CN109679753B

CN109679753B - Bentonite lubricating grease and preparation method thereof

Info

Publication number: CN109679753B
Application number: CN201710969235.5A
Authority: CN
Inventors: 郑会; 苏朔; 龙军; 段庆华; 孙洪伟; 张辉; 何懿峰; 刘中其; 姜靓
Original assignee: Sinopec Research Institute of Petroleum Processing; China Petroleum and Chemical Corp
Current assignee: Sinopec Research Institute of Petroleum Processing; China Petroleum and Chemical Corp
Priority date: 2017-10-18
Filing date: 2017-10-18
Publication date: 2022-05-03
Anticipated expiration: 2037-10-18
Also published as: CN109679753A

Abstract

The invention provides bentonite lubricating grease and a preparation method thereof. The bentonite grease of the invention, which takes the total weight of the grease as the reference, comprises the following components: benzotriazole derivatives, bentonite, phenothiazine and a major amount of a lubricating base oil. The bentonite lubricating grease synthesized by the invention has good heat resistance, excellent extreme pressure property, rust resistance and corrosion resistance, lower friction coefficient, excellent oxidation resistance and colloid stability, and can meet the lubricating requirements under severe working conditions such as high temperature, high load and the like.

Description

Bentonite lubricating grease and preparation method thereof

Technical Field

The invention relates to lubricating grease, in particular to bentonite lubricating grease.

Background

Bentonite greases are an important class of non-soap based greases prepared by thickening mineral or synthetic lubricating oils with modified bentonite. The bentonite lubricating grease not only has good heat resistance, but also has good mechanical stability and colloid stability, and the heat-resistant bentonite lubricating grease and the extreme pressure bentonite lubricating grease are widely applied to the lubrication of equipment such as metallurgical equipment, casting and steel rolling equipment, heavy mining machinery equipment, large trucks, paper making machinery, cement production equipment, high-temperature tunnel kiln cars, airplane wheel bearings, railway diesel locomotives, tubular thread seal assemblies and the like.

In recent years, many patents discuss the formulation, production process and performance of bentonite grease. CN1504552 adopts vegetable oil as base oil to prepare biodegradable lubricating grease, which meets the requirement of environmental protection; CN 1197107 adopts poly-alpha-olefin as base oil to prepare the bentonite lubricating grease for aviation, and the grease has good high and low temperature performance; CN 101886017 adopts furfural refined oil to prepare bentonite grease, antioxidant and pigment are added into the grease, so that the bentonite has good oxidation stability and corrosion resistance, and the addition of the pigment can play a role in endowing the product with special appearance and assisting in distinguishing the types of the grease.

With the increasing of parameters such as power, speed, precision and the like of modern mechanical equipment, the working load is higher and higher, the service environment is more and more severe, so that the abrasion and the service life of mechanical parts are greatly influenced, and in order to improve the lubricating performance of the lubricating grease and prolong the service life of the equipment, an anti-wear and anti-wear agent is required to be added into the lubricating grease to reduce the frictional resistance between frictional surfaces and prevent the abrasion and the scuffing of materials.

Disclosure of Invention

The invention provides bentonite lubricating grease and a preparation method thereof.

Specifically, the present invention relates to the following aspects.

1. The bentonite grease comprises the following components by taking the total weight of the grease as a reference: benzotriazole derivatives, bentonite, phenothiazine and a main amount of lubricating base oil, wherein the benzotriazole derivatives have the structure shown in the general formula (I):

in the general formula (I), the radical R' is selected from C_1-25Hydrocarbyl radical, C_3-25A linear or branched heteroalkyl radical having a number average molecular weight Mn of from 300 to 3000 (preferably from 500 to 2000, more preferably from 500 to 1500), or from the group C_1-20Hydrocarbyl and C_3-20A linear or branched heteroalkyl radical, preferably selected from C_10-25Straight or branched alkyl, C_10-25Straight-chain or branched alkenyl, C_10-25Straight-chain or branched alkynyl, C_10-25A linear or branched heteroalkyl group and a polyisobutenyl group having a number average molecular weight Mn of from 300 to 3000 (preferably from 500 to 2000, more preferably from 500 to 1500), more preferably C_10-25A linear or branched alkyl group; n is selected from an integer from 0 to 10, preferably from an integer from 0 to 5, more preferably 0; n radicals R₀Are the same or different from each other and are each independently selected from C_1-10Straight or branched alkylene, preferably independently selected from C_2-5A linear or branched alkylene group; n +2 groups A, which may be the same or different from each other, are each independently selected from the group consisting of hydrogen, a group represented by the formula (I-1), a group represented by the formula (I-2), C_1-25A hydrocarbon group and a hydrocarbon group having a number average molecular weight Mn of 300 to 3000 (preferably 500 to 2000, more preferably 500 to 1500), and are preferably each independently selected from the group consisting of hydrogen, a group represented by the formula (I-1), a group represented by the formula (I-2), C_1-6Straight or branched alkyl, C_10-25Straight or branched alkyl, C_10-25A linear or branched alkenyl group and a polyisobutenyl group having a number average molecular weight Mn of 300 to 3000 (preferably 500 to 2000, more preferably 500 to 1500), each of which is preferably independently selected from the group consisting of hydrogen, a group represented by the formula (I-1), a group represented by the formula (I-2) and C_1-4A linear or branched alkyl group, preferably each independently selected from hydrogen, a group represented by formula (I-1) and a group represented by formula (I-2), provided that at least one of the n +2 groups A is a group represented by formula (I-1) and at least one of the n +2 groups A is a group represented by formula (I-2); when at least one of said groups A is C_10-25Straight or branched alkyl, C_10-25Straight-chain or branched alkenyl or hydrocarbon radicals having a number-average molecular weight Mn of from 300 to 3000, preferably from 500 to 2000, more preferably from 500 to 1500, the radicals R' may also be hydrogen,

in the general formula (I-1) and the general formula (I-2), the group R₅And R₆Are the same or different from each other and are each independently selected from C_1-20Hydrocarbyl (especially C)_1-20Straight or branched alkyl), preferably each independently selected from C_1-15Straight or branched alkyl, more preferably each independently selected from C_3-12A linear or branched alkyl group; the groups X and Y, equal to or different from each other, are each independently selected from an oxygen atom and a sulfur atom, preferably both groups X are sulfur atoms and both groups Y are oxygen atoms; the two radicals R' are identical or different from each other and are each independently selected from hydrogen and C_1-20Hydrocarbyl, preferably independently selected from hydrogen and C_1-20Straight or branched chain alkyl, more preferably each independently selected from hydrogen and C_1-6Straight or branched chain alkyl, more preferably both hydrogen; radical R₁、R₂、R₃、R₄Are the same or different from each other and are each independently selected from hydrogen and C_1-20Hydrocarbyl, preferably independently selected from hydrogen and C_1-10Straight or branched alkyl, more preferably R₁And R₄Are each hydrogen, R₂And R₃One of them is C_1-10Straight or branched alkyl (preferably C)_1-6Linear or branched alkyl), the other being hydrogen, the linear or branched heteroalkyl meaning that the carbon chain structure of the linear or branched alkyl is selected from-O-, -S-and-NR- (wherein the group R is selected from H and C) by one or more (such as 1 to 5, 1 to 4, 1 to 3, 1 to 2 or 1) of_1-4Straight-chain or branched alkyl, preferably selected from H and methyl).

2. A grease according to any one of the preceding aspects, wherein the benzotriazole derivative is selected from the following specific compounds or mixtures of any two or more thereof:

3. the bentonite grease comprises the following components by taking the total weight of the grease as a reference: a benzotriazole derivative, bentonite, phenothiazine, and a major amount of a lubricating base oil, the benzotriazole derivative being produced by a method comprising the step of reacting a phosphorus compound represented by formula (I-A), an amine compound represented by formula (I-B), and a benzotriazole compound represented by formula (I-C) in the presence of an aldehyde represented by formula (I-D),

wherein the radical R' is selected from C_1-25Hydrocarbyl radical, C_3-25A linear or branched heteroalkyl radical having a number average molecular weight Mn of from 300 to 3000 (preferably from 500 to 2000, more preferably from 500 to 1500), or from the group C_1-20Hydrocarbyl and C_3-20A linear or branched heteroalkyl radical, preferably selected from C_10-25Straight or branched alkyl, C_10-25Straight-chain or branched alkenyl, C_10-25Straight-chain or branched alkynyl, C_10-25A linear or branched heteroalkyl group and a polyisobutenyl group having a number average molecular weight Mn of from 300 to 3000 (preferably from 500 to 2000, more preferably from 500 to 1500), more preferably C_10-25A linear or branched alkyl group; n is selected from an integer from 0 to 10, preferably from an integer from 0 to 5, more preferably 0; n radicals R₀Are the same or different from each other and are each independently selected from C_1-10Straight or branched alkylene, preferably independently selected from C_2-5A linear or branched alkylene group; n +2 radicals A', equal to or different from each other, are each independently selected from hydrogen, C_1-25A hydrocarbon group and a hydrocarbon group having a number average molecular weight Mn of 300 to 3000 (preferably 500 to 2000, more preferably 500 to 1500), and preferably each independently selected from hydrogen and C_1-6Straight or branched alkyl, C_10-25Straight or branched alkyl, C_10-25Linear or branched alkenyl radicals and polyisobutenyl radicals having a number average molecular weight Mn of from 300 to 3000 (preferably from 500 to 2000, more preferably from 500 to 1500), each independently of the others, are preferably selected from hydrogen and C_1-4Straight-chain or branched alkyl, with the proviso that at least two of the n +2 groups A' represent hydrogen; when at least one of said groups A' is C_10-25Straight or branched alkyl, C_10-25Straight or branched alkenyl or number averageIn the case of hydrocarbon radicals having a molecular weight Mn of from 300 to 3000 (preferably from 500 to 2000, more preferably from 500 to 1500), the radical R' can also be hydrogen; radical R₅And R₆Are the same or different from each other and are each independently selected from C_1-20Hydrocarbyl (especially C)_1-20Straight or branched alkyl), preferably each independently selected from C_1-15Straight or branched alkyl, more preferably each independently selected from C_3-12A linear or branched alkyl group; the groups X and Y, equal to or different from each other, are each independently selected from an oxygen atom and a sulfur atom, preferably both groups X are sulfur atoms and both groups Y are oxygen atoms; the radical R' is selected from hydrogen and C_1-20Hydrocarbyl, preferably selected from hydrogen and C_1-20Straight or branched alkyl, more preferably selected from hydrogen and C_1-6Straight or branched alkyl, more preferably hydrogen; radical R₁、R₂、R₃、R₄Are the same or different from each other and are each independently selected from hydrogen and C_1-20Hydrocarbyl, preferably independently selected from hydrogen and C_1-10Straight or branched alkyl, more preferably R₁And R₄Are each hydrogen, R₂And R₃One of them is C_1-10Straight or branched alkyl (preferably C)_1-6Linear or branched alkyl), the other being hydrogen, the linear or branched heteroalkyl meaning that the carbon chain structure of the linear or branched alkyl is selected from-O-, -S-and-NR- (wherein the group R is selected from H and C) by one or more (such as 1 to 5, 1 to 4, 1 to 3, 1 to 2 or 1) of_1-4Straight-chain or branched alkyl, preferably selected from H and methyl).

