Nothing Special   »   [go: up one dir, main page]

CN109485965A - A kind of solar cell backboard substrate and preparation method and solar cell backboard - Google Patents

A kind of solar cell backboard substrate and preparation method and solar cell backboard Download PDF

Info

Publication number
CN109485965A
CN109485965A CN201811241650.XA CN201811241650A CN109485965A CN 109485965 A CN109485965 A CN 109485965A CN 201811241650 A CN201811241650 A CN 201811241650A CN 109485965 A CN109485965 A CN 109485965A
Authority
CN
China
Prior art keywords
parts
solar cell
polyethylene
ethylene
mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201811241650.XA
Other languages
Chinese (zh)
Inventor
赵正柏
夏修旸
陈洪野
宇野敬
宇野敬一
吴小平
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzhou Competition Application Technology Ltd By Share Ltd
Original Assignee
Suzhou Competition Application Technology Ltd By Share Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suzhou Competition Application Technology Ltd By Share Ltd filed Critical Suzhou Competition Application Technology Ltd By Share Ltd
Priority to CN201811241650.XA priority Critical patent/CN109485965A/en
Publication of CN109485965A publication Critical patent/CN109485965A/en
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
    • C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L45/00—Compositions of homopolymers or copolymers of compounds having no unsaturated aliphatic radicals in side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic or in a heterocyclic ring system; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/04—Non-macromolecular additives inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08—Macromolecular additives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/04—Homopolymers or copolymers of ethene
    • C09J123/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/20—Adhesives in the form of films or foils characterised by their carriers
    • C09J7/22—Plastics; Metallised plastics
    • C09J7/24—Plastics; Metallised plastics based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C09J7/241—Polyolefin, e.g.rubber
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/20—Adhesives in the form of films or foils characterised by their carriers
    • C09J7/22—Plastics; Metallised plastics
    • C09J7/24—Plastics; Metallised plastics based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C09J7/241—Polyolefin, e.g.rubber
    • C09J7/243—Ethylene or propylene polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10F—INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
    • H10F19/00—Integrated devices, or assemblies of multiple devices, comprising at least one photovoltaic cell covered by group H10F10/00, e.g. photovoltaic modules
    • H10F19/80—Encapsulations or containers for integrated devices, or assemblies of multiple devices, having photovoltaic cells
    • H10F19/85—Protective back sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/06—Properties of polyethylene
    • C08L2207/066—LDPE (radical process)
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2203/00—Applications of adhesives in processes or use of adhesives in the form of films or foils
    • C09J2203/33—Applications of adhesives in processes or use of adhesives in the form of films or foils for batteries or fuel cells
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
    • C09J2301/12—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
    • C09J2301/122—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present only on one side of the carrier, e.g. single-sided adhesive tape
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00—Energy generation through renewable energy sources
    • Y02E10/50—Photovoltaic [PV] energy

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

本发明提供了一种太阳能电池背板基材与制备方法及太阳能电池背板。本发明的一种太阳能电池背板基材，包含芯材层，按重量份计，所述芯材层包含以下组分：60～85份的聚烯烃、1～30份的耐热补强树脂、1～5份的增韧剂、1～5份的相容剂、0～20份的无机填料和0～3份的助剂。本发明的制备方法简单，制得的太阳能电池背板基材具有很好的水汽阻隔能力，且同时具备良好的热稳定性和机械性能，可广泛用于太阳能电池片背板的加工；本发明的太阳能电池背板，成型简单，可回收，水汽阻隔性好，与封装胶膜的粘接性优良，可防止电池片被氧化，提高了电池片的发电效率，延长了太阳能电池组件的使用寿命。

The invention provides a solar cell backplane base material, a preparation method and a solar cell backplane. A solar cell back sheet substrate of the present invention comprises a core material layer, and in parts by weight, the core material layer comprises the following components: 60-85 parts of polyolefin, 1-30 parts of heat-resistant reinforcing resin , 1-5 parts of toughening agent, 1-5 parts of compatibilizer, 0-20 parts of inorganic filler and 0-3 parts of auxiliary agent. The preparation method of the invention is simple, the prepared solar cell back sheet substrate has good water vapor barrier capability, and at the same time has good thermal stability and mechanical properties, and can be widely used in the processing of solar cell back sheets; the present invention The solar cell backsheet is simple to form, recyclable, has good water vapor barrier properties, and has excellent adhesion to the encapsulation film, which can prevent the cells from being oxidized, improve the power generation efficiency of the cells, and prolong the service life of the solar cell modules. .

