CN108329426B - 一种n-乙烯基吡咯烷酮和n-乙烯基己内酰胺的无规共聚物溶液及其制备方法 - Google Patents
一种n-乙烯基吡咯烷酮和n-乙烯基己内酰胺的无规共聚物溶液及其制备方法 Download PDFInfo
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- CN108329426B CN108329426B CN201810127888.3A CN201810127888A CN108329426B CN 108329426 B CN108329426 B CN 108329426B CN 201810127888 A CN201810127888 A CN 201810127888A CN 108329426 B CN108329426 B CN 108329426B
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- Prior art keywords
- vinyl pyrrolidone
- random copolymer
- added
- vinyl
- parts
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- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 title claims abstract description 56
- 229920005604 random copolymer Polymers 0.000 title claims abstract description 42
- JWYVGKFDLWWQJX-UHFFFAOYSA-N 1-ethenylazepan-2-one Chemical compound C=CN1CCCCCC1=O JWYVGKFDLWWQJX-UHFFFAOYSA-N 0.000 title claims abstract description 40
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- 239000007787 solid Substances 0.000 claims abstract description 19
- 229920001577 copolymer Polymers 0.000 claims abstract description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 55
- 239000000243 solution Substances 0.000 claims description 48
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 47
- 238000006243 chemical reaction Methods 0.000 claims description 37
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 claims description 35
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 21
- 239000002904 solvent Substances 0.000 claims description 16
- 239000003999 initiator Substances 0.000 claims description 15
- 239000007864 aqueous solution Substances 0.000 claims description 11
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 claims description 7
- 239000007795 chemical reaction product Substances 0.000 claims description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 3
- 230000035484 reaction time Effects 0.000 claims description 3
- 230000000379 polymerizing effect Effects 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims 4
- -1 azodiisoheptonitrile Chemical compound 0.000 claims 1
- 239000000203 mixture Substances 0.000 abstract description 7
- 239000012456 homogeneous solution Substances 0.000 abstract 1
- 238000003756 stirring Methods 0.000 description 12
- 229920000642 polymer Polymers 0.000 description 8
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 5
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 4
- 229920000191 poly(N-vinyl pyrrolidone) Polymers 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 230000035945 sensitivity Effects 0.000 description 3
- 239000003431 cross linking reagent Substances 0.000 description 2
- 125000001165 hydrophobic group Chemical group 0.000 description 2
- 231100000053 low toxicity Toxicity 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- OSSNTDFYBPYIEC-UHFFFAOYSA-N 1-ethenylimidazole Chemical compound C=CN1C=CN=C1 OSSNTDFYBPYIEC-UHFFFAOYSA-N 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 241000482268 Zea mays subsp. mays Species 0.000 description 1
- 125000000304 alkynyl group Chemical group 0.000 description 1
- 125000000852 azido group Chemical group *N=[N+]=[N-] 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 239000011557 critical solution Substances 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 235000013373 food additive Nutrition 0.000 description 1
- 239000002778 food additive Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F226/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen
- C08F226/06—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen by a heterocyclic ring containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Materials For Medical Uses (AREA)
- Medicinal Preparation (AREA)
Abstract
Description
