CN109576122A - Utilize the method for Zeolite-purification wine - Google Patents
Utilize the method for Zeolite-purification wine Download PDFInfo
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- CN109576122A CN109576122A CN201811629392.2A CN201811629392A CN109576122A CN 109576122 A CN109576122 A CN 109576122A CN 201811629392 A CN201811629392 A CN 201811629392A CN 109576122 A CN109576122 A CN 109576122A
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- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12H—PASTEURISATION, STERILISATION, PRESERVATION, PURIFICATION, CLARIFICATION OR AGEING OF ALCOHOLIC BEVERAGES; METHODS FOR ALTERING THE ALCOHOL CONTENT OF FERMENTED SOLUTIONS OR ALCOHOLIC BEVERAGES
- C12H1/00—Pasteurisation, sterilisation, preservation, purification, clarification, or ageing of alcoholic beverages
- C12H1/02—Pasteurisation, sterilisation, preservation, purification, clarification, or ageing of alcoholic beverages combined with removal of precipitate or added materials, e.g. adsorption material
- C12H1/04—Pasteurisation, sterilisation, preservation, purification, clarification, or ageing of alcoholic beverages combined with removal of precipitate or added materials, e.g. adsorption material with the aid of ion-exchange material or inert clarification material, e.g. adsorption material
- C12H1/0408—Pasteurisation, sterilisation, preservation, purification, clarification, or ageing of alcoholic beverages combined with removal of precipitate or added materials, e.g. adsorption material with the aid of ion-exchange material or inert clarification material, e.g. adsorption material with the aid of inorganic added material
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Abstract
The invention belongs to wine product processing technology fields, are related to a kind of method using Zeolite-purification wine.Method using Zeolite-purification wine of the invention, comprising the following steps: active modification is carried out to natural minerals zeolite using electromagnetic wave heating method, obtains activation modification zeolite；Activation modification zeolite is placed in wine, the harmful substance in sorbing liquor is carried out, obtains harmful substance by isolated wine.Harmful substance/impurity content in wine can be effectively reduced in the present invention, and adsorption effect is significant, and the wine product after absorption comply fully with the requirement of country and international standard, and product quality can be guaranteed, and easy to operate, easy to implement.
Description
Technical field
The invention belongs to wine product processing technology fields, in particular to a kind of method using Zeolite-purification wine.
Background technique
China is drinks production and consumption big country, and in recent years, drinks has become indispensable drink in people's daily life
The various drinks enormous amounts that product, China or even the whole world consume every year.Wherein, a conventional industries of the white wine as China, it is deep
Liked by compatriots, even to this day, liquor culture is still full of the various aspects in life, and relatives and friends meet, celebrate a festival with jubilation
Various occasions drink one, two glass of white wine unavoidably all to show and celebrate.In recent years, with the development of economy with living standards of the people
Improve, people are also higher and higher for the quality of alcohol product and the requirement of flavor, especially the white wine of high-quality be even more by
People greatly pay close attention to.
Wine is the mixture of a variety of chemical components, and water and ethyl alcohol are wherein most important ingredients.But in addition to this, exist
In the preparation process of wine, for example, white wine in brewing process, in addition to mainly generating ethyl alcohol, can also generate alcohol, aldehyde, ketone, acid, ester
Equal catabolites and its derivative, these substances may damage body.Various impurity can be also generated, including muddy
The suspension of turbid state；With the change of temperature, the solubility in white wine changes this suspension therewith, to influence mouthfeel
And visual effect.
The harmful substance of health is endangered since white wine can generate in making and blending, such as manganese, lead, methanol, first
Aldehyde, light dydrocarbon, free radical, solid content, plasticiser etc..Thus in the production process of white wine, it should increase and white wine harmful substance is contained
The control of amount；It is very heavy that harmful substance or the technique of impurity in the effective removal white wine of one kind are found for liquor-making enterprises
It wants.Although there are some physics and chemical method to be used to remove harmful substance/impurity in white wine at present, but still there are some
Problem, such as removal effect are unobvious, complicated for operation, and technical requirements are high, and some chemical methodes, which may introduce, new toxic to be had
The problems such as evil substance or impurity, risk is larger, brings environmental pollution, higher cost.
In consideration of it, the present invention is specifically proposed.