Description

A kind of solar cell backboard substrate and preparation method and solar cell backboard
Technical field
The invention belongs to solar energy backplane technology field, it is related to a kind of solar cell backboard substrate and preparation method and too Positive energy battery back-sheet.
Background technique
In field of solar thermal power generation, the backboard of solar components is located at the outermost layer of module backside, plays guarantor to cell piece Shield and supporting role.Backboard should have reliable electric insulating quality, water vapor barrier property and good resistance to ag(e)ing.To make solar energy Battery keeps optimal working condition and maintains 25 years service life, and backboard should have excellent water vapor barrier property and hydrolysis Performance, this is one of the important indicator for measuring backboard performance quality.If solar energy backboard water vapor barrier property is bad, steam passes through back Plate penetrates into the cementability that will affect packaging adhesive film inside encapsulation system, causes backboard and packaging adhesive film delamination, makes cell piece It is oxidized to seriously reduce the service life of cell piece generating efficiency and component, anti-hydrolytic performance is also what water vapor rejection deteriorated One of the major reasons.
Existing backboard on the market can be divided into the compound backboard using PET as core material, and with polyolefin for main material The co-extrusion type integration backboard of material.PET have intensity height, good weatherability, thermal stability by force etc. major advantages, but simultaneously there is also The disadvantage of water vapor transmittance height, hydrolysis wet-hot aging performance difference；Co-extrusion type backboard has molding simple, and water vapor transmittance is low, can The advantages that recycling, but there is also intensity simultaneously it is low, thermal stability is poor the disadvantages of.How the advantages of the two, is combined, into one Step overcomes the shortcomings that the two to will be the Main way that the following backboard develops.
CN104403282A discloses a kind of solar cell backboard modified PET substrate and preparation method thereof the modification PET base material includes the component of following parts by weight meter: 30~80 parts of n-butyl acetate, PET40~80 part, hexabromocyclododecane 40~ 100 parts, 30~150 parts of 3-M2BOL, 100~200 parts of methyl ethyl ketone, 40~80 parts of titanium dioxide, maleic anhydride 20~50 parts of graft polypropylene, 40~120 parts of stabilizer, 20~120 parts of carbonate, 30~40 parts of phthalate.System Preparation Method: by n-butyl acetate, PET, hexabromocyclododecane, 3-M2BOL, titanium dioxide, phthalic acid ester Class is uniformly mixed, and is heated to 800~950 DEG C, is slowly added to residual components, and inert gas is filled with, and reacts 2~3h；It is dry to squeeze out, Cooling slab；Drawing and setting.The n-butyl acetate of the invention significantly improves the linking power between PET macromolecular, makes substrate Surface can increase with tensile strength, and mechanical performance is stronger.But the steam of solar cell backboard made from the invention Obstructing capacity needs to be further increased.
CN103618015A discloses a kind of novel solar battery backboard and preparation method thereof, solar cell backboard by Hydrophobic polymer layer, biaxially oriented polyester film substrate, adhesive phase, Polyofefine adhesive layer pass through coating complex technique preparation It forms.The invention uses hydrophobic polymer layer, has ultra-hydrophobicity, can avoid droplet in the adherency of back plate surface, improves The anti-hydrolytic performance of backboard can effectively guarantee the long-term work of solar components.Although its hydrophobic performance is improved, It is that water vapor rejection ability, thermal stability and mechanical performance need to be further increased.
Therefore it provides a kind of solar energy for the water vapor transmittance and good thermal stability and mechanical performance having had simultaneously Battery back-sheet material is necessary.
Summary of the invention
In view of the deficiencies of the prior art, the purpose of the present invention is to provide a kind of solar cell backboard substrates and preparation side Method and solar cell backboard, the solar cell backboard substrate have good water vapor rejection ability, and are provided simultaneously with good Thermal stability and mechanical performance.
To achieve this purpose, the present invention adopts the following technical scheme:
One of the objects of the present invention is to provide a kind of solar cell backboard substrate, the solar cell backboard substrate Comprising core layer, by weight, the core layer includes following components:
Due to the design feature and crystallinity in process of polyolefin itself, film prepared therefrom obstructs steam Ability is strong, and still, only the mechanical performance of the film itself of polyolefin preparation is bad, and especially break-draw rate is insufficient, and pure Polyolefin film be easy be heat-shrinked under the high temperature conditions.The present invention selects main material of the polyolefin as backboard substrate Material, the block-water performance that heat-resisting reinforced resin is added to enhance heat resistance, while keeping polyolefin outstanding, by by polyolefin, Heat-resisting reinforced resin and toughener carry out tertiary blending, and the backboard substrate being prepared is under the ability for having water vapor rejection, also With heat resistanceheat resistant shrinkage and good mechanical strength.
Wherein, by weight, the core layer includes following components:
60~85 parts of polyolefin, such as the parts by weight of polyolefin are 60 parts, 61 parts, 62 parts, 63 parts, 64 parts, 65 parts, 66 Part, 67 parts, 68 parts, 69 parts, 70 parts, 71 parts, 72 parts, 73 parts, 74 parts, 75 parts, 76 parts, 77 parts, 78 parts, 79 parts, 80 parts, 81 Part, 82 parts, 83 parts, 84 parts, 85 parts.
1~30 part of heat-resisting reinforced resin, such as the parts by weight of heat-resisting reinforced resin are 1 part, 2 parts, 3 parts, 4 parts, 5 parts, 6 Part, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts, 16 parts, 17 parts, 18 parts, 19 parts, 20 parts, 21 parts, 22 Part, 23 parts, 24 parts, 25 parts, 26 parts, 27 parts, 28 parts, 29 parts, 30 parts.
1~5 part of toughener, such as the parts by weight of toughener are 1 part, 2 parts, 3 parts, 4 parts, 5 parts.
1~5 part of compatilizer, such as the parts by weight of compatilizer are 1 part, 2 parts, 3 parts, 4 parts, 5 parts.
0~20 part of inorganic filler, such as the parts by weight of inorganic filler are 1 part, 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 Part, 9 parts, 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts, 16 parts, 17 parts, 18 parts, 19 parts, 20 parts.
