CN100408772C - Inorganic noncombustible plank and its application - Google Patents
Inorganic noncombustible plank and its application Download PDFInfo
- Publication number
- CN100408772C CN100408772C CNB031159443A CN03115944A CN100408772C CN 100408772 C CN100408772 C CN 100408772C CN B031159443 A CNB031159443 A CN B031159443A CN 03115944 A CN03115944 A CN 03115944A CN 100408772 C CN100408772 C CN 100408772C
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- China
- Prior art keywords
- parts
- inorganic non
- water
- sulfate
- plate
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/30—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing magnesium cements or similar cements
- C04B28/32—Magnesium oxychloride cements, e.g. Sorel cement
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/28—Fire resistance, i.e. materials resistant to accidental fires or high temperatures
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Building Environments (AREA)
Abstract
The present invention relates to an inorganic noncombustible plate and an application thereof. The inorganic noncombustible plate is characterized in that the inorganic noncombustible plate is composed of 80 to 130 parts of light calcined magnesium oxide powder (the MgO content is more than or equal to 85%.), 30 to 60 parts of halogen sheets (the MgCl2 content is more than or equal to 46%.), 40 to 70 parts of water, 5 to 40 parts of pulverized fuel ashes, 10 to 30 parts of wood dust, 0 to 25 parts of expanded perlite (the grain diameter is from 1 to 5mm.), 0.1 to 5 parts of composite water-resistant additives, two layers of fiberglass grid cloth (50 to 200 g/m2 of medium alkali glass) and two layers of non-woven cloth (16 to 20 g/m2 of polypropylene fiber), wherein the composite water resistant additive is formed by compounding phosphate with sulfate, and the compounding ratio of the phosphate to the sulfate is 1: 9 to 9: 1; the pulverized coal ashes are used as addition agents. The prepared inorganic noncombustible plate has the advantages of light weight, high strength, heat insulation, fire retardation, sound insulation, no poison, no harm and mechanical processing, and can be widely used for partition walls, suspended ceiling plates, roof plates in dwelling houses which are changed into slopes from planes and steel structure fireproof plates.
Description
Technical field
The present invention relates to a kind of inorganic non-combustible plate and application thereof, belong to the magnesium gelatinous material field.
Background technology
Magnesia oxychloride cement have that sclerosis is fast, hardness is high, fireproof performance good and with advantages such as the mixed performance of many sound and thermal insulating materials is good, yet its solubility in water has but limited range of application widely.From the knowledge that accumulated as can be known, under the normal temperature the main aquation after the magnesia oxychloride cement sclerosis to produce crystalline substance be 5Mg (OH)
2MgCl
28H
2O (being called for short 5 phases) and 3Mg (OH)
2MgCl
28H
2O (being called for short 3 phases).Studies show that 5 is that magnesia oxychloride cement is solidified and produces the phase that intensity plays main contribution mutually, 5 phase crystal habits are mainly needle-like, long column shape, and intersect each other and connect to net structure.5 meet is converted into 3 phases, so should manage at MgO-MgCl yet under certain condition,
2-H
2In the O system, strict control proportioning suppresses 5 conversions of 3 phases in opposite directions as far as possible.
Based on above understanding, the patent of invention that has provides a kind of waterproof magnesia cement (CN1225344A); What have provides a kind of aerated light wall panel material, unit weight≤0.5g/cm
3(CN1263065A).More be the report of inorganic fire plate, reported a kind of inorganic fire plate as Shanghai sea-freight group, it is to be matrix with the inorganic material, adds different additives after, the employing special process is made, Main Ingredients and Appearance is MgO, MgCl
2And inorganic reinforcing fiber (sea-freight science and technology 1995 (8) 9.8-9); And for example " composite fireproof Baoli polywood laminate " (building materials newly draw skill 1995 (4) 17-19) of Shandong Building Material College's Materials Science and Engineering system development is by inorganic coagulation material, glass fiber, increases compound making such as steel, Admixture, and it is to be main cementitious material with the water chestnut hardship; Waterproof, the PLASTIC LAMINATED of the development of US 5767178 report U.S. pyrotite companies are made up of cellulosic material, magnesia oxychloride cement or magnesium oxysulfide concrete etc. for another example, can make floor, wallboard and other sheet material.
