Nothing Special   »   [go: up one dir, main page]

CN109401519A - A kind of bituminous pavement repair materials - Google Patents

A kind of bituminous pavement repair materials Download PDF

Info

Publication number
CN109401519A
CN109401519A CN201811529638.9A CN201811529638A CN109401519A CN 109401519 A CN109401519 A CN 109401519A CN 201811529638 A CN201811529638 A CN 201811529638A CN 109401519 A CN109401519 A CN 109401519A
Authority
CN
China
Prior art keywords
parts
thermosetting
polymer
rubber
variety
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201811529638.9A
Other languages
Chinese (zh)
Other versions
CN109401519B (en
Inventor
韩俊南
张婷婷
武震林
常钧
申人生
王宝民
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dalian University of Technology
Original Assignee
Dalian University of Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dalian University of Technology filed Critical Dalian University of Technology
Priority to CN201811529638.9A priority Critical patent/CN109401519B/en
Publication of CN109401519A publication Critical patent/CN109401519A/en
Application granted granted Critical
Publication of CN109401519B publication Critical patent/CN109401519B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D107/00—Coating compositions based on natural rubber
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D109/00—Coating compositions based on homopolymers or copolymers of conjugated diene hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D111/00—Coating compositions based on homopolymers or copolymers of chloroprene
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
    • C09D161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C09D161/26—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
    • C09D161/28—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds with melamine
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D181/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur, with or without nitrogen, oxygen, or carbon only; Coating compositions based on polysulfones; Coating compositions based on derivatives of such polymers
    • C09D181/04—Polysulfides
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

A kind of bituminous pavement repair materials, it belongs to engineering material field, the bituminous pavement repair materials include include thermosetting polymer monomer and/or 20-60 parts of performed polymer, 2-8 parts of antioxidant, 1-8 parts of promotor of thermosetting polymer, 10-30 parts of admixture, 5-60 parts of thermoplastic polymer, 10-40 parts of initiator, 10-20 parts of reinforcing agent, 1-60 parts of diluent, gather materials 10-40 parts.The advantages that bituminous pavement repair materials provided by the invention have rate of set fast, and road surface can be repaired in 30min and is resumed traffic, and intensity is high, high dense water, wearability and simple construction.By the road surface compression strength of the bituminous pavement repair materials reparation up to 100MPa, wet wheel wearing valve is less than 800 gm‑2, 1d is less than 450 gm for Sand adhesion immersion‑2。