0~3 part of auxiliary agent, such as the parts by weight of auxiliary agent are 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts.
0~30 part of fire retardant, such as the parts by weight of fire retardant are 0,1 part, 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9 Part, 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts, 16 parts, 17 parts, 18 parts, 19 parts, 20 parts, 21 parts, 22 parts, 23 parts, 24 Part, 25 parts, 26 parts, 27 parts, 28 parts, 29 parts, 30 parts.
Wherein, the polyolefin is one of polyethylene, polypropylene, ethylene-propylene copolymer and cycloolefin or at least Two kinds of mixture.
In the present invention, the heat-resisting reinforced resin is polyester, polyketone, polyamide, cycloolefin, plastic polyurethane elastomer (TPU), polyester and one of polyether block copolymer (TPEE) and mineral or at least two mixture.
Preferably, the polyester is polyethylene terephthalate, Isosorbide-5-Nitrae cyclohexanedimethanol polyester, poly- terephthaldehyde One of sour butanediol ester, poly- 2,6- (ethylene naphthalate) and polypropylene terephthalate or at least two it is mixed Close object.
Preferably, the polyamide is one kind or at least two in nylon 6, nylon 12, nylon 612, nylon 1212 and MXD6 The mixture of kind.
Preferably, the mineral are the mixing of one of talcum powder, carbon black, mica powder and barium sulfate or at least two Object.
Wherein, the toughener be polyolefin elastomer (POE), ethylene propylene diene rubber (EPDM), ethylene vinyl acetate it is total Polymers (EVA), ethylene-methyl acrylate copolymer (EMA), vinyl-acrylate copolymer (EAA), butadiene-styrene rubber (SBR), Polystyrene-Polyethylene-polybutene-polystyrene (SEBS), polystyrene-poly butylene-polystyrene (SBS), ACR In (general name of acrylic acid esters co-polymer) elastomer, methyl methacrylate, butadiene and styrene copolymer (MBS) One kind or at least two mixture.
In the present invention, the compatilizer is that polyethylene-g- maleic anhydride, polypropylene-g- maleic anhydride, ethylene-propylene are total Polymers-g- maleic anhydride, polyethylene-g- glycidyl methacrylate, polypropylene-g- glycidyl methacrylate, Ethylene-propylene copolymer-g- glycidyl methacrylate, polyolefin elastomer-g- maleic anhydride, bibasic ethylene propylene rubber- G- maleic anhydride, ethylene propylene diene rubber-g- maleic anhydride, ethylene-ethyl acetate copolymer-g- maleic anhydride, ethylene-methyl-prop Olefin(e) acid ester copolymer-g- maleic anhydride, butadiene-styrene rubber-g- maleic anhydride, gathers vinyl-acrylate copolymer-g- maleic anhydride Styrene-polyethylene-polybutene-polystyrene-g- maleic anhydride, polystyrene-poly butylene-polystyrene-g- maleic anhydride, Polyolefin elastomer-g- glycidyl methacrylate, bibasic ethylene propylene rubber-g- glycidyl methacrylate, ternary EP rubbers-g- glycidyl methacrylate, ethylene-ethyl acetate copolymer-g- glycidyl methacrylate, second Alkene-methacrylate copolymer-g- glycidyl methacrylate, vinyl-acrylate copolymer-g- methacrylic acid Ethylene oxidic ester, butadiene-styrene rubber-g- glycidyl methacrylate, Polystyrene-Polyethylene-polybutene-polystyrene-g- One of glycidyl methacrylate and polystyrene-poly butylene-polystyrene-g- glycidyl methacrylate Or at least two mixture.
In the present invention, the inorganic filler is one in talcum powder, titanium dioxide, montmorillonite, whisker, mica powder and calcium carbonate Kind or at least two mixture.
Preferably, the auxiliary agent is antioxidant and/or hydrolysis agent.
Preferably, the fire retardant is to have one of halogen fire retardant, halogen-free flame retardants or inorganic matter.
Preferably, the fire retardant is one of aluminium hydroxide, magnesium hydroxide or bromobenzene.
In the present invention, the solar cell backboard substrate is made of core layer and adhesive layer；Adhesive layer enhances The bonding force of core layer and package material.
Preferably, by weight, the adhesive layer includes following components:
Preferably, the inorganic filler is titanium dioxide or carbon black.
Preferably, the polyolefin blend is polyolefin and polyamide, ultra-high molecular weight polyethylene, cycloolefin, nylon Or ASA (Acrylonitrile Styrene acrylate copolymer, engineering plastics are acrylate rubber like body with The graft copolymer of acrylonitrile, styrene) at least one of mixture.Such as the polyolefin blend be polyolefin with The mixture of the mixture of the mixture of polyamide, polyolefin and ultra-high molecular weight polyethylene, polyolefin and cycloolefin, polyolefin With the mixture of nylon, the mixture of polyolefin and ASA, the mixture of polyolefin and polyamide, ultra-high molecular weight polyethylene gathers The mixture of the mixture of alkene and polyamide, cycloolefin, polyolefin and polyamide, nylon, polyolefin and polyamide, ASA The mixture of the mixture of mixture, polyolefin and ultra-high molecular weight polyethylene, cycloolefin, polyolefin and superhigh molecular weight polyethylene The mixture of alkene, nylon, the mixture of polyolefin and ultra-high molecular weight polyethylene, ASA, polyolefin and cycloolefin, nylon it is mixed Close object, the mixture of polyolefin and cycloolefin, ASA, the mixture of polyolefin and nylon, ASA, polyolefin and polyamide, superelevation The mixture of molecular weight polyethylene, cycloolefin, polyolefin and polyamide, ultra-high molecular weight polyethylene, nylon mixture, polyene Hydrocarbon and polyamide, ultra-high molecular weight polyethylene, ASA mixture, polyolefin and polyamide, cycloolefin, nylon mixture, gather Alkene and polyamide, cycloolefin, ASA mixture, polyolefin and ultra-high molecular weight polyethylene, cycloolefin, nylon, ASA it is mixed Close object, polyolefin and polyamide, ultra-high molecular weight polyethylene, cycloolefin, nylon, ASA mixture.
Preferably, the polyolefin is one of polyethylene, polypropylene, ethylene-propylene copolymer and cycloolefin or extremely Few two kinds of mixture.Such as the polyolefin is polyethylene, polyacrylic mixture, polyethylene, ethylene-propylene copolymer Mixture, the mixture of polyethylene, cycloolefin, the mixture of polypropylene, ethylene-propylene copolymer, polypropylene, cycloolefin it is mixed Close object, the mixture of ethylene-propylene copolymer and cycloolefin, polyethylene, polypropylene, ethylene-propylene copolymer mixture, gather Ethylene, polypropylene, cycloolefin mixture, the mixture of polyethylene, ethylene-propylene copolymer and cycloolefin, polypropylene, second The mixture of alkene-propylene copolymer and cycloolefin, polyethylene, polypropylene, ethylene-propylene copolymer and cycloolefin mixture.
Preferably, the polyolefin blend is the copolymer of polyethylene and polyamide, the polyethylene and the polyamides The mass ratio of amine is (1:10)~(10:1), such as the mass ratio of the polyethylene and the polyamide is 1:1,1:2,1:3,1: 4、1:5、1:6、1:7、1:8、1:9、1:10、2:1、2:3、2:5、2:7、2:9、3:1、3:2、3:4、3:5、3:7、3:8、3:10、 4:1、4:3、4:5、4:7、4:9、5:1、5:2、5:3、5:4、5:6、5:7、5:8、5:9、6:1、6:5、6:7、7:1、7:2、7:3、 7:4、7:5、7:6、7:8、7:9、7:10、8:1、8:3、8:5、8:7、8:9、9:1、9:2、9:4、9:5、9:7、9:8、9:10、10: 1、10:3、10:7、10:9。
