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CN109734397A - A kind of environmental protection type wall body building material and preparation method thereof - Google Patents

A kind of environmental protection type wall body building material and preparation method thereof Download PDF

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Publication number
CN109734397A
CN109734397A CN201910194651.1A CN201910194651A CN109734397A CN 109734397 A CN109734397 A CN 109734397A CN 201910194651 A CN201910194651 A CN 201910194651A CN 109734397 A CN109734397 A CN 109734397A
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China
Prior art keywords
parts
waste residue
wall body
environmental protection
protection type
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Pending
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CN201910194651.1A
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Chinese (zh)
Inventor
朱迎华
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Xuzhou New Building Materials Co Ltd Dili Waylen
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Xuzhou New Building Materials Co Ltd Dili Waylen
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Priority to CN201910194651.1A priority Critical patent/CN109734397A/en
Publication of CN109734397A publication Critical patent/CN109734397A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a kind of environmental protection type wall body building materials and preparation method thereof, raw material including following parts by weight: 10~15 parts of bentonite, 6~10 parts of quick lime, 0.8~1.2 part of magnesium silicate, 2~3 parts of wetting agent, 1~3 part of additive, 0.1~0.3 part of silylation hydrophober, 10~15 parts of epoxy resin, 1~2 part of toughener, 0.5~0.9 part of waterproofing agent, 0.8~1.6 part of heat stabilizer, 12~16 parts of ceramic waste residue, 10~20 parts of clinker, 2~4 parts of graphene oxide, 4~8 parts of fire retardant, 8~15 parts of steel-making waste residue, 20~30 parts of building waste residue, 5~10 parts of calcium carbonate, 10~15 parts of cement waste residue, the water of 15~25 parts of clinker and surplus.The environmental protection type wall body building material and preparation method thereof can either reasonably utilize waste, and reduce the cost manufactured, and saved the consumption of the energy, while the use of a variety of waste residues, can also improve to environment, reduce the pollution of environment.

