CN108310900A - A kind of nano molecular charcoal - Google Patents
A kind of nano molecular charcoal Download PDFInfo
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- CN108310900A CN108310900A CN201810084796.1A CN201810084796A CN108310900A CN 108310900 A CN108310900 A CN 108310900A CN 201810084796 A CN201810084796 A CN 201810084796A CN 108310900 A CN108310900 A CN 108310900A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/72—Organic compounds not provided for in groups B01D53/48 - B01D53/70, e.g. hydrocarbons
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/81—Solid phase processes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
- B01J20/205—Carbon nanostructures, e.g. nanotubes, nanohorns, nanocones, nanoballs
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/102—Carbon
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
- B01D2257/702—Hydrocarbons
- B01D2257/7027—Aromatic hydrocarbons
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
- B01D2257/704—Solvents not covered by groups B01D2257/702 - B01D2257/7027
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
- B01D2257/708—Volatile organic compounds V.O.C.'s
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Abstract
The invention discloses a kind of nano molecular charcoals, including following component；Active powdered carbon, silicate, effervescent tablet, titanium dioxide, this kind of nano molecular charcoal, not only adsorption capacity and capacity of decomposition are strong, and purification efficiency is high, long shelf-life, the harmful substances such as formaldehyde, Benzene and Homologues in purification air that can be lasting for a long time, and traditional sorbing material is changed without capacity of decomposition, or some have the material of capacity of decomposition but the poor problem of adsorption energy, it is non-volatility, non-corrosive, nontoxic, it is outstanding toxic gas scavenging material, and preparation method is simple, and production cost is low.
Description
Technical field
The present invention relates to material for air purification technical fields, more particularly, to a kind of nano molecular charcoal.
Background technology
Air purification refers to removing haze for indoor various environmental problems offer sterilizings, depositing dust, dispelling harmful finishing
Residual and the total solution such as peculiar smell, raising makes the life better, office conditions, promotes physically and mentally healthy, indoor environmental pollution object
Include mainly radgas, mould, particulate matter, finishing residual, secondhand smoke etc. with pollution source, people need to suck sky when breathing
Gas, oxygen is ingested in alveolar, is then discharged out containing high concentration carbon dioxide and some other toxic, pernicious gas.Research
It was found that people's lung, which can be discharged more than 20, plants noxious material, wherein more than 10 kinds contain volatile poison, therefore, people crowded, air not
It in the room of circulation, often comes over dizzy, have difficulty in breathing, uncomfortable in chest, cold perspiration, nausea etc., symptom occurs in severe patient.In addition, suffering from
Pathogen can be broadcast to other people by the patient of respiratory infectious disease by expiratory air, sneeze, cough, phlegm and nasal mucus etc..
Tobacco will produce nicotine, tar, hydrocyanic acid etc. in burning.Nicotine can excitor nerve, vasoconstriction, rise
Hypertension and reduction tissue blood supply can improve zmount of oxygen consumption by increasing heart rate, and continuous sucking nicotine can excessively make one
It dies.Tar contains a variety of organic compounds, wherein containing substances such as micro BaP, benzene anthracenes, BaP has stronger carcinogenic
Effect.The data that the World Health Organization announces shows the lung cancer death of 65 years old or less male 90/100,75/100 chronic branch gas
The death of Guan Yan and pulmonary emphysema is due to caused by smoking, with being done step-by-step for fairly comfortable life, quality of the people to home environment
It also has higher requirement, finishing has become fashion at home, however people often ignore the living environment by finishing to strong
The influence of health and safety.
In recent years, the room air pollution situation caused by finishing problem was more and more common, and in these finishing pollutions,
Formaldehyde pollution, benzene homologues pollution etc. is very big to the health hazard of human body, causes the attention of all circles' understanding.Currently on the market
Air purifying preparation is mainly based on activated carbon and photocatalyst spray, and activated carbon is administered pernicious gas and is not thorough, because of adsorption saturation
Later, it is particularly easy to the case where pernicious gas overflows, sky is caused to go secondary pollution again occur, photocatalyst spray is of high cost, and
And photocatalyst is that spray is aerial, can only solve the pernicious gases such as the formaldehyde for being discharged into air for the moment, can not solve Interior Space
Gas pollutant acquisition time is up to the fundamental issue of 3-15, therefore, it is also desirable to novel material for air purification be developed, to avoid
It is insufficient existing for current material.
Invention content
The technical problem to be solved by the present invention is to overcome the existing defects, provides a kind of nano molecular charcoal, on solving
State problem.
To achieve the above object, the present invention provides the following technical solutions：A kind of nano molecular charcoal, including following component；
Active powdered carbon, silicate, effervescent tablet, titanium dioxide.