4. The production process according to any one of the preceding aspects, wherein the reaction time of the reaction is 0.1 to 24 hours, preferably 0.5 to 6 hours, and the reaction temperature of the reaction is 0 to 250 ℃, preferably 60 to 120 ℃.

5. The production process according to any one of the preceding aspects, wherein the molar ratio of the phosphorus compound represented by the formula (I-A) to the amine compound represented by the formula (I-B) is 1:0.1 to 10, preferably 1:0.6 to 1.5; the molar ratio of the phosphorus compound represented by the formula (I-A) to the benzotriazole compound represented by the formula (I-C) is 1:0.1 to 10, preferably 1:0.6 to 1.5; the molar ratio of the phosphorus compound represented by the formula (I-A) to the aldehyde represented by the formula (I-D) is 1:1 to 10, preferably 1:2 to 4.

6. A grease according to any one of the preceding aspects, wherein the benzotriazole derivative comprises from 0.01% to 10% (preferably from 0.1% to 5%) of the total mass of the grease; the bentonite accounts for 5-35% (preferably 10-25%) of the total mass of the lubricating grease; the phenothiazine accounts for 0.1-10% (preferably 0.5-2%) of the total mass of the lubricating grease; the lubricating base oil constitutes the main component of the grease.

7. In the grease of any of the preceding aspects, the bentonite is preferably an organobentonite, and may be selected from one or more of sodium, potassium, calcium and magnesium organobentonites, and most preferably sodium organobentonites. The lubricating base oil is preferably one or more of mineral oil, vegetable oil and synthetic oil, and preferably has a kinematic viscosity of 5-60mm at 100 ℃²A lubricating base oil of which the kinematic viscosity at 100 ℃ is from 10 to 30mm is most preferred²Lubricating base oil per second.

In the grease composition of the present invention, the content of each component can be calculated according to the amount of the charged components. Wherein the content of the bentonite thickener is 100 percent multiplied by the weight of the bentonite/the total weight of the grease.

8. The method for preparing the bentonite grease lubricant of any one of the preceding aspects comprises the following steps: adding part of lubricating base oil and bentonite into a grease making kettle, uniformly mixing, adding a dispersing agent, and stirring until a lubricating grease structure is formed in the kettle; heating to 50-80 deg.C and maintaining for 10-30 min; adding the rest lubricating base oil, stirring and cooling, adding the benzotriazole derivative and the phenothiazine, and stirring uniformly; grinding into grease.

The dispersant is preferably acetone and/or propylene carbonate, most preferably acetone.

According to the invention, the ratio between the partial lubricating base oil and the remaining lubricating base oil is preferably between 50 and 75: 25-50.

The bentonite lubricating grease disclosed by the invention has the advantages of good heat resistance, excellent extreme pressure property, antirust property, corrosion resistance, lower friction coefficient, excellent oxidation resistance, excellent colloid stability and the like, and can meet the lubricating requirements under severe working conditions such as high temperature and high load.

Technical effects

The benzotriazole derivative according to the present invention does not contain a metal element, is less likely to generate ash and deposits, and is an environmentally friendly lubricant additive.

The benzotriazole derivatives according to the present invention show significantly improved antiwear properties and extreme pressure properties as compared with prior art lubricating oil additives, and are effective in improving the antiwear properties and load-bearing capacity of lubricating oils.

The benzotriazole derivative according to the present invention, in a preferred embodiment, exhibits excellent abrasion resistance and, at the same time, further exhibits excellent thermal oxidation stability (thermal stability). This is not the case with the prior art lubricating oil additives.

The benzotriazole derivative according to the present invention, in a preferred embodiment, exhibits excellent anti-wear properties while further exhibiting excellent anti-corrosion properties. This is not the case with the prior art lubricating oil additives.

According to the benzotriazole derivative of the present invention, in a preferred embodiment, while exhibiting excellent anti-wear properties, it further exhibits excellent rust inhibitive properties. This is not the case with the prior art lubricating oil additives.

According to the benzotriazole derivative of the present invention, in a preferred embodiment, it further exhibits excellent friction reducing properties while exhibiting excellent abrasion resistance. This is not the case with the prior art lubricating oil additives.

The method for preparing the benzotriazole derivative has the characteristics of simple process, no waste gas discharge, less waste water, safety, environmental protection and the like.

Detailed Description

The following detailed description of the embodiments of the present invention is provided, but it should be noted that the scope of the present invention is not limited by the embodiments, but is defined by the appended claims.

All publications, patent applications, patents, and other references mentioned in this specification are herein incorporated by reference in their entirety. Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art. In case of conflict, the present specification, including definitions, will control.

When the specification concludes with claims with the heading "known to those skilled in the art", "prior art", or a synonym thereof, directed to a material, substance, method, step, device, or component, the subject matter from which the heading is derived encompasses those conventionally used in the art as presented in the present application, but also includes those not currently in use, but which would become known in the art to be suitable for a similar purpose.

In the context of the present specification, anything or things which are not mentioned, except where explicitly stated, are directly applicable to those known in the art without any changes. Moreover, any embodiment described herein may be freely combined with one or more other embodiments described herein, and the technical solutions or concepts resulting therefrom are considered part of the original disclosure or original disclosure of the invention, and should not be considered as new matters not disclosed or contemplated herein, unless a person skilled in the art would consider such a combination to be clearly unreasonable.

In the context of the present invention, the term "halogen" refers to fluorine, chlorine, bromine or iodine.

In the context of the present invention, the term "hydrocarbyl" has the meaning conventionally known in the art and includes straight or branched chain alkyl, straight or branched chain alkenyl, straight or branched chain alkynyl, cycloalkyl, cycloalkenyl, aryl, or combinations thereof. As the hydrocarbon group, a linear or branched alkyl group, a linear or branched alkenyl group, an aryl group, or a combination thereof is preferable. Specific examples of the hydrocarbon group include C_1-30The hydrocarbon group is more specifically C_1-30Straight or branched alkyl, C_2-30Straight-chain or branched alkenyl, C_3-20Cycloalkyl radical, C_3-20Cycloalkenyl radical, C_6-20Aryl or a combination thereof.

In the context of the present specification,as C_1-4Examples of the straight-chain or branched alkyl group include methyl, ethyl and propyl groups, and C is_2-4Examples of the straight-chain or branched alkenyl group include a vinyl group, an allyl group, and an propenyl group.

In the context of the present invention, the term "linear or branched heteroalkyl" refers to a linear or branched alkyl having a carbon chain structure selected from the group consisting of-O-, -S-and-NR- (wherein the radical R is selected from the group consisting of H and C) by one or more (such as 1 to 5, 1 to 4, 1 to 3, 1 to 2 or 1)_1-4Straight-chain or branched alkyl, preferably selected from H and methyl). It is preferable from the viewpoint of structural stability that, when plural, any two of the hetero groups are not directly bonded to each other. It is apparent that the hetero group is not at the end of the carbon chain of the linear or branched alkyl group or the linear or branched heteroalkyl group. It is expressly stated here that, although the interruptions may be present (for example by a heterogroup-NR-and R represents C)_1-4Linear or branched alkyl) may result in the linear or branched heteroalkyl group having a different total number of carbon atoms than the linear or branched alkyl group, but for convenience, the number of carbon atoms in the linear or branched heteroalkyl group prior to the interruption is still used to refer to the number of carbon atoms in the linear or branched heteroalkyl group after the interruption.

In the context of the present specification, the number average molecular weight Mn is determined by Gel Permeation Chromatography (GPC), unless otherwise specified.

In the context of the present specification, any reference to Gel Permeation Chromatography (GPC) or measurement conditions of a GPC profile, unless otherwise specified, is: the instrument adopts a Waters 2695 type gel permeation chromatographic analyzer of the Waters company in America, tetrahydrofuran is adopted as a mobile phase, the flow rate is 1mL/min, the temperature of a chromatographic column is 35 ℃, the outflow time is 40min, and the mass fraction of a sample is 0.16-0.20%.

Finally, unless otherwise expressly indicated, all percentages, parts, ratios, etc. referred to in this specification are by weight unless otherwise generally recognized by those skilled in the art.

According to the invention, firstly, the benzotriazole derivative is shown as a general formula (I).

According to the invention, in the general formula (I), the radical R' is chosen from C_1-25Hydrocarbyl radical, C_3-25Straight-chain or branched heteroalkyl radicals and hydrocarbyl radicals having a number average molecular weight Mn of from 300 to 3000.

According to a particular embodiment of the invention, in formula (I), the radical R' is chosen from C_1-20Hydrocarbyl and C_3-20Linear or branched heteroalkyl.

