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CN1098820C - Process for mfg. synthetic stone - Google Patents

Process for mfg. synthetic stone Download PDF

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Publication number
CN1098820C
CN1098820C CN00122026A CN00122026A CN1098820C CN 1098820 C CN1098820 C CN 1098820C CN 00122026 A CN00122026 A CN 00122026A CN 00122026 A CN00122026 A CN 00122026A CN 1098820 C CN1098820 C CN 1098820C
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stone
mould
ready
kraft paper
stone flour
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CN00122026A
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CN1287980A (en
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骆荣泰
杨杰
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Abstract

The present invention discloses manufacture technology for synthesizing stone, which belongs to the field of building material. The synthesized stone mixture is cast in a mold arranged on a glass plate according to a production principle of concrete components to directly form a flat plate. The maximum diameter of the flat plate containing stone material reaches 12CM. The present invention overcomes the defects of large investment, large loss and complicated technology because stereo square material is cast and cut into the flat plate when the similar product is manufactured. The technology manufactures various synthetic stone slab, deck plates, etc. The present invention utilizes waste material and broken stone blocks, so the present invention has the advantages of small investment, low cost and simple technology. The specification of the product is freely adjusted, and the synthetic material by the present invention is new building decoration material having the advantages of good quality and low cost.

Description

The manufacture method of synthesis stone
The present invention is a kind of manufacturing process of synthesis stone, belongs to building material field.
Along with the progressively raising of people's living standard, synthesis stone is feeded as a kind of novel building, the color and luster that it is beautiful, and novel pattern, elegant decorative effect more and more is subjected to people's favor, and various synthesis stones also arise at the historic moment.
The manufacturing process of at present domestic and international synthesis stone is nothing more than following two kinds: a kind of is the slabstone that natural marble, granite powder is broken into suitable size, rubble and particulate, after mixing with pigment, lime carbonate and resin etc., cast in the mould, be cured, make 1.3 * 1.3 * 3.3 meters cubes square stock, from mould, take out then to cut to saw and be processed into plate.The shortcoming of this making method has: 1, the investment of equipment mould is big; 2, energy consumption is big; 3, loss is big.Only the work in-process square stock loss of sawing square stock cutting linear slit (does not also comprise the loss of square stock at the good-for-nothing clout of three directions of length just up to more than 30%.) therefore, adopt that this manufacture craft yield rate is low, cost is high and operation is numerous and diverse.
The manufacturing process of another kind of synthesis stone is: the inorganic fines composition and the following inorganic particles composition of 100 orders that will contain the 5-70 order granularity that accounts for full dose 89% weight, account for the following resinous principle of full dose 11% weight with containing, being equipped with pigment is mixed, cast in the cured body member, then pressurization, hot briquetting.Also there are many drawbacks in the preparation method of this synthesis stone: 1, facility investment is big: 2, the Heating temperature in the product process flow, time are wayward, easily warpage, distortion; 3, limitation is big; Only can produce and include the synthesis stone of building stones diameter more than 5 orders.
In order to overcome the deficiency of above-mentioned synthesis stone manufacture craft, the present invention proposes a kind of less investment, technology is succinct, product is of high quality and at a reasonable price synthesis stone manufacturing process.
The object of the present invention is achieved like this:
Main component prescription of the present invention (respectively with Xiao Hua shape Type B two classes of the Da Hua shape A type that includes building stones diameter≤12cm and diameter≤6mm explanation respectively) in addition:
A, the synthesis stone prescription (by weight percentage) that includes building stones diameter≤12cm are:
Unsaturated polyester resin 8-11% coarse whiting 400 order 4-7%
Methylethyl ketone peroxide 0.1-0.3% stone flour 0-2mm 25-32%
Cobalt naphthenate 0.03%-0.1% stone grain 2-5mm 12-16%
Stone 1# Φ 8-12cm 3.5-7 % stone grain 5-10mm 12-16%
