CN108358707A - Composite enzyme fertilizer and preparation method thereof - Google Patents
Composite enzyme fertilizer and preparation method thereof Download PDFInfo
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- CN108358707A CN108358707A CN201810397212.6A CN201810397212A CN108358707A CN 108358707 A CN108358707 A CN 108358707A CN 201810397212 A CN201810397212 A CN 201810397212A CN 108358707 A CN108358707 A CN 108358707A
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F17/00—Preparation of fertilisers characterised by biological or biochemical treatment steps, e.g. composting or fermentation
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F3/00—Fertilisers from human or animal excrements, e.g. manure
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/40—Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse
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- Pest Control & Pesticides (AREA)
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Abstract
The invention discloses a kind of composite enzyme fertilizer and preparation method thereof.(1) 35~40 DEG C of water is mixed with plant enzyme, leaf, fruit, pine nut, soybean residue, soya-bean cake, vegetable oil residue, rice bran and malt sugar, is aerated 25~200 minutes, obtains mixture；In the mixture, plant enzyme accounts for 2~6wt%, leaf accounts for 3~8wt%, fruit accounts for 3~8wt%, pine nut accounts for 0.5~2wt%, soybean residue accounts for 0.5~2wt%, soya-bean cake accounts for 0.5~2wt%, vegetable oil residue accounts for 0.5~2wt%, rice bran accounts for 0.5~2wt% and malt sugar accounts for 0.5~2wt%；By fermented mixture 30~60 days, zymotic fluid is obtained；(2) zymotic fluid is diluted with water, obtains composite enzyme liquid；(3) animal wastes are contacted with composite enzyme liquid, ferments 20~50 days, obtains the composite enzyme fertilizer.The method of the present invention can obtain solid fertilizer, reduce fermentation time, cost is relatively low.
Description
Technical field
The present invention relates to a kind of composite enzyme fertilizer and preparation method thereof, especially a kind of microorganism composite enzyme fertilizer and
Preparation method.
Background technology
Fertilizer is available to plant more than one required nutrients, improves soil property, level of increasing soil fertility
Substance.Fertilizer includes ammonium phosphate fertilizers, Macroelement water-soluble fertilizer, secondary nutrients, bio-feritlizer, organic fertilizer
Deng.The bio-feritlizer of broad sense is not only containing the nutrient needed for plant, but also contains microbial product, thus can replace partization
Fertilizer.
Currently, most of livestock and poultry cultivation fecaluria treatment technology is to carry out fermentation process with various microorganisms to solids to have
Machine fertilizer.The fermentation process time of these organic fertilizer is long, 120 days or so winter, 60 days or so summer.In addition, their processing
It is of high cost.Use microbiological treatment organic fertilizer, solids (excrement, tangerine bar) strain expense generally in 40 yuan/m in the market2。
Enzyme microb is the fermentate containing various active probiotics, has the function of promoting animal and plant growth existence,
It can make active organism generation biochemical reaction or be difficult that the biochemical reaction occurred accelerates at normal temperatures and pressures.Commonly
Enzyme microb is mostly composite enzyme.But composite enzyme cost used at present is higher.
Invention content
In view of this, the purpose of the present invention is to provide a kind of preparation method of composite enzyme fertilizer, shape can be reduced
It is cost-effective at the fermentation time of fertilizer.It is another object of the present invention to provide the compound ferment that above-mentioned preparation method obtains
Fertilizer can substitute part chemical fertilizer, reduce fertilizer amount.
The preparation method of the composite enzyme fertilizer of the present invention includes the following steps：
(1) by 35~40 DEG C of water and plant enzyme, leaf, fruit, pine nut, soybean residue, soya-bean cake, vegetable oil residue, rice bran
It is mixed with malt sugar, is aerated 25~200 minutes, obtains mixture；In the mixture, plant enzyme account for 2~6wt%, leaf account for 3~
8wt%, fruit account for 3~8wt%, pine nut accounts for 0.5~2wt%, soybean residue accounts for 0.5~2wt%, soya-bean cake accounts for 0.5~2wt%, plant
The object dregs of fat account for 0.5~2wt%, rice bran accounts for 0.5~2wt% and malt sugar accounts for 0.5~2wt%；By fermented mixture 30~60 days,
Obtain zymotic fluid；
(2) zymotic fluid is diluted with water, obtains composite enzyme liquid；
(3) animal wastes are contacted with the composite enzyme liquid, ferments 20~50 days, obtains the composite enzyme fertilizer.
