CN109221190A - A kind of compounded pesticides effectively preventing cotten aphid - Google Patents
A kind of compounded pesticides effectively preventing cotten aphid Download PDFInfo
- Publication number
- CN109221190A CN109221190A CN201811181517.XA CN201811181517A CN109221190A CN 109221190 A CN109221190 A CN 109221190A CN 201811181517 A CN201811181517 A CN 201811181517A CN 109221190 A CN109221190 A CN 109221190A
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- Prior art keywords
- cotten aphid
- imidacloprid
- compounded pesticides
- double
- aphid
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 241001124076 Aphididae Species 0.000 title claims abstract description 31
- 239000000575 pesticide Substances 0.000 title claims abstract description 28
- 239000005906 Imidacloprid Substances 0.000 claims abstract description 25
- YWTYJOPNNQFBPC-UHFFFAOYSA-N imidacloprid Chemical compound [O-][N+](=O)\N=C1/NCCN1CC1=CC=C(Cl)N=C1 YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 claims abstract description 25
- 229940056881 imidacloprid Drugs 0.000 claims abstract description 25
- 208000002474 Tinea Diseases 0.000 claims abstract description 20
- 241000893966 Trichophyton verrucosum Species 0.000 claims abstract description 20
- 241001600408 Aphis gossypii Species 0.000 claims abstract description 14
- 230000002265 prevention Effects 0.000 claims abstract description 9
- 150000002148 esters Chemical class 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 6
- 239000000470 constituent Substances 0.000 claims description 5
- 201000010099 disease Diseases 0.000 claims description 4
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 2
- 230000002195 synergetic effect Effects 0.000 abstract description 6
- 230000012865 response to insecticide Effects 0.000 abstract description 5
- 230000008901 benefit Effects 0.000 abstract description 4
- -1 esters compound Chemical class 0.000 abstract description 3
- 230000001018 virulence Effects 0.000 abstract description 3
- 238000004920 integrated pest control Methods 0.000 abstract 1
- 239000003814 drug Substances 0.000 description 9
- 231100000820 toxicity test Toxicity 0.000 description 9
- 238000000034 method Methods 0.000 description 6
- 229920000742 Cotton Polymers 0.000 description 5
- 241000219146 Gossypium Species 0.000 description 5
- 239000002917 insecticide Substances 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- 239000003153 chemical reaction reagent Substances 0.000 description 4
- MTXSIJUGVMTTMU-JTQLQIEISA-N (S)-anabasine Chemical compound N1CCCC[C@H]1C1=CC=CN=C1 MTXSIJUGVMTTMU-JTQLQIEISA-N 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 3
- 241000607479 Yersinia pestis Species 0.000 description 3
- 229930014345 anabasine Natural products 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 231100000419 toxicity Toxicity 0.000 description 3
- 230000001988 toxicity Effects 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- WCXDHFDTOYPNIE-RIYZIHGNSA-N (E)-acetamiprid Chemical compound N#C/N=C(\C)N(C)CC1=CC=C(Cl)N=C1 WCXDHFDTOYPNIE-RIYZIHGNSA-N 0.000 description 2
- PGOOBECODWQEAB-UHFFFAOYSA-N (E)-clothianidin Chemical compound [O-][N+](=O)\N=C(/NC)NCC1=CN=C(Cl)S1 PGOOBECODWQEAB-UHFFFAOYSA-N 0.000 description 2
- 239000005875 Acetamiprid Substances 0.000 description 2
- 241001600407 Aphis <genus> Species 0.000 description 2
- 239000005888 Clothianidin Substances 0.000 description 2
- 206010059866 Drug resistance Diseases 0.000 description 2
- 240000007594 Oryza sativa Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 2
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 2
- 241001414989 Thysanoptera Species 0.000 description 2
- 229920004890 Triton X-100 Polymers 0.000 description 2
- 239000013504 Triton X-100 Substances 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000007689 inspection Methods 0.000 description 2
- 230000010534 mechanism of action Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 235000009566 rice Nutrition 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- HOKKPVIRMVDYPB-UVTDQMKNSA-N (Z)-thiacloprid Chemical compound C1=NC(Cl)=CC=C1CN1C(=N/C#N)/SCC1 HOKKPVIRMVDYPB-UVTDQMKNSA-N 0.000 description 1
- 229920001817 Agar Polymers 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 1
- 241001414720 Cicadellidae Species 0.000 description 1
- 241001498622 Cixius wagneri Species 0.000 description 1
- 240000008067 Cucumis sativus Species 0.000 description 1
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 1
- 241000258937 Hemiptera Species 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 206010034133 Pathogen resistance Diseases 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000005940 Thiacloprid Substances 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- LRZWFURXIMFONG-HRSIRGMGSA-N afidopyropen Chemical compound C([C@@]1(C)[C@H]2[C@]([C@H]3[C@@H](O)C=4C(=O)OC(=CC=4O[C@]3(C)[C@@H](O)C2)C=2C=NC=CC=2)(C)CC[C@@H]1OC(=O)C1CC1)OC(=O)C1CC1 LRZWFURXIMFONG-HRSIRGMGSA-N 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 238000004113 cell culture Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000002728 pyrethroid Substances 0.000 description 1
- 230000000384 rearing effect Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 229930192474 thiophene Natural products 0.000 description 1
- 230000009261 transgenic effect Effects 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a kind of compounded pesticides for effectively preventing cotten aphid.For the technical problem for solving Insecticide Resistance of Cotton Aphids, the present invention is on the basis of a large amount of indoor virulences screen, it was found that double third ring worm esters compound the generation that can effectively delay Insecticide Resistance of Cotton Aphids with imidacloprid, and there is synergistic function to the prevention and treatment of cotten aphid, it provides for the integrated pest management of cotten aphid and new effectively prevents means.Present invention reduces Pesticide use amounts, to reduce costs and reduce the pollution to environment, are conducive to the resistance management of cotten aphid, popularization and application have huge economic benefit and social benefit.
Description
Technical field
The invention belongs to technical field of pesticide, and in particular to a kind of compounded pesticides for effectively preventing cotten aphid.
Background technique
Cotten aphid (cotton aphids, Aphis gossypii Glover) is a kind of universal important pests,
It can the feeding in 700 various plants including cotton, cucumber etc..Cotten aphid mainly passes through direct feeding plant juice and propagation
Plant virus causes damages, and causes huge economic loss to agricultural production.Cotten aphid is fast with reproduction speed, population quantity is big,
The features such as serious extent, for a long time, chemical prevention are always the main means of China's cotton aphid control.Due to chemical pesticide
Long-term a large amount of uses, cotten aphid produce height to a variety of insecticides such as organic phosphorus, carbamate, pyrethroid, anabasine
Horizontal resistance.
Insecticide, which is used for a long time, so that cotten aphid is developed drug resistance, and the simple usage amount for increasing pesticide more pollutes the environment.But
Recently as a large amount of frequent uses of anabasine insecticide, cotten aphid also gets worse the resistance of such medicament.Cui Li etc.
(2016) result of study shows that Aksu Prefecture cotten aphid has reached 26.3 times to the resistance of imidacloprid, has reached medium resistance water
It is flat.And the Aphis gossypiipopulation in Koo etc. (2014) report some areas of South Korea is to Acetamiprid, clothianidin, imidacloprid, thiacloprid and thiophene worm
The neonicotinoid insecticides such as piperazine produce the result of study of high horizontal resistance, and wherein cotten aphid is to imidacloprid, Acetamiprid and clothianidin
Resistant multiple respectively reached 1500,2600 and 14000 times.
Double third ring worm esters (Afidopyropen) be botanical pesticide, structure novel and have completely new mechanism of action,
It can be used for preventing and treating rice, fruit tree, vegetables, mini pest such as scale insect, thrips, leafhopper, powder on imtertilled crop and ornamental plant
Lice and wood louse etc., either foliar treatment, seed treatment or soil treatment have good result, and toxicity is very low.
Imidacloprid (Imidacloprid), be it is a kind of efficiently, the strong anabasine insecticide of wide spectrum, absorbability, have low
Poison, low-residual, lasting period are long, the features such as to people, animal and natural enemies security, and have and tag, the multiple actions such as stomach toxicity and interior suction.Mainly
For preventing and treating agriculturally important sucking pest, such as aphid, plant hopper, thrips.
Summary of the invention
For the technical problem for solving Insecticide Resistance of Cotton Aphids, the present invention is on the basis of a large amount of indoor virulences screen, discovery double third
Ring worm ester compounds the generation that can effectively delay Insecticide Resistance of Cotton Aphids with imidacloprid, and has synergistic make to the prevention and treatment of cotten aphid
With being provided for cotten aphid evil comprehensive treatment and new effectively prevent means.
The present invention adopts the following technical scheme that.
A kind of compounded pesticides effectively preventing cotten aphid, active constituent include double third ring worm esters and imidacloprid, the two matter
Amount is than being 1:(5-10).
Further, the mass ratio of double third ring worm esters and imidacloprid is 1:5 or 1:10 in the compounded pesticides.
Further, the active constituent of the compounded pesticides is made of double third ring worm esters with imidacloprid.
The research of the invention finds that double third ring worm esters compound within the scope of aforementioned proportion with imidacloprid can effectively delay cotten aphid
The generation of drug resistance also has synergistic function to the prevention and treatment of cotten aphid, achieves unexpected technical effect.Wherein, double
In optimum proportioning 1:5, co-toxicity coefficient reaches 159.15 for third ring worm ester and imidacloprid, has apparent synergistic effect, improves
Control efficiency.
Further, the available carrier of pesticide field or auxiliary material are also contained in the compounded pesticides.
Further, the compounded pesticides can be made into the available various dosage forms of pesticide field.
Aforementioned compounded pesticides can be prepared by conventional method in that art.
The present invention also provides aforementioned compounded pesticides in prevention and control of aphides disease or in the pesticide for preparing prevention and control of aphides disease
In application.
On the basis of common knowledge of the art, above-mentioned each optimum condition can be combined with each other each preferably to get the present invention
Example.
Cotten aphid of the present invention is Aphis gossypii Glover, is a kind of insect of Aphidiadae Aphis, is commonly called as aphid.
The present invention is especially the study found that double third ring worm esters are compounded with imidacloprid, its mechanism of action in terms of prevention and control of aphides
It is unique that cross resistance is especially not present, delay the generation and development of Insecticide Resistance of Cotton Aphids, reduced Pesticide use amount, to drop
Low cost and reduce the pollution to environment, is conducive to the resistance management of cotten aphid, popularization and application have huge economic benefit
And social benefit.
Specific embodiment
The following examples are used to illustrate the present invention, but are not intended to limit the scope of the present invention..It is not specified in embodiment specific
Technology or conditions person, described technology or conditions according to the literature in the art, or carried out according to product description.It is used
Production firm person is not specified in reagent or instrument, is the conventional products that can be commercially available by regular distributor.
Experimental example 1
This experiment using double third ring worm esters, imidacloprid as reagent agent, using blade medicine embrane method carry out toxicity test, single dose with
Each ratio mixture carries out blade medicine embrane method toxicity test, calculates LC50, co-toxicity coefficient (CTC) and optimum proportioning.
1. research object
The cotton Aphid in laboratory rearing mostly generation.Cotton Aphid picks up from cotton in Xinjiang field, and non-turn of indoor culture
Gene cotton seedling raising mostly generation.
2. method
Reagent agent double third ring worm esters, imidacloprid carry out indoor toxicity test, including double third rings using blade medicine embrane method
Worm ester, Imidacloprid single dose toxicity test;The toxicity test of double third ring worm esters and each ratio mixture of imidacloprid.To toxicity test result
It is calculated, calculates LC50, co-toxicity coefficient (CTC), obtain optimum proportioning.
The double third ring worm esters of reagent agent, imidacloprid are raw medicine, with acetone solution, 4 DEG C of preservations.The medicament of toxicity test is dense
Degree is set as 6~7, and sets three simple repetitions;Each ratio mixture is mixing before dilution.
Blade used is non-transgenic cotton (plantation in constant incubator).
The preparation and dilution of 2.1 raw medicine mother liquors
Double third ring worm esters are that 10:1,5:1,1:1,1:5,1:10 are compounded according to mass ratio with imidacloprid, and raw medicine is molten
Solution is deposited in flask for medicinal preparations after acetone, volumetric flask constant volume, and sealed membrane sealing, 4 DEG C of refrigerators save.Before toxicity test, with containing
The distilled water of 0.05% (v/v) Triton X-100 is diluted to each concentration, spare.
The 2.2 raw selections and use for surveying blade
The leaf dish that the non-Bt cotton leaf of fresh cleaning is broken into diameter 2cm with punch, soaks in the medical fluid diluted
It takes out, dries after stain 15s.Then, the leaf dish back side is placed in the 12 hole cell culture that bottom is covered with 2% agar gel of 2mL upward
In plate.It is control with the distilled water containing 0.05% (v/v) Triton X-100.
The selection of 2.3 toxicity test examination aphids
The cotton Aphid of indoor raising is selected, the consistent aptery adult aphid of picking health is tested, each prepared
Leaf dish place 30 aphids, sealed with rice paper, be placed in growth cabinet raising (23 ± 1 DEG C of temperature, relative humidity 50%
~75%, illumination 16L:8D).
2.4 result inspections and death standard judgement
Handle inspection result after 48h, mesopodium is motionless, and with small writing brush touch it is completely motionless be denoted as death, with control
The death rate is effectively measurement less than 10%, and is corrected with the control death rate.6~7 concentration, Mei Genong is arranged in each medicament
3 repetitions are spent, data processing analyzes software using POLO Plus, calculates LC50, calculate the LC of single dose and each proportion mixture50And
95% confidence limit, virulence regression equation etc..And according to calculated result, mixture co-toxicity coefficient (CTC) is found out using Sun Yunpei's Method, altogether
Malicious coefficient (CTC value) >=120 shows as synergistic effect;Co-toxicity coefficient (CTC value)≤80 is antagonism;80 < co-toxicity coefficient
(CTC value) < 120 shows as summation action, compares synergy situation according to CTC value, obtains the best of double third ring worm esters and imidacloprid
Proportion.
Test result is shown in Table 1.
1 pair of the third ring worm ester of table compounds The Toxicity Determination result with imidacloprid
It is malicious altogether when double third ring worm esters are compounded with imidacloprid than being respectively 1:5 and 1:10 it can be seen from 1 test result of table
Coefficient is greater than 120, shows as synergistic function.
Although above the present invention is described in detail with a general description of the specific embodiments,
On the basis of the present invention, it can be made some modifications or improvements, this will be apparent to those skilled in the art.Cause
This, these modifications or improvements, fall within the scope of the claimed invention without departing from theon the basis of the spirit of the present invention.
Claims (7)
1. a kind of compounded pesticides for effectively preventing cotten aphid, active constituent includes double third ring worm esters and imidacloprid, the two quality
Than for 1:(5-10).
2. compounded pesticides according to claim 1, which is characterized in that the matter of the double third ring worm esters and imidacloprid of active constituent
Amount is than being 1:5 or 1:10.
3. compounded pesticides according to claim 1 or 2, which is characterized in that the active constituent by double third ring worm esters with
Imidacloprid composition.
4. compounded pesticides according to claim 1-3, which is characterized in that also contain the available load of pesticide field
Body or auxiliary material.
5. compounded pesticides according to claim 1-4, which is characterized in that the cotten aphid is Aphis
gossypii Glover。
6. any one of the claim 1-5 compounded pesticides are in prevention and control of aphides disease or in the pesticide for preparing prevention and control of aphides disease
In application.
7. application according to claim 6, which is characterized in that the cotten aphid is Aphis gossypii Glover.
Priority Applications (1)
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CN201811181517.XA CN109221190A (en) | 2018-10-11 | 2018-10-11 | A kind of compounded pesticides effectively preventing cotten aphid |
Applications Claiming Priority (1)
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---|---|---|---|
CN201811181517.XA CN109221190A (en) | 2018-10-11 | 2018-10-11 | A kind of compounded pesticides effectively preventing cotten aphid |
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Publication Number | Publication Date |
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Family
ID=65052641
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CN201811181517.XA Pending CN109221190A (en) | 2018-10-11 | 2018-10-11 | A kind of compounded pesticides effectively preventing cotten aphid |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110200004A (en) * | 2019-07-04 | 2019-09-06 | 山东省农业科学院植物保护研究所 | A kind of compound drug composition for preventing and treating Bemisia tabaci, melon aphid |
CN111374144A (en) * | 2018-12-27 | 2020-07-07 | 燕化永乐(乐亭)生物科技有限公司 | Insecticidal composition |
CN115281201A (en) * | 2022-07-15 | 2022-11-04 | 新疆天禾嘉信农业科技有限公司 | Insecticide compounded by diclocycline dispersant and application thereof |
Citations (2)
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CN101626687A (en) * | 2007-03-08 | 2010-01-13 | 明治制果株式会社 | Pest control composition |
CN105432653A (en) * | 2015-12-18 | 2016-03-30 | 广东中迅农科股份有限公司 | Insecticidal composition |
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2018
- 2018-10-11 CN CN201811181517.XA patent/CN109221190A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101626687A (en) * | 2007-03-08 | 2010-01-13 | 明治制果株式会社 | Pest control composition |
CN105432653A (en) * | 2015-12-18 | 2016-03-30 | 广东中迅农科股份有限公司 | Insecticidal composition |
Non-Patent Citations (1)
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111374144A (en) * | 2018-12-27 | 2020-07-07 | 燕化永乐(乐亭)生物科技有限公司 | Insecticidal composition |
CN110200004A (en) * | 2019-07-04 | 2019-09-06 | 山东省农业科学院植物保护研究所 | A kind of compound drug composition for preventing and treating Bemisia tabaci, melon aphid |
CN110200004B (en) * | 2019-07-04 | 2021-07-06 | 山东省农业科学院植物保护研究所 | Compound medicament composition for preventing and treating bemisia tabaci and aphis cucumeriae |
CN115281201A (en) * | 2022-07-15 | 2022-11-04 | 新疆天禾嘉信农业科技有限公司 | Insecticide compounded by diclocycline dispersant and application thereof |
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