CN100443450C - High-energy coal mine permitted powder emulsified explosive and preparation method thereof - Google Patents
High-energy coal mine permitted powder emulsified explosive and preparation method thereof Download PDFInfo
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- CN100443450C CN100443450C CNB2006100392357A CN200610039235A CN100443450C CN 100443450 C CN100443450 C CN 100443450C CN B2006100392357 A CNB2006100392357 A CN B2006100392357A CN 200610039235 A CN200610039235 A CN 200610039235A CN 100443450 C CN100443450 C CN 100443450C
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Abstract
A high-energy powdered emulsified explosive with high exploding power and low cost for coal mine is proportionally prepared from ammonium nitrate, anti-caking agent, oil-phase material, combustible solid material, emulsifier, water and flame inhibitor through preparing oxidant solution, preparing combustible material solution, mixing, and cooling.
Description
One, technical field
The present invention relates to a kind of explosive and preparation method thereof, particularly a kind of high-energy coal mine permitted powder emulsified explosive and preparation method thereof.
Two, background technology
Common powdery allowed for use in coal mines industrial explosive is a solid mixt, such explosive formulation complexity, contain poisonous composition, oxygenant and combustible agent mix inhomogeneous, blast performance is low, production capacity is little, water resisting property is poor, high temperature, high humidity are produced difficulty season, production technique falls behind.Existing emulsion explosive is to be disperse phase mutually with oxygenant, and organic-fuel is the water-in-oil-type emulsoid of external phase.Such explosive oxidizer contains the water of (8～15) % in mutually, so capacity for work is less.And emulsion explosive is generally colloidal state, is not easy to storage and use.Chinese patent ZL00112441.2 has proposed a kind of coal mine allowable powdered emulsified explosive and manufacture method thereof, this method at first adopts emulsifying manner that oxygenant water and combustible agent compound wax are made latex, adopts the method for spray pulverization that latex is made coal mine allowable powdered emulsified explosive then.This explosive has blast performance preferably, but recipe ratio is higher; , energy consumption is big, product density is little.
Three, summary of the invention
The object of the present invention is to provide that a kind of prescription is simple, blast performance is good, bulk strength is big, the product shelf-stable, water repelling property is good, do not contain poisonous composition, human body and environment there is not harm, production technique advanced person, production capacity is big, energy consumption is little and with low cost high-energy coal mine permitted powder emulsified explosive and preparation method thereof.
The technical solution that realizes the object of the invention is: a kind of high-energy coal mine permitted powder emulsified explosive is made of the following component of representing with mass percent: ammonium nitrate 81～88, octadecane amine 0.01～0.8, flame-cooling agent 4～10, compound wax 2～5, solid-state combustiblematerials 0.1～4, emulsifying agent 0.5～1.5, water 0.1～1 are formed; Wherein ammonium nitrate, octadecane amine, flame-cooling agent water have been formed this explosive oxidizer solution, compound wax and emulsifying agent have been formed the combustiblematerials solution of emulsion explosive, two kinds of solution form uniform water-in-oil-type mixture after mixing, the spray-dried high-energy coal mine permitted powder emulsified explosive of making.
A kind of preparation method of high-energy coal mine permitted powder emulsified explosive is characterized in that its preparation method is: the first step, and the mixture heating up dissolving that ammonium nitrate, octadecane amine, flame-cooling agent and water are formed also is warming up to 100～135 ℃, forms oxidizing agent solution; In second step, with the fusing of the mixture heating up of compound wax and emulsifying agent and be warming up to 100～125 ℃, form the combustiblematerials solution of this explosive; In the 3rd step, the oxidizing agent solution that the first step is obtained joins in the combustiblematerials solution that is stirring that second step obtained and mixes; The 4th step, the 3rd mixture spraying drying that make of step is made high-energy coal mine permitted powder emulsified explosive, the temperature of dry wind is 70～120 ℃, or sneaks into solid-state combustiblematerials simultaneously spray-dired.The 5th step made high-energy coal mine permitted powder emulsified explosive cooling back powder charge with the 4th step, and the temperature of cold wind is 10～30 ℃.