The fertilizer of the present invention is preferably solid fertilizer.The fermentation raw material of the present invention contains leaf, more cheap and easy to get.Plant
Ferment may be used it is those of known in the art, for example, by using fruit ferment, pectase etc..Commercially available plant ferment may be used
Element, or prepared using existing method.For example, CN103609985A, CN104012896A, CN104473170A are disclosed
Its full text, is incorporated herein by the preparation methods of some fruit ferment herein.
In the present invention, malt sugar is also referred to as molasses, is acted on made by the starch in cracking rice by the carbohydrase in malt
A kind of sugar；Malt sugar is thick pale yellow transparency liquid, and main component is maltose, glucose and dextrin.The malt sugar of the present invention
Sugarcane may be used, beet is substituted, and these equivalent substitutes also belong to protection scope of the present invention.
In the present invention, vegetable oil residue is remaining residue after plant oil expression.For example, the residue obtained after soybean extract oil,
Residue after peanut oil expression, the residue etc. after flax oil expression.
In the step (1) of the present invention, preceding 10~15 days fermentation temperatures are 30~40 DEG C, and subsequent fermentation temperature is 10
~40 DEG C；Need within first 20~25 days stirring 10~50 minutes daily.That is, first 10~15 days send out at a higher temperature
Ferment then can then ferment at a lower temperature.Be conducive to the breeding of active probiotic in this way.First 10~15 days fermentation temperature
Preferably 35~40 DEG C of degree, subsequent fermentation temperature is 20~30 DEG C.It is stirred daily within first 20~25 days, is conducive to live in this way
The breeding of property probiotics.The time of stirring can be 10~50 minutes, preferably 10~20 minutes.In the zymotic fluid of the present invention
In, total bacteria count can reach 3 × 108~3 × 109CFU/ml, lactic acid bacteria account for 80% of total bacteria count or more；Actinomyces, photosynthetic bacteria,
Other probiotics such as nitrogen-fixing bacteria, bacillus subtilis, saccharomycete then account for 5~20%.This may be used in total bacteria count and various bacterium
The method of field routine measures, and which is not described herein again.
In the present invention, the fermentation of step (1) can carry out in closed container.Closed container includes but not limited to close
Fermentation tank.Be conducive to being smoothed out for fermentation process in this way.During the fermentation, closed container can be opened to be stirred.
The time of stirring can be 10~50 minutes, preferably 10~20 minutes.
According to embodiment of the present invention, in the mixture, plant enzyme account for 3~5wt%, leaf account for 6~
7.5wt%, fruit account for 6~7.5wt%, pine nut accounts for 1~1.5wt%, soybean residue accounts for 1~1.5wt%, soya-bean cake account for 1~
1.5wt%, vegetable oil residue account for 1~1.5wt%, rice bran accounts for 1~1.5wt% and malt sugar accounts for 1~1.5wt%.The weight of above-mentioned raw materials
Amount percentage is all based on the total weight of mixture.
In the present invention, the leaf includes Poplar leaves, pine tree leaf, Folium Pterocaryae, peach leaves, apple leaf and loguat leaf；It is excellent
Selection of land, leaf are made of Poplar leaves, pine tree leaf, Folium Pterocaryae, peach leaves, apple leaf and loguat leaf.Above-mentioned leaf is provided with ability
Meaning known to domain, which is not described herein again.The fruit of the present invention includes pears, apple, hawthorn, blueberry, orange, apricot and lichee；It is excellent
Selection of land, fruit are made of pears, apple, hawthorn, blueberry, orange, apricot and lichee.Above-mentioned fruit is provided with known in the art contain
Justice, which is not described herein again.Preferably, the persticide residue of above-mentioned leaf and fruit it is not exceeded preferably.Using above-mentioned leaf and
Fruit can improve the quantity of active probiotic.
