CN109810749A - A kind of fully synthetic cutting fluid - Google Patents
A kind of fully synthetic cutting fluid Download PDFInfo
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- CN109810749A CN109810749A CN201910159896.0A CN201910159896A CN109810749A CN 109810749 A CN109810749 A CN 109810749A CN 201910159896 A CN201910159896 A CN 201910159896A CN 109810749 A CN109810749 A CN 109810749A
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Abstract
The present invention relates to metal cutting process lubrication technical fields, and in particular to arrives a kind of fully synthetic cutting fluid.A kind of fully synthetic cutting fluid, including following component: including following component: triethanolamine and its derivative, antirust agent, turkey red oil, glycerol, oleic acid, antibacterial agent, water.Rustless property, greasy property, clean-up performance are preferable when in use for cutting fluid provided by the present invention, unsuitable putrid and deteriorated, and clear is able to maintain in use process, and stability is good, is not easily decomposed under high temperature, and indoor storage period is long.In addition, the rust prevention during manufacture use that product of the present invention general can be used for steel material, cast iron, component of machine, steel alloy article assembly and material, rust-proof life is long, and the not harmful substances such as chloride, phenol, will not cause to burn to skin, meet environmental requirement.
Description
Technical field
The invention belongs to metal cutting process lubrication technical fields, more particularly it relates to a kind of fully synthetic cutting
Liquid.
Background technique
Cutting fluid is a kind of in metal cutting, mill process, for cooling down and lubricating the work of cutter and workpiece
Industry liquid is formed by multiple functions auxiliary agent through the compound compatibility of science.As a kind of the important complementary of metal cutting process
Supplementary material, metalworking fluid can extend the service life of cutter and grinding tool, improve the finish of workpiece, reduce cutting, grinding
Power, main function include cooling, four lubrication, antirust and cleaning aspects.The cutting fluid generally used is mainly oil base and water
Two class of base, in recent years, water-base cutting fluid cooling, cleaning, rust-preventing characteristic, in terms of have outstanding feature and obtain
To be more and more widely used, water-base cutting fluid can be divided into micro-emulsion type, emulsifying and fully synthetic type.In manufacturing with mechanized equipment
The requirement of harsh new processing technology and new material, along with continually developing for new type water-solubility additive, so that water base cutting
Liquid is developed rapidly.
Semi-synthetic water-soluble metalworking liquid on the market easily corrodes workpiece, volatile, easy decomposition at present, should to Long Term Contact
The health of the operator of cutting fluid is very unfavorable, and waste water is not easy to handle, need to increase oily water separating equipment and commission environmental protection company
Recovery processing.In addition, the revolving speed S and process amount F of existing cutting fluid are unable to satisfy the demand of processing production capacity.
Although traditional fully synthetic cutting fluid have in terms of cleaning and heat dissipation some superiority, antirust and greasy property compared with
Difference.And although micro-emulsion cutting fluid combines the advantage of fully synthetic cutting fluid and oil emulsion, but exist in modulated process big
The oleophylic hydrophilic surfactant of amount, it is on the high side to cause dilution foam, influences to process.Although oil emulsion lubricating and antirust performance is excellent
Show, but service life is short.It is preferable therefore, it is necessary to develop a kind of lubricating action, anti-rust action and cleaning action, and use
In still keep clarification to facilitate look at the cutting fluid of workpiece.
Summary of the invention
To solve the above-mentioned problems, first aspect of the present invention provides a kind of fully synthetic cutting fluid, including following component:
Triethanolamine and its derivative, antirust agent, turkey red oil, glycerol, oleic acid, antibacterial agent, water.
As a kind of perferred technical scheme, by weight, including following component: triethanolamine and its derivative 5-15
Part, 3-10 parts of antirust agent, 1-7 parts of turkey red oil, 2-8 parts of glycerol, 1-6 parts of oleic acid, 0.5-3 parts of antibacterial agent, 40-70 parts of water.
As a kind of perferred technical scheme, the triethanolamine and its derivative are selected from carbinolamine, monoethanolamine, diethyl
Hydramine, Propanolamine, 1,2- dipropanolamine, monoethanolamine borate, diethanol amine boric acid monoesters, triethanolamine borate, Carvedilol
One of oleic acid diacetayl amide borate is a variety of.
As a kind of perferred technical scheme, the antirust agent includes monoacid, binary acid, ternary acid, sulfonate.
As a kind of perferred technical scheme, the monoacid is selected from glycolic, lactic acid, glyceric acid, gluconic acid, bigcatkin willow
Acid, 2- hydroxy-iso-butyric acid, 3-hydroxybutyrate, 4 hydroxybutyric acid, 2- hydroxyl-n-butyric acie, 2- hydroxycaproic acid, 3- hydroxycaproic acid, 4-
Hydroxycaproic acid, 5- hydroxycaproic acid, 6 hydroxycaproic acid, 2- hydroxypentanoic acid, 3- hydroxypentanoic acid, oleic acid, isooctyl acid, 4- hydroxypentanoic acid,
One of hydroxypropyl sulfonic acid is a variety of.
As a kind of perferred technical scheme, the binary acid is selected from malonic acid, succinic acid, glutaric acid, adipic acid, heptan two
One of acid, suberic acid, azelaic acid, decanedioic acid, 2,3- dimethylated pentanedioic acid, diglycolic acid, 2,5- norcamphane dicarboxylic acids or
It is a variety of.
As a kind of perferred technical scheme, the ternary acid includes ternary polycarboxylic acids.
As a kind of perferred technical scheme, the sulfonate is selected from alkylsulfonate, sulfamate, arylsulphonate
One of or it is a variety of.
As a kind of perferred technical scheme, the antibacterial agent is selected from quaternary ammonium salt, isothiazolinone, glutaraldehyde, two sulphur cyanogen
One of methylmethane is a variety of.
As a kind of perferred technical scheme, the weight ratio of the triethanolamine and its derivative and antirust agent is (1.5-
1.7): 1.
The utility model has the advantages that rustless property, greasy property, clean-up performance are preferable when in use for cutting fluid provided by the present invention,
It is unsuitable putrid and deteriorated, and clear is able to maintain in use process, stability is good, is not easily decomposed under high temperature, and indoor storage period is long.
In addition, product of the present invention can the general process for steel material, cast iron, component of machine, steel alloy article assembly and material
Between antirust use, rust-proof life is long, and the not harmful substances such as chloride, phenol, will not cause to burn to skin, meet environmental protection and want
It asks.
Specific embodiment
It is further clear, complete that the technical characteristic work in technical solution is provided to the present invention With reference to embodiment
Description, not to the limitation of its protection scope.
Word " preferred ", " preferred " in the present invention etc. refer to, can provide in some cases certain beneficial to effect
The embodiment of the present invention of fruit.However, other embodiments are also likely to be preferred under identical circumstances or in the case of other
's.In addition, do not imply that other embodiments are unavailable to the statement of one or more preferred embodiments, be also not intended to by
Other embodiments exclude except the scope of the present invention.
When a numberical range disclosed herein, above range is considered as continuously, and the minimum value including the range and most
Big value and each value between this minimum value and maximum value.Further, when range refers to integer, including the model
Each integer between minimum value and maximum value enclosed.In addition, when providing multiple range Expressive Features or characteristic, Ke Yihe
And the range.In other words, unless otherwise specified, otherwise all ranges disclosed herein are understood to include and are wherein included into
Any and all subrange.For example, should be regarded as including between minimum value 1 and maximum value 10 from the specified range of " 1 to 10 "
Any and all subrange.The Exemplary range of range 1 to 10 include but is not limited to 1 to 6.1,3.5 to 7.8,5.5 to
10 etc..
To solve the above-mentioned problems, first aspect of the present invention provides a kind of fully synthetic cutting fluid, including following component:
Triethanolamine and its derivative, antirust agent, turkey red oil, glycerol, oleic acid, antibacterial agent, water.
In a preferred embodiment, by weight, including following component: triethanolamine and its derivative 5-15
Part, 3-10 parts of antirust agent, 1-7 parts of turkey red oil, 2-8 parts of glycerol, 1-6 parts of oleic acid, 0.5-3 parts of antibacterial agent, 40-70 parts of water.
Triethanolamine and its derivative
Triethanolamine of the present invention be heterocyclic compound and aliphatic compound containing N atom, can be in matrix
Adsorption forms hydrophobicity film and reaches the slow releasing function to metal erosion.
In a preferred embodiment, the triethanolamine and its derivative are selected from carbinolamine, monoethanolamine, diethyl
Hydramine, Propanolamine, 1,2- dipropanolamine, monoethanolamine borate, diethanol amine boric acid monoesters, triethanolamine borate, Carvedilol
One of oleic acid diacetayl amide borate is a variety of.
In a kind of preferred embodiment, the triethanolamine and its derivative are triethanolamine and triethanolamine boron
Acid esters is (2.5-3.5) according to weight ratio: 1 compounding obtains.
Antirust agent
Antirust agent of the present invention is a kind of synthesis bleeding agent of super grade high efficiency, it can strongly penetrate into iron rust, erosion, oil
To easily dispose screw, the rusty stain on snail and erosion in dirty, there is infiltration derusting, loosen lubrication, resist burn into
Protect the performances such as metal.
In a preferred embodiment, the antirust agent includes monoacid, binary acid, ternary acid, sulfonate.
Preferably, the monoacid is selected from glycolic, lactic acid, glyceric acid, gluconic acid, salicylic acid, 2- hydroxy-iso-butyric acid, 3-
Hydroxybutyric acid, 4 hydroxybutyric acid, 2- hydroxyl-n-butyric acie, 2- hydroxycaproic acid, 3- hydroxycaproic acid, diethoxalic acid, 5- hydroxyl oneself
Acid, 6 hydroxycaproic acid, 2- hydroxypentanoic acid, 3- hydroxypentanoic acid, oleic acid, isooctyl acid, 4- hydroxypentanoic acid, one in hydroxypropyl sulfonic acid
Kind is a variety of.
It is furthermore preferred that the monoacid is isooctyl acid.
Preferably, the binary acid is selected from malonic acid, succinic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, nonyl two
One of acid, decanedioic acid, 2,3- dimethylated pentanedioic acid, diglycolic acid, 2,5- norcamphane dicarboxylic acids are a variety of.
It is furthermore preferred that the binary acid is decanedioic acid.
Preferably, the ternary acid is ternary polycarboxylic acids, buys Shanghai Pu Cai chemical material Co., Ltd, model L-
90。
Preferably, the sulfonate is selected from one of alkylsulfonate, sulfamate, arylsulphonate or a variety of.
It is furthermore preferred that the sulfonate is that dodecyl benzene sulfonic acid amine and-two ethanesulfonic acid of piperazine-Isosorbide-5-Nitrae are according to weight ratio
(6.5-8): 1 compounding obtains, and No. CAS of-two ethanesulfonic acid of piperazine-Isosorbide-5-Nitrae is 5623-37-6.
It is further preferred that the antirust agent is the mixture of isooctyl acid, decanedioic acid, ternary polycarboxylic acids, sulfonate,
In, the isooctyl acid, decanedioic acid, ternary polycarboxylic acids, sulfonate weight ratio be (4-6): (1-3): (1-3): 1；The sulfonic acid
It is (6.5-8) that salt, which is dodecyl benzene sulfonic acid amine and two ethanesulfonic acid of piperazine -1,4- according to weight ratio: 1 compounding obtains.
In a preferred embodiment, the weight ratio of the triethanolamine and its derivative and antirust agent is (1.5-
1.7): 1.
The present invention uses the organic acid with certain greasy property as antirust agent, because it is with water-soluble well
Property, and cooling is more excellent, but when inventor has found that organic acid is used alone as antirust agent, easy to be broken by microorganism
It is bad that its service life is caused to shorten, and hit in high speed mill and be easy to cause breaking, therefore inventor is a certain amount of in being wherein added
Sulfonate, when the weight ratio of the triethanolamine and its derivative and antirust agent be (1.5-1.7): when 1, product not only have compared with
Good rustless property, and stability improves, and also has certain lubricity.Inventor speculates, the possible reason is each
Under the synergistic effect of component, antirust agent component first is by chelating chip, flocculation, forms precipitating after emulsifying it, into
One step disperses greasy dirt, secondly by the collective effect of triethanolamine and its derivative, makes it in alkalinity, in the same metal in metal surface
Chemically reactive generates composite deposition film, and under a variety of membrane interactions, the interfacial property and state of charge of metal surface occur
Variation, makes the energy on its surface be in stable state, has the function that antirust.
Turkey red oil
Turkey red oil of the present invention is also known as turkey red oil, alizarin oil, red oil, and the chemical name of main ingredient is castor-oil plant
Sour sulfuric ester sodium salt is to be reacted at a lower temperature by castor oil and the concentrated sulfuric acid, neutralizes using sodium hydroxide.
The present invention is not particularly limited the source of the turkey red oil, can be obtained by synthesis, can also pass through quotient
It buys, it is preferred that oil content >=70% in the turkey red oil, sulfonation base >=1.8%, for example (,) it is commercially available from the prosperous Cyanastraceae in Xingtai
Skill Co., Ltd.
Glycerol
Glycerol of the present invention, i.e. glycerine, national standard is known as glycerol, colourless, odorless, sweet, and appearance is in clear and bright glutinous
Magma state is a kind of organic matter, and No. CAS is 56-81-5.
Oleic acid
Oleic acid of the present invention is a kind of unsaturated fatty acid, is formed in the bodies of aminal and plant.
The present invention is not particularly limited the source of the oleic acid, can be commercially available, such as can buy certainly
The industrial oil and fat chemical Co., Ltd in Shandong Yangxin.
The present invention is used as lubricant using turkey red oil, glycerol and oleic acid, can adjust respectively preferably among involvement system
Among component ratio to suitable range, so that product keeps clarification preferably to work.
Antibacterial agent
Antibacterial agent of the present invention is also known as biocide, Biocidal algae-killing agent, microbicide etc., typically refers to effectively to control
The chemicals of system or microorganism-bacterium, fungi and algae in kill water system.
In a preferred embodiment, the antibacterial agent is selected from quaternary ammonium salt, isothiazolinone, glutaraldehyde, two sulphur cyanogen
One of methylmethane is a variety of.
It is furthermore preferred that the antibacterial agent includes BIT-20, BIT-20 chemical name is 1,2- phenylpropyl alcohol isothiazoline -3- ketone,
It is a kind of wide spectrum, long-acting killing various bacteria, saccharomycete and the antibacterial agent of mould.
It is further preferred that the antibacterial agent further includes modified manometer silicon dioxide；Still more preferably, the modification
Nano silica is imidazoles villaumite modified manometer silicon dioxide, and preparation step is as follows:
(1) 1- methylimidazole and 3- chloropropyl -3- methoxy silane are fed intake in a round bottom flask respectively, magnetic force at 80 DEG C
It is stirred at reflux 3 days, resulting crude product ether washes repeatedly 3 times, and then 40 DEG C of vacuum drying 12h remove ether, obtains light
Yellow thick liquid is chlorination 1- methyl -3- (3- trimethoxy silane propyl) benzimidazole product；
(2) by Nano-meter SiO_22Powder, chlorination 1- methyl -3- (3- trimethoxy silane propyl) imidazoles feed intake Yu Sankou respectively
Round-bottomed flask and magnetic agitation, 100 DEG C of constant temperature reflux 8h, during feeding intake, SiO2Powder is first dissolved in dimethyl acetamide, and 90
After DEG C magnetic agitation is uniform, it is slowly added to constant pressure funnel dissolved with chlorination 1- methyl -3- (3- trimethoxy silane propyl)
The dimethylacetamide solution of imidazoles drips speed control in 4~5 seconds every drops, obtains modified manometer silicon dioxide.
Wherein, the molar ratio of the 1- methylimidazole and 3- chloropropyl -3- methoxy silane is 1:1.2；Nanosized SiO2 powders
Last, chlorination 1- methyl -3- (3- trimethoxy silane propyl) imidazoles molar ratio is 1:1.8.
In a preferred embodiment, the antibacterial agent includes BIT-20, modified manometer silicon dioxide, wherein institute
State BIT-20, the weight ratio of modified manometer silicon dioxide is (5-9): 1.
Present inventor's discovery is added the effect that nano silica has enhancing to antibiotic property in antibacterial agent, can be made
Product resting period extends, but nanometer powder poor dispersion in system, and therefore, inventor uses modified manometer silicon dioxide
Dispersibility can not only be improved, improve anti-microbial property, moreover it is possible to further increase rustless property, inventor speculates the possible reason is receiving
Rice corpuscles and metal friction roll, and mutually agree with to form protective film, and modified nanoparticle and positively charged substance are anti-
It answers, is complexed in wear process with metallic atom, or in conjunction with metal surface electronics escaping rear remaining positive charge position, further
The more stable skin covering of the surface of forming properties competes under the conditions of extreme pressure with remaining component, weakens because grinding caused by stability
Damage compensates for the deficiency of remaining component film-formation result difference at high temperature.
The second aspect of the present invention provides a kind of preparation method of fully synthetic cutting fluid, and step includes:
(1) it weighs triethanolamine and its derivative is added to the water, be stirred until homogeneous, be heated to 35-50 DEG C；
(2) antirust agent, oleic acid are added in the mixture of step (1) while stirring, turkey red oil, glycerol is added later；
(3) antibacterial agent is added in the mixture of step (2) to stir evenly, after being cooled to room temperature, can discharges.
The present invention is specifically described below by embodiment, in addition, if without other explanations, it is raw materials used to be all
It is commercially available.
Embodiment
Embodiment 1
Embodiment 1 provides a kind of fully synthetic cutting fluid, by weight, including following component: triethanolamine and its spreading out
Biological 5 parts, 3 parts of antirust agent, 1 part of turkey red oil, 2 parts of glycerol, 1 part of oleic acid, 0.5 part of antibacterial agent, 40 parts of water.
It is 2.5:1 compounding that the triethanolamine and its derivative, which are triethanolamine and triethanolamine borate according to weight ratio,
It obtains.
The antirust agent is the mixture of isooctyl acid, decanedioic acid, ternary polycarboxylic acids, sulfonate, wherein the isooctyl acid,
Decanedioic acid, ternary polycarboxylic acids, sulfonate weight ratio be 4:1:1:1；The sulfonate is dodecyl benzene sulfonic acid amine and piperazine-
Bis- ethanesulfonic acid of 1,4- is that 6.5:1 compounds to obtain according to weight ratio.
The turkey red oil is bought from the prosperous blue star Science and Technology Ltd. in Xingtai.
The oleic acid is bought from the industrial oil and fat chemical Co., Ltd in Shandong Yangxin.
The antibacterial agent includes BIT-20, modified manometer silicon dioxide, wherein the BIT-20, modified nano-silica
The weight ratio of silicon is 5:1.
The modified manometer silicon dioxide is imidazoles villaumite modified manometer silicon dioxide, and preparation step is as follows:
(1) 1- methylimidazole and 3- chloropropyl -3- methoxy silane are fed intake in a round bottom flask respectively, magnetic force at 80 DEG C
It is stirred at reflux 3 days, resulting crude product ether washes repeatedly 3 times, and then 40 DEG C of vacuum drying 12h remove ether, obtains light
Yellow thick liquid is chlorination 1- methyl -3- (3- trimethoxy silane propyl) benzimidazole product；
(2) by Nano-meter SiO_22Powder, chlorination 1- methyl -3- (3- trimethoxy silane propyl) imidazoles feed intake Yu Sankou respectively
Round-bottomed flask and magnetic agitation, 100 DEG C of constant temperature reflux 8h, during feeding intake, SiO2Powder is first dissolved in dimethyl acetamide, and 90
After DEG C magnetic agitation is uniform, it is slowly added to constant pressure funnel dissolved with chlorination 1- methyl -3- (3- trimethoxy silane propyl)
The dimethylacetamide solution of imidazoles drips speed control in 4~5 seconds every drops, obtains modified manometer silicon dioxide.
Wherein, the molar ratio of the 1- methylimidazole and 3- chloropropyl -3- methoxy silane is 1:1.2；Nano-meter SiO_22Powder
Last, chlorination 1- methyl -3- (3- trimethoxy silane propyl) imidazoles molar ratio is 1:1.8.