Summary of the invention
It is an object of the present invention to provide a kind of methods using Zeolite-purification wine, and simple process is easy to implement, peace
Atoxic, it is not high for the technical requirements of equipment and operator, the harmful substance in wine can be effectively removed, treatment effect is aobvious
It writes.
It handles to obtain using the method using Zeolite-purification wine it is another object of the present invention to provide a kind of
Wine, the requirement of country and GB standard is complied fully with using the purified wine of the method for the present invention, product quality can be protected
Card.
To achieve the above object, the technical solution adopted by the present invention are as follows:
According to an aspect of the present invention, the present invention provides a kind of method using Zeolite-purification wine, comprising the following steps:
Active modification is carried out to natural minerals zeolite using electromagnetic wave heating method, obtains activation modification zeolite；
Activation modification zeolite is placed in wine, the harmful substance in sorbing liquor is carried out, obtains harmful substance by isolated wine.
As further preferred technical solution, the wine includes at least one of beer, white wine, fruit wine and yellow rice wine；
Preferably, the wine is white wine.
As further preferred technical solution, the natural minerals zeolite includes clinoptilolite, analcime, laumontite, water chestnut
At least one of zeolite, phillipsite, heulandite, sodalite, modenite and faujasite；
Preferably, the natural minerals zeolite is natural minerals clinoptilolite.
As further preferred technical solution, the electromagnetic wave heating includes: that electromagnetic wave heating is extremely in 0.5~50 second
300~600 DEG C；
Preferably, the electromagnetic wave heating include: in 1~30 second electromagnetic wave heating to 400~500 DEG C.
As further preferred technical solution, the electromagnetic wave heating includes: the zeolite knot when electromagnetic wave is by Zeolite absorption
The crystallization water rapid oscillation of 10~15% contained in structure, phase mutual friction, increase water temperature rapidly, to be heated.
As further preferred technical solution, active modification packet is carried out to natural minerals zeolite using electromagnetic wave heating method
It includes: the natural minerals zeolite being activated using the microwave of frequency consecutive variations between 1000~5000MHz, locate
The reason time is 20~45min.
As further preferred technical solution, the granularity of the activation modification zeolite is 2~200 mesh；
Preferably, the granularity of the activation modification zeolite is 4~100 mesh.
As further preferred technical solution, the mass ratio of activation modification zeolite and wine is 1:0.8~1:20, preferably 1:
1~1:10；
Preferably, the temperature of absorption is 20~35 DEG C, preferably 24~28 DEG C；
Preferably, the time of absorption is 10~200h, preferably 60~120h.
As further preferred technical solution, the harmful substance include heavy metal, formaldehyde, methanol, light dydrocarbon, sulfide,
At least one of plasticiser, free radical, solid content and O-phthalic acids；
Preferably, the heavy metal includes at least one of manganese, lead, mercury, chromium and arsenic.
According to another aspect of the present invention, the present invention also provides a kind of using above-described using Zeolite-purification wine
The wine that method is handled；
Preferably, the wine is white wine.
Compared with prior art, the beneficial effects of the present invention are:
1, the method provided by the invention using Zeolite-purification wine, using electromagnetic wave heating method to natural minerals zeolite into
Row active modification, greatly improves the absorption property of zeolite, and large amount of adsorption has high efficiency of additive capability, also improves zeolite
Ion-exchange performance, and then apply harmful substance or impurity in sorbing liquor etc. unnecessary in zeolite after activation modification
Ingredient can be effectively reduced harmful substance/impurity content in wine, and adsorption effect is significant, and the wine product after absorption comply fully with
The requirement of country and international standard, product quality can be guaranteed.
2, method of the invention is not high to equipment requirement, technical threshold is low, easy to operate, small investment, at low cost, safety collar
It protects, economy and facility effectively reduces injury of the harmful substance to human body in wine, improves the quality and taste of wine.
Detailed description of the invention
It, below will be to specific in order to illustrate more clearly of the specific embodiment of the invention or technical solution in the prior art
Embodiment or attached drawing needed to be used in the description of the prior art be briefly described, it should be apparent that, it is described below
Attached drawing is some embodiments of the present invention, for those of ordinary skill in the art, before not making the creative labor
It puts, is also possible to obtain other drawings based on these drawings.