According to a particular embodiment of the invention, in formula (I), the radical R' is chosen from C_10-25Straight or branched alkyl, C_10-25Straight-chain or branched alkenyl, C_10-25Straight-chain or branched alkynyl, C_10-25Linear or branched heteroalkyl radicals and polyisobutenyl radicals having a number average molecular weight Mn of from 300 to 3000.

According to one embodiment of the invention, in formula (I), the radical R' represents C_10-25Straight or branched chain alkyl. Here, as the C_10-25Straight or branched alkyl, such as C_10-25Examples of the straight-chain alkyl group include n-dodecyl group, n-tridecyl group, n-tetradecyl group, n-pentadecyl group, n-hexadecyl group, n-heptadecyl group, n-octadecyl group, n-eicosyl group, n-tetracosyl group, neododecyl group, neotridecyl group, neotetradecyl group, neopentadecyl group, neohexadecyl group, neoheptadecyl group, neooctadecyl group, neoeicosyl group, neoheneicosyl group, and neotetracosyl group.

According to one embodiment of the invention, in formula (I), the radical R' represents C_10-25Straight or branched alkenyl. Here, as the C_10-25Straight-chain or branched alkenyl, for example, C_10-25Straight chain alkenyl, or there may be mentioned, for example, n-6-dodecenyl, n-6-tridecenyl, n-7-tetradecenyl, n-7-pentadecenyl, n-8-hexadecenyl and n-8-heptadecenylAlkenyl, n-9-octadecenyl, n-9-eicosenyl, n-10-heneicosenyl, n-12-tetracosenyl, new 6-dodecenyl, new 6-tridecenyl, new 7-tetradecenyl, new 7-pentadecenyl, new 8-hexadecenyl, new 8-heptadecenyl, new 9-octadecenyl, new 9-eicosenyl, new 10-heneicosenyl, new 12-tetracosenyl and the like.

According to a particular embodiment of the invention, in the general formula (I), the radical R' represents a hydrocarbon radical having a number-average molecular weight Mn of from 300 to 3000. Examples of the hydrocarbon group having a number average molecular weight Mn of 300 to 3000 include a hydrocarbon group (referred to as a polyolefin residue) obtained by removing one hydrogen atom from a polyolefin having a number average molecular weight Mn of 300 to 3000 (particularly, the terminal of the polyolefin molecular chain). Here, the number average molecular weight Mn as the polyolefin or the polyolefin residue is preferably 500 to 2000, more preferably 500 to 1500. Examples of the polyolefin include ethylene, propylene and C₄-C₁₀A homo-polymerization of α -olefins such as n-butene, isobutene, n-pentene, n-hexene, n-octene or n-decene or a polyolefin obtained by copolymerization of two or more of these olefins, with Polyisobutylene (PIB) being more preferred.

According to the invention, in the general formula (I), n is selected from integers from 0 to 10.

According to a particular embodiment of the invention, in formula (I), n is chosen from integers from 0 to 5.

According to a particular embodiment of the invention, in formula (I), n is 0, 1,2 or 3, such as 0.

According to the invention, in the general formula (I), n radicals R₀Are the same or different from each other and are each independently selected from C_1-10Straight or branched chain alkylene.

According to a particular embodiment of the invention, in the general formula (I), n radicals R₀Are the same or different from each other and are each independently selected from C_2-5Straight or branched chain alkylene. Here, as the C_2-5Examples of the straight-chain or branched alkylene group include an ethylene group and a propylene group.

According to the invention, in general formula (I), n +2 groups A, which may be the same or different from each other, are each independently selected from hydrogen, a group represented by the formula (I-1), a group represented by the formula (I-2), C_1-25A hydrocarbyl group having a number average molecular weight Mn of 300 to 3000.

According to a particular embodiment of the invention, in the general formula (I), n +2 groups A, equal to or different from each other, are each independently selected from hydrogen, the group represented by formula (I-1), the group represented by formula (I-2), C_1-6Straight or branched alkyl, C_10-25Straight or branched alkyl, C_10-25Linear or branched alkenyl radicals and polyisobutenyl radicals having a number average molecular weight Mn of from 300 to 3000.

According to a particular embodiment of the invention, in the general formula (I), n +2 groups A, equal to or different from each other, are each independently selected from hydrogen, the group represented by formula (I-1), the group represented by formula (I-2) and C_1-4Straight or branched chain alkyl.

According to a particular embodiment of the invention, in the general formula (I), n +2 groups A, equal to or different from each other, are each independently selected from hydrogen, the group represented by formula (I-1) and the group represented by formula (I-2).

According to one embodiment of the invention, in the general formula (I), the group a represents hydrogen.

According to one embodiment of the invention, in the general formula (I), the group A represents C_1-4Straight or branched chain alkyl.

According to one embodiment of the invention, in the general formula (I), the group A represents C_10-25Straight or branched chain alkyl. Here, as the C_10-25Straight or branched alkyl, such as C_10-25Examples of the straight-chain alkyl group include n-dodecyl group, n-tridecyl group, n-tetradecyl group, n-pentadecyl group, n-hexadecyl group, n-heptadecyl group, n-octadecyl group, n-eicosyl group, n-tetracosyl group, neododecyl group, neotridecyl group, neotetradecyl group, neopentadecyl group, neohexadecyl group, neoheptadecyl group, neooctadecyl group, neoeicosyl group, neoheneicosyl group, and neotetracosyl group.

According to one embodiment of the invention, inIn the general formula (I), the group A represents C_10-25Straight or branched alkenyl. Here, as the C_10-25Straight-chain or branched alkenyl, for example, C_10-25Examples of the linear alkenyl group include n-6-dodecenyl, n-6-tridecenyl, n-7-tetradecenyl, n-7-pentadecenyl, n-8-hexadecenyl, n-8-heptadecenyl, n-9-octadecenyl, n-9-eicosenyl, n-10-heneicosenyl, n-12-tetracosenyl, new 6-dodecenyl, new 6-tridecenyl, new 7-tetradecenyl, new 7-pentadecenyl, new 8-hexadecenyl, new 8-heptadecenyl, new 9-octadecenyl, new 9-eicosenyl, new 10-heneicosenyl, new 12-tetracosenyl and the like.

According to a particular embodiment of the invention, in the general formula (I), the radical A represents a hydrocarbon radical having an average molecular weight Mn of from 300 to 3000. Examples of the hydrocarbon group having an average molecular weight Mn of 300 to 3000 include a hydrocarbon group (referred to as a polyolefin residue) obtained by removing one hydrogen atom from a polyolefin having a number average molecular weight Mn of 300 to 3000 (particularly, the terminal of the polyolefin molecular chain). Here, the number average molecular weight Mn as the polyolefin or the polyolefin residue is preferably 500 to 2000, more preferably 500 to 1500. Examples of the polyolefin include ethylene, propylene and C₄-C₁₀A homo-polymerization of α -olefins such as n-butene, isobutene, n-pentene, n-hexene, n-octene or n-decene or a polyolefin obtained by copolymerization of two or more of these olefins, with Polyisobutylene (PIB) being more preferred.

According to the invention, in the general formula (I), at least one of the n +2 groups A is a group represented by the formula (I-1), and at least one of the n +2 groups A is a group represented by the formula (I-2). Specifically, for example, when n is 0, in the general formula (I), one of 2 groups A is a group represented by the formula (I-1), and the other is a group represented by the formula (I-2). Or, specifically for example, when n is 1, in the general formula (I), one of 3 said groups A is a group represented by the formula (I-1) and the other two are groups represented by the formula (I-2), or two of 3 said groups A are groups represented by the formula (I-1) and the other is a group represented by the formula (I-2)Groups of the table. Or, for example, when n is 1, in the general formula (I), one of 3 said groups A is a group represented by formula (I-1), one is a group represented by formula (I-2), one is hydrogen, C_1-4Straight or branched alkyl, C_10-25Straight or branched alkyl, C_10-25Straight-chain or branched alkenyl or hydrocarbyl having a number average molecular weight Mn of 300 to 3000.

According to a particular embodiment of the invention, in formula (I), when at least one of said n +2 groups A represents said C_10-25Straight or branched alkyl, said C_10-25The radical R' may also be hydrogen or hydrogen when the linear or branched alkenyl radical or the hydrocarbon radical has a number-average molecular weight Mn of from 300 to 3000. In other words, according to this particular embodiment of the invention, in formula (I), at least one of the group A and the group R' must represent said C_10-25Straight or branched alkyl, said C_10-25A linear or branched alkenyl group or a hydrocarbon group having a number average molecular weight Mn of 300 to 3000.

According to the invention, in the general formula (I-1), the radical R₁、R₂、R₃、R₄Are the same or different from each other and are each independently selected from hydrogen and C_1-20A hydrocarbyl group.

According to a particular embodiment of the invention, in formula (I-1), the radical R₁、R₂、R₃、R₄Are the same or different from each other and are each independently selected from hydrogen and C_1-10Straight or branched chain alkyl. Here, as the C_1-10Straight-chain or branched alkyl, such as C_1-6Straight or branched alkyl, more specific examples being C_1-6Examples of the straight-chain alkyl group include methyl, n-butyl, isobutyl and n-hexyl.

According to a particular embodiment of the present invention, in the general formula (I-1), R₁And R₄Are each hydrogen, R₂And R₃One of them is C_1-10Straight or branched chain alkyl, the other being hydrogen. Here, as the C_1-10Straight-chain or branched alkyl, such as C_1-6Straight or branched alkyl, more specific examples being C_1-6Examples of the straight-chain alkyl group include methyl, n-butyl, isobutyl and n-hexyl.

According to a particular embodiment of the present invention, in the general formula (I-1), R₁、R₃And R₄Are each hydrogen, R₂Is C_1-10Straight or branched chain alkyl. Here, as the C_1-10Straight-chain or branched alkyl, such as C_1-6Straight or branched alkyl, more specific examples being C_1-6Examples of the straight-chain alkyl group include methyl, n-butyl, isobutyl and n-hexyl.

