CN109568177A

CN109568177A - A kind of combination product and its use and preparation method

Info

Publication number: CN109568177A
Application number: CN201710895797.XA
Authority: CN
Inventors: 孙颖浩
Original assignee: Shanghai Krypton Li Long Technology Development Co Ltd
Current assignee: Shanghai Krypton Li Long Technology Development Co Ltd
Priority date: 2017-09-28
Filing date: 2017-09-28
Publication date: 2019-04-05
Also published as: WO2019062623A1

Abstract

A kind of purposes the present invention relates to combination product containing pretreatment fluid and dye cream, the method and the combination product that make and use the combination product for hair dyeing, wherein the combination product includes pretreatment fluid and dye cream, the pretreatment fluid is made of cationic polymer, and the dye cream includes polymer polysaccharides, vaseline and dyestuff or is made of them, the dyestuff is selected from that lemon yellow, famille rose, brilliant blue, CB-2, alkalinity is red 5, Indian yellow 2 and combinations thereof.

Description

A kind of combination product and its use and preparation method

Technical field

The present invention relates to a kind of combination product containing pretreatment fluid and dye cream, make and use the side of the combination product The purposes of method and the combination product for hair dyeing.

Background technique

Hair most surface layer is epidermis squama, and the inside is cortical cell, and hair centre is medula.Among cell It is keratin together bonded to each other.Each cell forms keratin fiber element along hair stem, the spot in cellulose For melanin granule.The color of hair is exactly formd by them.Inorganic hair dye currently on the market is mainly leaded, iron, The compound of the metals such as copper.Metal ion in hair dye penetrates into hair, in the cysteine in hair protein Sulphur effect, generates black vulcanized lead etc., and user's hair is contaminated black.But the heavy metal ion contained in inorganic hair dye is easily drawn Accumulation of poisoning is played, it is very big to the harm of human body, in addition to damaging hair healthy and easily causing allergy, a variety of diseases can also be caused.Lead is easy It is absorbed by the body to form slow poisoning, slow poisoning initial stage feels tired, loss of appetite etc., and when development may cause eyesight barrier Hinder and the diseases such as regenerative anemia.Copper is absorbed by the body, and lipid peroxide can excessively be promoted by slowly depositing, so as to cause artery Hardening and arterial fibrillation etc..Wherein, synthetic dyes are that p-phenylenediamine makes hair dye black, but p-phenylenediamine has Carcinogenicity.And vegetalitas hair dye be from natural plants extract or using natural plants as hair dye made of raw material, but its Fastness is bad, and the Shi Junhui that has one's hair wash every time after hair dyeing fades.

Therefore, need a kind of dyefastness high at present, repeatedly color is not easily to fall off after hair washing and the hair dyeing of small toxicity produces Product.

Summary of the invention

In the first aspect of the present invention, it is related to a kind of combination product, the combination product includes pretreatment fluid and dye cream, Or it is made of pretreatment fluid and dye cream.Further, wherein the pretreatment fluid includes cationic polymer or is made from it, And the dye cream (is selected from lemon yellow, famille rose, brilliant blue, CB-2, red 5 and of alkalinity by polymer polysaccharides, vaseline and dyestuff One of Indian yellow 2 or two or more any composition in them) composition.Still further, the wherein sun Ionomer is selected from polyethyleneimine, epsilon-polylysine and the two, and the polymer polysaccharides are selected from sodium alginate, shell Glycan and the two.Still further, wherein the concentration of the polyethyleneimine is 1-400mg/ml, preferably 50-150mg/ Ml, 50-100mg/ml, 100-150mg/ml, more preferably 50mg/ml, 100mg/ml or 150mg/ml, and the ε-is poly- bad The concentration of propylhomoserin is 1-400mg/ml, preferably 50-300mg/ml, 50-200mg/ml, 50-160mg/ml, 50-133.3mg/ ml、 50-100mg/ml、50-83.3mg/ml、83.3-300mg/ml、83.3-200mg/ml、 83.3-160mg/ml、83.3- 133.3mg/ml、83.3-100mg/ml、100-300mg/ml、 100-200mg/ml、100-160mg/ml、100-133.3mg/ Ml, 133.3-300mg/ml, 133.3-200mg/ml, 133.3-160mg/ml, 160-300mg/ml or 160-200mg/ml, More preferably 50mg/ml, 83.3mg/ml, 100mg/ml, 133.3mg/ml, 160mg/ml, 200mg/ml or 300mg/ml.Again Further, the amount of the sodium alginate or chitosan is about 0.1-1.2g, preferably 0.1g, 0.2g, 0.3g, 0.35g, Range between each amount of 0.4g, 0.5g, 0.6g, 0.7g, 0.8g, 0.9g, 1.0g, 1.1g, 1.2g or described, for example, 0.2- 1.1g.Still further, the amount of the vaseline be 0.1-1.5g, preferably 0.1g, 0.2g, 0.3g, 0.4g, 0.5g, Range between each amount of 0.58g, 0.6g, 0.7g, 0.8g, 0.9g, 1.0g, 1.1g, 1.2g, 1.3g, 1.4g, 1.5g or described, For example, 0.2-1.4g.Also further, the dyestuff is (that is, selected from lemon yellow, famille rose, brilliant blue, CB-2, alkalinity red 5 and acid Property one of Huang 2 and combinations thereof) amount be 1-20ml, preferably 11-14ml, more preferable 11ml, 12ml, 13ml or 14ml。

