CN109090107A - Plant protein source film forming insecticides adjuvant and its preparation method and application - Google Patents
Plant protein source film forming insecticides adjuvant and its preparation method and application Download PDFInfo
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- CN109090107A CN109090107A CN201811247695.8A CN201811247695A CN109090107A CN 109090107 A CN109090107 A CN 109090107A CN 201811247695 A CN201811247695 A CN 201811247695A CN 109090107 A CN109090107 A CN 109090107A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
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- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a kind of plant protein source film forming insecticides adjuvants, including A phase component and B phase component, the A phase component is made of by weight percentage following component: 8-10% vegetable protein, 3-5% methylcellulose, 7-9% glycerol, 2-3%DCM2,1-3% Negel, 2-3% Nekal BX, 5-7% dispersing agent NNO, 1-3% suspending agent D06,2-3% neopelex；Surplus is deionized water；The B phase component is made of by weight percentage following component: 8-12% calcium chloride, 5-8% magnesium chloride；Surplus is deionized water.Component A albumen and pesticide spray in advance is laid on crop surface, and crop surface is sprayed on after B phase and plays the role of ordering halogen, makes albumen precipitation gel in crop surface.Auxiliary agent of the present invention can form safety and environmental protection biomembrane in crop surface, to increase the pesticide lasting period, increase drug effect, reduce pesticide to endophytic infiltration, reduce pesticide residue.
Description
Technical field
The present invention relates to a kind of plant protein source film forming insecticides adjuvant and its preparation method and application, the insecticides adjuvant is suitable
For insecticide, fungicide, herbicide and plant growth regulator pesticide, belong to insecticides adjuvant technical field.
Background technique
According to the applicant understood, conventional pesticide spray auxiliary agent composition be faced with whether Environmental security, whether ecological safety
Query, many inherent shortcomings having in itself in addition, such as: though (1) application of auxiliary agent can reduce pesticide usage amount, reduces and use
Medicine cost, but domestic pesticidal preparations price itself is lower, even if cost can be reduced using auxiliary agent, it is also difficult to peasant be allowed to spend portion
Additional money goes to buy auxiliary agent.(2) domestic per hectare arable land spouting liquid is excessively high, weakens by auxiliary agent bring economic benefit.It is some
The application amount of auxiliary agent is, the usually auxiliary agent 0.125%-1% that accounts for spouting liquid, due to there is such ratio directly proportional with spouting liquid
In the presence of so higher spouting liquid improves the application cost of per hectare auxiliary agent naturally.Meanwhile high spouting liquid is instead sometimes
The synergistic effect of auxiliary agent can be reduced.(3) domestic that less, auxiliary agent single variety is studied to auxiliary agent.Late nineteen eighties, the nineties
Just, solvent, such as YZ-901, AA-921 are mostly done with ethyl alcohol in the nonionic surfactants auxiliary agent of weedicide that China promotes,
In certain humidity range, there is synergistic effect to pesticide, but synergy is unobvious under drought condition.
Present invention applicant gradually confirmed the advantage of film forming insecticides adjuvant in practical studies, then to film forming agriculture
Medicine auxiliary agent has conducted extensive research.Present invention applicant thinks that vegetable protein may have in investigation and helps as film forming pesticide
The prospect of agent component, but also needing further to study can just know whether successfully develop plant protein source film forming pesticide
Auxiliary agent.
