Nothing Special   »   [go: up one dir, main page]

CN109181894B - 一种超浓缩洗洁精及制备方法 - Google Patents

一种超浓缩洗洁精及制备方法 Download PDF

Info

Publication number
CN109181894B
CN109181894B CN201811157361.1A CN201811157361A CN109181894B CN 109181894 B CN109181894 B CN 109181894B CN 201811157361 A CN201811157361 A CN 201811157361A CN 109181894 B CN109181894 B CN 109181894B
Authority
CN
China
Prior art keywords
parts
super
detergent
liquid detergent
low
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201811157361.1A
Other languages
English (en)
Other versions
CN109181894A (zh
Inventor
孙红霞
郭剑
徐晓辉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Beijing Reward Home Care Chemical Co ltd
Original Assignee
Beijing Reward Home Care Chemical Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Beijing Reward Home Care Chemical Co ltd filed Critical Beijing Reward Home Care Chemical Co ltd
Priority to CN201811157361.1A priority Critical patent/CN109181894B/zh
Publication of CN109181894A publication Critical patent/CN109181894A/zh
Application granted granted Critical
Publication of CN109181894B publication Critical patent/CN109181894B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2041—Dihydric alcohols
    • C11D3/2044—Dihydric alcohols linear
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2065—Polyhydric alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2068—Ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2086—Hydroxy carboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/33—Amino carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/34—Organic compounds containing sulfur
    • C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/008—Polymeric surface-active agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)

Abstract

本发明涉及一种超浓缩洗洁精，其组分及质量分为：表面活性剂15‑98份、磺酸异丙胺盐20‑50份、改性油脂乙氧基化物10‑40份、改性油脂乙氧基化物磺酸盐10‑30份、乙氧基化异构十三烷基醇10‑30份、有机溶剂1‑30份、香精0.1‑2份和防腐剂0.01‑1份。本发明的超浓缩洗洁精包含非离子和/或阴离子表面活性剂，活性物含量(百分比)极高，具有强去污力，粘度低，具有极佳的高低温流动性。而且产品温和、润湿性好，成本较低，适用于酒店、餐馆等餐具洗涤。