In sum, refractory slab of reporting in the prior art of being introduced or PLASTIC LAMINATED all are to contain fiber, it or be glass fiber or for inorganic reinforcing fiber or cellulosic material, though because the adding of fiber improves the intensity of fire-proof board, fire resistance greatly, its cost improves and complex manufacturing technology.And still do not have up to now and see that the report of making adulterant with flyash is arranged.
Summary of the invention
Widely-used fiber improves its intensity and anti-flammability in the prior art in order to overcome; the object of the present invention is to provide a kind of high performance inorganic non-combustible plate; but it not only has lightweight, heat insulation, sound insulation, nontoxic but also fire prevention machining; not only can be used as wall panel, ceiling board, sound barrier, and can be used for the roof panel in " flat-changed-into-sloping " project and the flameproof protection of steel work.
The objective of the invention is to implement by the following technical programs:
Specifically the consisting of of the inorganic non-combustible plate that provides (weight):
80～130 parts of light-magnesite powder (MgO content 〉=85%)
Halogen sheet (MgCl
2〉=46%) 30～60 part
40～70 parts in water
5～40 parts in flyash
10～30 parts of wood chips
Expanded perlite (1～5mm) 0～25 part of particle diameter
0.1～5 part of compound anti-water additive
Glass fiber reticular cloth (middle alkali glass, 50～200g/m
2) 2 layers
Nonwoven (polypropylene fibre, 16～20g/m
2) 2 layers
The present invention uses flyash as adulterant: and react with base material, form water-fast compound 5 around mutually, thereby make 5 to be difficult for being converted into 3 phases mutually.With wood chip and expanded perlite as inserts; Compound anti-water additive is the compound sulfate of phosphate, and compound ratio 1: 9～9: 1, described phosphate are a kind of in calcium dihydrogen phosphate, magnesium dihydrogen phosphate, aluminium dihydrogen phosphate, sodium dihydrogen phosphate or the zinc dihydrogen phosphate; Described sulfate is a kind of in aluminum sulfate, copper sulphate or the ferrous sulfate.
The fibrous material that uses in the glass fiber reticular cloth replacement prior art with middle alkali glass can reduce production costs greatly and simplify activities, can avoid fiber skewness problem, or for solving complicated technology or the equipment that glass evenly distributes and adopts, and according to need, the mesh-density of glass fiber reticular cloth can be regulated in quite wide scope, with the increase of products thickness, mesh-density can be from 50～200g/cm
2, increasing (seeing embodiment for details), grid cloth and nonwoven lay respectively at two surfaces of composite plate, play a supportive role.
The inorganic non-combustible plate that the present invention makes is applicable to furred ceiling, roof panel, partition wall and steel structure fireproof protection.The concrete roof panel that has been used for the international welfare center for children in Shanghai, partition wall and the furred ceiling of silver-colored mansion Nan Lou handed over by Pudong, the partition wall of ZSPD and Golden Bridge Japan Toshiba factory building, supporting project of the steel work of General Motors and middle good fortune mansion steel structure fireproof protection etc.Usually make furred ceiling thickness 3～6mm; Thickness 8～the 12mm of roof panel, partition wall; General 10～the 12mm of steel structure fireproof protection specifically decides on the actual requirement of engineering.
In a word; inorganic non-combustible plate provided by the invention (DF plate) has lightweight, high-strength, heat insulation, sound insulation, fire-retardant, nontoxic, durable in use (changes in temperature circulation 〉=25 times, not aliquation, flawless) but advantages such as machining; not only can be used as wall panel, ceiling board, sound barrier, ventilating duct, car and boat body decorative panel; and being applicable to roof panel and steel structure fireproof protection in dwelling house " flat-changed-into-sloping " project, application prospect is good.
The specific embodiment
Below by the specific embodiment, further illustrate substantive distinguishing features of the present invention and marked improvement.