Description

A kind of environmental protection type wall body building material and preparation method thereof
Technical field
The invention belongs to building material technical fields, and in particular to a kind of environmental protection type wall body building material and its preparation side Method.
Background technique
The range that environment-friendly type building material includes is very wide, has thermal insulation material, heat-barrier material, high-strength material, can breathe Material etc. belongs to new material.Construction material is the general designation of material used in civil engineering and architectural engineering.Construction material Structural material, ornament materials and certain proprietary materials can be divided into.Structural material include timber, bamboo wood, stone material, cement, concrete, Metal, brick and tile, ceramics, glass, engineering plastics, composite material etc.;Ornament materials include various coating, paint, coating, veneer, Assorted ceramic tile, glass with special-effect etc.;Proprietary material refer to for waterproof, moisture-proof, anti-corrosion, fire prevention, fire-retardant, sound insulation, every Heat, heat preservation, sealing etc..
Currently, clay class used in building field and using cement as the wall body building material of gelling agent, although it has The advantages that intensity is high, durability is good, but it is in process of production, the material for needing to consume is more, to the cost of architecture production Burden is brought, while in production process, be also easy to cause the pollution to environment, does not meet the energy-efficient theme of advocating environment protection now.
Summary of the invention
The purpose of the present invention is to provide a kind of environmental protection type wall body building materials and preparation method thereof, to solve above-mentioned background The problem of being proposed in technology.
To achieve the above object, the invention provides the following technical scheme: a kind of environmental protection type wall body building material, including it is as follows The raw material of parts by weight: 10~15 parts of bentonite, 6~10 parts of quick lime, 0.8~1.2 part of magnesium silicate, 2~3 parts of wetting agent, addition 1~3 part of agent, 0.1~0.3 part of silylation hydrophober, 10~15 parts of epoxy resin, 1~2 part of toughener, waterproofing agent 0.5~0.9 Part, 0.8~1.6 part of heat stabilizer, 12~16 parts of ceramic waste residue, 10~20 parts of clinker, 2~4 parts of graphene oxide, fire retardant 4 ~8 parts, 8~15 parts of steel-making waste residue, 20~30 parts of building waste residue, 5~10 parts of calcium carbonate, 10~15 parts of cement waste residue, clinker 15 The water of~25 parts and surplus.
Preferably, the fire retardant includes one of magnesium hydroxide, aluminium hydroxide and magnesium chloride or multiple combinations.
Preferably, the wetting agent is one of alkyl sulfate, sulfonate and polyoxyethylene or multiple combinations.
Preferably, the additive is the mixture of ethylene~vinyl acetate copolymerization emulsion and calcium carbonate composition.
Preferably, the toughener is EP rubbers, and waterproofing agent is inorganic aluminate, thermostabilization is just zinc stearate.
Preferably, the building waste residue is any one of barren rock brick, barren rock block and the remaining feldspar of use.
A kind of preparation method of environmental protection type wall body building material, comprising the following steps:
S1, taken according to the ratio of raw material proportioning cement waste residue, clinker, steel-making waste residue, building waste residue, bentonite, quick lime, Magnesium silicate and ceramic waste residue are placed in crusher and carry out break process, and be put into batch mixer and be sufficiently mixed, and are made uniformly Mixed material;
S2, start additive, wetting agent, the toughener that a certain amount of water is slowly added, centainly matches in blender And fire retardant, it is uniformly mixing to obtain mixed liquor A;
S3, remaining water, heat stabilizer and silylation hydrophober are added in another blender, stirring is mixed with after Close liquid B;
S4, the obtained mixed liquor A of S2 and S3 and mixed liquid B are added separately to mix in batch mixer, are stirred and evenly mixed, It obtains being mixed into moulding mixture;
S5, it will be finally obtained in S4 and be mixed into moulding mixture and be injected into molding die, be press-formed, obtained using routine techniques Molding mass;
S6, the molding mass for obtaining S5 are dried, and after the completion of drying, are both arrived wall body building material, will finally be obtained again Construction material cutting processing, required size is made.
Preferably, in S2 and S3, the total amount that water is added is that the one third of other total deals of ingredient is added, and in S2 for the first time The total amount that water is added is 3/5ths.
Preferably, in S6, when molding mass carries out drying and processing, the temperature of drying is 80~90 DEG C, the time of drying is 4~ 8 hours.
