CN108417780A - A kind of preparation and its application of anode material of lithium-ion battery stainless (steel) wire load carbon covered stannum rice structure - Google Patents
A kind of preparation and its application of anode material of lithium-ion battery stainless (steel) wire load carbon covered stannum rice structure Download PDFInfo
- Publication number
- CN108417780A CN108417780A CN201810128510.5A CN201810128510A CN108417780A CN 108417780 A CN108417780 A CN 108417780A CN 201810128510 A CN201810128510 A CN 201810128510A CN 108417780 A CN108417780 A CN 108417780A
- Authority
- CN
- China
- Prior art keywords
- steel
- stainless
- wire
- solution
- tin oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
- H01M4/1391—Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/054—Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0471—Processes of manufacture in general involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/049—Manufacturing of an active layer by chemical means
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/362—Composites
- H01M4/366—Composites as layered products
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/483—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides for non-aqueous cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/624—Electric conductive fillers
- H01M4/625—Carbon or graphite
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Manufacturing & Machinery (AREA)
- Nanotechnology (AREA)
- Materials Engineering (AREA)
- Composite Materials (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Inorganic Chemistry (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
A kind of preparation and its application of anode material of lithium-ion battery stainless (steel) wire load carbon covered stannum rice structure, sodium hydroxide is dissolved in deionized water and obtains solution A；Stannic chloride is added into solution A and obtains solution B；Ammonium fluoride is added into solution B and obtains solution or emulsion C；Solution C is transferred to hydrothermal reaction kettle, the clean stainless (steel) wire of pre-wash is placed in solution C and carries out hydro-thermal reaction, is cooled down after reaction, dry stainless (steel) wire carrying tin oxide nanostructure under certain temperature；Stainless (steel) wire carrying tin oxide nanostructure is placed in organic solution, stainless (steel) wire load Coated with Organic Matter tin oxide nano structure is reacted to obtain；Stainless (steel) wire load Coated with Organic Matter tin oxide nano structure is placed in tube furnace and reacts to obtain stainless (steel) wire load carbon coating tin oxide nano structure；The present invention improves discharge and recharge, high rate performance and the cycle performance of sodium-ion battery.
Description
Technical field
The present invention relates to secondary power battery material technical field, more particularly to a kind of anode material of lithium-ion battery is stainless
Steel mesh loads the preparation and its application of carbon covered stannum rice structure.
Background technology
Oil, natural gas and coal are not the inexhaustible energy, and the gas of combustion of fossil fuel discharge
Serious Global Environmental Problems can be brought.In addition, national security can be threatened by relying on non-renewable resources import for a long time.Therefore generation
New, clean, green fungible energy source and energy conversion and storage system are all being found by Jie Ge states.Wherein chemical-electrical
Source is one of most important research direction, lithium ion battery be exactly grow up along with metal secondary batteries it is a kind of novel
Electrochmical power source.But content is few during elemental lithium is expensive and the earth's crust, with increasing for lithium ion battery applications, the demand of lithium
Also it greatly increases.Therefore it needs to develop other power alkali metal-ion batteries.
Sodium element is located in the periodic table of elements immediately below elemental lithium, has similar physicochemical properties, and sodium with lithium
It is the 6th abundant element of reserves in the earth's crust, it is widely distributed, therefore develop the sodium-ion battery technology tool of extensive stored energy application
There is important strategic importance.The raw material of sodium-ion battery is extensive, cheap, has become the heat of novel battery energy storage technology at present
Point.Sodium ion radius (0.98) is more than lithium ion radius (0.69) so that overcomes needed for sodium ion diffusion in charge and discharge process
Potential barrier bigger, to make diffusion rate substantially reduce, therefore need to find suitable battery cathode storage sodium material.Currently,
The sodium ion negative material of research mainly has carbon material, conversion class material etc..It is oxide material mostly to convert class material, is not had
Its corresponding metallic conductivity is high, while volume occurs for the insertion with abjection of sodium ion in single carbon-coated nano structural material
Expansion ratio oxide is small.Therefore sodium-ion battery first charge-discharge amount, cyclical stability and conductivity are improved.
Stainless (steel) wire loads carbon covered stannum rice structure as a kind of novel sodium-ion battery negative electrode active material, prepares
Method and correlative study work yet there are no report.