In the second aspect of the present invention, it is related to the preparation method of said combination product, which comprises use polymerization Object polysaccharide, vaseline and dyestuff preparation dye cream, wherein the polymer polysaccharides (preparing emulsifiable paste as emulsifier) are selected from seaweed Sour sodium, chitosan and combinations thereof, and use cationic polymer as pretreatment fluid, wherein the cationic polymer selects From polyethyleneimine, epsilon-polylysine and combinations thereof.Further, which comprises take vaseline about 0.1-1.5g (preferably 0.1g, 0.2g, 0.3g, 0.4g, 0.5g, 0.58g, 0.6g, 0.7g, 0.8g, 0.9g, 1.0g, 1.1g, 1.2g, Range between each amount of 1.3g, 1.4g, 1.5g or described, for example, 0.2-1.4g), sodium alginate or chitosan about 0.1-1.2g (preferably 0.1g, 0.2g, 0.3g, 0.35g, 0.4g, 0.5g, 0.6g, 0.7g, 0.8g, 0.9g, 1.0g, 1.1g, 1.2g or Range between each amount, for example, 0.2-1.1g), it is placed in the water-bath of 50 DEG C -90 DEG C (preferably 60 DEG C, 70 DEG C or 80 DEG C) It heats and is stirred continuously to melting in pot, be stirred continuously lower addition mixed dye solution, continue stirring to after being emulsified into paste completely Stop heating, continues stirring to room temperature；Use cationic polymer as pretreatment fluid, wherein the cationic polymer selects From polyethyleneimine, epsilon-polylysine and combinations thereof, wherein the concentration of the polyethyleneimine be 1-400mg/ml (preferably For 50-150mg/ml, 50-100mg/ml, 100-150mg/ml, more preferably 50mg/ml, 100mg/ml or 150mg/ml), The concentration of the epsilon-polylysine be 1-400mg/ml (preferably 50-300mg/ml, 50-200mg/ml, 50-160mg/ml, 50-133.3mg/ml、50-100mg/ml、50-83.3mg/ml、83.3-300mg/ml、 83.3-200mg/ml、83.3- 160mg/ml、83.3-133.3mg/ml、83.3-100mg/ml、 100-300mg/ml、100-200mg/ml、100-160mg/ ml、100-133.3mg/ml、 133.3-300mg/ml、133.3-200mg/ml、133.3-160mg/ml、160-300mg/ml Or 160-200mg/ml, more preferably 50mg/ml, 83.3mg/ml, 100mg/ml, 133.3mg/ml, 160mg/ml, 200mg/ Ml or 300mg/ml), and the dyestuff is (that is, in lemon yellow, famille rose, brilliant blue, CB-2, alkalinity red 5 and Indian yellow 2 One or more mixed dyes) amount be 1-20ml, preferably 11-14ml, more preferable 11ml, 12ml, 13ml or 14ml.

In the third aspect of the present invention, it is related to the hair colouring methods using said combination product, which comprises use The pretreatment fluid carries out sprinkling processing to hair, about dries after five minutes；Then the dye cream is uniformly smeared after treatment Hair on, make after about 10-15 minutes hair surface formed a tunic, complete hair dyeing.

