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CN109231319A - Leachate/waste water/waste oil atomization return evaporation burning zero-emission treatment device - Google Patents

Leachate/waste water/waste oil atomization return evaporation burning zero-emission treatment device Download PDF

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Publication number
CN109231319A
CN109231319A CN201811039056.2A CN201811039056A CN109231319A CN 109231319 A CN109231319 A CN 109231319A CN 201811039056 A CN201811039056 A CN 201811039056A CN 109231319 A CN109231319 A CN 109231319A
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CN
China
Prior art keywords
leachate
leachate site
treatment device
site
pump
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811039056.2A
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Chinese (zh)
Inventor
徐良洪
王志强
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shanghai Hanjing Power Technology Co ltd
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Shanghai Hanjing Power Technology Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shanghai Hanjing Power Technology Co ltd filed Critical Shanghai Hanjing Power Technology Co ltd
Priority to CN201811039056.2A priority Critical patent/CN109231319A/en
Publication of CN109231319A publication Critical patent/CN109231319A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/02Treatment of water, waste water, or sewage by heating
    • C02F1/04Treatment of water, waste water, or sewage by heating by distillation or evaporation
    • C02F1/048Purification of waste water by evaporation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/02Treatment of water, waste water, or sewage by heating
    • C02F1/04Treatment of water, waste water, or sewage by heating by distillation or evaporation
    • C02F1/10Treatment of water, waste water, or sewage by heating by distillation or evaporation by direct contact with a particulate solid or with a fluid, as a heat transfer medium
    • C02F1/12Spray evaporation
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G7/00Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
    • F23G7/05Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste oils
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/06Contaminated groundwater or leachate
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/18Nature of the water, waste water, sewage or sludge to be treated from the purification of gaseous effluents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/002Construction details of the apparatus
    • C02F2201/007Modular design

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  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Water Supply & Treatment (AREA)
  • Hydrology & Water Resources (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Heat Treatment Of Water, Waste Water Or Sewage (AREA)

Abstract

The invention relates to a leachate treatment device, which comprises a leachate back-spraying system and a reuse water pool sewage back-spraying system; the leachate back-spraying system comprises: the device comprises a liquid inlet system, a liquid return system, a liquid spraying system, an automatic cleaning filter, a buffer water tank, a spray gun, a monitoring system, a control system and a pipeline; the reuse basin sewage back-spraying system includes: bottom valve, booster pump, pressure sensor, flowmeter, electronic ball valve, pneumatic ball valve, spray gun and switch board. The leachate treatment device does not need biochemical treatment for treatment of leachate, wastewater or waste oil, does not need to invest expensive treatment cost, is economic, environment-friendly and efficient, and can fully reuse the heat value in the waste oil.