The characteristics of capable of playing a role according to protein, its functional character can be divided into 3 major class: (1) water and property depend on
In protein with the interaction between water, absorption and reservation, wettability, dilatancy, bonding, dispersibility and dissolution including water
Property etc.；(2) structural property is the related property of interaction between protein molecule, such as precipitating, gelatification, tissue
Change the formation etc. with dough；(3) surface nature of protein is related to protein generated work between the different two-phase of polarity
With the property of mainly have the blistering of protein, emulsify etc..In addition, somebody is according to protein in food aesthetic quality side
Its functional characteristic is marked off the 4th kind of property --- organoleptic properties, is related to protein and is eating by some effects possessed by face
Generated turbidity, color, flavor combinations, chewiness, smooth sense etc. in product.These functional characteristics of protein are not mutual
Independent, entirely different property, there is also connecting each other between them, such as the gelatification of protein both relates to albumen
Interaction (forming space three-dimensional reticular structure) between matter molecule, further relates to protein molecule with the phase between hydrone
Interaction (reservation of water)；And viscosity, solubility all refer to the effect between protein-protein.
Summary of the invention
The goal of the invention to be realized of the invention is: overcoming the problems, such as of the existing technology, provides a kind of plant protein source
Film forming insecticides adjuvant and its preparation method and application, the auxiliary agent can effectively improve drug effect and the duration of pesticide.
Present invention applicant has carried out in depth repeatedly practising research, and has obtained following technical solution, it can be achieved that above-mentioned
Goal of the invention:
A kind of plant protein source film forming insecticides adjuvant, including A phase component and B phase component, the A phase component are pressed by following component
Weight percent is constituted: 8-10% vegetable protein, 3-5% methylcellulose, 7-9% glycerol, 2-3% DCM2,1-3% alkylnaphthalene sulphur
Sour sodium, 2-3% Nekal BX, 5-7% dispersing agent NNO, 1-3% suspending agent D06,2-3% neopelex；Surplus be go from
Sub- water；
The B phase component is made of by weight percentage following component: 8-12% calcium chloride, 5-8% magnesium chloride；Surplus is deionization
Water.
Auxiliary agent of the invention more applies second of property of protein.Component A albumen sprays in advance with pesticide to be laid on
Crop surface is sprayed on crop surface after B phase and plays the role of ordering halogen, makes albumen precipitation gel in crop surface.Auxiliary agent of the present invention can
Safety and environmental protection biomembrane is formed in crop surface, to increase the pesticide lasting period, increase drug effect, reduces pesticide to endophytic infiltration
Thoroughly, pesticide residue is reduced.
Preferably, A phase component: 8% vegetable protein, 3% methylcellulose, 7% glycerol, 2% DCM2,1% alkyl naphthalene sulfonic acid
Sodium, 2% Nekal BX, 5% dispersing agent NNO, 1% suspending agent D06,2% neopelex, surplus is deionized water；B phase group
Point: 8% calcium chloride and 5% magnesium chloride, surplus are deionized water.
Preferably, A phase component: 10% vegetable protein, 5% methylcellulose, 9% glycerol, 3% DCM2,3% alkyl naphthalene sulfonic acid
Sodium, 3% Nekal BX, 7% dispersing agent NNO, 3% suspending agent D06,3% neopelex, surplus is deionized water；B phase group
Point: 12% calcium chloride and 8% magnesium chloride, surplus are deionized water.
Preferably, A phase component: 9% vegetable protein, 4% methylcellulose, 8% glycerol, 2.5% DCM2,2% alkyl naphthalene sulfonic acid
Sodium, 2.5% Nekal BX, 6% dispersing agent NNO, 2% suspending agent D06,2.5% neopelex, surplus is deionized water；B
Phase component: 10% calcium chloride and 7% magnesium chloride, surplus are deionized water.
Preferably, the vegetable protein includes big beans vegetable protein or wheat vegetable protein.
Present invention also provide that a kind of preparation method of afore-mentioned plants protein sources film forming insecticides adjuvant, comprising the following steps:
The first step prepares finished product A: take the vegetable protein of A phase component, be uniformly mixed after deionized water is added, vegetable protein with go
The weight ratio of ionized water is 1:3.0-3.5, is heated to 90-95 DEG C, then continues to the methylcellulose that A phase component is added, mixing
After uniformly, it is cooled to room temperature, adds the glycerol of A phase component, DCM2, Negel, Nekal BX, dispersing agent NNO, helps
Suspension D06 and neopelex after mixing, continuously add the deionized water of surplus, persistently stirring 0.5-1 hours, i.e.,
Obtain finished product A；
Second step prepares finished product B: taking the calcium chloride and magnesium chloride of B phase component, deionized water is added, be uniformly mixed to get finished product
B。
Further perfect technical solution is as follows for preparation method of the present invention: in the first step, vegetable protein and deionized water
Weight ratio is 1:3.0, is heated to 90 DEG C, is persistently stirred 0.5 hour.