As a preferred technical solution of the present invention, the activity powdered carbon weight is 60%.
As a preferred technical solution of the present invention, the silicate weight is 20%.
As a preferred technical solution of the present invention, the effervesce sheet weight is 5%.
As a preferred technical solution of the present invention, the titania weight is 15%.
Compared with prior art, the beneficial effects of the invention are as follows：This kind of nano molecular charcoal, not only adsorption capacity and resolution
Power is strong, and purification efficiency is high, long shelf-life, and formaldehyde, the Benzene and Homologues etc. in purification air that can be lasting for a long time have
Evil substance, and traditional sorbing material is changed without capacity of decomposition or some have the material of capacity of decomposition but adsorption energy is poor
Problem, it is non-volatility, non-corrosive, nontoxic, it is outstanding toxic gas scavenging material, and preparation method is simple, it is raw
It produces at low cost.
Specific implementation mode
Technical scheme in the embodiment of the invention is clearly and completely described, it is clear that described embodiment is only
It is a part of the embodiment of the present invention, instead of all the embodiments, based on the embodiments of the present invention, ordinary skill people
The every other embodiment that member is obtained without making creative work, shall fall within the protection scope of the present invention.
The present invention provides a kind of technical solution：A kind of nano molecular charcoal, including following component；
Active powdered carbon, silicate, effervescent tablet, titanium dioxide.
Active powdered carbon weight is 60%, and silicate weight is 20%, and effervesce sheet weight is 5%, and titania weight is
15%.
Embodiment 1
Active powdered carbon, silicate, effervescent tablet, titanium dioxide are weighed respectively, 10- is evacuated to by the container equipped with substance to be evaporated
After 6Pa high vacuum, it is filled with inert gas, then heats 20min, so that substance is evaporated the atom that nebulizes, arrived with inert-gas condensation
On condenser, the particle of the nanoscale of aggregation is collected in the range between 100-120 to get to nano-powder, wherein profit
Hybrid reaction is added by obtained nano powder with hydrothermal deposition and hydrothermal oxidization reaction, obtains metal nano powder oxide or compound
Oxide, the diameter of general active carbon particle at 11 μm or more, in addition, according to the structure and morphology of carbon ball can be divided into hollow carbon sphere,
Solid hard carbon ball, porous carbon ball, nucleocapsid carbon ball and gluey carbon ball pass through point of oxygen and nitrogen that pressure-variable adsorption is realized
From effervesce sheet weight is 5%, and titania weight 15%, the Microporous Carbon that charcoal molecule aperture size is adjusted allows phase
Small O2 molecules (diameter 0.346nm) are rapidly diffused into inside nano-space and block relatively large N2 molecule (diameters
0.364nm), since the kinetic selectivity of O2 is better than N2, so when carbon molecular sieve and air contact, oxygen-enriched absorption can be formed
Phase, here it is the bases that air separation is carried out with carbon molecular sieve, and persistently have to formaldehyde, the Benzene and Homologues etc. in air
It is basic that evil substance is purified.
Embodiment 2
Active powdered carbon, silicate, effervescent tablet, titanium dioxide are weighed respectively, 8- is evacuated to by the container equipped with substance to be evaporated
After 4Pa high vacuum, it is filled with inert gas, then heats 12min, so that substance is evaporated the atom that nebulizes, arrived with inert-gas condensation
On condenser, the particle of the nanoscale of aggregation is collected in the range between 108-110 to get to nano-powder, wherein profit
Hybrid reaction is added by obtained nano powder with hydrothermal deposition and hydrothermal oxidization reaction, obtains metal nano powder oxide or compound
Oxide, the diameter of general active carbon particle at 13 μm or more, in addition, according to the structure and morphology of carbon ball can be divided into hollow carbon sphere,
Solid hard carbon ball, porous carbon ball, nucleocapsid carbon ball and gluey carbon ball pass through point of oxygen and nitrogen that pressure-variable adsorption is realized
From effervesce sheet weight is 3%, and titania weight 12%, the Microporous Carbon that charcoal molecule aperture size is adjusted allows phase
Small O2 molecules (diameter 0.346nm) are rapidly diffused into inside nano-space and block relatively large N2 molecule (diameters
0.364nm), since the kinetic selectivity of O2 is better than N2, so when carbon molecular sieve and air contact, oxygen-enriched absorption can be formed
Phase, here it is the bases that air separation is carried out with carbon molecular sieve, and persistently have to formaldehyde, the Benzene and Homologues etc. in air
It is basic that evil substance is purified.