According to embodiment of the present invention, in step (1), the leaf includes Poplar leaves, pine tree leaf, willow
Leaf, peach leaves, apple leaf and loguat leaf；The fruit includes pears, apple, hawthorn, blueberry, orange, apricot and lichee.Poplar leaves,
Pine tree leaf, Folium Pterocaryae, peach leaves, apple leaf and loguat leaf weight ratio can be 1~1.5:1~1.5:1~1.5:1~1.5:
1~1.5:1~1.5；Preferably 1~1.3:1~1.3:1~1.3:1~1.3:1~1.3:1~1.3.Pears, apple, hawthorn, indigo plant
The certain kind of berries, orange, apricot and lichee weight ratio be 1~1.5:1~1.5:1~1.5:1~1.5:1~1.5:1~1.5:1~1.5；It is excellent
It is selected as 1~1.3:1~1.3:1~1.3:1~1.3:1~1.3:1~1.3:1~1.3.Using above-mentioned weight proportion, Ke Yigai
Kind ferment effect, to improve the quantity of active probiotic.Preferably, Poplar leaves, pine tree leaf, Folium Pterocaryae, peach leaves, apple
The weight ratio of leaf and loguat leaf is 1~1.5:1~1.5:1~1.5:1~1.5:1~1.5:1~1.5；Pears, apple, hawthorn, indigo plant
The certain kind of berries, orange, apricot and lichee weight ratio be 1~1.5:1~1.5:1~1.5:1~1.5:1~1.5:1~1.5:1~1.5.Make
For it is further preferred that Poplar leaves, pine tree leaf, Folium Pterocaryae, peach leaves, apple leaf and loguat leaf weight ratio be 1:1:1:1:1:1；Pears,
Apple, hawthorn, blueberry, orange, apricot and lichee weight ratio be 1:1:1:1:1:1:1.
According to another implementation of the invention, in step (1), the leaf is by Poplar leaves, pine tree leaf, willow
Leaf, peach leaves, apple leaf and loguat leaf composition；The fruit is made of pears, apple, hawthorn, blueberry, orange, apricot and lichee.Poplar
Leaf, pine tree leaf, Folium Pterocaryae, peach leaves, apple leaf and loguat leaf weight ratio can be 1~1.5:1~1.5:1~1.5:1
~1.5:1~1.5:1~1.5；Preferably 1~1.3:1~1.3:1~1.3:1~1.3:1~1.3:1~1.3.Pears, apple,
Hawthorn, blueberry, orange, apricot and lichee weight ratio be 1~1.5:1~1.5:1~1.5:1~1.5:1~1.5:1~1.5:1
~1.5；Preferably 1~1.3:1~1.3:1~1.3:1~1.3:1~1.3:1~1.3:1~1.3.Matched using above-mentioned weight
Than ferment effect can be improved, to improve the quantity of active probiotic.Preferably, Poplar leaves, pine tree leaf, Folium Pterocaryae, peach
The weight ratio of leaf, apple leaf and loguat leaf is 1~1.5:1~1.5:1~1.5:1~1.5:1~1.5:1~1.5；Pears, apple
Fruit, hawthorn, blueberry, orange, apricot and lichee weight ratio be 1~1.5:1~1.5:1~1.5:1~1.5:1~1.5:1~
1.5:1~1.5.More preferably, the weight ratio of Poplar leaves, pine tree leaf, Folium Pterocaryae, peach leaves, apple leaf and loguat leaf is 1:
1:1:1:1:1；Pears, apple, hawthorn, blueberry, orange, apricot and lichee weight ratio be 1:1:1:1:1:1:1.
In the step (2) of the present invention, the dosage of water is 5~50 times, preferably 10~15 times of the zymotic fluid weight.
Dilution appropriate is conducive to composite fermentation liquid and uniformly sprays, and cost-effective.Dilution is too many, and flora is caused to destroy, cannot be fine
Ferment excrement on ground；Dilution is very little, can increase cost.