Technical effect and advantage of the invention: the environmental protection type wall body building material and preparation method thereof, by using building The primary raw material of waste residue, cement waste residue, ceramic waste residue, clinker and steel-making waste residue as construction material, can either close waste Reason utilize, and reduces the cost manufactured, and saved the consumption of the energy, while the use of a variety of waste residues, also can It is enough that environment is improved, reduce the pollution of environment, meets and protrude the main feature of environmental protection;Simultaneously added with toughener, Additive, wetting agent and heat stabilizer, and cooperate the signal of ceramic waste residue, magnesium silicate, epoxy resin and graphene oxide, it can The heat insulating effect in material is enough improved, while can be improved the ability of waterproof again, improves the permeability of wall, makes inhabitation ring Border is more comfortable, the use of last fire retardant, additionally it is possible to the fire resistance property for improving material, make material during use more Add safety.
Specific embodiment
Below in conjunction with the contents of the present invention, the technical solution in the present invention is clearly and completely described, it is clear that Described content is only a part of content of the present invention, rather than whole contents.Based on the content in the present invention, this field Those of ordinary skill's every other content obtained without making creative work belongs to what the present invention protected Range.
Embodiment 1
The present invention provides a kind of environmental protection type wall body building material, the raw material including following parts by weight: 10 parts of bentonite, life 6 parts of lime, 0.8 part of magnesium silicate, 2 parts of wetting agent, 1 part of additive, 0.1 part of silylation hydrophober, 10 parts of epoxy resin, toughener 1 part, 0.5 part of waterproofing agent, 0.8 part of heat stabilizer, 12 parts of ceramic waste residue, 10 parts of clinker, 2 parts of graphene oxide, 4 parts of fire retardant, 8 parts of steel-making waste residue, 20 parts of building waste residue, 5 parts of calcium carbonate, 10 parts of cement waste residue, 15 parts of clinker and surplus water.
Specifically, the fire retardant includes one of magnesium hydroxide, aluminium hydroxide and magnesium chloride or multiple combinations.
Specifically, the wetting agent is one of alkyl sulfate, sulfonate and polyoxyethylene or multiple combinations.
Specifically, the additive is the mixture of ethylene~vinyl acetate copolymerization emulsion and calcium carbonate composition.
Specifically, the toughener is EP rubbers, waterproofing agent is inorganic aluminate, thermostabilization is just zinc stearate.
Specifically, the building waste residue is any one of barren rock brick, barren rock block and the remaining feldspar of use.
A kind of preparation method of environmental protection type wall body building material, comprising the following steps:
S1, taken according to the ratio of raw material proportioning cement waste residue, clinker, steel-making waste residue, building waste residue, bentonite, quick lime, Magnesium silicate and ceramic waste residue are placed in crusher and carry out break process, and be put into batch mixer and be sufficiently mixed, and are made uniformly Mixed material;
S2, start additive, wetting agent, the toughener that a certain amount of water is slowly added, centainly matches in blender And fire retardant, it is uniformly mixing to obtain mixed liquor A;
S3, remaining water, heat stabilizer and silylation hydrophober are added in another blender, stirring is mixed with after Close liquid B;
S4, the obtained mixed liquor A of S2 and S3 and mixed liquid B are added separately to mix in batch mixer, are stirred and evenly mixed, It obtains being mixed into moulding mixture;
S5, it will be finally obtained in S4 and be mixed into moulding mixture and be injected into molding die, be press-formed, obtained using routine techniques Molding mass;
S6, the molding mass for obtaining S5 are dried, and after the completion of drying, are both arrived wall body building material, will finally be obtained again Construction material cutting processing, required size is made.
Specifically, in S2 and S3, the total amount that water is added is that the one third of other total deals of ingredient is added, and in S2 for the first time The total amount that water is added is 3/5ths.
Specifically, when molding mass carries out drying and processing, the temperature of drying is 80 DEG C, and the time of drying is 4 hours in S6.
Embodiment 2
A kind of method of environmental protection type wall body building material, the raw material including following parts by weight: 13 parts of bentonite, quick lime 8 Part, 1.0 parts of magnesium silicate, 2.5 parts of wetting agent, 2 parts of additive, 0.2 part of silylation hydrophober, 13 parts of epoxy resin, toughener 1.5 Part, 0.7 part of waterproofing agent, 1.2 parts of heat stabilizer, 14 parts of ceramic waste residue, 15 parts of clinker, 3 parts of graphene oxide, 6 parts of fire retardant, refining 12 parts of steel waste residue, 25 parts of building waste residue, 7 parts of calcium carbonate, 12 parts of cement waste residue, 20 parts of clinker and surplus water.
Specifically, the fire retardant includes one of magnesium hydroxide, aluminium hydroxide and magnesium chloride or multiple combinations.
Specifically, the wetting agent is one of alkyl sulfate, sulfonate and polyoxyethylene or multiple combinations.
Specifically, the additive is the mixture of ethylene~vinyl acetate copolymerization emulsion and calcium carbonate composition.
Specifically, the toughener is EP rubbers, waterproofing agent is inorganic aluminate, thermostabilization is just zinc stearate.
Specifically, the building waste residue is any one of barren rock brick, barren rock block and the remaining feldspar of use.
A kind of preparation method of environmental protection type wall body building material, comprising the following steps:
S1, taken according to the ratio of raw material proportioning cement waste residue, clinker, steel-making waste residue, building waste residue, bentonite, quick lime, Magnesium silicate and ceramic waste residue are placed in crusher and carry out break process, and be put into batch mixer and be sufficiently mixed, and are made uniformly Mixed material;
S2, start additive, wetting agent, the toughener that a certain amount of water is slowly added, centainly matches in blender And fire retardant, it is uniformly mixing to obtain mixed liquor A;
S3, remaining water, heat stabilizer and silylation hydrophober are added in another blender, stirring is mixed with after Close liquid B;
S4, the obtained mixed liquor A of S2 and S3 and mixed liquid B are added separately to mix in batch mixer, are stirred and evenly mixed, It obtains being mixed into moulding mixture;
S5, it will be finally obtained in S4 and be mixed into moulding mixture and be injected into molding die, be press-formed, obtained using routine techniques Molding mass;
S6, the molding mass for obtaining S5 are dried, and after the completion of drying, are both arrived wall body building material, will finally be obtained again Construction material cutting processing, required size is made.
Specifically, in S2 and S3, the total amount that water is added is that the one third of other total deals of ingredient is added, and in S2 for the first time The total amount that water is added is 3/5ths.
Specifically, when molding mass carries out drying and processing, the temperature of drying is 85 DEG C, and the time of drying is 6 hours in S6.
Embodiment 3
A kind of environmental protection type wall body building material, the raw material including following parts by weight: 115 parts of bentonite, 10 parts of quick lime, silicon 1.2 parts of sour magnesium, 3 parts of wetting agent, 3 parts of additive, 0.3 part of silylation hydrophober, 115 parts of epoxy resin, 2 parts of toughener, waterproof 0.9 part of agent, 1.6 parts of heat stabilizer, 16 parts of ceramic waste residue, 20 parts of clinker, 4 parts of graphene oxide, 8 parts of fire retardant, steel-making waste residue 15 parts, 30 parts of building waste residue, 10 parts of calcium carbonate, 15 parts of cement waste residue, 25 parts of clinker and surplus water.
Specifically, the fire retardant includes one of magnesium hydroxide, aluminium hydroxide and magnesium chloride or multiple combinations.
Specifically, the wetting agent is one of alkyl sulfate, sulfonate and polyoxyethylene or multiple combinations.
Specifically, the additive is the mixture of ethylene~vinyl acetate copolymerization emulsion and calcium carbonate composition.
Specifically, the toughener is EP rubbers, waterproofing agent is inorganic aluminate, thermostabilization is just zinc stearate.
Specifically, the building waste residue is any one of barren rock brick, barren rock block and the remaining feldspar of use.
A kind of preparation method of environmental protection type wall body building material, comprising the following steps:
S1, taken according to the ratio of raw material proportioning cement waste residue, clinker, steel-making waste residue, building waste residue, bentonite, quick lime, Magnesium silicate and ceramic waste residue are placed in crusher and carry out break process, and be put into batch mixer and be sufficiently mixed, and are made uniformly Mixed material;
S2, start additive, wetting agent, the toughener that a certain amount of water is slowly added, centainly matches in blender And fire retardant, it is uniformly mixing to obtain mixed liquor A;
S3, remaining water, heat stabilizer and silylation hydrophober are added in another blender, stirring is mixed with after Close liquid B;
S4, the obtained mixed liquor A of S2 and S3 and mixed liquid B are added separately to mix in batch mixer, are stirred and evenly mixed, It obtains being mixed into moulding mixture;
S5, it will be finally obtained in S4 and be mixed into moulding mixture and be injected into molding die, be press-formed, obtained using routine techniques Molding mass;
S6, the molding mass for obtaining S5 are dried, and after the completion of drying, are both arrived wall body building material, will finally be obtained again Construction material cutting processing, required size is made.
Specifically, in S2 and S3, the total amount that water is added is that the one third of other total deals of ingredient is added, and in S2 for the first time The total amount that water is added is 3/5ths.
Specifically, when molding mass carries out drying and processing, the temperature of drying is 90 DEG C, and the time of drying is 8 hours in S6.
Finally, it should be noted that the foregoing is only a preferred embodiment of the present invention, it is not intended to restrict the invention, Although the present invention is described in detail referring to the foregoing embodiments, for those skilled in the art, still may be used To modify the technical solutions described in the foregoing embodiments or equivalent replacement of some of the technical features, All within the spirits and principles of the present invention, any modification, equivalent replacement, improvement and so on should be included in of the invention Within protection scope.