A kind of preparation method of fully synthetic cutting fluid, step include:
(1) it weighs triethanolamine and its derivative is added to the water, be stirred until homogeneous, be heated to 40 DEG C；
(2) antirust agent, oleic acid are added in the mixture of step (1) while stirring, turkey red oil, glycerol is added later；
(3) antibacterial agent is added in the mixture of step (2) to stir evenly, after being cooled to room temperature, can discharges.
Embodiment 2
Embodiment 2 provides a kind of fully synthetic cutting fluid, by weight, including following component: triethanolamine and its spreading out
Biological 15 parts, 10 parts of antirust agent, 7 parts of turkey red oil, 8 parts of glycerol, 6 parts of oleic acid, 3 parts of antibacterial agent, 70 parts of water.
It is 3.5:1 compounding that the triethanolamine and its derivative, which are triethanolamine and triethanolamine borate according to weight ratio,
It obtains.
The antirust agent is the mixture of isooctyl acid, decanedioic acid, ternary polycarboxylic acids, sulfonate, wherein the isooctyl acid,
Decanedioic acid, ternary polycarboxylic acids, sulfonate weight ratio be 6:3:3:1；The sulfonate is dodecyl benzene sulfonic acid amine and piperazine-
Bis- ethanesulfonic acid of 1,4- is that 8:1 compounds to obtain according to weight ratio.
The turkey red oil is bought from the prosperous blue star Science and Technology Ltd. in Xingtai.
The oleic acid is bought from the industrial oil and fat chemical Co., Ltd in Shandong Yangxin.
The antibacterial agent includes BIT-20, modified manometer silicon dioxide, wherein the BIT-20, modified nano-silica
The weight ratio of silicon is 9:1.
The modified manometer silicon dioxide is imidazoles villaumite modified manometer silicon dioxide, and preparation step is the same as embodiment 1.
A kind of preparation method of fully synthetic cutting fluid, step is the same as embodiment 1.
Embodiment 3
Embodiment 3 provides a kind of fully synthetic cutting fluid, by weight, including following component: triethanolamine and its spreading out
Biological 8 parts, 5 parts of antirust agent, 3 parts of turkey red oil, 3 parts of glycerol, 2 parts of oleic acid, 1 part of antibacterial agent, 45 parts of water.
It according to weight ratio is that 3:1 is compounded that the triethanolamine and its derivative, which are triethanolamine and triethanolamine borate,
It arrives.
The antirust agent is the mixture of isooctyl acid, decanedioic acid, ternary polycarboxylic acids, sulfonate, wherein the isooctyl acid,
Decanedioic acid, ternary polycarboxylic acids, sulfonate weight ratio be 5:1:1.5:1；The sulfonate is dodecyl benzene sulfonic acid amine and piperazine
Two ethanesulfonic acid of piperazine -1,4- is that 7:1 compounds to obtain according to weight ratio.
The turkey red oil is bought from the prosperous blue star Science and Technology Ltd. in Xingtai.
The oleic acid is bought from the industrial oil and fat chemical Co., Ltd in Shandong Yangxin.
The antibacterial agent includes BIT-20, modified manometer silicon dioxide, wherein the BIT-20, modified nano-silica
The weight ratio of silicon is 6:1.
The modified manometer silicon dioxide is imidazoles villaumite modified manometer silicon dioxide, and preparation step is the same as embodiment 1.
A kind of preparation method of fully synthetic cutting fluid, step is the same as embodiment 1.
Embodiment 4
Embodiment 4 provides a kind of fully synthetic cutting fluid, by weight, including following component: triethanolamine and its spreading out
Biological 12 parts, 8 parts of antirust agent, 6 parts of turkey red oil, 6 parts of glycerol, 5 parts of oleic acid, 2 parts of antibacterial agent, 60 parts of water.
It according to weight ratio is that 3:1 is compounded that the triethanolamine and its derivative, which are triethanolamine and triethanolamine borate,
It arrives.
The antirust agent is the mixture of isooctyl acid, decanedioic acid, ternary polycarboxylic acids, sulfonate, wherein the isooctyl acid,
Decanedioic acid, ternary polycarboxylic acids, sulfonate weight ratio be 5.5:2:3:1；The sulfonate is dodecyl benzene sulfonic acid amine and piperazine
Two ethanesulfonic acid of piperazine -1,4- is that 7.5:1 compounds to obtain according to weight ratio.
The turkey red oil is bought from the prosperous blue star Science and Technology Ltd. in Xingtai.
The oleic acid is bought from the industrial oil and fat chemical Co., Ltd in Shandong Yangxin.
The antibacterial agent includes BIT-20, modified manometer silicon dioxide, wherein the BIT-20, modified nano-silica
The weight ratio of silicon is 8:1.
The modified manometer silicon dioxide is imidazoles villaumite modified manometer silicon dioxide, and preparation step is the same as embodiment 1.
A kind of preparation method of fully synthetic cutting fluid, step is the same as embodiment 1.
Embodiment 5
Embodiment 5 provides a kind of fully synthetic cutting fluid, by weight, including following component: triethanolamine and its spreading out
Biological 10 parts, 6 parts of antirust agent, 4 parts of turkey red oil, 4 parts of glycerol, 3 parts of oleic acid, 1.5 parts of antibacterial agent, 50 parts of water.
It according to weight ratio is that 3:1 is compounded that the triethanolamine and its derivative, which are triethanolamine and triethanolamine borate,
It arrives.
The antirust agent is the mixture of isooctyl acid, decanedioic acid, ternary polycarboxylic acids, sulfonate, wherein the isooctyl acid,
Decanedioic acid, ternary polycarboxylic acids, sulfonate weight ratio be 5:2:2:1；The sulfonate is dodecyl benzene sulfonic acid amine and piperazine-
Bis- ethanesulfonic acid of 1,4- is that 7:1 compounds to obtain according to weight ratio.
The turkey red oil is bought from the prosperous blue star Science and Technology Ltd. in Xingtai.
The oleic acid is bought from the industrial oil and fat chemical Co., Ltd in Shandong Yangxin.
The antibacterial agent includes BIT-20, modified manometer silicon dioxide, wherein the BIT-20, modified nano-silica
The weight ratio of silicon is 7:1.
The modified manometer silicon dioxide is imidazoles villaumite modified manometer silicon dioxide, and preparation step is the same as embodiment 1.
A kind of preparation method of fully synthetic cutting fluid, step is the same as embodiment 1.
Comparative example 1
Comparative example 1 provides a kind of fully synthetic cutting fluid, by weight, including following component: triethanolamine and its spreading out
Biological 0.5 part, 6 parts of antirust agent, 4 parts of turkey red oil, 4 parts of glycerol, 3 parts of oleic acid, 1.5 parts of antibacterial agent, 50 parts of water.
It according to weight ratio is that 3:1 is compounded that the triethanolamine and its derivative, which are triethanolamine and triethanolamine borate,
It arrives.
The antirust agent is the mixture of isooctyl acid, decanedioic acid, ternary polycarboxylic acids, sulfonate, wherein the isooctyl acid,
Decanedioic acid, ternary polycarboxylic acids, sulfonate weight ratio be 5:2:2:1；The sulfonate is dodecyl benzene sulfonic acid amine and piperazine-
Bis- ethanesulfonic acid of 1,4- is that 7:1 compounds to obtain according to weight ratio.
The turkey red oil is bought from the prosperous blue star Science and Technology Ltd. in Xingtai.
The oleic acid is bought from the industrial oil and fat chemical Co., Ltd in Shandong Yangxin.
The antibacterial agent includes BIT-20, modified manometer silicon dioxide, wherein the BIT-20, modified nano-silica
The weight ratio of silicon is 7:1.
The modified manometer silicon dioxide is imidazoles villaumite modified manometer silicon dioxide, and preparation step is the same as embodiment 1.
A kind of preparation method of fully synthetic cutting fluid, step is the same as embodiment 1.
Comparative example 2
Comparative example 2 provides a kind of fully synthetic cutting fluid, by weight, including following component: triethanolamine and its spreading out
Biological 10 parts, 0.2 part of antirust agent, 4 parts of turkey red oil, 4 parts of glycerol, 3 parts of oleic acid, 1.5 parts of antibacterial agent, 50 parts of water.
It according to weight ratio is that 3:1 is compounded that the triethanolamine and its derivative, which are triethanolamine and triethanolamine borate,
It arrives.
The antirust agent is the mixture of isooctyl acid, decanedioic acid, ternary polycarboxylic acids, sulfonate, wherein the isooctyl acid,
Decanedioic acid, ternary polycarboxylic acids, sulfonate weight ratio be 5:2:2:1；The sulfonate is dodecyl benzene sulfonic acid amine and piperazine-
Bis- ethanesulfonic acid of 1,4- is that 7:1 compounds to obtain according to weight ratio.
The turkey red oil is bought from the prosperous blue star Science and Technology Ltd. in Xingtai.
The oleic acid is bought from the industrial oil and fat chemical Co., Ltd in Shandong Yangxin.
The antibacterial agent includes BIT-20, modified manometer silicon dioxide, wherein the BIT-20, modified nano-silica
The weight ratio of silicon is 7:1.
The modified manometer silicon dioxide is imidazoles villaumite modified manometer silicon dioxide, and preparation step is the same as embodiment 1.
A kind of preparation method of fully synthetic cutting fluid, step is the same as embodiment 1.
Comparative example 3
Comparative example 3 provides a kind of fully synthetic cutting fluid, by weight, including following component: triethanolamine and its spreading out
Biological 10 parts, 6 parts of antirust agent, 4 parts of turkey red oil, 4 parts of glycerol, 3 parts of oleic acid, 0 part of antibacterial agent, 50 parts of water.
It according to weight ratio is that 3:1 is compounded that the triethanolamine and its derivative, which are triethanolamine and triethanolamine borate,
It arrives.
The antirust agent is the mixture of isooctyl acid, decanedioic acid, ternary polycarboxylic acids, sulfonate, wherein the isooctyl acid,
Decanedioic acid, ternary polycarboxylic acids, sulfonate weight ratio be 5:2:2:1；The sulfonate is dodecyl benzene sulfonic acid amine and piperazine-
Bis- ethanesulfonic acid of 1,4- is that 7:1 compounds to obtain according to weight ratio.
The turkey red oil is bought from the prosperous blue star Science and Technology Ltd. in Xingtai.
The oleic acid is bought from the industrial oil and fat chemical Co., Ltd in Shandong Yangxin.
The modified manometer silicon dioxide is imidazoles villaumite modified manometer silicon dioxide, and preparation step is the same as embodiment 1.
A kind of preparation method of fully synthetic cutting fluid, step is the same as embodiment 1.
Comparative example 4
Comparative example 4 provides a kind of fully synthetic cutting fluid, by weight, including following component: triethanolamine and its spreading out
Biological 10 parts, 6 parts of antirust agent, 4 parts of turkey red oil, 4 parts of glycerol, 3 parts of oleic acid, 1.5 parts of antibacterial agent, 50 parts of water.
It is 3:0.1 compounding that the triethanolamine and its derivative, which are triethanolamine and triethanolamine borate according to weight ratio,
It obtains.
The antirust agent is the mixture of isooctyl acid, decanedioic acid, ternary polycarboxylic acids, sulfonate, wherein the isooctyl acid,
Decanedioic acid, ternary polycarboxylic acids, sulfonate weight ratio be 5:2:2:1；The sulfonate is dodecyl benzene sulfonic acid amine and piperazine-
Bis- ethanesulfonic acid of 1,4- is that 7:1 compounds to obtain according to weight ratio.
The turkey red oil is bought from the prosperous blue star Science and Technology Ltd. in Xingtai.
The oleic acid is bought from the industrial oil and fat chemical Co., Ltd in Shandong Yangxin.
The antibacterial agent includes BIT-20, modified manometer silicon dioxide, wherein the BIT-20, modified nano-silica
The weight ratio of silicon is 7:1.
The modified manometer silicon dioxide is imidazoles villaumite modified manometer silicon dioxide, and preparation step is the same as embodiment 1.
A kind of preparation method of fully synthetic cutting fluid, step is the same as embodiment 1.
Comparative example 5
Comparative example 5 provides a kind of fully synthetic cutting fluid, by weight, including following component: triethanolamine and its spreading out
Biological 10 parts, 6 parts of antirust agent, 4 parts of turkey red oil, 4 parts of glycerol, 3 parts of oleic acid, 1.5 parts of antibacterial agent, 50 parts of water.
It according to weight ratio is that 3:1 is compounded that the triethanolamine and its derivative, which are triethanolamine and triethanolamine borate,
It arrives.
The antirust agent is the mixture of isooctyl acid, decanedioic acid, ternary polycarboxylic acids, sulfonate, wherein the isooctyl acid,
Decanedioic acid, ternary polycarboxylic acids, sulfonate weight ratio be 5:2:2:0.1；The sulfonate is dodecyl benzene sulfonic acid amine and piperazine
Two ethanesulfonic acid of piperazine -1,4- is that 7:1 compounds to obtain according to weight ratio.
The turkey red oil is bought from the prosperous blue star Science and Technology Ltd. in Xingtai.
The oleic acid is bought from the industrial oil and fat chemical Co., Ltd in Shandong Yangxin.
The antibacterial agent includes BIT-20, modified manometer silicon dioxide, wherein the BIT-20, modified nano-silica
The weight ratio of silicon is 7:1.
The modified manometer silicon dioxide is imidazoles villaumite modified manometer silicon dioxide, and preparation step is the same as embodiment 1.
A kind of preparation method of fully synthetic cutting fluid, step is the same as embodiment 1.
Comparative example 6
Comparative example 6 provides a kind of fully synthetic cutting fluid, by weight, including following component: triethanolamine and its spreading out
Biological 10 parts, 6 parts of antirust agent, 4 parts of turkey red oil, 4 parts of glycerol, 3 parts of oleic acid, 1.5 parts of antibacterial agent, 50 parts of water.
It according to weight ratio is that 3:1 is compounded that the triethanolamine and its derivative, which are triethanolamine and triethanolamine borate,
It arrives.
The antirust agent is the mixture of isooctyl acid, decanedioic acid, ternary polycarboxylic acids, sulfonate, wherein the isooctyl acid,
Decanedioic acid, ternary polycarboxylic acids, sulfonate weight ratio be 5:2:2:1；The sulfonate is dodecyl benzene sulfonic acid amine and piperazine-
Bis- ethanesulfonic acid of 1,4- is that 7:1 compounds to obtain according to weight ratio.
The turkey red oil is bought from the prosperous blue star Science and Technology Ltd. in Xingtai.
The oleic acid is bought from the industrial oil and fat chemical Co., Ltd in Shandong Yangxin.
The antibacterial agent includes BIT-20, modified manometer silicon dioxide, wherein the BIT-20, modified nano-silica
The weight ratio of silicon is 7:0.1.
The modified manometer silicon dioxide is imidazoles villaumite modified manometer silicon dioxide, and preparation step is the same as embodiment 1.
A kind of preparation method of fully synthetic cutting fluid, step is the same as embodiment 1.