According to the invention, in the general formula (I-1), the radical R' is chosen from hydrogen and C_1-20A hydrocarbyl group.

According to a particular embodiment of the invention, in formula (I-1), the radical R' is chosen from hydrogen and C_1-20Straight or branched chain alkyl.

According to a particular embodiment of the invention, in formula (I-1), the radical R' is chosen from hydrogen and C_1-6Straight or branched chain alkyl. Here, as the C_1-6Straight-chain or branched alkyl, such as C_1-6Examples of the straight-chain alkyl group include methyl, ethyl and n-propyl.

According to a particular embodiment of the invention, in formula (I-1), the radical R' represents hydrogen.

According to the invention, in the general formula (I-2), the radical R₅And R₆Are the same or different from each other and are each independently selected from C_1-20A hydrocarbyl group.

According to a particular embodiment of the invention, in formula (I-2), the radical R₅And R₆Are the same or different from each other and are each independently selected from C_1-20Straight or branched chain alkyl.

According to a particular embodiment of the invention, in formula (I-2), the radical R₅And R₆Are the same or different from each other and are each independently selected from C_1-15Straight or branched chain alkyl.

According to a particular embodiment of the invention, in formula (I-2), the radical R₅And R₆Are the same or different from each other and are each independently selected from C_3-12Straight or branched chain alkyl. Here, as the C_3-12Specific examples of the linear or branched alkyl group include n-propyl, n-butyl, n-hexyl, n-decyl, n-dodecyl, isobutyl, isopentyl, isooctyl, isodecyl, isododecyl, 2-ethyl-n-hexyl, 2-ethyl-n-heptyl, 2-ethyl-n-octyl, and 2-ethyl-n-decyl.

According to the invention, in the general formula (I-2), the groups X and Y, equal to or different from each other, are each independently selected from an oxygen atom and a sulfur atom.

According to a particular embodiment of the invention, in formula (I-2), both groups X are sulfur atoms and both groups Y are oxygen atoms.

According to the invention, in the general formula (I-2), the radical R' is chosen from hydrogen and C_1-20A hydrocarbyl group.

According to a particular embodiment of the invention, in formula (I-2), the radical R' is chosen from hydrogen and C_1-20Straight or branched chain alkyl.

According to a particular embodiment of the invention, in formula (I-2), the radical R' is chosen from hydrogen and C_1-6Straight or branched chain alkyl. Here, as the C_1-6Straight-chain or branched alkyl, such as C_1-6Examples of the straight-chain alkyl group include methyl, ethyl and n-propyl.

According to a particular embodiment of the invention, in formula (I-2), the radical R' represents hydrogen.

According to the present invention, the benzotriazole derivative may be present, produced or used in the form of a single (pure) compound, or in the form of a mixture (in any ratio) of two or more thereof, without affecting the achievement of the effects of the present invention.

According to the present invention, the benzotriazole derivative can be produced, for example, by the following production method.

According to the present invention, the production method comprises a step of reacting the phosphorus compound represented by the formula (I-A), the amine compound represented by the formula (I-B), and the benzotriazole compound represented by the formula (I-C) in the presence of the aldehyde represented by the formula (I-D). This step will be referred to simply as the reaction step hereinafter.

According to the invention, in the general formula (I-A), the radical R₅And R₆Are the same or different from each other and are each independently selected from C_1-20A hydrocarbyl group.

According to a particular embodiment of the invention, in the formula (I-A), the radical R₅And R₆Are the same or different from each other and are each independently selected from C_1-20Straight or branched chain alkyl.

According to a particular embodiment of the invention, in the formula (I-A), the radical R₅And R₆Are the same or different from each other and are each independently selected from C_1-15Straight or branched chain alkyl.

According to a particular embodiment of the invention, in the formula (I-A), the radical R₅And R₆Are the same or different from each other and are each independently selected from C_3-12Straight or branched chain alkyl. Here, as the C_3-12Specific examples of the linear or branched alkyl group include n-propyl, n-butyl, n-hexyl, n-decyl, n-dodecyl, isobutyl, isopentyl, isooctyl, isodecyl, isododecyl, 2-ethyl-n-hexyl, 2-ethyl-n-heptyl, 2-ethyl-n-octyl, and 2-ethyl-n-decyl.

According to the invention, in the general formula (I-A), the groups X and Y, equal to or different from each other, are each independently selected from an oxygen atom and a sulphur atom.

According to a particular embodiment of the invention, in formula (I-A), both groups X are sulfur atoms and both groups Y are oxygen atoms.

According to the present invention, the phosphorus compound represented by the formula (I-A) may be produced by a commercially available method as it is or by a method conventionally known in the art, and is not particularly limited. Further, the phosphorus compound represented by the formula (I-A) may be used alone or in combination of two or more.

According to the invention, in the general formula (I-B), the radical R' is chosen from C_1-25Hydrocarbyl radical, C_3-25Straight-chain or branched heteroalkyl radicals and hydrocarbyl radicals having a number average molecular weight Mn of from 300 to 3000.

According to a particular embodiment of the invention, in formula (I-B), the radical R' is chosen from C_1-20Hydrocarbyl and C_3-20Linear or branched heteroalkyl.

According to a particular embodiment of the invention, in formula (I-B), the radical R' is chosen from C_10-25Straight or branched alkyl, C_10-25Straight-chain or branched alkenyl, C_10-25Straight-chain or branched alkynyl, C_10-25Linear or branched heteroalkyl radicals and polyisobutenyl radicals having a number average molecular weight Mn of from 300 to 3000.

According to one embodiment of the invention, in the general formula (I-B), the radical R' represents C_10-25Straight or branched chain alkyl. Here, as the C_10-25Straight or branched alkyl, such as C_10-25Examples of the straight-chain alkyl group include n-dodecyl group, n-tridecyl group, n-tetradecyl group, n-pentadecyl group, n-hexadecyl group, n-heptadecyl group, n-octadecyl group, n-eicosyl group, n-tetracosyl group, neododecyl group, neotridecyl group, neotetradecyl group, neopentadecyl group, neohexadecyl group, neoheptadecyl group, neooctadecyl group, neoeicosyl group, neoheneicosyl group, and neotetracosyl group.

According to one embodiment of the invention, in the general formula (I-B), the radical R' represents C_10-25Straight or branched alkenyl. Here, as the C_10-25Straight-chain or branched alkenyl, for example, C_10-25Examples of the linear alkenyl group include n-6-dodecenyl, n-6-tridecenyl, n-7-tetradecenyl, n-7-pentadecenyl, n-8-hexadecenyl, n-8-heptadecenyl, n-9-octadecenyl, n-9-eicosenyl, n-10-heneicosenyl, n-12-tetracosenyl, new 6-dodecenyl, new 6-tridecenyl, new 7-tetradecenyl, new 7-pentadecenyl, new 8-hexadecenyl, new 8-heptadecenyl, new 9-octadecenyl, new 9-eicosenyl, new 10-heneicosenyl, new 12-tetracosenyl and the like.

According to a particular embodiment of the invention, in the general formula (I-B), the radical R' represents a hydrocarbon radical having a number-average molecular weight Mn of from 300 to 3000. Examples of the hydrocarbon group having a number average molecular weight Mn of 300 to 3000 include a hydrocarbon group (referred to as a polyolefin residue) obtained by removing one hydrogen atom from a polyolefin having a number average molecular weight Mn of 300 to 3000 (particularly, the terminal of the polyolefin molecular chain). Here, the number average molecular weight Mn as the polyolefin or the polyolefin residue is preferably 500 to 2000, more preferably 500 to 1500.

In the context of the present specification, the polyolefin residues may be saturated (present as long-chain alkyl groups) or may contain an amount of olefinic double bonds in the polymer chain (such as those remaining during the polyolefin production process), depending on the starting polyolefin species or the production process, but this does not affect the achievement of the effect of the present invention, and the present invention is not intended to make explicit this amount.

According to a particular embodiment of the invention, the polyolefin is, for example, ethylene, propylene or C₄-C₁₀Homo-polymerization of alpha-olefins such as n-butene, isobutene, n-pentene, n-hexene, n-octene or n-decene or polyolefins obtained by copolymerization of two or more of these olefins.

According to a particular embodiment of the present invention, as the polyolefin, polybutene is more preferred. As used herein, unless otherwise indicated, the term "polybutene" broadly includes polymers obtained by the homopolymerization of 1-butene or isobutylene, as well as polymers obtained by the copolymerization of two or three of 1-butene, 2-butene and isobutylene. Commercial products of such polymers may also contain negligible amounts of other olefinic components, but this does not affect the practice of the invention.

According to a particular embodiment of the invention, as the polyolefin, Polyisobutylene (PIB) or highly reactive polyisobutylene (HR-PIB) is further preferred. In such polyisobutenes, at least 20% by weight (preferably at least 50% by weight, more preferably at least 70% by weight) of the total terminal olefinic double bonds are provided by methylvinylidene groups.

According to the invention, in the general formula (I-B), n is selected from integers from 0 to 10.

According to a particular embodiment of the invention, in formula (I-B), n is chosen from integers from 0 to 5.

According to a particular embodiment of the invention, in the general formula (I-B), n is 0, 1,2 or 3, and may be, for example, 0.

According to the invention, in the general formula (I-B), n radicals R₀Are the same or different from each other and are each independently selected from C_1-10Straight or branched chain alkylene.

According to a particular embodiment of the invention, in the formula (I-B), n radicals R₀Are the same or different from each other and are each independently selected from C_2-5Straight or branched chain alkylene. Here, as the C_2-5Examples of the straight-chain or branched alkylene group include an ethylene group and a propylene group.

According to the invention, in the general formula (I-B), n +2 radicals A', equal to or different from each other, are each independently selected from hydrogen, C_1-25A hydrocarbyl group having a number average molecular weight Mn of 300 to 3000.

According to a particular embodiment of the invention, in the general formula (I-B), n +2 radicals A', equal to or different from each other, are each independently selected from hydrogen, C_1-6Straight or branched alkyl, C_10-25Straight or branched alkyl, C_10-25Straight or branched alkenesA polyisobutenyl radical having a number average molecular weight Mn of from 300 to 3000.

