CN109437585B - Manufacturing method of anti-skid glass - Google Patents
Manufacturing method of anti-skid glass Download PDFInfo
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- CN109437585B CN109437585B CN201811351572.9A CN201811351572A CN109437585B CN 109437585 B CN109437585 B CN 109437585B CN 201811351572 A CN201811351572 A CN 201811351572A CN 109437585 B CN109437585 B CN 109437585B
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- glass
- silk
- screen printing
- printing ink
- skid
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
- C03C17/008—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character comprising a mixture of materials covered by two or more of the groups C03C17/02, C03C17/06, C03C17/22 and C03C17/28
- C03C17/009—Mixtures of organic and inorganic materials, e.g. ormosils and ormocers
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C15/00—Surface treatment of glass, not in the form of fibres or filaments, by etching
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/40—Coatings comprising at least one inhomogeneous layer
- C03C2217/43—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
- C03C2217/44—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the composition of the continuous phase
- C03C2217/445—Organic continuous phases
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/40—Coatings comprising at least one inhomogeneous layer
- C03C2217/43—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
- C03C2217/46—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase
- C03C2217/47—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase consisting of a specific material
- C03C2217/475—Inorganic materials
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
- C03C2217/77—Coatings having a rough surface
- C03C2217/775—Coatings having a rough surface to provide anti-slip characteristics
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/11—Deposition methods from solutions or suspensions
- C03C2218/119—Deposition methods from solutions or suspensions by printing
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Wood Science & Technology (AREA)
- Geochemistry & Mineralogy (AREA)
- Inorganic Chemistry (AREA)
- Composite Materials (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Paints Or Removers (AREA)
Abstract
The invention provides a manufacturing method of anti-skid glass, which is characterized by comprising the following steps: putting the glass fragments into a glass crusher to be crushed to obtain glass powder; placing glass powder into a reaction kettle, adding a mixed acid solution containing hydrofluoric acid into the reaction kettle, starting a stirring paddle, and carrying out hydrothermal reaction at the temperature of 50-70 ℃; filtering the mixture in the reaction kettle to obtain glass particles with smooth and non-angular surfaces after reaction; adding the glass particles into the thermosetting ink, and uniformly mixing to obtain the silk-screen printing ink; printing silk-screen printing ink on the plane glass by a silk-screen printing process; and (3) placing the plane glass printed with the silk-screen printing ink into a tempering furnace, softening the plane glass at the temperature of 350-450 ℃, fusing the plane glass with the silk-screen printing ink, and cooling to obtain the anti-skid glass. The manufacturing method of the anti-skid glass provided by the invention is simple to operate, the manufactured glass is stable in structure, the silk-screen printing ink is not easy to fall off, and the anti-skid performance is good.
Description
Technical Field
The invention relates to the field of glass processing, in particular to a manufacturing method of anti-skid glass.
Background
With the increasing demand for resource protection and human living environment protection, the modern glass industry is facing a serious challenge of recycling glass production waste. A series of waste materials are generated in the glass production process, including waste water, waste gas and solid waste materials, and the waste water and the waste gas can be recycled to generate the solid waste materials. Some solid wastes contain toxic substances and need special treatment by manufacturers, thus greatly increasing the production cost. Deep burial of toxic waste is not a good solution. Therefore, how to treat the waste glass becomes an extremely important issue.
In order to solve the problem, a processing technology for manufacturing anti-skid glass by using waste glass appears, and in the processing technology for anti-skid glass, application number 201710881424.7, waste ultra-white glass is crushed into glass powder by glass crushing equipment, the glass powder, fluorescent powder and silica gel particles are mixed to form an anti-skid material, the anti-skid material is adhered to the surface of the glass by glue, and the anti-skid material is scattered on the glue, so that the anti-skid glass is manufactured. Due to the bonding of the glue and the glass, the glue is easy to fall off, and the anti-slip material is also easy to fall off a glue layer in the using process, so that the defect is large.