Embodiment 1
100 parts of light-magnesite powder, 50 parts of halogen sheets, 50 parts in water, 30 parts in flyash, 25 parts of wood chips, 0.3 part of compound anti-water additive, the concrete composition of described compound anti-water additive is the compound copper sulphate of zinc dihydrogen phosphate, and the ratio of the two is 2: 8, glass fiber reticular cloth (70g/m
2) two layers, nonwoven (18g/m
2) two layers; The thick DF plate of 3mm records rupture strength 19.5Mpa after maintenance in 28 days; The inorganic non-combustible plate that present embodiment makes is applicable to furred ceiling.
Embodiment 2
100 parts of light-magnesite powder, 50 parts of halogen sheets, 50 parts in water, 30 parts in flyash, 20 parts of wood chips, 0.8 part of compound anti-water additive, described compound anti-water additive forms and ratio is: magnesium dihydrogen phosphate/aluminum sulfate=7: 3, glass fiber reticular cloth (90g/m
2) two layers, nonwoven (18g/m
2) two layers; The thick DF plate of 6mm records rupture strength 16.0Mpa after maintenance in 28 days.The inorganic non-combustible plate that present embodiment is made is applicable to furred ceiling.
Embodiment 3
100 parts of light-magnesite powder, 52 parts of halogen sheets, 48 parts in water, 25 parts in flyash, 30 parts of wood chips, 1.8 parts of compound anti-water additives, described compound anti-water additive consists of the compound ferrous sulfate of calcium dihydrogen phosphate, and the two ratio is 6: 4, glass fiber reticular cloth (150g/m
2) two layers, nonwoven (18g/m
2) two layers; The thick DF plate of 8mm records rupture strength 14.2Mpa after maintenance in 28 days; The inorganic non-combustible plate that present embodiment makes is applicable to roof panel, partition wall, steel work protected apron.
Embodiment 4
100 parts of light-magnesite powder, 52 parts of halogen sheets, 48 parts in water, 25 parts in flyash, 15 parts of wood chips, 15 parts of expanded perlites, 2.4 parts of compound anti-water additives, described compound anti-water additive consist of the compound copper sulphate of aluminium dihydrogen phosphate, the ratio of the two is 2: 8, glass fiber reticular cloth (200g/m
2) two layers, nonwoven (18g/m
2) two layers; The thick DF plate of 10mm records rupture strength 12.0Mpa after maintenance in 28 days; The inorganic non-combustible plate that present embodiment makes is applicable to roof panel, partition wall, steel work protected apron.
Embodiment 5
100 parts of light-magnesite powder, 52 parts of halogen sheets, 48 parts in water, 20 parts in flyash, 20 parts of wood chips, 20 parts of expanded perlites, 4 parts of compound anti-water additives, described compound anti-water additive consists of the compound copper sulphate of sodium dihydrogen phosphate, the two compositely proportional is 9: 1, glass fiber reticular cloth (200g/m
2) two layers, nonwoven (18g/m
2) two layers; The thick DF plate of 12mm records rupture strength 10.2Mpa after maintenance in 28 days; The inorganic non-combustible composite plate that present embodiment is made is applicable to partition wall, the protection of barium structure fire.
Claims (6)
1. inorganic non-combustible plate, its composition contains light calcined magnesia, halogen sheet, water, wood chip, expanded perlite, glass grid cloth and nonwoven, it is characterized in that:
(1) also has flyash and compound anti-water additive in forming as adulterant;
(2) described compound anti-water additive is the compound sulfate of phosphate, compound ratio 1: 9～9: 1;
(3) the concrete parts by weight of forming are:
80～130 parts of light-magnesite powder
30～60 parts of halogen sheets
40～70 parts in water
5～40 parts in flyash
10～30 parts of wood chips
Expanded perlite (1～5mm) 0～25 part of particle diameter
0.1～5 part of compound anti-water additive
In addition, glass fiber reticular cloth is 2 layers
2 layers of nonwoven.
2. by the described inorganic non-combustible plate of claim 1, it is characterized in that phosphate is a kind of in calcium dihydrogen phosphate, magnesium dihydrogen phosphate, aluminium dihydrogen phosphate, sodium dihydrogen phosphate or the zinc dihydrogen phosphate in the described compound anti-water additive; Sulfate is a kind of in aluminum sulfate, copper sulphate or the ferrous sulfate.
