CN109287629A - The new application of cis- 3- hexenol and adverse-resistant agent including cis- 3- hexenol - Google Patents
The new application of cis- 3- hexenol and adverse-resistant agent including cis- 3- hexenol Download PDFInfo
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- CN109287629A CN109287629A CN201811322619.9A CN201811322619A CN109287629A CN 109287629 A CN109287629 A CN 109287629A CN 201811322619 A CN201811322619 A CN 201811322619A CN 109287629 A CN109287629 A CN 109287629A
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- Prior art keywords
- cis
- hexenol
- adverse
- resistant agent
- plant
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/02—Acyclic compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
- A01N25/10—Macromolecular compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
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- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention provides cis- 3- hexenols to apply in the resistance for improving plants against abiotic stress.The present invention also provides application of the cis- 3- hexenol in the adverse-resistant agent for preparing the resistance for improving plants against abiotic stress.The present invention also provides a kind of adverse-resistant agents, include cis- 3- hexenol 20%-87%, cellulose 2%-20%, polyoxyethylene methyl esters 0.5%-10%, mineral oil 10%-50% based on mass content.
Description
Technical field
The invention belongs to chemical farming technical field, in particular it relates to the new application of cis- 3- hexenol and including
The adverse-resistant agent of cis- 3- hexenol.
Background technique
Cis- 3- hexenol is a kind of alcohol compound, is easy to degrade, molecular formula C6H12O, chemical structure are as follows:
There is the specific synthesis technology of cis- 3- hexenol now, for example, making lithium metal (or metallic sodium) in liquefied ammonia
Acetylene (or sodium acetylide) is generated with acetylene reaction, then generates ethyl acetylene, ethyl acetylene and reacting ethylene oxide with ethanol synthesis
3- acetylene -1- alcohol is obtained, product leaf-alcohol (i.e. cis- 3- hexenol) is made in most back end hydrogenation.It is starting material by tetrahydrofuran, or uses
The chosen property of 3- hexynol hydrogenates.Wittig can also be carried out by 3- chloropropyl alcohol, triphenylphosphine and propionic aldehyde to react.
Currently, cis- 3- hexenol is mainly used in agricultural insect pest's prevention and control field.For example, application No. is
200610048482.3 Chinese invention patent application discloses a kind of Pyralid attractant, in every 100 parts of attractants, by volume
Example includes the auxiliary agent of 0.5-5 parts of trans- 2- hexenoic aldehyde, 0.5-5 parts of cis- 3- hexenol, 2-15 parts of aromatic compound and surplus.Shen
Number a kind of broad spectrum attractant for tumblebug perfect insects please be disclosed for 200610048485.7 Chinese invention patent application, every 100
The volume parts of each constitutive material are 0.005-2 parts of cis- 3- hexenol in part preparation, and aromatic compound 0.05-45, remaining is
Auxiliary agent.
Summary of the invention
The object of the present invention is to provide the new applications of cis- 3- hexenol.
On the one hand, the application the present invention provides cis- 3- hexenol in the resistance for improving plants against abiotic stress.
On the other hand, the present invention provides cis- 3- hexenols to prepare the resistance for improving plants against abiotic stress
Adverse-resistant agent in application.
On the other hand, the present invention provides a kind of adverse-resistant agents, based on mass content, include: cis- 3- hexenol 20%-
87%, cellulose 2%-20%, polyoxyethylene methyl esters 0.5%-10%, mineral oil 10%-50%.
Beneficial effects of the present invention: the anti-adversity of cis- 3- hexenol is good, and the special efficacy phase is long, and does not influence to plant after use
The growing way of object is agriculturally ideal adverse-resistant agent.Adverse-resistant agent provided by the invention has control efficiency good, nontoxic, noresidue, nothing
Pollution, it is nuisanceless, have the characteristics that volatile, be particularly conducive to environmental protection.