Claims (6)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201810127888.3A CN108329426B (zh) | 2018-02-08 | 2018-02-08 | 一种n-乙烯基吡咯烷酮和n-乙烯基己内酰胺的无规共聚物溶液及其制备方法 |
Applications Claiming Priority (1)
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CN201810127888.3A CN108329426B (zh) | 2018-02-08 | 2018-02-08 | 一种n-乙烯基吡咯烷酮和n-乙烯基己内酰胺的无规共聚物溶液及其制备方法 |
Publications (2)
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CN108329426A CN108329426A (zh) | 2018-07-27 |
CN108329426B true CN108329426B (zh) | 2020-11-17 |
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CN201810127888.3A Active CN108329426B (zh) | 2018-02-08 | 2018-02-08 | 一种n-乙烯基吡咯烷酮和n-乙烯基己内酰胺的无规共聚物溶液及其制备方法 |
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CN (1) | CN108329426B (zh) |
Families Citing this family (1)
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CN113409987B (zh) * | 2021-08-19 | 2021-11-16 | 西安宏星电子浆料科技股份有限公司 | 结合剂、有机载体、正面导电银浆及其制备方法和太阳能电池 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4521404A (en) * | 1981-08-13 | 1985-06-04 | Gaf Corporation | Polymeric hair preparation |
CN101563376A (zh) * | 2006-12-21 | 2009-10-21 | 巴斯夫欧洲公司 | 热敏聚合物染料转移抑制剂 |
WO2010056934A1 (en) * | 2008-11-13 | 2010-05-20 | Isp Investments Inc. | Polymers derived from n-vinyl formamide, vinyl amides or acrylamides, and reaction solvent, and the uses thereof |
CN103429630A (zh) * | 2010-09-27 | 2013-12-04 | 罗地亚管理公司 | 水性介质中的n-乙烯基内酰胺的可控自由基聚合 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1207107A (zh) * | 1996-02-06 | 1999-02-03 | Isp投资股份有限公司 | 乙烯基吡咯烷酮和乙烯基己内酰胺的可聚合组合物 |
US20050101740A1 (en) * | 2003-09-01 | 2005-05-12 | Nathalie Mougin | Block ethylenic copolymers comprising a vinyllactam block, cosmetic compositions containing them and cosmetic use of these copolymers |
CN102181275B (zh) * | 2011-02-15 | 2013-04-24 | 中国海洋石油总公司 | 一种复合型水合物抑制剂及其应用 |
CN102276954B (zh) * | 2011-05-28 | 2012-12-19 | 河南工业大学 | 基于n-乙烯基己内酰胺和柠檬酸的形状记忆聚合物及制备方法 |
US10494466B2 (en) * | 2013-03-15 | 2019-12-03 | Isp Investments Llc | Polymers polymerized from at least four monomers, and compositions and uses thereof |
RU2706428C2 (ru) * | 2015-04-28 | 2019-11-19 | Басф Се | Применение состава для отбеливания зубов |
-
2018
- 2018-02-08 CN CN201810127888.3A patent/CN108329426B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4521404A (en) * | 1981-08-13 | 1985-06-04 | Gaf Corporation | Polymeric hair preparation |
CN101563376A (zh) * | 2006-12-21 | 2009-10-21 | 巴斯夫欧洲公司 | 热敏聚合物染料转移抑制剂 |
WO2010056934A1 (en) * | 2008-11-13 | 2010-05-20 | Isp Investments Inc. | Polymers derived from n-vinyl formamide, vinyl amides or acrylamides, and reaction solvent, and the uses thereof |
CN103429630A (zh) * | 2010-09-27 | 2013-12-04 | 罗地亚管理公司 | 水性介质中的n-乙烯基内酰胺的可控自由基聚合 |
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CN108329426A (zh) | 2018-07-27 |
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Effective date of registration: 20220302 Address after: 454450 No. 1888, Cultural Road (eastern section), Poai County, Jiaozuo, Henan Patentee after: Boai Xinkaiyuan Pharmaceutical Co.,Ltd. Address before: 454450 No. 1888, Cultural Road (eastern section), Poai County, Jiaozuo, Henan Patentee before: BOAI NKY MEDICAL HOLDINGS Ltd. |
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Effective date of registration: 20231208 Address after: 454000, located 20 meters north of the intersection of Xinyuan Road and Zhongbing Road in Zhongzhan District, Jiaozuo City, Henan Province, China, inside a technology enterprise incubator Patentee after: Xinkaiyuan (Jiaozuo) Polymer Materials Co.,Ltd. Address before: 454450 No. 1888, Cultural Road (eastern section), Poai County, Jiaozuo, Henan Patentee before: Boai Xinkaiyuan Pharmaceutical Co.,Ltd. |
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