CN108385375A - A kind of preparation method of super-hydrophobic antibiotic fabric - Google Patents
A kind of preparation method of super-hydrophobic antibiotic fabric Download PDFInfo
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- CN108385375A CN108385375A CN201810230501.7A CN201810230501A CN108385375A CN 108385375 A CN108385375 A CN 108385375A CN 201810230501 A CN201810230501 A CN 201810230501A CN 108385375 A CN108385375 A CN 108385375A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
- D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
- D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/12—Hydrophobic properties
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The present invention discloses a kind of preparation method of super-hydrophobic antibiotic fabric.The method includes：Fabric is handled using the Tris buffer solutions of dopamine at room temperature, then fabric is impregnated in the mixed solution of silver nitrate, ammonium citrate and boric acid, the fabric harsh surface constructed by nano silver is obtained after taking out drying；The fabric harsh surface that nano silver constructs is post-processed with free-floride water repellent again, assigns fabric low-surface-energy.The fabric that the present invention obtains has good super-hydrophobicity and excellent anti-microbial property, realizes the multifunction of fabric, and preparation method is easy, environmentally protective.
Description
Technical field
The present invention relates to the preparing technical fields of multifunctional fabric, and in particular to a kind of preparation side of super-hydrophobic antibiotic fabric
Method.
Background technology
Ultra-hydrophobicity is a kind of special state of body surface wettability, and in general, static contact angle is more than
150 °, surface of the roll angle less than 10 ° is referred to as super hydrophobic surface.People's lotus leaf from nature does not get wet, water skipper can be in water
It is found that super-hydrophobic effect in phenomena such as upper walking, and attempts this effect being applied in life and production.It is artificial super-hydrophobic
Surface has self-cleaning property, anticorrosive property, anti-freeze property, Drag Reduction etc., there is very strong practical application meaning.
With the development of science and technology and the continuous improvement of living standard, requirement of the people to fabric are no longer only limitted to protect
It is warm comfortable etc., also require it with more functions.The antibiotic property and self-cleaning of fabric meet people to clothes health and cleaning
Pursuit in terms of property.Some super-hydrophobic and antibiotic fabric preparation methods are developed at present, however, these methods still have
Some shortcomings, for example, to disclose a kind of super-hydrophobic antibacterial for pure cotton fabric washable multi-functional by patent of invention 103981718A
The preparation method and application of finishing agent, preparation method are with binary isocyanates, short fluorine chain block polyether dihydric alcohol, chain extension
Agent, cationic reagent, end-capping reagent are that milky reactive cationic water dispersed polyurethane finishing agent is made in raw material, but is somebody's turn to do
The synthetic method of finishing agent is complicated, and is related to a variety of fluorochemicals.
Invention content
The present invention overcomes the deficiencies of the prior art and provide a kind of preparation method of super-hydrophobic antibiotic fabric.This method is first
It using dopamine as reducing agent and adhesive, restores nano silver particles and it is made to be adhered on fabric, in fabric surface structure
Produce micro-nano coarse structure；Then further low-surface-energy free-floride water repellent is utilized to handle, obtains that there is super-hydrophobic anti-microbial property
Fabric.The fabric that this method is handled has excellent hydrophobicity and antibiotic property, and with environmentally protective, easy to operate easy
Capable feature.
The present invention is achieved through the following technical solutions.
A kind of preparation method of super-hydrophobic antibiotic fabric, includes the following steps：
(1) at room temperature, fabric is impregnated in the Tris buffer solutions of dopamine, the pH value of solution is 8~10, concentration
0.8~6g/L, bath raio 1：30~1：80, dipping 12h~take out afterwards for 24 hours are dried at a temperature of not higher than 80 DEG C；.
(2) mixed solution for preparing silver nitrate, ammonium citrate, boric acid adjusts pH value to 9~10, by step (1) with ammonium hydroxide
Middle gained fabric is impregnated in this mixed solution, bath raio 1：20~1：It is taken out after impregnating 3~15min at 50,50 DEG C~80 DEG C,
It is dried at a temperature of not higher than 80 DEG C；
(3) gained fabric in step (2) is impregnated in floride-free water repellent agent emulsion or solution at room temperature after 5~20min and is taken
Go out, 60~85 DEG C of drying, 125~135 DEG C bake 3~10min.