Fig. 1 is the adsorbance of harmful substance and time in activation modification clinoptilolite sorbing liquor in the embodiment of the present invention 1
Relation schematic diagram (abscissa is time month, day in figure, and ordinate is adsorbance)；
Fig. 2 is the adsorbance of harmful substance and the relationship of time in natural clinoptilolite sorbing liquor in comparative example 1 of the present invention
Schematic diagram.
Specific embodiment
Embodiment of the present invention is described in detail below in conjunction with embodiments and examples, but this field skill
Art personnel will be understood that following embodiments and embodiment are merely to illustrate the present invention, and are not construed as limiting model of the invention
It encloses.Based on the embodiments of the present invention, obtained by those of ordinary skill in the art without making creative efforts
Every other embodiment, shall fall within the protection scope of the present invention.The person that is not specified actual conditions, according to normal conditions or manufacturer builds
The condition of view carries out.
In a first aspect, providing a kind of method using Zeolite-purification wine at least one embodiment, comprising the following steps:
Active modification is carried out to natural minerals zeolite using electromagnetic wave heating method, obtains activation modification zeolite；
Activation modification zeolite is placed in wine, the harmful substance in sorbing liquor is carried out, obtains harmful substance by isolated wine.
The harmful substance of health is endangered since wine such as white wine can generate in making and blending, is examined through relevant department
The content of harmful substance is surveyed up to a variety of, wherein content is higher endangers that health is biggish manganese, lead, mercury, arsenic, methanol, first
Aldehyde, carbon 5, free radical, solid content, sulphur, O-phthalic acids, plasticiser etc..In consideration of it, the invention proposes a kind of pair of wine to carry out
Purification, can effectively remove or reduce the content of above-mentioned harmful substance in wine, also the reservation original flavor of wine product, and wine product
Quality and taste increase, and are more in line with consumer demand.
Method of the invention first carries out active modification to natural minerals zeolite using electromagnetic wave heating method, greatly mentions
The high absorption property of zeolite, large amount of adsorption have high efficiency of additive capability, also improve the ion-exchange performance of zeolite, in turn
Zeolite after activation modification is applied to the unnecessary ingredients such as harmful substance or the impurity in sorbing liquor, can be effectively reduced wine
In harmful substance/impurity content, adsorption effect is significant, and wine product after absorption comply fully with country and international standard is wanted
It asks, product quality can be guaranteed.
Preparation process of the present invention is simple, and obtained activation modification zeolite is nontoxic, tasteless, pollution-free, for harmful in wine
Substance/impurity has higher selectivity and ion-exchange capacity, i.e., imitates to harmful substance/impurity Adsorption in wine in wine
Fruit is significant.Also, this method small investment, easy to operate, economically feasible, natural zeolite low in raw material price, processing cost are low.
In addition, method of the invention is not high to equipment requirement, technical threshold is low, easily operated, safety and environmental protection is economical easy
Row, effectively reduces injury of the harmful substance to human body in wine, improves the quality and taste of wine, large batch of can produce,
Meets the needs of market.
It is understood that above-mentioned harmful substance, impurity are unnecessary ingredient in wine, human health may be caused
Certain injury, it is also possible to it affects to the quality of wine, and method of the invention can effectively remove or reduce this
The content of a little unnecessary ingredients, improves the quality and taste of wine.
In a preferred embodiment, the wine includes at least one of beer, white wine, fruit wine and yellow rice wine；
Preferably, the wine is white wine.
It, can be effectively in Adsorption white wine it is understood that method of the invention is mainly used in the purification to white wine
Harmful substance, but it is not limited to this, for other drinks, contains as the harmful substance in yellow rice wine, fruit wine can also reduce it
Amount.It is mainly described in further detail by taking white wine as an example below the present invention, but those skilled in the art should be understood that
, this method is also applied for other kinds of drinks.
In a preferred embodiment, the natural minerals zeolite includes clinoptilolite, analcime, laumontite, water chestnut
At least one of zeolite, phillipsite, heulandite, sodalite, modenite and faujasite；
Preferably, the natural minerals zeolite is natural minerals clinoptilolite.