Specific embodiment
In order to fully understand the purpose of the present invention, feature and effect, by following specific embodiments, the present invention is made detailed
It describes in detail bright.For process of the invention in addition to following the description, remaining is all made of the conventional method or device of this field.
Plant is all extremely sensitive to temperature and moisture condition, and high temperature, the Droughts of summer seriously affect plant growth hair
It educates, seriously also results in Plant death.In order to improve plant high temperature and drought resistance, need to eliminate or weaken using certain method high
Injury of the warm arid to plant, allows plant to spend Summer High-Temperature Times safely.
It is primarily present and agricultural insect pest's prevention and control field for the research of cis- 3- hexenol at present.The present inventor is logical
Cross study the cis- 3- hexenol of discovery beyond expectation be it is a kind of there are degeneration-resistant active volatile products, be easily absorbed by plants and
Conduction, to plant without phytotoxicity, is easy to degradation of volatilizing in the environment.
Firstly, main terms involved in the present invention are described as follows:
Abiotic stress refers to that any abiotic factor is adversely affected caused by plant for example, high in certain circumstances
Temperature, arid, flood, saline and alkaline, mineral deficiency and unfavorable pH etc..In the present invention, abiotic stress refers in particular to high temperature
And/or arid.
Plant, plant is primarily referred to as angiosperm, such as tea tree, rice, corn, rape in the present invention.Following reality
The effect that example mainly illustrates technical solution of the present invention by taking tea tree as an example is applied, but this is illustrative, and not restrictive.
In the first aspect of the present invention, the present invention provides cis- 3- hexenols to improve the anti-of plants against abiotic stress
Application in property.
Preferably, it is 0.1%- that the application mode of cis- 3- hexenol, which can be cis- 3- hexenol being configured to mass concentration,
100% (preferably 30%-60%, plant of the more preferable spray solution 50%) in plant to be processed, or atomization plant to be processed
Plant, or pour the root of plant to be processed；Alternatively, missible oil, suspending agent, aqueous emulsion, microemulsion is made in cis- 3- hexenol
Or water dispersion granule.
In the second aspect of the present invention, the present invention provides cis- 3- hexenol in preparation for improving plants against abiotic
Application in the adverse-resistant agent of the resistance of stress.
Preferably, the application mode of cis- 3- hexenol is that cis- 3- hexenol is made to missible oil, suspending agent, aqueous emulsion, micro-
Emulsion or water dispersion granule.
The present inventor by studying discovery beyond expectation, cis- 3- hexenol can activated plant it is resistant to high temperatures, anti-
The relevant transcription factor expression of drought, and then air vent switch, photosynthesis, respiration, metabolism degree are adjusted, final realize is improved
The effect of plant high temperature and drought resistance.
In the third aspect of the present invention, the present invention provides a kind of adverse-resistant agent, can effectively improve plant to high temperature and/or
The resistance of arid.
Based on mass content, adverse-resistant agent of the invention includes: cis- 3- hexenol 20%-87%, cellulose 2%-20%,
Polyoxyethylene methyl esters 0.5%-10%, mineral oil 10%-50%.
Preferably, adverse-resistant agent of the invention includes: cis- 3- hexenol 40%-70%, cellulose 10%-20%, polyoxy second
Alkene methyl esters 3.5%-8%, mineral oil 20%-35%.
It is highly preferred that adverse-resistant agent of the invention includes: cis- 3- hexenol 50%, cellulose 10%, polyoxyethylene methyl esters
5%, mineral oil 35%.
Cis- 3- hexenol, cellulose, polyoxyethylene methyl esters and the mineral oil that adverse-resistant agent of the invention uses can pass through city
Purchase obtains.
Cis- 3- hexenol, cellulose, polyoxyethylene methyl esters, mineral oil are pressed above-mentioned mass content by adverse-resistant agent of the invention
It can make to generate synergistic effect between each component after being combined, specifically, cis- 3- hexenol is to improve plant high temperature and drought
The active constituent of resistance, cellulose are sustained release agents, and polyoxyethylene methyl esters is emulsifier, and mineral oil is sticker.By cis- 3- oneself
The synergistic effect of enol, cellulose, polyoxyethylene methyl esters, mineral oil, can be realized adverse-resistant agent it is long-term efficient resistant to high temperatures and/or
The effect of arid.