In the above method, solution system described in step (2) be 0.03~0.10mol/L silver nitrate, 0.06~
The mixed solution of the ammonium citrate of 0.20mol/L, the boric acid of 0.3~1.0mol/L.
In the above method, the floride-free water repellent described in step (3) is floride-free long-chain siloxanes, amino modified poly- silica
One kind of alkane, hydroxyl-terminated injecting two methyl siloxane, dimethyl silicone polymer, polycarbodiimide.
In the above method, the solvent in step (3) the floride-free water repellent agent solution is in ethyl alcohol, ethyl acetate, hexamethylene
It is one or more of.
In the above method, the mass fraction of floride-free water repellent is in the floride-free water repellent agent emulsion or solution described in step (3)
3%~10%.
The present invention method do not limited by fabric substrate fiber, to cellulose fibre, terylene, nylon, acrylic fibers, wool,
Fiber crops etc. are naturally and one or more kinds of fiber blends or union of science fabric are suitable for.
Advantage using the present invention is：
1, silver ion both became the basis that fabric obtains super-hydrophobicity as elementary particle construction rough surface in the present invention,
Assign fabric excellent anti-microbial property as antibacterial material again.
2, the basic reaction system that is made of silver ion and ammonium citrate of dipping solution in the present invention, ammonium citrate and
PH adjusting agent ammonium hydroxide is common silver-colored complexing agent, successively sequentially forms three silver medal of citric acid and silver ammonia complex by being added, this makes
Existing in solution of can stablizing of silver ion.The pH stabilizer boric acid solutions additionally incorporated slow down the speed of pH value of solution rising
Degree, to ensure the stability and activity of reaction.
3, the low-surface-energy decorative material that the present invention uses is not fluorine-containing, has environment friendly.
4, as reducing agent but also it not only had been used as adhesive using dopamine in the present invention, nano silver is made preferably to be attached to fabric
Surface improves the durability of super-hydrophobic antibiotic fabric.
5, the dipping process in step (2) of the present invention is only once, easy to operate easily-controllable without repeatedly impregnating repeatedly.
Specific implementation mode
The present invention will be further specifically described in detail with reference to specific embodiments, but embodiments of the present invention are not
It is limited to this, for not specifically specified technological parameter, can refer to routine techniques progress.
The static contact angle and roll angle of fabric described in embodiment are using upper marine morning JC2000D1 type contact angles test
Instrument is tested, and it is 5 μ L deionized waters to test water droplet used, and each sample takes 3 points, takes its average value.
The suction of the People's Republic of China's standard GB/T/T20944.2 is followed in the antibiotic rate test of fabric described in embodiment
Receipts method is operated, and strain selected by embodiment is staphylococcus aureus and Escherichia coli.
Sample in comparative example 1, comparative example 2 and comparative example 3 is the former cloth sample without super-hydrophobic antimicrobial treatment.
Embodiment 1
(1) at room temperature by through move back boil pre-treatment pure cotton plain weave cloth be impregnated in pH value be 8.5 1g/L DOPA
In the Tris buffer solutions of amine, bath raio 1：It is taken out after 50,20h, 40 DEG C of drying；
(2) mixed solution for preparing 0.05mol/L silver nitrates, 0.10mol/L ammonium citrates, 0.5mol/L boric acid, uses ammonia
Water adjusts pH value to 9, fabric obtained by step (1) is impregnated wherein under conditions of 50 DEG C, bath raio 1：It is taken out after 30,10min, 40
DEG C drying.
(3) ethyl alcohol that fabric obtained by step (2) is impregnated in the hexadecyl trimethoxy silane that mass fraction is 3% is molten
It in liquid, is taken out after 8min, 80 DEG C of drying, 135 DEG C bake 3min.
Embodiment 2
(1) at room temperature by through moving back boil pre-treatment polyester cotton knitting twill (cotton 80%, terylene 20%) be impregnated in pH
In Tris buffer solutions of the value for 9 0.8g/L dopamines, bath raio 1：60, it takes out later for 24 hours, 60 DEG C of drying；
(2) mixed solution for preparing 0.03mol/L silver nitrates, 0.06mol/L ammonium citrates, 0.5mol/L boric acid, uses ammonia
Water adjusts pH value to 10, fabric obtained by step (1) is impregnated under conditions of 60 DEG C in this mixed solution, bath raio 1：20,
It is taken out after 5min, 60 DEG C of drying.
(3) fabric obtained by step (2) is impregnated in the polycarbodiimide lotion PM-3705 that mass fraction is 3%,
It is taken out after 10min, 75 DEG C of drying, 125 DEG C bake 7min.
Embodiment 3
(1) it will boil pre-treatment polyester cotton plain weave cloth (cotton 15%, terylene 85%) through moving back at room temperature and be impregnated in pH and be
In the Tris buffer solutions of 8.5 2g/L dopamines, bath raio 1：It is taken out after 35,18h, 55 DEG C of drying；
(2) mixed solution for preparing 0.04mol/L silver nitrates, 0.8/L ammonium citrates, 0.5mol/L boric acid, with ammonium hydroxide tune
PH value is saved to 9, fabric obtained by step (1) is impregnated in wherein under conditions of 55 DEG C, bath raio 1：It is taken out after 25,8min, 55 DEG C
Drying.
(3) ethyl alcohol that fabric obtained by step (2) is impregnated in the hexadecyl trimethoxy silane that mass fraction is 8% is molten
It in liquid, is taken out after 15min, 80 DEG C of drying, 130 DEG C bake 5min.
The static contact angle and roll angle of 1 fabric of table
Note：Comparative sample is the former cloth sample without super-hydrophobic antimicrobial treatment.
The bacteriostasis rate of 2 fabric of table
The above embodiment of the present invention be only to clearly illustrate example of the present invention, and not be to the present invention
Embodiment restriction.For those of ordinary skill in the art, it can also make on the basis of the above description
Other various forms of variations or variation.There is no necessity and possibility to exhaust all the enbodiments.It is all the present invention
All any modification, equivalent and improvement etc., should be included in the protection of the claims in the present invention made by within spirit and principle
Within the scope of.
Claims (6)
1. a kind of preparation method of super-hydrophobic antibiotic fabric, which is characterized in that include the following steps：
（1）At room temperature, fabric being impregnated in the Tris buffer solutions of dopamine, the pH value of solution is 8 ~ 10, concentration 0.8 ~
6g/L, bath raio 1：30~1：80, dipping 12h ~ take out afterwards for 24 hours are dried at a temperature of not higher than 80 DEG C；
（2）The mixed solution for preparing silver nitrate, ammonium citrate, boric acid adjusts pH value to 9 ~ 10, by step with ammonium hydroxide（1）Middle institute
It obtains fabric to be impregnated in the mixed solution, dipping temperature is 50 DEG C ~ 80 DEG C, bath raio 1：20~1：50, it is taken after impregnating 3~15min
Go out, is dried at a temperature of not higher than 80 DEG C；
（3）By step（2）Middle gained fabric is impregnated in 5 ~ 20min in floride-free water repellent agent emulsion or solution at room temperature, 60 after taking-up ~
85 DEG C of drying, 125 ~ 135 DEG C bake 3 ~ 10min.
2. a kind of preparation method of super-hydrophobic antibiotic fabric according to claim 1, which is characterized in that step（2）In, institute
State silver nitrate, the ammonium citrate of 0.06 ~ 0.20mol/L and the boron of 0.3 ~ 1.0mol/L that mixed solution is 0.03 ~ 0.10mol/L
The mixed solution of acid.
3. a kind of preparation method of super-hydrophobic antibiotic fabric according to claim 1, which is characterized in that step（3）In, institute
It is floride-free long-chain siloxanes, amino modified polysiloxane, hydroxyl-terminated injecting two methyl siloxane, poly dimethyl silicon to state floride-free water repellent
One kind in oxygen alkane, polycarbodiimide.
4. a kind of preparation method of super-hydrophobic antibiotic fabric according to claim 1, which is characterized in that step（3）In, institute
It is one or more of in ethyl alcohol, ethyl acetate, hexamethylene to state the solvent in floride-free water repellent agent solution.
5. a kind of preparation method of super-hydrophobic antibiotic fabric according to claim 1, which is characterized in that step（3）In, institute
The mass fraction for stating floride-free water repellent in floride-free water repellent agent emulsion or solution is 3% ~ 10%.
6. a kind of preparation method of super-hydrophobic antibiotic fabric according to claim 1, which is characterized in that the fabric is
The fiber blend or union of one or more of cellulose fibre, terylene, nylon, acrylic fibers, wool, fiber crops.
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| CN201810230501.7A CN108385375A (en) | 2018-03-20 | 2018-03-20 | A kind of preparation method of super-hydrophobic antibiotic fabric |
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| CN201810230501.7A CN108385375A (en) | 2018-03-20 | 2018-03-20 | A kind of preparation method of super-hydrophobic antibiotic fabric |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109267354A (en) * | 2018-09-07 | 2019-01-25 | 安徽亚源印染有限公司 | A kind of hydrophobic finishing method of CVC fabric |
| CN109722900A (en) * | 2019-01-28 | 2019-05-07 | 扬州大学 | Ultra-hydrophobic conductive compound fabric with electromagnetic shielding performance and preparation method thereof |
| CN110004722A (en) * | 2019-03-28 | 2019-07-12 | 江南大学 | A kind of preparation method of dopamine and the hydrophobic cotton fabric of hydrophobic compound copolymerization |
| CN110130114A (en) * | 2019-04-25 | 2019-08-16 | 王兵兵 | A kind of biomass graphene fabric and preparation method thereof |
| CN111270514A (en) * | 2020-03-03 | 2020-06-12 | 江苏理工学院 | Preparation method of stable superhydrophobic antibacterial cotton fabric based on glutaraldehyde crosslinking |
| CN112538762A (en) * | 2020-12-16 | 2021-03-23 | 江苏理工学院 | Method for preparing stable super-hydrophobic antibacterial fabric by one-pot method |
| CN113699791A (en) * | 2021-08-30 | 2021-11-26 | 杨春云 | Soft antibacterial non-woven fabric and preparation method thereof |
| CN114000138A (en) * | 2021-11-05 | 2022-02-01 | 哈尔滨工业大学 | Method for preparing super-hydrophobic surface by utilizing nano metal hot pressing |
| CN114481612A (en) * | 2021-12-28 | 2022-05-13 | 福建成东新材料科技有限公司 | Manufacturing process of modified fluoride-free waterproof dyed yarn |
| CN115058887A (en) * | 2022-07-22 | 2022-09-16 | 武汉纺织大学 | Super-hydrophobic antibacterial textile and preparation method thereof |
| CN115538169A (en) * | 2022-10-12 | 2022-12-30 | 山东中康国创先进印染技术研究院有限公司 | Durable super-hydrophobic cotton fabric and preparation method thereof |
| CN116397431A (en) * | 2023-04-11 | 2023-07-07 | 安徽新虹纺织有限公司 | Preparation method of antibacterial wear-resistant fabric |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101724841A (en) * | 2008-10-10 | 2010-06-09 | 北京化工大学 | Method for preparing polymer/silver composite membrane by depositing dopamine |
| CN101864670A (en) * | 2010-06-23 | 2010-10-20 | 东华大学 | Method for preparing nano silver-containing anti-bacterial fabric by immersion process |
| CN103276379A (en) * | 2013-05-29 | 2013-09-04 | 北京化工大学 | Method for preparing surface silver-plated electric-spinning fiber by using dopamine |
| CN105195025A (en) * | 2015-09-09 | 2015-12-30 | 天津大学 | Method of preparing antibacterial anti-pollution ultrafiltration membrane by adopting silver-loaded nano composite material |
| CN107435247A (en) * | 2017-08-07 | 2017-12-05 | 烟台大学 | A kind of floride-free durable super-hydrophobic property fabric and preparation method thereof |
-
2018
- 2018-03-20 CN CN201810230501.7A patent/CN108385375A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101724841A (en) * | 2008-10-10 | 2010-06-09 | 北京化工大学 | Method for preparing polymer/silver composite membrane by depositing dopamine |
| CN101864670A (en) * | 2010-06-23 | 2010-10-20 | 东华大学 | Method for preparing nano silver-containing anti-bacterial fabric by immersion process |
| CN103276379A (en) * | 2013-05-29 | 2013-09-04 | 北京化工大学 | Method for preparing surface silver-plated electric-spinning fiber by using dopamine |
| CN105195025A (en) * | 2015-09-09 | 2015-12-30 | 天津大学 | Method of preparing antibacterial anti-pollution ultrafiltration membrane by adopting silver-loaded nano composite material |
| CN107435247A (en) * | 2017-08-07 | 2017-12-05 | 烟台大学 | A kind of floride-free durable super-hydrophobic property fabric and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 上海市化工轻工供应公司 上海化工采购供应站技术室: "《化工商品检验方法》", 31 October 1988, 化学工业出版社 * |
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109267354A (en) * | 2018-09-07 | 2019-01-25 | 安徽亚源印染有限公司 | A kind of hydrophobic finishing method of CVC fabric |
| CN109722900A (en) * | 2019-01-28 | 2019-05-07 | 扬州大学 | Ultra-hydrophobic conductive compound fabric with electromagnetic shielding performance and preparation method thereof |
| CN109722900B (en) * | 2019-01-28 | 2021-09-17 | 扬州大学 | Super-hydrophobic conductive composite fabric with electromagnetic shielding performance and preparation method thereof |
| CN110004722A (en) * | 2019-03-28 | 2019-07-12 | 江南大学 | A kind of preparation method of dopamine and the hydrophobic cotton fabric of hydrophobic compound copolymerization |
| CN110130114A (en) * | 2019-04-25 | 2019-08-16 | 王兵兵 | A kind of biomass graphene fabric and preparation method thereof |
| CN111270514B (en) * | 2020-03-03 | 2022-06-10 | 江苏理工学院 | Preparation method of stable superhydrophobic antibacterial cotton fabric based on glutaraldehyde crosslinking |
| CN111270514A (en) * | 2020-03-03 | 2020-06-12 | 江苏理工学院 | Preparation method of stable superhydrophobic antibacterial cotton fabric based on glutaraldehyde crosslinking |
| CN112538762A (en) * | 2020-12-16 | 2021-03-23 | 江苏理工学院 | Method for preparing stable super-hydrophobic antibacterial fabric by one-pot method |
| CN112538762B (en) * | 2020-12-16 | 2022-07-08 | 江苏理工学院 | Method for preparing stable super-hydrophobic antibacterial fabric by one-pot method |
| CN113699791A (en) * | 2021-08-30 | 2021-11-26 | 杨春云 | Soft antibacterial non-woven fabric and preparation method thereof |
| CN114000138A (en) * | 2021-11-05 | 2022-02-01 | 哈尔滨工业大学 | Method for preparing super-hydrophobic surface by utilizing nano metal hot pressing |
| CN114481612A (en) * | 2021-12-28 | 2022-05-13 | 福建成东新材料科技有限公司 | Manufacturing process of modified fluoride-free waterproof dyed yarn |
| CN115058887A (en) * | 2022-07-22 | 2022-09-16 | 武汉纺织大学 | Super-hydrophobic antibacterial textile and preparation method thereof |
| CN115538169A (en) * | 2022-10-12 | 2022-12-30 | 山东中康国创先进印染技术研究院有限公司 | Durable super-hydrophobic cotton fabric and preparation method thereof |
| CN115538169B (en) * | 2022-10-12 | 2023-10-17 | 山东中康国创先进印染技术研究院有限公司 | Durable super-hydrophobic cotton fabric and preparation method thereof |
| CN116397431A (en) * | 2023-04-11 | 2023-07-07 | 安徽新虹纺织有限公司 | Preparation method of antibacterial wear-resistant fabric |
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Application publication date: 20180810 |