Description

一种超浓缩洗洁精及制备方法
技术领域
本发明涉及一种商用洗涤剂用品，具体涉及一种超浓缩洗洁精。
背景技术
随着社会的发展，人们的生活节奏越来越快，洗洁精作为人们的日常生活用品，尤其是酒店、餐馆等需要节省时间、成本，追求更高的效率，人们的需求早已不局限于普通洗洁精，而更希望能延长购买时间，减少资源浪费。况且近年来消费者的节能环保意识也慢慢增强,对洗洁精的要求也逐渐提高。因此,开发一种既可以节省包装成本、运输成本,又能减少塑料瓶装污染问题的超浓缩洗洁精也成了一种趋势。
现在市面上大部分浓缩洗洁精产品的活性物含量都是普通洗洁精的两倍左右,但粘度都较大,水溶性不太理想。消费者尤其是酒店等用起来较麻烦。而本发明超浓缩洗洁精粘度较低，水溶性好，容易控制洗洁精的使用量,且能实现真正的环保。
发明内容
本发明的目的是提供一种商用超浓缩洗洁精，中性无刺激，粘度很低，具有水溶性好、去污力强和生物环保功能。
本发明的超浓缩洗洁精，其组分及其质量份数为：
Figure BDA0001819214380000011
优选地，本发明的商用超浓缩洗洁精，其组分及其质量份数为：
Figure BDA0001819214380000012
Figure BDA0001819214380000021
优选地，所述表面活性剂为十二烷基苯磺酸异丙胺盐、改性油脂乙氧基化物、改性油脂乙氧基化物磺酸盐、乙氧基化异构烷基醇、脂肪醇聚氧乙烯醚中的一种或几种。
优选地，所述有机溶剂为丙二醇、甘油、乙醇和二丙二醇甲醚中的一种或几种。
优选地，所述香精为食品级香精。
优选地，所述防腐剂为甲基异噻唑琳酮和甲基氯异噻唑琳酮的混合物。
优选地，所述螯合剂为谷氨酸二乙酸四钠、柠檬酸钠、甲基甘氨酸二乙酸中的一种或几种。
优选地，通过反复试验论证，尽管原理不是很清楚，但是意外地发现，同时采用了十二烷基苯磺酸异丙胺盐、改性油脂乙氧基化物、改性油脂乙氧基化物磺酸盐和乙氧基化异构十三烷基醇作为表面活性剂，且含量在特定范围时，产生了意想不到的协同作用，去油污效果明显优于其它成分、配比的组合。
本发明是一种商用超浓缩洗洁精，配方温和,粘度很低，具有强去污力和极佳的高低温流动性,成本低,浓缩倍数是普通洗洁精的三倍以上而且使用方便。使用时,直接将洗洁精按量倒入要求比例的水中，稍加搅拌，瞬间混合均匀，再洗涤餐具。另外,本产品能延长购买时间，减少资源浪费，节约了成本,使用方便，迎合了商家及消费者的需求。
具体实施方式
为了更好地说明本发明，下面结合本发明实施例，对本发明实施例中的技术方案进行清楚、完整地描述。
实施例1
一种商用超浓缩洗洁精，其组分及其质量份数为：
Figure BDA0001819214380000031
所述的防腐剂剂为甲基异噻唑琳酮和甲基氯异噻唑琳酮的混合物。
上述商用超浓缩洗洁精的制备方法如下：
1.加入计量好的去离子水4.8份，丙二醇10份，开始搅拌；
2.加入乙氧基化异构十三烷基醇15份继续搅拌至物料完全溶解；
3.加入磺酸异丙胺盐30份、改性油脂乙氧基化物20份、改性油脂乙氧基化物磺酸盐20份，继续搅拌至物料透明；
4.加入食品级香精0.1份和防腐剂0.1份，继续搅拌使之溶解，调节pH≈7。
5.用300目滤网过滤后包装。
实施例2
按照与实施例1同样的制备方法，制备具有下述主要活性组分及质量份数的商用超浓缩洗洁精：
Figure BDA0001819214380000032
Figure BDA0001819214380000041
所述的防腐剂剂为甲基异噻唑琳酮和甲基氯异噻唑琳酮的混合物。
实施例3
按照与实施例1同样的制备方法，制备具有下述主要活性组分及质量份数的商用超浓缩洗洁精：
Figure BDA0001819214380000042
所述的防腐剂剂为甲基异噻唑琳酮。
实施例4
按照与实施例1同样的制备方法，制备具有下述主要活性组分及质量份数的商用超浓缩洗洁精：
Figure BDA0001819214380000043
所述的防腐剂剂为甲基异噻唑琳酮和甲基氯异噻唑琳酮的混合物。
实施例5
按照与实施例1同样的制备方法，制备具有下述主要活性组分及质量份数的商用超浓缩洗洁精：
Figure BDA0001819214380000044
Figure BDA0001819214380000051
所述的防腐剂剂为甲基异噻唑琳酮和甲基氯异噻唑琳酮的混合物。
去污效果：
按GB9985规定的方法测定浓缩洗洁精去油率。实施例1和实施例3超浓缩洗洁精的用量为标准餐具洗涤剂用量的1/5，A、B为市售二倍浓缩洗洁精，用量为标准餐具洗涤剂用量的1/2，对比去污效果，结果如表1：
表1去污指标对比
产品 标准餐具洗涤剂 实施例1 实施例3 A B
去油率(％) 51.2 57.8 54.4 51.4 52.3
表2实施例1-5的产品的去污指标
产品 实施例1 实施例2 实施例3 实施例4 实施例5
去油率(％) 57.8 58.1 54.4 57.7 53.9
通过表1可以看出，本发明实施例1和3的产品去油率明显高于现有市售产品，本专利的产品用量小但产生更好的洗涤效果。
通过表2可以看出，同时采用了十二烷基苯磺酸异丙胺盐、改性油脂乙氧基化物、改性油脂乙氧基化物磺酸盐和乙氧基化异构十三烷基醇作为表面活性剂的实施例1、2和4的产品，去油率明显高于采用其他成分作为表面活性剂的实施例3和5的产品，具有更优异的洗涤效果。
虽然上文描述了商用超浓缩洗洁精及其具体实施方式，但是，在本发明的上述教导下，本领域技术人员可以在上述实施例的基础上进行各种改进和变形，而这些改进或者变形落在本发明的保护范围内。本领域技术人员应该明白，上面的具体描述只是为了解释本发明的目的，并非用于限制本发明。本发明的保护范围由权利要求及其等同物限定。

Claims (1)

1.一种超浓缩洗洁精，其主要活性组分及其质量份数为：
Figure FDA0002444961980000011
所述的防腐剂剂为甲基异噻唑琳酮和甲基氯异噻唑琳酮的混合物。
CN201811157361.1A 2018-09-30 2018-09-30 一种超浓缩洗洁精及制备方法 Active CN109181894B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811157361.1A CN109181894B (zh) 2018-09-30 2018-09-30 一种超浓缩洗洁精及制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811157361.1A CN109181894B (zh) 2018-09-30 2018-09-30 一种超浓缩洗洁精及制备方法

Publications (2)

Publication Number Publication Date
CN109181894A CN109181894A (zh) 2019-01-11
CN109181894B true CN109181894B (zh) 2020-07-03

Family

ID=64946690

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201811157361.1A Active CN109181894B (zh) 2018-09-30 2018-09-30 一种超浓缩洗洁精及制备方法

Country Status (1)

Country Link
CN (1) CN109181894B (zh)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111733024A (zh) * 2020-05-20 2020-10-02 中万恩科技有限公司 不含阴离子表面活性剂的商用餐具洗涤剂及其制备方法
CN112251298A (zh) * 2020-10-22 2021-01-22 特丝丽化工有限公司 一种超浓缩洗衣液及其稀释液制备方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1865422A (zh) * 2006-03-30 2006-11-22 中国日用化学工业研究院 一种手洗餐具洗涤剂及制备方法
CN101979489A (zh) * 2010-11-03 2011-02-23 广州南顺清洁用品有限公司 无水无防腐剂超浓缩手洗洗洁精组合物
CN107937171A (zh) * 2017-11-29 2018-04-20 黑龙江省科学院高技术研究院 一种低泡绿色cip杀菌浓缩型清洗剂

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1865422A (zh) * 2006-03-30 2006-11-22 中国日用化学工业研究院 一种手洗餐具洗涤剂及制备方法
CN101979489A (zh) * 2010-11-03 2011-02-23 广州南顺清洁用品有限公司 无水无防腐剂超浓缩手洗洗洁精组合物
CN107937171A (zh) * 2017-11-29 2018-04-20 黑龙江省科学院高技术研究院 一种低泡绿色cip杀菌浓缩型清洗剂

Also Published As

Publication number Publication date
CN109181894A (zh) 2019-01-11

Similar Documents

Publication Publication Date Title
CN106318686B (zh) 一种高效环保浓缩硬表面清洗剂
CN105695159B (zh) 一种无溶剂高浓缩餐具洗涤剂及其制备方法
WO2008106290A1 (en) Cleaning compositions and methods using the same
CN103343065B (zh) 一种非水基高活性物衣物洗涤剂、制备方法及所用的包装袋
CN107937171B (zh) 一种低泡绿色cip杀菌浓缩型清洗剂
CA2158541C (en) Cleaning compositions with short chain nonionic surfactants
CN103834487A (zh) 一种重油垢环保型水基清洗剂
CN103242971A (zh) 一种不添加任何酸碱的绿色高效稠油垢近中性水基清洗剂
CN109181894B (zh) 一种超浓缩洗洁精及制备方法
CN104059790A (zh) 一种绿色环保的护手浓缩洗洁精
CN103194328B (zh) 一种无助溶剂的浓缩洗涤剂及其制备方法
CN108048245A (zh) 天然浓缩型泡沫餐具洗涤剂
CN104327962A (zh) 以皂角提取物为主要活性成分的餐具洗涤剂及其制备方法
US6465411B2 (en) Pine oil cleaning composition
CN102787034A (zh) 一种化油清洗剂
CN103320238A (zh) 一种用于稠油垢去除的微弱酸性水基清洗剂及其制备方法
CN103695197A (zh) 一种高浓缩洗衣液
CN104232345A (zh) 一种高浓缩洗衣液
CN111286424A (zh) 一种超浓缩洗洁精组合物
CN104830561A (zh) 超浓缩低泡高效洗衣液
CN103849504A (zh) 一种玻璃制品专用清洗剂
JPS61157589A (ja) 液体洗剤組成物
CN107937159B (zh) 一种低粘度超浓缩果蔬餐具洗涤剂组合物及其制备方法
CN112322399B (zh) 一种清洁剂及其制备方法和应用
JP3314206B2 (ja) 高濃度液体せっけん組成物

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant