9.29 |
葡萄糖(%,按DS计) | 3.9 | 0.5 | 5.8 |
木糖(%,按DS计) | 63.3 | 97.6 | 43.1 |
半乳糖+鼠李糖(%,按DS计) | 3.3 | 0.0 | 4.6 |
阿拉伯糖+甘露糖(%,按DS计) | 4.2 | 0.0 | 7.0 |
低聚糖(%,按DS计) | 0.1 | 0.0 | 0.1 |
进料的组成 | 以DS计的% |
木糖 | 13.9 |
葡萄糖 | 1.9 |
半乳糖+鼠李糖 | 1.4 |
阿拉伯糖+甘露糖 | 1.9 |
木质酸 | 4.5 |
其它 | 76.4 |
级分 | 木糖 | 尾级分 | 循环 |
体积,升 | 17 | 96 | 9.5 |
DS,克/100毫升 | 23.8 | 16.4 | 21.7 |
木糖 | 50.4 | 1.2 | 45.7 |
葡萄糖 | 4.8 | 0.9 | 4.2 |
葡萄糖+鼠李糖 | 4.7 | 0.2 | 4.4 |
阿拉伯糖+甘露糖 | 5.9 | 0.4 | 5.8 |
木质酸 | 6.9 | 3.5 | 7.8 |
其它 | 27.3 | 93.8 | 32.1 |
PH | 3.7 | 3.6 | 3.9 |
进料 | 渗透物 | |
PH | 4.9 | 4.6 |
DS,克/100克 | 13.5 | 67.7 |
低聚糖,%(按DS计) | 0.5 | 0.0 |
木糖 | 50.4 | 76.0 |
葡萄糖 | 4.1 | 2.0 |
半乳糖+鼠李糖 | 4.7 | 2.5 |
阿拉伯糖+甘露糖 | 5.9 | 3.9 |
木二糖 | 0.04 | 0.02 |
木质酸 | 6.9 | 3.6 |
乙酸 | 1.6 | 0.6 |
Na<sup>+</sup> | 0.0 | 0.0 |
K<sup>+</sup> | 0.1 | 0.6 |
Ca<sup>2+</sup> | 0.1 | 0.0 |
Mg<sup>2+</sup> | 2.0 | 0.2 |
SO<sub>4</sub><sup>2-</sup> | 2.3 | 0.1 |
进料 | 渗透物 | |
PH | 4.2 | 3.5 |
DS,克/100克 | 16.3 | 63.4 |
低聚糖,%,以DS计 | 2.9 | 0.9 |
木糖 | 20.5 | 48.3 |
葡萄糖 | 5.8 | 3.8 |
半乳糖+鼠李糖 | 5.0 | 3.8 |
阿拉伯糖+甘露糖 | 6.8 | 6.1 |
木质酸 | 13.6 | 14.0 |
Na<sup>+</sup> | 0.0 | 0.0 |
K<sup>+</sup> | 0.2 | 1.3 |
Ca<sup>2+</sup> | 0.1 | 0.0 |
Mg<sup>2+</sup> | 3.0 | 0.2 |
SO<sub>3</sub><sup>-</sup> | <0.1 | 0.3 |
SO<sub>4</sub><sup>2+</sup> | 3.6 | 0.3 |
冷却结束时的物料 | 用于过滤的物料 | Larox滤饼 | Larox母液 | |
DS(重量%) | 92.8 | 89.8 | 95.9 | 81.6 |
DS为39-49%时的pH | 3.6 | 3.5 | 3.5 | 3.5 |
DS为10%时的电导率(mS/cm) | 3.32 | 3.23 | 1.58 | 4.49 |
pH为5时的颜色 | 22600 | 22300 | 9440 | 31800 |
葡萄糖(%,按DS计) | 3.7 | 3.7 | 2.1 | 5.0 |
木糖(%,按DS计) | 47.3 | 46.4 | 76.0 | 24.6 |
半乳糖+鼠李糖(%,按DS计) | 4.1 | 4.2 | 1.5 | 6.0 |
阿拉伯糖+甘露糖(%,按DS计) | 6.1 | 6.6 | 2.7 | 8.9 |
低聚糖(%,按DS计) | 0.8 | 0.6 | 0.3 | 1.5 |
进料 | 渗透物 | |
PH | 4.6 | 4.4 |
DS,%(克/100克) | 50.2 | 62.6 |
颜色,ICUMSA | 1145 | 220 |
葡萄糖,%,按DS计 | 3.5 | 3.7 |
果糖,%,按DS计 | 87.8 | 92.8 |
低聚糖,%,按DS计 | 3.0 | 0.8 |
DS | ||
Na,毫克/千克DS | 239 | 228 |
K,毫克/千克DS | 22 | 20 |
Ca,毫克/千克DS | 76 | 6.9 |
Mg,毫克/千克DS | 4.6 | <2 |
SO<sub>4</sub> | 71 | 14 |
加入离心机的物料(克) | 901 |
洗涤(毫升) | 20 |
洗涤(%,按滤饼DS计) | 5 |
滤饼(克) | 442 |
滤饼厚度(厘米) | 0.7 |
物料RDS(重量%) | 92.5 |
物料纯度(%,按RDS计) | 92.3 |
滤饼DS(重量%) | 95.4 |
滤饼纯度(%,按RDS计) | 100.0 |
流出物纯度(%,按RDS计) | 87.8 |
产率DS/DS(%) | 51 |
产率果糖/果糖(%) | 56 |
蒸发后的物料 | 滤饼,20毫升洗涤 | 流出物,20毫升洗涤 | |
RDS(重量%) | 92.4 | 95.4 | 85.0 |
RDS为44-58%时的pH | 4.5 | 4.6 | 4.5 |
颜色 | 130 | 49 | 500 |
RDS为10%时的电导率(μS/cm) | 190 | 40 | 334 |
葡萄糖(%,按RDS计) | 3.6 | 0.6 | 6.8 |
果糖(%,按RDS计) | 93.3 | 100.0 | 87.8 |
阿洛酮糖(%,按RDS计) | 0.5 | 0.0 | 1.4 |
低聚糖(%,按RDS计) | 0.2 | 0.0 | 0.4 |
化合物 | 进料,以DS计的% | 渗透物,以DS计的% |
麦芽三糖 | 13.0 | 0.6 |
麦芽糖 | 72.0 | 95.5 |
葡萄糖 | 0.5 | 2.4 |
>DP3 | 14.5 | 1.5 |
Claims (24)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FI20021262A FI115919B (fi) | 2002-06-27 | 2002-06-27 | Menetelmä kiteytysinhibiittoreiden poistamiseksi monosakkaridisokeriliuoksista |
FI20021262 | 2002-06-27 |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN200910209376A Division CN101724718A (zh) | 2002-06-27 | 2003-06-26 | 糖类的结晶 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1671867A CN1671867A (zh) | 2005-09-21 |
CN100575501C true CN100575501C (zh) | 2009-12-30 |
Family
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Application Number | Title | Priority Date | Filing Date |