Embodiment 3
Active powdered carbon, silicate, effervescent tablet, titanium dioxide are weighed respectively, 10- is evacuated to by the container equipped with substance to be evaporated
After 8Pa high vacuum, it is filled with inert gas, then heats 23min, so that substance is evaporated the atom that nebulizes, arrived with inert-gas condensation
On condenser, wherein adding hybrid reaction by obtained nano powder using hydrothermal deposition and hydrothermal oxidization reaction, obtains metal and receive
The diameter of rice flour oxide or composite oxides, general active carbon particle passes through the oxygen that pressure-variable adsorption is realized at 10 μm or more
The separation of gas and nitrogen, effervesce sheet weight are 6%, and titania weight 17%, charcoal molecule aperture size is adjusted
Microporous Carbon allows relatively small O2 molecules (diameter 0.346nm) to rapidly diffuse into inside nano-space and block relatively large N2
Molecule (diameter 0.364nm), since the kinetic selectivity of O2 is better than N2, so when carbon molecular sieve and air contact, it can shape
At oxygen-enriched absorption phase, here it is the bases that air separation is carried out with carbon molecular sieve, and persistently in air formaldehyde, benzene and its
The harmful substances such as homologue are purified basic.
Embodiment 4
Active powdered carbon, silicate, effervescent tablet, titanium dioxide are weighed respectively, 11- is evacuated to by the container equipped with substance to be evaporated
After 3Pa high vacuum, it is filled with inert gas, then heats 16min, so that substance is evaporated the atom that nebulizes, arrived with inert-gas condensation
On condenser, the particle of the nanoscale of aggregation is collected in the range between 90-100 to get to nano-powder, wherein utilizing
Hydrothermal deposition and hydrothermal oxidization reaction add hybrid reaction by obtained nano powder, obtain metal nano powder oxide or composite oxygen
Compound, the diameter of general active carbon particle is at 11 μm or more, in addition, can be divided into hollow carbon sphere, reality according to the structure and morphology of carbon ball
Hard-hearted carbon ball, porous carbon ball, nucleocapsid carbon ball and gluey carbon ball pass through point of oxygen and nitrogen that pressure-variable adsorption is realized
From effervesce sheet weight is 4%, and titania weight 14%, the Microporous Carbon that charcoal molecule aperture size is adjusted allows phase
Small O2 molecules (diameter 0.346nm) are rapidly diffused into inside nano-space and block relatively large N2 molecule (diameters
0.364nm), since the kinetic selectivity of O2 is better than N2, so when carbon molecular sieve and air contact, oxygen-enriched absorption can be formed
Phase, here it is the bases that air separation is carried out with carbon molecular sieve, and persistently have to formaldehyde, the Benzene and Homologues etc. in air
It is basic that evil substance is purified.
Embodiment 5
Active powdered carbon, silicate, effervescent tablet, titanium dioxide are weighed respectively, 10- is evacuated to by the container equipped with substance to be evaporated
After 6Pa high vacuum, it is filled with inert gas, then heats 22min, so that substance is evaporated the atom that nebulizes, arrived with inert-gas condensation
On condenser, the particle of the nanoscale of aggregation is collected in the range between 105-130 to get to nano-powder, wherein profit
Hybrid reaction is added by obtained nano powder with hydrothermal deposition and hydrothermal oxidization reaction, obtains metal nano powder oxide or compound
Oxide, the diameter of general active carbon particle at 11 μm or more, in addition, according to the structure and morphology of carbon ball can be divided into hollow carbon sphere,
Solid hard carbon ball, porous carbon ball, nucleocapsid carbon ball and gluey carbon ball pass through point of oxygen and nitrogen that pressure-variable adsorption is realized
From effervesce sheet weight is 5%, and titania weight 15%, the Microporous Carbon that charcoal molecule aperture size is adjusted allows phase
Small O2 molecules (diameter 0.346nm) are rapidly diffused into inside nano-space and block relatively large N2 molecule (diameters
0.364nm), since the kinetic selectivity of O2 is better than N2, so when carbon molecular sieve and air contact, oxygen-enriched absorption can be formed
Phase, here it is the bases that air separation is carried out with carbon molecular sieve, and persistently have to formaldehyde, the Benzene and Homologues etc. in air
It is basic that evil substance is purified.
Embodiment 6
Active powdered carbon, silicate, effervescent tablet, titanium dioxide are weighed respectively, 11- is evacuated to by the container equipped with substance to be evaporated
After 8Pa high vacuum, it is filled with inert gas, then heats 18min, so that substance is evaporated the atom that nebulizes, arrived with inert-gas condensation
On condenser, the particle of the nanoscale of aggregation is collected in the range between 100-120 to get to nano-powder, wherein profit
Hybrid reaction is added by obtained nano powder with hydrothermal deposition and hydrothermal oxidization reaction, obtains metal nano powder oxide or compound
Oxide, the diameter of general active carbon particle at 11 μm or more, in addition, according to the structure and morphology of carbon ball can be divided into hollow carbon sphere,
Solid hard carbon ball, porous carbon ball, nucleocapsid carbon ball and gluey carbon ball pass through point of oxygen and nitrogen that pressure-variable adsorption is realized
From effervesce sheet weight is 6%, and titania weight 17%, the Microporous Carbon that charcoal molecule aperture size is adjusted allows phase
Small O2 molecules (diameter 0.346nm) are rapidly diffused into inside nano-space and block relatively large N2 molecule (diameters
0.364nm), since the kinetic selectivity of O2 is better than N2, so when carbon molecular sieve and air contact, oxygen-enriched absorption can be formed
Phase, here it is the bases that air separation is carried out with carbon molecular sieve, and persistently have to formaldehyde, the Benzene and Homologues etc. in air
It is basic that evil substance is purified.
Concrete principle：In use, nano molecular charcoal distributes purification factor, persistently to formaldehyde, benzene and its homology in air
The harmful substances such as object are purified.
This kind of nano molecular charcoal, not only adsorption capacity and capacity of decomposition are strong, but also purification efficiency is high, long shelf-life, can be with
The harmful substances such as formaldehyde, Benzene and Homologues in lasting for a long time purification air, and change traditional sorbing material without point
Solution ability or some have the material of capacity of decomposition but a poor problem of adsorption energy, it is non-volatility, non-corrosive, nontoxic, be
Outstanding toxic gas scavenging material, and preparation method is simple, and production cost is low.
Finally it should be noted that：The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention,
Although the present invention is described in detail referring to the foregoing embodiments, for those skilled in the art, still may be used
With technical scheme described in the above embodiments is modified or equivalent replacement of some of the technical features,
All within the spirits and principles of the present invention, any modification, equivalent replacement, improvement and so on should be included in the present invention's
Within protection domain.
Claims (5)
1. a kind of nano molecular charcoal, which is characterized in that including following component；
Active powdered carbon, silicate, effervescent tablet, titanium dioxide.
2. a kind of nano molecular charcoal according to claim 1, which is characterized in that the activity powdered carbon weight is 60%.
3. a kind of nano molecular charcoal according to claim 1, which is characterized in that the silicate weight is 20%.
4. a kind of nano molecular charcoal according to claim 1, which is characterized in that the effervesce sheet weight is 5%.
5. a kind of nano molecular charcoal according to claim 1, which is characterized in that the titania weight is 15%.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810084796.1A CN108310900A (en) | 2018-01-29 | 2018-01-29 | A kind of nano molecular charcoal |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810084796.1A CN108310900A (en) | 2018-01-29 | 2018-01-29 | A kind of nano molecular charcoal |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102284287A (en) * | 2010-06-18 | 2011-12-21 | 上海牛翼新能源科技有限公司 | Titanium dioxide molecular sieve supported platinum cold catalyst for removing formaldehyde in indoor air |
| CN104186539A (en) * | 2014-08-01 | 2014-12-10 | 东莞市邦尼洁生物科技有限公司 | Controlled-release agent for purifying spatial environment |
| CN106139893A (en) * | 2016-07-13 | 2016-11-23 | 吴美燕 | A kind of preparation method of the effervesce air purifying preparation removing pernicious gas |
| CN106799000A (en) * | 2017-01-24 | 2017-06-06 | 南京双全科技有限公司 | Except formaldehyde effervescent tablet and preparation method thereof |
-
2018
- 2018-01-29 CN CN201810084796.1A patent/CN108310900A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102284287A (en) * | 2010-06-18 | 2011-12-21 | 上海牛翼新能源科技有限公司 | Titanium dioxide molecular sieve supported platinum cold catalyst for removing formaldehyde in indoor air |
| CN104186539A (en) * | 2014-08-01 | 2014-12-10 | 东莞市邦尼洁生物科技有限公司 | Controlled-release agent for purifying spatial environment |
| CN106139893A (en) * | 2016-07-13 | 2016-11-23 | 吴美燕 | A kind of preparation method of the effervesce air purifying preparation removing pernicious gas |
| CN106799000A (en) * | 2017-01-24 | 2017-06-06 | 南京双全科技有限公司 | Except formaldehyde effervescent tablet and preparation method thereof |
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Application publication date: 20180724 |
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