Claims (9)

1. a kind of environmental protection type wall body building material, it is characterised in that: the raw material including following parts by weight: 10~15 parts of bentonite, 6~10 parts of quick lime, 0.8~1.2 part of magnesium silicate, 2~3 parts of wetting agent, 1~3 part of additive, silylation hydrophober 0.1~0.3 Part, 10~15 parts of epoxy resin, 1~2 part of toughener, 0.5~0.9 part of waterproofing agent, 0.8~1.6 part of heat stabilizer, ceramic waste residue 12~16 parts, 10~20 parts of clinker, 2~4 parts of graphene oxide, 4~8 parts of fire retardant, 8~15 parts of steel-making waste residue, building waste residue 20~30 parts, 5~10 parts of calcium carbonate, 10~15 parts of cement waste residue, 15~25 parts of clinker and surplus water.
2. a kind of environmental protection type wall body building material according to claim 1, it is characterised in that: the fire retardant includes hydrogen-oxygen Change one of magnesium, aluminium hydroxide and magnesium chloride or multiple combinations.
3. a kind of environmental protection type wall body building material according to claim 1, it is characterised in that: the wetting agent is alkyl sulfide One of hydrochlorate, sulfonate and polyoxyethylene or multiple combinations.
4. a kind of environmental protection type wall body building material according to claim 1, it is characterised in that: the additive be ethylene~ The mixture of vinyl acetate copolymerization emulsion and calcium carbonate composition.
5. a kind of environmental protection type wall body building material according to claim 1, it is characterised in that: the toughener is the third rubber of second Glue, waterproofing agent is inorganic aluminate, thermostabilization is just zinc stearate.
6. a kind of environmental protection type wall body building material according to claim 1, it is characterised in that: the building waste residue is barren rock Any one of brick, barren rock block and the remaining feldspar of use.
7. a kind of preparation method of environmental protection type wall body building material according to claim 1, it is characterised in that: including following Step:
S1, cement waste residue, clinker, steel-making waste residue, building waste residue, bentonite, quick lime, silicic acid are taken according to the ratio of raw material proportioning Magnesium and ceramic waste residue are placed in crusher and carry out break process, and be put into batch mixer and be sufficiently mixed, and are made uniform mixed Close material;
S2, start additive, wetting agent, toughener and the resistance that a certain amount of water is slowly added, centainly matches in blender Agent is fired, mixed liquor A is uniformly mixing to obtain;
S3, remaining water, heat stabilizer and silylation hydrophober are added in another blender, stirring obtains mixed liquor with after B;
S4, the obtained mixed liquor A of S2 and S3 and mixed liquid B are added separately to mix in batch mixer, stir and evenly mix, obtains It is mixed into moulding mixture;
S5, it will be finally obtained in S4 and be mixed into moulding mixture and be injected into molding die, be press-formed, formed using routine techniques Material;
S6, the molding mass for obtaining S5 are dried, and after the completion of drying, are both arrived wall body building material, are finally built again by what is obtained Material cutting processing is built, required size is made.
8. a kind of preparation method of environmental protection type wall body building material according to claim 7, it is characterised in that: S2 and S3 In, the total amount that water is added be the one third of other total deals of ingredient is added, and be added for the first time in S2 water total amount be five/ Three.
9. a kind of preparation method of environmental protection type wall body building material according to claim 7, it is characterised in that: in S6, at When moulding mixture carries out drying and processing, the temperature of drying is 80~90 DEG C, and the time of drying is 4~8 hours.
CN201910194651.1A 2019-03-14 2019-03-14 A kind of environmental protection type wall body building material and preparation method thereof Pending CN109734397A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115894052A (en) * 2022-09-20 2023-04-04 宜兴市隆昌耐火材料有限公司 Wear-resistant and fire-resistant new material for preheater outside kiln and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN104628314A (en) * 2013-11-12 2015-05-20 青岛青工建筑机械有限公司 Environment-friendly type high strength building material and manufacturing method thereof
CN105819778A (en) * 2016-03-16 2016-08-03 潍坊科技学院 Preparation method of light, thermal insulation, and environment-friendly composite wall construction material
CN107141010A (en) * 2017-05-10 2017-09-08 王武 A kind of sponge water-permeable brick and its production technology
CN107188484A (en) * 2017-08-02 2017-09-22 合肥广民建材有限公司 A kind of high-strength heat preservation sound isolating and flame-retardant environment friendly wall material and preparation method thereof
WO2018045622A1 (en) * 2016-09-09 2018-03-15 东南大学 Micro powder-reinforced, polyurethane-based, high-strength, waterproof, thermal-insulation decorative integrated material and preparation method therefor
CN108675687A (en) * 2018-08-07 2018-10-19 合肥易多方科技有限公司 A kind of ecological, environmental protective construction material

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104628314A (en) * 2013-11-12 2015-05-20 青岛青工建筑机械有限公司 Environment-friendly type high strength building material and manufacturing method thereof
CN105819778A (en) * 2016-03-16 2016-08-03 潍坊科技学院 Preparation method of light, thermal insulation, and environment-friendly composite wall construction material
WO2018045622A1 (en) * 2016-09-09 2018-03-15 东南大学 Micro powder-reinforced, polyurethane-based, high-strength, waterproof, thermal-insulation decorative integrated material and preparation method therefor
CN107141010A (en) * 2017-05-10 2017-09-08 王武 A kind of sponge water-permeable brick and its production technology
CN107188484A (en) * 2017-08-02 2017-09-22 合肥广民建材有限公司 A kind of high-strength heat preservation sound isolating and flame-retardant environment friendly wall material and preparation method thereof
CN108675687A (en) * 2018-08-07 2018-10-19 合肥易多方科技有限公司 A kind of ecological, environmental protective construction material

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115894052A (en) * 2022-09-20 2023-04-04 宜兴市隆昌耐火材料有限公司 Wear-resistant and fire-resistant new material for preheater outside kiln and preparation method thereof

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Application publication date: 20190510