Description

Evaporation burning zero discharge treatment device is melted down in a kind of Leachate site/waste water/waste oil atomization
Technical field:
The present invention relates to a kind of Leachate site, waste water, waste oil zero discharge treatment devices, are suitable for rubbish more particularly to one kind The leachate treatment device of power generation by waste combustion factory.
Background technique:
Existing garbage burning factory leachate treatment is to collect to carry out biochemical treatment to Leachate site to reach by Leachate site station To the purpose that can be discharged.However landfill leachate is a kind of high concentrated organic wastewater of complicated component, in general there is following spy Point: 1, water quality is complicated, and harmfulness is big;2, CODcr and BOD5 concentration is high;3, ammonia-nitrogen content is high, and with the extension of landfill time And increase, reach as high as 1700mg/L.Nitrogen in percolate is mostly with NH4+Form exists, and accounts for about TNK40%-50%.4, metal Content is higher.5, the microbial nutrition element ratio imbalance in percolate, mainly C, N, P's is out of proportion.General rubbish BOD5:P in percolate is both greater than greatly 300.Currently, mainly passing through chemical drugs for the desulfurization wastewater in thermal power plant Agent is discharged after being neutralized, and the waste oil of industrial and mining enterprises is by there is qualification enterprise to carry out recycling comprehensive utilization.Existing garbage leachate Biochemical treatment needs to be continuously replenished medicament and cultivates biological bacteria to handle, and processing cost is high, and is unable to reach zero-emission.Firepower hair Desulfurization wastewater in power plant, which also needs not deactivate medicament, to be handled, and processing cost is high, is also unable to reach zero-emission purpose.Operating condition enterprise The waste oil disposal of industry, be both needed to the processing cost of operating condition enterprise both expensive, and the calorific value energy in serious waste waste oil.
Summary of the invention:
It is an object of the present invention to solve above-mentioned the deficiencies in the prior art, a kind of device of novel process Leachate site is provided, The device does not need to be not required to the expensive processing cost of investment, warp with biochemical treatment for the processing of Leachate site, waste water or waste oil Ji environmental protection, efficiently, and can sufficiently recycle the calorific value in waste oil.
To achieve the above object, the invention adopts the following technical scheme:
A kind of leachate treatment device, including percolate return-spraying system and reuse pool sewage return spray system;The diafiltration Liquid returns spray system and specifically includes that feed liquor system, return liquid system, spray system, automatic cleaning strainer, buffer tank, spray gun, prison Examining system, control system and pipeline.The reuse pool sewage returns spray system and specifically includes that bottom valve, booster pump, pressure sensing Device, flowmeter, electrical ball valve, pneumatic ball valve, spray gun and control cabinet.
Preferably, the feed liquor system mainly includes immersible pump and self-cleaning filter.Further, Leachate site goes back to spray system Visual Leachate site separator tube liquid level of uniting carries out continuous drawing fluid infusion automatically.
Existing percolation liquid treating system passes through self-cleaning filtering through pumping liquid for submersible pump in the percolate of garbage stacking yard precipitating After device filtering, it is periodically delivered to Leachate site buffering fluid reservoir.Before self-cleaning superheater one threeway of circuit design with it is industrial Water lines connect, and when system is stopped transport for a long time, carry out cleaning maintenance to system using industrial water.
Preferably, the spray system uses two booster pumps, the corresponding boiler of every booster pump, booster pump passes through control Cabinet Frequency Converter Control boost pressure and flow processed.Flowmeter and pressure sensor are disposed in main pipe.Pass through total flow and pressure Variation, it can be determined that whether there is spray gun to block.
Preferably, the spray gun uses compressed air medium atomization nozzle.
Preferably, the control system includes control cabinet, pressure sensor, flow sensor, liquid level sensor, PLC, touching Touch screen, electrical component, frequency converter, PID table, display instrument and automatically controlled program etc..
1, buffer tank Liquid level
Buffer tank includes that there are three liquid levels, and pump, low low liquid level warning are opened in high liquid level termination of pumping, low liquid level.Main control is slow The matching of waste preventer water outlet and water inlet.
2, atomization water pump control
It is atomized water pump, that is, booster pump, 2 branches of water outlet respectively have one.It is atomized water pump and passes through frequency control, frequency converter frequency people Work is set on control cabinet operation panel.
Alarm: atomization pump variable frequency device fault alarm, buffer tank low liquid level warning.When two any triggerings of alarm, phase Corresponding atomization water pump stops working.
3, immersible pump controls
Two immersible pumps are arranged in this system, and separate unit dives under water pump discharge as 4m3/h, lift 22m, every immersible pump control mode All.
Immersible pump control directly initiates stopping, no frequency conversion.After starting corresponding immersible pump, PLC detects buffer tank automatically Water level, when lower than certain liquid level, pump startup of diving under water, after being higher than high liquid level, immersible pump stops.So on circulate.
Alarm: immersible pump is furnished with overcurrent protector, and when overcurrent alarm, immersible pump stops working.
Every immersible pump rear end is furnished with self-cleaning filter, and when pressure difference is greater than certain value, filter carries out turning brush automatically Cleaning.
4, sewage pump controls
In buffer tank bottom, design has blowoff line all the way, and after running for a period of time, water tank bottom has certain sink Product object, needs the carry out blowdown cleaning of timing.Tube outlet design has electrical ball valve, and water pump directly initiates stopping, no frequency conversion.
Alarm: sewage pump is furnished with overcurrent protector, buffer tank low liquid level warning.When two any triggerings of alarm, sewage Pump stops working.
5, long-range start & shutdown through one key
One-key start has been reserved in PLC input and a key stops input.Long-range start stop signal is active electric signal (24VAC)
6, flow indication
The simulation amount signal of system is shown on the operation panel of control cabinet.The start and stop of reuse pool control cabinet and long-range start and stop Signal.
Preferably, 2 furnace maximums of system return discharge rate 5t/h, each point of two-way of every furnace sprays into burner hearth, two furnaces totally 4 tunnel, setting There are 4 spray guns, the public sharing system of two boilers.
The invention has the advantages that:
1, the processing of Leachate site, waste water or waste oil is not needed to be not required to the expensive processing cost of investment with biochemical treatment, It is economic and environment-friendly, efficiently.It will directly pressurize after leachate collecting, be atomized back spirt boiler and be evaporated burning disposal.In Leachate site COD be incinerated completely by high temperature, the water in Leachate site is converted to water vapour, and the heavy metal in water can be attached to flying dust On, micro- useless curing process is carried out after collecting with flying dust again.
2, the present invention is not needed for the desulfurization wastewater in thermal power plant with chemicals treatment, it is no longer necessary to which investment is expensive Processing cost, pressurize after directly collecting desulfurization wastewater, be atomized back in spirt boiler or boiler back end ductwork and be evaporated, water Clean water vapour is become from liquid, the salinity, heavy metal in waste water are attached in the fly ash granule after coal dust firing, with flying Ash is handled together, and is contained salt in itself in flying dust, heavy metal.
3, the waste oil of industrial and mining enterprises is not required to the expensive processing cost of investment, pressurizes after being collected, be atomized back spirt boiler In burn, the calorific value of waste oil is released to the thermal energy for being converted into boiler, the attachment of heavy metal in waste oil in combustion process In flying dust, the calorific value in waste oil can be made full use of.
Detailed description of the invention:
Fig. 1 is percolate return-spraying system figure;
Fig. 2 is that recycle-water returns spray system diagram.
Wherein 1- strainer, 2- submersible sewage pump, 3- self-cleaning filter, 4- Leachate site surge tank, 5- liquidometer, 6- electric ball Valve, 7- dredge pump, 8- booster pump, pneumatic control valve of the 9- with feedback, 10- filter, the big channel atomizing lance of 11-.
Specific embodiment
Embodiment 1:
As depicted in figs. 1 and 2, Leachate site is lifted out through submersible sewage pump (2) pressurization by strainer (1) filtered Leachate site Pond.Leachate site enters Leachate site surge tank (4) after the self-cleaning filter (3) being arranged in pipeline carries out secondary filter.From Filter (3) are cleaned individually to control, can temporally cycle set self-cleaning program, can also be according to self-cleaning filter internal screen Front and back pressure difference carry out individual filter gauze cleaning control.Sewage in cleaning process is backflowed again into Leachate site pond.Leachate site warp Entering in Leachate site surge tank (4) after crossing the secondary filter of self-cleaning filter, Leachate site surge tank top is provided with overflow port, After Leachate site is more than overflow port, Leachate site meeting automatic overflow bleeds back drip liquid pool, fills and is equipped with liquidometer (5) on body, to control Automatic control of the cabinet processed to whole system.Leachate site surge tank lower part is provided with sewage draining exit, drips by the infiltration of self-cleaning filter Still contain tiny particle sediment in liquid, these sediments by the sewage draining exit of surge tank lower part, by electrical ball valve (6) and Periodically surge tank is discharged in sediment in Leachate site surge tank by the opening and closing of dredge pump (7), flows back into Leachate site pond.