In the step (3) of the present invention, animal wastes are contacted with the composite enzyme liquid by sprinkling, fermentation 20~50
It, obtains the composite enzyme fertilizer.The mode of contact is not particularly limited.For example, composite enzyme liquid is sprayed at animal
Excrement surface；For another example, composite enzyme liquid is stirred evenly with animal wastes.According to embodiment of the present invention, by animal
It is 10~60cm that excrement, which shakeouts to thickness, and the composite enzyme liquid is sprayed on excrement face；It is sprayed again after stirring evenly one time
Composite enzyme liquid；Then heap is played, heap width is 1~10m, a height of 1~5m of heap；The composite enzyme liquid is sprayed again after playing heap,
It ferments 20~50 days after sealing, obtains the composite enzyme fertilizer.
In the step (3) of the present invention, it is 10~60cm, preferably 20~50cm that animal wastes, which are shakeout to thickness,.This
Sample is conducive to composite enzyme liquid and is fully infiltrated into animal wastes.A composite enzyme liquid is sprayed on the excrement face of formation；Stirring is equal
A composite enzyme liquid is sprayed after even again；The composite enzyme liquid is sprayed again after playing heap.It can make composite enzyme in this way
Liquid and animal wastes are sufficiently mixed, and reduce incorporation time.The mode of stirring is not particularly limited, for example, by using rotary cultivator or
Other Mixing Machines are stirred.Rise heap heap it is wide can be 1~10m, preferably 2~6m；Heap height can be 1~5m, preferably
For 2~3m.Due to taking the mode of unsettled bulk, heap body is not easy wide excessively high, is otherwise unfavorable for having kept temperature and moisture.It is close
The mode of envelope preferably with solar film or is protected from light the objects such as the good felt of closure, blanket and covers sealing.The time of fermentation can be with 20~50
It, preferably 25~35 days.
The tunning that step (3) is obtained obtains compound ferment by crushing, screening, mixing and packaging and other steps
Fertilizer.Method those of known in the art may be used in above-mentioned steps, and which is not described herein again.
The present invention also provides a kind of composite enzyme fertilizer, and any of the above-described preparation method is used to obtain.The present invention's answers
It closes ferment fertilizer and contains various active probiotics, such as lactic acid bacteria, actinomyces, photosynthetic bacteria, nitrogen-fixing bacteria, bacillus subtilis, ferment
Female bacterium etc..
The raw materials used method of the present invention includes leaf, reduces the production cost of composite enzyme.The present invention is by zymotic fluid
Directly dilution is fermented for fertilizer, reduces fertilizer production cost.In addition, fertilizer fermentation can be reduced using above-mentioned composite enzyme
Time.According to currently preferred technical solution, composite enzyme fertilizer using the present invention can reduce 50% or more chemical fertilizer use
Amount.
Specific implementation mode
With reference to specific embodiment, the present invention is further illustrated, but protection scope of the present invention is not limited to
This.
Total bacteria count is measured using GB20287-2006.Lactic acid bacteria is measured using GB4789.35-2016.Using GB/T26428
Measure other bacterial populations such as bacillus subtilis.
Fruit ferment is prepared using the method for CN103609985A disclosed embodiments 1.
Embodiment 1
(1) the required various leaves of fermentation and fruit, pine nut, soybean residue, soya-bean cake, vegetable oil residue, rice bran are cleaned, malt sugar
It is diluted with 38 DEG C of warm water, it is spare.Raw material, which is weighed, according to the formula of table 1 carries out dispensing.