Capsule, missible oil, suspending agent, aqueous emulsion, microemulsion or water can be made using known method in adverse-resistant agent of the invention
Dispersible granule.Those skilled in the art can reasonably select according to actual needs, and details are not described herein.
Embodiment
The present invention is further illustrated below by embodiment, but protection scope of the present invention is not limited to specific embodiment.
Following raw materials used in the examples are purchased from one base Industrial Co., Ltd. of Shanghai.
Embodiment 1
Various substances used and its quality are shown in Table 1 in embodiment 1.
Preparation method: according to the ratio in table 1, cis- 3- hexenol and mineral oil are mixed, polyoxyethylene first is added immediately
Ester and cellulose, mixing, obtain the adverse-resistant agent of the present embodiment.
Embodiment 2 to 7
Various substances used and its quality are shown in Table 1 in embodiment 2 to 7.The preparation method of the adverse-resistant agent of embodiment 2 to 7 with
Embodiment 1 is identical, and difference is only that be adjusted by amount of the table 1 to various substances.
Table 1 (unit: gram)
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 | Embodiment 7 | |
| Cis- 3- hexenol | 50 | 40 | 70 | 20 | 86 | 35 | 75 |
| Cellulose | 10 | 20 | 9 | 20 | 3.5 | 18 | 5 |
| Polyoxyethylene methyl esters | 5 | 8 | 3.5 | 10 | 0.5 | 9 | 2.5 |
| Mineral oil | 35 | 32 | 17.5 | 50 | 10 | 38 | 17.5 |
| It is total | 100 | 100 | 100 | 100 | 100 | 100 | 100 |
Embodiment 8: effect experiment
Test method: selection growing way is 900 plants of tea tree Plug seedling identical, is divided into 9 groups.Reality is respectively adopted in 1st to 8 group
Adverse-resistant agent, the cis- 3- hexenol for applying example 1 to embodiment 7 are handled, and the 9th group as a control group, without processing.Divide later
It is not placed under the conditions of room temperature, arid, high temperature, high temperature and drought and is cultivated.It observes the growing way situation of tea shoot and counts its survival
Rate (is counted) on the 3rd day, the results are shown in Table 2.
Table 2
| Room temperature | Arid | High temperature | High temperature and drought | |
| 1st group | 100% | 64% | 72% | 72% |
| 2nd group | 100% | 56% | 64% | 68% |
| 3rd group | 100% | 48% | 52% | 56% |
| 4th group | 100% | 24% | 12% | 12% |
| 5th group | 100% | 52% | 56% | 60% |
| 6th group | 100% | 56% | 60% | 68% |
| 7th group | 100% | 52% | 56% | 64% |
| 8th group | 100% | 52% | 60% | 68% |
| 9th group | 100% | 12% | 4% | 4% |
From the experimental result of table 2, it can be seen that adverse-resistant agent of the invention can effectively improve plant resists to high temperature and drought
Property.
The above embodiment is a preferred embodiment of the present invention, but embodiments of the present invention are not by above-described embodiment
Limitation, other any substitutions made without departing from the spirit and principles of the present invention, combination, change, are simplified modification
Deng should be equivalent substitute mode, be included within the scope of the present invention.
Claims (10)
1. application of the cis- 3- hexenol in the resistance for improving plants against abiotic stress.
2. application of the cis- 3- hexenol in the adverse-resistant agent for preparing the resistance for improving plants against abiotic stress.
3. application according to claim 1 or 2, which is characterized in that the abiotic stress is high temperature and/or arid.
4. application according to claim 1 or 2, which is characterized in that the plant is angiosperm.
5. application according to claim 4, which is characterized in that the plant is tea tree, rice, corn and rape.