Stone 2# Φ 5-7cm 4-8%
Stone 3# Φ 2-4cm 18-25% annotates: stone thickness must not surpass the sheet metal thickness of producing.Pigment is joined by kind.
B, the synthesis stone prescription (by weight percentage) that includes building stones diameter≤6mm are:
Unsaturated polyester resin 9-13% stone flour 0-2mm 35-45%
Methylethyl ketone peroxide 0.1-0.3% stone grain 2-4mm 15-25%
Cobalt naphthenate 0.03-0.1% stone grain 4-6mm 15-25%
Coarse whiting 400 order 11-16% annotate: pigment is joined by kind.
The manufacturing process of synthesis stone is divided into two kinds of A, B according to the size that sheet material includes the building stones diameter:
A, the synthesis stone manufacturing process that includes building stones diameter≤12cm are: (one) screens stone,
1, from the discarded marble, granite scrap stock of deposit, filter out thickness and be no more than the stone of making plate thickness,
2, the stone of selecting by diameter 1# Φ 8-12cm, 2# Φ 5-7cm, 3# Φ 2-4cm, hammer into shape store classifiedly standby.(2) pulverize building stones, with the building stones crushing screening of deposit, it is standby to obtain stone flour, stone grain that specification is 0-2mm, 2-5mm, 5-10mm.(3) lay mould, the filling stone is seen accompanying drawing 1,
1, the thick sheet glass 1 of 10~12mm is placed on the river sand bedding course 3 in the groove that puzzles in advance 2, the dark 18cm of groove, the thick 15cm of river sand, with kraft paper 4 place mats on sheet glass 1,
2, mould 5 is brushed releasing agent, place on the kraft paper 4, four jiaos of mould connect draw-in groove, must block the jail, keep smooth, coincide,
3, will get 1#, 2#, 3# stone 6 ready is seated in the mould 5 equably by metering.(4). the making sheet moulding,
1, calculate by the sheet material quantity that once stirs or mix will be produced and need to measure with raw-material quantity, treat standby,
2, the unsaturated polyester resin of getting ready is dropped in vacuum mixer or the steel basin, successively pigment, coarse whiting, methylethylketone, cobalt naphthenate, stone flour, stone grain are dropped into then, through stir or mix evenly after, mixture 7 is seated in the mould of having got ready 5 by every aequum, floating, the 8 vibration compactings of kraft paper 4 usefulness small vibrating machines are 5-6 time on the pad
3, treat the gel demoulding about 30-60 minute, plate 9 is got in typing in 6-10 hour, smooth stacking, and self-vulcanizing can be ground, polish and become a useful person in 5-7 days.
B, the manufacturing process that includes the synthesis stone of building stones diameter≤6mm are: (one) pulverizes building stones.Marble, the granite waste material of deposit are carried out crushing screening, obtain stone flour, stone grain that specification is 0-2mm, 2-4mm, 4-6mm.(2), lay mould and see accompanying drawing 2,
1, the sheet glass 1 of thick 10~12mm is placed on the river sand bedding course 3 in the groove that puzzles in advance 2, the dark 18cm of groove, the thick 15cm of river sand, with kraft paper 4 place mats on sheet glass,
2, mould 5 is brushed releasing agent, place on the kraft paper 4, mould connects draw-in groove for four jiaos must block the jail, keeps smooth, coincide.(3) making sheet moulding,
1, calculate and need measure by once stirring or mix and stir the sheet material quantity that will produce with the quantity of raw and auxiliary material, ready for use,
2, with the stone grain of 0-2mm stone flour, 2-4mm, 4-6mm and pigment, coarse whiting, drop in vacuum mixer or the steel basin and stir,
3, drop into unsaturated polyester resin, methylethylketone, cobalt naphthenate successively, continue to stir,
4, mixture 7 is seated in by every sheet material aequum in the mould of having got ready 5, floating, kraft paper 4 on the pad, with small vibrating machine 8 vibration compactings 5-6 time,
5, treat the gel demoulding about 30-60 minute, plate 9 smooth stackings are got in typing in 6-10 hour, and self-vulcanizing can be ground, polish and become a useful person in 5-7 days.
In sum: because the present invention has adopted the simple and high-efficient manufacturing process, overcome the production like product three-dimensional square stock of cast earlier, sawing becomes the dull and stereotyped investment that causes big again, and loss is big, the shortcoming of complex process.Synthetic stone mixture is cast in the mould that places on the sheet glass, direct vibrations compactings molding plate, but and regulated at will product specification and kind, its advantage is very obvious.It has, and facility investment is few, and the starting material loss is minimum, and the existing mode of production of production cost reduces 30-40%, the product strength height, and glossiness is good, and the color and luster unanimity has avoided the aberration of lithotome and radioactive substance to exceed standard, and defective such as marble is frangible.Simultaneously, a large amount of utilization of the present invention discarded building stones and tailings, both improved the utilization ratio of rock material resource, protected ecotope again, and economic benefit and social benefit are all very outstanding, have high promotional value.