Zeolite is a kind of aluminium silicate salt natural minerals of rack-like structure, and inside hole and channel containing there are many have
The excellent physical and chemical performances and good environment attribute such as ion exchange, efficient selective absorption and catalysis.The lattice of zeolite is basic
On be made of silica and aluminium oxide.Also up to tens kinds of the type for the natural zeolite having now been found that, and it is therein a variety of
Application of the zeolite in the fields such as catalyst or carrier, soil conditioner, sewage-treating agent is increasingly subject to the attention of people.
Wherein, natural clinoptilolite is the big and distributed more widely a kind of nonmetallic minerals of china natural resources amount, is rack-like, aqueous
Alkali or alkaline earth metal aluminosilicate mineral.Clinoptilolite is a kind of natural special zeolite, by lake water or
Vitreous volcanics is converted into crystal structure to be formed in seawater.The basic unit of clinoptilolite crystal structure is silicon
(aluminium) oxygen tetrahedron.Clinoptilolite is from a wealth of sources, cheap.Activation modification zeolite in the present invention is preferably naturally tiltedly to send out
Zeolite is activation modification clinoptilolite obtained from raw material is modified, and but it is not limited to this, mainly tiltedly to send out below the present invention
Be described in further detail for zeolite, but those skilled in the art it should be appreciated that, the activation modifying method
It is equally applicable to the modification of other types part zeolite.
However, natural clinoptilolite haves the shortcomings that composition differs greatly, quality is uncontrollable, adsorbance is lower, thus need
Natural clinoptilolite is modified.What existing clinoptilolite method of modifying mostly used is addition surface modifier or chemistry
On the one hand the modes such as auxiliary agent are chosen suitable surface modifier and are not easy to, existing common surface modifier can not have
Effect improves the adsorption capacity of clinoptilolite；On the other hand, surface modifier is also easy to fall off and loses effect, is difficult to make surface living
Property agent and clinoptilolite effectively combine, thus practical application effect and bad.Due to the limitation of technology, so far, for oblique
The research of ptilolite activation modification remains in foundation phase, up for further excavating.
Based on this, the present invention breaks the confinement of those skilled in the art's conventional thought, off the beaten track, creatively provides
Active modification is carried out to natural minerals zeolite using electromagnetic wave heating method, and obtained activation modification clinoptilolite is applied
In white wine, for adsorbing the harmful substance in white wine, adsorption effect is significant, and it is bad to alleviate existing clinoptilolite modified effect
And in the prior art in white wine harmful substance removal effect is bad, can introduce new poisonous and harmful substance or impurity, risk compared with
Greatly, the problems such as trivial operations.
In a preferred embodiment, the electromagnetic wave heating includes: that electromagnetic wave heating is extremely in 0.5~50 second
300~600 DEG C；
Preferably, the electromagnetic wave heating include: in 1~30 second electromagnetic wave heating to 400~500 DEG C；
Preferably, the electromagnetic wave heating include: in 1~10 second electromagnetic wave heating to 450~500 DEG C.
Activation modification is carried out to clinoptilolite using electromagnetic wave or microwave heating technique, zeolite can be made to add in several seconds
Heat arrives several hundred degrees Celsius, quickly activates to zeolite, can not only save the energy and processing time, can also effectively mention
The absorption property of high zeolite.
In a preferred embodiment, the electromagnetic wave heating includes: the zeolite knot when electromagnetic wave is by Zeolite absorption
The crystallization water rapid oscillation of 10~15% contained in structure, phase mutual friction, increase water temperature rapidly, to be heated.The present invention
10~15% crystallization water contained in zeolite structured is mainly utilized, heating heating carries out active modification to zeolite.
In a preferred embodiment, active modification packet is carried out to natural minerals zeolite using electromagnetic wave heating method
It includes: the natural minerals zeolite being activated using the microwave of frequency consecutive variations between 1000~5000MHz, locate
The reason time is 20~45min；
Preferably, using frequency between 1000~5000MHz consecutive variations microwave to the natural minerals zeolite into
Row is activated, and the processing time is 25~35min.Compared to existing method of modifying need one hour or more the processing time and
Speech, present invention reduces the processing times, improve treatment effeciency, also save energy consumption and processing cost.
It should be noted that the present invention is not particularly limited used microwave frequency, in thousands of MHz frequency models
Enclose it is interior handled, can be regulated and controled according to the actual situation by those skilled in the art.