Preferably, the ultra-high molecular weight polyethylene is the polyethylene that molecular weight is 1,000,000 or more.
Preferably, the polyethylene is one of low density polyethylene (LDPE), high density polyethylene (HDPE), linear low density polyethylene Or at least two mixture, polyethylene improves the cohesive force of substrate and glue film.
Preferably, the auxiliary agent is the mixture of antioxidant and resistance to ultraviolet auxiliary agent.
Preferably, the mass ratio of the antioxidant and the resistance to ultraviolet auxiliary agent is (1:3)~(3:1), such as the antioxygen The mass ratio of agent and the resistance to ultraviolet auxiliary agent is 1:1,1:2,1:3,2:1,2:3,3:1,3:2.
The second object of the present invention is to provide a kind of preparation side of solar cell backboard substrate described in the first purpose Method, the preparation method is that, by weight, by 60~85 parts of polyolefin, 1~30 part of heat-resisting reinforced resin, 1~5 part Toughener, 1~5 part of compatilizer, 0~20 part of inorganic filler, 0~3 part of auxiliary agent and 0~30 part fire retardant be blended and squeeze It forms a film out, the solar cell backboard substrate with core layer is prepared.
The solar cell backboard substrate further includes adhesive layer, and the core layer and the adhesive layer pass through extrusion Film forming.
Wherein, the mode of the film extrusion is one of biaxial tension, simple tension, the tape casting or rolling process.
The third object of the present invention is to provide a kind of solar cell backboard, and the solar cell backboard includes successively Resistance to ultraviolet layer, glue layer, core layer, adhesive layer and/or the easy adhesive coating being arranged.
Wherein, one of for the purpose of the adhesive layer described in adhesive layer, pass through film extrusion；Easy adhesive coating is Coated on core layer or coated in adhesive layer by way of coating.
Wherein, the resistance to ultraviolet layer is resistance to ultraviolet fluorine film (for example, PVDF thin film) or resistance to ultraviolet PET (poly terephthalic acid Glycol ester, for example, the D269 type PET of Sichuan Dong Cai Science and Technology Ltd.) layer.
Preferably, the easy adhesive coating is fluorine-containing coat or acrylic acid coatings.
Compared with prior art, the invention has the benefit that
(1) solar cell backboard substrate of the invention has good water vapor rejection ability, and is provided simultaneously with good Thermal stability and mechanical performance, water vapor transmittance are 0.1~2.1g/m2Day, longitudinal percent thermal shrinkage are 0.02~0.04%, Lateral percent thermal shrinkage is 0.01~0.03%, and longitudinal tensile strength is 28~35MPa, and transverse tensile strength is 20~30MPa, is indulged It is 150~250% to break-draw rate, transverse breakage extensibility is 80~190%.
(2) solar cell backboard of the invention, molding is simple, can be recycled, and water vapor barrier property is good, viscous with packaging adhesive film Connecing property is excellent, cell piece can be prevented to be oxidized, and improves the generating efficiency of cell piece, extends the use of solar cell module Service life.
(3) preparation method of solar cell backboard substrate of the invention is simple, can be widely used for solar cell back The processing of plate.
Detailed description of the invention
Fig. 1 is first preferred embodiment that solar cell backboard of the invention forms；
Fig. 2 is second preferred embodiment that solar cell backboard of the invention forms；
Fig. 3 is the third preferred embodiment that solar cell backboard of the invention forms；
Appended drawing reference is as follows:
The resistance to ultraviolet layer of 1-；2- glue layer；3- core layer；The easy adhesive coating of 4-；5- adhesive layer.
Specific embodiment
1-3 with reference to the accompanying drawing, and pass through specific embodiment to further illustrate the technical scheme of the present invention.
Solar cell backboard substrate of the invention, the solar cell backboard substrate include core layer, by weight Meter, the core layer include following components:
Solar cell backboard of the invention, the solar cell backboard include resistance to ultraviolet layer, the glue set gradually Layer, core layer, adhesive layer and/or easy adhesive coating.Preferably, the solar cell backboard is from air side to electricity Pond piece surveys respectively resistance to ultraviolet layer 1, glue layer 2, core layer 3, easy adhesive coating 4, as shown in Figure 1；The solar battery back Plate surveys respectively resistance to ultraviolet layer 1, glue layer 2, core layer 3, adhesive layer 5 from air side to cell piece, as shown in Figure 2；It is described Solar cell backboard surveyed from air side to cell piece respectively resistance to ultraviolet layer 1, glue layer 2, core layer 3, adhesive layer 5, easily Adhesive coating 4, as shown in Figure 3.
Embodiment 1
By polyethylene 600g, polyethylene terephthalate 300g, ethylene-ethyl acetate copolymer-g- maleic anhydride 100g is mixed, then is used as core layer to prepare solar cell backboard substrate by biaxial tension film forming.
Embodiment 2
By polypropylene 500g, polybutylene terephthalate (PBT) 300g, polyolefin elastomer 50g, polypropylene-g- maleic acid Acid anhydride 100g, talcum powder 250g, is mixed, then as core layer prepares solar cell backboard substrate by casting film-forming.
Embodiment 3
By ethylene-propylene copolymer 850g, poly- 2,6-naphthalenedicarboxylic acid glycol ester 100g, ethylene propylene diene rubber 40g, second Alkene-methacrylate copolymer-g- glycidyl methacrylate 10g is mixed, then is formed a film and made by simple tension Solar cell backboard substrate is prepared for core layer.
Embodiment 4
By cycloolefin 800g, Isosorbide-5-Nitrae cyclohexanedimethanol polyester 150g, Polystyrene-Polyethylene-polybutene-polystyrene 20g, vinyl-acrylate copolymer-g- maleic anhydride 30g are mixed, then are used as core layer system by biaxial tension film forming Standby solar cell backboard substrate.
Embodiment 5
By polypropylene 700g, poly- 2,6-naphthalenedicarboxylic acid glycol ester 200g, vinyl-acrylate copolymer 30g, polyphenyl second Alkene-polybutene-polystyrene-g- glycidyl methacrylate 70g has halogen fire retardant 0.3g to be mixed, then passes through stream Prolong film forming as core layer and prepares solar cell backboard substrate.
Embodiment 6
By polypropylene 700g, polyethylene terephthalate 200g, vinyl-acrylate copolymer 30g, polyphenyl second Alkene-polybutene-polystyrene-g- glycidyl methacrylate 70g, halogen-free flame retardants 0.1g is mixed, as core material Layer；Again by low density polyethylene (LDPE) 60g, polypropylene 10g, polyethylene-polyamide copolymer 1 5g, titanium dioxide 5g, antioxidant 0.2g, resistance to ultraviolet auxiliary agent 0.5g are mixed, as adhesive layer, two layers by be cast co-extrusion form a film to obtain solar battery back Plate substrate.