Preferably, in the first step, the weight ratio of vegetable protein and deionized water is 1:3.5, is heated to 95 DEG C, lasting to stir
1 hour.
Preferably, in the first step, the weight ratio of vegetable protein and deionized water is 1:3.2, is heated to 92 DEG C, lasting to stir
0.8 hour.
The present invention also provides a kind of applications of plant protein source film forming insecticides adjuvant, comprising the following steps:
(1) after mixing finished product A and pesticide, crop is sprayed, finished product A dosage is 1.5Kg/ha；
(2) finished product B is individually sprayed on crop, and finished product B dosage is 1.5Kg/ha.
Inventor has found in depth practical studies, using the A phase component and B phase component of above-mentioned restriction as film forming group
Point, and above-mentioned preparation method is used, plant protein source film forming insecticides adjuvant can successfully be made, gained insecticides adjuvant can be in plant
Surface forms cuticula, and is attached to pesticide on the film, to increase the pesticide lasting period, increase drug effect, is conducive to reduce pesticide use
Amount is to reduce cost, reduce pollution by pesticides；Simultaneously because forming transparent cuticula in plant surface, pesticide can be reduced into plant
Infiltration, reduce pesticide residue, conducive to ensure agricultural product quality safety.
Specific embodiment
Below by embodiment, the present invention will be further described, but the present invention is not limited only to these examples.
Embodiment 1 prepares plant protein source film forming insecticides adjuvant
Insecticides adjuvant includes A phase component and B phase component, and A phase component is made of by weight percentage following component: 8-10% plant
Albumen, 3-5% methylcellulose, 7-9% glycerol, 2-3% DCM2,1-3% Negel, 2-3% Nekal BX, 5-7% expand
Powder NNO, 1-3% suspending agent D06,2-3% neopelex；Surplus is deionized water.B phase component is pressed by following component
Weight percent is constituted: 8-12% calcium chloride and 5-8% magnesium chloride；Surplus is deionized water.
In the present embodiment, vegetable protein uses soybean protein, is made by oneself by applicant.
Methylcellulose, glycerol are purchased from Shanghai Sheng Gong chemical reagent Co., Ltd；DCM2(CAS NO:51325-95-2) purchase
From Jilin OLED Optical and Electronic Materials Co., Ltd.；Negel is purchased from Zhejiang Hongda Chemicals Co., Ltd.；It draws
Opening powder BX(chemical component is diisobutyl sodium naphthalene sulfonate), dispersing agent NNO (chemical component is sodium methylene bis-naphthalene sulfonate), 12
Sodium alkyl benzene sulfonate is purchased from Historic Area of Zhongshan in Nanjing City chemical industry Co., Ltd；Suspending agent D06 is purchased from Shenzhen Lang Tai company, model
wgwin D06。
Specific preparation process is as follows:
The first step prepares finished product A: take the vegetable protein of A phase component, be uniformly mixed after deionized water is added, vegetable protein with go
The weight ratio of ionized water is 1:3.0-3.5, is heated to 90-95 DEG C；Then, the methylcellulose of A phase component is continuously added, is mixed
It closes, is cooled to room temperature, adds glycerol, DCM2, Negel, Nekal BX, dispersing agent NNO, the suspending agent of A phase component
D06, neopelex, after mixing, are added balance deionized water, stir 0.5-1 hours persistently to get finished product A；
Second step prepares finished product B: taking the calcium chloride and magnesium chloride of B phase component, deionized water dissolving is added, preparation obtains 8-12%
The mixed solution of calcium chloride, 5-8% magnesium chloride, gets product B.
Concrete application case:
The composition of each case is as shown in table 1, and the preparation parameter of each case is as shown in table 2.
Each case composition of table 1
The preparation parameter of each case of table 2
| Case | The first step | Second step |
| 1 | The weight ratio of vegetable protein and deionized water is 1:3.0, is heated to 90 DEG C；It connects , methylcellulose is continuously added, mixes, is cooled to room temperature, addition glycerol, DCM2, Negel, Nekal BX, dispersing agent NNO, suspending agent D06, ten Dialkyl benzene sulfonic acids sodium, after mixing, deionized water is added in surplus, lasting to stir 0.5 hour to get finished product A | Appropriate calcium chloride and magnesium chloride are weighed, deionized water dissolving is added, prepares 8% chlorination The mixed solution of calcium and 5% magnesium chloride is to get finished product B |
| 2 | The weight ratio of vegetable protein and deionized water is 1:3.5, is heated to 95 DEG C；It connects , methylcellulose is continuously added, mixes, is cooled to room temperature, addition glycerol, DCM2, Negel, Nekal BX, dispersing agent NNO, suspending agent D06, ten Dialkyl benzene sulfonic acids sodium, after mixing, deionized water is added in surplus, persistently stirs 1 Hour is to get finished product A | Appropriate calcium chloride and magnesium chloride are weighed, deionized water dissolving is added, prepares 12% chlorine Change the mixed solution of calcium and 8% magnesium chloride to get finished product B |
| 3 | The weight ratio of vegetable protein and deionized water is 1:3.2, is heated to 92 DEG C；It connects , methylcellulose is continuously added, mixes, is cooled to room temperature, addition glycerol, DCM2, Negel, Nekal BX, dispersing agent NNO, suspending agent D06, ten Dialkyl benzene sulfonic acids sodium, after mixing, deionized water is added in surplus, lasting to stir 0.8 hour to get finished product A | Appropriate calcium chloride and magnesium chloride are weighed, deionized water dissolving is added, prepares 10% chlorine Change the mixed solution of calcium and 6.5% magnesium chloride to get finished product B |
The using effect of 2 embodiment of embodiment, 1 case 2 is tested
It takes finished product A made from 100 grams of above-described embodiments to be added in common commercially available 20% chlorantraniliprole pesticide preparation, converts
It 15 kilograms of water, is sprayed on one mu of grape, then is watered 10 kilograms with 100 grams of finished product B, be sprayed on one mu of grape；Simultaneously with general
Lead to commercially available 20% chlorantraniliprole pesticide preparation and be watered 15 kilograms, is sprayed on one mu of grape.The two compares, as a result
It is shown in Table 3.
3 pesticide residue Comparative result (mg/kg) of table
From the data in table 3, it can be seen that the present embodiment insecticides adjuvant can not only make pesticide stagnate the longer time on pericarp, hold pesticide
Effective concentration is held in continuation of insurance, is increased the pesticide lasting period and is simultaneously increased drug effect, moreover it is possible to lock pesticide and prevent to permeate to pulp, make pulp from
Pollution by pesticides.
Claims (10)
1. a kind of plant protein source film forming insecticides adjuvant, characterized in that including A phase component and B phase component, the A phase component
It is made of by weight percentage following component: 8-10% vegetable protein, 3-5% methylcellulose, 7-9% glycerol, 2-3% DCM2,
1-3% Negel, 2-3% Nekal BX, 5-7% dispersing agent NNO, 1-3% suspending agent D06,2-3% dodecyl benzene sulfonic acid
Sodium；Surplus is deionized water；
The B phase component is made of by weight percentage following component: 8-12% calcium chloride, 5-8% magnesium chloride；Surplus is deionization
Water.
2. a kind of plant protein source film forming insecticides adjuvant according to claim 1, characterized in that A phase component: 8% plant
Albumen, 3% methylcellulose, 7% glycerol, 2% DCM2,1% Negel, 2% Nekal BX, 5% dispersing agent NNO, 1% helps
Suspension D06,2% neopelex, surplus are deionized water；B phase component: 8% calcium chloride and 5% magnesium chloride, surplus are to go
Ionized water.
3. a kind of plant protein source film forming insecticides adjuvant according to claim 1, characterized in that A phase component: 10% plant
Albumen, 5% methylcellulose, 9% glycerol, 3% DCM2,3% Negel, 3% Nekal BX, 7% dispersing agent NNO, 3% helps
Suspension D06,3% neopelex, surplus are deionized water；B phase component: 12% calcium chloride and 8% magnesium chloride, surplus are
Deionized water.
4. a kind of plant protein source film forming insecticides adjuvant according to claim 1, characterized in that A phase component: 9% plant
Albumen, 4% methylcellulose, 8% glycerol, 2.5% DCM2,2% Negel, 2.5% Nekal BX, 6% dispersing agent NNO,
2% suspending agent D06,2.5% neopelex, surplus is deionized water；B phase component: 10% calcium chloride and 7% magnesium chloride,
Surplus is deionized water.
5. according to claim 1 to a kind of any one of 4 plant protein source film forming insecticides adjuvants, characterized in that the plant
Object albumen includes big beans vegetable protein or wheat vegetable protein.
6. a kind of any one of claim 1 to 5 preparation method of plant protein source film forming insecticides adjuvant, characterized in that
The following steps are included:
The first step prepares finished product A: take the vegetable protein of A phase component, be uniformly mixed after deionized water is added, vegetable protein with go
The weight ratio of ionized water is 1:3.0-3.5, is heated to 90-95 DEG C, then continues to the methylcellulose that A phase component is added, mixing
After uniformly, it is cooled to room temperature, adds the glycerol of A phase component, DCM2, Negel, Nekal BX, dispersing agent NNO, helps
Suspension D06 and neopelex after mixing, continuously add the deionized water of surplus, persistently stirring 0.5-1 hours, i.e.,
Obtain finished product A；
Second step prepares finished product B: taking the calcium chloride and magnesium chloride of B phase component, deionized water is added, be uniformly mixed to get finished product
B。
7. a kind of preparation method of plant protein source film forming insecticides adjuvant according to claim 6, characterized in that the first step
In, the weight ratio of vegetable protein and deionized water is 1:3.0, is heated to 90 DEG C, is persistently stirred 0.5 hour.
8. a kind of preparation method of plant protein source film forming insecticides adjuvant according to claim 6, characterized in that the first step
In, the weight ratio of vegetable protein and deionized water is 1:3.5, is heated to 95 DEG C, is persistently stirred 1 hour.
9. a kind of preparation method of plant protein source film forming insecticides adjuvant according to claim 6, characterized in that the first step
In, the weight ratio of vegetable protein and deionized water is 1:3.2, is heated to 92 DEG C, is persistently stirred 0.8 hour.
10. a kind of application of plant protein source film forming insecticides adjuvant of any one of claim 6 to 9, characterized in that including
Following steps:
(1) after mixing finished product A and pesticide, crop is sprayed, finished product A dosage is 1.5Kg/ha；
(2) finished product B is individually sprayed on crop, and finished product B dosage is 1.5Kg/ha.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111802385A (en) * | 2020-02-29 | 2020-10-23 | 陕西师范大学 | Protein product capable of fixing target and removing according to need |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111802385A (en) * | 2020-02-29 | 2020-10-23 | 陕西师范大学 | Protein product capable of fixing target and removing according to need |
| CN111802385B (en) * | 2020-02-29 | 2021-08-31 | 西安曼特思生物科技有限公司 | Protein product capable of fixing target and removing according to need |
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