Description

A kind of bituminous pavement repair materials
Technical field
The present invention relates to engineering material technical field, in particular to a kind of bituminous pavement repair materials.
Background technique
The built highway 80% or so in China is bituminous pavement, is increased rapidly by the volume of traffic, vehicle is enlarged, again Loadization and extreme weather conditions influence, and the early stage damages such as different degrees of crack, track, the loose, pit slot in surface occurs in bituminous pavement It is bad, reduce Pavement Condition, it is serious or even pavement structure is caused to destroy.In order to keep the good service performance in road surface, Prolong the service life, needs in each different phase in pavement life period using different maintenance measures.
Currently, the maintenance operation of bituminous pavement is broadly divided into preventive maintenance, prosthetic maintenance, pavement recapping and road Face rebuilds four classes.Preventive maintenance, by Road Detection means, is referred to using every technology in the good situation of pavement behavior Evaluation path current condition is marked, by science, targeted, preventative maintenance technology means, it is public to be able to maintain high speed The good of road uses quality, improves the service life of road.Therefore, preventive maintenance is a kind of planned based on expense-effect The road maintenance strategy of benefit analysis is able to extend service life of road surface, improves Pavement Condition and reduces road surface and totally supports Shield expense.Just because of the tremendous economic and social benefit of preventive maintenance, rapidly develop this technology.
Currently, widely applied preventive maintenance mainly has mixture cover and brushing bituminous pavement protective coating two Kind mode.Wherein, mixing cover have it is closely knit it is durable, antiskid is wear-resisting, antifatigue, track resistant to high temperatures and to reduce cold cracking etc. special Point, but since cost is higher, application range is limited.Although and bituminous pavement protective coating in the prior art can alleviate road surface Hardening embrittlement degree, enhance the waterproof performance on road surface, but the abrasion resistance and intensity on road surface cannot be improved.
Summary of the invention
The purpose of the present invention is to provide have high-intensitive, high abrasion and dense water bituminous pavement reparation after a kind of hardening Material.
The technical proposal for solving the technical problem of the invention is: a kind of bituminous pavement repair materials, which is characterized in that It is grouped as by A class component and B class group, the A class component includes: by mass fraction
1-80 parts of performed polymer of the monomer of thermosetting polymer and/or thermosetting polymer；
5-40 parts of admixture；
The B class component includes: by mass fraction
1-80 parts of thermoplastic polymer；
The monomer of the thermosetting polymer and/or the performed polymer of thermosetting polymer polymerize to obtain thermosetting polymer；It is described The performed polymer of thermosetting polymer is pre- comprising heat-curable urethane performed polymer, thermosetting phenolic resin performed polymer, unsaturated polyester (UP) Aggressiveness, furane resins performed polymer, liquid polysulfide rubber performed polymer, epoxy resin prepolymer, polyureas performed polymer, thermosetting property melamine One of amine-formaldehyde resins, thermosetting acrylic resin are a variety of；
The monomer of the thermosetting polymer is that have the monofunctional monomer of reactable, bifunctional monomer, trifunctional monomer and more One of functional monomer is a variety of；Preferably contain multifunctional acrylic monomer (such as trimethylolpropane trimethacrylate) Or one of other multifunctional vinyl monomers (such as divinylbenzene) or a variety of.
The thermoplastic polymer includes natural rubber, butadiene-styrene rubber, nitrile rubber, butadiene rubber, EP rubbers, chlorine In buna, styrene butadiene thermoplasticelastomer, thermoplastic polyurethane elastomer, polypropylene glycol and road asphalt It is one or more.
The bituminous pavement repair materials that the program is prepared are only by the monomer of thermosetting polymer and/or thermosetting polymer Three kinds of performed polymer, admixture and thermoplastic polymer component compositions, obtained road surface repair materials coating is relatively thin, for road surface Maintenance and quickly reparation damage lesser road surface.
For well damage, high-intensitive and wearability repair materials road surfaces are needed, the present invention provides following technical scheme Bituminous pavement repair materials:
A kind of bituminous pavement repair materials, including A class component and B class component, the A class component include: by mass fraction
20-60 parts of performed polymer of the monomer of thermosetting polymer and/or thermosetting polymer；
2-8 parts of antioxidant；
1-8 parts of promotor；
10-30 parts of admixture；
B class component includes: by mass fraction
5-60 parts of thermoplastic polymer；
10-40 parts of initiator；
10-20 parts of reinforcing agent；
1-60 parts of diluent；
Gather materials 10-40 parts.
The bituminous pavement repair materials thickness obtained by the quality proportioning is thicker, has higher intensity, preferably close Aqueous and wearability.
The monomer of the thermosetting polymer and/or the performed polymer of thermosetting polymer polymerize to obtain thermosetting polymer, The thermosetting polymer includes thermosetting phenolic resin, thermoset urea aldehyde resin, thermosetting acrylic resin, thermoset epoxy Resin, heat-curable urethane, thermosetting property unsaturated polyester (UP), thermosetting polyurea and thermosetting property can one of vulcanized rubbers or more Kind.
The thermosetting phenolic resin is that have heat cured rosin modified phenolic resin, alcohols etherification of phenolic resin, ring One of oxygen phenol-formaldehyde resin modified and alkyd modified phenolic resin are a variety of；
The thermoset amino resin is the heat cured Lauxite, melamine resin, polyamide polyamines ring having One of oxygen chloropropane is a variety of；
The thermosetting acrylic resin is in the acrylic resin containing activity hydroxy functional group or carboxyl functional group It is one or more, oxyalkylation reaction solidification or and multi isocyanate crosslinking can be passed through with amino resins；It is described to contain work The acrylic resin of property hydroxy functional group or carboxyl functional group can be specially propylene hydroxyl ethyl ester, metering system hydroxyl ethyl ester, propylene One of sour hydroxypropyl acrylate, hydroxy propyl methacrylate, acrylic acid, methacrylic acid are a variety of.
The thermosetting epoxy resin is the heat cured glycidyl ether type epoxy resin having, glycidol esters ring Oxygen resin, glycidyl amine epoxy resin, aliphatic epoxy resin, cycloaliphatic epoxy resin, bisphenol A epoxide resin, bisphenol S One of epoxy resin, bisphenol S epoxy vingl ester resin and bisphenol S episulfide resin are a variety of；
The heat-curable urethane is by aliphatic isocyanates, alicyclic isocyanate, aromatic isocyanate, polyester polyols One of pure and mild polyether polyol or a variety of polymerizations obtain.
The thermosetting property unsaturated polyester (UP) is that the heat cured adjacent benzene-type unsaturated polyester (UP) having, metaphenylene unsaturation are poly- One of ester, terephthalic unsaturated polyester, bisphenol A-type unsaturated polyester (UP) and vinyl ester type unsaturated polyester (UP) are a variety of；
The thermosetting polyurea is by isophorone diisocyanate, methyl diphenylene diisocyanate or toluene di-isocyanate(TDI) One of thermosetting polyurea polymerizeing with ethylenediamine, m-phenylene diamine (MPD), diaminodiphenylmethane or amine terminated polyether is more Kind；
The thermosetting property can vulcanized rubber be that there are heat cured natural rubber, butadiene-styrene rubber, isoprene rubber, butadiene rubber, three First EP rubbers, butyl rubber, neoprene, carboxylic rubber, nitrile rubber, chlorosulfonated polyethylene rubber, silicon rubber, fluorubber With one of polysulfide rubber or a variety of.
The thermoplastic polymer includes to have thermoplastic polymethylacrylic acid, polymethyl methacrylate, ABS tree Rouge, polysulfide rubber, butadiene-styrene rubber, natural rubber, butadiene rubber, isoprene rubber, EP rubbers, polyvinyl alcohol, gathers nitrile rubber Vinyl butyral, polyvinyl formal, nitrocellulose, cellulose acetate, Triafol T, hydroxymethyl cellulose, Hydroxypropyl cellulose, Kynoar, polyacrylonitrile, polystyrene, polyarylsulfone (PAS), polyether sulfone, Nomex, gathers polyvinyl chloride Phenylate, polyphenylene sulfide, aromatic polyamides, aromatic polyamides hydrazine, polyphenylsulfone-paraphenylene terephthalamide, polyetherimide, polyethersulfone ketone, Polybenzimidazoles ketone, polybenzimidazoles, polyether-ketone, polyether-ether-ketone, polypiperazine-amide, polyurethane, polycarbonate, poly- terephthaldehyde Sour glycol ester, polyformaldehyde, styrene analog thermoplastic elastomer, block polyetheramides elastomer, polyolefin thermoplastic elastomer, Polyurethane termoplastic elastomer, thermoplastic elastomer of polyvinyl-chloride, polyester thermoplastic elastomer, diene analog thermoplastic elastomer and One of pitch is a variety of.
The admixture includes silica flour, flyash, ground granulated blast furnace slag, agstone, talcum powder, rubber powder, steel-making slag powder With one of CHARACTERISTICS OF TAILINGS SAND or a variety of
The partial size of the admixture is at 80 μm or less.
The initiator is more comprising peroxide type initiators, azo-initiator, persulfuric acid salt initiator, aliphatic Amine initiator, aromatic polyamine class initiator, imidazoles initiator, modified amine initiator, organic acid anhydride initiator and One of boron trifluoride class initiator, vulcanizer are a variety of.
The reinforcing agent include carbon black, white carbon black, carbon fiber, carbon nanotube, graphene, Paris white, clay, talcum, Diatomite, mica powder, asbestos, metal powder, metal oxide, thermosetting resin hollow ball, wood powder, cellulose powder, silane are even Join one of agent or a variety of.
The partial size to gather materials is 80 μm or more.
The antioxidant includes that amine antioxidants, phenol antioxidant, monothioester, phosphite ester and metal ion are blunt One of agent is a variety of.
Bituminous pavement repair materials provided by the invention, monomer and/or thermosetting polymer including thermosetting polymer Performed polymer, mass fraction be 1-80 parts, preferably 20-60 parts, more preferably 30-50 parts.The present invention polymerize thermosetting property The type of the performed polymer of the monomer and/or thermosetting polymer of object does not have special restriction, using known to those skilled in the art The monomer of thermosetting polymer and/or the performed polymer of thermosetting polymer can polymerize to obtain thermosetting polymer.Heat Solidity polymer preferably comprises thermosetting phenolic resin and its derivative, thermoset urea aldehyde resin and its derivative, thermosetting property third Olefin(e) acid resin and its derivative, thermosetting epoxy resin and its derivative, heat-curable urethane and its derivative, unsaturated polyester (UP) And its derivative, thermosetting polyurea and its derivative and can one of vulcanized rubber and its derivative or a variety of.Thermosetting property is poly- Close object monomer and/or thermosetting polymer performed polymer be preferably capable polymerization obtain it is any in above-mentioned thermosetting polymer One or more monomers and/or performed polymer.
In the present invention, the thermosetting phenolic resin and its derivative preferably comprise rosin modified phenolic resin, alcohols One of etherification of phenolic resin, epoxy modified phenolic resin and alkyd modified phenolic resin are a variety of.Thermosetting phenolic resin Monomer be preferably phenolic monomers and aldehyde monomers；Phenolic monomers are preferably in phenol, cresols, xylenol, alkyl phenol and bisphenol-A It is one or more；Aldehyde monomers are preferably one of formaldehyde, glyoxal, propionic aldehyde, methacrylaldehyde, valeral and benzaldehyde or more Kind.The monomer of thermosetting phenolic resin derivative is preferably bisphenol S, bisphenol-c, phthalazone (DHPZ), 4- chlorophenol, acetyl One of phloroglucin, cyclodextrin aldehyde, three halogen butyraldehyde, methacrylaldehyde and trichloroacetaldehyde are a variety of.
In the present invention, the thermoset amino resin and its derivative are passed through by the compound containing amino and formaldehyde The general name of resin made of polycondensation is more including but not limited to Lauxite (UF), melamine resin (MF), polyamide One of amine epoxychloropropane (PAE) is a variety of.The Ammonia monomer of thermoset amino resin and its derivative preferably contains Amino and the compound that can be copolymerized with formaldehyde and alcohols, it is highly preferred that being urea, thiocarbamide, melamine, sulfomethylation trimerization Cyanamide, lower alcohol etherified melamine amine (methylated melamine, butanol etherification melamine etc.), hydramine etherified melamine One of amine, benzoguanamine, polyurethane, dicyandiamide, sulfonamide and aniline are a variety of.Thermoset amino resin and its spread out The aldehyde monomers of biology are preferably one of formaldehyde, propionic aldehyde, glyoxal, furfural and benzaldehyde or a variety of.
In the present invention, the thermosetting acrylic resin and its derivative are that have heat cured poly-methyl methacrylate One of ester, poly- trimethylolpropane trimethacrylate and polymethylacrylic acid are a variety of.Thermosetting acrylic resin and its The monomer of derivative is preferably acrylate and/or its derivative, most preferably alkyl acrylate.Thermosetting acrylic resin Monomer can be specially one of methyl methacrylate, trimethylolpropane trimethacrylate and methacrylic acid or more Kind.
In the present invention, the thermosetting epoxy resin derivative preferably comprises glycidyl ether type epoxy resin, shrinks Glyceride type epoxy resin, glycidyl amine epoxy resin, aliphatic epoxy resin, cycloaliphatic epoxy resin, bisphenol S epoxy One of resin, bisphenol S epoxy vingl ester resin and bisphenol S episulfide resin are a variety of.The monomer of thermosetting epoxy resin is excellent It is selected as but is not limited to bisphenol-A, bisphenol S, resorcinol, methylol bisphenol-A, hydrogenated bisphenol A, epoxychloropropane, ethylene oxide With at least two in propylene oxide.The monomer of thermosetting epoxy resin can be specially bisphenol-A and epoxychloropropane.
In the present invention, the monomer of the thermosetting polyurethane resin is preferably aliphatic isocyanates, alicyclic isocyanide One of pure and mild polyether polyol of acid esters, aromatic isocyanate, polyester polyols (performed polymer of polyethers) is a variety of.Aliphatic Isocyanates is preferably hexamethylene diisocyanate (HDI), and alicyclic isocyanate is preferably isophorone diisocyanate (IPDI) and/or Methylcyclohexyl diisocyanate (HTDI)；Aromatic isocyanate is preferably toluene di-isocyanate(TDI) (TDI), methyl diphenylene diisocyanate (MDI), polyphenylene polyphenyl cyanate (PAPI), methyl diphenylene diisocyanate (PPDI), one of 1,5- naphthalene diisocyanate (NDI) or a variety of；Polyester polyol be preferably aliphatic chain polyester polyol, One of caprolactone ployester polyalcohol and polycarbonate type polyester polyol are a variety of；Polyether polyol is preferably epoxy third One of alkane polyether polyol, tetrahydrofuran polyether polyalcohol, amine terminated polyether are a variety of.