Embodiment 7
By polypropylene 700g, TPEE 200g, vinyl-acrylate copolymer 30g, polystyrene-poly butylene-polyphenyl second Alkene-g- glycidyl methacrylate 70g is mixed, as core layer；Again by low density polyethylene (LDPE) 60g, polypropylene 10g, polyethylene-polyamide copolymer 1 5g, titanium dioxide 5g, antioxidant 0.2g, resistance to ultraviolet auxiliary agent 0.5g are mixed, as Adhesive layer, two layers by be cast co-extrusion form a film to obtain solar cell backboard substrate.
Comparative example 1
Polyethylene 1000g is prepared into solar cell backboard substrate as core layer by casting film-forming.
Comparative example 2
Polyethylene terephthalate 1000g is prepared into solar battery back as core layer by biaxial tension film forming Plate substrate.
Comparative example 3
By polypropylene 860g, polyethylene terephthalate 40g, vinyl-acrylate copolymer 30g, polystyrene- Polybutene-polystyrene-g- glycidyl methacrylate 70g is mixed, as core layer；Again by low density polyethylene (LDPE) 60g, polypropylene 10g, polyethylene-polyamide copolymer 1 5g, titanium dioxide 5g, antioxidant 0.2g, resistance to ultraviolet auxiliary agent 0.5g are carried out Mixing, as adhesive layer, two layers by curtain coating co-extrusion form a film to obtain solar cell backboard substrate.
Comparative example 4
By polypropylene 600g, polyethylene terephthalate 350g, vinyl-acrylate copolymer 10g, polyphenyl second Alkene-polybutene-polystyrene-g- glycidyl methacrylate 40g is mixed, as core layer；Low-density is gathered again Ethylene 60g, polypropylene 10g, polyethylene-polyamide copolymer 1 5g, titanium dioxide 5g, antioxidant 0.2g, resistance to ultraviolet auxiliary agent 0.5g Mixed, as adhesive layer, two layers by be cast co-extrusion form a film to obtain solar cell backboard substrate.
Comparative example 5
By polypropylene 600g, polyethylene terephthalate 250g, vinyl-acrylate copolymer 100g, polyphenyl second Alkene-polybutene-polystyrene-g- glycidyl methacrylate 50g is mixed, as core layer；Low-density is gathered again Ethylene 60g, polypropylene 10g, polyethylene-polyamide copolymer 1 5g, titanium dioxide 5g, antioxidant 0.2g, resistance to ultraviolet auxiliary agent 0.5g Mixed, as adhesive layer, two layers by be cast co-extrusion form a film to obtain solar cell backboard substrate.
Comparative example 6
By polyamide 700g, polyethylene terephthalate 200g, vinyl-acrylate copolymer 30g, polyphenyl second Alkene-polybutene-polystyrene-g- glycidyl methacrylate 70g is mixed, as core layer；Low-density is gathered again Ethylene 60g, polypropylene 10g, polyethylene-polyamide copolymer 1 5g, titanium dioxide 5g, antioxidant 0.2g, resistance to ultraviolet auxiliary agent 0.5g Mixed, as adhesive layer, two layers by be cast co-extrusion form a film to obtain solar cell backboard substrate.
This comparative example compared with Example 6, the difference is that, polyolefin replaces with polyamide, it is other with implementation Example 6 is identical.
Comparative example 7
By polypropylene 700g, polyethylene glycol 200 g, vinyl-acrylate copolymer 30g, polystyrene-poly butylene-polyphenyl Ethylene-g- glycidyl methacrylate 70g is mixed, as core layer；Again by low density polyethylene (LDPE) 60g, polypropylene 10g, polyethylene-polyamide copolymer 1 5g, titanium dioxide 5g, antioxidant 0.2g, resistance to ultraviolet auxiliary agent 0.5g are mixed, as Adhesive layer, two layers by be cast co-extrusion form a film to obtain solar cell backboard substrate.
This comparative example compared with Example 6, the difference is that, heat-resisting reinforced resin replaces with polyethylene glycol, other It is same as Example 6.
Comparative example 8
By polypropylene 700g, polyethylene terephthalate 200g, polyethers 30g, polystyrene-poly butylene-polyphenyl second Alkene-g- glycidyl methacrylate 70g is mixed, as core layer；Again by low density polyethylene (LDPE) 60g, polypropylene 10g, polyethylene-polyamide copolymer 1 5g, titanium dioxide 5g, antioxidant 0.2g, resistance to ultraviolet auxiliary agent 0.5g are mixed, as Adhesive layer layer, two layers by be cast co-extrusion form a film to obtain solar cell backboard substrate.
This comparative example compared with Example 6, the difference is that, toughener replaces with polyethers, it is other with embodiment 6 It is identical.
Embodiment 1-7 and solar cell backboard substrate made from comparative example 1-8 are tested for the property, test result is such as Shown in table 1.Wherein, the ability of thin-film barrier steam is determined by steam penetrating capacity experiment.Wherein, steam penetrating capacity It is lower, illustrate that water vapor rejection ability is stronger；Steam penetrating capacity is higher, illustrates that water vapor rejection ability is weaker.It is saturating to test vapor Instrument used in excess is U.S. MOCON moisture-inhibiting instrument.The mechanical performance of film is by the direction MD and TD tensile strength and breaks Extensibility is split to be measured.Wherein, tensile strength and break-draw rate are bigger, illustrate that the mechanical performance of film is better.Test Instrument used in mechanical performance is electronic universal tester AGS-X Shimadzu.The stability of film passes through test MD and the side TD To percent thermal shrinkage measured.Wherein, shrinking percentage is smaller, illustrates that thermal stability is better.Test is heat-shrinked used instrument Device is Nikon Quadratic Finite Element.
Table 1
As can be seen from Table 1, the present invention has by adjusting raw material and proportion, solar cell backboard substrate obtained Good water vapor rejection ability, and it is provided simultaneously with good thermal stability and mechanical performance, water vapor transmittance is 0.1~2.1g/ M2day, longitudinal percent thermal shrinkage are 0.02~0.04%, and lateral percent thermal shrinkage is 0.01~0.03%, and longitudinal tensile strength is 28~35MPa, transverse tensile strength are 20~30MPa, and longitudinal fracture extensibility is 150~250%, and transverse breakage extensibility is 80~190%, there is good flame retardant property,.Solar cell backboard of the invention, molding is simple, can be recycled, water vapor rejection Property is good, excellent with the cementability of packaging adhesive film, and cell piece can be prevented to be oxidized, improve the generating efficiency of cell piece, extended The service life of component.
Above embodiments are only used to illustrate method detailed of the invention, and the invention is not limited to above-mentioned method detaileds, i.e., Do not mean that the invention must rely on the above detailed methods to implement.It should be clear to those skilled in the art, right Any improvement of the invention, the addition of equivalence replacement and auxiliary element to each raw material of product of the present invention, the selection of concrete mode Deng all of which fall within the scope of protection and disclosure of the present invention.