Below in conjunction with embodiment, the present invention is described in further detail,
With 1 square metre is example:
Embodiment 1,
Name of product is Yellow Jade, production board thickness 18mm, color: cream colour, include building stones diameter≤12cm, and belong to A type Da Hua shape marble synthesis stone,
Production process is:
(1) screening stone,
1, from the discarded marble Yellow Jade scrap stock of deposit, filter out the stone that thickness is no more than 18mm,
2, the stone of selecting by diameter 1# Φ 8-12cm, 2# Φ 5-7cm, 3# Φ 2-4cm, hammer into shape store classifiedly standby.(2) pulverize building stones, with the Yellow Jade building stones crushing screening of deposit, it is standby to obtain stone flour, stone grain that specification is 0-2mm2-5mm, 5-10mm.(3) lay mould, the filling stone is seen accompanying drawing 1,
1, the 10-12cm plate glass is placed on the river sand bedding course in the groove that puzzles in advance, the dark 18cm of groove, river sand 15cm, with ox degree paper place mat on sheet glass,
2, mould is brushed releasing agent, place on the kraft paper, mould connects draw-in groove for four jiaos must block the jail, keeps smooth, coincide,
3, stone 1#2.5kg, 2#3.4kg, the 3#11.5kg that gets ready filled in the mould equably.(4) making sheet moulding,
1, calculates and be unsaturated polyester resin 5.3kg by once stirring or mix and stir the quantity of producing one square metre of required raw and auxiliary material of sheet material, methylethylketone 70g, cobalt naphthenate 25g, coarse whiting 2.8kg, pigment: the yellow slurry of middle network 9.722g, bright red mill base 0.056g, stone flour 0-2mm16kg, stone grain 2-5mm 8.5kg, the 5-10mm8kg metering is got ready
2, the unsaturated polyester resin of getting ready is dropped in vacuum mixer or the steel basin, drop into pigment, coarse whiting, first and second bronze medals, cobalt naphthenate, stone flour, stone grain then successively, through stir or mix evenly after, mixture on average is seated in the mould of getting ready, floating, pad ox degree paper is with small vibrating machine vibration compacting 5-6 time
3, treat the gel demoulding about 30-60 minute, plate is got in typing in 6-10 hour, smooth stacking, and self-vulcanizing, 5-7 days completion of cures promptly grind, polish and become a useful person.
Embodiment 2 names of product: golden yellow jade, production board thickness 15mm, the color golden yellow includes building stones diameter≤6mm and belongs to Type B, Xiao Hua shape marble synthesis stone, and production process is:
(1) pulverize building stones, the marble Song Xiang Yellow building stones of laying in are carried out crushing screening, it is standby to obtain stone flour, stone grain that specification is 0-2mm, 2-4mm, 4-6mm.
(2) lay mould and see accompanying drawing 2,
1, the sheet glass of thick 10~12mm is placed on the interior river sand bedding course of the prior groove that has puzzled, the dark 18mm of groove, sand thick 15mm in river is layered on kraft paper on the sheet glass,
2, mould is brushed releasing agent, place on the kraft paper, mould connects draw-in groove for four jiaos must block the jail, keeps smooth, coincide.
(3) making sheet moulding,
1, by once stirring or mix and stir the quantity that the sheet material quantity that will produce calculates required raw and auxiliary material is: unsaturated polyester resin 4.5kg, methylethylketone 55g, cobalt naphthenate 20g, coarse whiting 4.9kg, pigment: iron oxide yellow 11g, iron oxide red 1g; Stone flour 0-2mm15.5kg, stone grain 2-4mm8.5kg, 4-6mm8kg, metering is got ready,
2, with the above-mentioned stone flour 0-2mm15.5kg that has got ready, stone grain 2-4mm8.5kg, 4-6mm8kg, pigment: iron oxide yellow 11g, iron oxide red 1g, coarse whiting 4.9kg drops in vacuum mixer or the steel basin and stirs,
3, drop into the above-mentioned unsaturated polyester resin 4.5kg that has got ready successively, methylethylketone 55g, cobalt naphthenate 20g continues to stir in stirrer or steel basin,
4, the mixture that stirs on average is seated in by every consumption in the mould of having got ready, floating, kraft paper on the pad, with small vibrating machine vibration compacting 5-6 time,
5, treat the gel demoulding about 30-60 minute, plate is got in typing in 6-10 hour, smooth stacking, and product innovation behind the 5-7 days completion of cures, can be ground, be polished to self-vulcanizing.