Present invention application electromagnetic wave heating technology is to natural minerals clinoptilolite activation modification.Further speaking:
During activation modification, generate electromagnetic wave magnetron be powered after voltage instantaneous increase to several kilovolts of high pressure,
Magnetron continuously generates electromagnetic wave under the excitation of high voltage power supply, and zeolite electromagnetic wave absorption energy in electromagnetic wave field makes itself to add
Heat.It is to convert electric energy into electromagnetic wave by magnetron that electromagnetic wave itself, which does not generate thermal energy, is worn with the frequency of oscillation of several kilovolts of MHz
Saturating zeolite, when electromagnetic wave is by Zeolite absorption, it is zeolite structured in containing 10~15% the crystallization water, these crystallization water category polarity point
Son can be attracted by electromagnetic wave, and with tens speed quick oscillations each second, acceleration molecular operating is and adjacent intermolecular
Mutually shield friction, and then increase water temperature rapidly.It heats in this way, electromagnetic wave is directed through zeolite and rises rapidly from inside to outside
Temperature, so quick heating, height, and uniformly.And then the time of the energy and heating can greatly be saved.
In practical operation, it can be controlled zeolite by temperature control device and be reached needed different time and different temperatures.
It should be understood that the content being not described in detail in the explanation of above-mentioned activation modifying method, is art technology
The Common Parameters that personnel are readily apparent that, therefore can be omitted detailed description thereof.
In a preferred embodiment, the granularity of the activation modification zeolite is 2~200 mesh；
Preferably, the granularity of the activation modification zeolite is 4~100 mesh；
Preferably, the granularity of the activation modification zeolite is 4~60 mesh.
The granularity of suitable activation modification zeolite helps to improve adsorption effect, and convenient for operation and post-processing.This
In invention, the granularity of activation modification zeolite is typical but non-limiting for example can be 2 mesh, 3 mesh, 4 mesh, 5 mesh, 6 mesh, 7 mesh,
8 mesh, 9 mesh, 10 mesh, 12 mesh, 14 mesh, 15 mesh, 16 mesh, 18 mesh, 20 mesh, 30 mesh, 40 mesh, 50 mesh, 55 mesh, 60 mesh, 70 mesh, 80
Mesh, 90 mesh, 100 mesh, 150 mesh or 200 mesh.
In a preferred embodiment, the mass ratio of activation modification zeolite and wine be 1:0.8~1:20, preferably 1:
1~1:10, further preferably 1:1~1:5；It is typical but unrestricted, the mass ratio of activation modification zeolite and wine for example 1:
0.8,1:1,1:1.5,1:2,1:3,1:4,1:5,1:6,1:7,1:8,1:9,1:10,1:12,1:15,1:18 or 1:20.
Preferably, the temperature of absorption is 20~35 DEG C, preferably 24~28 DEG C；Present invention spy no for the temperature of absorption
Different limitation, is adsorbed at room temperature；Typical but unrestricted, the temperature of absorption for example can be 20 DEG C, 22 DEG C, 24
DEG C, 25 DEG C, 26 DEG C, 28 DEG C, 30 DEG C, 32 DEG C, 34 DEG C or 35 DEG C.
Preferably, the time of absorption is 10~200h, preferably 60~120h.It is understood that adsorption time is not easy
Too short or too long, adsorption time is too short, and the harmful substance that zeolite cannot completely in sorbing liquor, adsorption capacity fails to reach best
Value, adsorption effect are bad；Adsorption time is too long, and adsorption capacity is increased unobvious, reduces production efficiency.It thus needs to control to inhale
The attached time is within the appropriate range, typical but unrestricted, the time of absorption for example can for 10h (hour), 12h, 18h,
20h、24h、30h、36h、40h、48h、60h、72h、80h、90h、100h、110h、120h、130h、140h、150h、160h、
170h, 180h, 190h or 200h.
Harmful substance in method or application modified active zeolite Adsorption white wine using Zeolite-purification wine of the invention
Method, easy to operate, only the active modification zeolite that need to will obtain, is added in the container for being loaded with wine according to a certain percentage,
Standing adsorption is carried out, without complicated, expensive processing equipment, the operation of technical staff is required also not high, it is also desirable to
Many and diverse post-processing, it is safe and efficient, environmentally friendly.For adsorbing heavy metals and the harmful methanol, first such as lead, mercury, manganese in white wine
The compound effects such as aldehyde, carbon 5, free radical, sulfide are significant, and the white wine after absorption complies fully with country and international standard.The party
Method meets the needs of market, it is easier to realize that industrially scalable metaplasia produces.