According to a particular embodiment of the invention, in the general formula (I-B), n +2 radicals A', equal to or different from each other, are each independently selected from hydrogen and C_1-4Straight or branched chain alkyl.

According to one embodiment of the invention, in the general formula (I-B), the group A' represents hydrogen.

According to one embodiment of the invention, in the formula (I-B), the group A' represents C_1-4Straight or branched chain alkyl.

According to one embodiment of the invention, in the formula (I-B), the group A' represents C_10-25Straight or branched chain alkyl. Here, as the C_10-25Straight or branched alkyl, such as C_10-25Examples of the straight-chain alkyl group include n-dodecyl group, n-tridecyl group, n-tetradecyl group, n-pentadecyl group, n-hexadecyl group, n-heptadecyl group, n-octadecyl group, n-eicosyl group, n-tetracosyl group, neododecyl group, neotridecyl group, neotetradecyl group, neopentadecyl group, neohexadecyl group, neoheptadecyl group, neooctadecyl group, neoeicosyl group, neoheneicosyl group, and neotetracosyl group.

According to one embodiment of the invention, in the formula (I-B), the group A' represents C_10-25Straight or branched alkenyl. Here, as the C_10-25Straight-chain or branched alkenyl, for example, C_10-25Examples of the linear alkenyl group include n-6-dodecenyl, n-6-tridecenyl, n-7-tetradecenyl, n-7-pentadecenyl, n-8-hexadecenyl, n-8-heptadecenyl, n-9-octadecenyl, n-9-eicosenyl, n-10-heneicosenyl, n-12-tetracosenyl, new 6-dodecenyl, new 6-tridecenyl, new 7-tetradecenyl, new 7-pentadecenyl, new 8-hexadecenyl, new 8-heptadecenyl, new 9-octadecenyl, new 9-eicosenyl, new 10-heneicosenyl, new 12-tetracosenyl and the like.

According to a particular embodiment of the invention, in the general formula (I-B), the radical A' represents a hydrocarbon radical having a number-average molecular weight Mn of from 300 to 3000. Examples of the hydrocarbon group having a number average molecular weight Mn of 300 to 3000 include a hydrocarbon group (referred to as a polyolefin residue) obtained by removing one hydrogen atom from a polyolefin having a number average molecular weight Mn of 300 to 3000 (particularly, the terminal of the polyolefin molecular chain). Here, the number average molecular weight Mn as the polyolefin or the polyolefin residue is preferably 500 to 2000, more preferably 500 to 1500.

According to the invention, in the general formula (I-B), at least two of said n +2 groups A' represent hydrogen. Specifically, for example, when n is 0, in the general formula (I-B),2 of said groups A' each represent hydrogen. Or, by way of specific example, when n is 1, in formula (I-B), two of the 3 said groups A' represent hydrogen and the other represents hydrogen, C_1-4Straight or branched alkyl, C_10-25Straight or branched alkyl, C_10-25Straight-chain or branched alkenyl or hydrocarbyl having a number average molecular weight Mn of 300 to 3000.

According to a particular embodiment of the invention, in formula (I-B), when at least one of said n +2 groups A' represents said C_10-25Straight or branched alkyl, said C_10-25The radical R' may also be hydrogen or hydrogen when the linear or branched alkenyl radical or the hydrocarbon radical has a number-average molecular weight Mn of from 300 to 3000. In other words, according to this particular embodiment of the invention, in formula (I-B), at least one of the groups A 'and R' must represent said C_10-25Straight or branched alkyl, said C_10-25A linear or branched alkenyl group or a hydrocarbon group having a number average molecular weight Mn of 300 to 3000.

According to the present invention, the amine compound represented by the formula (I-B) may be produced by a method conventionally known in the art without any particular limitation, as it is, or by a commercially available product. In addition, the amine compound represented by the formula (I-B) may be used alone or in combination of two or more.

According to the invention, in the general formula (I-C), the radical R₁、R₂、R₃、R₄Are the same or different from each other and are each independently selected from hydrogen and C_1-20A hydrocarbyl group.

According to a particular embodiment of the invention, in the formula (I-C), the radical R₁、R₂、R₃、R₄Are the same or different from each other and are each independently selected from hydrogen and C_1-10Straight or branched chain alkyl. Here, as the C_1-10Straight-chain or branched alkyl, such as C_1-6Straight or branched chain alkyl, moreSpecific examples thereof include C_1-6Examples of the straight-chain alkyl group include methyl, n-butyl, isobutyl and n-hexyl.

According to a particular embodiment of the invention, in the general formula (I-C), R₁And R₄Are each hydrogen, R₂And R₃One of them is C_1-10Straight or branched chain alkyl, the other being hydrogen. Here, as the C_1-10Straight-chain or branched alkyl, such as C_1-6Straight or branched alkyl, more specific examples being C_1-6Examples of the straight-chain alkyl group include methyl, n-butyl, isobutyl and n-hexyl.

According to a particular embodiment of the invention, in the general formula (I-C), R₁、R₃And R₄Are each hydrogen, R₂Is C_1-10Straight or branched chain alkyl. Here, as the C_1-10Straight-chain or branched alkyl, such as C_1-6Straight or branched alkyl, more specific examples being C_1-6Examples of the straight-chain alkyl group include methyl, n-butyl, isobutyl and n-hexyl.

According to the present invention, the benzotriazole compound represented by the formula (I-C) may be produced by a method conventionally known in the art without any particular limitation, as it is, using a commercially available product. Further, the benzotriazole compound represented by the formula (I-C) may be used alone or in combination of two or more.

According to the invention, in the general formula (I-D), the radical R' is chosen from hydrogen and C_1-20A hydrocarbyl group.

According to a particular embodiment of the invention, in the general formula (I-D), the radical R' is chosen from hydrogen and C_1-20Straight or branched chain alkyl.

According to a particular embodiment of the invention, in the general formula (I-D), the radical R' is chosen from hydrogen and C_1-6Straight or branched chain alkyl. Here, as the C_1-6Straight-chain or branched alkyl, such as C_1-6Examples of the straight-chain alkyl group include methyl, ethyl and n-propyl.

According to a particular embodiment of the invention, in the general formula (I-D), the radical R' represents hydrogen.

According to the present invention, the aldehyde represented by the formula (I-D) may be produced by a commercially available product as it is or by a method conventionally known in the art, and is not particularly limited. In addition, the aldehyde represented by the formula (I-D) may be used alone or in combination of two or more.

According to a particular embodiment of the invention, the aldehyde represented by formula (I-D) is formaldehyde. The formaldehyde may be, for example, an aqueous formaldehyde solution, paraformaldehyde or paraformaldehyde, and is not particularly limited.

According to the present invention, in the reaction step, the reaction time of the reaction is generally 0.1 to 24 hours, preferably 0.2 to 12 hours, and most preferably 0.5 to 6 hours, for example, but is not limited thereto in some cases.

According to the present invention, in the reaction step, for example, the reaction temperature of the reaction is generally 0 to 250 ℃, preferably 20 to 180 ℃, and most preferably 60 to 120 ℃, but is not limited thereto in some cases.

According to the present invention, in the reaction step, for example, the molar ratio of the phosphorus compound represented by the formula (I-A) to the amine compound represented by the formula (I-B) is generally 1:0.1 to 10, preferably 1:0.5 to 5.0, more preferably 1:0.6 to 1.5, but is not limited thereto in some cases.

According to the present invention, in the reaction step, for example, the molar ratio of the phosphorus compound represented by the formula (I-A) to the benzotriazole compound represented by the formula (I-C) is generally 1:0.1 to 10, preferably 1:0.5 to 5.0, more preferably 1:0.6 to 1.5, but is not limited thereto in some cases.

According to the present invention, in the reaction step, for example, the molar ratio of the phosphorus compound represented by the formula (I-A) to the aldehyde represented by the formula (I-D) is generally 1:1 to 10, preferably 1:1.5 to 6.0, more preferably 1:2 to 4, but is not limited thereto in some cases.

According to the present invention, in the reaction step, the manner of feeding each reaction raw material is not particularly limited, and may be, for example, one-time feeding, batch feeding or dropwise feeding.

According to the present invention, the order of feeding the reaction raw materials in the reaction step is not particularly limited, and specific examples thereof include the order of feeding the phosphorus compound represented by the formula (I-A), the amine compound represented by the formula (I-B), the benzotriazole compound represented by the formula (I-C), and the aldehyde represented by the formula (I-D), and the feeding may be carried out in any order.

According to the present invention, the reaction step may be carried out in the presence of a diluent and/or a solvent, or may be carried out without using a diluent and/or a solvent.

According to the present invention, in the reaction step, for example, as the diluent, one or more selected from the group consisting of polyolefin, mineral base oil and polyether can be cited. The mineral base oil includes, for example, API group I, II, and III mineral lubricant base oils, more specifically, mineral lubricant base oils having a viscosity of 20 to 120 centistokes (cSt) at 40 ℃ and a viscosity index of at least 50, and still more specifically, mineral lubricant base oils having a viscosity of 28 to 110 centistokes (cSt) at 40 ℃ and a viscosity index of at least 80. Examples of the polyolefin include ethylene, propylene and C₄-C₁₀One or more of polyolefins obtained by homopolymerization of alpha-olefins or copolymerization of two or more of these olefins, preferably one or more of Polyalphaolefins (PAO) having a viscosity of 2 to 25 centistokes (cSt) at 100 ℃ (preferably having a viscosity of 6 to 10 centistokes (cSt) at 100 ℃). Wherein, as said C₄-C₁₀Examples of the α -olefin include n-butene, isobutene, n-pentene, n-hexene, n-octene, and n-decene. In addition, the number average molecular weight Mn of the polyolefins is generally from 500 to 3000, preferably from 500 to 2500, most preferably from 500 to 1500. Examples of the polyether include polymers obtained by reacting an alcohol with an epoxide. Examples of the alcohol includeEthylene glycol and/or 1, 3-propanediol. Examples of the epoxide include ethylene oxide and/or propylene oxide. In addition, the polyethers generally have a number average molecular weight Mn of from 500 to 3000, preferably from 700 to 3000, most preferably from 1000 to 2500. These diluents may be used alone or in combination of two or more.