Table 1, fermentating formula
By 38 DEG C of water and fruit ferment, leaf (Poplar leaves, pine tree leaf, Folium Pterocaryae, peach leaves, apple leaf and loquat
Leaf), fruit (pears, apple, hawthorn, blueberry, orange, apricot and lichee), pine nut, soybean residue, soya-bean cake, vegetable oil residue, rice bran and sugar
Dilute (being diluted with water, but the total amount of water is constant) mixes, and is aerated 60 minutes or so, obtains mixture.By mixture in closed hair
It ferments 30 days or so in fermentation tank, obtains zymotic fluid.Preceding 15 days fermentation temperatures are 35 DEG C or so, and subsequent 15 days fermentation temperatures are
25 DEG C or so.It needs within first 25 days to open fermentation tank daily, stirs 30 minutes or so, then cover tightly fermentation tank.It ferments successfully main
Mark is：Fermented liquid has acetic acid taste, the distribution of zymotic fluid surface filiform.After testing, the total bacteria count in zymotic fluid is 3 × 108
~3 × 109CFU/ml, lactic acid bacteria be 80% or more, actinomyces, photosynthetic bacteria, nitrogen-fixing bacteria, bacillus subtilis, saccharomycete etc. its
He accounts for 5~20% by active probiotic.
(2) water of 10 times of weight of the zymotic fluid is diluted, obtains composite enzyme liquid.Animal wastes are shakeout, thickness
For 30cm or so.A composite enzyme liquid is sprayed on excrement face, with rotary cultivator uniform stirring, then sprays a composite enzyme liquid,
Then heap is played, heap width is 5m or so, a height of 2m of heap or so.After playing heap, then a composite enzyme liquid is sprayed, is covered with solar film close
Envelope, continuously ferments 30 days (summer), obtains composite enzyme fertilizer.It is exhausted according to yeastiness, stomata row is formed with club
Gas is conducive to improve curing efficiency.
Fertilizer is prepared using traditional fermentation process, winter needs 120 days or so, 60 days or so summer；Using the present invention
Method prepare fertilizer, winter needs 50 days or so, 30 days or so summer.Fertilizer, strain are prepared using traditional fermentation process
Expense is about 40 yuan/m2, composite enzyme liquid expense of the invention is about 8 yuan/m2Left and right, thus substantially reduce processing cost.
Composite enzyme fertilizer is uniformly sprinkled upon to the earth's surface of 0.07 hectare, during then conpound salto is buried again.Soil can be improved in this way
Fertility, loosing soil be not hardened.It is detected according to GB/T15063-2001, effective bacterium number：200000000/gram, pH value is 6~6.5,
Organic matter >=45%, total nutrient mass fraction (in terms of drying) >=5%.
Embodiment 2
The formula of fermentation is replaced with and is formulated shown in table 2, remaining condition is same as Example 1, obtains composite enzyme fertilizer
Material.
Table 2, fermentating formula
Embodiment 3
The formula of fermentation is replaced with and is formulated shown in table 3, remaining condition is same as Example 1, obtains composite enzyme fertilizer
Material.
Table 3, fermentating formula
Present invention is not limited to the embodiments described above, without departing from the essence of the present invention, this field skill
Any deformation, improvement, the replacement that art personnel are contemplated that each fall within the scope of the present invention.
Claims (10)
1. a kind of preparation method of composite enzyme fertilizer, which is characterized in that include the following steps：
(1) by 35~40 DEG C of water and plant enzyme, leaf, fruit, pine nut, soybean residue, soya-bean cake, vegetable oil residue, rice bran and sugar
Dilute mixing is aerated 25~200 minutes, obtains mixture；In the mixture, plant enzyme account for 2~6wt%, leaf account for 3~
8wt%, fruit account for 3~8wt%, pine nut accounts for 0.5~2wt%, soybean residue accounts for 0.5~2wt%, soya-bean cake accounts for 0.5~2wt%, plant
The object dregs of fat account for 0.5~2wt%, rice bran accounts for 0.5~2wt% and malt sugar accounts for 0.5~2wt%；By fermented mixture 30~60 days,
Obtain zymotic fluid；
(2) zymotic fluid is diluted with water, obtains composite enzyme liquid；
(3) animal wastes are contacted with the composite enzyme liquid, ferments 20~50 days, obtains the composite enzyme fertilizer.
2. preparation method according to claim 1, which is characterized in that in step (2), the dosage of water is the zymotic fluid weight
5~50 times of amount.