Method of the invention can adsorb multiple harmful substances middle in white wine, and adsorption effect is significant.In one kind
In preferred embodiment, the harmful substance include but is not limited to heavy metal, formaldehyde, methanol, light dydrocarbon, sulfide, plasticiser,
At least one of free radical, solid content and O-phthalic acids；
Preferably, the heavy metal includes but is not limited at least one of manganese, lead, mercury, chromium and arsenic.
The harmful substance in Adsorption wine is carried out using activation modification zeolite of the invention, mainly there is following spy
Point:
(1) zeolite absorption property is greatly improved
The polarity and electronegativity that zeolite is changed by activation modification, improve the absorption property of zeolite, largely
It is upper improve to the compounds such as sulfide, oxide, chloride, alkanes, phenols, benzene class, methanol, formaldehyde, carbon 5 and heavy metal lead,
The absorption of mercury, chromium, manganese, arsenic etc..Molecule in duct hole in activation modification zeolite is adsorbed by various aspects hole wall surface
The effect of power just generates the superposition of hole wall field, forms the super effect of holes, inhale the molecule being adsorbed firmly once entering hole
It is attached.Activation modification zeolite not only has very big dispersion adsorption capacity, but also there are also biggish electrostatic force.Activation modification zeolite is because coloured
The collective effect of adsorption capacity and electrostatic force is dissipated, therefore its adsorption capacity is especially powerful, so as to low concentration, the polarity of High Temperature And Velocity
Fluid still has stronger suction-operated.
(2) absorption of zeolite selectivity
The unique crystalline network structures of zeolite have fixed hole duct,It (angstrom is length unit, 1 milli
Rice is equal to 10,000,000 angstroms).And the hole duct after activation modification can be expanded toIt is less thanIt is greater than
Molecule, ion kept outside of the door, molecule, the ion being of moderate size are adsorbed, and more targeted can carry out selection absorption.
Compared to silica gel, activated alumina, active carbon all adsorbent materials, fixed uniform hole, pore diameter range do not change very greatly, such as
The pore size of silica gel fromActivated alumina Between differ, therefore sized molecules are all
Can enter its hole, without sieve performance, and adsorb it is not close, unlike zeolite adsorb it is secured, once molecule enters
It is banned solid in hole, it will not be discharged without processing.
(3) zeolite large amount of adsorption, efficient absorption
After activation modification, the original duct of zeolite, hole are expanded, is madeMolecular/ionic can be inhaled
Attached entrance, the species for increasing adsorption capacity and being adsorbed.In addition, crystallization of zeolites water is discharged, molten product is increased, compares table
Product increases to 2000m2/ g, the zeolite of a grain of rice size have than table product it is so big so that its adsorption capacity with super strength,
Greatly improve the adsorbance of zeolite.
Activation modification zeolite has high efficiency of additive capability, especially in a liquid；And active carbon and active carbon product, silica gel,
Adsorbance can strongly reduce after the full conjunction of activated alumina water suction.Water suction is full close after active carbon and its product adsorption capacity can under
Drop 73.4%, adsorption rate is only the 1/7 of dry activated carbon, and the zeolite after activation modification is hardly affected by humidity, evident
The superiority of zeolite efficient absorption is shown.Zeolite molecular sieve or unique high-temperature adsorbing agent, on silica gel, activated alumina temperature
Adsorption capacity can almost be lost by being raised to 100 DEG C, and activation modification zeolite does not influence to adsorb at 100 DEG C, also at 150 DEG C
50% or more adsorption capacity.
(4) zeolite ion switching performance is greatly improved
Another important performance of activation modification zeolite is reversible cationic exchange.The ion-exchange performance of zeolite is main
With it is zeolite structured in the height of silica alumina ratio, the size in hole of zeolite it is related.Zeolite after activation modification of the present invention, changes
Silica alumina ratio in zeolite structured.Silicon is replaced by aluminium in zeolite, that is, the oxygen-octahedron electrically neutralized, by the alumina of negative one valence
Tetrahedron replaces, and the remaining oxygen in each valence is made negative electrical charge occur.In order to neutralize these negative electrical charges it is necessary to there is cationic addition,
And then metal cation, lead, manganese, the mercury etc. in wine solution will be switched in the structure of zeolite and firmly be prohibited admittedly.