In the present invention, the unsaturated polyester (UP) preferably comprises adjacent benzene-type unsaturated polyester (UP), metaphenylene unsaturated polyester (UP), right One of benzene-type unsaturated polyester (UP), bisphenol A-type unsaturated polyester (UP) and vinyl ester type unsaturated polyester (UP) are a variety of.Thermosetting property is not The monomer of saturated polyester is preferably, but not limited to maleic acid (maleic acid), maleic anhydride (maleic anhydride), anti-fourth Enedioic acid, chlorination maleic acid, itaconic acid, citraconic acid, ethylene glycol, propylene glycol, diglycol, dipropylene glycol and new penta It is a variety of in glycol.
In the present invention, it is different to be preferably, but not limited to isophorone two for the monomer of the thermosetting polyurea and its derivative Cyanate (IPDI), methyl diphenylene diisocyanate (MDI), toluene di-isocyanate(TDI) (TDI), ethylenediamine, m-phenylene diamine (MPD), two It is a variety of in diaminodiphenylmethane and amine terminated polyether.
In the present invention, it is described can vulcanized rubber and its derivative be preferably, but not limited to that there is heat cured natural rubber Glue, butadiene-styrene rubber, isoprene rubber, butadiene rubber, ethylene propylene diene rubber, butyl rubber, neoprene, carboxylic rubber (acrylic acid Rubber), nitrile rubber, chlorosulfonated polyethylene rubber, silicon rubber, one of fluorubber and polysulfide rubber or a variety of.
In the present invention, the performed polymer of the thermosetting polymer includes heat-curable urethane performed polymer, thermosetting phenolic Resin prepolymer, unsaturated polyester (UP) performed polymer, furane resins performed polymer, liquid polysulfide rubber performed polymer, epoxy resin prepolymer, One of polyureas performed polymer, heat-curable melamine formaldehyde resin, thermosetting acrylic resin are a variety of.Preferably, thermosetting The performed polymer of property polymer can be specially unsaturated polyester (UP) performed polymer (191 types, 196 types), furane resins performed polymer, liquid polysulfide Rubber performed polymer (JLY-115, JYL-121, JYL-124, JLY-125, JLY-155, JYL-1225), epoxy resin prepolymer (E02, E12, E20, E21, E31, E42, E44, E51), MDI isocyanate performed polymer, IPDI Isocyanate prepolymers body, TDI are different Cyanate performed polymer, polyureas performed polymer, cyanoacrylate, melamine resin, in thermosetting phenolic resin performed polymer One or more.
Bituminous pavement repair materials provided by the invention include antioxidant, and mass fraction is 0-10 parts, preferably 2-8 Part, more preferably 4-6 parts.Preferably, which includes amine antioxidants, phenol antioxidant, monothioester, phosphorous acid One of ester and metallic ion passivation agent are a variety of.The antioxidant can prevent oxygen adverse effect, can help to capture simultaneously Neutralize free radical.
In the present invention, the amine antioxidants preferably comprises but is not limited to N, N- di-sec-butyl-p-phenyl enediamine, 4, One of 4 one dimethoxy diphenylamines, dioctyl-p-phenylenediamine and diisobutyl p-phenylenediamine are a variety of.Phenol antioxidant Preferably comprise hydroquinone, 2,4- dimethyl -6- tert-butyl phenol, tert-butyl hydroquinone, butylated hydroxy anisole, 2,6- bis- One of bis- tertiary amyl hydroquinone of tert-butyl-p-cresol and 2,5- is a variety of.Monothioester preferably comprises propyl gallate, sulphur For one of dipropionic acid laurel alcohol ester and thio-2 acid octadecanol ester or a variety of.Phosphite ester is preferably phosphorous acid hexichol The pungent own ester of base and/or tris phosphite.Metallic ion passivation agent preferably comprise melamine, propyl benzene triazole, 8-hydroxyquinoline and One of hydrazone is a variety of.
Bituminous pavement repair materials provided by the invention include promotor, and mass fraction is 0-10 parts, preferably 1-8 Part, more preferably 2-5 parts.Promotor preferably comprises accelerators for epoxy resins, polyurethane promotor, phenolic resin and promotes Agent, unsaturated polyester resin promotor, acrylic resin promotor, promotor used for anaerobic adhesive, rubber and rubber-type gluing One of agent promotor is a variety of.Preferably, the type of promotor is poly- according to the monomer and thermosetting property of thermosetting polymer The type for closing the performed polymer of object is selected.Promotor can be catalyzed thermosetting polymer monomer and thermosetting polymer it is pre- The cross-linking polymerization of aggressiveness improves reaction rate, shortens the curing time of bituminous pavement repair materials.
The present invention does not have special restriction to the type of accelerators for epoxy resins, and use is well known to those skilled in the art Accelerators for epoxy resins.Preferably, accelerators for epoxy resins is including but not limited to triethanolamine, dimethyl benzene One of amine, three -2 ethyl hexanoic acid salt, imidazoles, imidazole salt and transition metal organometallic compound are a variety of.Transition metal has Machine compound is preferably transition metal carboxylate, it is highly preferred that one of metal carboxylate comprising manganese, cobalt, calcium and zinc or It is a variety of.
The present invention does not have special restriction to the type of the polyurethane promotor, using known to those skilled in the art Polyurethane promotor.Preferably, polyurethane promotor is including but not limited to N, N- dimethyl cyclohexyl amine, three second Amine, N, N- dimethyl benzylamine, N-methylmorpholine, triethanolamine, diethyl toluene diamine, N, N '-dimethyl pyridine and dibutyl One of tin dilaurate is a variety of.
The present invention does not have special restriction to the type of phenolic resin promotor, and use is well known to those skilled in the art Phenolic resin promotor.Preferably, phenolic resin promotor including but not limited to sodium hydroxide, potassium hydroxide, Lithium hydroxide, ammonium hydroxide, triethylamine, barium hydroxide, magnesia, zinc acetate, stannous chloride, ferric trichloride and in Chlorobenzoic Acid It is one or more.
The present invention does not have special restriction to the type of unsaturated polyester resin promotor, using those skilled in the art Well known unsaturated polyester resin promotor.Preferably, unsaturated polyester resin promotor includes cobalt naphthenate, different One of cobalt octoate, dimethylaniline, diethylaniline, lauryl mercaptan and vanadium phosphate are a variety of.
The present invention does not have special restriction to the type of acrylic resin promotor, using known to those skilled in the art Acrylic resin promotor.Preferably, acrylic resin promotor is including but not limited to different zincic acid alum, tetramethyl Base thiocarbamide, vanadium acetylacetonate, acetylacetone,2,4-pentanedione, triphenylphosphine, n-butanal-one of aniline condensation object and benzyl dimethylamine or more Kind.
The present invention does not have special restriction to the type of promotor used for anaerobic adhesive, is detested using well known to those skilled in the art Oxygen glue promotor.Preferably, promotor used for anaerobic adhesive is including but not limited to N, N- dimethyl open-chain crown ether, three second One of amine, hydrogen quinoline, 8-hydroxyquinoline, saccharin, ferrocene and praseodynium aluminium are a variety of.
The present invention does not have special restriction to the type of the rubber and rubber-type adhesive promotor, using this field Rubber known to technical staff and rubber-type adhesive promotor.Preferably, rubber and rubber-type adhesive promote Agent is including but not limited to manganese dioxide, brown lead oxide, magnesia, zinc peroxide, dibenzoyl peroxide, peroxidating diisopropyl Benzene, two tertiary butane of peroxidating, 2,5- dimethyl -2,5- bis(t-butylperoxy) hexane (bis 25 vulcanizing agent), diphenylguanidine, 2- Benzothiazolyl mercaptan, tetramethylthiuram disulfide and zinc dimethyl dithiocarbamate, hexamethylene diamine, triethylenetetramine, Two cortex cinnamomis pitch hexamethylene diamine, Coumarin methene hexamethylene diamine, alkyl phenolic resin, halogenation resol resin, quinones (paraquinones and Oxime), maleimide (bismaleimide), one of isocyanates or a variety of.
Bituminous pavement repair materials provided by the invention include admixture, and mass fraction is 5-40 parts, preferably 10-30 Part, more preferably 15-25 parts.Preferably, admixture include talcum powder, silica flour, flyash, ground granulated blast furnace slag, agstone, One of rubber powder, steel-making slag powder and CHARACTERISTICS OF TAILINGS SAND are a variety of.The partial size of admixture is preferably 80 μm hereinafter, more preferably 10-60 μ M, most preferably 30-40 μm.The surface abrasion etch resistant properties of bituminous pavement repair materials can be improved in admixture.
Bituminous pavement repair materials provided by the invention include thermoplastic polymer, and mass fraction is 1-80 parts, preferably It is 5-60 parts, more preferably 30-50 parts.Thermoplastic polymer is preferably comprised with thermoplastic polymethylacrylic acid, poly- methyl Methyl acrylate, ABS resin, nitrile rubber, polysulfide rubber, butadiene-styrene rubber, natural rubber, butadiene rubber, isoprene rubber, second third Rubber, gelatin, polyvinyl alcohol, polyvinyl butyral, polyvinyl formal, nitrocellulose, cellulose acetate, three acetic acid Cellulose, hydroxymethyl cellulose, hydroxypropyl cellulose, polyvinyl chloride, Kynoar, polyacrylonitrile, polystyrene, poly- (virtue) Sulfone, polyether sulfone, poly- (virtue) amide, polyphenylene oxide, polyphenylene sulfide, aromatic polyamides, aromatic polyamides hydrazine, polyphenylsulfone-terephthaldehyde Acyl, polyethersulfone ketone, polybenzimidazoles ketone, polybenzimidazoles, polyether-ketone, polyether-ether-ketone, polypiperazine-amide, gathers at polyetherimide Urethane thermoplastic elastomer (TPE), polyester (alkyd resin), polycarbonate, polyethylene terephthalate, polyformaldehyde, phenylethylene Thermoplastic elastomer (TPE), block polyetheramides elastomer, polyolefin thermoplastic elastomer, polyurethane termoplastic elastomer, polychlorostyrene second One of thermoplastic olefinic elastomer, polyester thermoplastic elastomer, diene analog thermoplastic elastomer and pitch are a variety of.Thermoplasticity Polymer can be specially the combination of ABS resin and nitrile rubber or the combination of polysulfide rubber and polyvinyl butyral.ABS tree The mass ratio of rouge and nitrile rubber is preferably 1:0.5-1:3, more preferably 1:1-1:2；Polysulfide rubber and polyvinyl butyral Mass ratio be preferably 1:0.4-1:1, more preferably 1:0.6-1:0.8.Thermoplastic polymer has by thermal softening, hardening by cooling Performance, can be improved the flexibility of repair materials after solidifying.
Bituminous pavement repair materials provided by the invention include initiator, and mass fraction is 0-60 parts, preferably 10-40 Part, more preferably 20-30 parts.Preferably, initiator includes peroxide type initiators, azo-initiator, persulfuric acid salt It is initiator, aliphatic polyamine class initiator, aromatic polyamine class initiator, imidazoles initiator, modified amine initiator, organic Anhydride initiator, boron trifluoride and its one of derivative species initiator and vulcanizer or a variety of.In the present invention, Initiator is used to cause the cross-linking polymerization of the monomer of thermosetting polymer and/or the performed polymer of thermosetting polymer, simultaneously Have the function of curing agent, is also referred to as curing agent in this field, the curing time of bituminous pavement repair materials is adjusted.
Thermosetting polymer and its derivative are especially the performed polymer of multicomponent thermosetting polymer known in the art, Included thermosetting polymer solidifies required component, such as the bisphenol type epoxy contained in thermosetting epoxy resin performed polymer Resin and Polyamide Epoxy；The for another example TDI Isocyanate prepolymers body and polyethers performed polymer in heat-curable urethane performed polymer The requirement scope for belonging to curing agent does not illustrate curing agent at this.
The present invention does not have special restriction to peroxide type initiators, using peroxidating well known to those skilled in the art Species initiator.Preferably, peroxide type initiators be one of inorganic peroxide and organic peroxide or It is a variety of.Inorganic peroxide is preferably hydrogen peroxide, potassium peroxydisulfate, ammonium persulfate etc..Organic peroxide is preferably but not office It is limited to isopropyl benzene hydroperoxide, benzoyl peroxide, benzoyl peroxide, diphenyl peroxide ketone, peroxidating first and second One of ketone and cyclohexanone peroxide are a variety of.
The present invention does not have special restriction to azo-initiator, is caused using azo well known to those skilled in the art Agent.Preferably, azo-initiator is azodiisobutyronitrile and/or azobisisoheptonitrile.
The present invention does not have special restriction to the persulfuric acid salt initiator, using mistake well known to those skilled in the art Sulfate.Persulfuric acid salt initiator is preferably one of sodium peroxydisulfate, potassium peroxydisulfate and ammonium persulfate or a variety of.
The present invention does not have special restriction to the aliphatic polyamine class initiator, and use is well known to those skilled in the art Aliphatic polyamine.Aliphatic polyamine class initiator be preferably, but not limited to ethylenediamine, hexamethylene diamine, trimethylhexane diamine, Diethylenetriamine, triethylene tetramine, hexa, trien, triethylene diamine, tetraethylenepentamine, two propylene One of triamine and trimethylhexamethylenediamine are a variety of.
The present invention does not have special restriction to aromatic polyamine class initiator, using fragrance well known to those skilled in the art Race's polyamines.Aromatic polyamine class initiator is preferably, but not limited to m-phenylene diamine (MPD), m-xylene diamine, diamino-diphenyl One of methane, aminomethylamine and benzidine are a variety of.
The present invention does not have special restriction to the type of the imidazoles initiator, and use is well known to those skilled in the art Glyoxaline compound.Imidazoles initiator is preferably, but not limited to 2-ethyl-4-methylimidazole, l, 3 diazacyclos penta One of diene, 2-methylimidazole and 2- ethyl imidazol(e) are a variety of.
The present invention does not have special restriction to the type of modified amine initiator, is changed using well known to those skilled in the art Property aminated compounds.Modified amine compound is preferably Mannich phenolic modified amine initiator, epoxy amine addition One of object, glycidol ether amine additives, alkylene oxide amine additives and polyamine and alkene double bond addition modification amine initiator Or it is a variety of.
The present invention does not have special restriction to the type of organic acid anhydride initiator, and use is well known to those skilled in the art Organic acid anhydride.Organic acid anhydride initiator is preferably, but not limited to include pyromellitic dianhydride, phthalic anhydride, two Benzophenone carboxylic di-acid acid anhydride and dodecyl are for one of maleic anhydride or a variety of.
The present invention does not have special restriction to the type of vulcanizer, using rubber sulphur well known to those skilled in the art Agent.Preferably, vulcanizer is including but not limited to including sulphur, zinc oxide, lead oxide, manganese dioxide, four oxygen Change three lead, alkyl phenolic resin, tert-butyl benzaldehyde formaldehyde resin, t-Octylphenol formaldehyde resin, tetramethylthiuram disulfide Deng one of or it is a variety of.