In the fourth aspect of the present invention, be related to said combination product for hair dyeing purposes.

Detailed description of the invention

Fig. 1: influence of the different pretreatment fluids to the hair dyeing effect of yak hair.

Fig. 2: being shown by Electronic Speculum, influence of the pretreatment fluid containing epsilon-polylysine to the hair dyeing effect of yak hair.

Fig. 3: being shown by Electronic Speculum, hair dyeing of the pretreatment fluid containing epsilon-polylysine to people's hair (sample 1) of white The influence of effect.

Fig. 4: being shown by Electronic Speculum, hair dyeing of the pretreatment fluid containing epsilon-polylysine to people's hair (sample 2) of white The influence of effect.

Fig. 5: being shown by Electronic Speculum, repeatedly hair dyeing of the pretreatment fluid containing epsilon-polylysine to yak hair after washing The influence of effect.

Fig. 6: being shown by Electronic Speculum, and the pretreatment fluid containing epsilon-polylysine is to the hair dyeing effect of different colours hair It influences, wherein upper figure is that dye is preceding microcosmic in Fig. 6, the following figure is microcosmic after contaminating.

Fig. 7: the schematic diagram of beneficial effect brought by claimed combination product, i.e., by described group It closes product and forms layer protecting film in hair surface, bring dramatically increasing for fastness to washing.

Detailed description of the invention

Inventive point of the invention is: combination product of the invention includes the pretreatment fluid being made of cationic polymer And by polymer polysaccharides, vaseline and dyestuff (lemon yellow, famille rose, brilliant blue, CB-2, alkalinity red 5 and Indian yellow 2) group At dye cream, or be made of them, first handle hair with the pretreatment fluid being made of cationic polymer first when in use, Then the dye cream being made of polymer polysaccharides, vaseline and dyestuff is smeared in hair surface, they pass through strong Electrostatic Absorption Power adsorpting dye molecule, and form a film in hair surface, this not only reduces the toxicity of hair dyeing, but also increases dyefastness.

Definition

As used herein, term " hair " and " hair " refer to any fiber or fibrous material containing keratin, including appoint Hair, animal hair (including but not limited to, the rabbit hair, yak hair) and the writing brush hair of who class.

As it is used herein, term " pigment " is white, black or coloured powdery, water-soluble or water-insoluble object Matter is used for so that colouring containing the color compositions and/or becoming opaque.

As used herein, hair dyeing fastness (or fastness to washing) refer to color be subjected to the effect of various factors and in different journeys The ability of its original color, i.e., the ability of anti-discoloration are kept on degree.The high anti-discoloration for referring to color of hair dyeing fastness (or fastness to washing) Ability is high.Herein, after hair dyeing fastness (or fastness to washing) mainly passes through repeatedly washing (for example, 15-20 times), on hair The color that color still keeps its original to varying degrees does not take off to reflect.

As used herein, term " room temperature " refers to 25 DEG C ± 1 DEG C.Meanwhile if experimental temperature is not particularly pointed out, For room temperature.

As it is used herein, term " about " refers to ± the 20% of the numerical value that the term is modified, preferably ± 10%, More preferably ± 5%, therefore those skilled in the art clearly can determine term " about " according to the numerical value modified Range.

In the first aspect of the present invention, it is related to a kind of combination product, the combination product includes pretreatment fluid and dye cream, Or it is made of pretreatment fluid and dye cream.Further, wherein the pretreatment fluid includes cationic polymer or is made from it, And the dye cream includes polymer polysaccharides, vaseline and dyestuff (selected from lemon yellow, famille rose, brilliant blue, CB-2, alkalinity red 5 With one of Indian yellow 2 or a variety of mixed dyes), or be made of them.Still further, wherein the cation is poly- It closes object and is selected from polyethyleneimine, epsilon-polylysine and combinations thereof, and the polymer polysaccharides are selected from sodium alginate, chitosan And combinations thereof.Still further, the wherein concentration 1-400mg/ml of the polyethyleneimine, preferably 50-150mg/ml, 50-100mg/ml, 100-150mg/ml, more preferably 50mg/ml, 100mg/ml or 150mg/ml, and the poly- bad ammonia of the ε- The concentration of acid is 1-400mg/ml, preferably 50-300mg/ml, 50-200mg/ml, 50-160mg/ml, 50-133.3mg/ ml、50-100mg/ml、50-83.3mg/ml、 83.3-300mg/ml、83.3-200mg/ml、83.3-160mg/ml、83.3- 133.3mg/ml、 83.3-100mg/ml、100-300mg/ml、100-200mg/ml、100-160mg/ml、 100- 133.3mg/ml, 133.3-300mg/ml, 133.3-200mg/ml, 133.3-160mg/ml, 160-300mg/ml or 160- 200mg/ml, more preferably 50mg/ml, 83.3mg/ml, 100mg/ml, 133.3mg/ml, 160mg/ml, 200mg/ml or 300mg/ml.Still further, the amount of the sodium alginate or chitosan is about 0.1-1.2g, preferably 0.1g, 0.2g, Range between each amount of 0.3g, 0.35g, 0.4g, 0.5g, 0.6g, 0.7g, 0.8g, 0.9g, 1.0g, 1.1g, 1.2g or described, For example, 0.1-1.1g, 0.1-1.0g, 0.1-0.9g, 0.1-0.8g, 0.1-0.7g, 0.1-0.6g, 0.1-0.5g, 0.1- 0.4g、0.1-0.35g、0.1-0.2g、0.2-1.2g、0.2-1.1g、0.2-1.0g、0.2-0.9g、0.2-0.8g、0.2- 0.7g、0.2-0.6g、0.2-0.5g、 0.2-0.4g、0.2-0.35g、0.2-0.3g、0.3-1.2g、0.3-1.1g、0.3- 1.0g、0.3-0.9g、 0.3-0.8g、0.3-0.7g、0.3-0.6g、0.3-0.5g、0.3-0.4g、0.3-0.35g、0.4- 1.2g、 0.4-1.1g、0.4-1.0g、0.4-0.9g、0.4-0.8g、0.4-0.7g、0.4-0.6g、0.4-0.5g、 0.5- 1.2g、0.5-1.1g、0.5-1.0g、0.5-0.9g、0.5-0.8g、0.5-0.7g、0.5-0.6g、 0.6-1.2g、0.6- 1.1g、0.6-1.0g、0.6-0.9g、0.6-0.8g、0.6-0.7g、0.7-1.2g、 0.7-1.1g、0.7-1.0g、0.7- 0.9g、0.7-0.8g、0.8-1.2g、0.8-1.1g、0.8-1.0g、 0.8-0.9g、0.9-1.2g、0.9-1.1g、0.9- 1.0g, 1.0-1.1g, 1.0-1.2g or 1.1-1.2g.Still further, the amount of the vaseline is 0.1-1.5g, preferably 0.1g、0.2g、0.3g、 0.4g、0.5g、0.58g、0.6g、0.7g、0.8g、0.9g、1.0g、1.1g、1.2g、1.3g、 Range between each amount of 1.4g, 1.5g or described, for example, 0.1-1.5g, 0.1-1.4g, 0.1-1.3g, 0.1-1.2g, 0.1- 1.1g、0.1-1.0g、0.1-0.9g、0.1-0.8g、0.1-0.7g、0.1-0.6g、 0.1-0.58g、0.1-0.5g、0.1- 0.4g、0.1-0.2g、0.2-1.5g、0.2-1.4g、0.2-1.3g、 0.2-1.2g、0.2-1.1g、0.2-1.0g、0.2- 0.9g、0.2-0.8g、0.2-0.7g、0.2-0.6g、 0.2-0.58g、0.2-0.5g、0.2-0.4g、0.2-0.3g、0.3- 1.5g、0.3-1.4g、0.3-1.3g、 0.3-1.2g、0.3-1.1g、0.3-1.0g、0.3-0.9g、0.3-0.8g、0.3- 0.7g、0.3-0.6g、 0.3-0.58g、0.3-0.5g、0.3-0.4g、0.4-1.5g、0.4-1.4g、0.4-1.3g、0.4- 1.2g、 0.4-1.1g、0.4-1.0g、0.4-0.9g、0.4-0.8g、0.4-0.7g、0.4-0.6g、0.4-0.58g、 0.4- 0.5g、0.5-1.5g、0.5-1.4g、0.5-1.3g、0.5-1.2g、0.5-1.1g、0.5-1.0g、 0.5-0.9g、0.5- 0.8g、0.5-0.7g、0.5-0.6g、0.5-0.58g、0.58g-0.15g、 0.58g-0.14g、0.58g-0.13g、0.58g- 0.12g、0.58g-0.11g、0.58g-0.10g、 0.58g-0.9g、0.58g-0.8g、0.58g-0.7g、0.58g-0.6g、 0.6-1.5g、0.6-1.4g、 0.6-1.3g、0.6-1.2g、0.6-1.1g、0.6-1.0g、0.6-0.9g、0.6-0.8g、0.6- 0.7g、 0.7-1.5g、0.7-1.4g、0.7-1.3g、0.7-1.2g、0.7-1.1g、0.7-1.0g、0.7-0.9g、 0.7- 0.8g、0.8-1.5g、0.8-1.4g、0.8-1.3g、0.8-1.2g、0.8-1.1g、0.8-1.0g、 0.8-0.9g、0.9- 1.5g、0.9-14g、0.9-1.3g、0.9-1.2g、0.9-1.1g、0.9-1.0g、 1.0-1.5g、1.0-1.4g、1.0-1.3g、 1.0-1.2g、1.0-1.1g、1.1-1.5g、1.1-1.4g、 1.1-1.3g、1.1-1.2g、1.2-1.5g、1.2-1.4g、1.2- 1.3g,1.3-1.5g,1.3-1.4g, 1.4-1.5g.Also further, the dyestuff is (that is, selected from lemon yellow, famille rose, bright Indigo plant, CB-2, alkaline one of red 5 and Indian yellow 2 or a variety of mixed dyes) amount be 1-20ml, preferably 11-14ml, more It is preferred that 11ml, 12ml, 13ml or 14ml.