3. by the described inorganic non-combustible plate of claim 1, it is characterized in that MgO content 〉=85% of described light-magnesite powder; The MgCl of halogen sheet
2〉=46%.
4. by the described inorganic non-combustible plate of claim 1, it is characterized in that described glass fiber reticular cloth is the medium-alkali glass fibre grid cloth, specification is 50～200g/m
2
5. by the application of the described inorganic non-combustible plate of claim 1, it is characterized in that being used for furred ceiling, roof panel, partition wall or steel structure fireproof protection.
6. by the application of the described inorganic non-combustible plate of claim 5, the plate thickness that do not fire that it is characterized in that being used for furred ceiling is 3～6mm; The thickness that be used for roof panel, is used for wall is 3～12mm, and being used for steel structure fireproof protection thickness is 10～12mm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB031159443A CN100408772C (en) | 2003-03-21 | 2003-03-21 | Inorganic noncombustible plank and its application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB031159443A CN100408772C (en) | 2003-03-21 | 2003-03-21 | Inorganic noncombustible plank and its application |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1446993A CN1446993A (en) | 2003-10-08 |
| CN100408772C true CN100408772C (en) | 2008-08-06 |
Family
ID=28050490
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB031159443A Expired - Fee Related CN100408772C (en) | 2003-03-21 | 2003-03-21 | Inorganic noncombustible plank and its application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100408772C (en) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102464483A (en) * | 2010-11-17 | 2012-05-23 | 新化县荣辉建材有限责任公司 | Silicon-magnesium composite wall material |
| CN102503350B (en) * | 2011-10-10 | 2016-01-20 | 上海汇豪木门制造有限公司 | A kind of fire door core material and manufacture method thereof |
| CN102505828A (en) * | 2011-11-21 | 2012-06-20 | 吴旭明 | Water-fast and flame-resistant floorboard and manufacturing process |
| CN107417242A (en) * | 2017-08-03 | 2017-12-01 | 何明驹 | The preparation method and wallboard of wallboard |
| US12109790B1 (en) | 2018-09-24 | 2024-10-08 | Columbia Insurance Company | Composite panels having a melamine impregnated protective layer |
| CN109454949A (en) * | 2018-12-18 | 2019-03-12 | 孙杰 | A kind of light partition board made of flyash and preparation method thereof |
| CA3141906A1 (en) | 2019-06-07 | 2020-12-10 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
| WO2020247780A1 (en) | 2019-06-07 | 2020-12-10 | Frs Group, Llc | Long-term fire retardant with an organophosphate and methods for making and using same |
| WO2022132246A1 (en) | 2020-12-15 | 2022-06-23 | Frs Group, Llc | Long-term fire retardant with magnesium sulfate and corrosion inhibitors and methods for making and using same |
| US11975231B2 (en) | 2022-03-31 | 2024-05-07 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1097832A (en) * | 1994-05-09 | 1995-01-25 | 吴振生 | A kind of temperature preserving board |
| CN1113850A (en) * | 1994-05-30 | 1995-12-27 | 万德兵 | Magnesite inorganic decorative board and its technology |
| US5767178A (en) * | 1993-10-28 | 1998-06-16 | Pyrotite Corporation | Water and fire resistant materials and methods for making the same |
| CN1225344A (en) * | 1998-11-20 | 1999-08-11 | 中国科学院上海硅酸盐研究所 | Inorganic and flame-retardant type composite slab and method for mfg. same |
-
2003
- 2003-03-21 CN CNB031159443A patent/CN100408772C/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5767178A (en) * | 1993-10-28 | 1998-06-16 | Pyrotite Corporation | Water and fire resistant materials and methods for making the same |
| CN1097832A (en) * | 1994-05-09 | 1995-01-25 | 吴振生 | A kind of temperature preserving board |
| CN1113850A (en) * | 1994-05-30 | 1995-12-27 | 万德兵 | Magnesite inorganic decorative board and its technology |
| CN1225344A (en) * | 1998-11-20 | 1999-08-11 | 中国科学院上海硅酸盐研究所 | Inorganic and flame-retardant type composite slab and method for mfg. same |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1446993A (en) | 2003-10-08 |
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Granted publication date: 20080806 Termination date: 20140321 |