CN108384612A - A kind of wear-resistant rust preventive cutting fluid - Google Patents
A kind of wear-resistant rust preventive cutting fluid Download PDFInfo
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- CN108384612A CN108384612A CN201810292543.3A CN201810292543A CN108384612A CN 108384612 A CN108384612 A CN 108384612A CN 201810292543 A CN201810292543 A CN 201810292543A CN 108384612 A CN108384612 A CN 108384612A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/06—Metal compounds
- C10M2201/061—Carbides; Hydrides; Nitrides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/08—Inorganic acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/087—Boron oxides, acids or salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/1006—Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/283—Esters of polyhydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/287—Partial esters
- C10M2207/289—Partial esters containing free hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/102—Polyesters
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/042—Metal salts thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
The invention discloses a kind of wear-resistant rust preventive cutting fluid, raw material includes：Mineral oil, phthaloyl imino valeric acid hydramine rare-earth salts, citric acid sorbitol ester, four amylalcohol ester of tetrabutyl acetic acid season, Phytic acid lanthanum, zinc molybdate, tungsten carbide, copper borate, emulsifier, polyoxyethylene polyoxypropylene pentaerythrite ether, surfactant and water.Zinc molybdate, tungsten carbide, the corrosion mitigating effect of copper borate are good in the present invention, while having excellent antiwear and reducing friction performance, and the abrasion resistance of cutting fluid of the present invention is good, anticorrosion is efficient, safety and environmental protection.
Description
Technical field
The present invention relates to technical field of rust prevention more particularly to a kind of wear-resistant rust preventive cutting fluids.
Background technology
Cutting fluid is that one kind is used in metal cutting, mill process, for cooling down and lubricating the work of cutter and workpiece
Industry liquid, cutting fluid from a variety of super strong functional auxiliary agents it is compound through science with form, be provided simultaneously with good cooling performance, profit
Slip energy, rustless property, oil removing cleaning function, anti-corrosion function, easily dilutable feature.It is easy to overcome traditional tradition soap base emulsion summer
The difficult dilution of smelly, winter, rust-proof effect difference defect, also have no adverse effects to lathe paint, suitable for ferrous metal cutting and
Mill processing belongs to current most leading abrasive product.
Cutting fluid many index is superior to saponified oil, it has the characteristics that good cooling, cleaning, antirust, and has nothing
It is malicious, tasteless, non-corrosive to human body, to equipment, burn into does not pollute environment, but the wear-resisting property of traditional cutting fluid is poor, easy
Pollution, with the development of science and technology, the raising of quality requirement, how to prepare a kind of rust preventive cutting fluid of wear-resistant environmental protection be it is current urgently
The technical issues of solution.
Invention content
Technical problems based on background technology, the present invention propose a kind of wear-resistant rust preventive cutting fluid, abrasion resistance is good,
Anticorrosion is efficient, safety and environmental protection.
The present invention proposes that a kind of wear-resistant antirust cutting fluid, raw material include by weight：55-65 parts of mineral oil, adjacent benzene two
9-18 parts of formyl imino group valeric acid hydramine rare-earth salts, 6-12 parts of citric acid sorbitol ester, four amylalcohol ester 5-10 of tetrabutyl acetic acid season
Part, 5-10 parts of Phytic acid lanthanum, 5-10 parts of zinc molybdate, 3-6 parts of tungsten carbide, 2-4 parts of copper borate, 3-6 parts of emulsifier, polyoxyethylene polyoxy
0.5-1 parts of propylene pentaerythrite ether, 0.5-1 parts of surfactant, 6-14 parts of water.
Preferably, mineral oil 58-62 parts, 12-16 parts of phthaloyl imino valeric acid hydramine rare-earth salts, citric acid sorb
8-10 parts of alcohol ester, the tetrabutyl acetic acid season 6-8 parts of four amylalcohol ester, 6-8 parts of Phytic acid lanthanum, 6-8 parts of zinc molybdate, 4.5-5.5 parts of tungsten carbide,
2.5-3.5 parts of copper borate, 4-5 parts of emulsifier, 0.6-0.8 parts of polyoxyethylene polyoxypropylene pentaerythrite ether, surfactant
0.6-0.8 parts, 8-10 parts of water.
Preferably, phthaloyl imino valeric acid hydramine rare-earth salts is phthaloyl imino valeric acid hydramine lanthanum, neighbour
It is one or more in phthalimido valeric acid hydramine cerium.