The invention has the advantages that: the toxicity of hair dyeing is low and dyefastness is excellent, and fastness to washing is high.

Specific embodiment

Below in conjunction with the drawings and specific embodiments, the invention will be further described.It should be understood that following embodiment is only used In illustrate the present invention and be not intended to limit the range covered in the claims in the present invention.

Method in following embodiments is all made of conventional method unless otherwise specified.

Embodiment 1: influence of the different pretreatment fluids to the hair dyeing effect of yak hair

A. the preparation of pretreatment fluid

Prepare polyethyleneimine (that is, IP in Fig. 1) (molecular weight 800), epsilon-polylysine (that is, PLL in Fig. 1) The treatment fluid of (molecular weight 5000) or the composition of both of which: the epsilon-polylysine and polyethyleneimine of 200mg are weighed respectively Amine, respectively plus 1ml and 4ml deionized water is configured to the epsilon-polylysine with required concentration or polyethylenimine solution (divides Biao Ji for number and No. 2 pretreatment fluids), No. 1 pretreatment fluid concentration is about 200mg/ml, and the concentration of No. 2 treatment fluids is 50mg/ ml。

Citric acid 100mg is weighed, 2ml deionized water is added, is configured to the solution that concentration is 50mg/ml；Take 1ml concentrated ammonia liquor 9ml deionized water is added to dilute；The glacial acetic acid (2%) of the chitosan (that is, CTS in Fig. 1) plus 2.5ml that weigh 50mg is configured to Concentration is the solution of 20mg/ml.

Then as requested, following 6 groups for the treatment of fluids are prepared:

(i) No. 2 pretreatments of No. 1 pretreatment fluid (200mg/ml PLL) and 0.5ml (50mg/ml IP800) of 2ml are taken Liquid mixing, obtains the 1st group of pretreatment fluid；

(ii) 1ml citric acid (50mg/ml) is mixed with No. 1 pretreatment fluid, obtains the 2nd group of pretreatment fluid；

(iii) 2ml citric acid (50mg/ml) is mixed with No. 1 pretreatment fluid, obtains the 3rd group of pretreatment fluid；

(iv) take No. 1 treatment fluid 1ml (200mg/ml PLL) and 25 μ l ammonium hydroxide (ratio of ammonium hydroxide and deionized water is 1: 9) it mixes, obtains the 4th group of pretreatment fluid；

(v) No. 1 treatment fluid 1ml (200mg/ml PLL) is taken, the 5th group of pretreatment fluid is obtained；

(vi) it takes No. 1 treatment fluid 1ml (200mg/ml PLL) and 4ml CTS (20mg/ml) to mix, obtains the 6th group and locate in advance Manage liquid.