According to the present invention, in the reaction step, for example, as the solvent, C may be mentioned_2-10Aliphatic nitriles (e.g. acetonitrile, etc.), C_6-20Aromatic hydrocarbons (e.g. benzene, toluene, xylene and cumene), C_6-10Alkanes (e.g. n-hexane, cyclohexane and petroleum ether), C_1-6Aliphatic alcohols (such as methanol, ethanol, n-propanol, isopropanol, n-butanol and ethylene glycol), C_2-20Halogenated hydrocarbons (such as dichloromethane, carbon tetrachloride, chlorobenzene and 1, 2-dichlorobenzene), C_3-10Ketones (e.g. acetone, butanone and methyl isobutyl ketone) or C_3-10Amides (such as dimethylformamide, dimethylacetamide and N-methylpyrrolidone) and the like. These solvents may be used alone or in combination of two or more.

According to a particular embodiment of the present invention, the diluent and/or solvent may be added at any stage of the reaction step in an amount conventional in the art, and is not particularly limited.

According to the invention, it is evident that said reaction step is generally carried out under protection of an inert gas atmosphere. Examples of the inert gas include nitrogen gas and argon gas, and are not particularly limited.

According to the present invention, after the end of the process for producing the benzotriazole derivative, the benzotriazole derivative is obtained by removing water and a solvent, if any, from the finally obtained reaction mixture by any conventionally known means. Accordingly, the present invention also relates to a benzotriazole derivative produced by the aforementioned method for producing a benzotriazole derivative of the present invention.

According to the present invention, by the aforementioned method for producing a benzotriazole derivative, a single benzotriazole derivative can be produced as a reaction product, or a mixture of a plurality of benzotriazole derivatives, or a mixture of one or more of the benzotriazole derivatives and the diluent (if used) can be produced. These reaction products are all intended for the present invention, and the difference in the form of their existence does not affect the achievement of the effects of the present invention. Accordingly, these reaction products are collectively referred to as benzotriazole derivatives without distinction in the context of this specification. In view of this, according to the present invention, there is no absolute necessity to further purify the reaction product or to further isolate a benzotriazole derivative of a specific structure from the reaction product. Of course, such purification or isolation is preferable for further improvement of the intended effect of the present invention, but is not essential to the present invention. As the purification or separation method, for example, the reaction product may be purified or separated by a column chromatography method, a preparative chromatography method or the like.

The benzotriazole derivatives of the present invention are particularly useful for the manufacture of or as antiwear agents, especially lubricating oil antiwear agents. The antiwear agent of the present invention not only has excellent extreme pressure antiwear performance, but also has one or more excellent performances of thermal oxidation stability, corrosion resistance, antirust performance and antifriction performance. According to a particularly preferred embodiment of the present invention, the anti-wear agent has not only excellent extreme pressure anti-wear properties but also excellent thermal oxidation stability, anti-corrosion properties, anti-rust properties and anti-friction properties.

According to the present invention, the anti-wear agent comprises any of the aforementioned benzotriazole derivatives of the present invention (or mixtures thereof in any proportion) or a benzotriazole derivative produced according to the aforementioned method for producing a benzotriazole derivative of the present invention.

According to the present invention, in order to manufacture the anti-wear agent, the aforementioned diluent or other components conventionally used in the art for manufacturing anti-wear agents may be further added to the benzotriazole derivative. In this case, the diluents may be used alone or in combination of two or more. Of course, if the benzotriazole derivatives of the present invention already contain a certain amount of the diluent after the preparation as described above, then the amount of the diluent added can be correspondingly reduced, and even used as an anti-wear agent without further addition of the diluent, as will be apparent to those skilled in the art.

In general, in the anti-wear agent of the present invention, the benzotriazole derivative accounts for 5% to 100%, preferably 30% to 90%, by mass of the total mass of the anti-wear agent.

According to the present invention, in order to manufacture the anti-wear agent, for example, the benzotriazole derivative, the diluent, and the other components (if used) may be mixed at 20 ℃ to 60 ℃ for 1h to 6h, without particular limitation.

Since the diluents used in the foregoing description of the present invention are also often used in the art as lubricant base oils in practice, they are directly classified as lubricant base oils in the following description and are not described separately as a separate component.

Examples

The present invention will be described in further detail with reference to examples, but the present invention is not limited to these examples.

The performance evaluation in examples and comparative examples was carried out as follows.

The dropping point is determined by a GB/T3498 method;

the cone penetration is measured by a GB/T269 method;

the oxidation stability is measured by SH/T0325 method;

the method for measuring the oil separation of the steel mesh adopts an SH/T0324 method;

the GB/T5018 method is adopted for measuring the corrosion resistance;

test for four-ball machine_B、P_DAdopting an SH/T0202 method;

the GB/T7326 method is adopted for measuring the corrosion performance of the copper sheet;

the SH/T0204 method is adopted for measuring the antiwear property.

TABLE 1 sources of raw materials

Name of raw materials	Manufacturer of the product
		500SN base oil	Yanshan petrochemical
150BS base oil	Shuanglong Co Ltd
		PAO6 synthetic hydrocarbon oil	Mobil Corp.
500SN base oil	Mobil Corp.
		Acetone (II)	LANGFANG CITY JINHAI CHEMICAL Co.,Ltd.
Phenothiazines	Henan Noxia chemical products Co., Ltd
		Sodium type organic bentonite	Bentonite plant of Cheng Li county Anji

Example 1

Under the protection of nitrogen, 34.47 g (90mmol) of N-hydrogenated tallow dipropylene triamine, 13.5 g (450mmol) of paraformaldehyde, 10.16 g (85mmol) of benzotriazole and 100mL of toluene were added to a 500mL four-necked flask equipped with a stirrer, a thermometer, a condenser and a water separator, rapidly stirred, heated to 100 ℃, and 48.4 g (200mmol) of di-N-butyl dithiophosphoric acid was added dropwise and reacted for 6 hours at constant temperature. And after the reaction is finished, distilling under reduced pressure to remove the solvent and residual water, cooling to room temperature, settling for 24 hours, filtering to remove impurities, and separating by column chromatography to obtain a final product, wherein the label is M-1.

Product characterization data were as follows:

1H NMR(300MHz，CDCl3)：δ0.88(3H)，1.03(12H)，1.06-1.91(53H)，2.34-3.46(10H)，3.54-4.57(12H)，5.23-6.11(2H)，7.19-8.08(4H)；

C₄₉H₉₆N₆O₄P₂S₄calcd for C57.50, H9.45, N8.21, O6.25, P6.05, S12.53; measurement value: c57.42, H9.43, N8.16, O6.35, P6.10, S12.54.

Preparing bentonite lubricating grease:

the raw material components are as follows: 500SN lubricating base oil 890g (viscosity at 100 ℃ C. of 10 mm)²S); 100g of sodium type organic bentonite; 20g of acetone; 5g (M-1) of a benzotriazole derivative; 5g of phenothiazine.

Adding 445 g of lubricating base oil into a grease making kettle and stirring; slowly adding 100g of sodium type organic bentonite into the mixture, and stirring the mixture to uniformly mix the mixture with lubricating base oil; heating to 40 ℃, adding 20g of acetone, and stirring for 60min until a lubricating grease structure is formed; heating to 60 deg.C, and maintaining for 20 min; adding 445 g of lubricating base oil, stirring and cooling, uniformly mixing, then adding 5g of benzotriazole derivative (M-1) and 5g of phenothiazine, and uniformly stirring; the fat is formed by grinding 2-3 times by a three-roll mill and is marked as Z-1.

Example 2

Under the protection of nitrogen, 34.47 g (90mmol) of N-hydrogenated tallow dipropylene triamine, 13.5 g (450mmol) of paraformaldehyde, 17.93 g (150mmol) of benzotriazole and 120mL of toluene were added to a 500mL four-necked flask equipped with a stirrer, a thermometer, a condenser and a water separator, rapidly stirred, heated to 100 ℃, and 24.2 g (100mmol) of di-N-butyl dithiophosphoric acid was added dropwise and reacted for 8 hours at a constant temperature. And after the reaction is finished, distilling under reduced pressure to remove the solvent and residual water, cooling to room temperature, settling for 24 hours, filtering to remove impurities, and separating by column chromatography to obtain a final product, wherein the label is M-2.

Product characterization data were as follows:

1H NMR(300MHz，CDCl3)：δ0.88(3H)，1.03-1.95(51H)，2.45-3.30(9H)，3.54-4.32(7H)，5.58-6.20(4H)，7.19-8.08(8H)；

C₄₇H₈₂N₉O₂PS₂calcd for C62.70, H9.18, N14.00, O3.55, P3.44, S7.12; measurement value: c62.81, H9.22, N13.85, O3.56, P3.41, S7.15.

Preparing bentonite lubricating grease:

the raw material components are as follows: 820g (100 ℃ viscosity: 31 mm) of 150BS lubricating base oil²S); 150g of sodium type organic bentonite; 23g of acetone; 10g (M-2) of a benzotriazole derivative; 20g of phenothiazine.

Adding 620 g of lubricating base oil into a grease making kettle and stirring; slowly adding 150g of sodium type organic bentonite into the mixture, and stirring the mixture to uniformly mix the mixture with lubricating base oil; heating to 50 ℃, adding 23g of acetone, and stirring for 60min until a lubricating grease structure is formed; heating to 75 deg.C, and maintaining for 20 min; adding 200g of lubricating base oil, stirring and cooling, adding 10g of benzotriazole derivative (M-2) and 20g of phenothiazine after uniformly mixing, and uniformly stirring; the fat is formed by grinding 2-3 times by a three-roll mill, and is marked as Z-2.