Disclosure of Invention
Aiming at the problems, the invention provides the manufacturing method of the anti-skid glass, the operation is simple, the manufactured glass has a stable structure, the silk-screen printing ink is not easy to fall off, and the anti-skid performance is good.
In order to achieve the purpose, the invention is solved by the following technical scheme:
the manufacturing method of the anti-skid glass is characterized by comprising the following steps:
s1, collecting glass fragments, cleaning and drying for later use;
s2, putting the glass fragments into a glass crusher for crushing, screening out small-particle glass powder by using a 300-400-mesh screen plate, and screening the rest glass powder by using a 70-100-mesh screen plate to obtain glass powder with the particle size of 40-200 mu m;
s3, placing the glass powder finally obtained in the step S2 into a reaction kettle, adding a mixed acid solution containing hydrofluoric acid into the reaction kettle, starting a stirring paddle, and carrying out hydrothermal reaction at the temperature of 50-70 ℃ for 20-30 min;
s4, filtering the mixture in the reaction kettle to obtain glass particles with smooth and non-angular surfaces after reaction;
s5, adding the glass particles into the thermosetting ink, and uniformly mixing to obtain silk-screen printing ink;
s6, printing silk-screen printing ink on the plane glass through a silk-screen printing process;
s7, placing the plane glass printed with the silk-screen printing ink in a tempering furnace, softening the plane glass at the temperature of 350-450 ℃, fusing the plane glass with the silk-screen printing ink, and cooling to obtain the anti-skid glass.
Specifically, the rotating speed of the stirring paddle in the step S3 is 30-40 rpm.
Specifically, the mixed acid solution in step S3 is a mixed solution of hydrofluoric acid, hydrochloric acid and water, and the mass ratio of the hydrofluoric acid to the hydrochloric acid to the water is 1: 10: 100.
specifically, the surface roughness Ra of the non-slip glass in the step S7 is 1-5 μm.
Specifically, the thermosetting ink in the step S5 is composed of the following components in parts by weight:
35-45 parts of polyvinyl chloride, 30-40 parts of phthalate, 5-8 parts of talcum powder, 1-5 parts of stabilizer and 1-3 parts of thickener.
Specifically, the stabilizer is barium stearate or calcium stearate.
Specifically, the thickening agent is an acrylate polymer.
The invention has the beneficial effects that:
firstly, the method for manufacturing the anti-skid glass utilizes the waste glass fragments as raw materials to manufacture the anti-skid glass, and recycles the waste glass fragments, thereby saving energy and protecting environment;
secondly, in the manufacturing process, the crushed glass powder is stirred and subjected to acid etching, sharp edges and corners of the glass powder can be polished, the surface of the glass powder is smooth and has no edges and corners, and the safety of the anti-skid glass is improved;
thirdly, adding the glass powder into the silk-screen printing ink, and manufacturing the anti-skid layer by utilizing a conventional silk-screen printing process, wherein the operation is simple and the process is mature;
fourthly, after silk-screen printing, the plane glass is placed in a tempering furnace to be softened, the softened plane glass and the silk-screen printing ink are melted into a whole, and the cooled plane glass and the silk-screen printing ink are integrally formed, so that the adhesive force of the silk-screen printing ink is improved, the silk-screen printing ink is not easy to fall off, and the stability is good.
Detailed Description
The present invention will be described in further detail with reference to specific embodiments in order to provide a further understanding of the nature and technical means of the invention, as well as the specific objects and functions attained by the invention.
Example 1
The manufacturing method of the anti-skid glass is characterized by comprising the following steps:
s1, collecting glass fragments, cleaning and drying for later use;
s2, putting the glass fragments into a glass crusher for crushing, screening out small-particle glass powder by using a 400-mesh screen plate, and then screening the rest glass powder by using a 700-mesh screen plate to obtain glass powder with the particle size of 40-200 mu m;
s3, placing the glass powder finally obtained in the step S2 into a reaction kettle, adding a mixed acid solution containing hydrofluoric acid into the reaction kettle, starting a stirring paddle, controlling the rotating speed of the stirring paddle to be 30rpm, carrying out hydrothermal reaction at the temperature of 50 ℃, wherein the reaction time is 30min, and because of the rotation of the stirring paddle, when the glass powder reacts with the low-concentration hydrofluoric acid, the edge angles on the surface of the glass powder are fully reacted and rubbed with the inner wall of the reaction kettle, so that the glass powder forms a smooth surface;
s4, filtering the mixture in the reaction kettle to obtain glass particles with smooth and non-angular surfaces after reaction;
s5, adding the glass particles into the thermosetting ink, and uniformly mixing to obtain silk-screen printing ink;
s6, printing silk-screen printing ink on the plane glass through a silk-screen printing process;
s7, placing the plane glass printed with the silk-screen printing ink into a tempering furnace, softening the plane glass at the temperature of 400 ℃, fusing the plane glass with the silk-screen printing ink, and cooling to obtain the anti-skid glass with the surface roughness Ra of 2.5 mu m.
Preferably, the mixed acid solution in step S3 is a mixed solution of hydrofluoric acid, hydrochloric acid and water, and the mass ratio of hydrofluoric acid, hydrochloric acid and water is 1: 10: 100.
preferably, the thermosetting ink in step S5 is composed of the following components in parts by weight:
45 parts of polyvinyl chloride, 40 parts of phthalate, 7 parts of talcum powder, 2 parts of barium stearate and 2 parts of acrylic polymer.
Example 2
The manufacturing method of the anti-skid glass is characterized by comprising the following steps:
s1, collecting glass fragments, cleaning and drying for later use;
s2, putting the glass fragments into a glass crusher for crushing, screening out small-particle glass powder by using a 300-mesh screen plate, and then screening the rest glass powder by using a 100-mesh screen plate to obtain glass powder with the particle size of 46-150 mu m;
s3, placing the glass powder finally obtained in the step S2 into a reaction kettle, adding a mixed acid solution containing hydrofluoric acid into the reaction kettle, starting a stirring paddle, controlling the rotating speed of the stirring paddle to be 30rpm, carrying out hydrothermal reaction at the temperature of 60 ℃, wherein the reaction time is 20min, and because of the rotation of the stirring paddle, when the glass powder reacts with the low-concentration hydrofluoric acid, the edge angles on the surface of the glass powder are fully reacted and rubbed with the inner wall of the reaction kettle, so that the glass powder forms a smooth surface;
s4, filtering the mixture in the reaction kettle to obtain glass particles with smooth and non-angular surfaces after reaction;
s5, adding the glass particles into the thermosetting ink, and uniformly mixing to obtain silk-screen printing ink;
s6, printing silk-screen printing ink on the plane glass through a silk-screen printing process;
s7, placing the plane glass printed with the silk-screen printing ink into a tempering furnace, softening the plane glass at the temperature of 400 ℃, fusing the plane glass with the silk-screen printing ink, and cooling to obtain the anti-skid glass with the surface roughness Ra of 2 mu m.
Preferably, the mixed acid solution in step S3 is a mixed solution of hydrofluoric acid, hydrochloric acid and water, and the mass ratio of hydrofluoric acid, hydrochloric acid and water is 1: 10: 100.
preferably, the thermosetting ink in step S5 is composed of the following components in parts by weight:
40 parts of polyvinyl chloride, 35 parts of phthalate, 5 parts of talcum powder, 2 parts of barium stearate and 2 parts of acrylic polymer.
The above examples only show 2 embodiments of the present invention, and the description thereof is more specific and detailed, but not construed as limiting the scope of the present invention. It should be noted that, for a person skilled in the art, several variations and modifications can be made without departing from the inventive concept, which falls within the scope of the present invention. Therefore, the protection scope of the present patent shall be subject to the appended claims.
Claims (7)
1. The manufacturing method of the anti-skid glass is characterized by comprising the following steps:
s1, collecting glass fragments, cleaning and drying for later use;
s2, putting the glass fragments into a glass crusher for crushing, screening out small-particle glass powder by using a 300-400-mesh screen plate, and screening the rest glass powder by using a 70-100-mesh screen plate to obtain glass powder with the particle size of 40-200 mu m;
s3, placing the glass powder finally obtained in the step S2 into a reaction kettle, adding a mixed acid solution containing hydrofluoric acid into the reaction kettle, starting a stirring paddle, and carrying out hydrothermal reaction at the temperature of 50-70 ℃ for 20-30 min;
s4, filtering the mixture in the reaction kettle to obtain glass particles with smooth and non-angular surfaces after reaction;
s5, adding the glass particles into the thermosetting ink, and uniformly mixing to obtain silk-screen printing ink;
s6, printing silk-screen printing ink on the plane glass through a silk-screen printing process;
s7, placing the plane glass printed with the silk-screen printing ink in a tempering furnace, softening the plane glass at the temperature of 350-450 ℃, fusing the plane glass with the silk-screen printing ink, and cooling to obtain the anti-skid glass.
2. The method according to claim 1, wherein the rotation speed of the stirring paddle in step S3 is 30-40 rpm.
3. The method for manufacturing non-slip glass according to claim 1, wherein the mixed acid solution in the step S3 is a mixed solution of hydrofluoric acid, hydrochloric acid and water, and the mass ratio of the hydrofluoric acid to the hydrochloric acid to the water is 1: 10: 100.
4. the method according to claim 1, wherein the surface roughness Ra of the non-slip glass in the step S7 is 1-5 μm.
5. The method for manufacturing non-slip glass according to claim 1, wherein the thermosetting ink in the step S5 comprises the following components in parts by weight:
35-45 parts of polyvinyl chloride, 30-40 parts of phthalate, 5-8 parts of talcum powder, 1-5 parts of stabilizer and 1-3 parts of thickener.
6. The method for manufacturing the anti-slip glass according to claim 5, wherein the stabilizer is barium stearate or calcium stearate.
7. The method for manufacturing the anti-slip glass according to claim 5, wherein the thickening agent is an acrylate polymer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811351572.9A CN109437585B (en) | 2018-11-14 | 2018-11-14 | Manufacturing method of anti-skid glass |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811351572.9A CN109437585B (en) | 2018-11-14 | 2018-11-14 | Manufacturing method of anti-skid glass |
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| Publication Number | Publication Date |
|---|---|
| CN109437585A CN109437585A (en) | 2019-03-08 |
| CN109437585B true CN109437585B (en) | 2021-10-08 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201811351572.9A Active CN109437585B (en) | 2018-11-14 | 2018-11-14 | Manufacturing method of anti-skid glass |
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Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN111925125B (en) * | 2020-07-21 | 2022-12-20 | 安徽友坤玻璃有限责任公司 | Acid-etched anti-skid glass and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101792263B (en) * | 2010-04-19 | 2012-10-10 | 君达环保科技（宝鸡）有限公司 | Whole-body crystallized glass frosted skid-proof sheet material and manufacturing method thereof |
| ES2438441B1 (en) * | 2012-06-14 | 2014-10-22 | Onyx Solar Energy, S.L. | TRANSITABLE PHOTOVOLTAIC SOIL. |
| CN103011609A (en) * | 2012-12-03 | 2013-04-03 | 林鲜艳 | Method for manufacturing decorative glass |
| CN107640905B (en) * | 2017-03-29 | 2020-05-19 | 谢晓元 | Boron glass anti-skid particle blank and preparation process thereof, and anti-skid toughened glass and preparation process thereof |
| CN107651862B (en) * | 2017-09-26 | 2020-04-17 | 东莞泰升玻璃有限公司 | Anti-skid glass processing technology |
| CN107579130A (en) * | 2017-10-12 | 2018-01-12 | 成都中建材光电材料有限公司 | The preparation and its application of a kind of photovoltaic road brick |
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