Bituminous pavement repair materials provided by the invention include reinforcing agent, and mass fraction is 0-30 parts, preferably 10-20 Part, more preferably 12-16 parts.Preferably, reinforcing agent including but not limited to white carbon black, carbon fiber, carbon nanotube, graphene, Paris white, clay, talcum, diatomite, mica powder, asbestos, metal powder, metal oxide, thermosetting resin hollow ball, wood One of powder, cellulose powder and silane coupling agent are a variety of.Metal powder is preferably one of iron powder, aluminium powder and zinc powder Or it is a variety of.Metal oxide is preferably one of ferrous oxide, di-iron trioxide, aluminium oxide, zinc oxide and magnesia or more Kind.The partial size of reinforcing agent is preferably 80 μm hereinafter, more preferably 10-60 μm, most preferably 30-40 μm.In the present invention, enhance Agent can cooperate with admixture, further increase the Wear resistance and Anti corrosion energy of bituminous pavement repair materials.
Bituminous pavement repair materials provided by the invention include diluent, and mass fraction is 0-80 parts, preferably 1-60 Part, more preferably 20-40 parts.The present invention does not have special restriction to the type of diluent, using known to those skilled in the art Diluent.It is molten that diluent is preferably, but not limited to dimethicone, acrylic acid, fatty acid, tetrahydrofuran, esters One of agent, ketones solvent, alcohols solvent, aromatic solvents, amide solvent and sulfone class solvent are a variety of.Diluent can be with The levelability of bituminous pavement repair materials is improved, improvement can application property.
The esters solvent is preferably, but not limited to two fourth of ethyl acetate, diethyl phthalate and phthalic acid One of ester is a variety of.Ketones solvent is preferably, but not limited in acetone, methyl ethyl ketone, cyclohexanone and N-Methyl pyrrolidone It is one or more.Alcohols solvent is preferably, but not limited to one of ethyl alcohol, ethylene glycol and n-butanol or a variety of.Aromatics Solvent is preferably, but not limited to one of benzene,toluene,xylene and styrene or a variety of.Amide solvent preferably but not It is confined to one of formamide, dimethylformamide and dimethyl acetamide or a variety of.Sulfoxide type solvents are preferably but not office It is limited to dimethyl sulfoxide and/or sulfolane.
Bituminous pavement repair materials provided by the invention include gathering materials, and mass fraction is 0-60 parts, preferably 10-40 Part, more preferably 20-30 parts.The partial size to gather materials is preferably 80 μm or more, more preferably 100-400 μm, most preferably 200-300 μm.The present invention does not have special restriction to the type gathered materials, and is gathered materials using well known to those skilled in the art.Preferably, Gather materials includes one of rubber grain, quartz sand, rubble and cobble or a variety of.
In the present invention, the setting time of bituminous pavement repair materials at normal temperature is preferably 10min-24h, more preferably 1-20h, most preferably 5-10h.Density after bituminous pavement repair materials solidify is preferably 1.6-2.0g/cm3, more preferably 1.7-1.9g/cm3；Compression strength 10-100MPa after solidification, more preferably 70-90MPa；Bending tensile strength after solidification is excellent It is selected as 10-70MPa, more preferably 20-40MPa；Shearing strength after solidification is preferably 20-50MPa, more preferably 30- 40MPa；Elasticity modulus is preferably 8-15GPa, more preferably 10-13GPa；Poisson's ratio after solidification is preferably 0.20-0.35.
The present invention does not have special limitation to the preparation method of bituminous pavement repair materials, ripe using those skilled in the art That knows prepares the preparation method of composition.The preparation method of the bituminous pavement repair materials is preferred are as follows: polymerize thermosetting property It is the performed polymer of the monomer of object and/or thermosetting polymer, thermoplastic polymer, admixture, initiator, promotor, reinforcing agent, dilute It releases agent, gather materials and antioxidant mixing, obtain bituminous pavement repair materials.
In the present invention, the monomer of thermosetting polymer and/or the performed polymer of thermosetting polymer and initiator need to distinguish Encapsulation is protected from light storage.
The present invention does not have special restriction to the application method of the bituminous pavement repair materials, using those skilled in the art Coating coating method known to member.The preferably artificial brushing of the coating method of the bituminous pavement repair materials or mechanical spray It applies.
It is had the advantage that compared with the prior art in technical solution of the present invention
The present invention provides a kind of bituminous pavement repair materials, which is only gathered by the monomer of thermosetting polymer and/or thermosetting property Three kinds of performed polymer, admixture and thermal shrinkage type polymer component compositions of object are closed, obtained road surface repair materials coating is relatively thin, uses Lesser road surface is damaged in the maintenance on road surface and quick repair.The present invention provides another bituminous pavement repair materials, the material The performed polymer of monomer and/or thermosetting polymer including thermosetting polymer, admixture, three kinds of thermoplastic polymer main paintings Raw material, the monomer of thermosetting polymer and/or the active reactive functionality of the performed polymer of thermosetting polymer are covered, is able to carry out Cross-linking polymerization forms the thermosetting polymer of network molecular structure that is insoluble, not melting, improves the strong of road surface after solidification Degree.During the monomer of thermosetting polymer and/or the performed polymer cross-linked polymeric of thermosetting polymer, made by physics, chemistry It is evenly distributed in the network molecular structure of thermosetting polymer with by thermoplastic polymer, forms soft or hard polymer appropriate Layer, improves the flexibility and dense water of repair materials, admixture is uniformly mixed into thermosetting polymer and thermoplastic polymer In the polymer molecule of formation, the surface abrasion etch resistant properties of repair materials are further improved.The cross-linking polymerization room temperature Under can carry out, be not necessarily to extra heat source so that road surface repair it is simpler, it is convenient.
Add initiator in the bituminous pavement repair materials, for cause thermosetting polymer monomer and/or The cross-linking polymerization of the performed polymer of thermosetting polymer, improves the rate of cross-linking polymerization, and initiator has solidification simultaneously The effect of agent further adjusts the curing time of bituminous pavement repair materials, shortens the bituminous pavement repair materials road rehabilitation Time.
Reinforcing agent is added in the bituminous pavement repair materials, reinforcing agent enhances the cohesive force between different material, The Wear resistance and Anti corrosion energy of the bituminous pavement repair materials is further increased with admixture cooperation.
Add promotor in the bituminous pavement repair materials, the type of promotor is according to the list of thermosetting polymer The type of the performed polymer of body and thermosetting polymer is selected.Promotor can be catalyzed monomer and the thermosetting of thermosetting polymer Property polymer performed polymer cross-linking polymerization, improve reaction rate, shorten bituminous pavement repair materials curing time.
Antioxidant is added in the bituminous pavement repair materials, which can prevent the bad shadow of oxygen Ring, can help to capture and neutralize free radical, reduction oxygen for thermosetting polymer monomer and/or thermosetting polymer it is pre- The destruction of the active reaction functional group of aggressiveness, enhances the intensity of the material.
Diluent is added in the bituminous pavement repair materials and is gathered materials.Bituminous pavement reparation can be improved in diluent The levelability of material, improvement can application properties.Gather materials and is mainly used for reducing the volume change of material in the curing process.
Bituminous pavement preparation method of restoration materials provided by the invention is simple, under room temperature that raw material is simply mixed without heating Conjunction overcomes other road surface repair materials and needs the shortcomings that being heated at high temperature, greatly simplify road surface maintenance and It repairs, time saving while traffic congestion caused by reducing because of road rehabilitation.
The bituminous pavement repair materials rate of set is fast, and setting time at normal temperature is 10min-24h, after solidification Density is 1.6-2.0g/cm3, compression strength 10-100MPa, bending tensile strength 10-70MPa, shearing strength 20- 50MPa, elasticity modulus 8-15GPa, Poisson's ratio 0.20-0.35.Road surface can be repaired in bituminous pavement repair materials 30min It resumes traffic, intensity is high, constructs the advantages that simple.The road surface compression strength of reparation is up to 100MPa, wet wheel wearing valve < 800 g·m-2, Sand adhesion immersion 450 gm of 1d <-2。
Bituminous pavement repair materials provided by the invention are described in detail below with reference to embodiment, but cannot be by it Be interpreted as limiting the scope of the present invention.
Gather materials and is divided into coarse aggregate and fine aggregate (or referred to as coarse aggregate and fine aggregate) fine aggregate refers to that partial size is less than The general of 4.75mm is referred to as sand (limiting the partial size to gather materials is 80 μm or more, 80 μm below be known as powder or mud) more more；And It is known as stone, generally referred to as rubble or cobble greater than 4.75mm.In the examples below unless otherwise required, coarse aggregate The regulation is applicable in the specification of fine aggregate.
Embodiment 1:
The performed polymer of thermosetting polymer: TDI Isocyanate prepolymers body and thermosetting phenolic resin performed polymer；
Thermoplastic polymer: 90# road asphalt；
Initiator: polyethers performed polymer and triethylene diamine；
Promotor: dibutyl tin dilaurate；
Admixture: rubber powder and quartz sand；
Diluent: dimethicone；
The preparation mass fraction of material is respectively as follows: 50 parts of TDI Isocyanate prepolymers body, and 10 parts of thermosetting phenolic resin performed polymer, 30 parts of polyethers performed polymer, 5 parts of triethylene diamine, 6 parts of dimethicone, 3 parts of dibutyl tin dilaurate, 90# road asphalt 11 Part, 8 parts of rubber powder, 20 parts of quartz sand, need to compound rubble as coarse aggregate according to construction.
It is convenient for packaging, TDI Isocyanate prepolymers body, thermosetting phenolic resin performed polymer and 90# road asphalt are mixed Packaging is used as component A；Polyethers performed polymer, dimethicone, triethylene diamine, dibutyl tin dilaurate are hybrid packed to be used as B Component；Rubber powder and quartz sand are hybrid packed as component C；People is can be used into tri- component of A, B, C after mixing when construction Work brushing or mechanically spraying construction.
Setting time when bituminous pavement repair materials provided in this embodiment are repaired for road surface is 30min；Condensation The cohesion of 30min is 3.0 Nm, and wet wheel wearing valve is 512 gm-2, Sand adhesion immersion 1d is 320 g m-2。
Embodiment 2:
The monomer of thermosetting polymer: methyl methacrylate, methacrylic acid, trimethylolpropane trimethacrylate；
Thermoplastic polymer: ABS resin and nitrile rubber；
Initiator: isopropyl benzene hydroperoxide；
Promotor: hexa, vanadium iso-octoate；
Antioxidant: hydroquinone
Admixture: level-one flyash；
Diluent: ethylene glycol；
The mass fraction that material is prepared is respectively as follows: 45 parts of methyl methacrylate, and 12 parts of methacrylic acid, trimethylolpropane tris 5 parts of acrylate, 0.6 part of hydroquinone, 5 parts of ethylene glycol, 7 parts of ABS resin, 10 parts of nitrile rubber, isopropyl benzene hydroperoxide 4 Part, 3 parts of hexa, 0.3 part of vanadium iso-octoate, 8 parts of level-one flyash, need to compound rubble as thick bone according to construction Material.
It is convenient for packaging, by methyl methacrylate, methacrylic acid, trimethylolpropane trimethacrylate, to benzene two Phenol, ethylene glycol, ABS resin, isopropyl benzene hydroperoxide are hybrid packed to be used as A1Component；Hydroquinone, nitrile rubber, hexa-methylene Tetramine, vanadium iso-octoate, flyash are hybrid packed to be used as B1Component；By A when use1、B1Component can be used artificial after mixing It brushes or mechanically spraying is constructed.
Setting time 20min when bituminous pavement repair materials provided in this embodiment are repaired for road surface；Condense 30min Cohesion be 3.5 Nm, wet wheel wearing valve be 470 gm-2, Sand adhesion immersion 1d is 358 gm-2。
Embodiment 3:
The performed polymer of thermosetting polymer: thermosetting epoxy resin performed polymer (bisphenol A type resin 601)；
Thermoplastic polymer: polysulfide rubber, polyvinyl butyral；
Initiator: Polyamide Epoxy initiator；
Promotor: triethanolamine；
Antioxidant: phosphite ester；
Admixture: miberal powder S95；
Diluent: toluene, acetone；
The mass fraction that material is prepared is respectively as follows: 35 parts of thermosetting epoxy resin performed polymer (bisphenol A type resin 601), polyamide 14 parts of epoxy resin initiator, 1 part of phosphite ester, 6 parts of toluene, 6 parts of acetone, 10 parts of polysulfide rubber, polyvinyl butyral 6 Part, 4 parts of triethanolamine, 16 parts of miberal powder S95, need to compound rubble as coarse aggregate according to construction.
It is convenient for packaging, by thermosetting epoxy resin performed polymer (bisphenol A type resin 601), polysulfide rubber, triethanolamine, Toluene, it is hybrid packed be used as A2Component；Polyamide Epoxy curing agent, phosphite ester, polyvinyl butyral, acetone, mine Powder S95 is hybrid packed to be used as B2Component；By A when use2、B2Artificial brushing or mechanically spraying can be used in component after mixing Construction.
Setting time 25min when bituminous pavement repair materials provided in this embodiment are repaired for road surface；Condense 30min Cohesion be 4.6 Nm, wet wheel wearing valve be 437 gm-2, Sand adhesion immersion 1d is 321 gm-2。
Embodiment 4:
The performed polymer of thermosetting polymer: melamine resin；
Thermoplastic polymer: styrene butadiene thermoplasticelastomer；
Initiator: trien；
Promotor: cumyl peroxide；
Antioxidant: dibutyl hydroxy toluene；
Reinforcing agent: talcum powder；
Diluent: repefral；
The preparation mass fraction of material is respectively as follows: 53.5 parts of melamine resin, styrene butadiene thermoplasticelastomer 15 parts, 0.5 part of dibutyl hydroxy toluene, 6 parts of repefral, 12 parts of trien, cumyl peroxide 3 Part, 10 parts of talcum powder, need to compound rubble as coarse aggregate according to construction.
It is convenient for packaging, by melamine resin, dibutyl hydroxy toluene, the hybrid packed work of cumyl peroxide For A3Component；Styrene butadiene thermoplasticelastomer, repefral, trien, talcum powder mixing packet It pretends as B3Component；By A when use3、B3Artificial brushing or mechanically spraying construction can be used in component B after mixing.
Setting time 20min when bituminous pavement repair materials provided in this embodiment are repaired for road surface；Condense 30min Cohesion be 3.1 Nm, wet wheel wearing valve be 572 gm-2, Sand adhesion immersion 1d is 307 gm-2。
Embodiment 5:
The performed polymer and thermoset monomer of thermosetting polymer: thermosetting epoxy resin performed polymer E51 and cyanoacrylate Acid esters；
Thermoplastic polymer: thermoplastic polyurethane (black material)；
Admixture: silica flour；
Reinforcing agent: nothing；
Initiator: nothing；
Promotor: nothing；
Antioxidant: nothing；
Diluent: nothing；