Performance evaluation
1.65 DEG C of character tests: it using the method for range estimation, observes embodiment and the preparation-obtained product of comparative example exists
Stability at 65 DEG C.
2. rust-preventing characteristic is tested: it is tested according to method as defined in QB/T2117-1995: rust-preventing characteristic (cast iron monolithic, 5%
Aqueous solution, 35 ± 2 DEG C, RH (90 ± 2) %, day).
3. erosion test: tested according to method as defined in GB/T2361-1992 (5% aqueous solution, aluminium flake, 49 DEG C,
24h)。
4. stability test: weighing embodiment and the preparation-obtained product 5g of comparative example respectively, claim standard to 0.1g, set
In tool plug graduated cylinder, then stiffened degree is to shake up 1min after covering tightly at the water to 100mL graticule of 6000ppm, use pipette immediately
50mL dilution is drawn in 50mL buret, places the precipitation volume of observation soap after 3d, wherein soap is on dilution
One layer of white ester shape object.
Table 1
| 65 DEG C of characters | Rust-preventing characteristic/day | Corrosivity | Stability/mL | |
| Embodiment 1 | It is not muddy, it is not stratified | 435 | It is non-discolouring | 1.5 |
| Embodiment 2 | It is not muddy, it is not stratified | 450 | It is non-discolouring | 1.2 |
| Embodiment 3 | It is not muddy, it is not stratified | 465 | It is non-discolouring | 1.5 |
| Embodiment 4 | It is not muddy, it is not stratified | 480 | It is non-discolouring | 1 |
| Embodiment 5 | It is not muddy, it is not stratified | 500 | It is non-discolouring | 1 |
| Comparative example 1 | Muddiness, layering | 350 | Discoloration | 2.5 |
| Comparative example 2 | Muddiness, layering | 380 | Discoloration | 2.8 |
| Comparative example 3 | Muddiness, layering | 280 | Discoloration | 2.0 |
| Comparative example 4 | Muddiness, layering | 415 | Discoloration | 2.3 |
| Comparative example 5 | It is not muddy, it is not stratified | 385 | Discoloration | 2.5 |
| Comparative example 6 | It is not muddy, it is not stratified | 365 | Discoloration | 1.6 |
Claims (10)
1. a kind of fully synthetic cutting fluid, which is characterized in that including following component: triethanolamine and its derivative, antirust agent, romote antiquity
Oil, glycerol, oleic acid, antibacterial agent, water.
2. fully synthetic cutting fluid according to claim 1, which is characterized in that by weight, including following component: three second
Hydramine and its 5-15 parts of derivative, 3-10 parts of antirust agent, 1-7 parts of turkey red oil, 2-8 parts of glycerol, 1-6 parts of oleic acid, antibacterial agent 0.5-3
Part, 40-70 parts of water.
3. fully synthetic cutting fluid according to claim 1, which is characterized in that the triethanolamine and its derivative are selected from first
Hydramine, monoethanolamine, diethanol amine, Propanolamine, 1,2- dipropanolamine, monoethanolamine borate, diethanol amine boric acid monoesters, three
One of ethanol amine borate, tall oil acid diacetayl amide borate are a variety of.
4. fully synthetic cutting fluid according to claim 1, which is characterized in that the antirust agent include monoacid, binary acid,
Ternary acid, sulfonate.
5. fully synthetic cutting fluid according to claim 4, which is characterized in that the monoacid is selected from glycolic, lactic acid, sweet
Oleic acid, gluconic acid, salicylic acid, 2- hydroxy-iso-butyric acid, 3-hydroxybutyrate, 4 hydroxybutyric acid, 2- hydroxyl-n-butyric acie, 2- hydroxyl oneself
It is acid, 3- hydroxycaproic acid, diethoxalic acid, 5- hydroxycaproic acid, 6 hydroxycaproic acid, 2- hydroxypentanoic acid, 3- hydroxypentanoic acid, oleic acid, different
One of octanoic acid, 4- hydroxypentanoic acid, hydroxypropyl sulfonic acid are a variety of.
6. fully synthetic cutting fluid according to claim 4, which is characterized in that the binary acid be selected from malonic acid, succinic acid,
Camphane drops in glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid, decanedioic acid, 2,3- dimethylated pentanedioic acid, diglycolic acid, 2,5-
One of alkane dicarboxylic acids is a variety of.
7. fully synthetic cutting fluid according to claim 4, which is characterized in that the ternary acid includes ternary polycarboxylic acids.
8. fully synthetic cutting fluid according to claim 4, which is characterized in that the sulfonate is selected from alkylsulfonate, ammonia
One of base sulfonate, arylsulphonate are a variety of.
9. fully synthetic cutting fluid according to claim 1, which is characterized in that the antibacterial agent is selected from quaternary ammonium salt, isothiazole
One of quinoline ketone, glutaraldehyde, dithiocyano-methane are a variety of.
10. fully synthetic cutting fluid according to claim 1, which is characterized in that the triethanolamine and its derivative and anti-
The weight ratio of rust agent is (1.5-1.7): 1.
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| CN112457907A (en) * | 2020-06-08 | 2021-03-09 | 山东三晶润滑科技有限公司 | Novel cutting fluid special for glass ball production |
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