Example 3

Under the protection of nitrogen, 34.47 g (90mmol) of N-hydrogenated tallow dipropylene triamine, 13.5 g (450mmol) of paraformaldehyde, 10.16 g (85mmol) of benzotriazole and 100mL of toluene were added into a 500mL four-neck flask equipped with a stirrer, a thermometer, a condenser and a water separator, rapidly stirred, heated to 100 ℃, and 48.4 g (200mmol) of di-N-butyl dithiophosphoric acid was added dropwise and reacted for 6 hours at constant temperature. And after the reaction is finished, distilling under reduced pressure to remove the solvent and residual water, cooling to room temperature, settling for 24 hours, filtering to remove impurities, and separating by column chromatography to obtain a final product, wherein the label is M-3.

Product characterization data were as follows:

1H NMR(300MHz，CDCl3)：δ0.88(3H)，1.03(12H)，1.06-1.91(53H)，2.34-3.46(10H)，3.54-4.28(12H)，5.23-5.77(2H)，7.19-8.08(4H)；

C₄₉H₉₆N₆O₄P₂S₄calcd for C57.50, H9.45, N8.21, O6.25, P6.05, S12.53; measurement value: c57.62, H9.49, N8.13, O6.22, P6.09, S12.45.

Preparing bentonite lubricating grease:

the raw material components are as follows: 735g (viscosity at 100 ℃ C. of 6 mm) of PAO6 synthetic hydrocarbon lubricating base oil²S); 250g of sodium type organic bentonite; 30g of acetone; 5g of a benzotriazole derivative (M-3); 10g of phenothiazine.

Adding 500 g of lubricating base oil into a grease making kettle and stirring; slowly adding 250g of sodium type organic bentonite into the mixture, and stirring the mixture to uniformly mix the mixture with lubricating base oil; heating to 45 ℃, adding 30g of acetone, and stirring for 60min until a lubricating grease structure is formed; heating to 65 deg.C, and maintaining for 20 min; adding 235 g of lubricating base oil, stirring and cooling, adding 5g of benzotriazole derivative (M-3) and 10g of phenothiazine after uniformly mixing, and uniformly stirring; the fat is formed by grinding 2-3 times by a three-roll mill, and is marked as Z-3.

Example 4

In a 500ml four-neck flask equipped with a stirrer, a thermometer, a condenser and a water separator under a nitrogen atmosphere, 133.81 g (410mmol) of octadecylpropylenediamine and 25.8 g (860mmol) of paraformaldehyde, 55.89 g (380mmol) of 5-ethylbenzotriazole and 134.15 g (450mmol) of n-butyl 1-methylheptyl dithiophosphoric acid were added, stirred rapidly, and heated to 110 ℃ for reaction for 4 hours. And (3) after the reaction is finished, carrying out reduced pressure distillation to remove residual water, cooling to room temperature, settling for 24 hours, filtering to remove impurities, and carrying out column chromatography separation to obtain a final product, wherein the label is M-4.

Product characterization data were as follows:

¹H NMR(300MHz，CDCl₃)：δ0.88(6H)，1.03-1.93(57H)，2.43-2.74(8H)，3.46-4.10(4H)，4.24-4.63(2H)，5.31-6.20(2H)，7.19-7.82(3H)；

C₄₃H₈₂N₅O₂PS₂calcd for C64.86, H10.38, N8.80, O4.02, P3.89, S8.05; measurement value: c64.57, H10.05, N7.54, O4.37, P4.42, S9.05.

Preparing bentonite lubricating grease:

the raw material components are as follows: 770g (viscosity at 100 ℃ C. of 14 mm) of 150BS and 500SN mixed lubricating base oil²S); 200g of sodium type organic bentonite; 25g of acetone; 20g of a benzotriazole derivative (M-4); phenothiazine 10 g.

Adding 520 g of lubricating base oil into a grease making kettle and stirring; slowly adding 200g of sodium type organic bentonite into the mixture, and stirring the mixture to uniformly mix the mixture with lubricating base oil; heating to 45 ℃, adding 25g of acetone, and stirring for 60min until a lubricating grease structure is formed; heating to 70 deg.C, and maintaining for 20 min; adding 250g of lubricating base oil, stirring and cooling, adding 20g of benzotriazole derivative (M-4) and 10g of diphenylamine after uniformly mixing, and uniformly stirring; the fat is formed by grinding 2-3 times by a three-roll mill, and is marked as Z-4.

Example 5

Under the protection of nitrogen, 25.9 g (130mmol) of tertiary primary amine carbonate, 13.5 g (450mmol) of paraformaldehyde, 21.89 g (125mmol) of 6-butylbenzotriazole and 100mL of toluene are added into a 500mL four-neck flask provided with a stirrer, a thermometer, a condenser and a water separator, rapidly stirred, heated to 95 ℃, and added with 55.23 g (150mmol) of bis (2-ethylhexyl) dithiophosphoric acid dropwise for 5 hours at constant temperature. And after the reaction is finished, distilling under reduced pressure to remove the solvent and residual water, cooling to room temperature, settling for 24 hours, filtering to remove impurities, and separating by column chromatography to obtain a final product, wherein the label is M-5.

Product characterization data were as follows:

¹H NMR(300MHz，CDCl₃)：δ0.89(18H)，1.05-1.93(48H)，2.34-2.50(2H)，3.43-3.72(4H)，4.24-4.72(2H)，5.31-6.20(2H)，7.19-7.82(3H)；

C₄₂H₇₉N₄O₂PS₂calcd for C65.75, H10.38, N7.30, O4.17, P4.04, S8.36; measurement value: c64.50, H10.12, N7.43, O4.32, P4.57, S9.26.

Preparing bentonite lubricating grease:

the raw material components are as follows: 812g (viscosity at 100 ℃ C. of 10 mm) of 500SN lubricating base oil²S); 150g of sodium type organic bentonite; 26g of acetone; 8g of phenothiazine; 30g of a benzotriazole derivative (M-5);

adding 500 g of lubricating base oil into a grease making kettle and stirring; slowly adding 150g of sodium type organic bentonite into the mixture, and stirring the mixture to uniformly mix the mixture with lubricating base oil; heating to 40 ℃, adding 26g of acetone, and stirring for 60min until a lubricating grease structure is formed; heating to 60 deg.C, and maintaining for 20 min; adding 312 g of lubricating base oil, stirring and cooling, adding 8g of phenothiazine and 30g of benzotriazole derivative (M-5) after uniformly mixing, and uniformly stirring; grinding by three-roll mill for 2-3 times to obtain grease, and marking as Z-5.

Comparative example 1

Preparation of comparative grease:

a bentonite grease was prepared in accordance with the procedure of example 4, except that no benzotriazole derivative was added during the preparation. The resulting comparative grease was labeled DZ-1.

Comparative example 2

Under the protection of nitrogen, 35.04 g (130mmol) of octadecylamine, 9 g (300mmol) of paraformaldehyde, 29.78 g (250mmol) of benzotriazole and 100mL of toluene were added into a 250mL four-neck flask equipped with a stirrer, a thermometer, a condenser and a water separator, rapidly stirred, heated to 90 ℃ and reacted at constant temperature for 6 hours. And after the reaction is finished, distilling under reduced pressure to remove the solvent and residual water, cooling to room temperature, settling for 24 hours, and filtering to remove impurities to obtain the product, wherein the label is D-1.

Product characterization data were as follows:

¹H NMR(300MHz，CDCl₃)：δ0.88(3H)，1.25-1.51(32H)，3.27(2H)，5.55-6.24(4H)，7.19-8.08(8H)；

C₃₂H₄₉N₇calcd for C72.27, H9.29, N18.44; measurement value: c72.95, H10.32, N16.73.

Preparation of comparative grease:

a comparative grease was prepared as in example 4 except that the benzotriazole derivative used was D-1 and the resulting comparative grease was designated DZ-2.

The bentonite grease and the comparative grease prepared above were subjected to performance evaluation of dropping point, penetration, oxidation stability, steel mesh oil separation, corrosion resistance, four-ball machine test, copper sheet corrosion performance, and abrasion resistance, respectively, and the results are shown in table 2.

Table 2 grease performance evaluation

From the results in table 2, it can be seen that the bentonite grease of the present invention has a low friction coefficient, excellent anti-wear properties, extreme pressure properties, oxidation resistance, corrosion resistance, rust resistance, high temperature resistance, water resistance, adhesion, and colloid stability.

Claims

in the general formula (I), the radical R' is selected from C_1-25Hydrocarbyl radical, C_3-25A linear or branched heteroalkyl group and a hydrocarbyl group having a number average molecular weight Mn of 300-3000; n is an integer from 0 to 10; n radicals R₀Are the same or different from each other and are each independently selected from C_1-10A linear or branched alkylene group; n +2 groups A, which may be the same or different from each other, are each independently selected from the group consisting of hydrogen, a group represented by the formula (I-1), a group represented by the formula (I-2), C_1-25A hydrocarbon group and a hydrocarbon group having a number average molecular weight Mn of 300 to 3000, with the proviso that at least one of the n +2 groups A is a group represented by formula (I-1) and at least one of the n +2 groups A is a group represented by formula (I-2); when at least one of said groups A is C_10-25Straight or branched alkyl, C_10-25Linear or branched alkenyl or hydrocarbyl having a number average molecular weight Mn of from 300 to 3000, said group R' is optionally also hydrogen,

in the general formula (I-1) and the general formula (I-2), the group R₅And R₆Are the same or different from each other and are each independently selected from C_1-20A hydrocarbyl group; the groups X and Y, equal to or different from each other, are each independently selected from an oxygen atom and a sulfur atom; the two radicals R' are identical or different from each other and are each independently selected from hydrogen and C_1-20A hydrocarbyl group; radical R₁、R₂、R₃、R₄Are the same or different from each other and are each independently selected from hydrogen and C_1-20A hydrocarbon radical, said linear or branched heteroalkyl referring to a radical obtained by interrupting the carbon chain structure of a linear or branched alkyl radical by one or more hetero radicals selected from-O-, -S-and-NR-, wherein the radical R is selected from H and C_1-4Straight or branched chain alkyl.