Invention content
In order to overcome the above-mentioned deficiencies of the prior art, the purpose of the present invention is to provide a kind of anode material of lithium-ion batteries
Stainless (steel) wire loads the preparation and its application of carbon covered stannum rice structure, invention enhances the electric conductivity of sodium-ion battery,
Modulation slurry is eliminated simultaneously and applies blade technolgy, avoids the performance that battery is influenced using binder.
To achieve the goals above, the technical solution adopted by the present invention is：
A kind of preparation of anode material of lithium-ion battery stainless (steel) wire load carbon covered stannum rice structure, including following step
Suddenly：
Step 1：
0.625g~1.808g sodium hydroxides will be proportionally dissolved in 40mL deionized waters and obtain solution A；
Step 2：
Under magnetic stirring, stannic chloride is added into above-mentioned solution A and obtains solution B, the mass ratio of sodium hydroxide and stannic chloride
It is 2:1~4:1；
Step 3：
Under magnetic stirring, ammonium fluoride is added into above-mentioned solution B and obtains solution or emulsion C, sodium hydroxide and ammonium fluoride
Mass ratio be 12:1~36:1；
Step 4：
Above-mentioned solution C is transferred to hydrothermal reaction kettle, the clean stainless (steel) wire of pre-wash is placed in solution C, is carried out
Hydro-thermal reaction cools down after reaction, and stainless (steel) wire is cleaned with deionized water and ethyl alcohol, dry under certain temperature, obtains stainless steel
Net carrying tin oxide nanostructure；
Step 5：
Above-mentioned stainless (steel) wire carrying tin oxide nanostructure is placed in organic solution, reacts a timing at a certain temperature
Between, obtain stainless (steel) wire load Coated with Organic Matter tin oxide nano structure；
Step 6：
Above-mentioned stainless (steel) wire load Coated with Organic Matter tin oxide nano structure is placed in tube furnace, is roasted at a certain temperature
Certain time is burnt, calcination atmosphere is argon gas, obtains stainless (steel) wire load carbon coating tin oxide nano structure；
Step 7：
Above-mentioned carbon stainless steel net load carbon coating tin oxide nano structure is placed in tube furnace, in reducing gas hydrogen
It is made annealing treatment under atmosphere and predetermined temperature and just obtains final product stainless (steel) wire load carbon covered stannum rice structure after a certain period of time.
In the step 4, hydrothermal temperature be 160~200 DEG C, the reaction time be 0.5~for 24 hours.
In the step 5, organic carbon source is glucose, dopamine and beta-cyclodextrin etc., and reaction temperature is 160 DEG C~200
DEG C, 4 hours.
In the step 6, annealing temperature is 600 DEG C~750 DEG C, and annealing time is 1~4h, the flow velocity of argon gas is 10~
100sccm。
In the step 7, annealing temperature is 600~750 DEG C, and annealing time is 1~4h, the flow velocity of hydrogen is 300~
400sccm。
A kind of application of anode material of lithium-ion battery stainless (steel) wire load carbon covered stannum rice structure, stainless (steel) wire is born
It carries carbon covered stannum rice structural material and is washed into a diameter of 8mm disks as active material electrode, sodium is used as to electrode, and electrolyte is
(volume ratio of EC and DMC are 1 for the ethylene carbonate (EC) of 1M sodium hexafluoro phosphates and the solution of carbonic acid dioctyl phthalate (DMC)：1), gather
Propylene microcellular film is battery diaphragm, is assembled into button cell；After assembled button cell is stood 12 hours,
LANDCT2100A carries out electrochemical property test.Test voltage is 0.01V~2.6V, current density 50mA/g.
Beneficial effects of the present invention：
Invention enhances the electric conductivities of sodium-ion battery, while eliminating modulation slurry and applying blade technolgy, avoid making
The performance of battery is influenced with binder.By controlling the proportioning of reaction dissolvent, sintering temperature and soaking time improve the present invention
The size of substance, pattern and structure.The specific surface area of stainless (steel) wire load carbon coating tin oxide nano structure prepared by the present invention
Greatly, very large space stores sodium ion in charge and discharge process, carbon-coated rock-steady structure to be not easy in charge and discharge process
It caves in.Surfactant NH is used in the present invention4F can obtain the carbon-coated nano structure of size uniformity on stainless (steel) wire
Array stannic oxide.
Description of the drawings
Fig. 1 stainless (steel) wires load carbon covered stannum rice structure preparation process schematic diagram.
Specific implementation mode
Invention is further described in detail below in conjunction with the accompanying drawings.
Embodiment 1
A kind of preparation method of stainless (steel) wire load carbon covered stannum rice structure, includes the following steps：
1) sodium hydroxide that quality is 0.625g, under magnetic stirring, is dissolved in 40ml deionized waters and obtains solution A；
2) 0.47g stannic chlorides, under magnetic stirring, are added into above-mentioned solution A and obtain solution B；
3) 0.05g ammonium fluorides, under magnetic stirring, are added into B solution and obtain solution or emulsion C；
4), solution C is transferred in stainless steel cauldron, while the clean stainless (steel) wire of pre-wash is placed in solution
In, hydro-thermal reaction is carried out, stainless (steel) wire is cleaned with deionized water and ethyl alcohol, after being reacted 24 hours at a temperature of 200 DEG C, just obtained
Stainless (steel) wire carrying tin oxide nanostructure；
5), 4) the stainless (steel) wire tin supported nanostructure obtained in is placed in 3.6g glucose 40mL deionized waters, 180
The glucose cladding tin oxide nano structure of stainless (steel) wire load is obtained after being impregnated 4 hours in DEG C；
6), 3) the stainless (steel) wire load organic carbon source cladding tin oxide nano structure obtained in is placed in tube furnace,
Just final product stainless (steel) wire load carbon coating oxidation sijna is obtained after being made annealing treatment 2 hours at a temperature of 700 DEG C in argon gas atmosphere
Rice structure；
7), 4) the stainless (steel) wire load carbon coating tin oxide nano structure obtained in is placed in tube furnace, in hydrogen gas
650 DEG C of temperatures just obtain final product stainless (steel) wire load carbon covered stannum rice structure in atmosphere after 1 hour；
8), the assembling of button cell, using stainless (steel) wire load carbon covered stannum rice structure be washed into a diameter of 8mm disks as
Active material electrode, sodium are used as to electrode, and electrolyte is the ethylene carbonate (EC) and carbonic acid dioctyl phthalate of 1M sodium hexafluoro phosphates
(DMC) (volume ratio of EC and DMC are 1 to solution：1), microporous polypropylene membrane is battery diaphragm, is assembled into button cell；
9) after, assembled button cell stands 24 hours, electrochemical property test is carried out in LANDCT2100A.Test
Voltage is 0.01V~2.6V, current density 50mA/g.
Embodiment 2
A kind of preparation method of stainless (steel) wire load carbon covered stannum rice structure, includes the following steps：
1) sodium hydroxide that quality is 0.9375g, under magnetic stirring, is dissolved in 40ml deionized waters and obtains solution A；
2) 0.47g stannic chlorides, under magnetic stirring, are added into above-mentioned solution A and obtain solution B；
3) 0.05g ammonium fluorides, under magnetic stirring, are added into B solution and obtain solution or emulsion C；
4), solution C is transferred in stainless steel cauldron, while the clean stainless (steel) wire of pre-wash is placed in solution
In, hydro-thermal reaction is carried out, stainless (steel) wire is cleaned with deionized water and ethyl alcohol, after being reacted 24 hours at a temperature of 200 DEG C, just obtained
Stainless (steel) wire carrying tin oxide nanostructure；
5), 4) the stainless (steel) wire tin supported nanostructure obtained in is placed in 3.6g glucose 40mL deionized waters, 180
The glucose cladding tin oxide nano structure of stainless (steel) wire load is obtained after being impregnated 4 hours in DEG C；
6), 3) the stainless (steel) wire load organic carbon source cladding tin oxide nano structure obtained in is placed in tube furnace,
Just final product stainless (steel) wire load carbon coating oxidation sijna is obtained after being made annealing treatment 2 hours at a temperature of 700 DEG C in argon gas atmosphere
Rice structure；
7), 4) the stainless (steel) wire load carbon coating tin oxide nano structure obtained in is placed in tube furnace, in hydrogen gas
650 DEG C of temperatures just obtain final product stainless (steel) wire load carbon covered stannum rice structure in atmosphere after 1 hour；
8), the assembling of button cell, using stainless (steel) wire load carbon covered stannum rice structure be washed into a diameter of 8mm disks as
Active material electrode, sodium are used as to electrode, and electrolyte is the ethylene carbonate (EC) and carbonic acid dioctyl phthalate of 1M sodium hexafluoro phosphates
(DMC) (volume ratio of EC and DMC are 1 to solution：1), microporous polypropylene membrane is battery diaphragm, is assembled into button cell；
9) after, assembled button cell stands 24 hours, electrochemical property test is carried out in LANDCT2100A.Test
Voltage is 0.01V~2.6V, current density 50mA/g.
Embodiment 3
A kind of preparation method of stainless (steel) wire load carbon covered stannum rice structure, includes the following steps：
1) sodium hydroxide that quality is 1.25g, under magnetic stirring, is dissolved in 40ml deionized waters and obtains solution A；
2) 0.47g stannic chlorides, under magnetic stirring, are added into above-mentioned solution A and obtain solution B；
3) 0.05g ammonium fluorides, under magnetic stirring, are added into B solution and obtain solution or emulsion C；
4), solution C is transferred in stainless steel cauldron, while the clean stainless (steel) wire of pre-wash is placed in solution
In, hydro-thermal reaction is carried out, stainless (steel) wire is cleaned with deionized water and ethyl alcohol, after being reacted 24 hours at a temperature of 200 DEG C, just obtained
Stainless (steel) wire carrying tin oxide nanostructure；
5), 4) the stainless (steel) wire tin supported nanostructure obtained in is placed in 3.6g glucose 40mL deionized waters, 180
The glucose cladding tin oxide nano structure of stainless (steel) wire load is obtained after being impregnated 4 hours in DEG C；
6), 3) the stainless (steel) wire load organic carbon source cladding tin oxide nano structure obtained in is placed in tube furnace,
Just final product stainless (steel) wire load carbon coating oxidation sijna is obtained after being made annealing treatment 2 hours at a temperature of 700 DEG C in argon gas atmosphere
Rice structure；
7), 4) the stainless (steel) wire load carbon coating tin oxide nano structure obtained in is placed in tube furnace, in hydrogen gas
650 DEG C of temperatures just obtain final product stainless (steel) wire load carbon covered stannum rice structure in atmosphere after 1 hour；
8), the assembling of button cell, using stainless (steel) wire load carbon covered stannum rice structure be washed into a diameter of 8mm disks as
Active material electrode, sodium are used as to electrode, and electrolyte is the ethylene carbonate (EC) and carbonic acid dioctyl phthalate of 1M sodium hexafluoro phosphates
(DMC) (volume ratio of EC and DMC are 1 to solution：1), microporous polypropylene membrane is battery diaphragm, is assembled into button cell；
9) after, assembled button cell stands 24 hours, electrochemical property test is carried out in LANDCT2100A.Test
Voltage is 0.01V~2.6V, current density 50mA/g.
Embodiment 4
A kind of preparation method of stainless (steel) wire load carbon covered stannum rice structure, includes the following steps：
1) sodium hydroxide that quality is 1.808g is dissolved in 40ml deionized waters and obtains solution A；
2) 0.47g stannic chlorides, under magnetic stirring, are added into above-mentioned solution A and obtain solution B；
3) 0.05g ammonium fluorides, under magnetic stirring, are added into B solution and obtain solution or emulsion C；
4), solution C is transferred in stainless steel cauldron, while the clean stainless (steel) wire of pre-wash is placed in solution
In, hydro-thermal reaction is carried out, stainless (steel) wire is cleaned with deionized water and ethyl alcohol, after being reacted 24 hours at a temperature of 200 DEG C, just obtained
Stainless (steel) wire carrying tin oxide nanostructure；
5), 4) the stainless (steel) wire tin supported nanostructure obtained in is placed in 3.6g glucose 40mL deionized waters, 180
The glucose cladding tin oxide nano structure of stainless (steel) wire load is obtained after being impregnated 4 hours in DEG C；
6), 3) the stainless (steel) wire load organic carbon source cladding tin oxide nano structure obtained in is placed in tube furnace,
Just final product stainless (steel) wire load carbon coating oxidation sijna is obtained after being made annealing treatment 2 hours at a temperature of 700 DEG C in argon gas atmosphere
Rice structure；
7), 4) the stainless (steel) wire load carbon coating tin oxide nano structure obtained in is placed in tube furnace, in hydrogen gas
650 DEG C of temperatures just obtain final product stainless (steel) wire load carbon covered stannum rice structure in atmosphere after 1 hour；
8), the assembling of button cell, using stainless (steel) wire load carbon covered stannum rice structure be washed into a diameter of 8mm disks as
Active material electrode, sodium are used as to electrode, and electrolyte is the ethylene carbonate (EC) and carbonic acid dioctyl phthalate of 1M sodium hexafluoro phosphates
(DMC) (volume ratio of EC and DMC are 1 to solution：1), microporous polypropylene membrane is battery diaphragm, is assembled into button cell；
9) after, assembled button cell stands 24 hours, electrochemical property test is carried out in LANDCT2100A.Test
Voltage is 0.01V~2.6V, current density 50mA/g.
As shown in Figure 1：
1), the sodium hydroxide of certain mass, which is dissolved in 40mL deionized waters, obtains solution A；
2) stannic chloride, under magnetic stirring, is added into above-mentioned solution A and obtains solution B；
3) ammonium fluoride, under magnetic stirring, is added into above-mentioned solution B and obtains solution or emulsion C；
4) above-mentioned solution C, is transferred to hydrothermal reaction kettle, the clean stainless (steel) wire of pre-wash is placed in solution C, into
Row hydro-thermal reaction.It cools down after reaction, stainless (steel) wire is cleaned with deionized water and ethyl alcohol, dry under certain temperature, is obtained stainless
Steel mesh carrying tin oxide nanostructure；
5), above-mentioned stainless (steel) wire carrying tin oxide nanostructure is placed in organic solution, reacts one at a certain temperature
It fixes time, obtains stainless (steel) wire load Coated with Organic Matter tin oxide nano structure；
6), above-mentioned stainless (steel) wire load Coated with Organic Matter tin oxide nano structure is placed in tube furnace, in certain temperature
Lower roasting certain time, calcination atmosphere are argon gas, obtain stainless (steel) wire load carbon coating tin oxide nano structure；
7), above-mentioned carbon stainless steel net load carbon coating tin oxide nano structure is placed in tube furnace, in reducing gas hydrogen
It is made annealing treatment under the atmosphere and predetermined temperature of gas and just obtains final product stainless (steel) wire load carbon covered stannum rice after a certain period of time
Structure.
Claims (6)
1. a kind of preparation of anode material of lithium-ion battery stainless (steel) wire load carbon covered stannum rice structure, which is characterized in that packet
Include following steps：
Step 1：
0.625g~1.808g sodium hydroxides will be proportionally dissolved in 40mL deionized waters and obtain solution A；
Step 2：
Under magnetic stirring, stannic chloride is added into above-mentioned solution A and obtains solution B, the mass ratio of sodium hydroxide and stannic chloride is 2:1
~4:1；
Step 3：
Under magnetic stirring, ammonium fluoride is added into above-mentioned solution B and obtains solution or emulsion C, the matter of sodium hydroxide and ammonium fluoride
Amount is than being 12:1~36:1；
Step 4：
Above-mentioned solution C is transferred to hydrothermal reaction kettle, the clean stainless (steel) wire of pre-wash is placed in solution C, carries out hydro-thermal
Reaction, cools down after reaction, and stainless (steel) wire is cleaned with deionized water and ethyl alcohol, dry under certain temperature, and it is negative to obtain stainless (steel) wire
Carry tin oxide nano structure；
Step 5：
Above-mentioned stainless (steel) wire carrying tin oxide nanostructure is placed in organic solution, reacts certain time at a certain temperature,
It obtains stainless (steel) wire and loads Coated with Organic Matter tin oxide nano structure；
Step 6：
Above-mentioned stainless (steel) wire load Coated with Organic Matter tin oxide nano structure is placed in tube furnace, roasts one at a certain temperature
It fixes time, calcination atmosphere is argon gas, obtains stainless (steel) wire load carbon coating tin oxide nano structure；
Step 7：
Above-mentioned carbon stainless steel net load carbon coating tin oxide nano structure is placed in tube furnace, in the atmosphere of reducing gas hydrogen
Final product stainless (steel) wire load carbon covered stannum rice structure is just obtained after a certain period of time with being made annealing treatment under predetermined temperature.
2. a kind of anode material of lithium-ion battery stainless (steel) wire load carbon covered stannum rice structure according to claim 1
Prepare, which is characterized in that in the step 4, hydrothermal temperature be 160~200 DEG C, the reaction time be 0.5~for 24 hours.
3. a kind of anode material of lithium-ion battery stainless (steel) wire load carbon covered stannum rice structure according to claim 1
It prepares, which is characterized in that in the step 5, organic carbon source is glucose, dopamine and beta-cyclodextrin etc., and reaction temperature exists
160 DEG C~200 DEG C, 4 hours.
4. a kind of anode material of lithium-ion battery stainless (steel) wire load carbon covered stannum rice structure according to claim 1
It prepares, which is characterized in that in the step 6, annealing temperature is 600 DEG C~750 DEG C, and annealing time is 1~4h, the stream of argon gas
Speed is 10~100sccm.
5. a kind of anode material of lithium-ion battery stainless (steel) wire load carbon covered stannum rice structure according to claim 1
It prepares, which is characterized in that in the step 7, annealing temperature is 600~750 DEG C, and annealing time is 1~4h, the flow velocity of hydrogen
For 300~400sccm.
6. a kind of application of anode material of lithium-ion battery stainless (steel) wire load carbon covered stannum rice structure, which is characterized in that will
Stainless (steel) wire load carbon covered stannum rice structural material is washed into a diameter of 8mm disks as active material electrode, and sodium is used as to electricity
Pole, electrolyte are the solution of the ethylene carbonate and carbonic acid dioctyl phthalate of 1M sodium hexafluoro phosphates, are by volume 1：1, polypropylene is micro-
Pore membrane is battery diaphragm, is assembled into button cell；By assembled button cell stand 12 hours after, LANDCT2100A into
Row electrochemical property test, test voltage are 0.01V~2.6V, current density 50mA/g.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810128510.5A CN108417780A (en) | 2018-02-08 | 2018-02-08 | A kind of preparation and its application of anode material of lithium-ion battery stainless (steel) wire load carbon covered stannum rice structure |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810128510.5A CN108417780A (en) | 2018-02-08 | 2018-02-08 | A kind of preparation and its application of anode material of lithium-ion battery stainless (steel) wire load carbon covered stannum rice structure |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108417780A true CN108417780A (en) | 2018-08-17 |
Family
ID=63128073
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810128510.5A Pending CN108417780A (en) | 2018-02-08 | 2018-02-08 | A kind of preparation and its application of anode material of lithium-ion battery stainless (steel) wire load carbon covered stannum rice structure |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108417780A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109301229A (en) * | 2018-11-12 | 2019-02-01 | 陕西科技大学 | A kind of preparation method and application of kalium ion battery negative electrode material graphene coated tin oxide/stannic disulfide nano flower |
| CN113233497A (en) * | 2021-05-18 | 2021-08-10 | 哈尔滨工业大学 | Preparation method and application of carbon-coated tin dioxide material |
| CN114899375A (en) * | 2022-05-09 | 2022-08-12 | 西安工业大学 | Preparation method of PEDOT-coated sheet-shaped self-assembled FeNCN film |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101723315A (en) * | 2009-11-26 | 2010-06-09 | 上海大学 | Preparation method of Sn/C nano composite material with nucleocapsid structure |
| CN104022285A (en) * | 2014-06-24 | 2014-09-03 | 武汉理工大学 | SnO2@polymer coaxial heterogeneous nano rod array structural material as well as preparation method and application thereof |
| CN104157876A (en) * | 2014-08-14 | 2014-11-19 | 上海交通大学 | Preparation method of porous carbon-tin nanocomposite material for lithium battery cathode |
| CN106299306A (en) * | 2016-09-30 | 2017-01-04 | 江苏长园华盛新能源材料有限公司 | A kind of stannum/carbon composite of nanostructured and its preparation method and application |
| CN106935823A (en) * | 2017-03-20 | 2017-07-07 | 郑州大学 | A kind of lithium ion battery negative material Sn/C and preparation method thereof |
-
2018
- 2018-02-08 CN CN201810128510.5A patent/CN108417780A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101723315A (en) * | 2009-11-26 | 2010-06-09 | 上海大学 | Preparation method of Sn/C nano composite material with nucleocapsid structure |
| CN104022285A (en) * | 2014-06-24 | 2014-09-03 | 武汉理工大学 | SnO2@polymer coaxial heterogeneous nano rod array structural material as well as preparation method and application thereof |
| CN104157876A (en) * | 2014-08-14 | 2014-11-19 | 上海交通大学 | Preparation method of porous carbon-tin nanocomposite material for lithium battery cathode |
| CN106299306A (en) * | 2016-09-30 | 2017-01-04 | 江苏长园华盛新能源材料有限公司 | A kind of stannum/carbon composite of nanostructured and its preparation method and application |
| CN106935823A (en) * | 2017-03-20 | 2017-07-07 | 郑州大学 | A kind of lithium ion battery negative material Sn/C and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| WEI-MING ZHANG等: "Tin-Nanoparticles Encapsulated in Elastic Hollow Carbon Spheres for High-Performance Anode Material in Lithium-Ion Batteries", 《ADVANCED MATERIALS》 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109301229A (en) * | 2018-11-12 | 2019-02-01 | 陕西科技大学 | A kind of preparation method and application of kalium ion battery negative electrode material graphene coated tin oxide/stannic disulfide nano flower |
| CN109301229B (en) * | 2018-11-12 | 2021-02-05 | 陕西科技大学 | Preparation method and application of graphene-coated tin oxide/tin disulfide nanoflower serving as negative electrode material of potassium ion battery |
| CN113233497A (en) * | 2021-05-18 | 2021-08-10 | 哈尔滨工业大学 | Preparation method and application of carbon-coated tin dioxide material |
| CN114899375A (en) * | 2022-05-09 | 2022-08-12 | 西安工业大学 | Preparation method of PEDOT-coated sheet-shaped self-assembled FeNCN film |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109004199B (en) | Preparation method of biomass hard carbon material for negative electrode of sodium-ion battery | |
| CN107579291B (en) | Aqueous electrolyte and aqueous metal ion battery | |
| CN107799757B (en) | MoS2Nitrogen-doped carbon tube composite material and preparation method and application thereof | |
| CN103219551A (en) | Water-system alkali metal ion power storage device | |
| CN107342421B (en) | High-content pyridine nitrogen-doped porous carbon negative electrode material, and preparation method and application thereof | |
| CN108598394B (en) | Carbon-coated titanium manganese phosphate sodium microspheres and preparation method and application thereof | |
| CN109686953A (en) | A kind of lithium-sulfur battery composite cathode material and preparation method thereof | |
| CN107946564B (en) | Rich in Na4Mn2O5/Na0.7MnO2Composite material and preparation method and application thereof | |
| CN106972162A (en) | A kind of sodium-ion battery double-doped hard carbon microballoon of negative material phosphorus sulphur and preparation method thereof | |
| CN112928343B (en) | Water system copper ion battery suitable for large-scale energy storage application | |
| CN113422153B (en) | Preparation method of anode side interlayer material for lithium-sulfur battery | |
| CN104795564A (en) | Cathode material, electrode piece, secondary cell and application of aqueous-solution secondary cell | |
| CN104064824A (en) | Water system rechargeable battery | |
| CN107968195A (en) | Lithium-rich cathode material coated by lithium iron phosphate and preparation method thereof | |
| CN114702614A (en) | Cathode material for improving cycling stability of vulcanized polyacrylonitrile battery and preparation method thereof | |
| CN110931779A (en) | High-capacity long-life aqueous zinc ion battery positive electrode material and preparation method thereof | |
| CN108390067A (en) | A kind of preparation and its application of stainless (steel) wire load carbon coating tin oxide nano structure | |
| CN108417780A (en) | A kind of preparation and its application of anode material of lithium-ion battery stainless (steel) wire load carbon covered stannum rice structure | |
| CN104241628A (en) | Method for preparing titanium-dioxide-modified ferric oxide microspheres as well as produced product and use of titanium-dioxide-modified ferric oxide microspheres | |
| CN110828799A (en) | Water-system zinc ion battery MnOx@ C cathode material and preparation method thereof | |
| CN111082162B (en) | Aqueous sodium ion battery | |
| CN102751503A (en) | Carbon/lithium stannate/graphene composite cathode material of lithium battery and preparation method of material | |
| CN105047870A (en) | Nitrogen-doped carbon-coated silicon composite material and preparation method thereof | |
| CN110854365A (en) | Preparation method of polyaniline/carbon composite material for anode material of water-based zinc-ion battery | |
| CN108281620B (en) | Preparation method of negative electrode material titanium dioxide of sodium-ion battery |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180817 |