B. the preparation of cream is contaminated

It prepares dye cream: vaseline about 1.2g, sodium alginate about 0.4g being taken to be placed in 100ml beaker, in 60 DEG C of water-bath Heating is stirred continuously to melting in pot, and mixed dye 15ml solution is then added under constant stirring, continues stirring to complete cream Stop heating after being melted into paste, continues stirring to room temperature.

C. hair dye

Specific hair dye is as follows: selection yak hair, and above-mentioned preparation is respectively coated in smearing on its surface 6 groups are located in advance Liquid is managed, wipes pretreatment fluid remained on surface after 5min, uniformly smears one layer of dye cream, 10-15min is dyed, is observed after washing off.

D. result

The purpose of this experiment is to handle hair using different pretreatments liquid, (main indicator is washable to observation dyeing effect Degree, that is, use the color that hair is watched after Rejoice hair washing washing), to determine further experiment institute by the group of fastness to washing The pretreatment fluid used.

It is found in test, the pretreatment of polyethyleneimine, poly- epsilon-polylysine and polyethyleneimine/or epsilon-polylysine Liquid can reach pretreatment purpose (that is, can allow different colorations hair after treatment, catch black well, and through 15 After secondary hair washing washing, color is not taken off completely, and fastness to washing is preferable, and with the pretreatment fluid effect containing epsilon-polylysine It is best), please refer to Fig. 1.

Embodiment 2: influence of the pretreatment fluid containing epsilon-polylysine to the hair dyeing effect of yak hair

A. the preparation of pretreatment fluid, the specific steps are as follows:

It weighs 300mg epsilon-polylysine powder to be dissolved in the deionized water of 6ml, concentration is the treatment fluid of 50mg/ml.

B. the preparation of cream is contaminated, the specific steps are as follows:

Vaseline about 0.8g, sodium alginate about 0.7g are weighed, in 100ml beaker, is placed in 70 DEG C of water-bath and adds Heat is stirred continuously to melting, and the mixed dye solution of CB-2, alkalinity red 5 and Indian yellow 2 are then added under constant stirring 12ml continues stirring and stops heating to after being emulsified into paste completely, continues stirring to room temperature.

C. specific hair dye: selection yak hair is smeared one layer of pretreatment fluid on its yak hair surface, is wiped after 5min Treatment fluid remained on surface is removed, one layer of dye cream is smeared, contaminates 15min.

D. result

Hair surface is scanned under conditions of amplification factor is 3000 using SEM and observes to obtain Fig. 2, discovery is contaminating White yak hair surface afterwards forms a tunic and is covered on hair surface, to be conducive to dramatically increasing for hair dyeing fastness to washing.

Embodiment 3: shadow of the pretreatment fluid containing epsilon-polylysine to the hair dyeing effect of people's hair (sample 1) of white It rings

A. the preparation of pretreatment fluid, the specific steps are as follows:

The epsilon-polylysine powder for weighing 400mg, is dissolved in the deionized water of 4ml, and being configured to concentration is 100mg/ml's Treatment fluid.

B. the preparation of cream is contaminated, the specific steps are as follows:

Vaseline about 0.6g, sodium alginate about 0.4g are weighed, in 100ml beaker, is placed in 80 DEG C of water-bath and adds Heat is stirred continuously to melting, and CB-2, red 5 and 2 mixed dye solution 10ml of Indian yellow of alkalinity are then added under constant stirring, Continue stirring and stop heating to after being emulsified into paste completely, continues stirring to room temperature.

C. hair dye: selecting people's hair of white, smears one layer of pretreatment fluid on its surface, wipes surface after 5min Remaining treatment fluid smears one layer of dye cream, contaminates 15min.

D. result

People's hair (sample 1) of white is dyed into black, and electron microscope as shown in Figure 3 is seen, in people's hair of white Surface forms a tunic and is covered on hair surface, to be conducive to dramatically increasing for hair dyeing fastness to washing.

Embodiment 4: shadow of the pretreatment fluid containing epsilon-polylysine to the hair dyeing effect of people's hair (sample 2) of white It rings

A. the preparation of pretreatment fluid, the specific steps are as follows:

The epsilon-polylysine powder for weighing 500mg, is dissolved in the deionized water of 6ml, and being configured to concentration is 83.3mg/ml Treatment fluid.