Claims (10)

1.一种太阳能电池背板基材，其特征在于，所述太阳能电池背板基材包含芯材层，按重量份计，所述芯材层包含以下组分：1. A solar cell back sheet base material, characterized in that the solar cell back sheet base material comprises a core material layer, and in parts by weight, the core material layer comprises the following components: 2.根据权利要求1所述的太阳能电池背板基材，其特征在于，所述聚烯烃为聚乙烯、聚丙烯、乙烯-丙烯共聚物和环烯烃中的一种或至少两种的混合物。2 . The solar cell back sheet substrate according to claim 1 , wherein the polyolefin is one or a mixture of at least two of polyethylene, polypropylene, ethylene-propylene copolymer and cyclic olefin. 3 . 3.根据权利要求1或2所述的太阳能电池背板基材，其特征在于，所述耐热补强树脂为聚酯、聚酮、聚酰胺、环烯烃、塑性聚氨酯弹性体、聚酯与聚醚嵌段共聚物和矿物中的一种或至少两种的混合物；3. The solar cell back sheet substrate according to claim 1 or 2, wherein the heat-resistant reinforcing resin is polyester, polyketone, polyamide, cyclic olefin, plastic polyurethane elastomer, polyester and One or a mixture of at least two of a polyether block copolymer and a mineral; 优选地，所述聚酯为聚对苯二甲酸乙二醇酯、1,4环己烷二甲醇聚酯、聚对苯二甲酸丁二醇酯、聚2,6-萘二甲酸乙二醇酯和聚对苯二甲酸丙二醇酯中的一种或至少两种的混合物；Preferably, the polyester is polyethylene terephthalate, 1,4 cyclohexane dimethanol polyester, polybutylene terephthalate, polyethylene 2,6-naphthalate one or a mixture of at least two of esters and polytrimethylene terephthalate; 优选地，所述聚酰胺为尼龙6、尼龙12、尼龙612、尼龙1212和MXD6中一种或至少两种的混合物；Preferably, the polyamide is one or a mixture of at least two of nylon 6, nylon 12, nylon 612, nylon 1212 and MXD6; 优选地，所述矿物为滑石粉、碳黑、云母粉和硫酸钡中的一种或至少两种的混合物。Preferably, the mineral is one or a mixture of at least two of talc, carbon black, mica powder and barium sulfate. 4.根据权利要求1-3之一所述的太阳能电池背板基材，其特征在于，所述增韧剂为聚烯烃弹性体、三元乙丙橡胶、乙烯-醋酸乙酯共聚物、乙烯-甲基丙烯酸酯共聚物、乙烯-丙烯酸酯共聚物、丁苯橡胶、聚苯乙烯-聚乙烯-聚丁烯-聚苯乙烯、聚苯乙烯-聚丁烯-聚苯乙烯、ACR弹性体、甲基丙烯酸甲酯、丁二烯和苯乙烯三元共聚物中的一种或至少两种的混合物。4. The solar cell back sheet substrate according to any one of claims 1-3, wherein the toughening agent is polyolefin elastomer, EPDM rubber, ethylene-ethyl acetate copolymer, ethylene - methacrylate copolymer, ethylene-acrylate copolymer, styrene-butadiene rubber, polystyrene-polyethylene-polybutylene-polystyrene, polystyrene-polybutylene-polystyrene, ACR elastomers, One or a mixture of at least two of methyl methacrylate, butadiene and styrene terpolymers. 5.根据权利要求1-4之一所述的太阳能电池背板基材，其特征在于，所述相容剂为聚乙烯-g-马来酸酐、聚丙烯-g-马来酸酐、乙烯-丙烯共聚物-g-马来酸酐、聚乙烯-g-甲基丙烯酸缩水甘油酯、聚丙烯-g-甲基丙烯酸缩水甘油酯、乙烯-丙烯共聚物-g-甲基丙烯酸缩水甘油酯、聚烯烃弹性体-g-马来酸酐、二元乙丙橡胶-g-马来酸酐、三元乙丙橡胶-g-马来酸酐、乙烯-醋酸乙酯共聚物-g-马来酸酐、乙烯-甲基丙烯酸酯共聚物-g-马来酸酐、乙烯-丙烯酸酯共聚物-g-马来酸酐、丁苯橡胶-g-马来酸酐、聚苯乙烯-聚乙烯-聚丁烯-聚苯乙烯-g-马来酸酐、聚苯乙烯-聚丁烯-聚苯乙烯-g-马来酸酐、聚烯烃弹性体-g-甲基丙烯酸缩水甘油酯、二元乙丙橡胶-g-甲基丙烯酸缩水甘油酯、三元乙丙橡胶-g-甲基丙烯酸缩水甘油酯、乙烯-醋酸乙酯共聚物-g-甲基丙烯酸缩水甘油酯、乙烯-甲基丙烯酸酯共聚物-g-甲基丙烯酸缩水甘油酯、乙烯-丙烯酸酯共聚物-g-甲基丙烯酸缩水甘油酯、丁苯橡胶-g-甲基丙烯酸缩水甘油酯、聚苯乙烯-聚乙烯-聚丁烯-聚苯乙烯-g-甲基丙烯酸缩水甘油酯和聚苯乙烯-聚丁烯-聚苯乙烯-g-甲基丙烯酸缩水甘油酯中的一种或至少两种的混合物；5. The solar cell backsheet substrate according to one of claims 1-4, wherein the compatibilizer is polyethylene-g-maleic anhydride, polypropylene-g-maleic anhydride, ethylene- Propylene copolymer-g-maleic anhydride, polyethylene-g-glycidyl methacrylate, polypropylene-g-glycidyl methacrylate, ethylene-propylene copolymer-g-glycidyl methacrylate, poly Olefin elastomer-g-maleic anhydride, ethylene-propylene-diene rubber-g-maleic anhydride, ethylene-propylene-diene rubber-g-maleic anhydride, ethylene-ethyl acetate copolymer-g-maleic anhydride, ethylene- Methacrylate copolymer-g-maleic anhydride, ethylene-acrylate copolymer-g-maleic anhydride, styrene-butadiene rubber-g-maleic anhydride, polystyrene-polyethylene-polybutylene-polystyrene -g-maleic anhydride, polystyrene-polybutylene-polystyrene-g-maleic anhydride, polyolefin elastomers-g-glycidyl methacrylate, ethylene propylene diene rubber-g-methacrylic acid Glycidyl ester, EPDM rubber-g-glycidyl methacrylate, ethylene-ethyl acetate copolymer-g-glycidyl methacrylate, ethylene-methacrylate copolymer-g-methacrylic acid Glycidyl ester, ethylene-acrylate copolymer-g-glycidyl methacrylate, styrene butadiene rubber-g-glycidyl methacrylate, polystyrene-polyethylene-polybutene-polystyrene-g- One or a mixture of at least two of glycidyl methacrylate and polystyrene-polybutylene-polystyrene-g-glycidyl methacrylate; 优选地，所述无机填料为滑石粉、钛白粉、蒙脱土、晶须、云母粉和碳酸钙中的一种或至少两种的混合物；Preferably, the inorganic filler is one or a mixture of at least two of talc, titanium dioxide, montmorillonite, whisker, mica powder and calcium carbonate; 优选地，所述助剂为抗氧剂和/或耐水解剂；Preferably, the auxiliary agent is an antioxidant and/or a hydrolysis-resistant agent; 优选地，所述阻燃剂为有卤阻燃剂、无卤阻燃剂或无机物中的一种；Preferably, the flame retardant is one of halogenated flame retardant, halogen-free flame retardant or inorganic; 优选地，所述阻燃剂为氢氧化铝、氢氧化镁或溴苯中的一种。Preferably, the flame retardant is one of aluminum hydroxide, magnesium hydroxide or bromobenzene. 6.根据权利要求1-5之一所述的太阳能电池背板基材，其特征在于，所述太阳能电池背板基材由芯材层和易粘接层构成；6. The solar cell backplane substrate according to any one of claims 1-5, wherein the solar cell backplane substrate is composed of a core material layer and an easy-bonding layer; 优选地，按重量份计，所述易粘接层包含以下组分：Preferably, in parts by weight, the easy-bonding layer comprises the following components: 优选地，所述无机填料为钛白粉或炭黑；Preferably, the inorganic filler is titanium dioxide or carbon black; 优选地，所述聚烯烃混合物为聚烯烃与聚酰胺、超高分子量聚乙烯、环烯烃、尼龙或ASA中的至少一种的混合物；Preferably, the polyolefin mixture is a mixture of polyolefin and at least one of polyamide, ultra-high molecular weight polyethylene, cyclic olefin, nylon or ASA; 优选地，所述聚烯烃为聚乙烯、聚丙烯、乙烯-丙烯共聚物和环烯烃中的一种或至少两种的混合物；Preferably, the polyolefin is one or a mixture of at least two of polyethylene, polypropylene, ethylene-propylene copolymer and cyclic olefin; 优选地，所述聚烯烃混合物为聚乙烯与聚酰胺的共聚物，所述聚乙烯和所述聚酰胺的质量比为(1:10)～(10:1)；Preferably, the polyolefin mixture is a copolymer of polyethylene and polyamide, and the mass ratio of the polyethylene to the polyamide is (1:10)～(10:1); 优选地，所述超高分子量聚乙烯为分子量为100万以上的聚乙烯；Preferably, the ultra-high molecular weight polyethylene is polyethylene with a molecular weight of more than 1 million; 优选地，所述聚乙烯为低密度聚乙烯、高密度聚乙烯、线性低密度聚乙烯中的一种或至少两种的混合物；Preferably, the polyethylene is one or a mixture of at least two of low density polyethylene, high density polyethylene and linear low density polyethylene; 优选地，所述助剂为抗氧剂和耐紫外助剂的混合物；Preferably, the auxiliary agent is a mixture of antioxidant and UV-resistant auxiliary agent; 优选地，所述抗氧剂与所述耐紫外助剂的质量比为(1:3)～(3:1)。Preferably, the mass ratio of the antioxidant to the UV-resistant auxiliary is (1:3) to (3:1). 7.一种如权利要求1所述的太阳能电池背板基材的制备方法，其特征在于，所述制备方法为，按重量份计，将60～85份的聚烯烃、1～30份的耐热补强树脂、1～5份的增韧剂、1～5份的相容剂、0～20份的无机填料、0～3份的助剂和0～30份的阻燃剂共混挤出成膜，制备得到具有芯材层的太阳能电池背板基材。7 . The method for preparing a base material for a solar cell back sheet according to claim 1 , wherein the preparation method comprises, by weight, 60-85 parts of polyolefin, 1-30 parts of polyolefin Heat-resistant reinforcing resin, 1-5 parts of toughening agent, 1-5 parts of compatibilizer, 0-20 parts of inorganic filler, 0-3 parts of auxiliary agent and 0-30 parts of flame retardant are blended Extrusion into a film to prepare a solar cell back sheet substrate with a core material layer. 8.根据权利要求7所述的制备方法，其特征在于，所述太阳能电池背板基材还包括易粘接层，所述芯材层和所述易粘接层通过挤出成膜；8 . The preparation method according to claim 7 , wherein the solar cell backsheet base material further comprises an easy-bonding layer, and the core material layer and the easy-bonding layer are formed into a film by extrusion; 8 . 优选地，所述挤出成膜的方式为双向拉伸、单向拉伸、流延法或压延法中的一种。Preferably, the extrusion film forming method is one of biaxial stretching, uniaxial stretching, casting method or calendering method. 9.一种太阳能电池背板，其特征在于，所述太阳能电池背板包括依次设置的耐紫外层、胶水层、权利要求1所述的芯材层、易粘接层和/或易粘接涂层。9. A solar cell back sheet, characterized in that the solar cell back sheet comprises a UV-resistant layer, a glue layer, the core material layer according to claim 1, an easy-bonding layer and/or an easy-bonding layer arranged in sequence coating. 10.根据权利要求9所述的太阳能电池背板，其特征在于，所述耐紫外层为耐紫外氟膜或耐紫外PET层；10. The solar cell back sheet according to claim 9, wherein the UV-resistant layer is a UV-resistant fluorine film or a UV-resistant PET layer; 优选地，所述易粘接涂层为含氟涂层或丙烯酸涂层。Preferably, the easy-bonding coating is a fluorine-containing coating or an acrylic coating.
CN201811241650.XA 2018-10-24 2018-10-24 A kind of solar cell backboard substrate and preparation method and solar cell backboard Withdrawn CN109485965A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811241650.XA CN109485965A (en) 2018-10-24 2018-10-24 A kind of solar cell backboard substrate and preparation method and solar cell backboard

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811241650.XA CN109485965A (en) 2018-10-24 2018-10-24 A kind of solar cell backboard substrate and preparation method and solar cell backboard

Publications (1)

Publication Number Publication Date
CN109485965A true CN109485965A (en) 2019-03-19

Family

ID=65692633

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201811241650.XA Withdrawn CN109485965A (en) 2018-10-24 2018-10-24 A kind of solar cell backboard substrate and preparation method and solar cell backboard

Country Status (1)

Country Link
CN (1) CN109485965A (en)

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110183745A (en) * 2019-05-30 2019-08-30 苏州赛伍应用技术股份有限公司 A kind of enhancing wear-resisting type is crosslinked integrated backboard and preparation method thereof
CN110254007A (en) * 2019-05-27 2019-09-20 四川东方绝缘材料股份有限公司 A kind of high partial discharge voltage photovoltaic back basement membrane and preparation method thereof
CN110993711A (en) * 2019-11-05 2020-04-10 乐凯胶片股份有限公司 Polyester base film for solar back sheet and solar back sheet
CN111154237A (en) * 2020-01-14 2020-05-15 长春工业大学 A kind of polyethylene terephthalate/high density polyethylene blend and preparation method thereof
CN112409938A (en) * 2020-11-11 2021-02-26 乐凯胶片股份有限公司 Photovoltaic back sheet, method for preparing photovoltaic back sheet and photovoltaic module
CN112701177A (en) * 2020-12-28 2021-04-23 江苏双星彩塑新材料股份有限公司 PET (polyethylene terephthalate) base material for low-shrinkage solar cell backboard
CN112959770A (en) * 2021-02-05 2021-06-15 浙江中聚材料有限公司 Extrusion type solar photovoltaic backboard and preparation process thereof
CN113279084A (en) * 2021-06-19 2021-08-20 雅香丽化妆用品（深圳）有限公司 Anti-aging wear-resistant brush wire and preparation method thereof
CN113635578A (en) * 2021-05-25 2021-11-12 浙江玖邦科技有限公司 Preparation method of fuel cell protective film
CN114055894A (en) * 2021-10-13 2022-02-18 潍坊同有新材料科技有限公司 A kind of TPEE acoustic film and preparation method thereof
CN114639748A (en) * 2021-03-31 2022-06-17 浙江中聚材料有限公司 Super-toughness solar photovoltaic back plate and preparation method and application thereof
CN114702911A (en) * 2021-12-15 2022-07-05 浙江中聚材料有限公司 A fluorine-free environment-friendly photovoltaic backplane and its application
CN114736629A (en) * 2022-01-27 2022-07-12 浙江中聚材料有限公司 A kind of high-barrier flame-retardant backboard and preparation method thereof
CN115584082A (en) * 2022-10-10 2023-01-10 苏州优矿塑新材料股份有限公司 AB material for directly forming back plate film and preparation method thereof
CN115850865A (en) * 2022-12-29 2023-03-28 江阴瑞林精密机械制造有限公司 Photovoltaic corrosion-resistant anti-aging polypropylene plate and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107204384A (en) * 2016-03-16 2017-09-26 上海海优威新材料股份有限公司 Three layers of integral structure solar cell backboard and preparation method thereof
CN108329586A (en) * 2018-01-30 2018-07-27 苏州赛伍应用技术股份有限公司 A kind of three-decker water vapor rejection film and preparation method thereof
CN108456351A (en) * 2018-01-30 2018-08-28 苏州赛伍应用技术股份有限公司 A kind of water vapor rejection film and preparation method thereof
CN207818584U (en) * 2018-01-24 2018-09-04 苏州赛伍应用技术股份有限公司 A kind of photovoltaic cell fabric backplanes

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107204384A (en) * 2016-03-16 2017-09-26 上海海优威新材料股份有限公司 Three layers of integral structure solar cell backboard and preparation method thereof
CN207818584U (en) * 2018-01-24 2018-09-04 苏州赛伍应用技术股份有限公司 A kind of photovoltaic cell fabric backplanes
CN108329586A (en) * 2018-01-30 2018-07-27 苏州赛伍应用技术股份有限公司 A kind of three-decker water vapor rejection film and preparation method thereof
CN108456351A (en) * 2018-01-30 2018-08-28 苏州赛伍应用技术股份有限公司 A kind of water vapor rejection film and preparation method thereof

Cited By (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110254007A (en) * 2019-05-27 2019-09-20 四川东方绝缘材料股份有限公司 A kind of high partial discharge voltage photovoltaic back basement membrane and preparation method thereof
CN110183745B (en) * 2019-05-30 2021-11-23 苏州赛伍应用技术股份有限公司 Reinforced wear-resistant cross-linked integrated backboard and preparation method thereof
CN110183745A (en) * 2019-05-30 2019-08-30 苏州赛伍应用技术股份有限公司 A kind of enhancing wear-resisting type is crosslinked integrated backboard and preparation method thereof
CN110993711A (en) * 2019-11-05 2020-04-10 乐凯胶片股份有限公司 Polyester base film for solar back sheet and solar back sheet
CN110993711B (en) * 2019-11-05 2022-03-04 乐凯胶片股份有限公司 Polyester base film for solar back sheet and solar back sheet
CN111154237A (en) * 2020-01-14 2020-05-15 长春工业大学 A kind of polyethylene terephthalate/high density polyethylene blend and preparation method thereof
CN112409938A (en) * 2020-11-11 2021-02-26 乐凯胶片股份有限公司 Photovoltaic back sheet, method for preparing photovoltaic back sheet and photovoltaic module
CN112409938B (en) * 2020-11-11 2022-07-22 乐凯胶片股份有限公司 Photovoltaic back sheet, method for preparing photovoltaic back sheet and photovoltaic assembly
CN112701177B (en) * 2020-12-28 2022-01-11 江苏双星彩塑新材料股份有限公司 A PET substrate for low shrinkage solar cell backsheet
CN112701177A (en) * 2020-12-28 2021-04-23 江苏双星彩塑新材料股份有限公司 PET (polyethylene terephthalate) base material for low-shrinkage solar cell backboard
CN112959770A (en) * 2021-02-05 2021-06-15 浙江中聚材料有限公司 Extrusion type solar photovoltaic backboard and preparation process thereof
CN114639748A (en) * 2021-03-31 2022-06-17 浙江中聚材料有限公司 Super-toughness solar photovoltaic back plate and preparation method and application thereof
CN114639748B (en) * 2021-03-31 2024-04-12 浙江中聚材料有限公司 A super-tough solar photovoltaic backsheet and its preparation method and application
CN113635578B (en) * 2021-05-25 2023-07-18 浙江玖邦科技有限公司 Preparation method of fuel cell protective film
CN113635578A (en) * 2021-05-25 2021-11-12 浙江玖邦科技有限公司 Preparation method of fuel cell protective film
CN113279084A (en) * 2021-06-19 2021-08-20 雅香丽化妆用品（深圳）有限公司 Anti-aging wear-resistant brush wire and preparation method thereof
CN114055894A (en) * 2021-10-13 2022-02-18 潍坊同有新材料科技有限公司 A kind of TPEE acoustic film and preparation method thereof
CN114702911A (en) * 2021-12-15 2022-07-05 浙江中聚材料有限公司 A fluorine-free environment-friendly photovoltaic backplane and its application
CN114702911B (en) * 2021-12-15 2024-03-08 浙江中聚材料有限公司 Fluorine-free environment-friendly photovoltaic backboard and application thereof
CN114736629A (en) * 2022-01-27 2022-07-12 浙江中聚材料有限公司 A kind of high-barrier flame-retardant backboard and preparation method thereof
CN114736629B (en) * 2022-01-27 2024-02-27 浙江中聚材料有限公司 High-barrier flame-retardant backboard and preparation method thereof
CN115584082A (en) * 2022-10-10 2023-01-10 苏州优矿塑新材料股份有限公司 AB material for directly forming back plate film and preparation method thereof
CN115850865A (en) * 2022-12-29 2023-03-28 江阴瑞林精密机械制造有限公司 Photovoltaic corrosion-resistant anti-aging polypropylene plate and preparation method thereof

Similar Documents

Publication Publication Date Title
CN109485965A (en) A kind of solar cell backboard substrate and preparation method and solar cell backboard
CN102569452B (en) Polymer back panel of solar battery assembly and manufacture method of polymer back panel
CN102431239B (en) Polymer lithium ion battery core outer package forming material
CN105934831B (en) The solar cell backboard and its manufacture method of wet-heat resisting
CN103158312B (en) A kind of solar cell module back veneer and manufacture method thereof
CN102529258B (en) Improved solar cell assembly back plate and manufacturing method thereof
CN102544152B (en) Solar battery back panel and preparation method therefor
EP1249338A2 (en) Outer covering for solar battery
CN110315823A (en) A kind of high-efficiency solar photovoltaic battery backboard and preparation method thereof
CN103066141B (en) Modified polypropylene resin composition and solar energy rear panel made of the same
CN105870237A (en) Co-extruded one-time formed backplate with three-layer structure for solar cell module
CN104327433A (en) Preparation method of polyvinylidene fluoride-based thin film
WO2012029499A1 (en) 1,4-cyclohexylenedimethylene terephthalate/1,4-cyclohexylene­dimethylene isophthalate copolymer films, protective sheets for a solar cell module, and solar cell module
CN103897265B (en) Resin combination and preparation method for solar energy backboard base material
CN106229366A (en) A kind of novel solar battery backboard and assembly thereof and preparation method
TW201335262A (en) Solar cell module with good appearance and manufacturing method thereof
CN108034377A (en) A kind of glued membrane backboard integrated material and its preparation process
CN103057228B (en) Composition of solar energy backboard and preparation method thereof
CN109411558B (en) A kind of solar cell back sheet and preparation method thereof
CN103895304A (en) Solar energy back panel and preparation method thereof
CN102653154A (en) Self-adhesive polyvinylidene fluoride thin film and solar photovoltaic cell backsheet prepared by using same
CN103897266B (en) A kind of resin combination for sun power backboard base material
CN104538474B (en) A kind of backplane for photovoltaic cells and preparation method thereof
JP5700415B2 (en) Polyester film for solar cell back surface protection material
CN105848895A (en) Multi-layered sheet, solar cell back sheet, and solar cell module

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WW01 Invention patent application withdrawn after publication

Application publication date: 20190319

WW01 Invention patent application withdrawn after publication