(5) the harmful substance significant effect in sorbing liquor
Activation modification zeolite is nontoxic, tasteless, pollution-free, has excellent performance, and can be effectively reduced harmful substance/impurity in wine
Content, adsorption effect is significant, and the wine product after absorption comply fully with the requirement of country and international standard, and product quality can obtain
Guarantee.
Second aspect is provided handled using the above-described method using Zeolite-purification wine at least one embodiment
Obtained wine；
Preferably, the wine is white wine.
Silicon harmful substance contents are extremely low in treated by means of the present invention wine, and adsorption effect is obvious, reduces wine
Injury of the middle harmful substance to human body improves the quality and taste of wine.
Combined with specific embodiments below, comparative example and attached drawing, the invention will be further described.
Embodiment 1
A method of utilizing Zeolite-purification wine, comprising the following steps:
Active modification is carried out to natural minerals clinoptilolite using electromagnetic wave heating method, activation modification is obtained and tiltedly sends out boiling
Stone；
Activation modification clinoptilolite is placed in white wine, the harmful substance in absorption white wine is carried out, obtains harmful substance quilt
Isolated wine.
Wherein, electromagnetic wave heating include: when electromagnetic wave is by Zeolite absorption, contain in clinoptilolite structure 10~15%
Crystallization water rapid oscillation, phase mutual friction, increase water temperature rapidly, to be heated；Electromagnetic wave heating is extremely i.e. in 1~10 second
450~500 DEG C；Used electromagnetic wave be frequency consecutive variations between 1000~5000MHz microwave, processing the time be
30min；The granularity of activation modification clinoptilolite is 50 mesh.
The mass ratio of activation modification clinoptilolite and white wine is 1:1；The temperature of absorption is 25 DEG C；The time of absorption is 6 days
(144h)。
Comparative example 1
A method of using Zeolite-purification wine, the difference from embodiment 1 is that:
Harmful substance in sorbing liquor is carried out using natural minerals clinoptilolite, that is, is directlyed adopt natural non-modified
Zeolite is adsorbed.
The adsorbance of natural zeolite in modified zeolite and comparative example 1 in embodiment 1 is measured, i.e. experimentation
Middle timing weighs the increased weight of zeolite institute, as adsorbance of the zeolite to harmful substance.
Fig. 1 shows in embodiment 1 adsorbance of harmful substance and the pass of time in activation modification clinoptilolite sorbing liquor
It is schematic diagram；Fig. 2 shows that the adsorbance of harmful substance and the relationship of time are shown in natural clinoptilolite sorbing liquor in comparative example 1
It is intended to.As can be seen that the clinoptilolite using non-modified processing is adsorbed from Fig. 1 and Fig. 2, adsorption capacity maximum is only
It can achieve 3.5g/100g or so, and the activation modification clinoptilolite after activation modification of the invention used to be adsorbed, inhale
Attached capacity maximum only can achieve 12.1g/100g, greatly improve absorption property.
And the reason that the absorption property of non-modified zeolite is smaller, adsorption effect is poor includes: the hole of (1) crystal structure
Cavities road is smallerThe molecular/ionic diameter of selective absorption substance is greater thanBy difficulty of keeping outside of the door
It has sucked.(2) crystallization water in crystal containing 10~15% occupies the space in hole, duct, and molten product is reduced, and influences a large amount of ions
Into.(3) only to polar molecule/ion affinity, i.e., only polar molecule/ion is easily inhaled, such as lead, manganese, mercury a huge sum of money
Belong to ion, though may be inhaled into, not big enough the sucking of volume is limited；The impurity such as methanol, formaldehyde, carbon 5 are nonpolar molecules, even more
It is difficult to be inhaled into removal.
Embodiment 2
A method of using Zeolite-purification wine, the difference from embodiment 1 is that:
Wherein, in electromagnetic wave heating, the processing time is 25min；The granularity of activation modification clinoptilolite is 4 mesh.