Claims (2)

1. the manufacture method of a synthesis stone is characterized in that the stone material prescription, calculate by weight percentage,
Unsaturated polyester resin 8-11% coarse whiting 400-500 order 4-7%
The peroxidation first and second bronze medal 0.1-0.3% stone flour 0-2mm 25-32%
Cobalt naphthenate 0.03-0.1% stone flour 2-5mm 12-16%
Stone 1# Φ 8-12cm 3.5-7% stone flour 5-10mm 12-16%
Stone 2# Φ 5-7cm 4-8%
Stone 3# Φ 2-4cm 18-25% processing step
(1) screening stone,
1. from the discarded marble, granite scrap stock of deposit, filter out thickness and be no more than the stone of making plate thickness;
2. the stone of selecting by diameter 1# Φ 8-12cm, 2# Φ 5-7cm, 3# Φ 2-4cm hammer into shape store classifiedly standby;
(2) pulverize building stones, with the building stones crushing screening of deposit, it is standby to obtain stone flour, stone grain that specification is 0-2mm, 2-5mm, 5-10mm,
(3) lay mould, the filling stone,
1. the thick sheet glass of 10-12mm is placed river sand bedding course fovea superior groove depth 18cm in the groove that puzzles in advance, the thick 15cm of river sand, with the kraft paper place mat on sheet glass;
2. mould is brushed releasing agent, place on the kraft paper, four jiaos of connection draw-in grooves of mould must block the jail, keep smooth, coincide;
3. equably be seated in mould in by metering 1#, 2#, the 3# stone of getting ready;
(4) making sheet moulding,
1. calculate and need by once stirring or mix and stir the sheet material quantity of being produced with raw-material quantity ready for use;
2. the unsaturated polyester resin of getting ready is dropped in vacuum mixer or the steel basin, successively pigment, coarse whiting, peroxidation first and second bronze medals, cobalt naphthenate, stone flour, stone grain are dropped into then, after stirring or uniform mixing, mixture is seated in the mould of having got ready by every plate aequum, floating, kraft paper on the pad is with small vibrating machine vibration compacting 5-6 time;
3. treat the gel demoulding about 30-60 minute, 6-10 hour the typing, get plate, smooth stacking can be ground, polish and become a useful person in self-vulcanizing 5-7 days.
2. the manufacture method of a synthesis stone is characterized in that the stone material prescription, calculate by weight percentage,
Unsaturated polyester resin 9-13% stone flour 0-2mm 35-47%
The peroxidation first and second bronze medal 0.1-0.3% stone flour 2-4mm 15-25%
Cobalt naphthenate 0.03-0.1% stone flour 4-6mm 15-25%
Coarse whiting 400-500 order 11-16% processing step
(1) pulverize building stones, marble, the granite scrap stock of deposit carried out crushing screening, obtain stone flour, stone grain that specification is 0-2mm, 2-4mm, 4-6mm,
(2) lay mould,
1. the sheet glass of thick 10-12mm is placed in river sand bedding course fovea superior groove depth 18cm in the groove that puzzles in advance, sand thick 15cm in river is layered on kraft paper on glass;
2. mould is brushed releasing agent, place on the kraft paper, mould connects draw-in groove for four jiaos must block the jail, keeps smooth, coincide;
(3) making sheet moulding,
1. by once stirring or mix and stir the quantity metering that the sheet material quantity that will produce is calculated to be needed with raw and auxiliary material, ready for use;
2. the stone flour of 0-2mm, stone grain and pigment, the coarse whiting of 2-4mm, 4-6mm are dropped in vacuum mixer or the steel basin and stir;
3. drop into unsaturated polyester resin, methylethylketone, cobalt naphthenate successively, continue to stir;
4. mixture is seated in the mould of having got ready by every sheet material aequum, and kraft paper on floating, the pad is with small vibrating machine vibration compacting 5-6 time;
5. treat the gel demoulding about 30-60 minute, plate is got in typing in 6-10 hour, and smooth stacking can be ground in self-vulcanizing 5-7 days, and polishing is become a useful person.
CN00122026A 2000-07-23 2000-07-23 Process for mfg. synthetic stone Expired - Fee Related CN1098820C (en)