High-energy coal mine permitted powder emulsified explosive oxygenant of the present invention is a single-oxidizer ammonium nitrate.
The octadecane amine of high-energy coal mine permitted powder emulsified explosive of the present invention is crystalline form properties-correcting agent.
The flame-cooling agent of high-energy coal mine permitted powder emulsified explosive of the present invention is a Repone K.
Can add solid-state combustiblematerials in the high-energy coal mine permitted powder emulsified explosive prescription of the present invention.
The emulsifying agent of high-energy coal mine permitted powder emulsified explosive of the present invention is water-in-oil-type ester class and amides emulsifying agent.
High-energy coal mine permitted powder emulsified explosive of the present invention adopts liquid-phase mixing-spray-dired production technique.Adopt liquid-phase mixing technology to make oxygenant and the highly homogeneous mixture of combustiblematerials, adopt drying process with atomizing that mixture is made solid-state high-energy coal mine permitted powder emulsified explosive then.
The liquid-phase mixing technology that high-energy coal mine permitted powder emulsified explosive of the present invention adopts can adopt discontinuous, semi continuous and continuous process.
The spraying gun of high-energy coal mine permitted powder emulsified explosive of the present invention adopts air flow type jet nozzle or pressure nozzle.
The equipment that the pulverized coal preparation system of high-energy coal mine permitted powder emulsified explosive of the present invention adopts is two wind systems of warm air drying and cold wind refrigerated separation.
The present invention compared with prior art, its distinguishing feature is: 1. high-energy coal mine permitted powder emulsified explosive particle of the present invention has the microtexture of milk sap, each solid granulates in the explosive has kept oxygenant, flame-cooling agent and the mixed uniformly microtexture of combustiblematerials height, therefore high-energy coal mine permitted powder emulsified explosive has good blast performance and flame arrest performance, has improved the security that use the down-hole; 2. the oxygenant surface in the explosive is fully coated by compound wax, has good water resisting property, moistureproofness and anti-caking effect; 3. significantly reduce the mixing stirring velocity, improved the technology intrinsic safety; 4. prescription is simple; 5. two wind system advanced technology, production capacity is big, energy consumption is little, can carry out large-scale production under any envrionment conditions; 6, material cost is low, and is suitable with ammonium nitrate-fuel oil mixture; 7, do not contain toxic substances such as TNT in the explosive, thoroughly eliminated the harm of TNT human body and environment.
Four, description of drawings
Accompanying drawing is a high-energy coal mine permitted powder emulsified explosive process flow diagram of the present invention.
Five, embodiment
Below in conjunction with accompanying drawing the present invention is done and to describe in further detail.
The various starting material that high-energy coal mine permitted powder emulsified explosive adopted that the present invention proposes all meet the Ministry of Chemical Industry's ministerial standard or company standard.
Embodiment 1 is an example to produce 500 kilograms of high-energy coal mine permitted powder emulsified explosives, selects the mass percent of each component of high-energy coal mine permitted powder emulsified explosive to be: ammonium nitrate 84, Repone K 6, sodium laurylsulfonate 0.1, water 5, compound wax 4, polyisobutene succinimide 0.9.According to 420 kilograms in the accurate weighing ammonium nitrate of said ratio, 30 kilograms in Repone K, 0.5 kilogram of octadecane amine, 25 kilograms in water, 20 kilograms of compound wax, 4.5 kilograms of polyisobutene succinimides.Octadecane amine can change the crystal phase transition temperature of ammonium nitrate.
Operation steps: the first step is with ammonium nitrate, sodium laurylsulfonate, flame-cooling agent and water heating for dissolving and be warming up to 125 ℃; Second step is with compound wax and polyisobutene succinimide heat fused and be warming up to 125 ℃; The 3rd step was mixed into uniform mixture with oxidizing agent solution and combustiblematerials solution; The mixture that the 4th step made for the 3rd step atomizes through three fluid tips, adopts 80 ℃ warm air drying to form high-energy coal mine permitted powder emulsified explosive.The 5th step made high-energy coal mine permitted powder emulsified explosive powder charge after the air-flow cooling with the 4th step, and the temperature of cold wind is 20 ℃.Can adopt two wind systems to replace single wind system on the drying plant, improve the controllability of technology and the controllability of system greatly.Recording blast performance is: explosion velocity 3900m/s, brisance 15mm, capacity for work 332ml, gap distance 10cm.