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CN03818058A Expired - Lifetime CN100575501C (zh) | 2002-06-27 | 2003-06-26 | 糖类的结晶 |
CN200910209376A Pending CN101724718A (zh) | 2002-06-27 | 2003-06-26 | 糖类的结晶 |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
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CN200910209376A Pending CN101724718A (zh) | 2002-06-27 | 2003-06-26 | 糖类的结晶 |
Country Status (9)
Country | Link |
---|---|
US (3) | US20050211239A1 (zh) |
EP (1) | EP1552026A1 (zh) |
JP (1) | JP2005533494A (zh) |
KR (1) | KR20050026418A (zh) |
CN (2) | CN100575501C (zh) |
AU (1) | AU2003239644A1 (zh) |
FI (1) | FI115919B (zh) |
WO (1) | WO2004003236A1 (zh) |
ZA (1) | ZA200410320B (zh) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106163299A (zh) * | 2014-01-17 | 2016-11-23 | 赛罗尔比利时公司 | 用于制备高纯度的富含山梨糖醇的糖浆的方法 |
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EP1596955A1 (en) * | 2003-02-25 | 2005-11-23 | Finnfeeds Finland OY | A simulated moving bed system and process |
FI120590B (fi) * | 2005-10-28 | 2009-12-15 | Danisco Sweeteners Oy | Erotusmenetelmä |
US9101160B2 (en) | 2005-11-23 | 2015-08-11 | The Coca-Cola Company | Condiments with high-potency sweetener |
FI20065363A0 (fi) * | 2006-05-30 | 2006-05-30 | Danisco Sweeteners Oy | Erotusmenetelmä |
FR2905705B1 (fr) * | 2006-09-08 | 2011-11-04 | Syral | Procede d'obtention d'un sirop a haute teneur en maltitol et sirop ainsi obtenu |
US8017168B2 (en) | 2006-11-02 | 2011-09-13 | The Coca-Cola Company | High-potency sweetener composition with rubisco protein, rubiscolin, rubiscolin derivatives, ace inhibitory peptides, and combinations thereof, and compositions sweetened therewith |
WO2010002712A2 (en) * | 2008-06-30 | 2010-01-07 | 3M Innovative Properties Company | Method of crystallization |
EP2292803B1 (en) | 2009-07-07 | 2013-02-13 | DuPont Nutrition Biosciences ApS | Separation process |
JP2011062196A (ja) * | 2009-08-21 | 2011-03-31 | Kao Corp | 単糖類、二糖類、及び/又はオリゴ糖の製造方法 |
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MY186792A (en) | 2016-02-04 | 2021-08-20 | Ind Tech Res Inst | Method for separating hydrolysis product of biomass |
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- 2003-06-26 WO PCT/FI2003/000521 patent/WO2004003236A1/en active Application Filing
- 2003-06-26 EP EP03732618A patent/EP1552026A1/en not_active Withdrawn
- 2003-06-26 JP JP2004516823A patent/JP2005533494A/ja active Pending
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- 2003-06-26 CN CN200910209376A patent/CN101724718A/zh active Pending
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Publication number | Publication date |
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WO2004003236A1 (en) | 2004-01-08 |
KR20050026418A (ko) | 2005-03-15 |
FI20021262A0 (fi) | 2002-06-27 |
FI20021262A (fi) | 2003-12-28 |
US20070113840A1 (en) | 2007-05-24 |
US7314528B2 (en) | 2008-01-01 |
EP1552026A1 (en) | 2005-07-13 |
CN101724718A (zh) | 2010-06-09 |
US20080060638A1 (en) | 2008-03-13 |
JP2005533494A (ja) | 2005-11-10 |
US20050211239A1 (en) | 2005-09-29 |
FI115919B (fi) | 2005-08-15 |
CN1671867A (zh) | 2005-09-21 |
AU2003239644A1 (en) | 2004-01-19 |
ZA200410320B (en) | 2005-08-31 |
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