6. application according to claim 1, which is characterized in that the application mode of the cis- 3- hexenol is: described cis-
3- hexenol is sprayed with the mass concentration of 0.1%-100%, is applied, pouring the plant, alternatively, cis- 3- hexenol is made
Missible oil, suspending agent, aqueous emulsion, microemulsion or water dispersion granule.
7. a kind of adverse-resistant agent, which is characterized in that based on mass content, include: cis- 3- hexenol 20%-87%, cellulose 2%-
20%, polyoxyethylene methyl esters 0.5%-10% and mineral oil 10%-50%.
8. adverse-resistant agent according to claim 7, which is characterized in that based on mass content, include: cis- 3- hexenol 40%-
70%, cellulose 10%-20%, polyoxyethylene methyl esters 3.5%-8% and mineral oil 20%-35%.
9. adverse-resistant agent according to claim 8, which is characterized in that based on mass content, include: cis- 3- hexenol 50%,
Cellulose 10%, polyoxyethylene methyl esters 5%, mineral oil 35%.
10. according to the described in any item adverse-resistant agents of claim 7-9, which is characterized in that the adverse-resistant agent be missible oil, suspending agent,
Aqueous emulsion, microemulsion or water dispersion granule.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811322619.9A CN109287629A (en) | 2018-11-07 | 2018-11-07 | The new application of cis- 3- hexenol and adverse-resistant agent including cis- 3- hexenol |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811322619.9A CN109287629A (en) | 2018-11-07 | 2018-11-07 | The new application of cis- 3- hexenol and adverse-resistant agent including cis- 3- hexenol |
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| Publication Number | Publication Date |
|---|---|
| CN109287629A true CN109287629A (en) | 2019-02-01 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811322619.9A Pending CN109287629A (en) | 2018-11-07 | 2018-11-07 | The new application of cis- 3- hexenol and adverse-resistant agent including cis- 3- hexenol |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115927443A (en) * | 2023-01-30 | 2023-04-07 | 安徽农业大学 | Regulation and control of (Z) -3-hexenol and application thereof in drought resistance of tea trees |
| CN116326600A (en) * | 2023-02-22 | 2023-06-27 | 中国标准化研究院 | Growth regulator and preparation method and application thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103764642A (en) * | 2011-04-15 | 2014-04-30 | 拜耳知识产权有限责任公司 | Substituted vinyl and alkinyl cyclohexenols as active agents against abiotic stress in plants |
-
2018
- 2018-11-07 CN CN201811322619.9A patent/CN109287629A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103764642A (en) * | 2011-04-15 | 2014-04-30 | 拜耳知识产权有限责任公司 | Substituted vinyl and alkinyl cyclohexenols as active agents against abiotic stress in plants |
Non-Patent Citations (4)
| Title |
|---|
| TRISTAN M.COFER: "Green leaf volatiles protect maize (Zea mays) seedlings against damage from cold stress", 《PLANT CELL ENVIRON.》 * |
| 刘琴等: "干旱和高温对植物胁迫效应的研究进展", 《西华师范大学学报(自然科学版)》 * |
| 吴永波等: "高温干旱复合胁迫对构树幼苗抗氧化酶活性和活性氧代谢的影响", 《生态学报》 * |
| 曲亚楠等: "高温与干旱胁迫对匍匐翦股颖抗氧化代谢的影响", 《山东农业大学学报（自然科学版）》 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115927443A (en) * | 2023-01-30 | 2023-04-07 | 安徽农业大学 | Regulation and control of (Z) -3-hexenol and application thereof in drought resistance of tea trees |
| CN116326600A (en) * | 2023-02-22 | 2023-06-27 | 中国标准化研究院 | Growth regulator and preparation method and application thereof |
| CN116326600B (en) * | 2023-02-22 | 2024-10-01 | 中国标准化研究院 | Growth regulator and preparation method and application thereof |
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Application publication date: 20190201 |