Embodiment 2 is an example to produce 500 kilograms of high-energy coal mine permitted powder emulsified explosives, selects the mass percent of each component of high-energy coal mine permitted powder emulsified explosive to be: ammonium nitrate 81, Repone K 9, water 5, compound wax 4.8, SP-801.2.According to 405 kilograms in the accurate weighing ammonium nitrate of said ratio, Repone K 45,25 kilograms in water, 24 kilograms of compound wax, 6 kilograms of SP-80.Operation steps and test conditions are with embodiment 1.Recording blast performance is: explosion velocity 3800m/s, brisance 15mm, capacity for work 320ml, gap distance 16cm.
Embodiment 3 is an example to produce 500 kilograms of high-energy coal mine permitted powder emulsified explosives, and the mass percent of each component of high-energy coal mine permitted powder emulsified explosive is: ammonium nitrate 85, Repone K 4, octadecane amine 0.1, water 4, compound wax 4, polyisobutene succinimide 1.2, wood powder 2.7.According to 425 kilograms in the accurate weighing ammonium nitrate of said ratio, 20 kilograms in Repone K, 0.5 kilogram of octadecane amine, 20 kilograms in water, 20 kilograms of compound wax, 6 kilograms of polyisobutene succinimides, 13.5 kilograms of wood powders.
The production technique operation steps: the first step is with ammonium nitrate, octadecane amine and water heating for dissolving and be warming up to 130 ℃; Second step is with compound wax and polyisobutene succinimide heat fused and be warming up to 125 ℃; The 3rd step was mixed into uniform mixture with water and compound wax; The mixture that the 4th step made for the 3rd step atomizes through pressure nozzle, adopts 100 ℃ warm air drying to add wood powder formation high-energy coal mine permitted powder emulsified explosive simultaneously; High-energy coal mine permitted powder emulsified explosive powder charge after the air-flow cooling that the 5th step made for the 4th step, the cold wind temperature is 10 ℃.Recording blast performance is: explosion velocity 3800m/s, brisance 16mm, capacity for work 345ml, gap distance 8cm.
Claims (8)
1, a kind of high-energy coal mine permitted powder emulsified explosive, it is characterized in that: it contains the following component of representing with mass percent: ammonium nitrate 81～88, octadecane amine 0.01～0.8, compound wax 2～5, solid-state combustiblematerials 0.1～4, emulsifying agent 0.5～1.5, water 0.1～1, and flame-cooling agent 4～10 is formed; Wherein ammonium nitrate, water, flame-cooling agent and octadecane amine have been formed oxidizing agent solution, and compound wax and emulsifying agent have been formed combustiblematerials solution.
2, high-energy coal mine permitted powder emulsified explosive according to claim 1 is characterized in that emulsifying agent is ester class and amides emulsifying agent.
3, high-energy coal mine permitted powder emulsified explosive according to claim 2 is characterized in that emulsifying agent is a water-in-oil type emulsifier.
4, high-energy coal mine permitted powder emulsified explosive according to claim 1 is characterized in that flame-cooling agent is a Repone K.
5, the preparation method of the described high-energy coal mine permitted powder emulsified explosive of a kind of claim 1 is characterized in that comprising the steps:
The first step, the mixture heating up dissolving that ammonium nitrate, octadecane amine, flame-cooling agent and water are formed also is warming up to 100～135 ℃, forms oxidizing agent solution;
In second step, the mixture heating up fusing intensification with compound wax and emulsifying agent composition forms combustiblematerials solution;
The 3rd step joined oxidizing agent solution in the combustiblematerials solution that is stirring, and formed the water-in-oil-type mixture;
In the 4th step, the 3rd mixture that make of step through the atomizer spray drying, or is sneaked into solid-state combustiblematerials simultaneously and made high-energy coal mine permitted powder emulsified explosive;
In the 5th step, the 4th step was made high-energy coal mine permitted powder emulsified explosive cooling back powder charge.
6, the preparation method of high-energy coal mine permitted powder emulsified explosive according to claim 5 is characterized in that the mixture heating up fusing of compound wax and emulsifying agent composition is warming up to 100～125 ℃, forms combustiblematerials solution.
7, the preparation method of high-energy coal mine permitted powder emulsified explosive according to claim 5 is characterized in that spraying gun is air-flowing type or pressure type.
8, the manufacture method of high-energy coal mine permitted powder emulsified explosive according to claim 5 is characterized in that: at first with hot blast the particle that atomizes is carried out drying, use the particle of cold wind cooling drying then.
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| CNB2006100392357A CN100443450C (en) | 2006-03-31 | 2006-03-31 | High-energy coal mine permitted powder emulsified explosive and preparation method thereof |
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| CNB2006100392357A CN100443450C (en) | 2006-03-31 | 2006-03-31 | High-energy coal mine permitted powder emulsified explosive and preparation method thereof |
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| CN100443450C true CN100443450C (en) | 2008-12-17 |
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| CN103130591B (en) * | 2013-03-07 | 2014-01-22 | 煤炭科学研究总院爆破技术研究所 | High-energy type coal mine emulsion explosive |
| CN105481619B (en) * | 2014-09-15 | 2017-12-29 | 长沙银芒化工科技有限公司 | Combined films coat ANFO explosives prill and its manufacture method |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1027637C (en) * | 1991-06-14 | 1995-02-15 | 华东工学院 | Emulsified powdered ammonium nitrate explosive and its preparing process |
| CN1190090A (en) * | 1996-12-24 | 1998-08-12 | 冶金工业部长沙矿冶研究院 | Powdered nitramon without bulking agent and its preparing process |
| CN1121999C (en) * | 2000-07-05 | 2003-09-24 | 东南大学 | Powder emulsified explosive for coal mine and productive method thereof |
| CN1140438C (en) * | 2002-06-05 | 2004-03-03 | 西安建筑科技大学 | Technology for making buffer with straw or stalk as main raw material |
-
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- 2006-03-31 CN CNB2006100392357A patent/CN100443450C/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1027637C (en) * | 1991-06-14 | 1995-02-15 | 华东工学院 | Emulsified powdered ammonium nitrate explosive and its preparing process |
| CN1190090A (en) * | 1996-12-24 | 1998-08-12 | 冶金工业部长沙矿冶研究院 | Powdered nitramon without bulking agent and its preparing process |
| CN1121999C (en) * | 2000-07-05 | 2003-09-24 | 东南大学 | Powder emulsified explosive for coal mine and productive method thereof |
| CN1140438C (en) * | 2002-06-05 | 2004-03-03 | 西安建筑科技大学 | Technology for making buffer with straw or stalk as main raw material |
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Owner name: INNER MONGOLIA OTOG SHENG AN 929 CHEMICAL CO., LTD Free format text: FORMER OWNER: NANJIANG UNIV. OF SCIENCE + ENGINEERING Effective date: 20110926 |
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Effective date of registration: 20110926 Address after: 016064 Inner Mongolia city Etuokeqi Ordos Qipanjing town Patentee after: Inner Mongolia Etuokeqi Sheng 929 chemical limited liability company Address before: 210094 Xiaolingwei, Jiangsu, No. 200, Patentee before: Nanjing University of Science and Technology |
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Owner name: INNER MONGOLIA OTOG BANNER SHENG AN JIU ERJIU CHEM Free format text: FORMER NAME: INNER MONGOLIA OTOG BANNER SHENG AN 929 CHEMICAL CO., LTD. |
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Address after: 016064 Inner Mongolia city Etuokeqi Ordos Qipanjing town Patentee after: Inner Mongolia Etuoke County Sheng'an No.929 Chemical Co., Ltd. Address before: 016064 Inner Mongolia city Etuokeqi Ordos Qipanjing town Patentee before: Inner Mongolia Etuokeqi Sheng 929 chemical limited liability company |