3. preparation method according to claim 1, which is characterized in that in step (3), animal wastes are shakeout to thickness be
10~60cm sprays the composite enzyme liquid on excrement face；A composite enzyme liquid is sprayed after stirring evenly again；Then it rises
Heap, heap width are 1~10m, and a height of 1~5m of heap；The composite enzyme liquid is sprayed again after playing heap, fermentation 20~50 after sealing
It, obtains the composite enzyme fertilizer.
4. preparation method according to claim 1, which is characterized in that in step (1), preceding 10~15 days fermentation temperatures are
30~40 DEG C, subsequent fermentation temperature is 10~40 DEG C；Need within first 20~25 days stirring 10~50 minutes daily.
5. preparation method according to claim 1, which is characterized in that in the mixture of step (1), plant enzyme accounts for 3
~5wt%, leaf account for 6~7.5wt%, fruit accounts for 6~7.5wt%, pine nut accounts for 1~1.5wt%, soybean residue account for 1~
1.5wt%, soya-bean cake account for 1~1.5wt%, vegetable oil residue accounts for 1~1.5wt%, rice bran accounts for 1~1.5wt% and malt sugar account for 1~
1.5wt%.
6. preparation method according to claim 1, which is characterized in that in step (1), the leaf includes Poplar leaves, pine
Leaf, Folium Pterocaryae, peach leaves, apple leaf and loguat leaf；The fruit includes pears, apple, hawthorn, blueberry, orange, apricot and litchi
Branch.
7. preparation method according to claim 6, which is characterized in that in step (1), Poplar leaves, pine tree leaf, Folium Pterocaryae,
The weight ratio of peach leaves, apple leaf and loguat leaf is 1~1.5:1~1.5:1~1.5:1~1.5:1~1.5:1~1.5；Pears,
Apple, hawthorn, blueberry, orange, apricot and lichee weight ratio be 1~1.5:1~1.5:1~1.5:1~1.5:1~1.5:1~
1.5:1~1.5.
8. preparation method according to claim 1, which is characterized in that in step (1), the leaf is by Poplar leaves, pine tree
Leaf, Folium Pterocaryae, peach leaves, apple leaf and loguat leaf composition；The fruit is by pears, apple, hawthorn, blueberry, orange, apricot and lichee
Composition.
9. preparation method according to claim 8, which is characterized in that in step (1), Poplar leaves, pine tree leaf, Folium Pterocaryae,
The weight ratio of peach leaves, apple leaf and loguat leaf is 1~1.5:1~1.5:1~1.5:1~1.5:1~1.5:1~1.5；Pears,
Apple, hawthorn, blueberry, orange, apricot and lichee weight ratio be 1~1.5:1~1.5:1~1.5:1~1.5:1~1.5:1~
1.5:1~1.5.
10. a kind of composite enzyme fertilizer, which is characterized in that obtained using claim 1~9 any one of them preparation method.
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| CN109232028A (en) * | 2018-09-21 | 2019-01-18 | 大连市竹庭休闲农业有限公司 | A kind of ferment fertilizer and preparation method thereof |
| CN109516846A (en) * | 2019-01-29 | 2019-03-26 | 青海大学 | A kind of bar-headed goose manure fermentation method |
| CN109928839A (en) * | 2019-05-10 | 2019-06-25 | 内蒙古普拉瑞斯环保科技有限责任公司 | Fertilizer and preparation method thereof based on plant stalk substance |
| CN110452034A (en) * | 2019-08-22 | 2019-11-15 | 渭南顺天农用酵素科技有限公司 | A kind of solid agricultural plant ferment and preparation method thereof |
| CN110713423A (en) * | 2019-08-27 | 2020-01-21 | 山东圣鹏科技股份有限公司 | Enzyme fertilizer and preparation method and application thereof |
| CN112500216A (en) * | 2020-11-02 | 2021-03-16 | 东北农业大学 | Bio-organic fertilizer with crop rooting promoting function and preparation method thereof |
| CN113135779A (en) * | 2021-03-03 | 2021-07-20 | 北京福缘地科技有限公司 | Agricultural plant enzyme for preparing compost on site in field by using livestock and poultry manure |
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