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Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100374505C (en) * 2005-09-23 2008-03-12 贾若华 Natural texture irradiant artificial stone material and its production process
CN101612756B (en) * 2009-07-15 2011-03-30 陈友 High-temperature resistance waste synthetic stone re-use method
CN102336535B (en) * 2010-07-23 2016-03-16 福建鹏翔实业有限公司 A kind of production technique of rostone and formula
CN103572934A (en) * 2013-11-08 2014-02-12 上海寅意雕塑艺术有限公司 Method and system for compounding artificial stone materials to be mounted on various walls
CN103586972A (en) * 2013-11-08 2014-02-19 上海寅意雕塑艺术有限公司 Method and system for synthesizing artificial stone materials

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN86107572A (en) * 1986-12-01 1988-06-15 大连华美建筑装饰品厂 Artificial stoneware craft and goods
CN1103616A (en) * 1994-10-18 1995-06-14 张茂安 Structural product with colour stone effect and its producing method
CN1103857A (en) * 1993-12-16 1995-06-21 张连臣 Artificial granite flag and the mfg. method
CN1132298A (en) * 1995-03-27 1996-10-02 罗炳宏 Method for prodn. of regenerated granite sheet
CN1204486A (en) * 1997-07-07 1999-01-13 徐敏 Inlay technology for imitation jade and wooden product
CN1247879A (en) * 1999-09-17 2000-03-22 林小铁 Microcrystalline stone and its prep.

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN86107572A (en) * 1986-12-01 1988-06-15 大连华美建筑装饰品厂 Artificial stoneware craft and goods
CN1103857A (en) * 1993-12-16 1995-06-21 张连臣 Artificial granite flag and the mfg. method
CN1103616A (en) * 1994-10-18 1995-06-14 张茂安 Structural product with colour stone effect and its producing method
CN1132298A (en) * 1995-03-27 1996-10-02 罗炳宏 Method for prodn. of regenerated granite sheet
CN1204486A (en) * 1997-07-07 1999-01-13 徐敏 Inlay technology for imitation jade and wooden product
CN1247879A (en) * 1999-09-17 2000-03-22 林小铁 Microcrystalline stone and its prep.

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