The mass ratio of activation modification clinoptilolite and white wine is 1:2；The temperature of absorption is 26 DEG C；The time of absorption is
120h。
Embodiment 3
A method of using Zeolite-purification wine, the difference from embodiment 1 is that:
Wherein, in electromagnetic wave heating, the processing time is 35min；The granularity of activation modification clinoptilolite is 10 mesh.
The mass ratio of activation modification clinoptilolite and white wine is 1:5；The temperature of absorption is 24 DEG C；The time of absorption is
160h。
Embodiment 4
A method of using Zeolite-purification wine, the difference from embodiment 1 is that:
Wherein, in electromagnetic wave heating, the processing time is 40min；The granularity of activation modification clinoptilolite is 60 mesh.
The mass ratio of activation modification clinoptilolite and white wine is 1:10；The temperature of absorption is 28 DEG C；The time of absorption is
100h。
The maximum adsorption capacity of activation modification clinoptilolite in embodiment 1-4 is respectively 12.1g/100g, 11.5g/
100g, 12.8g/100g and 11.0g/100g.
Finally, it should be noted that the above embodiments are only used to illustrate the technical solution of the present invention., rather than its limitations；To the greatest extent
Pipe present invention has been described in detail with reference to the aforementioned embodiments, those skilled in the art should understand that: its according to
So be possible to modify the technical solutions described in the foregoing embodiments, or to some or all of the technical features into
Row equivalent replacement；And these are modified or replaceed, various embodiments of the present invention technology that it does not separate the essence of the corresponding technical solution
The range of scheme.
Claims (10)
1. a kind of method using Zeolite-purification wine, which comprises the following steps:
Active modification is carried out to natural minerals zeolite using electromagnetic wave heating method, obtains activation modification zeolite；
Activation modification zeolite is placed in wine, the harmful substance in sorbing liquor is carried out, obtains harmful substance by isolated wine.
2. the method according to claim 1 using Zeolite-purification wine, which is characterized in that the wine include beer, white wine,
At least one of fruit wine and yellow rice wine；
Preferably, the wine is white wine.
3. the method according to claim 1 using Zeolite-purification wine, which is characterized in that the natural minerals zeolite includes
In clinoptilolite, analcime, laumontite, chabasie, phillipsite, heulandite, sodalite, modenite and faujasite
It is at least one；
Preferably, the natural minerals zeolite is natural minerals clinoptilolite.
4. the method according to claim 1 using Zeolite-purification wine, which is characterized in that the electromagnetic wave heating includes:
Electromagnetic wave heating is to 300~600 DEG C in 0.5~50 second；
Preferably, the electromagnetic wave heating include: in 1~30 second electromagnetic wave heating to 400~500 DEG C.
5. the method according to claim 1 using Zeolite-purification wine, which is characterized in that the electromagnetic wave heating includes:
When electromagnetic wave is by Zeolite absorption, it is zeolite structured in contain 10~15% crystallization water rapid oscillation, phase mutual friction, make water temperature
It increases rapidly, to be heated.
6. the method according to claim 1 using Zeolite-purification wine, which is characterized in that use electromagnetic wave heating method pair
It includes: the microwave of the consecutive variations between 1000~5000MHz using frequency to described that natural minerals zeolite, which carries out active modification,
Natural minerals zeolite is activated, and the processing time is 20~45min.
7. described in any item methods using Zeolite-purification wine according to claim 1~6, which is characterized in that the activation changes
Property zeolite granularity be 2~200 mesh；
Preferably, the granularity of the activation modification zeolite is 4~100 mesh.
8. described in any item methods using Zeolite-purification wine according to claim 1~6, which is characterized in that activation modification boiling
The mass ratio of stone and wine is 1:0.8~1:20, preferably 1:1~1:10；
Preferably, the temperature of absorption is 20~35 DEG C, preferably 24~28 DEG C；
Preferably, the time of absorption is 10~200h, preferably 60~120h.
9. described in any item methods using Zeolite-purification wine according to claim 1~6, which is characterized in that the nuisance
Matter include in heavy metal, formaldehyde, methanol, light dydrocarbon, sulfide, plasticiser, free radical, solid content and O-phthalic acids at least
It is a kind of；
Preferably, the heavy metal includes at least one of manganese, lead, mercury, chromium and arsenic.
10. the wine handled using the method according to any one of claims 1 to 9 using Zeolite-purification wine；
Preferably, the wine is white wine.
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