B. the preparation of cream is contaminated, the specific steps are as follows:

Vaseline about 0.9g, sodium alginate about 0.3g are weighed, in 100ml beaker, is placed in 60 DEG C of water-bath and adds Heat is stirred continuously to melting, and CB-2, red 5 and 2 mixed dye solution 13ml of Indian yellow of alkalinity are then added under constant stirring, Continue stirring and stop heating to after being emulsified into paste completely, continues stirring to room temperature.

D. result

People's hair (sample 2) of white is dyed into black, and electron microscope as shown in Figure 4 is seen, in people's hair of white Surface forms a tunic and is covered on hair surface, to be conducive to dramatically increasing for hair dyeing fastness to washing.

Embodiment 5: repeatedly after washing, shadow of the pretreatment fluid containing epsilon-polylysine to the hair dyeing effect of yak hair It rings

A. the preparation of pretreatment fluid, the specific steps are as follows:

The epsilon-polylysine for weighing 800mg is dissolved in the deionized water of 6ml, and the processing that concentration is 133.3mg/ml is made Liquid.

B. the preparation of cream is contaminated, the specific steps are as follows:

Vaseline about 0.58g is weighed, sodium alginate about 0.35g is placed in 90 DEG C of water-bath in 100ml beaker Heating is stirred continuously to melting, and lemon yellow, famille rose, brilliant blue mixed dye solution 11ml are then added under constant stirring, after Continuous stirring stops heating to after being emulsified into paste completely, continues stirring to room temperature.

C. hair dye: selection yak hair smears one layer of pretreatment fluid on its surface, wipes remained on surface after 5min Treatment fluid, smear one layer of dye cream, contaminate 15min.Then it with hair washing washing 5-15 times, is observed after being dried up with hair dryer.

D. result

As shown in figure 5, showing according to electron microscope, yak hair its surface when washing different numbers with hair washing is contaminated Pattern is shown in when washing 5-15 times, and surface is still covered by a tunic, illustrate its have hair dyed fastness (or fastness to washing) it is splendid.

Influence of pretreatment fluid of the embodiment 6 containing epsilon-polylysine to the hair dyeing effect of different colours hair

A. the preparation of pretreatment fluid, the specific steps are as follows:

The epsilon-polylysine powder for weighing 600mg, is dissolved in the deionized water of 2ml, and being configured to concentration is 300mg/ml's Treatment fluid.

B. the preparation of cream is contaminated, the specific steps are as follows:

Vaseline about 1.1g, sodium alginate about 0.5g are weighed, in 100ml beaker, is placed in 70 DEG C of water-bath and adds Heat is stirred continuously to melting, and lemon yellow, famille rose, brilliant blue mixed dye solution 14ml are then added under constant stirring, is continued Stirring stops heating to after being emulsified into paste completely, continues stirring to room temperature.

C. hair (yellow that Guangzhou Bao Rou company gives, dark brown, grey bletilla flower of separate sources hair dye: are selected White), one layer of pretreatment fluid is smeared on it, treatment fluid remained on surface is wiped after 5min, smears one layer of dye cream, is contaminated 15min。

D. result

As shown in fig. 6, electron microscope of the different hairs before dye, shows to use this method on different colours people's hair Hair dyeing can form a tunic on surface, to be conducive to dramatically increasing for hair dyeing fastness to washing.

In conclusion the present invention effectively overcomes various shortcoming in the prior art and has high industrial utilization value.

The above-described embodiments merely illustrate the principles and effects of the present invention, and is not intended to limit the present invention.It is any ripe The personage for knowing this technology all without departing from the spirit and scope of the present invention, carries out modifications and changes to above-described embodiment.Cause This, have in the art usually intellectual without departing from the spirit and technical ideas disclosed in the present invention institute it is complete At all equivalent modifications or change, should be covered by the claims of the present invention.

Claims

1. combination product, the combination product includes pretreatment fluid and dye cream, wherein the pretreatment fluid is by cationic polymer Composition, and the dye cream includes polymer polysaccharides, vaseline and dyestuff or is made of them, the dyestuff selected from lemon yellow, Famille rose, brilliant blue, CB-2, alkalinity is red 5, Indian yellow 2 and combinations thereof.

2. combination product according to claim 1, wherein the cationic polymer be selected from polyethyleneimine, epsilon-polylysine and Its composition, and the polymer polysaccharides are selected from sodium alginate, chitosan and combinations thereof.

3. combination product according to claim 2, wherein the concentration of the polyethyleneimine is 1-400mg/ml, preferably 50- 150mg/ml, 50-100mg/ml, 100-150mg/ml, more preferably 50mg/ml, 100mg/ml or 150mg/ml, and the ε- The concentration of polylysine is 1-400mg/ml, preferably 50-300mg/ml, 50-200mg/ml, 50-160mg/ml, 50- 133.3mg/ml、50-100mg/ml、50-83.3mg/ml、83.3-300mg/ml、83.3-200mg/ml、83.3-160mg/ ml、83.3-133.3mg/ml、83.3-100mg/ml、100-300mg/ml、100-200mg/ml、100-160mg/ml、100- 133.3mg/ml, 133.3-300mg/ml, 133.3-200mg/ml, 133.3-160mg/ml, 160-300mg/ml or 160- 200mg/ml, more preferably 50mg/ml, 83.3mg/ml, 100mg/ml, 133.3mg/ml, 160mg/ml, 200mg/ml or 300mg/ml。

4. combination product according to claim 2, wherein the amount of the sodium alginate or chitosan is about 0.1-1.2g, preferably 0.1g, 0.2g, 0.3g, 0.35g, 0.4g, 0.5g, 0.6g, 0.7g, 0.8g, 0.9g, 1.0g, 1.1g, 1.2g or described respectively measure it Between range.

5. the preparation method of combination product as claimed in one of claims 1-4, which comprises more using polymer Sugar, vaseline and dyestuff preparation dye cream, wherein the polymer polysaccharides are selected from sodium alginate, chitosan and combinations thereof, and Use cationic polymer as pretreatment fluid, wherein the cationic polymer be selected from polyethyleneimine, epsilon-polylysine and Its composition.

6. preparation method according to claim 5, which comprises take vaseline about 0.1-1.5g, sodium alginate or shell poly- Sugar about 0.1-1.2g, is placed in heat in 50 DEG C -90 DEG C, preferably 60 DEG C, 70 DEG C or 80 DEG C of water-bath and is stirred continuously to melting, It is stirred continuously lower addition mixed dye solution, continues stirring and stops heating to after being emulsified into paste completely, continue stirring to room temperature； And wherein the concentration of the polyethyleneimine is 1-400mg/ml (preferably 50-150mg/ml, 50-100mg/ml, 100- 150mg/ml, more preferably 50mg/ml, 100mg/ml or 150mg/ml), the concentration of the epsilon-polylysine is 1-400mg/ml (preferably 50-300mg/ml, 50-200mg/ml, 50-160mg/ml, 50-133.3mg/ml, 50-100mg/ml, 50- 83.3mg/ml、83.3-300mg/ml、83.3-200mg/ml、83.3-160mg/ml、83.3-133.3mg/ml、83.3- 100mg/ml、100-300mg/ml、100-200mg/ml、100-160mg/ml、100-133.3mg/ml、133.3-300mg/ Ml, 133.3-200mg/ml, 133.3-160mg/ml, 160-300mg/ml or 160-200mg/ml, more preferably 50mg/ml, 83.3mg/ml, 100mg/ml, 133.3mg/ml, 160mg/ml, 200mg/ml or 300mg/ml).

7. preparation method according to claim 6, wherein the vaseline is 0.1g, 0.2g, 0.3g, 0.4g, 0.5g, 0.58g, Range between each amount of 0.6g, 0.7g, 0.8g, 0.9g, 1.0g, 1.1g, 1.2g, 1.3g, 1.4g, 1.5g or described, and it is described Sodium alginate or chitosan be 0.1g, 0.2g, 0.3g, 0.35g, 0.4g, 0.5g, 0.6g, 0.7g, 0.8g, 0.9g, 1.0g, Range between each amount of 1.1g, 1.2g or described.

8. using the hair colouring methods of combination product as claimed in one of claims 1-4, which comprises using described pre- Treatment fluid carries out sprinkling processing to hair, about dries after five minutes；Then by the dye cream hair that is uniformly applied to that treated On, make hair surface form a tunic after about 10-15 minutes, completes hair dyeing.

9. purposes of the combination product as claimed in one of claims 1-4 for hair dyeing.