2. Bentonite grease according to claim 1, characterized in that,

in the general formula (I), the radical R' is selected from C_10-25Straight or branched alkyl, C_10-25Straight-chain or branched alkenyl, C_10-25Straight-chain or branched alkynyl, C_10-25Linear or branched heteroalkyl groups and polyisobutenyl groups having a number average molecular weight Mn of from 300 to 3000; n is an integer from 0 to 5; n radicals R₀Are the same or different from each other and are each independently selected from C_2-5A linear or branched alkylene group; n +2 groups A, which may be the same or different from each other, are each independently selected from the group consisting of hydrogen, a group represented by the formula (I-1), a group represented by the formula (I-2), C_1-6Straight or branched alkyl, C_10-25Straight or branched alkyl, C_10-25Linear or branched alkenyl and polyisobutenyl having a number average molecular weight Mn of 300 to 3000;

in the general formula (I-1) and the general formula (I-2), the group R₅And R₆Are the same or different from each other and are each independently selected from C_1-15A linear or branched alkyl group; both groups X are sulfur atoms and both groups Y are oxygen atoms; the two radicals R' are identical or different from each other and are each independently selected from hydrogen and C_1-20A linear or branched alkyl group; radical R₁、R₂、R₃、R₄Are the same or different from each other and are each independently selected from hydrogen and C_1-10A linear or branched alkyl group;

the straight or branched heteroalkyl group means a group obtained by interrupting the carbon chain structure of the straight or branched alkyl group with 1 to 5 hetero groups selected from the group consisting of-O-, -S-, and-NR-.

3. Bentonite grease according to claim 1, characterized in that,

in the general formula (I), the radical R' is selected from C_10-25A linear or branched alkyl group; n is 0; n +2 groups A, which are the same or different from each other, are each independently selected from the group consisting of hydrogen, a group represented by the formula (I-1), a group represented by the formula (I-2) and C_1-4A linear or branched alkyl group;

in the general formula (I-1) and the general formula (I-2), the group R₅And R₆Are the same or different from each other and are respectively independentSelected from C_3-12A linear or branched alkyl group; the two radicals R' are identical or different from each other and are each independently selected from hydrogen and C_1-6A linear or branched alkyl group; r₁And R₄Are each hydrogen, R₂And R₃One of them is C_1-10Straight or branched chain alkyl, the other being hydrogen.

4. Bentonite grease according to claim 1, characterized in that in formula (I) the group R' is selected from C_1-20Hydrocarbyl and C_3-20Linear or branched heteroalkyl.

5. Bentonite grease according to claim 1, characterized in that the number average molecular weight Mn is between 500 and 2000.

6. Bentonite grease according to claim 1, characterized in that the number average molecular weight Mn is between 500 and 1500.

7. Bentonite grease according to claim 1, characterized in that the benzotriazole derivative is selected from the following specific compounds or mixtures of any two or more thereof:

8. the bentonite grease comprises the following components by taking the total weight of the grease as a reference: a benzotriazole derivative, bentonite, phenothiazine, and a major amount of a lubricating base oil, the benzotriazole derivative being produced by a method comprising the step of reacting a phosphorus compound represented by formula (I-A), an amine compound represented by formula (I-B), and a benzotriazole compound represented by formula (I-C) in the presence of an aldehyde represented by formula (I-D),

wherein the radical R' is selected from C_1-25Hydrocarbyl radical, C_3-25A linear or branched heteroalkyl group and a hydrocarbyl group having a number average molecular weight Mn of 300-3000; n is an integer from 0 to 10; n radicals R₀Are the same or different from each other and are each independently selected from C_1-10A linear or branched alkylene group; n +2 radicals A', equal to or different from each other, are each independently selected from hydrogen, C_1-25A hydrocarbyl group having a number average molecular weight Mn of from 300 to 3000, with the proviso that at least two of the n +2 groups A' represent hydrogen; when at least one of said groups A' is C_10-25Straight or branched alkyl, C_10-25The radical R' is optionally also hydrogen when a linear or branched alkenyl radical or a hydrocarbon radical having a number-average molecular weight Mn of from 300 to 3000; radical R₅And R₆Are the same or different from each other and are each independently selected from C_1-20A hydrocarbyl group; the groups X and Y, equal to or different from each other, are each independently selected from an oxygen atom and a sulfur atom; the radical R' is selected from hydrogen and C_1-20A hydrocarbyl group; radical R₁、R₂、R₃、R₄Are the same or different from each other and are each independently selected from hydrogen and C_1-20A hydrocarbon radical, said linear or branched heteroalkyl referring to a radical obtained by interrupting the carbon chain structure of a linear or branched alkyl radical by one or more hetero radicals selected from-O-, -S-and-NR-, wherein the radical R is selected from H and C_1-4Straight or branched chain alkyl.

9. Bentonite grease according to claim 8,

wherein the radical R' is selected from C_10-25Straight or branched alkyl, C_10-25Straight-chain or branched alkenyl, C_10-25Straight-chain or branched alkynyl, C_10-25Linear or branched heteroalkyl groups and polyisobutenyl groups having a number average molecular weight Mn of from 300 to 3000; n is an integer from 0 to 5; n radicals R₀Are the same or different from each other and are each independently selected from C_2-5Straight chain orA branched alkylene group; n +2 radicals A', equal to or different from each other, are each independently selected from hydrogen, C_1-6Straight or branched alkyl, C_10-25Straight or branched alkyl, C_10-25Linear or branched alkenyl and polyisobutenyl having a number average molecular weight Mn of 300 to 3000; radical R₅And R₆Are the same or different from each other and are each independently selected from C_1-15A linear or branched alkyl group; both groups X are sulfur atoms and both groups Y are oxygen atoms; the radical R' is selected from hydrogen and C_1-20A linear or branched alkyl group; radical R₁、R₂、R₃、R₄Are the same or different from each other and are each independently selected from hydrogen and C_1-10A linear or branched alkyl group;

10. Bentonite grease according to claim 8,

wherein the radical R' is selected from C_10-25A linear or branched alkyl group; n is 0; n +2 radicals A', equal to or different from each other, are each independently selected from hydrogen and C_1-4A linear or branched alkyl group; radical R₅And R₆Are the same or different from each other and are each independently selected from C_3-12A linear or branched alkyl group; the radical R' is selected from hydrogen and C_1-6A linear or branched alkyl group; r₁And R₄Are each hydrogen, R₂And R₃One of them is C_1-10Straight or branched chain alkyl, the other being hydrogen.

11. Bentonite grease according to claim 8, characterized in that in formula (I) the group R' is selected from C_1-20Hydrocarbyl and C_3-20Linear or branched heteroalkyl.

12. Bentonite grease according to claim 8, characterized in that the number average molecular weight Mn is between 500 and 2000.

13. Bentonite grease according to claim 8, characterized in that the number average molecular weight Mn is between 500 and 1500.

14. The bentonite grease as set forth in claim 8 wherein the reaction time of said reaction is from 0.1 to 24 hours and the reaction temperature of said reaction is from 0 to 250 ℃.

15. The bentonite grease according to claim 8, wherein the reaction time of the reaction is 0.5 to 6 hours and the reaction temperature of the reaction is 60 to 120 ℃.

16. The bentonite grease according to claim 8, wherein the molar ratio of the phosphorus compound represented by the formula (I-a) to the amine compound represented by the formula (I-B) is 1:0.1 to 10; the molar ratio of the phosphorus compound represented by the formula (I-A) to the benzotriazole compound represented by the formula (I-C) is 1: 0.1-10; the molar ratio of the phosphorus compound represented by the formula (I-A) to the aldehyde represented by the formula (I-D) is 1: 1-10.

17. The bentonite grease of claim 8, wherein the molar ratio of the phosphorus compound represented by the formula (I-a) to the amine compound represented by the formula (I-B) is 1:0.6 to 1.5; the molar ratio of the phosphorus compound represented by the formula (I-A) to the benzotriazole compound represented by the formula (I-C) is 1:0.6 to 1.5; the molar ratio of the phosphorus compound represented by the formula (I-A) to the aldehyde represented by the formula (I-D) is 1: 2-4.

18. The bentonite grease as set forth in any one of claims 1-17 wherein the benzotriazole derivative comprises from 0.01% to 10% by weight of the total mass of the bentonite grease; the bentonite accounts for 5-35% of the total mass of the bentonite lubricating grease; the phenothiazine accounts for 0.1-10% of the total mass of the bentonite lubricating grease; the lubricating base oil constitutes the main component of the bentonite grease.

19. Bentonite grease according to any of claims 1 to 17, characterized in that the benzotriazole derivative constitutes 0.1-5% of the total mass of the bentonite grease; the bentonite accounts for 10% -25% of the total mass of the bentonite lubricating grease; the phenothiazine accounts for 0.5-2% of the total mass of the bentonite lubricating grease; the lubricating base oil constitutes the main component of the bentonite grease.

20. The bentonite grease as set forth in any one of claims 1 to 17 wherein the bentonite is an organobentonite; the lubricating base oil is one or more of mineral oil, vegetable oil and synthetic oil.

21. The bentonite grease as set forth in any one of claims 1 to 17 wherein the bentonite is one or more of a sodium type, a potassium type, a calcium type and a magnesium type organobentonite; the lubricating base oil has a kinematic viscosity of 5-60mm at 100 DEG C²Lubricating base oil per second.

22. A method of preparing a bentonite grease as set forth in any one of claims 1 to 21 comprising: adding part of lubricating base oil and bentonite into a grease making kettle, uniformly mixing, adding a dispersing agent, and stirring until a lubricating grease structure is formed in the kettle; heating to 50-80 deg.C and maintaining for 10-30 min; adding the rest of the lubricating base oil, stirring and cooling, adding the benzotriazole derivative and phenothiazine as described in one of claims 1-21, stirring uniformly, and grinding into grease.