The preparation mass fraction of material be respectively as follows: thermosetting epoxy resin performed polymer E51 be 40 parts, 10 parts of cyanoacrylate, 40 parts of base polyurethane prepolymer for use as (black material), needs to compound rubble as coarse aggregate according to construction by 10 parts of silica flour.
Facilitate for packaging thermosetting epoxy resin performed polymer (E51) and cyanoacrylate is hybrid packed as A4Group Point；Base polyurethane prepolymer for use as (black material) 40 powder, silica flour are hybrid packed to be used as B4Component；By A when use4、B4Component is after mixing Artificial brushing or mechanically spraying construction can be used.
Setting time 25min when bituminous pavement repair materials provided in this embodiment are repaired for road surface；Condense 30min Cohesion be 2.7 Nm, wet wheel wearing valve be 637 gm-2, Sand adhesion immersion 1d is 403 gm-2。
Embodiment 6:
The performed polymer of thermosetting polymer: MDI isocyanate performed polymer；
Thermoplastic polymer: polyvinyl chloride；
Initiator: polyether polyol (N220) and ending amino polyether (Jefamine T-5000)
Promotor: diethyl toluene diamine；
Antioxidant: N- phenyl-2-naphthylamine；
Admixture: agstone；
Diluent: ethyl acetate；
The preparation mass fraction of material is respectively as follows: 44 parts of MDI isocyanate performed polymer, 8 parts of polyvinyl chloride；12 parts of ethyl acetate, 1 part of N- phenyl-2-naphthylamine, polyether polyol (N220) be 15 parts, 2 parts of diethyl toluene diamine, ending amino polyether (Jefamine T-5000) 10 parts, 8 parts of agstone, need to compound rubble as coarse aggregate according to construction.
It is convenient for packaging, MDI isocyanate performed polymer, agstone is hybrid packed as A5Component；By polyvinyl chloride It is hybrid packed with hydroquinone, polyether polyol N220, ending amino polyether, diethyl toluene diamine after being dissolved in ethyl acetate As B5Component；By A when use5、B5Artificial brushing or mechanically spraying construction can be used in component after mixing.
Setting time 20min when bituminous pavement repair materials provided in this embodiment are repaired for road surface；Condense 30min Cohesion be 3.7 Nm, wet wheel wearing valve be 434 gm-2；Sand adhesion soaks 1d for 327 gm-2。
Embodiment 7:
The performed polymer of thermosetting polymer: liquid polysulfide rubber performed polymer (JYL-124) and epoxy resin prepolymer (E44);
Thermoplastic polymer: polyacrylonitrile；
Initiator: manganese dioxide；
Promotor: triethylene tetramine；
Antioxidant: tert-butyl hydroquinone；
Reinforcing agent: white carbon black；
Diluent: dimethyl sulfoxide；
It is 50 parts, 6 parts of polyacrylonitrile that the preparation mass fraction of material, which is respectively as follows: liquid polysulfide rubber performed polymer (JYL-124),；Two 12 parts of methyl sulfoxide, 1 part of tert-butyl hydroquinone, 9 parts of epoxy resin prepolymer (E44), 4 parts of triethylene tetramine, manganese dioxide 6 Part, 12 parts of white carbon black, need to compound rubble as coarse aggregate according to construction.
It is convenient for packaging, liquid polysulfide rubber and triethylene tetramine is hybrid packed as A6Component；Polyacrylonitrile is molten It is hybrid packed as B with tert-butyl hydroquinone, epoxy resin, manganese dioxide, white carbon black after being dissolved in dimethyl sulfoxide6Group Part；By A when use6、B6Artificial brushing or mechanically spraying construction can be used in component after mixing.
Setting time 25min when bituminous pavement repair materials provided in this embodiment are repaired for road surface；Condense 30min Cohesion be 3.4 Nm, wet wheel wearing valve be 534 gm-2, Sand adhesion immersion 1d is 348 gm-2。
Embodiment 8:
The performed polymer of thermosetting polymer: unsaturated polyester (UP) performed polymer (191 type) and furane resins performed polymer
Thermoplastic polymer: polyether sulfone；
Initiator: benzoyl peroxide；
Promotor: N, accelerine；
Antioxidant: butylated hydroxy anisole；
Reinforcing agent: mica powder；
Diluent: tetrahydrofuran；
It is 50 parts that the preparation mass fraction of material, which is respectively as follows: unsaturated polyester (UP) performed polymer (191 type), furane resins performed polymer 20 Part, 5 parts of polyether sulfone, 8 parts of tetrahydrofuran, 3 parts of benzoyl peroxide, 1.4 parts of n,N-Dimethylaniline, butylated hydroxy anisole 0.6 part, 15 parts of mica powder, need to compound rubble as coarse aggregate according to construction.
By unsaturated polyester (UP) (191 type) and N, accelerine is hybrid packed to be used as A7Component；Polyether sulfone is dissolved in four It is hybrid packed as B with benzoyl peroxide, furane resins, butylated hydroxy anisole, mica powder after being dissolved in hydrogen furans7Group Part；By A when use7、B7Artificial brushing or mechanically spraying construction can be used in component after mixing.
Setting time 25min when bituminous pavement repair materials provided in this embodiment are repaired for road surface；Condense 30min 3.8 Nm of cohesion, wet wheel wearing valve be 324 gm-2, Sand adhesion immersion 1d is 243 gm-2。
Embodiment 9:
The performed polymer of thermosetting polymer: bisphenol S double propenyl ether, cyclodextrin aldehyde and IPDI Isocyanate prepolymers body
Thermoplastic polymer: nitrocellulose；
Admixture: ground granulated blast furnace slag；
Initiator: methyl ethyl ketone peroxide；
Promotor: dibutyl tin dilaurate；
Antioxidant: dioctyl-p-phenylenediamine；
Reinforcing agent: Paris white；
Diluent: styrene；
Gather materials: 100 μm of rubble and cobble；
The preparation mass fraction of material is respectively as follows: 20 parts of bisphenol S double propenyl ether, and 17.5 parts of cyclodextrin aldehyde, IPDI isocyanates 25 parts of performed polymer, 20 parts of nitrocellulose, 6 parts of styrene, 5 parts of methyl ethyl ketone peroxide, 2.3 parts of dioctyl-p-phenylenediamine, carbonic acid It 12 parts of calcium powder, 15 parts of ground granulated blast furnace slag, 100 μm 10 parts of rubble powder, 100 μm 10 parts of cobble powder, is needed to compound rubble according to construction Aggregate is as coarse aggregate.
The process for preparation and spraying method of material are referring to embodiment 8.
Setting time 25min when bituminous pavement repair materials provided in this embodiment are repaired for road surface；Condense 30min 3.2 Nm of cohesion, wet wheel wearing valve be 618gm-2, Sand adhesion immersion 1d is 357gm-2。
Embodiment 10:
The performed polymer of thermosetting polymer: furfural, methylated melamine
Thermoplastic polymer: polyether-ketone；
Admixture: talcum powder
Initiator: p-methyl benzenesulfonic acid；
Promotor: phosphate n-butyl；
Antioxidant: tert-butyl hydroquinone；
Reinforcing agent: diatomite and magnesium oxide powder；
Diluent: dimethyl acetamide；
Gather materials: 100 μm of quartz sand；
The preparation mass fraction of material be respectively as follows: furfural be 20 parts, 30 parts of methylated melamine, 10 parts of polyether-ketone, diformazan 10 parts of yl acetamide, 6 parts of p-methyl benzenesulfonic acid, 1 part of phosphate n-butyl, 1 part of tert-butyl hydroquinone, 20 parts of talcum powder, diatomite 5 Part, 5 parts of magnesium oxide powder, 10 parts of 100 μm of quartz sand needs to compound rubble as coarse aggregate according to construction.
The process for preparation and spraying method of material are referring to embodiment 8.
Setting time 25min when bituminous pavement repair materials provided in this embodiment are repaired for road surface；Condense 30min Cohesion 3.9Nm, wet wheel wearing valve be 512 gm-2, Sand adhesion immersion 1d is 379gm-2。
Embodiment 11:
The performed polymer of thermosetting polymer: trimethylolpropane trimethacrylate and polyureas performed polymer
Thermoplastic polymer: polymethyl methacrylate；
Admixture: steel-making slag powder；
Initiator: benzoyl peroxide；
Promotor: stannous octoate；
Antioxidant: thio-2 acid laurel alcohol ester；
Reinforcing agent: graphene；
Diluent: tetrahydrofuran；
Gather materials: 200 μm of rubber grain；
The preparation mass fraction of material be respectively as follows: trimethylolpropane trimethacrylate be 40 parts, 20 parts of polyureas performed polymer, poly- first 30 parts of base methyl acrylate, 20 parts of tetrahydrofuran, 2.5 parts of benzoyl peroxide, 0.5 part of stannous octoate, thio-2 acid laurel 2 parts of alcohol ester, 30 parts of steel-making slag powder, 10 parts of graphene, 30 parts of 200 μm of rubber grain needs to compound rubble as thick according to construction Aggregate.
The process for preparation and spraying method of material are referring to embodiment 8.
Setting time 25min when bituminous pavement repair materials provided in this embodiment are repaired for road surface；Condense 30min Cohesion 3.4Nm, wet wheel wearing valve be 417gm-2, Sand adhesion immersion 1d is 347 gm-2。
Embodiment 12:
The performed polymer of thermosetting polymer: epoxy resin prepolymer E42 and IPDI Isocyanate prepolymers body
Thermoplastic polymer: aromatic polyamides hydrazine；
Admixture: silica flour；
Initiator: dipropylenetriamine；
Promotor: zinc peroxide；
Antioxidant: the pungent own ester of phosphorous acid diphenyl；
Reinforcing agent: white carbon black；
Diluent: dibutyl phthalate；
Gather materials: 300 μm of rubble；
It is 25 parts that the preparation mass fraction of material, which is respectively as follows: epoxy resin prepolymer E42,25 parts of IPDI Isocyanate prepolymers body, 35 parts of aromatic polyamides hydrazine, 35 parts of dibutyl phthalate, 10 parts of dipropylenetriamine, 8 parts of zinc peroxide, phosphorous acid diphenyl 2 parts of pungent own ester, 28 parts of silica flour, 13.5 parts of white carbon black, 10 parts of 300 μm of rubble needs to compound rubble as thick according to construction Aggregate.
The process for preparation and spraying method of material are referring to embodiment 8.
Setting time 25min when bituminous pavement repair materials provided in this embodiment are repaired for road surface；Condense 30min 3.8 Nm of cohesion, wet wheel wearing valve be 346 gm-2, Sand adhesion immersion 1d is 413 gm-2。
Embodiment 13:
The performed polymer of thermosetting polymer: hexamethylene diisocyanate (HDI) performed polymer and methyl diphenylene diisocyanate (MDI) performed polymer
Thermoplastic polymer: polyolefin Thermoplastic elastomer；
Admixture: agstone；
Initiator: amine terminated polyether；
Promotor: barium hydroxide；
Antioxidant: dioctyl-p-phenylenediamine；
Reinforcing agent: 400 μm of clay；
Diluent: sulfolane；
Gather materials: rubble；
It is 13 parts that the preparation mass fraction of material, which is respectively as follows: hexamethylene diisocyanate (HDI) performed polymer, diphenyl methane two 17 parts of performed polymer of isocyanates (MDI), 50 parts of polyolefin Thermoplastic elastomer, 1 part of sulfolane, 3.5 parts of amine terminated polyether, hydrogen-oxygen 1.3 parts of barium of change, 1.4 parts of dioctyl-p-phenylenediamine, 23 parts of agstone, 17 parts of clay, 40 parts of 400 μm of rubble, according to construction Need to compound rubble as coarse aggregate.
The process for preparation and spraying method of material are referring to embodiment 8.
Setting time 25min when bituminous pavement repair materials provided in this embodiment are repaired for road surface；Condense 30min Cohesion 4.6Nm, wet wheel wearing valve be 621gm-2, Sand adhesion immersion 1d is 374gm-2。
Embodiment 14:
The performed polymer of thermosetting polymer: unsaturated polyester (UP) performed polymer (191 type) and furane resins performed polymer
Thermoplastic polymer: polyurethane Thermoplastic elastomer；
Admixture: rubber powder；
Initiator: azodiisobutyronitrile；
Promotor: methyl ethyl ketone；
Antioxidant: tert-butyl hydroquinone；
Reinforcing agent: wood powder and cellulose powder；
Diluent: dimethyl acetamide；
Gather materials: 350 μm of quartz sand；
The preparation mass fraction of material be respectively as follows: unsaturated polyester (UP) performed polymer (191 type) be 15 parts, 5 parts of furane resins performed polymer, 60 parts of polyurethane Thermoplastic elastomer, 15.5 parts of dimethyl acetamide, 1.7 parts of azodiisobutyronitrile, 1.2 parts of methyl ethyl ketone, tertiary fourth 0.8 part of base hydroquinone, 10 parts of rubber powder, 13 parts and 7 parts of cellulose powder of wood powder, 25 parts of 350 μm of quartz sand, according to construction Need to compound rubble as coarse aggregate.
The process for preparation and spraying method of material are referring to embodiment 8.
Setting time 25min when bituminous pavement repair materials provided in this embodiment are repaired for road surface；Condense 30min 4.8 Nm of cohesion, wet wheel wearing valve be 504 gm-2, Sand adhesion immersion 1d is 313gm-2。
Embodiment 15:
The performed polymer of thermosetting polymer: thermosetting phenolic resin performed polymer；
Thermoplastic polymer: block polyetheramides elastomer；
Admixture: steel-making slag powder；
Initiator: propene carbonate；
Promotor: acetylacetone,2,4-pentanedione；
Antioxidant: propyl gallate；
Reinforcing agent: iron powder and ferric oxide powder；
Diluent: n-butanol；
Gather materials: 200 μm of quartz sand；
The preparation mass fraction of material is respectively as follows: 55 parts of thermosetting phenolic resin performed polymer, and 8 parts of block polyetheramides elastomer, 22 parts of n-butanol, 3 parts of propene carbonate, 2 parts of acetylacetone,2,4-pentanedione, 2 parts of propyl gallate, 17 parts of steel-making slag powder, 7 parts of iron powder, three oxidations two 8 parts of iron powder, 27 parts of 200 μm of quartz sand needs to compound rubble as coarse aggregate according to construction.
The process for preparation and spraying method of material are referring to embodiment 8.
Setting time 25min when bituminous pavement repair materials provided in this embodiment are repaired for road surface；Condense 30min Cohesion 2.9Nm, wet wheel wearing valve be 537gm-2, Sand adhesion immersion 1d is 378gm-2。
Embodiment 16:
The performed polymer of thermosetting polymer: cyanoacrylate and liquid polysulfide rubber performed polymer
Thermoplastic polymer: polyphenylene oxide；
Admixture: flyash；
Initiator: manganese dioxide；
Promotor: diethylaniline；
Antioxidant: butylated hydroxy anisole；
Reinforcing agent: diatomite；
Diluent: ethyl acetate；
Gather materials: 300 μm of quartz sand；
The preparation mass fraction of material is respectively as follows: 25 parts of cyanoacrylate, and 20 parts of liquid polysulfide rubber performed polymer, polyphenylene oxide 45 Part, 33 parts of ethyl acetate, 5 parts of manganese dioxide, 1.5 parts of diethylaniline, 3.5 parts of butylated hydroxy anisole, 30 parts of flyash, silicon 11 parts of diatomaceous earth, 17 parts of 300 μm of quartz sand needs to compound rubble as coarse aggregate according to construction.
The process for preparation and spraying method of material are referring to embodiment 8.
Setting time 25min when bituminous pavement repair materials provided in this embodiment are repaired for road surface；Condense 30min Cohesion 3.8Nm, wet wheel wearing valve be 617gm-2, Sand adhesion immersion 1d is 369 gm-2。
Other embodiments of the invention provide the quality proportioning of raw material components with the form of table 1 and table 2, wherein table 1 embodiment is free of antioxidant, promotor, initiator, reinforcing agent, diluent, gathers materials, and resists in embodiment described in table 2 The specific object that oxidant, promotor, initiator, reinforcing agent, diluent, the selection gathered materials and mass fraction provide to specifications Matter and dosage are chosen, and the packaging and preparation method of material are referring to embodiment 8；
Table 1
Table 2
Above embodiments are the preferred embodiment of the present invention, are not intended to limit the present invention in any form.It should be pointed out that For those skilled in the art, without departing from the principle of the present invention, several change can also be made Into and retouching, these modifications and embellishments should also be considered as the scope of protection of the present invention.