The exit of Leachate site surge tank has pipeline connection to booster pump (8), is delayed Leachate site by the pressurization of booster pump The Leachate site rushed in tank is pressed and delivered to boiler room, and boiler wall is open, and big channel atomizing lance (11) is fixed on furnace Thorax high-temperature area.Leachate site after pressurization be directly entered after filter (10) filter three times big channel atomizing lance into Row atomization, atomizing medium are atomized using compressed air.The pneumatic control valve (9) of feedback is provided on compressed air hose road, Big channel atomizing lance import compressed air require is adjusted, when system is without being atomized back spray, can suitably keep one Fixed control valve opening, cools down atomizing lance, avoids big channel atomizing lance pipette tips scaling loss.
By pressurization, compressed air atomization Leachate site, short grained liquid-drop diameter and big channel atomizing lance design Flow is related, differs at 60-120 microns.Under high temperature environment, the droplet after atomization is in extremely short time (being less than 1S) and spray It penetrates apart from interior suction thermal evaporation.After pervaporation, the organic matter in Leachate site is incinerated totally at high temperature, inorganic in Leachate site Salt and heavy metal are attached on flying dust, itself contains a large amount of inorganic salts and heavy metal in flying dust, and flying dust is captured by deduster, into And carry out curing process.Thus the present invention is that water and noxious pollutant have been carried out necessary point using the high temperature in boiler furnace From having achieved the purpose that Leachate site reduction process expense zero-emission, great economic utility and environmentally friendly effectiveness.In addition, the system is not only Only Leachate site is handled in burning power plant, to the same system of desulfurization wastewater after the wet desulphurization in thermal power plant It can be handled.In addition, waste oil directly by big channel atomizing lance (11), is changed to atomized oil gun, can directly be handled useless Oil.
Every spray gun atomized liquid maximum stream flow is 1.25m3/h.Compressed air is provided by air compression station total in field, 0.5~0.6MPa of pressure.Spray gun pipette tips are fabricated using the Ni-based highly corrosion resistant alloy processing of Hastelloy+coating processing, are sprayed Gun barrel road uses corrosion-resistant 316L stainless steel tube.
Sewage pump design discharge 3t/h, 30 meters of lift.Self-cleaning filter uses brush type self-cleaning filter.Work as filter When the pressure difference of inlet and outlet reaches preset value (0.5bar) or time setting value, filter will start self-cleaning: open blowdown valve, electricity Machine drives cleaning brush rotation.Entire cleaning process time-consuming 15-30 seconds, system does not stop when cleaning, the whole service of filter Journey is controlled by a control cabinet being equipped at random.
2 effect experiment of embodiment
Certain garbage incinerating power plant is designed as the fire grate type waste incinerator of day output 400T/D, enters furnace material in burner hearth Enter waste heat boiler after interior carry out high-temp combustion.Flue gas purification system is removed using semidry method+active carbon/lime injection+pocket type The purification process that dirt device is combined.Leachate site returns spray system list furnace and is designed as 2.5T/H, and 2 incinerators design 4 rifles, and single hour Total treating capacity is 5T/H.
The system design parameters are as follows:
Serial number Title Unit Parameter
1 Return spray evaporation capacity T/H 5
2 Atomization air pressure MPA 0.35
3 Leachate site outlet pressure MPA 0.35
4 Leachate site atomized particle size Micron 90
5 Drop evaporation time Second 0.35
6 Evaporate distance Rice 3
Economy is analyzed as follows after returning spray system using Leachate site:
Project original design has the processing of hosted-type Leachate site station, and processing cost per ton is 50 yuan/T.Spray is returned by Leachate site It is as follows that system evaporation technique handles economy:
5T/H × 24H=120T (the daily Leachate site of 2 furnaces returns spray evaporation treatment capacity);
120T × 50 yuan/T=6000 is first (daily direct saving leachate treatment takes);
System power consumption statistics (being atomized using compressed air) is as follows:
System power consumption is about are as follows: 90KW;(main power consumption is air compressor machine);
Waste incineration and generating electricity mark post rate for incorporation into the power network: 0.65 yuan/kw;
90KW × for 24 hours × 0.65 yuan/kwh=1404 is first (electricity charge are lost daily);
Leachate site returns spray net saving handling daily are as follows:
6000 yuan/D-1404 member/D=4596 member/D;
1 year direct saving expense are as follows:
4596 yuan/T × 365 × 90% (year availability)=150.98 ten thousand yuan/year;
Note: only Leachate site time spray is brought this income.Because of the reduction of heating surface inlet temperature, the increasing of single hour garbage treatment quantity Add and the brings economy such as pollutant reduces are also more considerable.

Claims (7)

1. a kind of leachate treatment device, it is characterised in that: return spray system including percolate return-spraying system and reuse pool sewage; The percolate return-spraying system includes: feed liquor system, return liquid system, spray system, automatic cleaning strainer, buffer tank, spray Rifle, monitoring system, control system and pipeline;It includes: bottom valve, booster pump, pressure sensing that the reuse pool sewage, which returns spray system, Device, flowmeter, electrical ball valve, pneumatic ball valve, spray gun and control cabinet.
2. leachate treatment device as described in claim 1, wherein the feed liquor system includes immersible pump and self-cleaning filtering Device.
3. leachate treatment device as claimed in claim 1 or 2, wherein the spray system uses two force (forcing) pumps, every Booster pump corresponds to a boiler, and force (forcing) pump controls boost pressure and flow by control cabinet inverter, is disposed with flow in main pipe Meter and pressure sensor.
4. leachate treatment device as claimed in claim 1 or 2, wherein the control system includes control cabinet, pressure sensing Device, flow sensor, liquid level sensor, PLC automatic control cabinet, touch screen, electrical component, frequency converter, PID table, display instrument With automatically controlled program.
5. leachate treatment device as described in claim 1, wherein described device includes strainer, submersible sewage pump, self-cleaning filtering Device, Leachate site surge tank, liquidometer, electrical ball valve, dredge pump, booster pump, the pneumatic control valve with feedback, filter and big logical Road atomizing lance.
6. leachate treatment device as claimed in claim 5, wherein by the Leachate site after the strainer filtering through submersible sewage pump Pressurization is lifted out Leachate site pond;Leachate site enters Leachate site after the self-cleaning filter being arranged in pipeline carries out secondary filter Surge tank;Sewage in cleaning process is backflowed again into Leachate site pond;Leachate site is after the secondary filter of self-cleaning filter Into in Leachate site surge tank, Leachate site surge tank top is provided with overflow port, after Leachate site is more than overflow port, Leachate site meeting Automatic overflow bleeds back drip liquid pool, fills and is equipped with liquidometer on body, the automatic control so as to control cabinet to whole system;Leachate site is slow It rushes tank lower part and is provided with sewage draining exit, by still containing tiny particle sediment in the Leachate site of self-cleaning filter, these Sediment passes through the sewage draining exit of surge tank lower part, is periodically buffered Leachate site by the opening and closing of electrical ball valve and dredge pump Surge tank is discharged in sediment in tank, flows back into Leachate site pond.
7. such as leachate treatment device described in claim 5 or 6, wherein there is pipeline in the exit of the Leachate site surge tank It is communicated to booster pump, the Leachate site in Leachate site surge tank is pressed and delivered to by boiler room, Boiler Furnace by the pressurization of booster pump Wall is open, and big channel atomizing lance is fixed on burner hearth high-temperature area;Leachate site after pressurization carries out three by filter It is directly entered big channel atomizing lance after secondary filtering to be atomized, the pneumatic adjusting of feedback is provided on compressed air hose road Big channel atomizing lance import compressed air require is adjusted in valve.
CN201811039056.2A 2018-09-06 2018-09-06 Leachate/waste water/waste oil atomization return evaporation burning zero-emission treatment device Pending CN109231319A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811039056.2A CN109231319A (en) 2018-09-06 2018-09-06 Leachate/waste water/waste oil atomization return evaporation burning zero-emission treatment device

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Application Number Priority Date Filing Date Title
CN201811039056.2A CN109231319A (en) 2018-09-06 2018-09-06 Leachate/waste water/waste oil atomization return evaporation burning zero-emission treatment device

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111960598A (en) * 2020-08-31 2020-11-20 西安热工研究院有限公司 Landfill leachate back-spraying system
CN112892951A (en) * 2021-03-24 2021-06-04 大唐环境产业集团股份有限公司 Anti-blocking device and method for desulfurization wastewater spray gun system

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8926792B1 (en) * 2012-10-31 2015-01-06 Kelly K. Houston System and method for disposing of leachate and wastewater
CN206502710U (en) * 2016-08-13 2017-09-19 广东雅迪环保设备有限公司 Percolate concentrates liquid advanced treatment device
CN207006183U (en) * 2017-07-27 2018-02-13 杭州绿能环保发电有限公司 A kind of leachate recycle processing system
CN108328827A (en) * 2018-01-16 2018-07-27 张波 Leachate pyrolytic gasification treatment technology

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8926792B1 (en) * 2012-10-31 2015-01-06 Kelly K. Houston System and method for disposing of leachate and wastewater
CN206502710U (en) * 2016-08-13 2017-09-19 广东雅迪环保设备有限公司 Percolate concentrates liquid advanced treatment device
CN207006183U (en) * 2017-07-27 2018-02-13 杭州绿能环保发电有限公司 A kind of leachate recycle processing system
CN108328827A (en) * 2018-01-16 2018-07-27 张波 Leachate pyrolytic gasification treatment technology

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111960598A (en) * 2020-08-31 2020-11-20 西安热工研究院有限公司 Landfill leachate back-spraying system
CN112892951A (en) * 2021-03-24 2021-06-04 大唐环境产业集团股份有限公司 Anti-blocking device and method for desulfurization wastewater spray gun system

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Application publication date: 20190118