Preferably, phthaloyl imino valeric acid hydramine cerium, citric acid sorbitol ester, four amylalcohol of tetrabutyl acetic acid season
Ester, Phytic acid lanthanum weight ratio be 14：9：7：7.
Preferably, zinc molybdate, tungsten carbide, copper borate weight ratio be 8：5：3.
Preferably, emulsifier is polyoxyethylene oleic acid ester and/or fatty alcohol polyoxyethylene ether.
Preferably, surfactant fatty acid glyceride and/or stearic acid.
Phthaloylamino acetic acid hydramine rare-earth salts, citric acid sorbitol ester, tetrabutyl acetic acid season 4 penta in the present invention
The high rust resistance of alcohol ester, Phytic acid lanthanum, four, which cooperate, forms the antirust system of cutting fluid, is rich in hydroxyl and amide groups
Group, easily on adsorbing metal surface, prevents moisture attack surface, significantly improves antiseptic property；Zinc molybdate, carbonization in the present invention
Tungsten, copper borate can improve rust-proof effect as the inhibition synergist of cutting fluid antirust system, while have excellent wear-resistant subtract
Effect is ground, the abrasion resistance of cutting fluid is further increased；Suitable polyoxyethylene polyoxypropylene pentaerythrite is added in the present invention
Ether, surfactant and emulsifier reduce bubble, promote each component emulsification and dispersion in cutting fluid, improve cutting fluid and metal
Wetting effect, increase cutting fluid system stability.
Specific implementation mode
In the following, technical scheme of the present invention is described in detail by specific embodiment.
Embodiment 1
A kind of wear-resistant rust preventive cutting fluid, raw material include by weight：55 parts of mineral oil, phthaloyl imino valeric acid
9 parts of hydramine cerium, 6 parts of citric acid sorbitol ester, tetrabutyl acetic acid season 5 parts of four amylalcohol ester, 5 parts of Phytic acid lanthanum, 5 parts of zinc molybdate, carbonization
3 parts of tungsten, 2 parts of copper borate, 3 parts of polyoxyethylene oleic acid ester, 0.5 part of polyoxyethylene polyoxypropylene pentaerythrite ether, fatty acid glycerine
0.5 part of ester, 6 parts of water.
Embodiment 2
A kind of wear-resistant rust preventive cutting fluid, raw material include by weight：65 parts of mineral oil, phthaloyl imino valeric acid
18 parts of hydramine lanthanum, 12 parts of citric acid sorbitol ester, tetrabutyl acetic acid season 10 parts of four amylalcohol ester, 10 parts of Phytic acid lanthanum, 10 parts of zinc molybdate,
6 parts of tungsten carbide, 4 parts of copper borate, 6 parts of fatty alcohol polyoxyethylene ether, 1 part of polyoxyethylene polyoxypropylene pentaerythrite ether, stearic acid 1
Part, 14 parts of water.
Embodiment 3
A kind of wear-resistant rust preventive cutting fluid, raw material include by weight：58 parts of mineral oil, phthaloyl imino valeric acid
12 parts of hydramine cerium, 8 parts of citric acid sorbitol ester, tetrabutyl acetic acid season 6 parts of four amylalcohol ester, 6 parts of Phytic acid lanthanum, 6 parts of zinc molybdate, carbonization
4.5 parts of tungsten, 2.5 parts of copper borate, 4 parts of polyoxyethylene oleic acid ester, 0.6 part of polyoxyethylene polyoxypropylene pentaerythrite ether, aliphatic acid
0.6 part of glyceride, 8 parts of water.
Embodiment 4
A kind of wear-resistant rust preventive cutting fluid, raw material include by weight：62 parts of mineral oil, phthaloyl imino valeric acid
16 parts of hydramine cerium, 10 parts of citric acid sorbitol ester, tetrabutyl acetic acid season 8 parts of four amylalcohol ester, 8 parts of Phytic acid lanthanum, 8 parts of zinc molybdate, carbon
Change 5.5 parts of tungsten, 3.5 parts of copper borate, 5 parts of fatty alcohol polyoxyethylene ether, 0.8 part of polyoxyethylene polyoxypropylene pentaerythrite ether, fat
0.8 part of fatty acid glyceride and/or stearic acid, 10 parts of water.
Embodiment 5
A kind of wear-resistant rust preventive cutting fluid, raw material include by weight：60 parts of mineral oil, phthaloyl imino valeric acid
14 parts of hydramine cerium, 9 parts of citric acid sorbitol ester, tetrabutyl acetic acid season 7 parts of four amylalcohol ester, 7 parts of Phytic acid lanthanum, 7 parts of zinc molybdate, carbonization
5 parts of tungsten, 3 parts of copper borate, 4.5 parts of polyoxyethylene oleic acid ester, 0.7 part of polyoxyethylene polyoxypropylene pentaerythrite ether, aliphatic acid is sweet
0.7 part of grease, 9 parts of water.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Any one skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (7)
1. a kind of wear-resistant rust preventive cutting fluid, which is characterized in that its raw material includes by weight：55-65 parts of mineral oil, O-phthalic
9-18 parts of acylimino valeric acid hydramine rare-earth salts, 6-12 parts of citric acid sorbitol ester, the tetrabutyl acetic acid season 5-10 parts of four amylalcohol ester,
5-10 parts of Phytic acid lanthanum, 5-10 parts of zinc molybdate, 3-6 parts of tungsten carbide, 2-4 parts of copper borate, 3-6 parts of emulsifier, polyoxyethylene polyoxy third
0.5-1 parts of alkene pentaerythrite ether, 0.5-1 parts of surfactant, 6-14 parts of water.
2. wear-resistant rust preventive cutting fluid according to claim 1, which is characterized in that 58-62 parts of mineral oil, O-phthalic imide
12-16 parts of base valeric acid hydramine rare-earth salts, 8-10 parts of citric acid sorbitol ester, the tetrabutyl acetic acid season 6-8 parts of four amylalcohol ester, Phytic acid lanthanum
6-8 parts, 6-8 parts of zinc molybdate, 4.5-5.5 parts of tungsten carbide, 2.5-3.5 parts of copper borate, 4-5 parts of emulsifier, polyoxyethylene polyoxy third
0.6-0.8 parts of alkene pentaerythrite ether, 0.6-0.8 parts of surfactant, 8-10 parts of water.
3. wear-resistant rust preventive cutting fluid according to claim 1 or claim 2, which is characterized in that phthaloyl imino valeric acid hydramine
Rare-earth salts is one or more in phthaloyl imino valeric acid hydramine lanthanum, phthaloyl imino valeric acid hydramine cerium.
4. according to the wear-resistant rust preventive cutting fluids of any one of claim 1-3, which is characterized in that phthaloyl imino valeric acid hydramine
Cerium, citric acid sorbitol ester, four amylalcohol ester of tetrabutyl acetic acid season, Phytic acid lanthanum weight ratio be 14：9：7：7.
5. according to any one of the claim 1-4 wear-resistant rust preventive cutting fluids, which is characterized in that zinc molybdate, tungsten carbide, copper borate
Weight ratio be 8：5：3.
6. according to any one of the claim 1-5 wear-resistant rust preventive cutting fluids, which is characterized in that emulsifier is oleic acid polyoxyethylene
Ester and/or fatty alcohol polyoxyethylene ether.
7. according to any one of the claim 1-6 wear-resistant rust preventive cutting fluids, which is characterized in that surfactant fatty acid glycerine
Ester and/or stearic acid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810292543.3A CN108384612A (en) | 2018-03-30 | 2018-03-30 | A kind of wear-resistant rust preventive cutting fluid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810292543.3A CN108384612A (en) | 2018-03-30 | 2018-03-30 | A kind of wear-resistant rust preventive cutting fluid |
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| Publication Number | Publication Date |
|---|---|
| CN108384612A true CN108384612A (en) | 2018-08-10 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810292543.3A Withdrawn CN108384612A (en) | 2018-03-30 | 2018-03-30 | A kind of wear-resistant rust preventive cutting fluid |
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| CN (1) | CN108384612A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114350429A (en) * | 2022-03-21 | 2022-04-15 | 泰奥星（天津）有限公司 | Lubricating oil, preparation method and application thereof |
-
2018
- 2018-03-30 CN CN201810292543.3A patent/CN108384612A/en not_active Withdrawn
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114350429A (en) * | 2022-03-21 | 2022-04-15 | 泰奥星（天津）有限公司 | Lubricating oil, preparation method and application thereof |
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Application publication date: 20180810 |