Claims (10)

1. a kind of bituminous pavement repair materials, which is characterized in that be grouped as by A class component and B class group, the A class component presses matter It is composed of the following components to measure number:
1-80 parts of performed polymer of the monomer of thermosetting polymer and/or thermosetting polymer；
5-40 parts of admixture；
The B class component is composed of the following components by mass fraction:
1-80 parts of thermoplastic polymer；
The monomer of the thermosetting polymer and/or the performed polymer of thermosetting polymer polymerize to obtain thermosetting polymer；It is described The performed polymer of thermosetting polymer is pre- comprising heat-curable urethane performed polymer, thermosetting phenolic resin performed polymer, unsaturated polyester (UP) Aggressiveness, furane resins performed polymer, liquid polysulfide rubber performed polymer, epoxy resin prepolymer, polyureas performed polymer, thermosetting property melamine One of amine-formaldehyde resins, thermosetting acrylic resin are a variety of；
The monomer of the thermosetting polymer is that have the monofunctional monomer of reactable, bifunctional monomer, trifunctional monomer and more One of functional monomer is a variety of；
The thermoplastic polymer includes natural rubber, butadiene-styrene rubber, nitrile rubber, butadiene rubber, EP rubbers, neoprene rubber One of glue, styrene butadiene thermoplasticelastomer, thermoplastic polyurethane elastomer, polypropylene glycol and road asphalt Or it is a variety of.
2. a kind of bituminous pavement repair materials, which is characterized in that including A class component and B class component, the A class component presses quality Number includes:
20-60 parts of performed polymer of the monomer of thermosetting polymer and/or thermosetting polymer；
2-8 parts of antioxidant；
1-8 parts of promotor；
10-30 parts of admixture；
B class component includes: by mass fraction
5-60 parts of thermoplastic polymer；
10-40 parts of initiator；
10-20 parts of reinforcing agent；
1-60 parts of diluent；
Gather materials 10-40 parts；
The monomer of the thermosetting polymer and/or the performed polymer of thermosetting polymer polymerize to obtain thermosetting polymer；It is described Thermosetting polymer includes thermosetting phenolic resin, thermoset urea aldehyde resin, thermosetting acrylic resin, thermoset epoxy tree Rouge, heat-curable urethane, thermosetting property unsaturated polyester (UP), thermosetting polyurea and thermosetting property can one of vulcanized rubbers or a variety of.
3. bituminous pavement repair materials according to claim 2, which is characterized in that the thermosetting phenolic resin is that have Heat cured rosin modified phenolic resin, alcohols etherification of phenolic resin, epoxy modified phenolic resin and alkyd modified phenolic resin One of or it is a variety of；
The thermoset amino resin is that have heat cured Lauxite, melamine resin, polyamide polyamines epoxy One of chloropropane is a variety of；
The thermosetting acrylic resin is a kind of in the acrylic resin containing activity hydroxy functional group or carboxyl functional group Or it is a variety of, oxyalkylation reaction solidification or and multi isocyanate crosslinking can be passed through with amino resins；
The thermosetting epoxy resin is that have heat cured glycidyl ether type epoxy resin, glycidol esters asphalt mixtures modified by epoxy resin Rouge, glycidyl amine epoxy resin, aliphatic epoxy resin, cycloaliphatic epoxy resin, bisphenol-s epoxy resin, bisphenol S epoxy One of vinylite and bisphenol S episulfide resin are a variety of；
The thermosetting polyurethane resin is by aliphatic isocyanates, alicyclic isocyanate, aromatic isocyanate, polyester One of polyalcohol and polyether polyol or a variety of polymerizations obtain；
The thermosetting property unsaturated polyester (UP) is that have heat cured adjacent benzene-type unsaturated polyester (UP), metaphenylene unsaturated polyester (UP), to benzene One of type unsaturated polyester (UP), bisphenol A-type unsaturated polyester (UP) and vinyl ester type unsaturated polyester (UP) are a variety of；
The thermosetting polyurea is by isophorone diisocyanate, methyl diphenylene diisocyanate or toluene di-isocyanate(TDI) One of thermosetting polyurea polymerizeing with ethylenediamine, m-phenylene diamine (MPD), diaminodiphenylmethane or amine terminated polyether is more Kind；
The thermosetting property can vulcanized rubber be that there are heat cured natural rubber, butadiene-styrene rubber, isoprene rubber, butadiene rubber, three First EP rubbers, butyl rubber, neoprene, carboxylic rubber, nitrile rubber, chlorosulfonated polyethylene rubber, silicon rubber, fluorubber With one of polysulfide rubber or a variety of.
4. bituminous pavement repair materials according to claim 2, which is characterized in that the thermoplastic polymer includes to have Thermoplastic polymethylacrylic acid, ABS resin, SBS resin, butadiene rubber, nitrile rubber, gathers polymethyl methacrylate Sulphur rubber, butadiene-styrene rubber, natural rubber, butadiene rubber, isoprene rubber, EP rubbers, polyvinyl alcohol, polyvinyl butyral, Polyvinyl formal, nitrocellulose, cellulose acetate, Triafol T, hydroxymethyl cellulose, hydroxypropyl cellulose, Polyvinyl chloride, Kynoar, polyacrylonitrile, polystyrene, polyarylsulfone (PAS), polyether sulfone, Nomex, polyphenylene oxide, polyphenylene sulfide, Aromatic polyamides, aromatic polyamides hydrazine, polyphenylsulfone-paraphenylene terephthalamide, polyetherimide, polyethersulfone ketone, polybenzimidazoles ketone, Polybenzimidazoles, polyether-ketone, polyether-ether-ketone, polypiperazine-amide, thermoplastic polyurethane elastomer, polycarbonate, poly- terephthaldehyde Sour glycol ester, polyformaldehyde, styrene analog thermoplastic elastomer, block polyetheramides elastomer, polyolefin thermoplastic elastomer, Polyurethane termoplastic elastomer, thermoplastic elastomer of polyvinyl-chloride, polyester thermoplastic elastomer, diene analog thermoplastic elastomer and One of pitch is a variety of.
5. bituminous pavement repair materials according to claim 2, which is characterized in that the admixture includes silica flour, powder One of coal ash, ground granulated blast furnace slag, agstone, talcum powder, rubber powder, steel-making slag powder and CHARACTERISTICS OF TAILINGS SAND are a variety of.
6. bituminous pavement repair materials according to claim 5, which is characterized in that the partial size of the admixture 80 μm with Under.
7. bituminous pavement repair materials according to claim 2, which is characterized in that the initiator includes peroxide Initiator, azo-initiator, persulfuric acid salt initiator, aliphatic polyamine class initiator, aromatic polyamine class initiator, miaow One in azole initiator, modified amine initiator, organic acid anhydride initiator and boron trifluoride class initiator, vulcanizer Kind is a variety of.
8. bituminous pavement repair materials according to claim 2, which is characterized in that the reinforcing agent includes carbon black, hard charcoal Black, carbon fiber, carbon nanotube, graphene, Paris white, clay, talcum, diatomite, mica powder, asbestos, metal powder, metal oxygen One of compound, thermosetting resin hollow ball, wood powder, cellulose powder, silane coupling agent are a variety of.
9. bituminous pavement repair materials according to claim 2, which is characterized in that the partial size to gather materials be 80 μm with On.
10. bituminous pavement repair materials according to claim 2, which is characterized in that the antioxidant is anti-comprising amine One of oxidant, phenol antioxidant, monothioester, phosphite ester and metallic ion passivation agent are a variety of.
CN201811529638.9A 2018-12-14 2018-12-14 Asphalt pavement repairing material Active CN109401519B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811529638.9A CN109401519B (en) 2018-12-14 2018-12-14 Asphalt pavement repairing material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811529638.9A CN109401519B (en) 2018-12-14 2018-12-14 Asphalt pavement repairing material

Publications (2)

Publication Number Publication Date
CN109401519A true CN109401519A (en) 2019-03-01
CN109401519B CN109401519B (en) 2021-08-24

Family

ID=65459073

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201811529638.9A Active CN109401519B (en) 2018-12-14 2018-12-14 Asphalt pavement repairing material

Country Status (1)

Country Link
CN (1) CN109401519B (en)

Cited By (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109762468A (en) * 2019-03-25 2019-05-17 河北建设集团股份有限公司 A kind of asphalt concrete pavement protective agent and its preparation method and application
CN110067293A (en) * 2019-04-25 2019-07-30 广东景源建设工程有限公司 Sewage conduct engineering construction process
CN110205026A (en) * 2019-07-10 2019-09-06 安徽工业大学 It is a kind of with fire-retardant with rustless property high adhesion paint and preparation method thereof
CN110437633A (en) * 2019-07-11 2019-11-12 上海市政工程设计研究总院（集团）有限公司 A kind of road surface reduction sealing of biodegradable vehicle tail gas
CN110725176A (en) * 2019-10-29 2020-01-24 何浩 Cold paving method for asphalt pavement
CN110845738A (en) * 2019-11-28 2020-02-28 科迈特新材料有限公司 Proportioning process for processing high-molecular synthetic material
CN111253111A (en) * 2020-01-16 2020-06-09 交通运输部科学研究院 Preparation method and use method of normal-temperature rapid repair material for asphalt pavement
CN111393865A (en) * 2020-05-27 2020-07-10 吴碧玉 High-viscosity modified asphalt and preparation method thereof
CN111925706A (en) * 2020-08-13 2020-11-13 天津佰思特交通科技股份有限公司 Water-based MMA colored pattern anti-slip material and construction method thereof
CN112479632A (en) * 2020-11-12 2021-03-12 马鞍山十七冶工程科技有限责任公司 Unsaturated polyester concrete for pavement restoration and preparation method thereof
CN112920681A (en) * 2021-01-30 2021-06-08 常熟市中电机械设备有限公司 Epoxy resin-based polymer repair material
CN112962380A (en) * 2021-02-19 2021-06-15 中交第二公路工程局有限公司 Construction method of asphalt pavement
WO2021129409A1 (en) * 2019-12-25 2021-07-01 山西中涂交通科技股份有限公司 Method for rapidly repairing road surface
CN113088250A (en) * 2021-03-11 2021-07-09 祎禾科技有限公司 High-speed rail ballastless track slab crack maintenance material and preparation method thereof
CN113105155A (en) * 2021-04-25 2021-07-13 江西省交通设计研究院有限责任公司 Pressure-resistant highway concrete pavement waterproof material and preparation method thereof
CN113248937A (en) * 2021-05-19 2021-08-13 山东高速集团有限公司创新研究院 Special asphalt for airport pavement and preparation method thereof
CN113526907A (en) * 2021-08-11 2021-10-22 广东德泽建设工程有限公司 Solvent type cold-patch asphalt and road pit repairing method
CN113881343A (en) * 2021-11-24 2022-01-04 苏州市姑苏新型建材有限公司 Cold-construction non-cured rubber asphalt waterproof coating and preparation method thereof
CN114106571A (en) * 2021-12-14 2022-03-01 江苏争创磊固材料科技有限公司 Polymer material for rapidly repairing asphalt pavement cracks and preparation method thereof
CN115286972A (en) * 2022-07-28 2022-11-04 国能(山东)能源环境有限公司 Anticorrosive paint and preparation method of anticorrosive paint
CN115504709A (en) * 2022-11-11 2022-12-23 北京建筑大学 Bridge deck repairing polyurethane polymer concrete and preparation method thereof
CN115584202A (en) * 2022-09-28 2023-01-10 沥宏新材料科技(上海)有限公司 Silicon modified asphalt fog sealing layer material and preparation method thereof
CN115948120A (en) * 2022-12-23 2023-04-11 苏州市姑苏新型建材有限公司 Special non-cured rubber asphalt waterproof coating and preparation method thereof
CN116063811A (en) * 2021-10-29 2023-05-05 中国石油化工股份有限公司 Modified asphalt stabilizer for improving storage stability
CN117486537A (en) * 2023-12-27 2024-02-02 江苏瑞沃建设集团有限公司 Anti-rutting cement bridge deck asphalt pavement material and preparation method thereof
CN117601542A (en) * 2024-01-17 2024-02-27 新大运防水科技(唐山)有限公司 Impervious asphalt waterproof coiled material and preparation method thereof

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080188594A1 (en) * 2002-05-14 2008-08-07 Western Emulsions, Inc. Polymer modified asphalt emulstions for treatment of road surfaces
CN102173657A (en) * 2011-02-22 2011-09-07 武汉钢铁(集团)公司 Micro-surfacing steel slag mixture and preparation method thereof
CN102827567A (en) * 2012-09-13 2012-12-19 中南林业科技大学 Crack repair material for asphalt concrete pavement
CN106867358A (en) * 2016-12-31 2017-06-20 山西省交通科学研究院 A kind of wear-resisting low noise type road surface repair layer and preparation method thereof
CN108342071A (en) * 2018-02-28 2018-07-31 安平 Asphalt pavement crack restorative procedure
CN108411752A (en) * 2018-02-09 2018-08-17 温州市城南市政建设维修有限公司 The restorative procedure of asphalt pavement pit
CN108913093A (en) * 2018-06-25 2018-11-30 重庆交通大学 A kind of compounded Multifunctional asphalt road surface casting glue and its preparation process

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080188594A1 (en) * 2002-05-14 2008-08-07 Western Emulsions, Inc. Polymer modified asphalt emulstions for treatment of road surfaces
CN102173657A (en) * 2011-02-22 2011-09-07 武汉钢铁(集团)公司 Micro-surfacing steel slag mixture and preparation method thereof
CN102827567A (en) * 2012-09-13 2012-12-19 中南林业科技大学 Crack repair material for asphalt concrete pavement
CN106867358A (en) * 2016-12-31 2017-06-20 山西省交通科学研究院 A kind of wear-resisting low noise type road surface repair layer and preparation method thereof
CN108411752A (en) * 2018-02-09 2018-08-17 温州市城南市政建设维修有限公司 The restorative procedure of asphalt pavement pit
CN108342071A (en) * 2018-02-28 2018-07-31 安平 Asphalt pavement crack restorative procedure
CN108913093A (en) * 2018-06-25 2018-11-30 重庆交通大学 A kind of compounded Multifunctional asphalt road surface casting glue and its preparation process

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
吉晓东等: "沥青路面坑槽快速修复技术应用研究", 《中国新技术新产品》 *

Cited By (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109762468A (en) * 2019-03-25 2019-05-17 河北建设集团股份有限公司 A kind of asphalt concrete pavement protective agent and its preparation method and application
CN109762468B (en) * 2019-03-25 2021-07-09 河北建设集团股份有限公司 Asphalt concrete pavement protective agent and preparation method and application thereof
CN110067293A (en) * 2019-04-25 2019-07-30 广东景源建设工程有限公司 Sewage conduct engineering construction process
CN110205026A (en) * 2019-07-10 2019-09-06 安徽工业大学 It is a kind of with fire-retardant with rustless property high adhesion paint and preparation method thereof
CN110205026B (en) * 2019-07-10 2021-07-09 安徽工业大学 High-adhesion coating with flame retardant and antirust properties and preparation method thereof
CN110437633A (en) * 2019-07-11 2019-11-12 上海市政工程设计研究总院（集团）有限公司 A kind of road surface reduction sealing of biodegradable vehicle tail gas
CN110437633B (en) * 2019-07-11 2023-01-24 上海市政工程设计研究总院（集团）有限公司 Road surface reduction seal capable of degrading automobile exhaust
CN110725176A (en) * 2019-10-29 2020-01-24 何浩 Cold paving method for asphalt pavement
CN110845738A (en) * 2019-11-28 2020-02-28 科迈特新材料有限公司 Proportioning process for processing high-molecular synthetic material
WO2021129409A1 (en) * 2019-12-25 2021-07-01 山西中涂交通科技股份有限公司 Method for rapidly repairing road surface
CN111253111A (en) * 2020-01-16 2020-06-09 交通运输部科学研究院 Preparation method and use method of normal-temperature rapid repair material for asphalt pavement
CN111393865A (en) * 2020-05-27 2020-07-10 吴碧玉 High-viscosity modified asphalt and preparation method thereof
CN111925706A (en) * 2020-08-13 2020-11-13 天津佰思特交通科技股份有限公司 Water-based MMA colored pattern anti-slip material and construction method thereof
CN112479632A (en) * 2020-11-12 2021-03-12 马鞍山十七冶工程科技有限责任公司 Unsaturated polyester concrete for pavement restoration and preparation method thereof
CN112920681A (en) * 2021-01-30 2021-06-08 常熟市中电机械设备有限公司 Epoxy resin-based polymer repair material
CN112962380A (en) * 2021-02-19 2021-06-15 中交第二公路工程局有限公司 Construction method of asphalt pavement
CN113088250A (en) * 2021-03-11 2021-07-09 祎禾科技有限公司 High-speed rail ballastless track slab crack maintenance material and preparation method thereof
CN113105155A (en) * 2021-04-25 2021-07-13 江西省交通设计研究院有限责任公司 Pressure-resistant highway concrete pavement waterproof material and preparation method thereof
CN113105155B (en) * 2021-04-25 2023-08-29 江西省交通设计研究院有限责任公司 Pressure-resistant highway concrete pavement waterproof material and preparation method thereof
CN113248937A (en) * 2021-05-19 2021-08-13 山东高速集团有限公司创新研究院 Special asphalt for airport pavement and preparation method thereof
CN113526907A (en) * 2021-08-11 2021-10-22 广东德泽建设工程有限公司 Solvent type cold-patch asphalt and road pit repairing method
CN116063811A (en) * 2021-10-29 2023-05-05 中国石油化工股份有限公司 Modified asphalt stabilizer for improving storage stability
CN116063811B (en) * 2021-10-29 2024-08-13 中国石油化工股份有限公司 Modified asphalt stabilizer for improving storage stability
CN113881343A (en) * 2021-11-24 2022-01-04 苏州市姑苏新型建材有限公司 Cold-construction non-cured rubber asphalt waterproof coating and preparation method thereof
CN114106571A (en) * 2021-12-14 2022-03-01 江苏争创磊固材料科技有限公司 Polymer material for rapidly repairing asphalt pavement cracks and preparation method thereof
CN115286972B (en) * 2022-07-28 2023-05-23 国能(山东)能源环境有限公司 Anticorrosive paint and preparation method of anticorrosive paint
CN115286972A (en) * 2022-07-28 2022-11-04 国能(山东)能源环境有限公司 Anticorrosive paint and preparation method of anticorrosive paint
CN115584202A (en) * 2022-09-28 2023-01-10 沥宏新材料科技(上海)有限公司 Silicon modified asphalt fog sealing layer material and preparation method thereof
CN115504709A (en) * 2022-11-11 2022-12-23 北京建筑大学 Bridge deck repairing polyurethane polymer concrete and preparation method thereof
CN115948120A (en) * 2022-12-23 2023-04-11 苏州市姑苏新型建材有限公司 Special non-cured rubber asphalt waterproof coating and preparation method thereof
CN117486537A (en) * 2023-12-27 2024-02-02 江苏瑞沃建设集团有限公司 Anti-rutting cement bridge deck asphalt pavement material and preparation method thereof
CN117486537B (en) * 2023-12-27 2024-03-15 江苏瑞沃建设集团有限公司 Anti-rutting cement bridge deck asphalt pavement material and preparation method thereof
CN117601542A (en) * 2024-01-17 2024-02-27 新大运防水科技(唐山)有限公司 Impervious asphalt waterproof coiled material and preparation method thereof
CN117601542B (en) * 2024-01-17 2024-03-26 新大运防水科技(唐山)有限公司 Impervious asphalt waterproof coiled material and preparation method thereof

Also Published As

Publication number Publication date
CN109401519B (en) 2021-08-24

Similar Documents

Publication Publication Date Title
CN109401519A (en) A kind of bituminous pavement repair materials
CN112724698B (en) High-temperature secondary curing epoxy modified asphalt pavement paving material and preparation and use methods thereof
CN103964751B (en) A kind of epoxy resin mortar bridge floor thin layer pavement material and construction method thereof
KR102040532B1 (en) Modified-Asphalt Concrete Composition for Paving Road Using Petroleum Resin Added Hydrogen and Stylene Isoprene Stylene and Constructing Methods Using Thereof
KR101487855B1 (en) The recycling asphalt mixture for reforming
KR102054820B1 (en) Waterproof Asphalt Concrete Composition for Overlay Pavement Using Petroleum Resin Added Hydrogen, Stylene Isoprene Stylene and Stylene Butadien Stylene and Constructing Methods of Entire Type Waterproof for Cracks of Surface Using Thereof
KR102036879B1 (en) A Eco-friendly Waterproofing Treatment Composition for Road and Waterproofing Methods using Thereof
KR102119736B1 (en) Modified-Asphalt Concrete Compositions for Pavement of Roads Using Styrene Isoprene Styrene, Styrene Ethylene Butylene Styrene, Recycling Asphalt and Aggregate-powder of Improved Grain Size and Constructing Methods Using Thereof
KR102058674B1 (en) Modified-Asphalt Concrete Composition and Constructing Methods Using Thereof
CN111607312A (en) Toughened abrasion-resistant epoxy resin daub and preparation method thereof
CN101736911A (en) External protection or repair method for concrete
KR102059840B1 (en) Waterproof Asphalt Concrete Composition for Thin Overlay Pavement Using Petroleum Resin Added Hydrogen and Stylene Isoprene Stylene and Constructing Repairing Method of Entire Type Waterproof for Cracks of Surface Using Thereof
CN108947457B (en) Organic-inorganic composite photo-initiation latent soil curing agent and preparation method thereof
CN101704653A (en) Resin cement for levelling cement concrete road surface
KR102059837B1 (en) Half-Elastic Modified Asphalt Concrete Composition Using Petroleum Resin Added Hydrogen and Stylene Isoprene Stylene and Constructing Repairing Method of Entire Type Waterproof for Cracks of Surface Using Thereof
KR101219476B1 (en) Compositions for surface sign of paved road and construction method of surface sign using the same
CN113736402A (en) Environment-friendly abrasion-resistant anti-degradation epoxy resin daub and preparation method thereof
CN112280323A (en) Preparation method of asphalt regenerant with large-proportion RAP mixing amount
WO2023108764A1 (en) High-performance epoxy resin adhesive layer material, and preparation method therefor
CN113062167B (en) Smearing type asphalt-based road crack repairing adhesive
CN106866028B (en) A kind of composition being used to prepare permeability flexible brick and permeability flexible brick
JP2010121350A (en) Polyurethane composition for elastic pavement
KR102132607B1 (en) Modified-Resin Stone Mastic Asphalt Concrete Compositions Using Stylene Isoprene Stylene and Constructing Methods Using Thereof
KR102250270B1 (en) Composition of the watertight asphalt paving overlay for bridges and concrete roadways
CN108797333B (en) Combined steel bridge deck pavement structure

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant